TW476703B - A polymer resin composite layer and polymer resin coating the metal piping - Google Patents
A polymer resin composite layer and polymer resin coating the metal piping Download PDFInfo
- Publication number
- TW476703B TW476703B TW086114418A TW86114418A TW476703B TW 476703 B TW476703 B TW 476703B TW 086114418 A TW086114418 A TW 086114418A TW 86114418 A TW86114418 A TW 86114418A TW 476703 B TW476703 B TW 476703B
- Authority
- TW
- Taiwan
- Prior art keywords
- adhesive layer
- synthetic resin
- adhesive
- compound
- layer
- Prior art date
Links
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 62
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 52
- 239000002184 metal Substances 0.000 title claims abstract description 52
- 239000011248 coating agent Substances 0.000 title abstract description 4
- 238000000576 coating method Methods 0.000 title abstract description 4
- 239000002952 polymeric resin Substances 0.000 title abstract 5
- 239000002131 composite material Substances 0.000 title abstract 2
- 239000010410 layer Substances 0.000 claims abstract description 51
- 239000012790 adhesive layer Substances 0.000 claims abstract description 39
- 239000000758 substrate Substances 0.000 claims abstract description 19
- 239000003822 epoxy resin Substances 0.000 claims abstract description 12
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 12
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 12
- 229920001400 block copolymer Polymers 0.000 claims abstract description 10
- 239000000057 synthetic resin Substances 0.000 claims description 57
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 44
- 239000000853 adhesive Substances 0.000 claims description 42
- 230000001070 adhesive effect Effects 0.000 claims description 40
- 150000001875 compounds Chemical class 0.000 claims description 14
- -1 olefin compound Chemical class 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 12
- 239000000806 elastomer Substances 0.000 claims description 12
- 230000002079 cooperative effect Effects 0.000 claims description 11
- 239000004593 Epoxy Substances 0.000 claims description 7
- 229910000831 Steel Inorganic materials 0.000 claims description 7
- 238000006735 epoxidation reaction Methods 0.000 claims description 7
- 239000010959 steel Substances 0.000 claims description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical class ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- 239000000956 alloy Substances 0.000 claims 2
- 229910045601 alloy Inorganic materials 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 239000007769 metal material Substances 0.000 claims 2
- 229920001169 thermoplastic Polymers 0.000 claims 2
- 239000004416 thermosoftening plastic Substances 0.000 claims 2
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 abstract description 5
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 abstract 2
- 229920005989 resin Polymers 0.000 description 18
- 239000011347 resin Substances 0.000 description 18
- 238000000034 method Methods 0.000 description 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000005238 degreasing Methods 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 150000002632 lipids Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- AKUNSTOMHUXJOZ-UHFFFAOYSA-N 1-hydroperoxybutane Chemical compound CCCCOO AKUNSTOMHUXJOZ-UHFFFAOYSA-N 0.000 description 1
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- UGWOAPBVIGCNOV-UHFFFAOYSA-N 5-ethenyldec-5-ene Chemical compound CCCCC=C(C=C)CCCC UGWOAPBVIGCNOV-UHFFFAOYSA-N 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000010167 Allium cepa var aggregatum Nutrition 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- YQKXNEWHNMPIKL-UHFFFAOYSA-N Dioxamine Natural products C1=C2OCOC2=CC(C=CC(NCCC=2C=C3OCOC3=CC=2)=O)=C1 YQKXNEWHNMPIKL-UHFFFAOYSA-N 0.000 description 1
- 102000048470 Dixin Human genes 0.000 description 1
- 108700037673 Dixin Proteins 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 241000517307 Pediculus humanus Species 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- MKYQPGPNVYRMHI-UHFFFAOYSA-N Triphenylethylene Chemical compound C=1C=CC=CC=1C=C(C=1C=CC=CC=1)C1=CC=CC=C1 MKYQPGPNVYRMHI-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- HPIGCVXMBGOWTF-UHFFFAOYSA-N isomaltol Natural products CC(=O)C=1OC=CC=1O HPIGCVXMBGOWTF-UHFFFAOYSA-N 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- MZRVEZGGRBJDDB-UHFFFAOYSA-N n-Butyllithium Substances [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- HDBWAWNLGGMZRQ-UHFFFAOYSA-N p-Vinylbiphenyl Chemical compound C1=CC(C=C)=CC=C1C1=CC=CC=C1 HDBWAWNLGGMZRQ-UHFFFAOYSA-N 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
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- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/14—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
- F16L9/147—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups comprising only layers of metal and plastics with or without reinforcement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1355—Elemental metal containing [e.g., substrate, foil, film, coating, etc.]
- Y10T428/1359—Three or more layers [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24959—Thickness [relative or absolute] of adhesive layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
- Y10T428/31522—Next to metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31739—Nylon type
- Y10T428/31743—Next to addition polymer from unsaturated monomer[s]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31924—Including polyene monomers
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- Graft Or Block Polymers (AREA)
Description
476703 A7 B7 五、發明説明（） 發明之詳細說明 本發明係有關藉由於金屬基材層上設置的環氧樹脂系 黏f劑層及由特定的環氧化苯乙烯系熱塑性彈性體而成白勺 黏著劑層，而將合成樹脂層黏著的金屬一合成樹脂積層體 及前述金屬基材層為管狀的合成樹脂被覆金屬管。、曰 背景技術向來，為使金屬基材之耐蝕性提高，乃於金屬 基材上被覆合成知丨月曰而使用，例如，對於金屬管内表面丄被 覆合成樹脂之合成樹脂被覆内襯管，係依膨徑法或縮徑法予 以製造。 、二 在此膨徑法係預先準備金屬管及被覆用合成樹脂管，於 今屬f之内面設有黏著劑層，於其内側置放被覆用合成樹脂 I ’藉由加熱、加壓被覆用合成樹脂管使直徑膨脹，介由 f劑而積層合成樹脂層於金屬管之方法。此種方法係已 =於日本特開昭56-55227號公報、特開昭58-12720號公報， 特開昭59-59418號公報等。 m 俾縮徑法係於金屬管之内面設有黏著劑層，再 合成樹脂管，藉由利用輥筒等使金屬管 者屬管之製造方法。可使用於此種合成樹脂被 經濟部中央標準局員工消費合作社印製 方法的黏著劑，如聚醯胺系或聚s旨系黏著劑 赁予揭不於曰本特開昭56—55227號公報、又丁二 =段共聚體彈性體系熱溶膠黏著劑係予揭示於
Si 報，其他亦使用含有已共聚合不飽和脂 肪私羧酸或其酐的聚烯烴之黏著劑等。 々伽 然而為於金屬基材上積層合成樹脂層即使使用上述黏著 本紙張尺度適用中园丨ϋΓ標準（(210χϋ 476703 A7 B7 五、發明説明（ 劑’金屬基材與被覆合成樹脂層間之耐久黏著性並不足夠。 金，一f成樹脂積層體，由於金屬基材及被覆合成樹脂間之 線膨脹不相同，故由於重覆冷熱循環會使被覆合成樹 脂及金屬官容易產生剝離，此為對由於氣溫之變化所引起的 反覆伸縮亦同樣會生成此種現象。又，由於加工，對已積層 金屬施加彎折、沖孔、截斷等應力時，則金屬與 著並不足夠的情形時使兩者容易剝離。因此 ，乃被要求&咼金屬基材與積層合成樹脂間之黏著性。 發明之指示 妹要本目么^:，檢討有關金屬及合成樹脂間之黏著劑的 si璟蠢=? SΪ用由環氧系樹脂黏著劑及具有特定構 與合成 ㈡ JiSSi 二 Ιϊίί 的耐久性之積層體，以至完成本發^肩&方面亦具有優越 劑層亦’1 供 埽化&物或其部分氫化 濟 部 中 標 準 局 員 工 消 费 合 作 社 ▲卩 製 旨積層體者。又提供ϋ著，金屬— 熱塑性彈性體D之環氧化率相〜 本紙張尺度咖^mtmfTcNs) (210X297公兑） 476703 A7 B7 五、發明説明（ 合成樹，-層，者。再者提供於金屬管上積層以由第一黏著 ，層、第二黏著劑層及合成樹脂層而成的合成樹脂被覆金屬 管者。，艺金屬管之内表面上依序積層以前述第一黏著 劑f1第二黏著劑層及合成樹脂層而成的前述合成樹脂被覆 金屬管。 實施發明之最佳態樣 (1) 金屬一合成樹脂積層體 咕明之金屬一合成樹脂積層體，係由金屬基材層、 /一$者劑層、第二黏著劑層及合成樹脂層而成。 (2) 金屬基材層至於構成 本务明之金屬一合成樹脂積層體的金屬基材，传可使 =^:古銘等加工成板狀者或加4=者係】 3亦了為具有凹凸狀者’亦可為設有洞孔者。又，對金 ίίϊϊΐϊΐ_性、’可進行麟或鑛鉻等，罐酸或鉻 酉义孤等之表面處理，或為使提高黏著性亦 洗、有機化合物之底塗處理。布進仃脱月曰、酸 (3)第一黏著劑層. 經濟部中央標準局員工消费合作社印^ (讀先閱读背而之注意事項6填寫本乔 本發明之金屬一合成樹脂積層體，係於前 層上具有第1黏著劑層。第-黏著劑層基材 著劑（以下稱「第一黏著劑」）而成， 樹脂’計有雙g分A型環氧樹脂、雙鮮型環U用产展氧 清漆型環氧樹脂及各種脂環型環氧樹脂等f^:齡曝 用5化劑，可使用脂肪族胺或芳香族胺 2¼，樹月旨 酐系硬化劑及陽離子系硬化劑等。 、二更化劑、醆 μ氏張尺度適用中國阀家榡卒（CNS ) A4規格（210x297公玲 五、發明説明（ 黏著劑層之厚度宜為5〜2〇〇, 美ίΐίίΐ成於金屬基材層之單為10〜— 基材之兩面上。 干囬亦可予形成於金屬 (4)第二黏著劑層 具有第二黏著劑ί，於第—黏著劑層上 尤宜為50〜300//m。’、者d層之厚度宜為5〜500#m， 構成第二黏著劑層之黏著劑（以 ，J由以苯乙烯系化合物為主怂聚合^㊁:」二) HSiHf化物為主體之聚合體嵌段B而^的源？ 甘/J又，、水脰C之，、輛二烯化合物的雙鍵鍵結經環氧化的 化苯乙烯系熱塑性彈性體D而成的。 至於構成聚合體嵌段A之「苯乙烯系化合物」，例如可 由苯乙烯，α—甲基苯乙烯、乙烯基曱笨，對第三丁基苯乙 烯、二乙烯基苯，對曱基苯乙烯、1· 1 一二苯基苯乙烯、乙 烯基笨、乙烯基蔥等之中選出1種或2種以上，其中以苯乙 烯為佳。 至於構成聚合體嵌段Β之「共軛二烯」，例如可由丁二烯 、異戊二稀、1.3— 丁二烯、2.3 —二曱基一1.3 —丁二烯 ν 1.3 一戊二烯、3-丁基一 1. 3 —辛二烯、苯基一 1· 3 — 丁二烯等之中 選擇1種或2種以上，其中以丁一稀、異戍一細及此專之組合 為佳。 本發明所用的「嵌段共聚體」，通常以苯乙烯系化合物之 構成單位含有量在5〜70重量％為佳，以〜60重量％為較佳 5 $張尺度適用中國國家標準(〇阳）八4規格（21〇><297公釐） υ/uj Α7 五、發明説明（ 又’肷^又共聚體c之重量平均分 〜 以ί 里（Mw)i數月平均分子量（Mn)之比〕Mw/Mn)在10 共聚體c之分子構造，以直鍵狀為宜 烯李化人ϋΑ-Β—α、β—α_β-α、Α_Β_Α_β_Α等構造之苯乙 特^方以有上述構造者時 特公昭43—17979號、特公昭46-32415號 性述的方法’採用_媒等，在惰 體系化合物—共輛二稀化合物Μ共聚 特開日昭犯―87G4號、特公昭43-6636號、或 所，方法，在惰性溶劑中於氫化 上二可，出供本發明之環氧改質嵌段 由醜分析航前程度係藉 經濟部中央標準局員工消费合作社印製 I 體ΐ 共之共、 ，以氫化輸〜5之範 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公犛 476703
、發明説明（ 化劑反Ιίΐί#共聚體C與過氧化氫類、過氧類等之環氧 #] Ψ1¾ ^ f本本、醋酸乙®旨、四氣化碳、氯仿蒙用己燒、核己烧 環氧化劑之中，至於「過惫 斗 麵過1 化芩第三丁基、過氧化氫異：滅」等可2不有過氧化氫 類丄可例示有過m、過乙酸？過2g·又：至於「過氧 。其中以工業規模上可大量製造、芸二二氟過乙酸等 較咼的觀點則以過乙酸為宜。 了廉彳貝購侍，且安定度亦 狀的不同而可予適當選擇, 、。個肷段共聚體之性 酸翻與過氧化氫第三丁基可得觸人減虱，或六竣 I- 閱 背· 意 填 d 訂 經濟部中央標準局員工消费合作社印1?. 氧ί反應之條件並無嚴密的限制，惟例如使用過乙酸 實反應溫度則〜7G。⑽宜。若超·。。_乙酸^夂 2致且，環氧化之反應溫度依一般方法，依所用的環氧 化训^反應性而可適當選擇。又，於反應混合物並不需 別的操=，例如將原料之混合物攪拌2〜;[0小時即可。 、 所得的環氧化苯乙烯系熱塑性彈性體D之單離，係可以 7 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公廣） 經濟部中央榡準局員工消費合作衽印製 五、發明説明（ 氧化苯乙烯系熱塑性彈性體基iffΐ巧拌之下投入環 取終以減形態利用情形’亦可不單』進行。又對 j;原自ίί:之=以㉟g j氧化率， ☆雙ίίίί:經爾化者之百分率，由忒;) 表示⑽-SM s示苯乙烯系化合物之含有量（：量虱化率（％)、 當量之環氧 ⑻= 10000xw/(fXV) (W示滴定時所 數量)(g?、v示演化氯酸之i说以 10 〜 本發明之充分功效，反之若超過40%時，冬期 ίϊί^^,ίίΚ；^ 本發明中’第二黏著射之環氧化苯乙_熱塑性彈㈣ ___ 8 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X297公漦）
D之含有率，以在5 經濟部中央標準局員工消費合作社印製 重量％之篛圚6 >更K之範圍為宜，以在20〜ΐ〇Γ ③ 賦黏樹脂，係可添加松香類、托 、j，烴樹脂，系樹脂或以仏：^脂 ④ 脂對第二黏著劑可添加° 著劑可添加0〜60重量％、。反…、4。此4添加量對第二黏 ⑤ 流動調整劑，係可添加環烷系 ⑥ ：量甲：，第辛以 %之範圍。 里你奵弟一黏者釗可添加〇〜6〇重量 ⑦ ㈣ins要 [紙張尺度適則，CNS) χ 297公鯈 (請先閲讀背面之注意事項6Mr»:r本頁)
/U/UJ A7 B7 五 、發明説明（ 敎塑性劑之製造方法，可使用使環氧化苯乙埽系 及視必要時添加的各成分炫融而混合的ί 盆他2党ίχ化苯乙稀系熱塑性彈性體D溶解於溶劑而盘 要日守在惰性氣體籠罩氣下混合此等成分。 以 (5)合成樹脂層 至成本發明之金屬一合成樹脂積層體的合成樹脂， 聚 二氯乙烯系樹脂、烯烴系樹脂、聚酯系樹脂 酉ώ月女糸树月曰荨，以氯乙烯系樹脂為尤佳。 抖#對1：成樹脂使用氯乙烯系樹脂之情形，可舉計有氣乙烯 树月曰二虱$烯單體及該氯乙烯單體可共聚合的單體之共聚體 、將氣乙烯樹脂後氯化的氣化氯乙烯系樹脂等，可使用此等 之1種或2種以上。 、 且氣化烯單體及該氣乙烯單體可共聚合的單體間之共聚 $，例^可例示有氣乙烯、苯乙烯共聚體、氣乙烯一乙▲共 忒體、氣乙烯一乙烯、醋酸乙烯酯共聚體等。 ’、 經濟部中央標準局員工消费合作社印裝 本發明之金屬一合成樹脂積層體，雖係由金屬基材層 (M層）、第1黏著劑層（B1)、第二黏著劑層⑽)及合成 樹月曰層（P層）構成Μ層一B1層一B2層一P層，惟於金屬基材 層之兩面上設有Β1層，再於其兩面上設有Β2層，更於其兩 面上設有Ρ層之7層（Ρ層一Β2層一Β1層一Μ層一Β1層一G層 一 Ρ層）而成的積層體。 本發明之金屬一合成樹脂積層體上使用的第一黏著劑 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 476703 發明説明（ 乙著劑之環氧化笨 劑，合成樹脂間之黏著心JJ: 而万：J玄黏著 法為i製發^金屬—合成樹脂積層體時，以公知方 層，其次與合成樹脂板同時在加熱:¾¾¾各黏著劑 、6)合成樹被覆金屬管 ，同的線膨脹係數之情形在;ί循1¾¾ J脂完 亦吸收起因於線膨脹係數荽的f耐久性评估 屬基材間之黏著能更堅固。、、、’s<v"，使5成樹脂及金 本發明之合成樹脂被覆金屬管，係 f-黏著劑層（B1層）、第二黏著· ^ (Ρ層）而成者，於金屬管之内 於Bir，B2層，更於其以s以ί ί二】 則―似層―ρ層）而成的積曰層之體_】 經濟部中央榡準局員工消资合作衽印-¾ μ夂之合成樹Ϊ被覆金屬管係於合成樹脂管之外周6 f自宝布溶液狀之第二黏著劑及第一妳 j念―層’將此插入金屬管内而加熱以壓；=月而j 之月取徑法，或可由其他縮徑法等製造。 曰 依本發明之合成樹脂被覆金屬管，由於合成樹脂被覆^ 11
本紙張尺度適用中國國家標準（CNS ) A4規格（2i〇X29mH UJ 五、發明説明（ A7 B7 ，黏著較堅固，可有效的防止金屬管之腐 劇烈的場所所設置的内襯管之情形，可有效的防止 由於溫度差引起的被覆合成樹脂層之剝離。 、 實施例 經濟部中央標準局員工消费合作社印裝 (製造例1) 拌機^迴流冷辭及溫度計之套管反應器内，i人聚了5烯—聚苯乙烯之嵌段共聚體（曰 ^合成，膠股份有限公司製造「TR_」：苯⑽含量4〇%) ^、Sa酸乙酯1，500g並溶解。其次，連續滴下過醋酸之 酉曰馱乙酯溶液169g，在攪拌下進行4(TC3小時環氧化反應。俟 反應液回復主室溫後自反應器取出，加入大量的曱醇使聚合體 析$，過濾後水洗並使乾燥，而得環氧化苯乙烯系埶塑性彈性 體（稱作彈性體A)。彈性體A之環氧當量為 470 (環氧化率= 19%)。 # (製造例2) 於附有攪拌機、迴流冷凝管及溫度計之套管反應器内，饋 入直鏈聚苯乙烯一聚丁二烯一聚苯乙烯之嵌段共聚體（日本合 成橡膠股份有限公司製造、「TR2000」：苯乙烯含量40%) 300g:環己烷3000g並溶解，在溫度60°c加入氫化觸媒二一對 一甲苯基雙（1一環戊二烯基）鈦/環己烷溶液（濃度imm〇i/L) 40njl 二與正丁基鋰溶液（農度5mm〇i/L) 8ml在0°C，2·0 kg/cm2 之氫氣壓力下混合者，並於氫分壓2.5 kg/cm2反應30分鐘。 (請先閱讀背面之注意事項ve:#寫本R ) 4 ，丁 12 本紙張尺度適用中國國家標準（CNS) A4現格（210'〆297公缝） 476703 A7 B7 經濟部中央標率局員工消費合作社印製 五、發明説明（ 所得的部分氫化聚合體溶液，係藉由減壓乾燥以除 劑（源自丁二烯之雙鍵鍵結全體的氫化率3〇%)。將此“二 祭化聚合體300g、環己烷i5〇〇g饋入附有攪拌機、迴流^凝 :^溫度計之套管反應器内並溶解。其次使連續滴下過醋 酉文之30%醋酸乙酯溶液3〇〇g，在攪拌下進行4〇〇c 3小時 化巧應，俟反應液回復主室溫後自反應器取出，加入大量 曱醇使聚合體析出，過濾後水洗並使乾燥，而得環氧當 三環氧化苯乙烯系熱塑性彈性體彈性體B) (環氧化率一33.6%)。 實施例1 、^甲苯'溶解以表1所示的處方由環氧樹脂及硬化劑而 成的第1黏著劑至固形分成5〇重量％，又，於甲苯内溶解由 ϊίί! 1製得的彈性體A及表1記載的賦黏劑至固形分成50 重ϊ% 〇 其次，以曱醇將25mmXl25mmX厚度1.6mm之JIS G3141之 冷鋼板，表面脫脂後，於25_χ(3〇_之範圍依第1黏著劑 、巧2黏著劑，順序予以塗布。各黏著劑層之厚度各為5〇#m 乾燥黏著劑，疊合25_χΐ_η><厚度〇·5_之軟 質聚氣ρ烯（氣化聚氯乙烯）板片，在15(rc施加21^/〇：1112壓 力5分鐘予以黏著，而得金屬一合成樹脂積層體，測定此積 層體之180度剝離強度，拉伸剪力強度。結果示於表工。 /吏用七述製備的第一黏著劑，第二黏著劑，於外徑49_ 之氯^匕聚氯乙烯合成樹脂管之外緣面上，依序塗布第二黏著 劑、苐一黏著劑’各黏著劑之厚度各為15〇、5〇//m，乾 13 本紙張尺度適用中國國家標準（CNS ) A4規格（210x297公釐 (請先間靖背面之注意事項Θ寫本") 、τ
4/0/UJ A7 B7 五、發明説明（ 貫施例2〜5 經濟部中央標準局員工消资合作社印製 著叫與，ΐ備表1所示的第一黏著劑、第1 剪力強度’ “=以义=^表度2、拉伸 (比較例1) 合成樹脂被覆全金屬—合成樹脂積層體及 ，拉伸剪力^行ίΐ ί f⑽度剝離強度 度ϋί度及彈力性，由於18〇 並不佳。 金又較弱，故冷熱循環後之黏著狀態 (比較例2) 實施作黏著劑層黏著以外，與 被覆金屬管’盘|絲彳5丨二工脂積層體及合成樹脂 ，第二黏著劑層即使5 =‘表1、表2 °其結果 較弱，故冷熱循環後由於拉伸剪力強度 請 先-， 閱 4 · 意 事 項 iri 寫 本 4 訂 4/0703 經濟部中央標準局員工消费合作社印製 A7 B7 五、發明説明（ 比較例3 …一黏著劑層僅以第一黏著劑層黏著以外，盘實 5C2眘：得金屬一合成樹脂被覆積層體及合成樹脂 Ϊΐ f，1^貫化例1同法測定180度剝離強度，拉伸剪力 ϊί循環試驗。結果示於表1、表2。其結果，由 性之第二黏著劑層並不存在之故’不會吸收起 因於線知脹係數差的收縮應力，冷熱循環後之黏著狀態並不佳 15 本紙張尺度適用中國國家樣準（CNS ) A4規格（210X 297公婕） (讀先閲讀背而之注意事項4填寫本頁)
476703 A9 ' B9 C9 1 D9 表一1 實施例1 實施例2 寶施例3 Μ施例4 金屬基材之鋼板或鋼管 脫脂處理 脫脂處理 脫脂處理 脫脂處理 第1黏著劑層組成(重量部） EPIKOTE 1001* 1 100 : 100 100 100 D1CY* 2 6 · 6 TMA* 3 16 TETA* 4 6 第2黏翁劑府 苯乙烯系彈性體A 50 50 50 苯乙烯系彈性體B 50 YS Polystar T145* 6 50 50 50 50 Harimak T-80 * 7 黏著強度之評估 18〇度離強度(kg / 25mm) >5.7 >5.3 >5.5 >5.6 拉仲剪力強度(kg/25mm) 56.8 47.8 59.8 57.1 蹈環試驗 初期黏著狀態 〇 〇 〇 〇 冷熱循環70次後 〇 〇 〇 〇 (請先閱讀背面之注意事項再行繪製) * 1.環氧樹脂；汕shell Epoxy股份有限公司製雙酚Λ型環氧樹脂。 *2·硬化劑「二飢基二醯胺」。 經濟部中央標準局員工消費合作社印製 *3.硬化劑「苯均三酸」。 *4.硬化劑「三伸乙基四胺」。 * 6 .赋黏劑；Yasuham (安原)化學股份冇限公司脚 *7.賦黏劑；Hadma化成股份有限公司製松香改質順丁烯二酸樹脂 「llmimak T- 80」。 16 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 476703 A9 B9 C9 D9 圖式
表一2 實施例1 ΓΙ施例2 W施例3 vmm 4 金屣蕋材之鋼板或鋼管 脫脂處理 脫脂處理 脫胎處圳 脫脂處邱 第1黏著劑Μ組成(肅贾部） ΕΡΙΚΟΤΕ 1001* 1 100 100 100 DICY* 2 6 6 6 第2黏著劑層 苯乙烯系彈性體A 50 50 苯乙Μί系彈性體c*5 50 YS Polystar T145*6 50 50 Hai imak T-80 * 7 50 黏著強度之評佔 180度離強度(kg/25mm) >5.1 1.4 >5.3 0.2 拉仲剪力強（kg/25mm) 48.2 28.2 34.1 81.4 循環試驗 . 初期黏著狀態 ‘ 〇 〇 〇 〇 冷熱泥|環70次後 〇 .△ Δ X (請先閲讀背面之注意事項#行繪製) 經濟部中央標準局員工消費合作社印製 * 1.環氧樹脂；油化Shell Epoxy股份有限公司製雙骱Λ邶環氣_脂。 *2.硬(匕劑「二飢邮二醯胺」。 * 5.日本合成橡膠股份有限公司製，「TR 2000」：苯乙烯含M 4U %。 * 6·赋黏劑；Yasuham (安原）股份有限公司製。 *7.赋黏劑；Hmima化成股份有限公司製松香改質順j‘烯二酸樹脂 「HarimakT- 80」。 本紙張尺度適用中國國家標準（ CNS ) A4規格（210X297公釐） 476703 A7 B7 五、發明説明（） 評估試驗 (1) 180度剝離試驗 、+對金屬一合成樹脂積層體，於23°c僅截切積層體之合 成樹脂層成25mmX250mm，以lOOnim/分之速度剝離18〇度 。剝離強度之單位為kgf/cm2。 (2) 拉伸剪力試驗 、對金屬一合成樹脂積層體，於23°d以10麵/分之拉伸 速度進行拉伸剪力試驗，測定剪力強度。 (3) 冷熱循環試驗 以目視方式評估合成樹脂被覆金屬管之初期黏著狀態 。又，以在23°C之冷水浸潰5分鐘的狀態，及在85°c之‘ 水浸f責5分鐘的狀態作為冷熱循環，重複7〇次後，以目^ ^式评估其後之黏著狀態。且，評估後依以下的基準進 行0 (請先閱讀背面之注意事項填寫本頁) 、-口
〇△ X 態。 狀態 的狀 離的。 剝離態 有剝狀 現分的 發部離表有剝 全現乎 完發幾 間間間 烯烯烯 乙乙乙 氣氣氣 聚聚聚 匕匕匕 /1 /1 ΤΊ 氣氣氯 及及及 管管管 岡岡岡 β 0 β 經濟部中央榡準局員工消費合作社印製 產業上之可利用性 μ -金屬基材層及合成樹脂層間之黏著，係以特定 黏者训之組合而進行，可得具有優越黏著性之金屬一 s 脂積層體。第一黏著劑因係金屬基材及第二黏著劑之 以樹脂系黏著劑，故可得與金屬▲才 強度較同的金屬一合成樹脂積層體。又，由於第二 β者背1 ίτ、以具有特定構置之環氧化笨乙稀系熱塑性彈性體為 尺度適财關家縣（CNS ) …A、 5 476703 A7 B7 五、發明説明（） 主成分，故可有效的吸收由於合成樹脂及金屬間之線膨脹係 數之不同引起的變形。因此，可得冷熱循環試驗等之耐久性 優越的金屬一合成樹脂積層體，合成樹脂被覆金屬管。 (請先閲讀背面之Vi.意事項寫本頁) 、-rt 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家榡準（CNS ) Λ4規格（210X297公釐）
Claims (1)
- Λ^； Β8 (:8 D8 申請專利範圍修正 2001/6/26 申請專科範圍… /Ti备' .十： η' t ·Ί ：> — / ?m L 一種合成樹脂積層體，係以金屬基材、環氧樹脂系黏 (請先閱讀背面之注意事項再填寫本頁) 著劑層（第一黏著劑層）、源自苯乙烯系化合物為主 體之聚合體嵌段A及共輛二烯化合物或其部分氫化化 合物為主體之聚合物嵌段B而成的嵌段共聚體c，其 中喪段共聚體C之共輛二烯化合物的雙鍵結構經環氧 化的環氧化苯乙烯系熱塑性彈性體D而成的黏著劑層 (弟一黏著劍層）及氣乙烯系合成樹脂而成，其中第 二黏著劑層係由含有環氧化率為10至40%之環/氧化 苯乙烯系熱塑性彈性體D的5至100重量％之黏著劑 而成者。 2· —種合成樹脂被覆金屬管，係選自鋼、鐵、銅、鋁或 其合金等金屬材料中之一種作成的金屬管件上由環氧 樹脂系黏著劑層（第一黏著劑層）、源自苯乙稀系化 合物為主體之聚合體嵌段A及共軛二烯化合物或其部 分氫化化合物為主體之聚合物嵌段B而成的嵌段共聚 體C，其中嵌段共聚體C之共軛二烯化舍物的雙鍵結 構經環氧化的環氧化苯乙烯系熱塑性彈性體D而成的 黏著劑層（第二黏著劑層）及氯乙烯系合成樹脂經予 積層而成者。 經濟部智慈財.4局員工消費合作社印製 3·如申請專利範圍第2項之合成樹脂被覆金屬管，於選 自鋼、鐵、銅、鋁或其合金等金屬材料中之一種作成 的金屬管件之内表面上係依序積層以由環氧樹脂系黏 著劑層（第一黏著劑層）、源自苯乙烯系化合物為主 體之聚合體嵌段A及共軛二烯化合物或其部分氫化化 合物為主體之聚合物嵌段B而成的嵌段共聚體C，其 中嵌段共聚體C之共軛二烯化合物的雙鍵結構經環氧 化的環氧化苯乙烯系熱塑性彈性體D而成的黏著劑層 (第二黏著劑層）及氣乙烯系合成樹脂而成者。 木紙張尺度適用中國國家標準（CNS ) A4規格（：1〇Χ 29丨公嫠）
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| JP8283085A JPH10109378A (ja) | 1996-10-04 | 1996-10-04 | 金属−合成樹脂積層体および合成樹脂被覆金属管 |
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|---|---|---|---|
| TW086114418A TW476703B (en) | 1996-10-04 | 1997-10-21 | A polymer resin composite layer and polymer resin coating the metal piping |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6113998A (zh) |
| EP (1) | EP0882572B1 (zh) |
| JP (1) | JPH10109378A (zh) |
| KR (1) | KR19990071835A (zh) |
| DE (1) | DE69718622T2 (zh) |
| TW (1) | TW476703B (zh) |
| WO (1) | WO1998014323A1 (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI380915B (zh) * | 2010-04-02 | 2013-01-01 | ||
| TWI380914B (zh) * | 2010-02-11 | 2013-01-01 |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6361146B1 (en) * | 1999-06-15 | 2002-03-26 | Lexmark International, Inc. | Adhesive bonding laminates |
| US6247499B1 (en) * | 1999-08-13 | 2001-06-19 | Ico, Inc. | Pipe wrap corrosion protection system |
| US6976510B2 (en) * | 2000-01-19 | 2005-12-20 | Itt Manufacturing Enterprises, Inc. | Corrosion resistant metal tube and process for making the same |
| EP1361038B1 (de) | 2002-05-07 | 2011-02-02 | Geberit International AG | Verfahren und Vorrichtung zur Herstellung eines Verbundrohres |
| JP4418143B2 (ja) | 2002-08-30 | 2010-02-17 | 横浜ゴム株式会社 | 二酸化炭素冷媒輸送ホース |
| US6974129B2 (en) * | 2003-09-10 | 2005-12-13 | Igt | Gaming device having display with concentrically rotating and translating indicator therefore |
| US8387228B2 (en) | 2004-06-10 | 2013-03-05 | Ati Properties, Inc. | Clad alloy substrates and method for making same |
| US20060093769A1 (en) * | 2004-10-29 | 2006-05-04 | Ghislain Biebuyck | Multilayer tube assembly and methods for forming and using the same |
| FR2886307B1 (fr) * | 2005-05-26 | 2007-07-13 | Arkema Sa | Liant de coextrusion de pe et pp cogreffes dilues dans un pe non greffe. |
| US8696903B2 (en) * | 2005-09-21 | 2014-04-15 | Waters Technologies Corporation | High-pressure tubing |
| DE102007026805B4 (de) * | 2007-06-06 | 2009-08-20 | Woco Industrietechnik Gmbh | Mediendichtes Bauteil, insbesondere Entlüftungsrohr, umfassend mindestens ein Metallteil und mindestens ein Kunststoffteil |
| US20090139661A1 (en) * | 2007-11-30 | 2009-06-04 | Lubrizol Advanced Materials, Inc. | PVC/CPVC Composite Pipe With Metal Interlayer And Process For Making It |
| WO2009088663A1 (en) | 2008-01-02 | 2009-07-16 | Waters Technologies Corporation | Liquid-chromatography conduit assemblies having high-pressure seals |
| JP5778954B2 (ja) * | 2011-03-16 | 2015-09-16 | イビデン株式会社 | 排気管 |
| CN102501434B (zh) * | 2011-09-20 | 2014-01-08 | 徐为尔 | 一种在基材上制造复合涂层的方法及其型材 |
| CN104033667A (zh) * | 2013-03-08 | 2014-09-10 | 天源环保有限公司 | 特种环保改性高分子复合管 |
| DE102015118597A1 (de) * | 2015-10-30 | 2017-05-04 | Salzgitter Flachstahl Gmbh | Metall/Kunststoff-Verbundbauteil und Verfahren zur Herstellung eines solchen Verbundbauteils |
| JP7078068B2 (ja) * | 2019-07-30 | 2022-05-31 | Ｊｆｅスチール株式会社 | 硬質ポリ塩化ビニル被覆めっき鋼管 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3834009A (en) * | 1972-01-13 | 1974-09-10 | Takiron Co | Method of continuously producing a synthetic resin coated pipe |
| JPS5655227A (en) * | 1979-10-12 | 1981-05-15 | Sekisui Chem Co Ltd | Manufacture of pipe lined with polyvinyl chloride resin |
| JPS5812720A (ja) * | 1982-06-16 | 1983-01-24 | Mitsubishi Plastics Ind Ltd | 金属管のライニング方法 |
| JPS5959418A (ja) * | 1982-09-29 | 1984-04-05 | Mitsubishi Plastics Ind Ltd | 金属管のライニング方法 |
| JPH05237932A (ja) * | 1992-02-26 | 1993-09-17 | Sekisui Chem Co Ltd | 合成樹脂ライニング管の製造方法 |
| JPH06143493A (ja) * | 1992-11-11 | 1994-05-24 | Nippon Steel Corp | 高温埋設配管用ポリオレフィン被覆鋼管 |
| JPH06246835A (ja) * | 1993-02-26 | 1994-09-06 | Sekisui Chem Co Ltd | 合成樹脂ライニング管及びその製造方法 |
| US5393818A (en) * | 1993-04-06 | 1995-02-28 | Shell Oil Company | Solvent-free laminating adhesive composition from epoxidized block polymer |
| KR100448562B1 (ko) * | 1995-07-03 | 2004-11-16 | 다이셀 가가꾸 고교 가부시끼가이샤 | 에폭시화블록공중합체,그제법과조성물 |
-
1996
- 1996-10-04 JP JP8283085A patent/JPH10109378A/ja active Pending
-
1997
- 1997-10-01 DE DE69718622T patent/DE69718622T2/de not_active Expired - Fee Related
- 1997-10-01 KR KR1019980704117A patent/KR19990071835A/ko not_active Application Discontinuation
- 1997-10-01 US US09/077,832 patent/US6113998A/en not_active Expired - Fee Related
- 1997-10-01 WO PCT/JP1997/003512 patent/WO1998014323A1/ja not_active Application Discontinuation
- 1997-10-01 EP EP97943134A patent/EP0882572B1/en not_active Expired - Lifetime
- 1997-10-21 TW TW086114418A patent/TW476703B/zh not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI380914B (zh) * | 2010-02-11 | 2013-01-01 | ||
| TWI380915B (zh) * | 2010-04-02 | 2013-01-01 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH10109378A (ja) | 1998-04-28 |
| KR19990071835A (ko) | 1999-09-27 |
| DE69718622D1 (de) | 2003-02-27 |
| EP0882572B1 (en) | 2003-01-22 |
| WO1998014323A1 (fr) | 1998-04-09 |
| EP0882572A1 (en) | 1998-12-09 |
| EP0882572A4 (en) | 2000-01-19 |
| US6113998A (en) | 2000-09-05 |
| DE69718622T2 (de) | 2003-05-22 |
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Legal Events
| Date | Code | Title | Description |
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| GD4A | Issue of patent certificate for granted invention patent | ||
| MM4A | Annulment or lapse of patent due to non-payment of fees |