TW430675B - Supported metallocene catalysts, processes for the preparation thereof, and catalyst systems for olefin polymerization - Google Patents

Supported metallocene catalysts, processes for the preparation thereof, and catalyst systems for olefin polymerization

Info

Publication number
TW430675B
TW430675B TW087117450A TW87117450A TW430675B TW 430675 B TW430675 B TW 430675B TW 087117450 A TW087117450 A TW 087117450A TW 87117450 A TW87117450 A TW 87117450A TW 430675 B TW430675 B TW 430675B
Authority
TW
Taiwan
Prior art keywords
catalyst
supported
fine particle
inorganic fine
supported metallocene
Prior art date
Application number
TW087117450A
Other languages
English (en)
Inventor
Toshihiro Uwai
Tsugoshi Yahata
Jun Saito
Original Assignee
Chisso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chisso Corp filed Critical Chisso Corp
Application granted granted Critical
Publication of TW430675B publication Critical patent/TW430675B/zh

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
TW087117450A 1997-10-22 1998-10-21 Supported metallocene catalysts, processes for the preparation thereof, and catalyst systems for olefin polymerization TW430675B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29003297 1997-10-22

Publications (1)

Publication Number Publication Date
TW430675B true TW430675B (en) 2001-04-21

Family

ID=17750911

Family Applications (1)

Application Number Title Priority Date Filing Date
TW087117450A TW430675B (en) 1997-10-22 1998-10-21 Supported metallocene catalysts, processes for the preparation thereof, and catalyst systems for olefin polymerization

Country Status (8)

Country Link
US (1) US6420501B1 (zh)
EP (1) EP1026177A4 (zh)
JP (1) JP3695331B2 (zh)
KR (1) KR20010031327A (zh)
CN (1) CN1279694A (zh)
AU (1) AU9464198A (zh)
TW (1) TW430675B (zh)
WO (1) WO1999020661A1 (zh)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6346586B1 (en) * 1999-10-22 2002-02-12 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
JP4538768B2 (ja) * 2000-02-03 2010-09-08 チッソ株式会社 ポリオレフィン組成物およびその製造方法。
JP4820472B2 (ja) * 2000-09-13 2011-11-24 日本ポリプロ株式会社 オレフィン重合用触媒成分、オレフィン重合用触媒およびそれを用いたポリオレフィンの製造方法
US6960634B2 (en) * 2001-10-31 2005-11-01 Univation Technologies, Llc Methods for adjusting melt properties of metallocene catalyzed olefin copolymers
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
US6992034B2 (en) * 2003-07-10 2006-01-31 Formosa Plastics Corporation, U.S.A. Catalyst component for olefin polymerization
EP2006070A1 (en) * 2007-06-22 2008-12-24 Total Petrochemicals Research Feluy Process for producing a polyethylene-polypropylene multilayer blown film
KR100992715B1 (ko) 2008-08-21 2010-11-05 삼성토탈 주식회사 폴리올레핀 중합용 촉매의 제조방법 및 그를 이용한 폴리올레핀 중합체 제조방법
CN102050906A (zh) * 2009-10-27 2011-05-11 中国石油化工股份有限公司 茂金属催化剂预聚物及其烯烃聚合方法
WO2012097146A1 (en) 2011-01-14 2012-07-19 W. R. Grace & Co.-Conn. Process of making modified metallocene catalyst, catalyst produced and use thereof
KR101339474B1 (ko) * 2011-11-24 2013-12-10 삼성토탈 주식회사 올레핀 중합 및 공중합용 촉매 및 이를 사용하는 올레핀 중합 또는 공중합 방법
JP6314379B2 (ja) * 2012-07-27 2018-04-25 日本ポリエチレン株式会社 オレフィン重合触媒の製造方法、及びオレフィンの重合方法
CN103980396B (zh) * 2014-04-30 2016-06-15 中国科学院化学研究所 一种可用于3d打印的超高分子量等规聚丙烯树脂及其制备方法和应用
CN105085750A (zh) * 2014-05-08 2015-11-25 中国石油化工股份有限公司 一种聚丙烯催化剂预聚合溶剂
JP7004656B2 (ja) * 2015-12-31 2022-02-04 ハンファ ケミカル コーポレーション 混成メタロセン担持触媒、およびそれを用いたオレフィン重合体の製造方法
KR102291554B1 (ko) * 2016-10-12 2021-08-18 주식회사 엘지화학 폴리프로필렌의 제조 방법
US10968290B2 (en) 2017-03-28 2021-04-06 Exxonmobil Chemical Patents Inc. Metallocene-catalyzed polyalpha-olefins
WO2018182982A2 (en) * 2017-03-28 2018-10-04 Exxonmobil Chemical Patents Inc. Metallocene-catalyzed polyalpha-olefins
CN112409515B (zh) * 2019-08-23 2023-10-20 中国石油化工股份有限公司 茂金属聚丙烯催化剂的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3230763B2 (ja) * 1991-05-31 2001-11-19 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
DE69219206T2 (de) * 1991-05-31 1997-08-28 Mitsui Petrochemical Ind Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation
US5346872A (en) * 1993-01-29 1994-09-13 Quantum Chemical Corporation Cocatalyst for vanadium/titanium containing polymerization catalyst
CN1043474C (zh) * 1993-05-25 1999-05-26 埃克森化学专利公司 烯烃聚合用带载体的金属茂催化剂体系及其制备方法和用途
TW454020B (en) * 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
JP3910651B2 (ja) * 1994-08-09 2007-04-25 三井化学株式会社 有機アルミニウムオキシ組成物の製造方法
JPH08157515A (ja) 1994-12-09 1996-06-18 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
JP3945542B2 (ja) 1994-12-28 2007-07-18 三井化学株式会社 プロピレン重合用触媒およびプロピレン系重合体の製造方法
JPH08325327A (ja) 1995-06-02 1996-12-10 Chisso Corp 高立体規則性ポリプロピレン

Also Published As

Publication number Publication date
CN1279694A (zh) 2001-01-10
US6420501B1 (en) 2002-07-16
AU9464198A (en) 1999-05-10
JP3695331B2 (ja) 2005-09-14
EP1026177A4 (en) 2004-12-08
KR20010031327A (ko) 2001-04-16
EP1026177A1 (en) 2000-08-09
WO1999020661A1 (fr) 1999-04-29

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