TW383335B - A method for manufacturing a chemically adsorbed film and a chemical adsorbent solution for the method - Google Patents

Abstract

The invention provides methods of forming a chemically adsorbed film by contacting a substrate with a solution mixture containing an alkoxysilane surface active agent a non-aqueous solvent and a silanol-condensing catalyst to from a film covalently bonded to the substrate via siloxane bonds. The methods do not generate chlorine gas in the process of forming films and allow practical reaction rates.

Description

V. Description of the invention) The 1X example in Fang's surface decoration description is explained by Shi Shiming, and the explanation is explained. M said that the surface surface of the method is drawn with a diagram that is slightly simplified. The first material of the table, BenQi, is a flat-release hydrolysate, which is divided into two parts for the sake of large-scale display. According to the detailed description of the two examples, the actual application shows that the material of the wood is basically used for the leveling and solution of water. The detailed description of the three horizontal examples shows that the material is basically released, and the water is divided into four large pictures, and the surface is normal. The surface of the figure is broken, and the real surface of the cross section is shown. The real surface shows the basic release of the base material of the surface material. The level of water and water is divided into 5 and the large picture is released. The French surface is refined. The actual surface of the 5 broken cases shown in the figure is clearly shown. The basic solution of the hair material is exemplified by the solution of water. The size of the water is divided into 6 and the map is large. The surface of the French side is refined. The figure 6 on the illustration shows the horizontal surface of the real surface of the hair material, and the solution of the base solution is divided into 7 and the big picture (please read the precautions on the back-? Fill out this page). spring

Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs of the People's Republic of China. The explanation is detailed below. Different types are more than the application. The application should be clear, the application should be clear, and the material is also clear. 'Hair gel, plastic,' ceramic paint such as porcelain '. The oil is coated with gold-a precedent is applied to the surface material.丨 Base a Makes the paper size of instant stone stone paper applicable to China National Standards (CNS) Λ4 坭 (210X 297 public goods) Printed by A7; 'B7 V. Invention Description (/) Invention Description FIELD OF THE INVENTION The present invention relates to a method for producing chemisorption rhenium via a siloxane bond on the surface of a substrate containing active hydrogen, and a chemisorbent solution used in the method. More specifically, the present invention relates to a method for using chelate Method for producing chemisorption membrane by using oxysilane surfactant, non-aqueous solvent and silanol condensation catalyst, and chemisorbent solution used in this method. BACKGROUND OF THE INVENTION The surface portions of substrates such as plastic, metal, ceramic, fiber, wood, concrete, paint, etc. have been modified according to their purpose of use in various fields: for example, methods for improving surfaces containing macromolecules include: coating A method for providing water resistance and oil resistance by fluorosilicone 禹 Yu mixture κ; a method for coating 润滑 κ to provide lubricity; a method for coating with polyvinyl alcohol to provide hydrophilicity; and a method for coating κ carbon ib compound Method of suspending the polymer of the substrate so that the surface of the substrate is not contaminated: the methods mentioned above are well known: · However, the coating film of the prior art K has a weak binding to substrates containing macromolecules Force: Therefore, if the substrate is repeatedly wiped or washed with a cloth, the coating film will peel off from the substrate and lose its finishing effect. In addition, the prior art coating film has many pinholes on its surface because the molecules K are arranged in different directions, so its properties are impaired: even more, μfluorocarbon-based polymer coating films lack light transmission, making them丨 Skins and the like cannot be used in transparent optical materials that require light transmission: -3-This paper size is applicable to China National Standard (CNS) A4 (210X 297 mm) II-nn nn 1--mt ^ —ϋ. ί I ι ^ ϋ —ϋ \ <-...... In -i 1-. —-- I—, v '° (Please read the precautions on the back before filling this page)

Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (/ long) (b) Use cases of cutlery knives 懕 Kitchen knives and other knives Chisels, chisels, drills, badkins, cutting tools, drill bits, adapter blades, juicer blades, flour mill blades, mowing blades, mouth cutters * cutting blades, staplers, can opener blades, Surgical scalpels, etc .; (c) Application examples of needles-acupuncture needles, clothes needles, sewing needles, long thick needles used for tatami manufacturing, injection needles, surgical needles, safety pins, etc. (d) Ceramics Examples of industrial products use ceramic, glass, porcelain or enamel products, including sanitary pottery (such as night pots, wash basins, bathtubs, etc.), tableware (such as rice bowls, plates, bowls, tea cups, glass cups, bottles, coffee pots) , Pots and pots, pots, cups, etc.), vases (such as flower pots, flower pots, small vases, etc.), chemical equipment (such as beakers, reactor vessels, test tubes, flasks, petri dishes, condensers, stirrers) , Search mixer, bowl, vat, injection 茼) Roof tiles, tiles, enamel washbasins, and enamel pots and basins; (e) Mirror application examples-palm mirrors, full-length mirrors, bathroom mirrors, washroom mirrors, car mirrors (rear and side mirrors), half-width Mirrors, window mirrors, department store mirrors, etc .; (f) Molding parts / use cases-molds for compression molds, molds for thin molds, molds for injection molding, molds for transfer molding, molds for vacuum molding, blow molding Gas forming molds, extrusion molds, inflation molds, fiber access molds, calendering rolls; -1 6-This paper size applies Chinese National Standard (CNS) Λ4 specification (210X297) HI-! I -I! — —In n ^ i-I ί— I 士 ^, n ^ i ----- 1 ^ 1 —J Λτ ^ Ί (Please read the notes on the back before filling this page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Β7. 5. Description of the invention (>) The method for manufacturing a chemically-adsorbed monomolecular film was proposed by the inventors of the present invention (Japanese Published Patent No. (T 0 kkai- H ei) 4-1 3 2 6 3 7 Japanese Published Patent No. (_ T okkai-H ei) Japanese Patent Publication No. 4-2 2 1 6 3 Q (Tok k a i-H e i) 4-3 6 7 7 2 1). These films do not peel from the substrate, have no pinholes, have nanometer-level originality, and have high light transmittance, in other words, have light transmittance and gloss. However, according to legend, the traditional method of manufacturing chemisorption membranes is formed by the dehydrochlorination reaction between a nitrogen-based silane-based surfactant and the surface of the substrate: the result is the film formation process. Hazardous hydrogen acid gas is generated. In addition, there are methods that use molecular alkoxysilane surfactants to form a molecular film through a dealcoholization reaction. However, since this reaction proceeds slowly, it cannot be easily formed into a film. It is also possible to use de-alcohol to catalyze dysprosium, but if only a de-catalyst is added, the surfactant will crosslink with the water content in the air and lose its activity. In other words, if water-fluorine is contained in the finishing agent, the surfactant contained in the finishing agent cross-links before reacting to the surface of the substrate, so that the reaction of the solid-liquid interface is suppressed, making it difficult to form ib adsorption. In order to solve the above problems, the object of the present invention is to propose a method for forming rhenium, which has a practical reaction rate and does not generate chlorine hydrochloride gas in the process of forming a film: In order to achieve this objective, The present invention proposes a base with active hydrogen--1-this paper size is applicable to China National Standards (CNS) A4 specification (210X297 mm) --------- 1 clothing --------- --- 1T ------ ^ (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 11-5 ""; 戸 __I I /;, V. Description of the invention (丨 Γ) (g) Ornament application example one—watch, jewelry, pearl, sapphire, ruby, emerald, garnet, opal, diamond, topaz, bloodstone, aquamarine, turquoise, agate, marble, purple Crystal, embossed S stone, opal, crystal, glass Rings, bracelets, brooches, tie pins, earrings, necklaces, eyeglass frames (platinum, gold, silver, aluminum, titanium, tin, alloys of these elements, or made of stainless steel) or others; (h) food molds Application examples: one mold, one mold, bread mold, chocolate mold, jelly mold, ice cream mold, baking tray, ice tray, etc .; (i) Cookware application example: pot and pan, iron pot, pot, pot, frying Pots, hot plates, nets for grilling food, tools for draining oil, plates for takoyaki, etc .; (j) paper application examples 1-photocopying paper, drainage and oil paper, poster paper, high for brochures Quality, etc .; (k) Examples of resin applications-a polyolefin (such as polypropylene, polyethylene, etc.), polyvinyl chloride, polyvinyl chloride, polyimide, polyimide, polyimide, imide, polyester , Aromatic polyester, polystyrene, polycom, polyether®, polyphenylene sulfide, phenol resin, furan resin, urea resin, epoxy resin, polyurethane, silicone resin, ABS resin, Methacrylic resin * ethyl acrylate resin, ester resin, polyacetal, polyoxyphenylene, etc .; (l) Wish Use Cases for Household Electrical Appliances-Cinema Players, Radios, Recording Cards, Audio Cards, CD Players, Refrigerators, Freezers, Air Conditioners, Juicing Cards, Mixers, Fan Blades, Lighting Equipment, Dials, Electrical Hair dryers for perm, etc .; -17- This paper size applies to Chinese National Standards (CNS) Λ4 specifications (210X 297 cm) I mn ϋ IIIIII nn .T n __ n I; __________, good (please read the back first (Notes on this page, please fill in this page again) 5. Description of the invention (j) A7 B7 Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs to the agent oxygen-containing soluble silicon protons form active silicon water and the coating surface has dissolved silicon. The content of the non-reactive base-based water-bonded oxygen-based non-membrane-based non-membrane material is composed of the water boundary ih oxygen and non-monovalent silicon boundary ib oxygen. Non-alkane catalyst is used for co-initiating hydration polymerization by alkane: non-membrane. The silicon compound and the silicon compound have the hydrogenation agent-based condensate, the shape bond KI1 oxygen condensate, and the surface to the step hydrogen-based absorbent dissolved oxygen alcohol. Membrane Alcohol Facet Characteristic Synthetic Characterization The catalysed alkane-surface material oxygen method The surface material of the surface material can be touched by the silicon base and the surface base of the silicon base. The surface bond includes the key material, the key material, and the boundary material, and the boundary material is not included in the boundary line and the alkyl agent warp layer. There is a combination of alkyl and phosphonium, the combination of which has the agent oxygen and the layer coating surface contains agent oxygen. The silicon compound is mixed with the agent to accidentally dissolve the silicon to activate the coating film. The binding of the liquid containing the bond to the word W is composed of the facet membrane. The hydration of the alkane bond to the alkane side is an active fusion of water and water. The results of the "face" include non-metallic compounds, alkyl alkoxides, fluorenyl ketones, fluorene, and common silicon film boundary agents. The material price of the silicon-based materials is based on the cost of the materials. Soluble hydrogen-based co-activating agent to hydrogen-hydrogen-based co-forming agent is formed by silicon adsorption co-activator, square contact with oxygen, surface contact, and contact with the shape of M series of chemical base and water-soluble seed activator. Boundary surface knotting type splicing agent can bond _ fb oxygen to non-physical properties. The alkane surface bond | Contains physical properties. S. 垸 method should be formed into water in the form of a synthetic alcohol. The oxygen side and the shape of the alkyl alkane hydrogen should not be the same, the mixing surface and the base should be shared, the mixing surface should be silicon, and the last silicon bond. The agent liquid boundary agent oxygen to the M agent fatigue boundary solution-less layer Alcohol-soluble alkane-soluble alkene-soluble layer containing bond-soluble alkanes— ^ 1 ^^ i · — · * ^^ 1. ^ im ^ i ^ — 11 ^ 1 i ^ m \ f ^ nm ^ im ^ 1 (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) Α4 Specification (210 × 297 mm) Λ7 ηη (m) Use of a pole ball, (η) (Protective device) V. Description of the invention (Eight sporting goods application examples-ski toe, fishing rod, pole High Jump 'boat, sailing boat, jet ski, surfboard, Gol bowling, fishing line, fishing net, fishing raft, etc. Application examples of auto parts: 1) ABS resin one by one lampshade, dashboard, decoration Parts, car insurance (2) grade vitamin plastic_car flag, and steering wheel, (3) FRP (孅 dimensional reinforced plastic) a bumper and hood, (4) phenol resin a brake, (5) poly Acetal wiper, wiper gear, air valve, carburetor parts, (6) polyamide-radiator fan, (7) polyarylate (polycondensation polymer of bisphenol A and peptidic acid) ~ direction Indicator lights, hood lights, relay covers, (8) polybutylene terephthalate-1 rear, front fenders, (9) polyurethane-di-butylene diimide-1 engine parts, tooth Boxes, wheels, suspension drive systems, (10) methacrylic resin-shade lenses, dials and covers, center marks, (1 1) polypropylene-bumpers (12) polyoxyphenylene_ radiator grille Grid, (13) Polyurethane-bumper, mud board, instrument panel, and fan (14) Unsaturated polyurethane resin, car body, fuel tank, heater cover 18- This paper size applies to Chinese national samples Standard (CNS) Λ4 specification (210X 297 males) n 1- I 1:-I— -I! Shimin—--i-SI—---· τ »-1¾ (Please read the precautions on the back first (Fill in this page) Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Printed by the Central Standards Bureau of the Ministry of Economic Affairs. Printed by the WC Industrial Consumer Cooperatives. B7 ___ 5. The description of the invention (f). The invention further proposes a second method, comprising the steps of: contacting the substrate M with a solution mixture containing at least one first alkoxysilane surfactant, a non-aqueous solvent containing no active hydrogen and a silanol condensation catalyst to form a substrate M An inner layer, which is a sialoxane chemisorption membrane covalently bonded to the surface of the substrate via a siloxane bond M; and a non-aqueous material containing at least one second alkoxysilane surfactant, which does not contain active hydrogen A solution mixture of a solvent and a silanease condensation catalyst contacts the inner layer to form an outer layer, which contains a molecule of the second alkoxysilane surfactant and is chemically bound to the surface of the inner layer by a covalent chain through the siloxane hydrazone. An adsorption membrane, and the first alkoxysilane surfactant and the second alkoxysilane surfactant may be the same or different and are at least one selected from the group consisting of hexaalkoxy Disiloxane, octaalkoxytrisiloxane, dialkoxysilane, trialkoxysilane and tetraalkoxysilane. This method can effectively form a double-layer chemisorption membrane, which has an inner layer of a chemisorbed monomolecular siloxane film and a chemisorbed single-molecule second methoxysilane surfactant film. The second method may include contacting a substrate with a solution mixture containing at least the first alkoxysilane surfactant, a non-aqueous solvent that does not contain active hydrogen, and the silanol condensation catalyst, and one molecule is passed through the siloxane. The alkoxysilane surfactant K is covalently bonded to the surface of the substrate, and the substrate and the first alkoxysilane surfactant are washed with a non-aqueous solvent to form an inner layer containing the siloxane It is a chemically adsorbed monomolecular film that is bonded to the surface of the substrate via a covalent bond of siloxane. The size of this paper containing at least a second alkoxy group is applicable to China National Standard (CNS) A4. (2 丨 〇X 297 Mm) --------------. Order ----- ^ (Please read the notes on the back before filling in this page)

1Γ 5. Description of the Invention (/ 浐) Example 1 The following procedure is used to form a chemisorption military molecular film 13: A blue glass plate 1 containing active hydrogen on its surface is prepared and washed with an alkaline cleaner or equivalent and combined with Thereafter, the M degreasing was washed in water (Fig. 1 (a)); the prepared glass plate 1 was immersed in a chemisorption solution containing the following components: CF3 (CF2) 7 (CH2) 2 containing a catalyst fluorocarbon group S: (〇CH3) 3 (as alkoxysilane surfactant, its amount is 5%; metal carboxylate di-n-butyltin diacetate (as a silane fermentation condensation catalyst), its amount is 0.1% and n Decane (as a non-aqueous liquid solvent containing no active hydrogen), its amount is 94.9%, and the permeation is in a dry air environment with a relative humidity of 30% or lower, at a room temperature of 25C (the solution mixture can be obtained here) It is heated under the boiling point of a non-aqueous solvent for 2 hours; the prepared glass plate is taken out of the adsorption solution and washed thoroughly with chloroform; and the prepared glass plate substrate reacts with water vapor in the air to thereby A layer with a thickness of about 1.5 is formed on the surface of the glass plate 1 through covalent S Water-repellent and oil-repellent monomolecular adsorption membrane 3 (111 (b)) in meters (nm). Furthermore, the water-repellency and oil-repellency of the chemisorbed monomolecular membrane formed in the above procedure were tested by measuring the contact angle. The results are listed in Table 1. It is obvious from Table 1. • The chemical and chemical properties of the chemisorbed military molecular membrane obtained by the method for preparing a chemisorbed monomolecular film according to the present invention have both chemical properties of water drainage and oil drainage, even when 50GOQ is wiped with a wet cloth. There is no loss after this time. Therefore, the root -20- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297) while --------- installation ------- order- ----- " (Please read the notes on the back before filling out this page) Employees of the Central Standards Bureau of the Ministry of Economic Affairs, FFC Cooperative Impressions Employees of the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, printed A7 B7 V. Invention Description (<) A silane surfactant, a non-aqueous solvent containing no active hydrogen, and a weak mixture of the silanol condensation catalyst contact the inner layer, and a molecule of the second alkoxysilane surfactant κ is covalently bonded through the siloxane To the surface of the inner layer, and use a non-aqueous solvent The inner layer and the second alkoxysilane surfactant are washed to form the outer layer, which contains the one molecule of the second alkoxysilane surfactant and is covalently bonded to the surface of the inner layer via a siloxane bond M And the first alkoxysilane surfactant and the second alkoxysilane surfactant may be the same or different and are at least one selected from the group consisting of: Alkoxydisilaxane, octaalkoxytrisiloxane, dialkoxysilane, trialkoxysilane, and tetraalkoxysilane. This method can effectively form a double-layer chemisorption membrane, which It has an inner layer of a chemisorbed monomolecular siloxane siloxane and an outer layer of a chemisorbed single molecule second methoxysilane surfactant film. The second method may also include contacting a substrate with a solution mixture containing at least the first alkoxysilane surfactant, a non-aqueous solvent containing no active hydrogen, and the silanol condensation catalyst, and contacting a substrate via a siloxane bond. The alkoxysilicon surfactant M is covalently bonded to the surface of the substrate, and the substrate and the first alkoxysilicon surfactant are washed with a non-aqueous solution to form an inner layer, which contains siloxy Alkane is a chemisorbed monomolecular film bound to the surface of the substrate via a siloxane bond M covalent bond. A non-aqueous solvent containing at least a second alkoxysilane surfactant, no active hydrogen, and the silanol A solution mixture of a condensation catalyst is contacted with the inner layer, and a molecule of the second alkoxysilane surfactant M is covalently bonded to the inner layer via a siloxane bond. The paper is based on China National Standard (CNS) A4. Specifications (210X297 mm) I nn n ^ i-K ^ i 1 n--II tm UK i-= -1 II ^^ II i: I: ---- (Please read the precautions on the back before filling (This page)

A *) VI Xiu Wang supplemented by the Ministry of Economic Affairs of the Central Bureau of Standards, printed by the Consumer Cooperative Cooperative, Invention Description (i) or through electric discharge treatment, can be used on the surface of substrates without hydroxyl groups, such as plastic or synthetic paper. The hydroxyl group is inserted, thus making the surface hydrophilic. As the hydrophilic group, not only the hydroxyl group (-0Η), but also functional groups such as -COOH, -CHO, -NΗ, and diNΗ2 can be used. However, when using polyimide resins and polyurethane resins with an imine group (-ΝΒ) on the surface, the above-mentioned treatments are not necessary because the imine (-ΝΗ) The active hydrogen and the active hydrogen of the alkoxysilyl group (-SiOA) contained in the chemisorption membrane will accelerate the dealcoholization reaction and form a siloxane bond (-Si〇-). In the case where the substrate is nylon or polyurethane 11, the imine group 12 containing active hydrogen is exposed on the surface, and the chemisorbed monomolecular film 13 is formed in the same manner as the glass plate. Example 2 A polymer-morphic coating 23 was formed by the following procedure. A piece of stainless steel plate 21 containing active hydrogen on its surface is prepared and washed with an alkaline cleaner or the like, and then washed and degreased in water (FIG. 3 (a)). The prepared glass plate is immersed in a chemisorption solution. This mixture contains 5% of CF3 (CF2) 9 (CH2) Si (0CH3) 3 (an alkoxy surfactant) in an amount of 0.5% of the metal carboxylic acid toilet clamp compound- (Ethyl propyl propionate) di-n-butyl tin (as a silanol condensation catalyst) and its amount of 94.5% Fluorinert FC-40 (a product of 3M) (a non-aqueous liquid solvent containing no active hydrogen): its In a nitrogen atmosphere, -25- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297) nn-I— n I ^ iu-I j ---------- Γ n ---- -___ n; I, v '° s {Please read the notes on the back before filling out this page) Printed by A7 B7 of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. The surface of the invention description (heart), The non-aqueous solvent is evaporated, and the alkoxy group contained in the second alkoxysilane surfactant on the surface of the inner layer is reacted with water to form an outer layer. , A chemisorption polymer film containing the second alkoxysilane surfactant and covalently bonded to the surface of the inner layer via a oxalate bond, and the first alkoxysilane surfactant and The second alkoxysilane surfactant may be the same or different and is at least one selected from the group consisting of hexaalkoxydisilaxane, octaalkoxytrisiloxane, and dialkoxy Silanes, trialkoxysilanes and tetraalkoxysilanes. This method can effectively form a double-layer chemisorption membrane having an inner layer of a chemisorbed monomolecular siloxane film and an outer layer of a chemisorbed second alkoxysilane surfactant polymer film. The second method & may include attaching a substrate to a base material using a solvent mixture containing at least the first alkoxysilane surfactant, a non-aqueous solvent containing no active hydrogen, and the silanol condensation catalyst. A molecule of the first alkoxysilane surfactant is bonded to the surface of the substrate with a valence bond, and the water non-aqueous solvent is evaporated off. The first alkoxy group remaining on the surface of the substrate is evaporated. The alkoxy group contained in the silane surfactant reacts with water to form an inner layer of a film containing polyoxocyanine and covalently bonded to the surface of the substrate via a siloxane bond. A solution mixture of a silane-based surfactant, a non-aqueous solvent containing no active hydrogen, and a silanol condensing agent contacts the inner layer, and a molecule of the second alkoxysilane-based surfactant M is covalently bonded via a siloxane bond. Combined with the surface of the inner layer, and washing the substrate and the second alkoxysilane surfactant with a non-aqueous solvent to form the outer layer, which contains the paper standard applicable to China National Standard (CNS) A4 specifications (210 × 297) %)

Hi 1. N. Ml nil--! 1 I—. I 1!--I .1 SI I-(Please read the notes on the back before filling out this page) 5. Description of the invention (5 > 7) Film, Here, a substance containing at least one alkoxysilyl group is chemically adsorbed on the surface of the substrate via a Si atom. In other words, unlike the conventional method, the method of the present invention can efficiently form a protective film on various materials such as plastics, ceramics, and glass jars without generating chlorine gas when forming the film. The present invention can be used for articles that require a thin coating of heat, weather, and abrasion resistance, such as electrical appliances, housewares, automobiles, industrial equipment, mirrors, lenses, or glasses. The present invention may be implemented in other special forms without departing from its spirit or essential characteristics. The embodiments disclosed in this application are to be considered in all respects as illustrative and not restrictive. The scope of the present invention is defined by the appended claims. The scope of the patent application is not the indication of the foregoing description, and all changes that are within the meaning and equivalent scope of the patent application scope are to be included therein. Symbols of the main components of the drawing 1 Glass plate 2 * 32 Hydroxyl 3,13,33 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) 11 Substrate 12 Imide group 2 1 Non-tempered steel plate 2 3 Polymer coating 3 1 Plastic plate 33, 42 Single molecular inner layer with siloxane as matrix This paper is in accordance with Chinese national standard (CNS> A4) (210 X297 mm) Consumers' cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs, Du printed A7 B7. 5. Description of the invention (f) The second alkoxysilane surfactant is a chemisorption unit that is covalently bonded to the inner surface via a siloxane bond. Molecular membrane, and the first alkoxysilane surfactant and the second alkoxysilane surfactant may be the same or different and are at least one selected from the group consisting of: hexaalkoxy Disiloxanes, octaalkoxytrisiloxanes, dialkoxysiloxanes, trialkoxysilanes and tetraalkoxysilanes: This method can effectively form a double-layer chemisorption membrane, which has a Contains an inner layer of polysiloxane and a second alkoxy silicon The outer surface of the surfactant polymer 瞑. The second method may also include contacting a contact group with a solution mixture containing at least the first alkoxysilane surfactant, a non-aqueous solvent containing no active hydrogen, and the silanol condensation catalyst. Material, a molecule of the alkoxysilane surfactant κ is covalently bonded to the surface of the substrate via siloxane, the non-aqueous solvent is distilled off, and the first alkoxide remaining on the surface of the substrate This inner layer is formed by reacting an alkoxy group contained in a silylate surfactant with water, which contains a polysiloxane and is co-bonded to the surface of the substrate via a siloxane bond M, and contains at least a second alkane An oxysilane surfactant, a non-aqueous solvent containing no active hydrogen and a solution mixture of the silanol condensation catalyst contact the inner layer, and a molecule of the second alkoxysilane surfactant is covalently bonded via a siloxane bond. Bonding to the surface of the inner layer, evaporating the non-aqueous solvent, and reacting the alkoxy group contained in the second alkoxysilane surfactant on the surface of the inner layer with water to form an outer layer containing the first Two kinds of alkoxysilicone surfactants are ib-adsorbed polymer films that are covalently bonded to the surface of the inner layer through a siloxane bond M, and the first alkoxysilane surfactant-9-present Paper size is applicable to Chinese National Standard (CNS) A4 now (210X 297 mm) ---------------- ΪΤ ----- ^ (Please read the precautions on the back first (Fill in this page) V. Description of invention bv) 3 4 4 1 4 3 5 1 5 2 5 3 6 1 6 3 6 2 A 'li ft tip filled with molecular outer layer aluminum plate oil drain coating film (polymer film) paper silicon oxide Alkane coated with inner membrane and molecular outer membrane alumina board polymer coated with 瞑 --------- seed coat -------, 1τ ------ I (Please read the note on the back first Please fill in this page again) Printed by the Central Consumers ’Cooperative of the Ministry of Economic Affairs 36 Printed on this paper. Applicable to the Chinese National Standard (CNS) M standard (210 × 297). Printed by the Central Consumers’ Cooperative of the Ministry of Economic Affairs A7 B7. (Multiple) and the second alkoxysilane surfactant may be the same or different and are at least one selected from the group consisting of hexaalkoxydisilaxane, octaalkoxytrisiloxane Siloxanes, dialkoxysilanes, trialkoxysilanes, and tetraalkoxysaranes. This method can effectively form a double-layer chemisorption membrane having an inner diameter containing a polysiloxane and an outer layer that is a second alkoxysilane surfactant polymer. The present invention further proposes a third method, which comprises the steps of: contacting the substrate with a solution mixture containing at least one silane surfactant, a non-aqueous solvent containing no active hydrogen and a silanol condensation catalyst, and forming a composition containing siloxane via a siloxane bond. Siloxane is a chemisorption film that is covalently bonded to the surface of the substrate, and the silane surfactant is at least one selected from the group consisting of hexaalkoxydisiloxane, octyloxy Trisiloxane, dialkoxysilane, trialkoxysilane and tetraalkoxysilane. This method can effectively form a hydrophilic molecular film containing siloxane. The third method may include contacting a substrate with a solution mixture containing at least the silane surfactant, a non-aqueous solvent that does not contain active hydrogen, and a silanol condensation catalyst, and a molecule of the silicon sulfide interfacial activity via the silicon sulfonium. Agent K is covalently bonded to the surface of the substrate and the substrate and the silane surfactant are washed with the non-aqueous solvent to form a silicone-containing agent which is covalently bonded to the surface of the substrate via siloxane K Chemical adsorption monomolecular film, and the silane surfactant is at least one selected from the group consisting of hexaalkoxydisilaxane, octaalkoxytrisiloxane, dialkoxysilane, Trialkoxysilanes and tetraalkoxysilicones. This method can effectively form silicon-10.-This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 > < 297 mm)-installed ------ 1τ ----- line ( Please read the notes on the back before filling this page) A7 B7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the Invention (X) Hydrophilic molecular film of oxane. The third method may also include contacting the substrate with a solution containing at least the silane surfactant, a non-aqueous solvent containing no active hydrogen, and a silanol condensation catalyst, and contacting a molecule of the molecule via a siloxane bond. The silane surfactant K is covalently bonded to the surface of the substrate, the non-aqueous solvent is distilled off, and the alkoxy group contained in the silamine surfactant on the surface of the substrate is reacted with water to form a polysiloxane containing polysiloxane. It is a film bound to the surface of the substrate via a covalent bond of a siloxane bond *, and the silane surfactant is at least one selected from the group consisting of hexaalkoxydisiloxane, octane Oxytrisiloxane, dialkoxysilane, trialkoxysilane and tetraalkoxysilane. This method can effectively form a hydrophilic molecular film containing siloxane. In the method of the present invention, the silanol condensation halide is preferably at least one substance selected from the group consisting of a metal carboxylate, a carboxylic acid ester metal salt, a metal carboxylic acid 13 polymer, and a metal carboxylic acid. Salt clamp compounds, Titanate and Titanate compounds. These catalysts have high catalytic activity. Examples of catalysts include tin (I) acetate, dibutyltin dilaurate, dibutyltin dioctoate, dibutyltin diacetate, dioctyltin dilaurate, dioctyltin dioctoate, dioctyltin diacetate, dioctanoic acid Tin (I), lead naphthenate, cobalt naphthenate, ferric acetate 2-ethylhexanoate, dioctyltin di- (octylthioglycolate), dioctyltin maleate Acetate, dibutyltin maleic acid polymer, dimethyltin hydrosulfide propionate polymer, di-acetylfluorinated dibutyltin, di-ethynyl laurate dioctyltin, titanium Tetrabutyl Titanate, Tetranonyl Titanate and Di- (propyltitanate) Di-Ethylacetonyl § Purpose) These catalysts can be used turbidly or -1 1-This paper size is applicable to Chinese national standards (CNS) Α4 specification (210 × 297 mm) -------- Attack ------ 1T ----- # (Please read the precautions on the back before filling this page) Central Standard of the Ministry of Economic Affairs Bureau employee consumer cooperatives printed policy A 7 'B7 V. Invention description (〖〇) Combined use. In the method of the present invention, the silane surfactant preferably contains a fluorocarbon group. This fluorocarbon-based silane surfactant can provide a second layer (outer layer) having water-repellent, oil-repellent and stain-removing properties. The fluorinated silane-containing silane surfactant comprises a substance represented by one selected from the following two formulae:

WrT⑻nTSiXP (〇A) 3-P where η is 0 or an integer, R represents alkylene, vinylene, ethynyl, aryl, or a substituent containing a silicon atom or an oxygen atom, and m is Q Or 1, X represents a hydrogen atom, healdyl, healdyl, fluorine-containing hexyl or fluoro-containing hexyl, A is alkyl, and P is an integer of G, 1 or 2; and CF3C00-CCH2) w -SiXp (〇A) 3_p where w is an integer, X represents a hydrogen atom, an alkyl group, an alkoxy group, a fluorine-containing alkyl group or a fluorine-containing alkoxy group, and A is an alkyl group, and p is Q, 1 or 2 Integer. In the method of the present invention, the substrate is preferably formed of at least one material family selected from the group consisting of: metal, ceramic, glass, plastic, paper, fabric, and leather: when the substrate is made of plastic When it is formed by synthetic fiber fabric, it is preferred that the substrate be treated with oxygen-containing plasma or placed in a corona discharge enclosure (c 〇r ο naat π sphere) to make the substrate hydrophilic. . This treatment enables the surfactant M to be immobilized on the substrate at a high concentration. In the method of the present invention, the non-aqueous solvent is preferably anhydrous -1 2 containing hydrocarbons. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm). Installation ----- 1τ ---- -Line (Please read the precautions on the back before filling this page) A7 B7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (丨 ./) Solvents or anhydrous solvents containing fluorocarbons. M-carbon compounds are particularly solvent-based solvents that are relatively easy to use because they are less harmful. The term "anhydrous solvent" means a solvent that does not contain water. The invention further provides a chemisorption solution comprising a solution mixture containing at least one alkoxysilane surfactant, a non-aqueous solvent containing no active hydrogen, and a silane alcohol condensation catalyst. The IB adsorption solution may contain other ingredients as long as the ingredients do not inhibit the catalytic reaction. The silanol condensation catalyst disclosed above can also be used in the chemisorption solution of the present invention. The chemical adsorption solution of the present invention may also contain an alkoxysilane surfactant having a fluorocarbon group, particularly a substance represented by one of the two formulas mentioned above. The IB adsorption solution of the present invention may contain a non-aqueous solvent selected from the group consisting of an anhydrous solvent containing a hydroxyl group and an anhydrous solvent containing a fluorocarbon compound. The solution mixture in the chemisorption solution of the present invention preferably has a water content of 1Q P P m or less. The water content has the function of maintaining the stability of the alkoxysilane interfacial activity 劏 and the silanol condensation catalyst ib 劏 and maintaining the pot life of the chemisorption solution. In the present invention, it is preferable that 100 parts by weight of the solution warm compound contains 0.1 to 3 Q parts by weight of an alkoxysilane surfactant, and 0. ㈣ () 1 to 7.5 parts by weight of a silanol condensation catalyst, and 62.5 to 99.9. 99.9 parts by weight of a non-aqueous solvent containing no active hydrogen. The method of the present invention can achieve a practical reaction rate and Forming film-1 3-This paper size applies Chinese National Standard (CNS) A4 specification (210X 297mm)--I mu m.-. ^ 1 ^ 1------i I-111!- ——------^ m I— i — ^ n ------- (Please read the notes on the back before filling out this page) Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5 2. Method of forming a chemical adsorption film that does not generate hydrochloric acid gas in the procedure of the invention description (/ 〆). Before forming the chemical adsorption film, use hexaalkoxydisilaxane * octadecoxytrisiloxane, When a dialkoxysilane, trialkoxysilane, tetraalkane or tetraalkoxysilane is melt-treated on the surface of the substrate, a high-density silanol 鐽 will be produced on the surface of the substrate. Preferred silanol condensation The catalysts are metal carboxylates, carboxylate metal salts, gold phosphonium carboxylate polymers, metal sulfonate adducts, teraesters or titanate clamps. These catalysts are more acidic than the control of the reaction rate. Catalysts are more useful. Fluorocarbon-based alkoxysilane surfactants can improve the drainage and oil drainage of the resulting coatings. In particular, the substances listed in the above two formulas can be used to form high-density chemisorption membranes In addition, the anhydrous hydrocarbon-based non-aqueous solvent or anhydrous M fluorocarbon-based non-aqueous solvent can promote the formation of a high-density chemisorption membrane without reducing the catalytic activity of the catalyst. The fluorocarbon Compound-based, non-aqueous solvents are particularly useful for forming polymer films because the solvents have a small specific heat value and can volatilize quickly. When substrates such as plastics and synthetic fabrics have few active hydrogen atoms on their surfaces The substrate is preferably treated with a plasma containing oxygen or treated with M in a corona discharge enclosure to make the surface hydrophilic: This treatment can promote the formation of a polymer on the surface of the polymer. It is very difficult to form a chemisorption film on a polymer when using traditional methods. The chemisorption solution of the present invention can achieve a useful chemisorption solution. 4-This paper is suitable for China National Standards (CNS) ) Α4 specifications (2! 0 × 297mm) — — — — — — — —.. Taste ^ — I —— III Ding — ___I ^ 0¾ T Koufu (Please read the precautions on the back before filling this page)

V. Description of the invention) The 1X example in Fang's surface decoration description is explained by Shi Shiming, and the explanation is explained. M said that the surface surface of the method is drawn with a diagram that is slightly simplified. The first material of the table, BenQi, is a flat-release hydrolysate, which is divided into two parts for the sake of large-scale display. According to the detailed description of the two examples, the actual application shows that the material of the wood is basically used for the leveling and solution of water. The detailed description of the three horizontal examples shows that the material is basically released, and the water is divided into four large pictures, and the surface is normal. The surface of the figure is broken, and the real surface of the cross section is shown. The real surface shows the basic release of the base material of the surface material. The level of water and water is divided into 5 and the large picture is released. The French surface is refined. The actual surface of the 5 broken cases shown in the figure is clearly shown. The basic solution of the hair material is exemplified by the solution of water. The size of the water is divided into 6 and the map is large. The surface of the French side is refined. The figure 6 on the illustration shows the horizontal surface of the real surface of the hair material, and the solution of the base solution is divided into 7 and the big picture (please read the precautions on the back-? Fill out this page). spring

Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs of the People's Republic of China. The explanation is detailed below. Different types are more than the application. The application should be clear, the application should be clear, and the material is also clear. 'Hair gel, plastic,' ceramic paint such as porcelain '. The oil is coated with gold-a precedent is applied to the surface material.丨 Base a Makes the size of instant paper stone paper applicable to the Chinese National Standard (CNS) Λ4 grid (210X 297 goods)

Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (/ long) (b) Use cases of cutlery knives 懕 Kitchen knives and other knives • Scissors, carving knives, shaving blades, hair clips, saws, planers Chisels, chisels, drills, badkins, cutting tools, drill bits, adapter blades, juicer blades, flour mill blades, mowing blades, mouth cutters * cutting blades, staplers, can opener blades, Surgical scalpels, etc .; (c) Application examples of needles-acupuncture needles, clothes needles, sewing needles, long thick needles used for tatami manufacturing, injection needles, surgical needles, safety pins, etc. (d) Ceramics Examples of industrial products use ceramic, glass, porcelain or enamel products, including sanitary pottery (such as night pots, wash basins, bathtubs, etc.), tableware (such as rice bowls, plates, bowls, tea cups, glass cups, bottles, coffee pots) , Pots and pots, pots, cups, etc.), vases (such as flower pots, flower pots, small vases, etc.), chemical equipment (such as beakers, reactor vessels, test tubes, flasks, petri dishes, condensers, stirrers) , Search mixer, bowl, vat, injection 茼) Roof tiles, tiles, enamel washbasins, and enamel pots and basins; (e) Mirror application examples-palm mirrors, full-length mirrors, bathroom mirrors, washroom mirrors, car mirrors (rear and side mirrors), half-width Mirrors, window mirrors, department store mirrors, etc .; (f) Molding parts / use cases-molds for compression molds, molds for thin molds, molds for injection molding, molds for transfer molding, molds for vacuum molding, blow molding Gas forming molds, extrusion molds, inflation molds, fiber access molds, calendering rolls; -1 6-This paper size applies Chinese National Standard (CNS) Λ4 specification (210X297) HI-! I -I! — —In n ^ i-I ί— I 士 ^, n ^ i ----- 1 ^ 1 —J Λτ ^ Ί (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 11-5 ""; 「__ I I /;, V. Description of Invention (丨 Γ) (g) Ornament Application Example 1-Watch, Jewelry, Pearl, Sapphire, Ruby, Emerald, Garnet, opal, diamond, topaz, bloodstone, aquamarine, turquoise, agate, Dali Stone, amethyst, engraved S stone, opal, crystal, glass, ring, bracelet, brooch, tie pin, earrings, necklace, glasses frame (platinum, gold, silver, aluminum, titanium, tin, these elements Alloy or stainless steel) or others; (h) Food mold application examples-molds, molds, bread molds, chocolate molds, jelly molds, ice cream molds, baking trays, ice trays, etc .; (i) Examples of cookers: pots and pans, iron pots, pans, pots, frying pans, hot plates, grills for grilling food, draining tools, plates for takoyaki, etc .; (j) Examples of paper applications 1—photocopy paper, drainage and oily paper, poster paper, high quality for brochures, etc. (k) resin application examples—polyolefin (such as polypropylene, polyethylene, etc.), polyvinyl chloride, polyvinyl chloride, Polyamine, Polyimide, Polyamidamine, Polyester, Aromatic Polyester, Polystyrene, Polycom, Polyether®, Polyphenylene Sulfide, Phenol Resin, Furan Resin, Urea Resin, Epoxy resin, polyurethane, silicone, ABS resin, methacrylic resin * acrylic Ethyl resin, ester resin, polyacetal, polyoxyphenylene, etc .; (l) Desired use cases of household electrical appliances-movie machines, radios, audio cassettes, audio cassettes, CD players, refrigerators, freezers, air Regulators, juice extractors, blenders, fan blades, lighting equipment, dials, hair dryers for perm hair, etc. -17- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 cm) I mn ϋ IIIIII nn .T n __ n I; __________, good (please read the precautions before filling in this page) Λ7 ηη (m) Use a pole ball, (η) (Protector, V. Description of the invention (Eight sporting goods application examples-ski rafts, fishing rods, pole vaults' boats, sailboats, jet skis, surfboards, Gol bowling, fishing lines, fishing nets, fishing rafts, etc .; cars Application examples of parts: 1) ABS resin one-on-one lampshade, dashboard, decorative parts, car insurance (2) grade Victoria plastic _ car flag, and steering wheel, (3) FRP (孅 dimensional reinforced plastic) a bumper And bonnet, (4) phenolic-brake, (5) polyacetal-wiper, rain Brush gear, air valve, carburetor parts, (6) Polyamide-radiator fan, (7) Polyarylate (polycondensation polymer of bisphenol A and peptidic acid) ~ direction indicator, hood Lights, relay covers, (8) polybutylene terephthalate-a rear, front fender, (9) polyurethane-bis-cis-butene diamidine-engine parts, gear boxes, wheels, Suspension drive system, (10) methacrylate resin-shade lens, watch plate and cover, center mark, (1 1) polypropylene-bumper bar (12) polyoxyphenylene_radiator grid, (13 ) Polyurethane-bumper, mud board, instrument panel, and fan (14) unsaturated polyurethane resin, a car body, fuel tank, heater cover 18-This paper size applies to China's national standard · (CNS ) Λ4 specification (210X 297 males) n 1- I 1:-I— -I! Shimin—--i-SI—---· τ »-1¾ (Please read the precautions on the back before filling this page) Printed by the Consumers 'Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Printed A7 B7 by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the Invention (q) (〇) Application of Stationery Supplies 洌-一Fountain pen, ball pen, mechanical pencil, pencil cover, nails, table, chair, bookcase, bookshelf, phone holder, ruler, drawing tools, etc. (P) Application example of building materials department-roofing materials (such as tiles, Slate, tin such as those used in galvanized iron sheet, external wall materials (such as wood including processed wood, stucco, concrete, ceramic glue, metal glue, brick, building stone, plastic materials, metal materials including aluminum, etc.), internal Materials (for example, wood includes processed wood, metal materials including aluminum, plastic materials, paper, fiber, etc.) or the like; (C1) Examples of stone applications-granite, marble, or similar * for construction, Building materials, artwork, decorations, troughs, tombstones, monuments, gateposts, stone walls, sidewalks, paving stones, etc .; Cr) Application examples of musical instruments and audio equipment-percussion instruments, string instruments, keyboard instruments, woodwind instruments, steel pipes Musical instruments, etc., more specifically, drums, cymbals, violin, cello, guitar, ukulele, piano, fife, clarinet, Shaknhachi, etc. And microphones, speakers, headphones, etc .; ('s) other high-voltage insulators, including thermos flasks, vacuum appliances, electricity transmission insulators, spark plugs, which have good drainage, oil drainage, and drainage properties-this invention is to be referred to the accompanying drawings The following examples and K are explained in detail 3 In the following examples,% indicates weight%. Example 1 -1 9-This paper size is applicable to China National Standard (CNS) A4 specification (210X 297mm) --------. Installation ------ order ----- line (Please read the notes on the back before filling this page)

1Γ 5. Description of the Invention (/ 浐) Example 1 The following procedure is used to form a chemisorption military molecular film 13: A blue glass plate 1 containing active hydrogen on its surface is prepared and washed with an alkaline cleaner or equivalent and combined with Thereafter, the M degreasing was washed in water (Fig. 1 (a)); the prepared glass plate 1 was immersed in a chemisorption solution containing the following components: CF3 (CF2) 7 (CH2) 2 containing a catalyst fluorocarbon group S: (〇CH3) 3 (as alkoxysilane surfactant, its amount is 5%; metal carboxylate di-n-butyltin diacetate (as a silane fermentation condensation catalyst), its amount is 0.1% and n Decane (as a non-aqueous liquid solvent containing no active hydrogen), its amount is 94.9%, and the permeation is in a dry air environment with a relative humidity of 30% or lower, at a room temperature of 25C (the solution mixture can be obtained here) It is heated under the boiling point of a non-aqueous solvent for 2 hours; the prepared glass plate is taken out of the adsorption solution and washed thoroughly with chloroform; and the prepared glass plate substrate reacts with water vapor in the air to thereby A layer with a thickness of about 1.5 is formed on the surface of the glass plate 1 through covalent S Water-repellent and oil-repellent monomolecular adsorption membrane 3 (111 (b)) in meters (nm). Furthermore, the water-repellency and oil-repellency of the chemisorbed monomolecular membrane formed in the above procedure were tested by measuring the contact angle. The results are listed in Table 1. It is obvious from Table 1. • The chemical and chemical properties of the chemisorbed military molecular membrane obtained by the method for preparing a chemisorbed monomolecular film according to the present invention have both chemical properties of water drainage and oil drainage, even when 50GOQ is wiped with a wet cloth. There is no loss after this time. Therefore, the root -20- This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297) while --------- installation ------- order- ----- " (Please read the notes on the back before filling this page) Staff of the Central Standards Bureau of the Ministry of Economic Affairs, Cooperative Impression A7 B7 V. Description of Invention (/ /) If the chemical adsorption solution used in this example When a catalyst is added, the surface of the adsorption solution in contact with the glass plate passes through the alkoxysilyl group (S i 0 R: 1? Epialkyl group) possessed by the alkoxysilane surfactant. In this embodiment, Methyl), water vapor adsorbed on the surface of the glass plate and the surface Reaction was carried out (FIG. 1 (A)) between the 2 groups. The reaction is carried out by catalytic ·· Formula 1 Formula 1 and 2

CF3 (CF2) 7 (CH2) 2-Si〇CH3 + H2〇- (CF >> 7 (CH2) 2 + + CH3 〇H Formula 2 --------- Cloth! (Please read the note on the back first) Please fill in this page again) CF3 (CF2) 7 (CH2) 2-SiOH + HO-dehydration reaction of the substrate> CF3 (CF2) 7 (CH2) 2-Si〇-substrate + H20 Ordered as a result of this treatment On the interface between the glass plate and the adsorption solution, there is at least an alkoxysilane surfactant, which is fixed to the surface of the glass plate by covalent bonding of Si atoms, thereby forming an ultra-thin protective film. It is clear from the formulae 1 and 2 of the example that water is an important element. In other words, if the finish contains water, before it reacts on the surface of the substrate, the finish t is crosslinked: its As a result, the reaction on the solid-liquid-liquid interface is interrupted and a chemical adsorption film cannot be formed properly. The water content in the K finishing agent should be as small as possible, and the water content should preferably not exceed 10 pp m. When the reaction is completed, use a non-aqueous solvent to wash away the glass surface. -21- This paper size is applicable to China National Standard (CNS) A4 standard (210X29?). Central Bureau of Standards, Ministry of Economic Affairs Printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, Consumers’ Cooperative, printed A7 B7 V. Unreacted chemical adsorbent of the invention description (i). As a result, only the covalent knots of Si atoms are fixed on the glass. A monomolecular film composed of alkoxysilane surfactant molecules on the surface of the board, thus forming a layer of chemisorbed monomolecular film 3. For the alkoxysilane surfactant of the present invention, K can be used 31.); 9- (0 A) 4-p Formula (wherein X represents Η, alkyl, alkoxy, or a substituent containing fluoroalkyl or fluoroalkoxy; A represents alkyl; and P represents Q, 1, 2 or 3). In addition, for example, CF 3-(CF 2-U) m-S i X (0 A) is represented by the formula (wherein η is 0 or an integer; R represents an alkylene group, an ethylene group, an ethylene group, or an ethylene group. Aryl or a substituent containing a silicon or oxygen atom; m represents Q or 1; and X represents H, alkyl, alkoxy or a substituent containing fluoroalkyl or fluoroalkoxy; A represents alkyl; and P Table G, 1 or 2) can provide coatings with excellent drainage and oil drainage. However, other agents can also be used as alkoxysilane surfactants. The following are the gardenias available: CH3 ~ (CH2) r- SiXp (OA) 3_p; CH3- (CH2) s-0- (CH2) t-SiXp (0A) 3_p; CH3- (CH2) u-Si ( CH3) 2- (CH2) v-SiXp (OA) 3_p; CF3C00- (CH2) wS: iXp (0A) 3_p; where r is from 1 to 2 5; s is from 0 to 1 2; t is from 1 to 2 0; u is 0 to 1 2; v is 1 to 20; w is 1 to 2 5; X is Η, alkyl, alkoxy or a substituent containing fluoroalkyl or fluoroalkoxy; A is 垸 垸; And p represents Q, 1 or 2. In addition, the following list includes specific examples of these molecules: CH3CH2〇 (CH2) 15Si (OCH3) 3, CF3CH2〇 (CH2) 15Si (OCH3) 3, ch3 (Ch2) 2si (ch3) 2 (ch2) 15si (〇 ch3) 3, ch3 (CH2) 6Si (CH3) 2 (¾) gSi (〇ch3) 3, this paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) -------- Raid- ----- IT -----. ^ (Please read the notes on the back before filling out this page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (Y) CH3COO (CH2) 15Si (OCH3) 3, CF3 (CF2) 5 (CH2) 2Si (OCH3) 3, CF3 (CF2) 7_C6H6_Si (〇CH3) 3, CH3CH2〇 (CH2) 15Si (OC2H5) 3, CH3 (CH2) 2Si (CH3) 2 (CH2) 15Si (OC2H5) 3, CH3 (CH2) 6Si (CH3) 2 (CH2) 9Si (〇C2H5) 3, cf3 (ch2) 6Si (ch3) 2 (ch2) gsi (〇c2h5) 3, CH3COO (CH2 ) 15Si (OC2H5) 3, CF3COO (CH2) 15Si (OC2H5) 3, CF3COO (CH2) 15Si (OCH3) 3 > CF3 (CF2) g (CH2) 2Si (OC2H5) 3, CF3 (CF2) 7 (CH2) 2Si (OC2H5) 3, CF3 (CF2) 5 (CH2) 2Si (OC2H5) 3, CF3 (CF2) 7C6H6Si (OC2H5) 3) CF3 (CF2) g (CH2) 2Si (OCH3) 3, CF3 (CF2) 5 (CH2 ) 2Si (OCH3) 3, cf3 (cf2) 7 (ch2) 2sich3 (〇c2h5) 2, CF3 (CF2) 7 (CH2) 2SiCH3 (0CH3) 2, CF3 (CF2) 7 (CH2) 2Si (CH3) 2. C2H5 ^ CF3 (CF2) 7 (CH2) 2Si (CH3) 2CH3.

In the method for manufacturing a chemisorption membrane of the present invention, the content of the alkoxysilane surfactant is preferably 0 · 1-3 Q% -'I -23- The standard of this paper is applicable to Chinese National Standard (CNS) A4 ( 210X 297 mm) -------- install ------ order ----- line {Please read the precautions on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs Preparation of A7 B7 V. Description of the invention (y > 0 In particular, if a metal carboxylate and a metal carboxylate clamp compound are used, a stable chemisorption membrane can be obtained. Furthermore, the comparison of the silanol condensation catalyst to be used A preferred amount is 0.1 to 2 5% of the amount of the surfactant. If only the alcohol removal reaction using an alkoxy group needs to be accelerated, an inorganic or organic acid can be used instead of the silanol condensation catalyst. However, as mentioned above Moreover, the chemical adsorption liquid is preferably free of water vapor. Therefore, the available catalysts are still limited to silanol condensation catalysts. In addition, for non-aqueous solvents that do not contain active oxygen, non-aqueous K-based hydrocarbon solvents or Carbon fluoride as the solvent and M polysiloxane as Quality solvents. In particular, agents with 1㈣-boiling point can be easily used. For other available solvents, the following can be included: petroleum naphtha, solvent oil, petroleum ether, petroleum benzene, isoalkane, n-alkane, Naphthalene, industrial gasoline, kerosene, petrolatum, dimethyl polysiloxane, phenyl polysiloxane, alkyl modified polysiloxane, polysiloxane. In addition, for K-fluorocarbon-based solvents, It is possible to use M fluorochloroalkane-based solvents, FlLiorinert (a product of 3M) and Afluid (a product of Asahi Glass). The examples mentioned above can be used in the present invention as a liquid or solid medium turbidly or in combination. Examples of substrates useful in the present invention include substrates having active hydrogen, that is, hydroxyl groups, on their surfaces, such as metals such as A 1, Cu or stainless steel, and glass, ceramics, paper, natural fiber fabrics, Leather and other hydrophilic substrates: After being treated at 100 W for 20 minutes in a plasma enclosure containing oxygen, or by corona discharge treatment, it can be used on substrates without hydroxyl groups, such as plastic-24- This paper size is applicable National Standards (CNS) Α4 current grid (210X297 mm). Loaded ------, 1τ ----- line (please read the note and then fill in the back of this page)

A *) VI Xiu Wang supplemented by the Ministry of Economic Affairs of the Central Bureau of Standards, printed by the Consumer Cooperative Cooperative, Invention Description (i) or through electric discharge treatment, can be used on the surface of substrates without hydroxyl groups, such as plastic or synthetic paper. The hydroxyl group is inserted, thus making the surface hydrophilic. As the hydrophilic group, not only the hydroxyl group (-0Η), but also functional groups such as -COOH, -CHO, -NΗ, and diNΗ2 can be used. However, when using polyimide resins and polyurethane resins with an imine group (-ΝΒ) on the surface, the above-mentioned treatments are not necessary because the imine (-ΝΗ) The active hydrogen and the active hydrogen of the alkoxysilyl group (-SiOA) contained in the chemisorption membrane will accelerate the dealcoholization reaction and form a siloxane bond (-Si〇-). In the case where the substrate is nylon or polyurethane 11, the imine group 12 containing active hydrogen is exposed on the surface, and the chemisorbed monomolecular film 13 is formed in the same manner as the glass plate. Example 2 A polymer-morphic coating 23 was formed by the following procedure. A piece of stainless steel plate 21 containing active hydrogen on its surface is prepared and washed with an alkaline cleaner or the like, and then washed and degreased in water (FIG. 3 (a)). The prepared glass plate is immersed in a chemisorption solution. This mixture contains 5% of CF3 (CF2) 9 (CH2) Si (0CH3) 3 (an alkoxy surfactant) in an amount of 0.5% of the metal carboxylic acid toilet clamp compound- (Ethyl propyl propionate) di-n-butyl tin (as a silanol condensation catalyst) and its amount of 94.5% Fluorinert FC-40 (a product of 3M) (a non-aqueous liquid solvent containing no active hydrogen): its In a nitrogen atmosphere, -25- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297) nn-I— n I ^ iu-I j ---------- Γ n ---- -___ n; I, v '° s {Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 ___ 5. Description of the invention (> ^) The prepared substrate is taken out of the adsorption solution and the adsorption solution mentioned above remaining on the surface thereof is evaporated, so that silicon-containing material is formed on the substrate. An alkanol condensation catalyst and an alkoxysilane-based surfactant coating 22, as shown in FIG. 3 (b) (in this procedure, if the adsorption solution is heated, the evaporation can be accelerated .); And then the substrate is allowed to react with the moisture contained in the air to form a water- and oil-repellent polymer coating with a thickness of about 5 nanometers through covalent bonding of Si on the stainless steel plate. 2 3 (Figure 3 (c)). In addition, the drainage and oil drainage properties of the chemisorbed monomolecular film formed by this procedure were also examined in the same manner as in Example 1. The results are shown in Table 1. As is clear from Table 1, the contact angle of the sample in Example 2 is worse than that obtained in Example 1. However, the chemisorbed polymer film treated by the method for manufacturing a chemisorbed monomolecular film of the present invention is even wiped with a wet cloth. After 50000 times, it also hardly damages its drainage and oil drainage properties. According to the method of the present invention, a coating having high durability is proposed. Example 3 K acrylic resin plastic plate 3 1 is used as the base material, and it is treated with 3 QG plasma for 5 minutes. K cleans the surface of the plate and provides active hydroxyl groups 3 2 (see Figure 4 (a) ). The chemical adsorption solution used is a non-aqueous solvent Fluor inert FC-40 and Q.25% dibutyltin dioctanoate, which are non-aqueous solvents using 1% hexamethoxydisilazane and 98.75% K fluorocarbon as the matrix. A solution mixture made as a δ-alkanol condensation catalyst. Hexamethoxydisiloxane is a kind of hexadecane-2 6-This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) -------- 'Packing ------ Order ----- line (please read the precautions on the back before filling this page) A7 B7 V. Description of the invention (> oxydisiloxane: in a dry air environment, the relative humidity will be below 25% The solution mixture was coated on the surface of the plastic plate 31. 'The plastic plate 31 was left to stand in a dry air atmosphere at room temperature for 2 hours. K The hexaalkoxydisilazone was chemically adsorbed on the plastic. Above the plate 31. The plastic plate 31 was washed with a non-aqueous solvent F1 based on M fluorocarbons as a matrix (product of Daiki Industries L td.) To remove excess adsorbent. The remaining unreacted alkoxy group in the adsorbent is hydrolyzed to form K siloxan, which is covalently bonded to the plastic plate 31 via the siloxane bond K. The inner layer 3 3 (see 圔 4 (b)): the inner layer 3 3 is a monomolecular film containing hexamethoxysiloxan. As shown in FIG. 4 (b), the above method provides the plastic plate 31 with many active hydrogen-containing hydroxyl groups. K The contact angle of the obtained single-molecule siloxane film 3 3 was measured in a conventional manner, and the contact angle was 3 (Γ or lower: the surface of the film 3 3 was tested to be hydrophilic: Please note the & I refill the page. Bookmark z C < 1α {宿 / ν · Λ Fsal < JC 垸 tlxro ... i¾ -ΐ'η,-., Ϊ́ 面 1-/ ο 界 ly Μ ο Silicon Is the amount of oxygen and its alkane '' B r0%) 5 3 is the amount of CH (0 and s

ib II The base of ethylene is hydrogen in the amount of ILL · dlN. It contains insoluble%. y is the solubility of ethylene glycol and rt solution.

The plastic glue passes through the S-Carboxyline I line, the Ministry of Economic Affairs, Central Standards Bureau, the Consumer Cooperatives, printed greenhouse N " — -Π El! -RD Ι „· The boiling solubility is high and the PI is converted from 3 to PI Shape layer fri 々 ,. Liquid non-plastic dissolve out of the place taken in Nakahama liquid immersion and dissolving enclosing mixed aspirating liquid The dry solvent from the dry .. Add heat or low temperature or order temperature % ia of 30 immersion ¾ the solvent-soluble water th • ms washing and filling M board is the outer it ro -rJ 1IA board 7 glue (0 plastic SI to the junction Hz bond (C valence 7 total) MF2 Bll I ^ ~ ) Bond ί alkane 3 oxygen CF eg. Has 5 '] containing

Z This paper size applies + National National Standard (CNS) A4 specification (210X297 mm) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Description of the invention (W) The adsorption of a single molecular film (see Figure 4 (C )). The drainage and oil drainage of the obtained chemisorbed monomolecular accumulation layer were tested in the same manner as in Example 1. The test results are shown in Table 1. As can be seen from Table 1, the obtained water-repellent and oil-repellent properties were hardly damaged even after repeatedly wiping and washing the board in two wet markets. The resulting film was found to be a very durable coating. In addition to the surfactant hexamethoxydisiloxane, other agents such as octadecyltrisiloxane, dialkoxysilane, trialkoxysilane or tetraalkoxysilane can also be used. Similar coatings. Example 4 An aluminum plate 41 treated with sodium alumite (a 1 umite) was used as a substrate and thoroughly washed (see FIG. 5 (a)): The chemical adsorption solution used was rumored to reduce the amount to 3%. Hexahexyloxydisiloxane and its amount of 96.5% as a non-aqueous solvent without active hydrogen, n-decane and its amount of 0.5% of dioctyltindi (octylthioglycolate 13 as silicon The solution was prepared by condensing the catalyzed ib catalyst by fermentation: 5) The solution mixture was added to the surface of an aluminum plate 41 in a dry atmosphere at room temperature for 2 hours to chemically adsorb hexaethoxydisilazene to Above the aluminum plate 4 1: Then wash the aluminum plate 41M with a non-aqueous solvent one by one to remove excess unreacted adsorption 劏: Hydrolyze unreacted oxygen remaining in the adsorbent to form a siloxane bond through Covalent bond to the inner layer 42 of K 5 々 垸 垸 which is a substrate to the aluminum plate 41 (see FIG. 5 (13)): This inner layer 42 is a hexaethoxy 垸 垸 (monosorbent monolayer film: As shown in Figure 5 (b), the above-2 8-This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) ^^^ 1 II-^^^^ 1 11 · ... I tn--\ ~~ ^---I 11 (Please read the notes on the back before filling this page) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Invention Explanation (> y) The method can raise the co-aluminum plate 4 1 many hydroxyl groups containing active hydrogen: Secondly, use 5% fluoroalkoxysiliconium surfactant CF 3-(CF2) 7 (CH2) 2 Si (OC2) 3, 1% of dioctyltin di- (ethylpanyllaurate) and 94% of non-aqueous non-aqueous solvent F 1 u 〇rinert FC-4 Q Only one solution mixture is prepared. Dioctyltin di- (ethylenyl laurate) is a metal carboxylate clamp compound used as a silanol condensation catalyst. For users: heat the solution mixture to 7inc, and Soak the S-treated aluminum plate 41 in the solution mixture for 10 minutes in a dry + dry gas circle: then remove the aluminum plate 41 from the adsorption solution and remove the remaining adsorbent solution on the substrate. Solvent containing solvent evaporates to form a fluoroalkoxysilane surfactant coating containing the silanol condensation agent on the surface of the substrate: In the immersion process, The heated solution mixture allows the solvent to evaporate quickly: when the substrate is removed from the solution, the methoxyl groups remaining on the substrate react with the moisture contained in the air to form drainage on the stainless plate And oil drain coating 4 3. The coating 4 3 is a polymer film that is bonded to the surface of the board via a silicon bond, and has a thickness of 7 nm (sink 5 (c) ) Examine the drainage and oil draining properties of the IB adsorption monomolecular accumulation layer in the same way as in Example 1. The test results are listed in Table 1. `` As can be seen from Table i. Even in wet cloth After repeated wiping and washing of the board, the water-repellent and oil-repellent properties of the resulting film were also hardly damaged. The obtained film was found to have a very long-lasting coating: Example 5-2 9-The paper size of the paper applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 1 mu ^^^ 1-.-_- ϋ.---1.1 ^ ϋ ^ —. I -1 HI I -I -OJ- ii -I—I ml _ (Please read the precautions on the back before filling this page) 5. Description of the invention (>) The picture shows A7 B7 dry and dry enough: and 0 / «11 ro 5 layers of paper-coated alkoxyhydroxide are agglomerated to form the upper surface sequence table. Among them, the solution-soluble adsorption and chemical absorption on the impregnated paper are good preparations. The alcoholic alkyl active silicon surface is used as a boundary for the alkane {silyloxybutane tetracarboxylic acid. Oxygen% of the texture base A. 1 ④ ¾ is hydrogen-differentiated 10 Active content is not included in the surrounding gas ί nitrogen id temperature 1U room Af system ¾ stains. 4 dip 9, 9 should be; amount} Its agent and solution) body agent liquid ib nature hydration and non-compliance; the heat added at the time of shrinking the residual surface will be dissolved and attached to the paper system with 51 absorbent paper. this Take the solution. (Dissolve the dry and vaporize the aspirate. The solvent will be removed from the aspirated and desorbed water and air will be on the top of the basic oxygen; Table) Paper short 潖 ΙΓ * β can be left in the room to leave residual steam. It consists of the hydroxyl groups that pass through the paper above, and the thickness should be about the same as the thickness.) Knot (b bond figure. A total of 52 membranes 10; (Please read the precautions on the back before filling in this purchase) -Installation-The production line of the Fang Jiansheng system of the seal type corner of the staff consumer cooperative of the Central Prototype Bureau of the Ministry of Economics and the K test system can be hydroxyl 5 without multiple layers. "Paint supply for water and oxygen extraction" · Silicon high surface type with surface paper <! □ In order to contact the surface angle of the K surface angle due to the cause caused by water, the water affinity of the 3 acid FC B The percentage of active amphiphilic surface. 1 boundary j alkanosilyloxy alkane) 3% 5 3 is 2 quantity 0C which 1 (using S 2 /-, /. By 2 times CH times) 7 2 is quantity Its content is 9-9. • Mixing 4 9 liquids is one of the dissolved amount and the other, the fL agent produced by the food 0 promotes the solubility and shrinkage. -Non-alcoholic hydrogen-based silicon active material is based on non-tin based material. Ding 垸 zheng is sixty or twenty paper sizes. Applicable to China National Standard (CNS) A4 specification (210X 297 mm). 5. Description of the invention (> f A7 B7 Add the mixture solution to the 瞑 5 2 in a nitrogen atmosphere: the paper is valenced to the bond to be mixed ΠΜΜ fcs Li Yin Shi Μ The bond-washing bond iodoalkane chloride is post-polymerized with silicon Of course, the high score of the Mi Zhong consists of 20 chambers with a temperature-containing chamber formed in the shape of a hydrolyzed 51 surface spoon, and a white surface.-Fiberglass 3 Water hF 0 The membrane is attached to the suction ib. Examination). Check C) Formula 6 (Same as the same diagram (phase 53 of the middle layer and the outer layer of the film 1) The example of the film is divided into a single sheet and attached to the substrate. The basic knowledge is that it can be displayed because it is clear. The surface water has a high degree of alignment, and there is an inspection tool inspection membrane. Ο achievable oil 5 uufr Ηϋ 0 实 and dragging real f member inspection ί Φ]: Accepted s 3 1U_} η · 7ί Use inferiority at ttl Comparing for Μύι :: [t, Ξ 性 # 2: x tanj < fw 平 Mj 的 不 Ξ _ Qi and must be slashed — 三 户 柔 _ί, ~, as follows: ¾ 的 表 πί compare spoon f d. 0 ow t paper 0: paper and 00 base paper 10 body is a paper solid material should be: wash 2 .__ δ static film if clear coating, alkali oxygen and silicon 6 to form a plate Is sequence Oxygen ceramic noodles 6 examples of the implementation of the system ax 'decoupling (please read the precautions on the back before filling out this page)-installed.,? Τ line Ministry of Economic Affairs Central Standards Bureau staff consumer cooperation Du printed packaging After -4 = ° · pair is 1 which has its liquid-soluble adsorption D + '. ° ¾ plate aluminum ib oxygen active surface 垸 silicon based oxygen finish 1st " alkoxysilyl based % Of oxymethylene hexamethylene stilbene and the middle compound 13% of acid carboxylic acid gold 5 ο the amount of acid is ib and its propyl group is 丨 the amount of oxygen and its solution and hexamer.,} The liquid bell-shaped nature of this ir water 30 is to promote the non-delivery of the warm vaporization M chamber fluid _s in alkane dissolving active with silicon containing static absorption is not 61 as the board surface (for aluminum surface fib board 垸 oxygen The deceased will stay in the country, the remaining lotus will be B.0 in two 94? Rb This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5. Description of the invention :) Disiloxane (in this procedure > if the adsorption solution is heated, its evaporation time can be shortened.); And it will remain on the surface of the cooked alumina board The methoxy group was placed in the air to be hydrolyzed, thereby forming a hydrophilic polysiloxane coating w 6 2 with a thickness of about 5 nm on the surface of the alumina plate via a si-coupling junction of si (FIG. 7 ( b)): Secondly, by using 5% fluorocarbon-based alkoxysilane surfactant CF 3-(CF2) 7 (CH2) 2 Si (OC2 H5) 3, the amount of which is 1% of dioctyltin di-acetamidyl laurate salt as a silanol condensation catalyst and the amount of which is 3 4% A non-aqueous solvent F 1 u ο ninert FC-40 containing active hydrogen was used to prepare another chemisorption solution. Take the alumina plate from the adsorption solution and place it in the air, and evaporate the solution remaining on the surface of the plate to form a coating containing aerosol silane surfactant 6 3 If the adsorption solution is heated, the solvent will evaporate. Can be accelerated: Then, the prepared alumina plate is allowed to react with water vapor in the air, thereby forming a water-repellent and oil-repellent polymer state coating film having a thickness of about 6 nm through a polysiloxane bond 6 3 ( Fig. 7 (c) In addition, the drainage and oil drainage properties of the IB adsorption film formed in this procedure were tested in the same manner as in Column 1. The results are listed in Table 1: It is clear from Table 丨 that The chemisorbent polymer formed in Example 6 has water-repellent and oil-repellent properties, that is, after being wiped with a wet cloth 5 0 (] Q [) times & hardly damaged: according to the method of the present invention, the Highly applicable coating film: -3 2-This paper size applies the Chinese National Standard (CMS) A4 specification (210X297 mm) ^^^^ 1 HHV fn ^ i ^^^^ 1 \ β, v'o service (Please read the precautions on the back before filling out this page) A7 B7 V. Invention Description U / :) Reference 1 The same experiment as described in Example 1, but in this case the chemical adsorption solution is free of di-n-butyltin diacetate. The results are listed in Table 1. The durability of the coating obtained after wiping 50,000 Q Q times has virtually been lost. Reference Example 2 The same experiment as described in Example 4 was performed, but in this example, dioctyltin di- (octylthioacetate) and dioctyltin di-ethylic lauric acid were not used. Ester salt. The results are shown in Table 1. As obtained with reference to 洌 1, the applicability of the coating is almost lost. Table 1 (Please read the precautions on the back before filling out this page) Printed water angle bracelets by the Consumers' Cooperatives of the Ministry of Economic Affairs of the Ministry of Economic Affairs) Oil connection angle (〇) Initial value wipe test after initial value wipe test Net 1 11 8 116 98 9 5 Example 2 11 3 111 9 4 9 3 Example 3 1 5 5 3 9 3 9 1 Example 4 11 7 115 9 6 3 3 Example 5 5 4 10 6 10 8 83 Example 6 11 5 1 1 3 9 5 9 4 Example 1 10 8 48 6 1 2 4 Example 2 10 5 4 7 4 5 16 -33- This paper size applies Chinese national standards (CNS) A4 size (210X 297mm) A7 B7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention It is clear from Table 1 that the substrate treated with the finishing agent of the present invention is a wet cloth. After repeatedly wiping the surface, the water-repellent and oil-repellent properties were maintained. In Reference Examples 1 and 2, the water-repellency and oil-repellency were low, and, among others, these properties were almost completely lost after the wiping test. As explained above, the method of the present invention can realize a method for forming a chemisorption film which has a practical reaction rate and does not generate chlorine gas during the film formation process. The IB adsorption solution of the present invention can realize a useful chemisorption solution. According to the method of the present invention, the contact is performed by contacting a weak mixture containing a non-aqueous solvent containing active hydrogen and a silanol. The substrate can form a double-layer chemisorption membrane bonded to the surface of the substrate via a covalent bond of silicon oxide: In addition, by using at least one first silicon oxide surfactant, such as dialkoxy, Siloxane, trialkoxysilane or tetraalkoxysilane, a solution mixture of non-aqueous solvent containing no active hydrogen and 5 silanol condensation catalyst ib is connected to the substrate. The inner diameter of the siloxane chemisorption membrane that is valence-bonded to the surface of the substrate. The solution mixture is connected to the inner layer M to form a chemisorption containing one molecule of the second alkoxysilane surfactant and covalently bonded to the surface of the R layer via a siloxane bond. The outer layer is safe and easy. The floor is formed into a film fixed to the substrate due to covalent bonds, where a substance containing at least one alkoxysilyl group is passed through Si original-3 4-This paper size is applicable to China National Standard (CNS) A4 specifications (210X 297 mm): -_ nn I-. 1 ϋϋ I- — I ^^, 1-- -----i-i in I 1- \-JI —i 1 '-I. (Please read first Note on the back page, please fill in this page again) 5. Description of the invention (5 &7; 7) The film, where a substance containing at least one alkoxysilyl group is chemically adsorbed on the surface of the substrate via Si atoms. In other words, unlike the conventional method, the method of the present invention can efficiently form a protective film on various materials such as plastics, ceramics, and glass jars without generating chlorine gas when forming the film. The present invention can be used for articles that require a thin coating of heat, weather, and abrasion resistance, such as electrical appliances, housewares, automobiles, industrial equipment, mirrors, lenses, or glasses. The present invention may be implemented in other special forms without departing from its spirit or essential characteristics. The embodiments disclosed in this application are to be considered in all respects as illustrative and not restrictive. The scope of the present invention is defined by the appended claims. The scope of the patent application is not the indication of the foregoing description, and all changes that are within the meaning and equivalent scope of the patent application scope are to be included therein. Symbols of the main components of the drawing 1 Glass plate 2 * 32 Hydroxyl 3,13,33 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) 11 Substrate 12 Imide group 2 1 Non-tempered steel plate 2 3 Polymer coating 3 1 Plastic plate 33, 42 Single molecular inner layer with siloxane as matrix This paper is in accordance with Chinese national standard (CNS> A4) (210 X297 mm) V. Description of the invention bv) 3 4 4 1 4 3 5 1 5 2 5 3 6 1 6 3 6 2 A 'li ft tip filled with molecular outer layer aluminum plate oil drain coating film (polymer film) paper siloxane coating inner Membrane molecular outer membrane alumina plate polymer coated quilt --------- seed coat --------, 1τ ------ I (Please read the precautions on the back before filling in this Page) Printed by the Central Consumers Bureau of the Ministry of Economic Affairs of the Consumer Cooperatives 36 This paper size is applicable to the Chinese National Standard (CNS) M specifications (210 × 297)

Claims (1)

Printed by the Central Laboratories of the Ministry of Economic Affairs and Consumer Cooperatives 6. Scope of Patent Application1. A method for forming a chemisorption film on a substrate with active hydrogen, which includes the following steps: using at least one fluorocarbon-based An alkoxysilane surfactant, a solution mixture of a non-aqueous solvent containing no active hydrogen and a silane enzyme condensation catalyst contacts the substrate, and K is chemically adsorbed through the silane coupling to form a K covalent bond to the surface of the substrate. Membrane, wherein the fluorocarbon-based alkoxysilane surfactant is a substance selected from one of the following two formulas: CF3- (CF2) n- (R) m-SiXp (OA) 3_p where η is An integer from 0 to 9, R represents a Ci-C3 alkylene group, ϋ is 0 or 1, X represents a hydrogen atom or -C3 alkyl group, A represents "-C3 alkyl group, and P is an integer of 0, 1 or 2 And 3 2 w * p 3-p where w is an integer from 0 to 15, X represents a hydrogen atom, A represents a Ci-C3 alkyl group, and P is 0; the non-aqueous solvent containing no active hydrogen is selected from the group consisting of A group consisting of a hydrocarbon anhydrous solvent and a fluorocarbon anhydrous solvent; and the silanol condensation catalyst is selected from tin (I) acetate, Dibutyltin laurate * Dibutyltin dioctoate, dibutyltin diacetate, dioctyl dilaurate, dioctyl dioctoate, dioctyl diacetate, dioctyl dioctate (I), lead cyclopentanoate, # Cobalt alkanoate, osmium 2-ethylhexenoate, dioctyltin di- (octylthioacetate), dioctyltin maleate, dibutyltin sulfonate Aggregate-1- This paper size applies to China National Standards (CNS) A4 grid (210X297 mm) --m-. Ί---- m--I-.-------m HI (Please read the notes on the back before filling this page) Printed by the Central Laboratories of the Ministry of Economic Affairs and Consumer Cooperatives 6. Scope of Patent Application1. A method for forming a chemisorption film on a substrate with active hydrogen, which includes the following steps: using at least one fluorocarbon-based An alkoxysilane surfactant, a solution mixture of a non-aqueous solvent containing no active hydrogen and a silane enzyme condensation catalyst contacts the substrate, and K is chemically adsorbed through the silane coupling to form a K covalent bond to the surface of the substrate. Membrane, wherein the fluorocarbon-based alkoxysilane surfactant is a substance selected from one of the following two formulas: CF3- (CF2) n- (R) m-SiXp (OA) 3_p where η is An integer from 0 to 9, R represents a Ci-C3 alkylene group, ϋ is 0 or 1, X represents a hydrogen atom or -C3 alkyl group, A represents "-C3 alkyl group, and P is an integer of 0, 1 or 2 And 3 2 w * p 3-p where w is an integer from 0 to 15, X represents a hydrogen atom, A represents a Ci-C3 alkyl group, and P is 0; the non-aqueous solvent containing no active hydrogen is selected from the group consisting of A group consisting of a hydrocarbon anhydrous solvent and a fluorocarbon anhydrous solvent; and the silanol condensation catalyst is selected from tin (I) acetate, Dibutyltin laurate * Dibutyltin dioctoate, dibutyltin diacetate, dioctyl dilaurate, dioctyl dioctoate, dioctyl diacetate, dioctyl dioctate (I), lead cyclopentanoate, # Cobalt alkanoate, osmium 2-ethylhexenoate, dioctyltin di- (octylthioacetate), dioctyltin maleate, dibutyltin sulfonate Aggregate-1- This paper size applies to China National Standards (CNS) A4 grid (210X297 mm) --m-. Ί---- m--I-.-------m HI (Please read the notes on the back before filling out this page) A8 B8 C8 D8 The scope of patent application, dimethyl hydrogen thiopropionate polymer, diethylacetonide, printed by Shelley Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs Dibutyltin acetonate, dioctyltin diethylacetonyl laurate, tetrabutyl titanate, tetranonyl titanate and di (propyl titanate) dione (diethyl ether acetonyl). 2 * For example, the method of claim 1 in the patent application circle includes: using a non-aqueous solvent containing at least the alkoxy tablet active interface, no active hydrogen, and the silane fermentation catalyst The liquid mixture contacts the substrate; a molecule of the alkoxysilane surfactant is covalently bonded to the surface of the substrate via a siloxane bond; and the alkoxysilane surfactant is cleaned with a non-aqueous solvent and The substrate forms a single-molecule film coating composed of one molecule of the alkoxysilane surfactant and bonded to the surface of the substrate via a siloxane bond M covalently bonded. 3 ♦ As claimed in patent scope No. 1 The method of item, comprising: contacting the substrate with a solution mixture containing at least the alkoxysilane surfactant * containing no active hydrogen and the silane fermentation condensation catalyst; contacting a molecule of the molecule via a silane bond The alkoxysilane surfactant is covalently bonded to the surface of the substrate; the non-aqueous solvent is evaporated; and the substrate and the alkoxysilane surfactant are reacted with water to form a A polymeric film coating that is bonded to the surface of the substrate. 4 * The method according to item 1 of the patent application, wherein the base material is formed of at least one material selected from the following combinations: gold tin, ceramics, -2- This paper size applies to China National Standards (CNS) ) Α4 grid (210 × 297 mm) Ϊ ^^ 1 I— n —I— nn m nn »-* i-II—-i---I: TJ_. Deafness, νδ (Please read the precautions on the back first (Fill in this page again) Printed A8, B8, C8, D8 by the Consumer Cooperatives of the Central Government Procurement Bureau of the Ministry of Economic Affairs 6. Scope of patent application Glass, plastic, paper, stretchers and leather. 5 * The method according to item 4 of the patent application, wherein the substrate is made of at least one material selected from the group consisting of plastic and Materials in things. 6. A method for forming a chemisorption film on a substrate having active hydrogen, comprising the following steps: using at least one first argon argon surfactant, a non-aqueous solvent containing no active hydrogen and a silane enzyme The solution mixture of the condensation catalyst contacts the substrate K to form an inner layer *, which is a siloxane chemisorption membrane that is covalently bonded to the surface of the substrate via a siloxane; and using at least one second alkoxysilane A surfactant, a solution mixture of a non-aqueous solvent containing no active hydrogen, and a silanease condensation catalyst contact the inner layer to form an outer layer, which contains a molecule of the second alkoxysilane surfactant and is via a siloxane bond K A chemical adsorption film covalently bonded to the surface of the inner layer; wherein the first alkanosilane surfactant and the second alkoxysilane surfactant may be the same or different and are at least one selected from the following: Among the combinations: hexaalkoxydisiloxane, octaoxytrisiloxane, dialkoxysilane, trialkoxysilane, and tetraalkoxysilane. 7. The method of claim 6 including: applying a solution mixture containing at least the first alkoxysilane surfactant, the non-aqueous solvent containing no active hydrogen and the silane fermentation condensation catalyst to contact the base Material; -3- This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) -------- Titanium -------- Order ------ \ (Please read first Note on the back page, please fill in this page again) Λ 8, Β8 C8 D8 6. Application scope of the patent The molecule of the first alkoxysilane surfactant is bound to the surface of the substrate via siloxane κ covalent 鐽; Washing the substrate and the first alkoxysilane surfactant with a non-aqueous solvent to form the inner layer, which contains siloxane and is chemically bonded to the surface of the substrate via a siloxane bond κ covalent bond Adsorb a monomolecular film; contact the inner layer with a solution mixture containing at least the second alkoxysilane surfactant, a non-aqueous solvent containing no active hydrogen, and the silane enzyme condensation catalyst; the interface activity of the second alkoxysilane The molecules of the agent are covalently bonded via a siloxane bond The surface of the inner layer and the non-aqueous solvent are used to wash the inner layer and the second alkoxysilane surfactant to form the outer layer. The outer layer contains the molecule of the second alkoxysilane surfactant and passes through silicon gas. The chemical adsorption film of the alkyl chain K covalently bonded to the surface of the inner layer is printed on the consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs HI m — ^ 1 ϋ »1 ^ 1 in ml i--— 1. 士 之 ^^ 1 In -..... ^^ 1 II (please read the precautions on the back before filling in this f), where the first alkanosilane surfactant and the second alkoxysilane surfactant can be the same Or different and at least one selected from the group consisting of hexaalkoxydisilaxane, octaalkoxytrisiloxane, dialkoxysilane, trialkoxysilane, and tetraoxane Oxysilane. 8. The method according to item 6 of the patent application, which includes: contacting the base with a solution mixture containing at least the first alkoxysilane surfactant, the non-aqueous solvent containing no active hydrogen, and the silane fermentation condensation catalyst The molecules of the first alkoxysilane surfactant are passed through the siloxane bond -4-this paper size uses the Chinese National Standard (CNS) A4 specification (210X297 mm). Alkaline alkane contains alkane, but not siloxane, and the base sand *, the oxygen is mixed by the film agent and the alginate liquid to be active and single-sided; the side of the alkane boundary and the oxygen absorber Combining surface materials Silicone-based silicon-based fermenting materials should contain alkane groups to wash the surface of the surface. The agent should have a small amount of soluble materials and a suitable internal base to the agent. Formed to contain valence-formed water and form a non-M valence. 6. The scope of the patent application. The molecule of this second alkoxysilane surfactant is covalently bonded to the surface of the inner layer through a siloxane bond K. ; Distilled off the non-aqueous solvent; and the residual on the surface of the inner layer The alkoxy group containing the second alkoxysilane surfactant reacts with water to form a chemisorption that contains the second alkoxysilane surfactant molecule and is covalently bonded to the surface of the inner layer via a siloxane bond K The outer layer of the polymer film, wherein the first alkoxysilane surfactant and the second alkoxysilane surfactant may be the same or different, and are at least one selected from the group consisting of: six Alkoxydisilanes, octaalkoxytrisiloxanes, dialkoxysilanes, trialkylsilanes and tetraalkoxysilanes. 9. The method according to item 6 of the patent application, which comprises: contacting the solution mixture containing at least the first alkane-based silane surfactant, the non-aqueous solvent containing no active hydrogen, and the silane fermentation condensation catalyst with the solution Substrate; the molecule of the first alkoxysilane surfactant is passed through a siloxane bond. The scale is in accordance with China National Standard (CNS) A4 (210X297 mm) --------- installation ------ Order (please read the notes on the back before filling this page) Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, and printed by the Central Standards Bureau of the Ministry of Economic Affairs, printed by A'S B8 C8 D8, Six The scope of the patent application: κ covalent bond is bonded to the surface of the substrate; the non-aqueous solvent is distilled off; the alkoxy group of the first alkoxysilane surfactant on the surface of the substrate is reacted with water and Forming the inner layer, which contains a polysiloxane and is bonded to the surface of the inner layer via a siloxane κ covalent 鐽; using a non-active hydrogen-containing non- Aqueous solvent and the silanease condensation catalyst The solution mixture contacts the inner layer; the molecules of the second alkoxysilane surfactant are covalently bonded to the surface of the inner layer via a siloxane bond K, and the substrate and the second alkane are washed with a non-aqueous solvent Oxysilane surfactant to form the outer layer, which contains the second alkoxysilane surfactant and is a chemisorption film that is covalently bonded to the surface of the inner layer via siloxane ΜΜ, wherein the first alkane The alkoxysilane surfactant and the second alkoxysilane surfactant may be the same or different and are at least one selected from the group consisting of hexaalkoxydisiloxane, octaoxy Trisiloxanes, dialkoxysilanes, trialkoxysilanes, and tetraalkanesilanes. 1 0. The method of claim 6 including: contacting the solution mixture containing at least the first alkoxysilane surfactant, the non-aqueous solvent containing no active hydrogen, and the silane fermentation catalyst Substrate; the molecule of the first alkoxysilane surfactant is passed through the siloxane bond-6-this paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm) ^^ 1 ^^^ 1 nna ^ n ^^ 1 mf Shizhi ^^ 1 ^^ 1 ^^^ 1 ^^ 1 1 ^ 1 TJ. (Please read the notes on the back before filling out this page) Printed by the Central Samples Bureau of the Ministry of Economic Affairs and Consumer Cooperatives Preparation A8 Β8 C8 D8 VI. Patent application scope M Covalent bond to the surface of the substrate; Distill off the non-aqueous solvent; 谉 The first alkoxysarane interface activity remaining on the surface of the substrate. The alkoxy group contained in the Γ agent reacts with water to form the inner layer, which contains polysiloxane and is a film that is covalently bonded to the surface of the substrate via a siloxane bond; using at least the second alkoxy group Silane surfactant, the non-aqueous solvent containing no active hydrogen and the sarane fermentation condensing agent The liquid mixture contacts the inner layer; the molecules of the second alkoxysilane surfactant are covalently bonded to the surface of the inner layer via a siloxane coupling; the non-aqueous solvent is distilled off; and the remaining on the surface of the inner layer The alkoxy group containing the second alkoxysilan surfactant on the above reacts with water to form the second alkoxysilan surfactant containing the molecule and is covalently bonded via a siloxane bond K To the outer layer of the chemisorption polymer film on the surface of the inner layer, wherein the first alkoxysilane surfactant and the second alkoxysilane surfactant may be the same or different and are at least one selected from the group consisting of Among the combinations: hexaalkoxydisilanes, octaalkoxytrisiloxanes, dialkoxysilanes, trialkoxysilanes, and tetraalkoxysilanes. 1 1 · The method according to item 6 of the scope of patent application, wherein the silane fermentation condensation catalyst is at least one substance selected from the group consisting of: gold tincture carboxylate, carboxylate metal salt, metal carboxylate polymerization Compounds, metal carboxylate clamps, titanates and titanates. This paper uses the Chinese National Standard (CNS) A4 size (210X297 mm) I ml I ......--I II. II-^^ 1 (Please read the precautions on the back before filling this page ) A8 B8 'C8 08 6. Application for patent scope 1 2 · The method according to item 6 of the patent scope, wherein the silanease condensation catalyst is at least one substance selected from the following combinations: tin (I) acetate, Dibutyltin dilaurate, dibutyltin dioctoate, dibutyltin diacetate, dioctyltin dilaurate, dioctyltin dioctoate, dioctyl diacetate, tin (I) dioctoate * lead naphthenate, Cobalt Naphthenate, 2-Ethylhexenoic Acid Acetic Acid, Dioctyltin Di- (octylthioacetate), Dioctyltin Maleate, Dibutyltin Maleate Polymer, dimethyltin hydrosulfopropionate polymer, di-butyltin propionate dibutyltin, dioctyltin diethylacetate, tetrabutyltin titanate, tetranonanoic titanate And di- (propyl titanic acid) di- (ethanyl propionate). 1 3. The method according to item 6 of the application, wherein the alkoxysilane surfactant has a fluorocarbon group. 14. The method according to item 13 of the scope of patent application, wherein the fluorocarbon group-containing alkoxysilane surfactant is a substance represented by one selected from the following two formulas: CF3- (CF2) n- (R ) m-SiXp (OA) 3_p Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy-I--1 —- 1 In 1 < nn ·-n ^^ 1 I, T (Please read the notes on the back first ^ Refill this page) where η is an integer from 0 to 9, R represents Ci -C3 alkylene, π or 0 or 1, x represents a hydrogen atom or Ci -C3 alkyl, and "—Cs alkyl" P is an integer of 0, 1 or 2; and CF3COO- (CH2) w-SiXp (OA) 3_p, where w is an integer of 0 to 15, X represents a hydrogen atom, and pill represents "-C3 alkyl, and " 8- This paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 mm) A8 B8 C8 D8 6. The scope of patent application p is 0. 15. The method according to item 6 of the scope of patent application, wherein the substrate is formed of at least one material selected from the group consisting of metal, ceramic, glass, plastic, paper, stretchers, and leather. 1 6 ♦ The method according to item 15 of the patent application, wherein the substrate is made of at least one plastic and male selected from the group consisting of treating the substrate with an oxygen-containing mortar or placing it in an electric discharge garden to make it hydrophilic. Materials in things. 17 · The method according to item 6 of the patent application, wherein the non-aqueous solvent is at least one solvent selected from the group consisting of a hydrocarbon-containing anhydrous solvent and a fluorocarbon-containing anhydrous solvent. 1 8 · A method for forming a chemisorption film on a substrate having active hydrogen, comprising the following steps: using a solution mixture containing at least one silane surfactant, a non-aqueous solvent containing no active hydrogen and a silane fermentation condensation catalyst The substrate M is contacted to form a chemisorption film containing siloxane, which is covalently bonded to the substrate by the siloxane hafnium. It is printed 1 ^ 1 mm by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs »< n · m · 1 ^ 1 ^^ 1 .n 0¾-9 (please read the notes on the reverse side before filling out this page) where the silane surfactant is at least one selected from the group consisting of: 6 Alkoxydisilanes, octaalkoxytrisiloxanes, dialkoxysilanes, trialkoxysilanes and tetraalkoxysilanes. 19. The method of claim 18, comprising: contacting the substrate with a solution mixture containing at least the silane surfactant, the non-aqueous solvent containing no active hydrogen, and the silane fermentation condensation catalyst; contacting the silane Molecules of surfactants are covalently bonded via siloxane -9- This paper size is printed with China National Standard (CNS) Α4% grid (210X297 mm) Printed by the Shell Standard Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Α8 Β8 C8 D8 6. The scope of the patent application is applied to the surface of the substrate; and the substrate and the silane surfactant are washed with a non-aqueous solvent to form a covalent bond containing siloxane and via a siloxane bond M A chemisorbed monomolecular film bonded to the surface of the substrate, wherein the sintered surfactant is at least one selected from the group consisting of hexaalkoxydisilaxane, octaalkoxytrisiloxane , Dialkoxysilane, trialkoxysilane and tetraalkoxysilane. 20. The method according to item 18 of the patent application scope, comprising: contacting the substrate with a solution mixture containing at least the silane surfactant, the non-aqueous solvent containing no active hydrogen and the silane fermentation condensation catalyst, and contacting the silane The molecule of the surfactant is covalently bonded to the surface of the substrate via a siloxane bond K; the non-aqueous solvent is distilled off; the alkoxy group contained in the silane surfactant on the surface of the substrate is reacted with water Forming a film containing polysiloxane and covalently bonded to the surface of the substrate via a siloxane bond K, wherein the silane surfactant is at least one selected from the group consisting of hexaalkoxy Disiloxane, octaalkoxytrisiloxane, dialkoxysilane, trialkoxysilane and tetraalkoxysilane. 2 1 · The method according to item 18 of the scope of patent application, wherein the silanease condensation catalyst is at least one substance selected from the group consisting of: metal carboxylate, carboxylate gold phosphonium salt, metal carboxylate Polymers, metal carboxylate clamps, titanates and titanate clamps. This paper size is applicable to China National Standard for Ladder (CNS) A4 (210 × 297 mm) Packing — (Please read the notes on the back before filling out this page) Order the policy of the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A8 B8 C8 D8 2. Patent application scope 22: The method according to item 18 of the patent application scope, wherein the silanease condensation catalyst is at least one substance selected from the following combinations: tin (I) acetate, dibutyltin dilaurate, Dibutyltin dioctoate, dibutyltin diacetate, dioctyltin dilaurate, dioctyltin dioctoate, dioctyltin diacetate, tin (I) dioctanoate, lead naphthenate, cobalt alkanoate, 2- Ethylhexenoic acid iron acetate, dioctyltin bis- (octylthioacetate), dioctyltin, butenedioic acid salt, dibutyltin maleic acid polymer, dimethyl Polymers of tin hydrosulfopropionate, di-butyltin diethylacetate, dioctyltin diethylacetate, tetrabutyltin titanate, tetranonyl titanate, and di_ (propyl Titanic acid) bis- (ethynylpropionyl ester). 23 ♦ The method according to item 18 of the patent application scope, wherein the silane surfactant has a fluorocarbon group. 24. The method of claim 23, wherein the fluorocarbon-containing silane surfactant is a substance represented by one selected from the following two formulas: CF-(CF,) n- (R)- SiX ^ (OA). Λ-ο I nmp 3-p where n is an integer from 0 to 9, R represents Ci -C3 alkylene, π or 0 or 1, X represents a hydrogen atom or Ci -C3 alkyl, A is Ci_C3, and p is an integer of 0, 1 or 2; and CF3C00- (CH2) w-SiXp (OA) 3_p, where w is an integer of 0 to 15, X is a hydrogen atom, and pill table ^ -C3 alkyl, and -11- This paper size uses China National Standard (CNS) A4 (210X297 mm) --------- ^ ----;-Order ---- ----- ^ (Please read the notes on the back before filling out this page) A8 B8 C8 D8 printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 々, the scope of patent application P is 0. 25 * The method of claim 18, wherein the substrate is formed of at least one material selected from the group consisting of metal, ceramic, glass, plastic, paper, fabric, and leather. 26 * The method according to item 25 of the patent application, wherein the substrate is made of at least one material selected from the group consisting of an oxygen-containing plasma or a corona discharge treatment to make the substrate hydrophilic plastic and male. Material. 2.7. The method of claim 18 in the scope of patent application, wherein the non-aqueous solvent is at least one solvent selected from the group consisting of a hydrocarbon-free anhydrous solvent and a fluorocarbon-based anhydrous solvent. 28. A chemisorption solution comprising a solution mixture containing at least one alkoxysilane surfactant, a non-aqueous solvent containing no active hydrogen, and a silanol condensation catalyst. 29. The chemical adsorption solution according to item 28 of the application, wherein the silane fermentation condensation catalyst is at least one substance selected from the group consisting of: metal carboxylic acid toilets, carboxylic acid ester metal toilets, and gold phosphonium carboxylates. Polymers, metal carboxylic acids, adducts, titanates and titanates. 30. The chemical adsorption solution according to item 28 of the application, wherein the silane fermentation condensation catalyst is at least one substance selected from the group consisting of tin (I) acetate, dibutyl dilaurate, and dioctanoic acid Dibutyltin, dibutyltin diacetate, dioctyltin dilaurate, dioctyltin dioctoate, dioctyltin diacetate, tin (I) dioctanoate, lead naphthenate, n-naphthenate, 2-ethyl Hexenoic acid iron acetate, dioctyltin di- (octylthioacetate), dioctyl " 1 2 ~ This paper size applies to China National Standard (CNS) A4 (210X297 mm)- -------- Raid ------ 1T ------ / Ί (Please read the precautions on the reverse side before filling out this page) Printed by Shellfish Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs Α8 Β8 C8 D8 6. Scope of patent application: maleic acid salt of maleic acid, dibutyltin maleic acid polymer, dimethyltin hydrothiopropionate polymer, di-ethylfluorinated dibutyltin dibutyltin , Dioctyltin diacetate, octyltin laurate, tetrabutyl titanate, tetranonyl titanate, and di- (propyl titanate) di- (acetamidoacetone). 31. The chemical adsorption solution according to item 28 of the patent application, wherein the alkoxysilane surfactant has a fluorocarbon group. 32 * The chemical adsorption solution of item 28 of the patent application, wherein the fluorocarbon-containing siloxane surfactant is a substance selected from the group consisting of the following formulae: CF3- (CF2) n- (R) m-SiXp (OA) 3_p where η is an integer from 0 to 9, R represents a Ct -C3 alkylene group, B or 0 or 1 * X represents a hydrogen atom or Ci -C3 alkyl group, and Ran "- C3 alkyl * and P is an integer of 0,1 or 2; and CF.COO- (CH.,) -SiX „(OA) 0 ο w w ρ j -ρ where w is an integer from 0 to 15, J [ Table hydrogen atom, 々 ^ -C3 alkyl group, and P is 0 〇33. The chemical adsorption solution according to item 28 of the patent application range, wherein the non-aqueous solvent is at least one selected from a hydrocarbon-containing anhydrous solvent and a fluorocarbon Of anhydrous solvents. 34. A chemisorption solution according to item 28 of the application, wherein the solution mixture has a water content of 10 PPB or less. -13- This paper uses Chinese National Standard (CNS) Α4 size (210X297mm).-(Please read the precautions on the back before filling out this page) Order 8 88 8 A BCD VI. Application for patent scope 35 For example, the chemical adsorption solution in the scope of application for item 28, wherein 100 parts by weight of the solution mixture contains 0.1 to 30 parts by weight of the alkoxysilane surfactant, and 0.0001 to 7.5 parts by weight of the silane enzyme \ Condensation catalyst * and 62, 5 to 99.899 9 reset parts of the active hydrogen-free non-aqueous solvent. ---------- t .----.-- Order .------, Α (Please read the precautions on the back before filling out this page) Staff Consumption of the Central Bureau of Standards, Ministry of Economic Affairs Printed by the cooperative -14- This paper size applies to China National Standard (CNS) A4 (210X297 mm)