TW404977B - Finishing agent and method of using the same - Google Patents

Abstract

The invention provides a finishing agent comprising alkoxysilane surface active agent, silanol condensing catalyst, and nonaqueous liquid or solid medium. Moreover, the finishing agent comprises alkoxysilane surface active agent, acid catalyst and liquid and solid medium. In the above-mentioned finishing agent, at least one of alkoxysilane surface agent and acid catalyst are microencapsuled. The finishing agent permits formation of chemically adsorbed protecting films. Such protecting films are used for substrates of; such equipments as electronics products, electric domestic products, automobile, industrial equipments, mirrors, lenses for glasses and the like. The protecting films have a durability and heat, weather and abrasion resistance, and also water and oil repellent properties.

Description

404977 Λ7 ΙΓ 5. Description of the invention (I) Invented pig city The present invention relates to a final treatment agent and a method for using the same. More specifically, the present invention relates to a final treatment agent and a method for forming a durable ultra-thin, water- and oil-repellent, chemically-adsorbed protective film on a substrate. According to the invention, according to the conventional practice, the final treatment agent has been used as a gloss agent or the like. The final treatment agent of the prior art is mainly solid or emulsified, and usually contains a mixture of petroleum solvents, polysiloxanes, osmium, or lower alcohols, and abrasive materials (for example, Japanese Laid-Open Patent (JP-A-Hei) No. 2-151676, No. 2-1708 78). Furthermore, the use of a fluorine-containing silane compound as a final treating agent has also been proposed (for example, Japanese Laid-Open Patent (Japanese Patent Application Laid-Open) No. 3-100060, EP Publication No. 0577951A1). The finishing agents of the prior art have weak water resistance and gloss properties, and the protective films of the prior art lack durability and solidity, so they are only applied to the surface of the substrate. Other than that, they have almost no oil resistance. According to the method proposed in Japanese Laid-Open Patent (JP-A-Hei) No. 3-1 0 0 0 60 or EP Publication No. 0577951A1, since the reaction of the alkoxysilane surfactant is slow, the film cannot be easily formed. A method using a dealcoholization catalyst is also possible, however, when only the dealcoholization catalyst is added, the surfactant crosslinks with moisture in the air to lose activity. In other words, if the final treating agent includes moisture, the surfactant is cross-linked before reacting with the surface of the substrate, preventing the substrate from reacting at the interface of the solid and liquid, making it difficult to form a chemisorption film. Furthermore, if an alkoxysilane surfactant is used and the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 cm) ---------- Doing clothes ------- 、 Order ——.----- '&quot; * 1.-• (Please read the notes on the back before filling out this page) · Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Print 404977 5. Invention Description (&gt;) Acid catalysts, in fact it is difficult to blend both of them at the same time. Therefore, two-liquids, alkoxysilane surfactants and acid catalysts need to be manufactured separately. The method used is not easy. An object of the present invention is to provide a final treatment agent and a method for using the same, wherein the reaction of an alkoxysilane surfactant is promoted by using a silicidation condensation catalyst, and the final treatment agent therein efficiently and moderately affects the surface of the substrate The reaction avoids the influence of water on the surfactant by M. Another object of the present invention is to provide a final treating agent and a method for using the same, so as to form a protective film having not only excellent gloss properties and waterproof properties, but also not only applied to the surface of the substrate, but also durability and hardness, and chemical bonding. Bonded to the substrate surface is further water and oil resistant. A more specific object of the present invention is to provide a protective film having excellent heat resistance, weather resistance, and abrasion resistance by thinly and adhesively applying a fluorocarbon (Phlorocarbon) polymer to a substrate. A protective layer M is required to make the comodi ties such as household electrical appliances, automobiles, industrial equipment, glass, mirrors, lenses for spectacles, internal goods * clothing items, and the like. The purpose of the present invention is to provide a final treatment agent comprising an alkoxysilane surfactant, a silanol condensation catalyst, and a non-aqueous liquid or solid medium. It is preferable that the final treatment agent in the present invention includes a final treatment agent. Alkoxysilane surfactants in an amount of 0.1 to 30 wt% (wt%) of the total weight | 0.0 0 Q 1 to 20 wt% of a silanol condensation catalyst and 5 to -4- Paper size applies to Chinese National Standard (0 ~ 5) 8 4 specifications (2 丨 0 \ 297 public dredging) --------- installation ------! ---...—:- ------ Please!-(Please 4. Read the notes on the back and then fill out this page) Λ7 404977 V. Description of the invention ($) (Please read the notes on the back and fill out this page) 99.8999% by weight Non-aqueous liquid or solid medium. In addition to the three components mentioned above, optional additives such as pigments, filler particles, perfumes or the like may be included. It is preferred that the final treatment agent of the present invention further comprises an abrasive material. It is also preferred that the alkoxysilane surfactant is present in the present invention in an amount of 0.1 to 30% by weight based on 100% by weight of the total final treating agent. The silanol condensation catalyst is present in an amount of 0.0001 to 20% by weight, non-aqueous liquid and solid media is present in an amount of 5 to 99.8999% by weight, and the abrasive material is present in an amount greater than 0 and not less than 60% to 100% by weight. In addition to the four ingredients mentioned above, optional additives such as pigments, filler particles * perfumes or the like may be included. It is preferred that at least one selected from the group consisting of a silanol condensation catalyst and an alkoxysilane surfactant in the present invention is microencapsulated. This is because if one or both of the silicic acid condensation catalyst and the alkoxysilane surfactant are microencapsulated, they will not be exposed to moisture in the air, and the storage time of the final treatment agent will be shortened. It is preferred that the silanol condensation catalyst in the catalyst of the present invention is at least one selected from the group consisting of metal carboxylic acid 塩, carboxylic acid ester salt, metal carboxylic acid 塩 polymer • Jin 靥 carboxylic acid, printed by the Consumers' Cooperative of the Central Standards Bureau, Ministry of Economic Affairs Materials of the group consisting of a titanium compound, a titanate and a titanate adduct. The moisture content in the present invention is preferably 10 ppm. If the water content exceeds 10 ppm, a strong odor of chlorine is generated. According to the present invention, the second final treatment agent comprises an alkoxysilane surfactant | silicone condensing and dissolving agent and a non-aqueous weary or solid medium and at least this paper size applies the Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 404977 Λ7 1Γ _ V. Description of the Invention (#) One of the alkoxysilane surfactants and the silanol condensation catalyst are microencapsulated. In addition, the final treatment agent may include an abrasive material and / or calcium carbonate. It is preferable that the viscosity of the liquid or solid medium in the first or second final treatment agent of the present invention is not less than 10 at a temperature of 2 5 ° c. Q 0 cps (c PS table per-second period). The better viscosity in one step is in the range of 10 0 0-5 Q 0 Q c ps. 0 The liquid or solid medium in the final treatment agent is preferably a medium with a boiling point greater than 200 scoop and a medium with a 10QC-2G0tM Fu point. mixture. Depending on the final treatment agent, if the alkoxysilane surfactant contains a fluorocarbon group, the final treated film may have water and oil repellent properties. As for the alkoxysilane-based surfactant, for example, CF3_ (CF2) n- (R) m-SiXp (0A) 3_P (where n is 0 or an integer; R is an alkenyl group, and vinylidene is preferably used). , Ethynylene, aromatic group and molecular bonds containing silicon or oxygen atoms; m represents 0 or 1; X represents Η atoms, alkyl, alkoxy, or molecules containing fluoroalkyl or fluoroalkoxy 鐽A epialkyl group or fluoroalkyl group, and ρ table 0, 1 or 2) 0 It is preferred that the grinding material in the final treatment agent contains at least one component, particles smaller than 10 um in diameter, selected from alumina, oxidation A group of calcium, calcium carbonate, silicon carbide, boron carbide, chromium oxide, iron oxide, synthetic diamond and fine-grained silica. It is particularly preferred that the abrasive materials have an average particle size of 0.2 to 3 wm. The method for using the first final treatment agent of the present invention includes the following steps: The paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297). (Please read the precautions on the back before filling this page.) Binding 404977 Λ7五-V. Description of the invention (<Please read the precautions on the back before filling in this page) Step: Thoroughly wash the surface of the substrate; it will contain at least one alkoxysilane surfactant, δ-fermentation condensation catalyst And a non-aqueous liquid or solid medium as the final treatment agent is applied to the substrate; the active hydrogen on the substrate surface is reacted to an alkoxysilane surfactant and a silanol condensation catalyst; and the unreacted final agent is removed from the substrate. The surface moves away. The molecular film in which the orientation of the molecules is in a good order can be reacted with active hydrogen on the substrate surface to the alkoxysilane surfactant and silanase condensation catalyst for a sufficient time, by removing excess unreacted final treatment agent from the substrate surface And formed. In addition, by using non-aqueous liquid hips or solid media, during the application • Avoid reactions between alkoxysilane surfactants or silanol condensation catalysts and moisture in the air. As a result, the reaction between the substrate and the alkoxysilane surfactant and the siliceous condensation catalyst can be promoted. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs' It is preferred in this method that at least one of the silicic acid condensation catalyst and the alkoxysilane surfactant is microencapsulated. It is also preferred to use a final treatment agent in this method while crushing a capsule of a microencapsulated alkoxysilane surfactant or a silanol condensation catalyst. By applying the final treatment agent simultaneously destroying the capsules * The reaction on the substrate surface can proceed smoothly without being affected by moisture in the air. Its preferred liquid medium has a viscosity of not less than 1 Q oc c ps. The liquid does not drip during application. In addition, it is preferred that the liquid or solid medium is composed of a mixture of a medium having a boiling point of more than 200 t and a medium having a boiling point of 100 ° C-200 ° C. Therefore, rapid solidification during application due to evaporation of the medium. -7- This paper music scale is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297gt) Printed on the staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 ___ 40497 ^ 7 __________________

V. Description of the invention (U) The method of using the second final treatment agent of the present invention includes the following steps: Good washing of the surface of the substrate; application of alkoxysilane surfactants, acid catalysts and non-aqueous liquids or The final treatment agent for the solid medium simultaneously destroys the microcapsules that protect at least one alkoxysilane surfactant and the acid catalyst; reacts the alkoxysilane surfactant and the acid catalyst to the surface of the substrate; and removes an excess of the final treatment agent from the substrate Quality surface removal ° It is preferred in this method that an abrasive material is added to the final treatment agent 'and that the final treatment agent is applied to the substrate and at least one substrate is polished. Applying the agent while polishing the substrate Improved grinding effect. In addition, this method allows it to react on the purified side of the substrate. As a result, it can preferably include a coating with higher durability. As for the substrate, you can use gold drawers, pottery * glass, plastic , Paper 'didimensional, leather or the like. In the case of materials, such as plastic or fiber, not waterproof, can be in the plasma atmosphere or corona atmosphere Hydroxyl groups are introduced to the surface * This makes the surface hydrophilic. In other words, it is better for the surface to contain hydroxyl groups. Figure 1 (a)-(c) are cross-sections of the surface of the substrate. The degree of the molecule explains a specific example of the surface of the substrate. Figure 1 (a) shows the surface of the substrate before the application of the K final treatment agent; Figure 1 (b) shows the surface of the substrate after the application of the K final treatment agent Figure 1 (c) shows the surface of the chemically-adsorbed film formed on the substrate after the reaction has proceeded further. Figure 虢 illustrates that the paper size applies the Chinese National Standard (CNS) Α4 specification (2 丨 0'〆297〆)- ------- install --_: --- J1T-.--C Please read the notes on the back before filling this page) 404977 Λ7 V. Description of the invention (7) 1 Glass substrate 3 Ten t: Fluorodecyltrimethoxysilicone 2-0Η 4 Chemical adsorption membrane invention: &gt; Note: Note printed by the Consumers' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs I «(Please read the notes on the back before filling in (This page) According to the present invention, the first final treatment agent contains an alkoxysilane surfactant * Chemical agents and non-aqueous liquid or solid media, or final treatment agents comprising, when added, at least one material selected from the group consisting of silane catalysts, and alkoxysilane surfactants are microencapsulated. In addition, an abrasive material is added to the above composition. As a result, the reaction of the alkoxysilane surfactant is promoted so that the surfactant is affected by moisture before reacting to the surface. In other words, the surfactant reacts efficiently and moderately to the surface of the substrate. Because the silicic acid condensation catalyst and the alkoxysilane surfactant are protected by K microcapsules or non-aqueous liquid or solid media, the final treatment agent of the present invention can be used on the surface of the substrate in the air. As a result, a final treatment agent can be provided with a long storage time in which an alkoxysilane surfactant and a siliceous condensation catalyst are blended together. Compared with the case where the two liquids are prepared separately, the final treating agent can be easily used. Moreover, according to the final treatment agent of the present invention, the alkoxysilane surfactant and the silanol condensation catalyst react on the surface of the substrate, and the alkoxysilane surfactant can directly react on the substrate and by A covalent knot is fixed to it. As a result, the final treating agent of the present invention allows the formation of a durable, ultra-thin, water- and oil-resistant protective layer. As for the alkoxysilane surfactant used in the final treatment agent of the present invention, these MSiXp. (OA) 4_ρ (wherein X represents Η alkyl, alkoxy and fluoroalkyl and fluoroalkoxy containing Substituents of the base; and P table 0,1 This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 404977 1〇27 A7 _B7 V. Description of the invention ( S) or a surfactant represented by 2). For example, the following hydrocarbon-based molecules can be used as alkoxysilane agents having a fluorocarbon group; CF3-(CFz) n- (R) i-SiXp (0A) 3 _P &gt; where n is 0 or an integer R represents an alkylene group, a vinylene group, an ethynylene group, an arylene group and a substituent containing a silicon or oxygen atom; b is 0 or 1; and X is a H * alkyl * alkoxy group and a fluoroalkyl group Or a fluoroalkoxy substituent; A is an alkyl or fluoroalkyl group; and P is 0, 1 or 2. Furthermore, the following include examples of useful surfactants: CH3-(CH2) r-SiXp (0Α) 3 _Ρ ί CHs-(CHz) s-0- (CH2) t-SiXp (0A) 3 _P ; CH3-(CH2) u-Si2 (CH3) 2-(CH2) v-SiXp-0A3 _p; CF3 C00- (CH2) w-SiXp (0A) 3 _P; where r is 1 to 2 5; s is 0 To 12; t Tables 1 to 20; u Tables 0 to 12; v Tables 1 to 20; w Tables 1 to 2 5; X represents Η, alkyl, alkoxy and fluoroalkyl or fluoroalkoxy-containing Substituents; A epialkyl; and ρ represent 0, 1 or 2. In addition, special examples including the following molecules: * CH3 CHz 〇 (CHz) 1 s Si (0CH3) 3, CF3 CHz 〇 (CH2) i 5 Si (0CH3) 3. CHs (CHz) 2 Si (CH3) z (CHz) is Si (0CH3) a, CH3 (CH2) e Si (CH3) 2 (CH2) 9 Si (0CH3) 3, CH3 COO (CHz) i 5 Si (OCH3) 3, -10- The paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 public love Ί — • I ---.------- .Install ------- II ο Order ----; --- t &quot;. (Please read the precautions on the back before filling out this page) The Central Consumers Bureau of the Ministry of Economic Affairs, the Consumer Cooperatives of India Yin Chang 404977_ir______ 7. Invention Explanation (/) CF3 (CF2) 5 (CHz) z Si (0CH3) 3, CF3 (CFz ) v -C, H4 -Si (0CH3) 3, CH3 CH2 〇 (CHz) i 5 Si (0C2 H5) 3. CH3 (CH2) 2 Si (CH3) z (CHz) i 5 Si (0C2 H5) 3, CHs (CH2) s Si [CH3) 2 (CH2) 9 Si (0C2 H5) 3, CF3 (CH2) 6 Si (CH3) 2 (CH2) 9 Si (0C2 Hs) 3, CH3 C00 (CH2) i 5 Si (0C2 Hs) 3, CF3 C00 (CH2) i 5 Si (0Cz H5) 3, CF3 COOiCHz) i 5 Si (0CH3) 3 1 CF3 (CFz) 9 (CH2) z Si (0Cz Hs) 3 »CFs (CF2 ) v (CHz) z Si (0C2 H5) 3, CF 3 (CF z) 5 (CH 2) 2 S i (0 C 2 H 5) 3, CF3 (CF2) 7 C6 H4 Si (0Cz H5) 3, CF3 (CF2) 9 (CH2) 2 Si (0CH3) 3, CF3 (CF2) 5 (CH2) 2 Si (0CH3) 3, CF3 (CF2) 7 (CH2) 2 SiCH3 (〇C2 H5) z, CF3 (CF2 ) 7 (CH2) z S1CH3 (OCH3) z, CF3 (CF2) 7 (CH2) z Si (CH3) 2 OC2 H5, CF3 (CF2) 7 (CH2) z Si (CH3) z OCHs, the following items include the use of Specific examples of silanol condensation catalysts in the first final treating agent of the present invention: metal carboxylic acid fluorene such as tin (I) -dibutyltin dilaurate, dibutyltin dioctoate, dibutyl Tin diacetate, dioctanate tin (I), lead naphthenate, cobalt naphthenate-U-This paper size applies to China Standard (CNS) A4 specification (21〇 × 297 公 楚) ---------- ¾ clothing ----- rI, 玎-----(Please read &quot; 'Notes on the back side before (Fill in this page) 404977_ V. Description of the Invention (ί〇), 2-ethylhexenoic acid osmium; carboxylic acid gold phosphonium salts such as dioctylbis-octylfluorenyltin acetate, dioctyltin maleate ; Ca 丨 b 0 sy I ate metal adducts such as dibutyltin maleic acid polymer, dimethyltin fluorenyl propionate polymer, dibutyl bisethylfluorenyl acetate, dioctyl bis -Fluorenyl tin laurate; titanates such as tetrabutyl titanate, tetranonyl titanate; titanate adducts such as di-propyl titanate bis- (ethylamidoacetonyl) ester. It is preferable that the above-mentioned catalyst can be dissolved in a non-aqueous solvent and the water content is not included in the reagent. Furthermore, any non-aqueous solvent that does not decompose a surfactant or a siliceous condensation catalyst can be used as a liquid or solid medium. It is preferred to use a solvent based on silicone or petroleum. More specifically, as the solvent, the following examples can be included: petroleum brain; petroleum solvent; petroleum ether; petroleum essence; isoparaffin; n-paraffin; decalin; industrial gasoline; kerosene Petrochemical; Dimethicone; Phenylpolysiloxane; Alkyl-modified polysiloxane; Polyether polysiloxane; Bonded alkane fluorene; Microcrystalline fluorene; Polyethylene wax; Esterium fluorene; Rhenium oxide; And petroleum wax. The above embodiments can be used alone or in combination as a liquid or solid medium in the present invention. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ------------------------- Ordered * * (Please read the notes on the back before filling in this purchase) Furthermore, If abrasive materials having a diameter of less than 10 wm, such as alumina, calcium oxide, calcium carbonate, silicon carbide, boron carbide, chromium oxide, iron oxide, synthetic diamond or fine-grained silica are added to the final treatment agent alone or in combination In the process, a small amount of the surface of the substrate will be removed during the application of the agent. As a result, it is preferable that the reagent including at least one microencapsulated chlorosyl group can directly react to the surface of the purified substrate. -12- This paper is applicable to the standard Chinese National Standard (CNS) A4 Specification (210X297 Gt) 404977_b: V. Description of the Invention (ιί) i The method of using the first final treatment agent of the present invention includes the following steps: thoroughly washing the surface of the substrate; the application includes at least An alkoxysilicone surfactant, a silanol condensation destroyer and a non-aqueous liquid or solid medium; a final treatment agent; and an alkoxysilane surfactant at room temperature in the presence of a silanol condensation catalyst. Accept This reaction is, for example, the dehydrogenation condensation between the hydroxyl group (-0H) on the surface of the substrate and the alkoxy group (-OR, R-epialkyl) at the terminal of the alkoxysilane surfactant molecule. The reaction time is preferably at room temperature (approximately 25-30 ° C), preferably 20 to 30 minutes. If a decapsulated silanol condensation catalyst or alkoxysilane surfactant is added to the medium, the final The preservative time or activation life of the treatment agent can be extended. At the same time as printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, at least one of the alkoxysilane surfactants and the acid catalyst was micro-based according to the invention's second final treatment agent. Encapsulation is then mixed with a liquid or solid medium. As a result, only when those microcapsules are broken, the alkoxysilane surfactant comes into contact with the acid catalyst. As a result, the final treatment agent can be surface-active by blending the alkoxysilane And an acid catalyst. Compared with the prior art method (in which two liquids are prepared), the final treatment agent can be easily used. Moreover, according to the present invention, the final treatment agent, silicon alkoxide Surfactants and silanol condensation catalysts react on the surface of the substrate, so the K alkoxysilane surfactant can directly react on the substrate and is fixed on it by covalent bonding. As a result, the invention is finally The treatment agent allows the formation of a durable, ultra-thin, water- and oil-resistant protective layer. For the alkoxysilane surfactant used in the second final treatment agent of the present invention, M SiBq (0A) 4 _q (where B is functional Base, A Table-1 3- This paper size applies Chinese National Standards (CNS) Λ4 grid (210X 297gt) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _404977_B7_ 5. Description of the invention (/?) Alkyl and q Test cocoons in Table 1, 2 or 3). In more detail, an M hydrocarbon-based molecule or a fluorinated carbon-based molecule represented by the following formula can be used; CH3-(CHz) r-SiXp (0A) 3 _P, CF3-(CH2) s- 0- (CB2) t-SipX3 _p * CFb-(CHz) u-Si (CH3) 2-(CH2) v-SiXp (0A) s ~ P · CF 3 C 0 0-(CH 2) w-S i X p (0 A) 3 _ P, (where r is 1 to 2 5; s is 0 to 12; t is 1 to 2 0; u is 0 to 12; v is 1 to 20; w is 1 to 25 Integer; X represents H. alkyl, alkoxy or a substituent including fluoroalkyl or fluoroalkoxy; and P represents 0, 1 or 2); CFs-(CFz) n- (R) ffl-SiXp ( 0A) 3 _P «(where n represents 0 or an integer; R represents an alkylene group, a vinylene group, an acetylene group, an arylene group and a substituent containing a silicon or oxygen atom; Table 0 or 1; and X represents Η, Alkylalkoxy and substituents containing fluoroalkyl or fluoroalkoxy; and P represents 0, 1 or 2). In addition, special examples of molecules including the following; CH3 CHz 〇 ( CHz) 1 5 Si (0CH3) s, CH3 (CH2) 2 Si (CH3) z (CH2) i 5 Si (0CH3) s, CH3 (CH2) 6 Si (CH3) 2 (CH2) 9 Si (0CH3) 3 ， CH3 COO (Cfl2) i 6 Si (0CH3) 3. CF3 CHz 〇 (CH2) is Si (OCH3) 3, CF3 (CHz ) z Si (CH3) 2 (CHz) is Si (0CH3) 3, CF3 (CF2) s SUCH3) 2 (CH2) 9 Si (0CH3) s, -14- ^ Paper size applies to China National Standard (CNS) A4 specifications (210 x 297 mm) II --------------- Pack -------- IIΊ Order ---- ΊΙ-Tick (Please read the precautions on the back before filling this page ) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 404977_J; __________ V. Description of the Invention (M) CFs COO (CH2) 1 $ Si (0CH3) 3, CF3 (CF2) 7 (CH2) z Si (0CH3) 3, CF3 (CFz) s (CHz) z Si (0CH3) 3, CF3 (CF2) 7 H4 -Si (0CH3) 3, CH3 CHz 0 (CH2) 1 5 Si (0C2 H5) 3, CH3 (CH2) 2 Si (CH3 ) z (CH2) i 5 Si (0C2 Ης) 3. CH3 (CH2) 6 Si (CH3) 2 (CH2) 9 Si (0C2 Hs) 3, CH3 COO (CH2) 1 5 Si (0C2 H5) 3, CF3 (CF2) 7 (CH2) 2 Si (OC2 Hs) 3, CF3 (CF2) 5 (CH2) 2 Si (OC2 H5) 3, CFs (CFZ) 7 -C6 H4 -Si (OC2 Hs) 3, 'In this book The content of the alkoxysilane surfactant in the final treating agent of the invention is preferably from 0.1 to 30% by weight. For the acid catalyst of the second final treating agent of the present invention, it is preferable to use osmic acid such as hydrochloric acid * nitric acid, sulfuric acid, phosphoric acid, carbonic acid, and sulfonic acid. Moreover, an inactive oxyorganic amine compound can be used. The preferred amount is 0.1 to 15% by weight. For the liquid or solid medium of the second final treatment agent of the present invention, any solvent, water or non-aqueous type can be used * which can be dispersed without breaking the microcapsules. It is preferred to use an M-based solvent or a petroleum-based solvent. Solvents such as butanol, isopropion, liquid stone, polysiloxane, and alkane-based waxes can be used. As the solvent, the following items may be included: 1. This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm t). --i --- Good *-I-• (Please *? Read the notes on the back and fill out this page) __404977_ ^ __ V. Description of the invention (ice) The examples include: petroleum brain; petroleum solvents; petroleum ether Petroleum essence; hetero-bonded smoke; n-paraffin; decalin; industrial gasoline; kerosene; petroleum spirit; dimethylpolysiloxane; phenylpolysiloxane; alkyl-modified polysiloxane; polyether Polymer sand oxygen; paraffin rhenium; microcrystalline wax; polyethylene rhenium; fermented rhenium; rhenium oxide; and petroleum rhenium. The above embodiments can be used alone or in combination. 9 重量 ％。 Liquid or solid medium in the final treatment agent preferably content of 45-99.8% by weight. If the viscosity of the final treatment agent is 10D0 cps or K, the final treatment agent will not run down, and the treatment of the agent is easy. However, the control of too hard processing agents is difficult. If the liquid or solid medium is a mixture of a medium with a boiling point of 200 υ or M and a medium with a boiling point of 100-200 C. As a result, after the application medium component having a lower boiling point evaporates, the removal of the unreacted final treating agent is simple and the coating film is cured quickly. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs- (Please read the notes on the back before filling this page) Furthermore, if you use alone or in combination abrasive materials with an average particle size of less than 1 Q wm, such as alumina, oxidation Calcium, calcium carbonate, silicon carbide, boron carbide, chromium oxide, iron oxide, synthetic diamond or fine-grained silica are added to the final treatment agent, and a small amount of the surface will be removed during the application of the agent. As a result, it is preferred that a reagent comprising at least one microencapsulated c h 1 or 0 sy 1 base can directly react to the surface of the purified substrate. The content of the abrasive material in the second final treating agent is 1 to 50% by weight. The second final treating agent according to the present invention further contains calcium carbonate, in case volatile acids such as hydrochloric acid and nitric acid are used as acid catalysts, the most volatile acids are captured by the reaction between the volatile acid and calcium carbonate. As a result, -1 6- This paper size is in accordance with the Chinese National Standard (CNS) A4 (210X297 g) printed by the Central Bureau of Standards of the Ministry of Economic Affairs and printed by Shellfish Consumer Cooperative 404977. 5. Description of the invention (/ 〇 can avoid acid smell. Use this The method of inventing the second final treating agent comprises the following steps: thoroughly washing the surface of the substrate; applying the final treating agent to the surface of the substrate while destroying at least the microcapsules; making the alkoxysilane surfactant and the acid The catalyst reacts on the substrate surface. Another method using the second final treatment agent of the present invention includes the following steps: washing the thoroughly substrate surface; applying the final treatment agent to the substrate surface while grinding by using an abrasive material Light-accepting the surface and destroying at least the microcapsules and at the same time; reacting the alkoxysilane and the acid catalyst to the surface of the substrate for 20-30 minutes. This reaction is performed on the surface of the substrate by an alkoxysilane surfactant and an acid catalyst. It is as follows: Formula 1 H +-—SiOA-&gt;-SiOH-&gt;-SiO- Substance After these steps shown at least • At least alkoxysilane surfactant is covalently via Si atom The knot is fixed on the surface of the substrate, thereby forming an ultra-thin film. The substrate of the present invention includes substrates having, for example, hydroxyl (-0H), metals such as Al, Cu, stainless steel or the like, glass, ceramics, paper, fibers Leather, or other hydrophilic substrates. In the case of materials such as plastics, synthetic resins, and synthetic resins, there are no hydroxyl groups on the surface. These hydroxyl groups can be treated with 100 W of electricity in an oxygen-containing plasma atmosphere. Introduced to Table-1 in 20 minutes 7- This paper size applies to Chinese National Standard (CNS) A4 specifications (210X 297 public narrative) (Please read the precautions on the back before filling out this page). Binding Staff Consumption of Central Standards Bureau, Ministry of Economic Affairs Cooperative printed 404977 V. Description of the invention (4) The surface is used to make the surface hydrophilic. Not only hydroxyl (-0H), but functional groups with active hydrogen, such as-COOH, -CHO, = NH, -NH2 or the like is used as a hydrophilic group. When a polyimide and a polyurethane resin having an imine group (-NH) is used as a substrate, the imine group and the alkoxy group (- S i 0 A, A epialkyl) active hydrogen is reversed , M forms a siloxane bond (-SiO). Therefore, the final treatment is not required. In this case, for example, the substrate contains nylon or polyurethane, and many imine groups (including active hydrogen) are exposed to On the surface of the substrate, the chemical adsorption film can be formed in the same manner as that of the glass substrate. As a result, the present invention can be applied to various applications and materials described in the following; the present invention can be applied to the following The various uses and materials described above; (a) Examples of substrates: gold tincture, ceramics, plastics, wood * stone (even when the substrate M is painted or M-like material is pre-coated, the present invention can also be (Applicable); (b) Example of a knife. Kitchen and other knives, scissors, engravers, brake blades, hair scissors, saws, planers, chisels, screw cones, badkin, cutting tools, drilling machine tops, blending Combiner blades, juicer blades, flour grinder blades, fine sieve mower blades, punchers, net grass cutters, major producers, blades for can openers, surgical scalpels or the like; (c) Needles A real example of a drag, Needle, tailor needle, used for manufacturing-1 8-This paper size applies to Chinese National Standard (CNS) Λ4 specification (210 × 297 cm) --------- Approved clothing I- ^ (Please read first Note on the back, please fill out this page again) Order 404977 V. Description of the invention (q) Long thick needles, syringe needles, surgical needles, safety pins or M-like materials on straw mats; (d) Examples of ceramic products-μ Products made of pottery, glass' pottery or enamel-coated products, including sanitary pottery (such as pots, washbasins, bathtubs, etc.), tableware (such as rice bowls, dishes, bowls, tea cups, glasses, bottles, coffee bottles, Pots and pans, crockery bowls, cups, etc.), vases (eg flower bowls, flower pots, small vases, etc.), chemical instruments (eg beakers, reaction vessels, test tubes, bottles, petri dishes, condensers, stir bars, stirrers) , Mortar, vat I syringe), roof tiles, ceramic tiles, enamel-coated utensils, enamel-coated washbasins, and enamel-coated pots and pans; (e) Examples of mirrors-hand mirror, full-length mirror, bath, room mirror , Bathroom mirror, 'car (back and side Mirror) Mirror, half mirror, display window mirror, used in department store mirrors or the like; printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economy-(Please read the precautions on the back before filling out this page) (Π Example 1 of a molded part: a mold for a compression mold * a mold for a mold, a mold for injection molding, a mold for transfer molding, a mold for vacuum molding, and a mold for blow molding , Molds for extrusion molding, molds for inflatable molding, molds for fiber spinning, calendar rolls; (g) examples of decorations-watches, jewelry, pearls, sapphires, rubies, emeralds , Garnet, opal, diamond, topaz, hematite, aquamarine, turquoise, ma brain, marble, amethyst, embossed gemstone or shellfish, opal, crystal, glass, ring, hand-19 -This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297) while it is printed ~ '404977 Printed by the Central Government Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, V. Description of Invention (Θ) 1 1 I m 9 Brooch &gt; Straps »Earrings 1 Necklace» Glasses Frame (Platinum, Gold, 1 1 1 Silver Aluminium Titanium Tin »Gold Rings Of Compounds Of These Elements» Or Not m Steel 1 I Please 1 |) Or similar Read 1 I (h) Examples of food utensils—bread molds biscuit molds bread molds t read back. 1¾ 1 I chocolate mold jelly mold ice cream mold oven 磲 9 ice tray note 1 I meaning I or U-like items I 1 I (i) cooking utensils Example of pan and pan wok iron pot teapot oil% Ben • 1 pack I frying pan hot plate used for grilling food net X used for fume exhaustion X 'sheet ^ 1 t is gold-plated or similar for making ta koy aki 1 1 I ⑴ Example of paper-gravure printing paper waterproof and oil-proof paper for posters 1 paper High-quality paper or the like for brochures 1 Order (k) resin Example 1 Polyolefin (such as polypropylene, polyethylene, etc.) Poly 1 Vinyl chloride Polyvinylidene chloride Polyfluorene resin Polyimide Polyfluorene 1 Y Amine resin Polyimide Polyester Aromatic Polyester Polyphenylene Ethylene, 1 1 | Polyton t polyether urethane 9 polyphenylene sulfide m phenol resin furan resin t 1 .. spring aldehyde resin epoxy compound polyurethane silicone resin ABS resin 1 1 9 methacrylic resin ethyl acrylic acid Ester Resin Ester Resin Polyurethane 1 I Aldehyde Polyphenylene Ether or U-like 1 1 (1) Example 1 of Household Electrical Appliances TV i Video Recorder & Recorder t CD 1 1 Turntable Refrigerator Freezer Air Conditioner Juicer Blender I &gt; Blades of electric fan Zhao Ya \, Ming equipment 9 dial t perm hair 1 | dryer or U-like thing 1 1 (a) Example of sports equipment-shoes «fishing rod 1 On the pole vault 1 1 -20-1 1 This paper size applies to Chinese National Standard (CNS) Λ4 specification (2 丨 OX297 mm) Λ7 Β7 404977 V. Description of the invention), boat 'Sailing boat', shooting shoes, surfboard, golf club , Ball, fishing line, fishing net, fishing drifter or the like; (π) Examples of vehicle parts; (1) ABS grease-motorcycle lampshade, dashboard, adjustment parts, and protection board, ( 2) Divisor plastics a car's mark, and steering wheel, (3) FRP (Divisor reinforced plastic) a bumper, and hood, (4) phenolic resin-brake, (5) polyacetal-wiper , Wiper gear, air valve, carburetor parts, (6) polyamide-radiator fan, (7) polyarylate (polycondensation polymerization bisphenol A and pseudophthalic acid)-direction indicator light (or Mirrors), dashboard mirrors, delivery boxes, '(8) polybutylene terephthalate, rear fender, (9) polyurethane biscis butylene diimide-engine parts, M gearbox, Wheels, suspension drive system, (10) methacrylate resin one lamp cover mirror, instrument panel and cover, and center marker (11) Polypropylene-bumper, (1 2) Polystyrene-heater stove grill, wheel cap, (13) Polyurethane-bumper, defense, dashboard * and fan, (14 ) Unsaturated polyester resin one car body, gas box, heater packaging, instrument panel, -2 1- This paper size applies to China National Standard (CNS) Α4 specification (210 × 297 mm) (please first-read the precautions on the back) Refill this page), 11 Printed by the Consumers 'Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, printed 404977 V. Description of the invention (/) (0) Examples of stationary equipment-fountain pens, steel balls , Mechanical pencil, lead II box, adhesive, desk, chair, bookshelf, hat holder, phone holder, ruler, cartographer's appliances or the like; (P) Example of building materials-roofing materials (such as tiles, slate, Tin is used, for example, in galvanized iron plate, and others. Exterior wall materials (such as wood includes treated wood, stucco, cement, pottery sizing agent, gold tint sizing agent, brick, building stone, plastic materials, including Gold tin material of aluminum, etc.), inside Materials (for example, wood including treated wood, gold-containing materials including aluminum, plastic materials, paper, fiber, etc.) or the like (q) Examples of stone materials-granite, marble, or the like, used in buildings * buildings Materials, art materials, decoration, bath materials, cornerstones, monuments, gateposts, stone walls, sidewalks, paving stones, etc. (r) Examples of musical instruments and sound instruments-auscultation tools, string instruments, wind instruments, woodwind instruments, brass instruments or the like, more specifically drums, mirrors, violin, cello, guitar, koto, piano , Flute, clarinet, shakuhachi, horn, etc., and microphone, speaker, earphone or similar. (s) Other high-voltage insulators with good waterproof, oil-proof, and pollution-proof properties, including thermos bottles, vacuum instruments, insulators for transmitting electricity, spark plugs or the like. Because the fluorocarbon-based polymer film is applied thinly and adhesively to the substrate, the substrate of the present invention is not easily soiled and has excellent heat resistance. The paper size applies to Chinese national standards (CNS ) Λ4 specification (210 × 297 mm) Λ clothing-* (Please read the precautions on the back before filling this page), 1T A7 ____B7 V. Description of the invention ("丨) (Please read the precautions on the back before completing this P.) Climatic, and abrasive properties. The substrate can be used for furniture items, automobiles, industrial equipment, glass, rafters, lenses for glasses, interior items, male sex items, clothing items, or the like. The method of microencapsulated silanase catalyst, alkoxysilane surfactant and acid catalysis can be described as "the new technology for microencapsulation and its development and application examples (1978) sold at Keeii Kaihatsu Center" ) "; Or" Wei Mi II-its manufacturing method, properties, and application examples "published by Sankyo Syuppan. The present invention will be clearly explained in the following specific examples and various sections. In the following examples,% means% by weight. Li Li 1 (A) Preparation of final treatment (1) Decafluorodecyltrimethoxysilane [fluoroalkoxysilane surfactant: (CF3 (CFz)? (CHZ) 2 Si (0CH3) 3 10 g (2) normal one-alkane (non-aqueous liquid medium: bp. 210¾) 20 g printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs (3) polysiloxane (non-aqueous liquid medium: Sinetsu

Kagaku Kougyou KF-96 »1000 cps) 15 g (4) Pinane (non-aqueous liquid rhenium medium: Kanto

Kagaku · ρ 94-96 * 0) 20g (5) Alfa-alumina (abrasive material: average particle size is 1 w) 5g This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) ) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs __404977 V. Description of the Invention (&gt;) The above materials are mixed in a conical flask, and the mixed materials are stirred at 100 ° C to make a suspension. After the suspension was cooled to room temperature, 2 g of (6) w formalin condensation resin microcapsule-encapsulated dibutyltin dilaurate (silicon condensation catalyst: gold sulfonate) was added and stirred. Therefore, a solid softener and final treatment agent can be provided. At this point, dibutyltin dilaurate was microencapsulated as described in the above document. Unlike Example i, the same results were obtained when the alkoxysilane surfactant was microencapsulated and when both the fermentative condensation catalyst and the alkoxysilane surfactant were microencapsulated. (B) Application of final treatment agent The waterproofness, oiliness and durability of the final treatment agent are tested by the following treatments. The window glass of the automobile 1 was used as a substrate for the final treatment agent. The surface of the glass substrate 1 contains many -0H groups 2 containing active hydrogen (Fig. 1 (a)). The glass substrate is thoroughly washed and then the final treatment agent for the mash produced is pickled by rubbing the surface of the glass with a sponge. As a result, the capsules of the mufflen condensation resin were broken * so dibutyltin dilaurate and heptafluorodecyltrimethoxysilane were blended together and brought into contact with the surface of the cleaned glass. Then the final treatment agent-coated glass was placed in air at room temperature (approximately 25C) and the n-paraffins were evaporated in 30-40 minutes to form a white protective layer. At this time * even if polysiloxane oil and paraffin exist on the protective layer and the surface of the substrate, in the presence of a certain proportion of catalyst, heptafluorodecyltrimethoxysilane 3 p-〇Η on the surface of the substrate. Radical 2 reaction, (Fig.1 (b)). -24 in the air This paper size applies to the Chinese National Standard (CNS) Λ4 specification (21〇 × 297 公 t) ---------- buttoning ———--- ^-^ — order-- _. (Please read the notes on the back before filling out this page)-40497? V. Description of the invention (&gt;)) The water is interrupted by non-aqueous n-paraffins. The dealcoholization reaction shown in the following formula is carried out by using a heptafluorodecyltrimethoxysilane surfactant, and water is adsorbed to the surface of the glass and the surface of the substrate by -0H. When the dealcoholization reaction proceeds *, it is formed Heptafluorodecyltrimethoxysilane surface-active molecules. Formula 2 Silicone Condensation Catalyst CF3 (CF2) 7 (CH2) z -S1OCH3 + H2 Ο-&gt;

CF3 (CF2) 7 (CH2) z-SiOH + CH3 0H Further, the silanol group prepared by the reaction represented by the formula 2 and the active hydrogen of the group generate a dehydrogenation reaction represented by the formula 3. As a result, the heptafluorodecyltrimethoxysilan surfactant was chemisorbed and fixed to the surface of the substrate via a covalent bond through a SiO bond. Type 3 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ------------ Installation I _!-'-(Please read the precautions on the back before filling this page) Spring Silicon Fermentation Condensation Catalyst CF3 ( CF2) 7 (CH2) 2 -SiOH + H0-Acceptor- &gt; -25- This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X 297 Gongjie) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4049 ^ 7_ -_____ 5. Description of the invention (&gt; f) CF3 (CFz) 7 (CH2) 2 _Si〇-accepting group + H2 0 When excess unreacted reagent M cloth is wiped, a lot of ten t-fluorodecyltrimethoxysilane Molecules are immobilized on the surface of the substrate by network bonding via Si 0 bonding (Figure 1 (c)). The thickness of the fluorinated carbon-based chemical adsorption film 4 is several nanometers. In this step, no microcapsule seal is required for the silane condensation catalyst or alkoxysilane surfactant. However, if the silanol condensation catalyst or alkoxysilane surfactant is microencapsulated, it can be stored longer. The contact angle of water is Π5 °. The film did not peel off by a transverse cutting test. The salad oil applied on the substrate was easily wiped off with toilet paper. In addition, the contact angle hardly deteriorated after 500 G 0 wet cloth wipes. The results are shown in Table 1. Furthermore, by performing the same experiment using the same final treating agent (which has been maintained for one year), the same results can be obtained. As is clear from the above formulae 2 and 3, according to the method of the present invention, water is an important element. In other words, if the final treatment agent contains water, the final treatment agent is crosslinked before reacting with the surface of the substrate. As a result, the reaction at the interface of the solid hip fluid is interrupted, and the chemisorption film is not easily formed. Therefore, the water content in the final treatment agent must be as small as possible. The moisture content in the composition is preferably not more than 10 ppm. By using Au 靥 carboxylic acid 靥 or metal carboxylic acid admixture as silanol -26- This paper size applies Chinese National Standard (CNS) Λ4 specification (210X297 mm) ---------- Packing-^ ---- ^-Order ------- Quan. '--2 Please read the precautions on the back before filling out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 40497 * 7 _____ V. Description of the invention (&gt; &lt;) The catalyst can obtain an appropriate protective layer for chemical adsorption. The preferred content of the silicon condensing agent ib is 0.5 wt%. In order to generate only dealcoholization by an alkoxy group, an inorganic acid or an organic acid may be used. However, as mentioned above, the final treatment agent package is not preferred. Therefore, the catalyst used in the first final treatment agent is preferably a siliconase condensation catalyst. The following final treating agents were prepared and the preparation of the final treating agents was examined in the same manner as in Example 1. Normal Paraffin (bp · 18QTC) 20g Shinetsu Kagaku

Kogyo, KF-9 6 »1 0 0 0 cps) 10 g of bonded hydrocarbon (Kanto Kagaku, mp. 86Ό) 15 g of heptafluorofluorodecyltrimethylaminosilane (CF3 (CF2) 7 (CH2) z Si (0C2 Hs) 3) 10 g of calcium carbonate (abrasive material · · average particle size is 1 wm) 15 g Furthermore, a microcapsule-sealed dibutyltin acetate resin (3 g) with mufflen condensation was added to the above reagent And stirring M to obtain a soft wax final treatment agent. This final treatment agent has high fluidity. However, the same results as in Example 1 were obtained, except that a white protective layer M was provided after the final treatment agent was applied to the glass substrate and the glass was left to stand for 20-30 minutes. The results are shown in Table 1. -27- The size of this paper applies to Chinese National Standard (CNS) Λ4 specification (210X297 cm) --------- Installation ----- „-Order — * ------ &quot;. ---(Please read the precautions on the back before filling this page) A7 4049ΤΪ B7___ V. Description of the invention (J) SJS Example 3 The same experiment as in Example 2 except that it is used in Example 2-10 • tFluorine Decyltrimethoxysilyl K tridecylfluorooctyltriethoxysilane (CF3 (CF2) s (CH2) 2 —Si (OC2 HS) 3) was substituted. The results are shown in Table 1. i The same experiment as in Example 2, except that the rear-view mirror substitution of the waste code K used in Example 2 and 2 grams of dibutyltindiacetylglycollate were not microencapsulated. The results are shown in Table 1. The activation life of this test is about 3 months.

The same experiment as in Example 2 was performed as in Example 2. The valve 蘯 used in the glass K automobile of Example 2 was replaced and 5 g of acetic acid was further added as an aqueous solvent. The results are shown in Table 1. This final treatment can be used for several hours after preparation, but solidifies within 2 or 3 days and cannot be used. The same experiment as in Example 2 was performed, except that the glassy WM urethane acetate used in Example 2 was replaced by the same. The results are shown in Table 1. When Fu Li 7 was the same experiment as in Example 2, except that Alpha-alumina M silica used in Example 2 (average particle size was 5 replaced. The results are shown in Table 1. Fenma Li «- 2 8-This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) ----- ^ -------. Packing --------- 1 Order ---- --1IA. (Please read the notes on the back before filling out this page) Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumers ’Cooperatives of the Ministry of Economics and Intellectual Property Bureau Printed A7 JB7_ V. Description of the invention (7) As in Example 2 The same experiment was performed except that the number of normal one-chain alkanes was 40 g. The viscosity of the prepared liquid rhenium was about 3 000 to 4 00 cps. The results are shown in Table 1.

Taking care of Q The same experiment as in Example 1, except that moisture was further added at 5 reset% of Dong. In this case * if the prepared liquid crocodile is used immediately after preparation, the same results as in Example 4 are obtained. Capsules are shown in Table 1. However, this preparation liquid was solidified overnight and it was not possible to use the same experiment as in Example 1 except that the decapsulated dibutyltin dilaurate was removed. The results are shown in Table 1. If the zymolysis catalyst does not include the protective shoes formed by those like this reference example *, it is almost non-permanent. Hair 祢 2 was the same experiment as in Example 2 except that the microencapsulated dibutyl bis-ethyl acetotin acetate was removed. The results are shown in Table 1. Similar to the reference example, the resulting protective layer has almost no durability. Μ_1_ Connection angle of water (°) Contact angle of oil (°) Initial shooting friction test After initial testing number After testing the number after the test Example 1 115 116 98 96 -29- This paper size applies Chinese national standards ( CNS) A4 specification (210 X 297 mm) ----------------order ------ '--- ^ (Please read the Note for refilling this page) Λ 7 ΙΓ Printed by the Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs 5. Description of invention (&gt; points) 1 1 I Example 2 114 113 96 94 1 1 I Example 3 118 115 9 7 9 1 1-1 I Example 4 113 111 9 1 92 Please read 1 1 first | Example 5 10 5 10 0 9 3 81 Read Back-I Example 6 1 18 10 5 95 82 1 I I 1 I Spring Example 7 114 10 9 9 5 88 Matter 1 I Re 1 Example 8 116 111 92 94 Fill in 1 Write this example Example 9 109 105 9 1 86 Pages &gt; w- 1 Reference 1 99 48 6 1 24 1 1 Reference Example 2 87 4 7 45 16 1 1 As can be clearly seen from Table 1, even after the surface was repeatedly wiped with a wet cloth, I was wiped &gt; The substrate maintains its water-repellent 1 1 and oil-repellent properties. In Reference Example 1 and Reference Example 2, the water-repellent and oil-repellent properties are 1 low and almost completely free of these properties after testing. 0 1 1 I soft solid rhenium is prepared in the following steps: 1 1 1 The following materials are mixed; 1 n-Hydrocarbon hydrocarbon (bp. 2 10) 20 g 1 1 isopropanol 5 g | polysiloxane (S hinet S υ K agaku 1 I Ko gy 〇, RF- 96 &gt; 1000 C PS) 5 g I 1 as M 鐽 hydrocarbon-based 撖 1 1 -30- 1 1 This paper size applies Chinese National Standard (CNS) Λ4 specification (210X297 Mm) B7 &amp; Description of Invention (g t; J) Bonded alkane (Kanto Kagaku · · ρ · 94-96Ό) 20 grams of heptafluorodecyltrimethoxysilane (Please read the precautions on the back before filling this page) (CF3 (CFz)?-(CH2 ) 2 -Si (0CH3) slO g of silver monoxide (average particle size is 1 «) 5 g at 100 t: stir the mixed material * so as to provide a suspension; cool the suspension to room temperature; add as The acid catalyzed the microencapsulation of 10 g of M forlin resin with 3% sulfuric acid and further stirred. Therefore, a solid soft palate with a viscosity of 2500 cps is provided for final processing. 3% oleic acid is included in the manner suggested in the above-mentioned public money. The water- and oil-repellent properties and long-lasting properties of the final treatment agent are checked by the following methods by using the final treatment. Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, “Huabo”, which uses cars 1, as the final treatment agent. The surface of this glass substrate 1 includes a number of -0 fluorenyl groups (1 (a)) containing active hydrogen. The glass was thoroughly cleaned and then the final treated surface prepared was applied to the glass surface by wiping it with a sponge. As a result, the surface of the glass was removed by thin abrasion and cleaned by an abrasive material (Melfa-Vaporized Aluminum). In addition, Ma Fulin suspected that the capsules of A. sibiricum were broken, so K sulfuric acid and ten t of fluorodecyltrimethoxysilane were blended together, and the blended reagent was in contact with the surface of the cleaned glass. The final treating agent is then left in the air for 30-40 minutes to evaporate the n-bonded alkane to form a white protective layer. At this time, on the boundary surface and the substrate surface of the protective layer, even if polysiloxane and bonded alkanes are present, in a certain proportion of catalytic suspicion * ten t of fluorodecyltrimethylaminosilane 3 to -0H group 2 Reverse (Fig.1 (b)). At this time, perform the fermentation indicated in Equation 4 -3. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm)

"*" Description of the invention (NO) Reaction M causes the formation of ten t of fluorodecyltrimethoxysilane surfactant molecules.

-SiOCH3 + Η2 Ο-&gt;-SiOH + CH3 OH In addition, the silanol group obtained in the reaction represented by the above formula and the active hydrogen of the -OH group generate a dehydrogenation reaction shown in formula 3. As a result, the ten: 1: fluorodecyl trimethoxysilane surfactant was chemically adsorbed and fixed on the surface of the substrate via the SiO bond through the covalent bond.

The formula R-H +--SiOH + HO-substance- &gt; -SiO-substance + Hz 0 excess unreacted reagent M cloth is wiped and removed, and the heptafluorodecyltrimethoxysilane molecule is bonded via SiO through the net Coated knots are fixed to the surface of the substrate. An M fluorocarbon-based adsorbable polymer film 4 (film thickness of several nanometers) was formed. The film did not peel off by a transverse cutting test. The contact angle of water is 11 5 °. In addition, the contact angle hardly deteriorates after 50,000 wet cloth wipes. -32- This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 public capital) ---------: -----; --- Order-^ --- 耒 (please read the precautions on the back first and then fill out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 404¾ ^ 5. Description of the invention ) A7 B7. The salad oil applied on the substrate is easily wiped off with toilet paper. The results are shown in Table 2. (Please read the notes on the back before filling this page.) In this example, by adding microcapsules, an acid catalyst is added to obtain corrosion resistance and prevent self-reflection. The deterioration of the preservation property is mainly caused by hydrolysis reaction between water and an alkoxysilane agent in the presence of an acid catalyst. Therefore, in order to improve the corrosion resistance, the acid catalyst and the alkoxysilane surfactant must be prevented from being mixed with each other. In other words, avoid mixing if one or both of the alkane-based sand surfactant and the acid catalyst are microencapsulated when added *. As a result, only the acid catalyst was not microencapsulated. Moreover, according to one method, the acid catalyst and the alkoxysilane surfactant must be mixed, and the mixture is in contact with the surface of the substrate. In other words, alkane-based silanes and acid catalysts need to react on the surface of the sacrifice * However, the catalyst and surfactant, if microencapsulated, are not mixed. To solve the problem * use stress capsules. As a result, the microlumbar sac shattered when the Lulian surface was finally applied to the substrate. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Furthermore, if volatile acids such as osmic acid and nitric acid or the like are used as the acid catalyst, it is preferable to add calcium carbonate in an amount of 5 to 30% by weight. As a result, excess volatile acids are captured by the reaction between the volatile acids and calcium carbonate to avoid acid odors. V mm η In this example, calcium carbonate was added. The following materials κ were mixed to prepare a final treating agent and the same as in Example 10. The following materials are mixed in a conical flask; this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 404977 V. Description of the invention (32) Positive — Bonded alkanes (bp · 180 * 0) 20 g butyrate 4 g polysiloxane (S hi π etsu K agaku

Kogyo »KF-96» 1 000 cps) 3 g_ Kanto Kagaku (· ρ · 86Ό) 25 g calcium carbonate (average particle size is lui. It is added as a grinding material or hydrochloric acid capture_) 15 g mixed The material was stirred at 100 t :, so a suspension was provided; the suspension was cooled to room temperature; 8 g of 4% »acid and 10 g of heptafluorodecyltrimethoxy group were microencapsulated with an imapolin resin catalyst as an acid catalyst Silane (CF3 (CF 2) 7-(CH2 U -Si (0C2 Hs) 3 and agitated. Therefore, provide a final curing agent for solid 鼍 soft 鼸 with a viscosity of 4500 cps. Ten t fluorine decyl trimethylsilyl silane based K The method suggested in the announcement wraps the waist. This final treatment agent has a high throbability. However, the same experiments as in Example 10 indicate that in this example * except that the final treatment was applied to the boban subject and the glass was allowed to瓖 After leaving for 20-30 minutes, a white protective layer was obtained. The results are shown in Table 2. 謇 _ 利 12 The same experiment as in Example 10, except that ten fluorodecyltrimethoxysilane was used in Example 10 to Tridecylfluorooctyltriethoxysilane (CF3 (CF2) 5 (CHZ) 2 -Si (0C2 HS) 3). The results are shown in Table 2. If the glass is coated in this final treatment, the smell of hydrochloric acid is hardly -34- This paper size applies Chinese National Standard (CNS) A4 specification (210 x 297 mm) — — — — — — — — — — — Install! 1 ·! 'Order • τ:! · &quot; ·-, (Please read the notes on the back before filling out this page) Central Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Standards Bureau 404977 Λ7 ___________W _________ V. Description of the invention () Today) Can be identified. Fen Example 1 q The same experiment as in Example 11, except that the glass W rearview mirror used in Example 11 was replaced In addition, in this case, some odors of hydrochloric acid are recognized. The results are shown in Table 2. Example M The same experiment as in Example 13 except for the bunnet substitution and activation of the mirror K vehicle used in Example 13. Alumina (15 g) was used instead of the calcium carbonate used in Example 13. In this case, some odors of hydrochloric acid were recognized. The results are shown in Table 2. Window Example 15 The same experiment as in Example 11, Except used in Example 11 The glass M urethane bumper element was replaced. The results are shown in Table 2. Tube Example 1 β The same experiment as in Example 10, except that Alfa-Alumina M silica was used in Example. (Average particle size is 5 μm) except for substitution. The results are shown in Table 2. When the same experiment as in Example 10 was performed for the bottle example 17 except that the amount of n-pinene was 40 g. The viscosity of the prepared liquid osmium is about 3 G00 to 4 G 0 0 c ps. The results are not shown in Table 2. Participant Example 3 The same experiment as in Example 10, except that the microcapsule-sealed sulfuric acid-35 was removed. This paper size applies the Chinese National Standard (CNS) A4 specification (2 丨 〇 &gt; &lt; 297 Gonghuan) ^: ~ IiT—p ------ 0--(Please read the precautions on the back first to write this page),-A7 ΑΠ4977 V. Invention description (^ PRIVATE) Other than B7. The results are shown in Table 2. As with this reference example, if only an alkoxysilane-based material is used, the protective plutonium formed will have almost no durability. Participant Li 4 As in the interphase experiment in Example 11, except that the microencapsulated osmic acid was removed. The results are shown in Table 2. As in Reference Example 3, the formed protective calendar has almost no longevity. Table 2 Contact angle of water (°) Contact angle of oil (°) Initial rubbing test Number of initial rubbing test After number test After pickling Example 10 115 116 98 96 Example 11 114 113 95 94 Example 12 116 114 96 92 Example 13 113 111 95 93 Example 14 111 108 99 89 Example 15 113 104 95 87 Example 16 113 108 96 88 Example 17 116 111 92 94 Reference Example 3 98 49 60 23 Reference Example 4 89 47 45 16 It is clear from Table 2 that even after the surface is repeatedly wiped with Mae cloth -36- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back first Please fill in this page for the items) Install i! J--Ί-ΙΙΓ · ΤΤ · if Printed by the Employees 'Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Printed by 404977 r _________ Η The substrate treated by the inventive final treatment agent maintains its water and oil repellent properties. In Reference Examples 3 and 4, the water and oil repellent properties are low, and almost no such properties after testing. As explained above, borrow The method of using the final treating agent of the present invention can form a polymer hafnium through the use of active hydrogen on a substrate, thus effectively forming a protective layer on a substrate such as plastic, ceramic, sloped glass, or the like. At the same time, in one or both of the alkoxysilane surfactant and the acid seeding agent, the microcapsules are sealed and added to the final treatment agent to make the activation life appear as long as in the case where the reagents are not microencapsulated. Alternatively, if a volatile acid is used, it is preferable to add a material that reacts with the acid. As a result, the additional volatile acid is captured by the reaction between the volatile acid and the material that reacts with the acid. This can avoid the acid smell. The method can be used to make such equipment as electronics, appliances, automobiles, industrial equipment, mirrors, glasses lenses and the like. The above equipment requires a protective film to prevent dirt easily, and has heat resistance, weather resistance, And abrasion resistance and water and oil resistance. The present invention can be embodied in other specific forms without leaving its spirit or basic special stamps. Disclosed in this application This embodiment is to be considered in all respects as an illustration and not to be limited. The scope of the present invention is as shown in the scope of the appended patent application rather than as described above. * All equivalent meanings and scope changes included in the scope of the patent application are subject to change. It is intended to be included in this. This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 public power) ---------- 1¾ clothing ----.-- 1T ------.--- Λ r..--(¾ Please read the precautions on r side before filling in this page)

Claims (1)

404977 Patent application scope 肷 10 · 27 1. A final treatment agent comprising an alkoxysilane surfactant, an acid catalyst and a non-aqueous liquid or solid medium, wherein at least one of the alkoxysilane surfactant and the acid catalyst is microencapsulated, wherein the alkoxy Silane surfactants include fluorocarbon-based and hydrocarbon-based 2 * Abrasive materials are included according to the application. 3 · According to the application include calcium carbonate. 4 · According to the viscosity of the application body medium at 5 * According to the application of liquid or solid medium Ό-2 0 0 ¾Boiling point of 6 · According to the application of the final treatment agent in the scope of patent No. 1 according to the surface of alkoxysilane, further to the scope of patent scope The final treatment agent of 1 item * Furthermore, the final treatment agent of item 1 of the patent specification &gt; wherein the temperature of liquid 25 ° C is not less than 1000 cps. Please refer to the final treatment agent of item 1 of the patent, where the system is a mixture of a medium with a boiling point greater than 2Q () t: and a medium with 100. Please refer to the final treatment agent of item 1 of the patent, in which the active agent is provided by the following formula: CF3-(CF2) n- (R) a-SiXp (0A) 3 _P Please. Read First-Read · Back. f Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, the table Q 1 _2 〇 Burning the foundation, B table 0 or Ci _ 3 alkyl; and P table 〇, 1 or 7 · According to the final treatment agent in the scope of patent application, item 2 The abrasive material contains at least one component with a diameter smaller than that selected from the group consisting of: alumina, calcium oxide, calcium carbonate, silicon carbide, boron carbide, and chromium oxide. This paper size is applicable to China National Standard (CNS) A4. (210X297 mm) 888 8 ABCD 404977 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 6. Application for patent scope 1 | 1 Oxidation A ± h 撖 Synthetic diamond and fine-grained silica 0 Chapter 1 1 1 8 A method of using the final treatment agent is to include the steps m /--! I please-1 I will include alkoxysilane surfactants Read catalysts and non-aqueous first read 1 I read 1 1 Final treatment agent for sexual fatigue or solid media is applied to the well-received substrate back * 1 to 1 surface syllable 1 will react with active hydrogen on the substrate surface懕 to Alkoxysilicone Surfactants and Items | Resilanol Condensation Catalysts and Filling · This 1 Pack | Remove excess unreacted final treatment agent from the surface of the substrate 0 page 1 1 9 The method of using the final treatment agent in item 8 further includes a step of washing the substrate before applying the final treatment agent. I ΰ-order 10 0 The method of using the final treatment agent to surround the item according to item 8 of the patent claim Of which at least __ · the silanol condensation catalyst and alkoxy Silane surface 1 I The active agent is microencapsulated and the microencapsulation is broken while applying the final treatment agent &gt; 1 k 1 1 Capsule of alkoxysilane surfactant or silanol condensation catalyst 0 1 line 1 1 according to The 1 1 method using the final treatment agent of the patent application No. 8 wherein the final treatment agent further includes at least one abrasive material and the most-1 I final treatment agent is applied on the surface of the substrate &gt; 1 at least a part of the polishing Part of the surface of the substrate '1 0 1 1 2 — * A method for using the final treatment agent, which includes these steps 1 step application including an alkoxysilane surfactant acid catalyst and a non-aqueous 1 I fatigue or solid hip The final treatment agent of the medium is at least one of the alkoxy 1 1 I-based silane surfactants and acid catalysts are microencapsulated to a good wash in advance 1 1 — 2- 1 1 This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) A8 404977 and D8 VI. Patent application scope: The microcapsules are broken during the application of the final treatment agent; the microcapsules are broken during the application of the final treatment agent; The alkoxysilane surfactant of the final treatment agent reacts with the acid catalyst; and the excess of the final treatment agent is removed from the substrate surface. 1 3 * The method for using a final treatment agent according to item 12 of the scope of patent application, further comprising a step of washing the substrate before applying the final treatment agent. '1 4 · The method for using a final treatment agent according to item 12 of the patent application, wherein the final treatment agent further includes at least one abrasive material and the final treatment agent is applied to the surface of the substrate; The textured surface. --------- 丨 Installation -----: Order -------- Line ram "Please read the precautions for ^^^^, then buy this) Intellectual property of the Ministry of Economic Affairs The paper size printed by the Bureau's Consumer Cooperative is applicable to China National Standard (CNS) A4 (210X297 mm)