TW380112B - Process for applying labels with delayed adhesive activation - Google Patents

Process for applying labels with delayed adhesive activation Download PDF

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Publication number
TW380112B
TW380112B TW086109816A TW86109816A TW380112B TW 380112 B TW380112 B TW 380112B TW 086109816 A TW086109816 A TW 086109816A TW 86109816 A TW86109816 A TW 86109816A TW 380112 B TW380112 B TW 380112B
Authority
TW
Taiwan
Prior art keywords
label
adhesive
interface
patent application
item
Prior art date
Application number
TW086109816A
Other languages
English (en)
Inventor
Lynn E Bright
Original Assignee
B & H Mfg Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by B & H Mfg Co Inc filed Critical B & H Mfg Co Inc
Application granted granted Critical
Publication of TW380112B publication Critical patent/TW380112B/zh

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/38Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor by liberation of internal stresses
    • B29C63/40Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor by liberation of internal stresses using sheet or web-like material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/02Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
    • B29C63/04Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like
    • B29C63/06Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material by folding, winding, bending or the like around tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C3/00Labelling other than flat surfaces
    • B65C3/06Affixing labels to short rigid containers
    • B65C3/08Affixing labels to short rigid containers to container bodies
    • B65C3/14Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical
    • B65C3/16Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical by rolling the labels onto cylindrical containers, e.g. bottles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C3/00Labelling other than flat surfaces
    • B65C3/06Affixing labels to short rigid containers
    • B65C3/08Affixing labels to short rigid containers to container bodies
    • B65C3/14Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical
    • B65C3/16Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical by rolling the labels onto cylindrical containers, e.g. bottles
    • B65C3/163Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical by rolling the labels onto cylindrical containers, e.g. bottles where the label is of the wrap-around type
    • B65C3/166Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical by rolling the labels onto cylindrical containers, e.g. bottles where the label is of the wrap-around type the label being shrunken after application
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00Details of labelling machines or apparatus
    • B65C9/08Label feeding
    • B65C9/18Label feeding from strips, e.g. from rolls
    • B65C9/1803Label feeding from strips, e.g. from rolls the labels being cut from a strip
    • B65C9/1815Label feeding from strips, e.g. from rolls the labels being cut from a strip and transferred by suction means
    • B65C9/1819Label feeding from strips, e.g. from rolls the labels being cut from a strip and transferred by suction means the suction means being a vacuum drum
    • B65C9/1823Label feeding from strips, e.g. from rolls the labels being cut from a strip and transferred by suction means the suction means being a vacuum drum the transfer involving heating means, e.g. heat activated glue-coating of the label
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00Details of labelling machines or apparatus
    • B65C9/20Gluing the labels or articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00Details of labelling machines or apparatus
    • B65C9/20Gluing the labels or articles
    • B65C9/22Gluing the labels or articles by wetting, e.g. by applying liquid glue or a liquid to a dry glue coating
    • B65C9/2247Gluing the labels or articles by wetting, e.g. by applying liquid glue or a liquid to a dry glue coating using liquid rollers or bands
    • B65C9/2256Applying the liquid on the label
    • B65C9/226Applying the liquid on the label discretely, i.e. several points or strips or interrupted films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00Details of labelling machines or apparatus
    • B65C9/20Gluing the labels or articles
    • B65C9/24Gluing the labels or articles by heat
    • B65C9/25Gluing the labels or articles by heat by thermo-activating the glue
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2795/00Printing on articles made from plastics or substances in a plastic state
    • B29C2795/002Printing on articles made from plastics or substances in a plastic state before shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/481Non-reactive adhesives, e.g. physically hardening adhesives
    • B29C65/4815Hot melt adhesives, e.g. thermoplastic adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/481Non-reactive adhesives, e.g. physically hardening adhesives
    • B29C65/4825Pressure sensitive adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/483Reactive adhesives, e.g. chemically curing adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/483Reactive adhesives, e.g. chemically curing adhesives
    • B29C65/485Multi-component adhesives, i.e. chemically curing as a result of the mixing of said multi-components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/486Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by their physical form being non-liquid, e.g. in the form of granules or powders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4895Solvent bonding, i.e. the surfaces of the parts to be joined being treated with solvents, swelling or softening agents, without adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/66Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by liberation of internal stresses, e.g. shrinking of one of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/78Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus
    • B29C65/7858Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus characterised by the feeding movement of the parts to be joined
    • B29C65/7861In-line machines, i.e. feeding, joining and discharging are in one production line
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/78Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus
    • B29C65/7858Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus characterised by the feeding movement of the parts to be joined
    • B29C65/7888Means for handling of moving sheets or webs
    • B29C65/7894Means for handling of moving sheets or webs of continuously moving sheets or webs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/43Joining a relatively small portion of the surface of said articles
    • B29C66/432Joining a relatively small portion of the surface of said articles for making tubular articles or closed loops, e.g. by joining several sheets ; for making hollow articles or hollow preforms
    • B29C66/4322Joining a relatively small portion of the surface of said articles for making tubular articles or closed loops, e.g. by joining several sheets ; for making hollow articles or hollow preforms by joining a single sheet to itself
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/49Internally supporting the, e.g. tubular, article during joining
    • B29C66/496Internally supporting the, e.g. tubular, article during joining using a support which remains in the joined object
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/53Joining single elements to tubular articles, hollow articles or bars
    • B29C66/532Joining single elements to the wall of tubular articles, hollow articles or bars
    • B29C66/5324Joining single elements to the wall of tubular articles, hollow articles or bars said single elements being substantially annular, i.e. of finite length
    • B29C66/53245Joining single elements to the wall of tubular articles, hollow articles or bars said single elements being substantially annular, i.e. of finite length said articles being hollow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/53Joining single elements to tubular articles, hollow articles or bars
    • B29C66/532Joining single elements to the wall of tubular articles, hollow articles or bars
    • B29C66/5326Joining single elements to the wall of tubular articles, hollow articles or bars said single elements being substantially flat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/727General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being porous, e.g. foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/83General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/834General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools moving with the parts to be joined
    • B29C66/8341Roller, cylinder or drum types; Band or belt types; Ball types
    • B29C66/83411Roller, cylinder or drum types
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
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    • B29K2023/06PE, i.e. polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • B29K2023/12PP, i.e. polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29K2025/00Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2705/00Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29K2709/00Use of inorganic materials not provided for in groups B29K2703/00 - B29K2707/00, for preformed parts, e.g. for inserts
    • B29K2709/08Glass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2711/00Use of natural products or their composites, not provided for in groups B29K2601/00 - B29K2709/00, for preformed parts, e.g. for inserts
    • B29K2711/12Paper, e.g. cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
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Description

A7 B7 —__五、發明説明(1 ) ': / 技術領域 本發明係關於使用可於施用於物件後W成具有黏著性 之標籤材料標示物件。 ! 背景技術 i 賣產品陳列時 及堆疊方法施 經濟部中央標準局員工消費合作社印製 物件經標示來鑑別容器內容物並提供販 的吸引力。標籤可成捲供料,套筒,或切割 I 用。曾經開發不同的標籤材料包含紙標籤,i薄膜標籤,層 合膜與紙標籤,苯乙烯發泡體,及層合薄膜i與發泡體。標 示容器外觀可藉收縮塑膠標籤材料緊密嵌合於容器周圍來 改良,甚至服貼容器輪廓而產生放大招牌外觀。 通常,標籤係打點黏著於物件或呈感壓標籤施用。感 壓標籤通常整個塗有黏著材料,屬於最昂貴b標示方法。 標籤也可恰於標示之前藉黏著劑施用於容器I。黏著劑可以 ; 多種類型施用,包含前緣及尾緣,間隔點,_框,或全面 黏著。 某些用途中,需要最小量黏著劑,特別一欲回收容器 時尤爲如此。先前技術無法提供廉價而有效p標示方法, 可使黏著劑,溶劑,或複雜熔接機轉的使用Μ至最少。 其它用途更適合物件或容器之完全黏著#籤。通常, 越多黏著劑施用於標籤,則標籤越可能出現皺紋或表面變 形。於黏著點上加熱收縮標籤材料也可能引起變形。 需要完全黏著表面之一種用途爲標籤施相於事先印刷 I 罐上。此種方法可使用具有外側裝飾的罐。_由將標籤黏 著於外加標籤的容器,則可大體防止或妨礙標I籤被去除。 — I -- - I ^― I--:本—----—訂 /1-, (請先閲讀背面之注意事項再填篇本頁) 本紙張尺度適用中國國家標準(CNS ) Α4規格(210 X 297公釐) -:4 五、發明説明(2 ) A7 B7 另一種需要完全黏著標籤的情況爲標示接受巴氏滅菌 過程的容器。例如,釀造啤酒時,酒瓶塡充後放置於熱水 或水蒸氣內巴氏滅菌,可能使標籤由容器条脫或於標籤下 方產生氣泡與皺摺。 另一種較佳完全黏著標籤的情況爲使用 籤。例如,廉價聚乙烯或聚丙烯標籤可提供 特性但具有彈性而可拉伸。若薄膜標籟直接 容器,則可消除施用於容器後的標籤拉伸問^ 先前技術提供罐之全然黏著標籤之方法 之加拿大專利1,012,906。Germiat專利案提示 標籤材料,其中surlyn之擠塑層作爲黏著劑 薄的可拉伸標 多種絕佳標示 黏著於物件或 提示於Germiat 使用共同擠塑 標籤材料及有 待標示罐於Germiat方法中加熱,同時施用標 黏著性且完全黏著於容器。Germiat標籤之缺 活化不一定均勻,結果導致容器與標籤間形 ,特別於巴氏滅菌後。 另一種獨特之標示用途中,使用熱收縮 籤使標籤變成 點爲黏著劑之 成皴紋或氣泡 眼貼於容器輪 廓的標籤,如Hoffman之美國專利4,704,173所揭示。如 (請先閱讀背面之注意事項再填寫.本頁) 經濟部中央標準局員工消費合作社印製
Hoffman專利案提示,使用收縮標籤,標籤的 槪略垂直線有熱熔黏著劑施於標籤之前緣及 餘部份較佳不含黏著劑,使標籤收縮時可移 籤材料的趨皺。雖然Hoffman專利案之包裹收 遍有效用於多種標示用途,但未完全塗覆黏#劑使得此種 方法不適合某些用途。 前述先前技術的問題及相關限制可藉申_靑人之發明解 前緣及後緣於 後緣。標籤其 丨立而未造成標 縮標示方法普 本紙張尺度適用中國國家標準(CNS ) A4規格(21 〇 X 297公釐) A7 B7 五、發明説明(3 ) 決,摘述如下。 發明槪述 本發明提供一種標示方法,其中標籤$置於物件上的 所需位置,隨後經由活化可變化黏著性的塗層、層或表面 固定於物件上,該等塗層或表面於標籤最d放置於物件上 時大體不具黏著性。 根據實施本發明之一種方法,標籤係經 份之物件然後將標籤包裹於物件周圍而施用 。標籤之第二部份可黏著於物件或標籤。標 . 變成黏著性的界面,其界定爲不會黏著於物 裹於物件周圍時可滑動或位移的表面。可能 藉加工步驟變成黏著於物件。 根據此種方法可以快速發明熱熔膠施用 及後緣而達成快速成捲進料標示用途。可能 由下列方式施用:與標籤共同擠塑,將黏著 上,將油墨印刷於標籤上使其變成黏著性 於標籤上。另外,可能黏著表面實際上可爲 或容器的聚合物。 經濟部中央標準局貝工消費合作社印製 由黏著第一部 於物件表面上 籤包含一種可 件但當標籤包 黏著界面稍後 於標籤的前緣 黏著界面可經 劑印製於標籤 或將塗層噴灑 用來形成標籤 (請先閱讀背面之注意事項再填爲本頁) 可能黏著界面亦可爲物件塗層或表面。%件塗層於稍 後可藉加熱、施用照射能、暴露於化學劑或1¾用機械力活 化。 全然黏合標籤至物件之另一優點爲標籤t支撐或加強 玻璃瓶’而使瓶壁可變得更薄並減少容器破#機會。全然 黏著的標籤也可延伸至容器帽區並提供極爲有效的仿僞標 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐) 經濟部中央標準局員工消費合作社印製 前緣及後緣或 變成黏著性。 後緣變成黏著 化直到標籤置 堆疊標示技術' 之,套筒施用 能黏著界面。 物件或藉局部 上固定定位或 眼貼於物件或 A7 B7 五、發明説明(4) 示機制。 根據本發明之另一態樣,標籤薄膜也可|服貼容器輪廓 收縮。收縮步驟過程中,特別使用熱來引d標籤薄膜收縮 時可活化熱可活化黏著劑。 本發明之其它方法包含使用溶劑於標籤 其它部份原地形成黏著劑而使材料局部區域 打點施用照射或熱也可例如使標籤的前緣及 性,同時留下前緣與後緣間之部份大體未活 於容器後才活化。 雖然前述方法係針對成捲進料及切割與 ,但本發明也可應用於套筒施用標籤。簡言 標籤可提供介於有待標示物件與套筒間的可 然後將套筒置於物件上,藉手指局部固定於 施用黏著劑或活化黏著劑,而使標籤於物件 藉其它機械固持機制固定定位。標籤可收縮 於標籤固定於物件之步驟後藉活化潛在黏著碎面而黏著於 物件。 根據本發明,當由於成份改變或直接平P印刷的容器 (例如罐)之印刷錯誤而需要改變容器上方#示時,可於 容器提供新標籤。也較佳若政府的標示規定改變時可對物 件提供新標籤。本發明可用於任何物件。但#別適合的領 域爲標示各型容器。包含塑膠容器、玻璃容t、金屬罐及 紙板容器等容器廣泛使用皆可由本發明獲益 本發明之此等及其它優點及目的鑑於下文附圖之說明 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐〉 -7 - (請先閲讀背面之注意事項再填寫本頁)
介於前緣與後 該標籤具有 空氣之下收縮 容器而使可能 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明(5 ) 及如下本發明之較佳具體例綜論附圖將顯然烏明 圖式之簡單說明 第1圖爲流程圖示例說明本發明之標示p法之步驟 第2圖爲捲筒進料標示生產線之示意平#圖。 第3圖爲套筒施用標示方法之示意透視。 第4圖爲切割與堆疊標示方法之示意透+圖。 第5圖爲具有前緣及後緣黏著劑圖樣及, 緣間之可能黏著材料塗層之標籤之平面圖 第6圖爲示意圖顯示施加有標籤之容器 前緣及後緣黏膠圖樣及介於中間的可能黏著介面 第7圖爲容器之示意圖,該容器置於熱 部份標籤服貼容器輪廓。 第8圖爲容器之示意圖,熱空氣導引至 黏著界面被活化且全然黏著於容器。 發明之詳細說明 現在參考第1圖,流程圖顯示本發明之步驟之排列 實例及多種變化。附圖中各圖表示第1圖之各適當步驟。 參照第1至4圖,顯示本發明適用於廣泛多種標示技 術。特別示例說明成捲進料標示,如第2圖所示;套筒施 用標籤如第3圖所示;及切割與堆疊標籤如第4圖所示。 使用第2至4圖所示之任一種標示方法可提供標籤來標示 物件如容器。 現在參考第2圖,圖解顯示捲軸進料標+機1〇,其中 —捲12標鐵材料解捲,而標籤材料的胚料14+料至標織切 本紙張尺度適用中國國家標隼(CMS ) A4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁)
五、發明説明(6) A7 B7 經濟部中央標準局員工消費合作社印製 割機16。真空轉鼓18接受並支撐各別標籤20,標籤20係藉 切割機16由胚料14切下。真空轉鼓18係於#黏膠施用器施 用黏膠22支撐標籤20,隨後將標籤20施用至+器24。容器24 利用星輪26以依序關係進料真空轉鼓1 8,星輪由輸送帶28 拾取容器24,餵進真空轉鼓18內部然後於^示之後沈積容 器於輸送帶28上。 可提供廣泛多種標籤材料包含紙標籤 標籤,發泡苯乙烯發泡體標籤,薄膜標籤包 丙烯及聚苯乙烯薄膜之組合或此等材料之層4 標籤可藉切割機16切成足夠完全圈住容 於容器24上方提供點狀標籤。黏膠施用器U 緣黏膠類型、圖框、分隔點、黏膠線或寬帶 劑類型。 根據本發明,黏膠施用器22可提供全型 可留下標籤2 0之某些部份未施用任何黏著劑 籤20之容器24之前係處於黏著狀態。黏膠施 施用熱熔膠,冷凍或溶劑,該溶劑當施用於 原地形成黏著劑。另外,黏膠施用器22可爲 籤20上形成黏著劑部份的裝置。例如,熱桿 紙聚丙烯層合 含聚乙烯,聚r ° 器24長度或僅 可施用前及後 滾花滾軸黏著 黏著劑,但也 其於施用標 用器22可用於 標籤20時,可 另一種可於標 熱空氣噴槍 ,輻射發射器或水施用器可匹配特殊標籤或標籤塗層而提 供局部黏著劑,該黏著劑可使容器24拾取標籤20,將標籤20 黏至容器24上,使容器被標籤20所包裹。 現在參考第3圖,示例說明套筒試用標示方法,一個 瓶30放置於套筒標籤32上,標籤之放置可由下方滑動至瓶30 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 9 - (請先閲讀背面之注意事項再填寫本頁) A7 B7 五、發明説明(7) 922,459 (倂述 。套筒施用標籤系統之揭示參考美國專利3,< 於此以供參考)。 現在參考第4圖,顯示切割與堆疊標示-,其中標籤36 由物件38由標籤庫34上拾取。 無論標籤之供應機制如何,介於標籤與 間提供可能黏著界面。可能黏著界面包括一 料於標籤上,一層潛在黏著材料與聚合物標 由黏著材料製成的個別薄片,一層塗層提供 物件上或聚合物標籤材料或物件表面其可藉I 變成黏著性。 如第5圖所示,顯示一段標籤20其可由 進料標籤機或第4圖之切割與堆疊標籤機提 有待標示物件 種印刷黏著材 籤共同擠塑, 於有待標示的 隨後加工步驟 第2圖之成捲 供。標籤20包 (請先閱讀背面之注意事項再填寫本頁)
、1T 經濟部中央標準局員工消費合作社印製 含一個前緣黏著劑長條40及一個尾緣黏著劑長條42。未被 前緣及後緣黏著劑長條40及42遮蓋的標籤份塗覆有潛 在黏著塗層44 ,塗層44之提供方法容後述 如第6圖所示,前緣黏著劑40呈現至容#24而於容器 接觸標籤段20時提供快速拾取黏著劑。容器旋轉而使標籤 包裹於容器24周圍直到後緣黏著劑42重疊且黏合至標籤20 之面向外部份爲止。當標籤20裹於容器24周圍時,使標籤 移位且自由移動,不受任何活性黏著劑干擾,否則可能使 標籤開始黏合而導致皺紋或其它表面瑕疵。雖然潛在黏著 塗層44具有極低黏著性質,但較佳塗層於標示過程中不會 沾黏至容器至少至標籤固定於容器爲止不會法黏。標籤可 利用尾緣黏著劑42直接固定於物件 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 五、發明説明(8) A7 B7 另外,標籤可藉部份收縮套於瓶3 0或其它容器例如金 屬罐外部的套筒32固定。標籤定位並固定於物件或容器後 經濟部中央標準局員工消費合作社印製 ,服貼於容器輪廓之標籤收縮持續進行,如 無論是否需要收縮至輪廓上,標籤可藉活化 而永久性黏著於其整個表面,如第8圖所示 可使用多種機制來提供本發明之延遲黏 黏著界面的選擇可決定活化機制。熱(^\_黏 噴灑 Century CX887或 Cellu Craft White Coat 、-'—.....- 黏著劑公司及Cellu Craft出售)於聚乙烯及聚 標籤內側。其它替代活化機制包含照射,照 或其它光源,微波照射或其它市售可活化黏 實際變成具有黏著性的照射來源。其它類型 藉施用水、施用流體或氣體化學品,或施用 過變成黏著性的時間延遲黏著劑活化類型。p —種潛在黏 著劑微包膠黏著劑,其包含微膠囊,例如環氧成份膠囊 其接受壓力或機械力時破裂,使得物件與標籤間形成環氧 樹脂黏合。 雖然如前述,本發明槪略集中敘述施用可能黏著界面 至標籤,但也可藉噴灑,浸塗,或以其它方#塗覆物件而 於平或其它物件上形成可能黏著界面,隨後+加標籤。若 可能黏著界面於容器或物件上形成,則可於標籤施用之前 維持潛在黏著狀態,而僅於標籤以所需取向ψ定於物件或 容器後才活化標籤。 隨著可能黏著界面通常預期爲遮蓋標籤萍瓶間整個面 第7圖所示。 可能黏著界面 著功能。可能 著Λ之範例爲 劑(Century 丙烯層合薄膜 射可爲紅外光 著劑或聚合物 潛在黏著劑可 障著時間的經
(請先閲讀背面之注意事項再填寫本頁) 、-° 本紙張尺度適用中國囡家標準(CNS〉Λ4規格(210X297公釐〉 五、發明説明(9 ) A7 B7 積的界面,但也預期使用部份遮蓋該面積的界面。例如 若希望於標籤上方提供折價卷’則較佳避免 於折價卷後方 施用潛在黏著材料,因而容易由物件或容器_離 環在參考第1圖,最末步驟係將全然黏 於物件或容器上。於標籤於物件或容器上占 合的標籤提供 據期望位置之 後,將標籤黏合至物件,相信可提供一致高品質的標籤 前文本較佳具體例之詳細說明僅供舉例 絕非限制其範圍。本發明之廣義範圍係依據 利範圍界定。 說明之用,而 隨附之申請專 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消费合作社印製 本紙張尺度適用中國國家操準(CNS ) A4規格(210X297公釐) A7 經濟部中央標準局員工消費合作社印製 Β7 五、發明説明(10) 元件標號對照 10.. ..標籤機 12·· •.捲 14.. ..胚料 16.· ..標籤切割機 18._ ..真空轉鼓 20,36.…標籤 22·. ..黏膠施用器 24.. ..容器 26·· ..星輪 28·· ..輪送帶 30.· .•瓶 32·. ..套筒標籤 34.· ..標籤庫 38·. ..物件 40.. ..前緣黏著劑長條 42·. ..後緣黏著劑長條 44.. ..潛在黏著劑長條 本紙張尺度適用中國國家標準(CNS ) Α4規格(210 X 297公釐) - 13 - (請先閱讀背面之注意事項再填寫本頁)
、1T

Claims (1)

  1. 申請專利範團 κ ~種標示物件之方法包括: 提供一個有待標示的物件; 提供一個有待施用至該物件的標籤 提供一個潛在黏著界面介於物件與肆籤間; 黏著標籤之第一部份至物件; 完全環繞該物件包裏該標籤,而潛担黏著界面係 與物件接觸; 黏著標籤之第二部份至標籤遠離該物(件之表面; 於黏著第一部份之物件及第二部份Ψ標籤之遠離 物件之表面步驟後,使潛在黏著界面黏著 2·如申請專利範圍第1項之方法,其中該f 於物件。 在黏著界面 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印裝 爲可活化黏著劑塗層提供於標籤上,且_持大體非黏 著狀態,而使標籤之介於第一部份與第:t部份間之部 份於包裏步驟中於物件上移位。 3.如申請專利範圍第2項之方法,其中該靖在黏著界面 爲標籤之共同擠塑層 4·如申請專利範圍第1項之方法,其中該g在黏著界面 爲標籤,該標籤係由一種材料製成,該材^料可變成黏 著性但於包裏步驟期間可維持大體非黏著 使標籤之介於第一部份與第二部份間之部 步驟期間於物件上移位 5. 如申請專利範圍第4項之方法,其中該標籤係選自聚 乙烯,聚苯乙烯及聚丙烯。 6. 如申請專利範圍第1項之方法’其中該使表面黏著於 狀態,因而 份可於包裏 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -14 · 訂 A8 B8 C8 D8 申請專利範圍 物件之步驟係經由加熱標籤之潛在黏著:^面之局部部 份進行。 7. 如申請專利範圍第1項之方法,其中該_表面黏著於 物件之步驟係經由使標籤之潛在黏著界&暴露於照射 能進行。 8. 如申請專利範圍第1項之方法,其中該使表面黏著於 物件之步驟係經由使標籤之潛在黏著界^暴露於化學 劑使界面變成黏著性進行。 9. 如申請專利範圍第1項之方法,其中該4層爲微包膠 黏著劑,及該使界面黏著於物件之步驟係經由施加機 械力至標籤之潛在黏著界面,使界面變成黏著性進行 〇 10. 如申請專利範圍第1項之方法,其中該第二部份黏著 於物件之步驟後與使潛在黏著界面黏著;4物件之步驟 前,加熱標籤使其收縮服貼物件輪廓。 ------*----衣-- (請先閲讀背面之注意事項再填寫本頁) 、1T 經濟部中央標準局®c工消費合作社印製 施用熱熔膠至標籤之前端及尾端。 12.如申請專利範圍第1項之方法,其中該黏 著步驟包含 施用溶劑至標籤材料而原地形成黏著劑。 13.如申請專利範圍第12項之方法,其中該溶 劑施用於前 緣使包裏步驟中前緣變成黏著性。 14.如申請專利範圍第1項之方法,其中該黏 著步驟包含 活化潛在黏著界面之有限部份使標籤之第 一部份及第 二部份黏著於物件。 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) - 15 - A8 B8 C8 D8 申請專利範圍 15. 如申請專利範圍第1項之方法,其中該 係經由將黏著劑印製於標籤之整個表面上 16. 如申請專利範圍第1項之方法,其中該 係經由將黏著劑以某種圖樣印製於標籤之 f在黏著界面 形成。 _在黏著界面 表面上形成 經濟部中央標準局負工消费合作社印装 17. —種標示物件之方法包括: 提供一個有待標示的物件; 提供一個有待施用至該物件的標籤 可能黏著表面; 黏著標籤之第一部份至物件; 環繞該物件包裏該標籤而可能黏著表面係與物件 接觸_ ; 黏著標籤之第二部份至標籤之與標_第一部份隔 開的某個位置; 黏著第一及第二部份至物件後,使可能黏著表面 黏著於物件。 18. —種標示物件之方法包括: 提供一個有待標示的物件; 提供一個有待施用至該物件的標籤 可能黏著表面; 黏著標籤之第一部份至物件; 環繞該物件包裏該標籤而可能黏著詞 接觸; 黏著標籤之第二部份至標籤之與標籤 該標籤具有 該標鐵具有 面係與標籤 第一部份隔 本紙張尺度適用中國國家標準(CNS ) A4規格(2i〇X297公釐) · 16 - 請 先 閲 背 面 之 注 意 事 項 再 訂 u/i.1六、申請專利範圍 A8 B8 C8 D8 開的某個位置; 黏著第一及第二部份至物件後, 黏著於物件。 19. 一種標示物件之方法包括: 提供一個有待標示的物件; 提供一個標籤材料套筒; 提供潛在黏著界面介於物件與套筒間; 將套筒安放於物件上; 固定套筒之物件;及 於固定步驟之後經由活化潛在黏著#面而使套筒 黏著於物件。 20. 如申請專利範圍第19項之方法,其中該幸驟係至少部 份藉由將標籤縐縮至物件上進行。 可能黏著表面 經濟部中夬標準局員工消費合作社印装 本紙張尺度逋用中國國家標準(CNS ) A4規格(210X297公釐〉 17 ('請先閲讀背面之注意事項再填寫本頁)
TW086109816A 1996-07-12 1997-07-11 Process for applying labels with delayed adhesive activation TW380112B (en)

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ATE278610T1 (de) 2004-10-15
IL128023A (en) 2001-05-20
AU729573B2 (en) 2001-02-01
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JP2000505764A (ja) 2000-05-16
DE69731115D1 (de) 2004-11-11
US5897722A (en) 1999-04-27
CA2260952C (en) 2003-12-09
CA2260952A1 (en) 1998-01-22
MXPA99000492A (es) 2002-07-22
BR9710301A (pt) 1999-08-17
AU3719497A (en) 1998-02-09
PE93898A1 (es) 1998-12-31
IL128023A0 (en) 1999-11-30
EP0954441A4 (zh) 1999-12-01
EP0954441A1 (en) 1999-11-10
US6485803B1 (en) 2002-11-26
CZ7199A3 (cs) 1999-08-11
AR008775A1 (es) 2000-02-23
EP0954441B1 (en) 2004-10-06

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