TW202336112A - ε-己內醯胺及聚醯胺6寡聚物之回收方法、以及聚醯胺6之製造方法 - Google Patents

ε-己內醯胺及聚醯胺6寡聚物之回收方法、以及聚醯胺6之製造方法 Download PDF

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Publication number
TW202336112A
TW202336112A TW111140198A TW111140198A TW202336112A TW 202336112 A TW202336112 A TW 202336112A TW 111140198 A TW111140198 A TW 111140198A TW 111140198 A TW111140198 A TW 111140198A TW 202336112 A TW202336112 A TW 202336112A
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TW
Taiwan
Prior art keywords
polyamide
oligomer
caprolactam
water
solid
Prior art date
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TW111140198A
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English (en)
Chinese (zh)
Inventor
山下浩平
高橋昌佑
加藤昌史
西村美帆子
加藤公哉
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日商東麗股份有限公司
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Publication of TW202336112A publication Critical patent/TW202336112A/zh

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/14Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with steam or water
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D223/00Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08Oxygen atoms
    • C07D223/10Oxygen atoms attached in position 2
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D201/00Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02Preparation of lactams
    • C07D201/12Preparation of lactams by depolymerising polyamides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D201/00Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/16Separation or purification
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/04Preparatory processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/28Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic compounds containing nitrogen, sulfur or phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14Lactams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/46Post-polymerisation treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Polyamides (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
TW111140198A 2021-10-29 2022-10-24 ε-己內醯胺及聚醯胺6寡聚物之回收方法、以及聚醯胺6之製造方法 TW202336112A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2021178292 2021-10-29
JP2021-178292 2021-10-29

Publications (1)

Publication Number Publication Date
TW202336112A true TW202336112A (zh) 2023-09-16

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Application Number Title Priority Date Filing Date
TW111140198A TW202336112A (zh) 2021-10-29 2022-10-24 ε-己內醯胺及聚醯胺6寡聚物之回收方法、以及聚醯胺6之製造方法

Country Status (7)

Country Link
US (1) US20250257037A1 (https=)
EP (1) EP4424748A4 (https=)
JP (1) JPWO2023074437A1 (https=)
KR (1) KR20240100346A (https=)
CN (1) CN117940485A (https=)
TW (1) TW202336112A (https=)
WO (1) WO2023074437A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2024286546A1 (en) * 2023-06-06 2025-12-18 Basf Se Process for hydrolytically depolymerizing a polyamide
WO2025234419A1 (ja) * 2024-05-08 2025-11-13 国立大学法人大阪大学 ポリアミド化合物の解重合用触媒及びそれを用いたポリアミド化合物の解重合方法
CN119613281A (zh) * 2024-12-06 2025-03-14 东华大学 一种含酰胺基聚合物的解聚再生方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4624035B1 (https=) * 1967-03-10 1971-07-09
DE4407222A1 (de) * 1994-03-04 1995-09-07 Basf Ag Verfahren zur Rückgewinnung von Caprolactam aus Oliogo- und/oder Polymeren des Caprolactams
US5495015A (en) 1994-12-12 1996-02-27 Basf Aktiengesellschaft Process for producing caprolactam through hydrolytic cleavage of molten polycaprolactam
US5455346B1 (en) 1994-12-12 1999-02-09 Basf Corp Obtaining caprolactam by cleavage of molten polycaprolactam
JPH08217746A (ja) 1995-02-09 1996-08-27 Toray Ind Inc ε−カプロラクタムの精製法
JPH10287645A (ja) * 1997-04-11 1998-10-27 Unitika Ltd 回収ε−カプロラクタム及びその精製法
NL1006575C2 (nl) * 1997-07-14 1999-01-15 Dsm Nv Depolymeriseren van polyamiden.
JP2000034363A (ja) * 1998-07-21 2000-02-02 Toray Ind Inc ナイロン6製品類のリサイクル方法
JP4182273B2 (ja) * 2000-06-27 2008-11-19 住友化学株式会社 ε−カプロラクタムの製造方法
JP2011088943A (ja) * 2009-10-20 2011-05-06 Toray Ind Inc ナイロン6製品のリサイクル方法
CN102352034B (zh) * 2011-07-22 2013-01-30 浙江华建尼龙有限公司 一种除去聚已内酰胺中环状低聚物的机械方法
WO2018055555A1 (en) 2016-09-22 2018-03-29 Sabic Global Technologies, B.V. An integrated process configuration involving the steps of pyrolysis, hydrocracking, hydrodealkylation and steam cracking

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Publication number Publication date
EP4424748A4 (en) 2026-02-11
EP4424748A8 (en) 2024-12-25
WO2023074437A1 (ja) 2023-05-04
US20250257037A1 (en) 2025-08-14
EP4424748A1 (en) 2024-09-04
JPWO2023074437A1 (https=) 2023-05-04
CN117940485A (zh) 2024-04-26
KR20240100346A (ko) 2024-07-01

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