TW202045252A - 用於製造乙烯性不飽和羧酸或酯之催化劑及方法 - Google Patents

用於製造乙烯性不飽和羧酸或酯之催化劑及方法 Download PDF

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Publication number
TW202045252A
TW202045252A TW109107713A TW109107713A TW202045252A TW 202045252 A TW202045252 A TW 202045252A TW 109107713 A TW109107713 A TW 109107713A TW 109107713 A TW109107713 A TW 109107713A TW 202045252 A TW202045252 A TW 202045252A
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TW
Taiwan
Prior art keywords
titanium
catalyst
modified silica
carrier
metal
Prior art date
Application number
TW109107713A
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English (en)
Chinese (zh)
Inventor
亞當 庫倫
Original Assignee
英商盧希特國際公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 英商盧希特國際公司 filed Critical 英商盧希特國際公司
Publication of TW202045252A publication Critical patent/TW202045252A/zh

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001—Calcining
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicon Compounds (AREA)
TW109107713A 2019-03-13 2020-03-09 用於製造乙烯性不飽和羧酸或酯之催化劑及方法 TW202045252A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1903452.9 2019-03-13
GBGB1903452.9A GB201903452D0 (en) 2019-03-13 2019-03-13 A catalyst and a process for the production of ethylenically unsaturated carboxylic acids for esters

Publications (1)

Publication Number Publication Date
TW202045252A true TW202045252A (zh) 2020-12-16

Family

ID=66380284

Family Applications (1)

Application Number Title Priority Date Filing Date
TW109107713A TW202045252A (zh) 2019-03-13 2020-03-09 用於製造乙烯性不飽和羧酸或酯之催化劑及方法

Country Status (11)

Country Link
US (2) US12059669B2 (https=)
EP (1) EP3938101A1 (https=)
JP (1) JP2022524605A (https=)
KR (1) KR20210134782A (https=)
CN (1) CN113631268B (https=)
BR (1) BR112021017311A2 (https=)
GB (1) GB201903452D0 (https=)
MX (1) MX2021011045A (https=)
SG (1) SG11202109282TA (https=)
TW (1) TW202045252A (https=)
WO (1) WO2020183196A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116920819A (zh) * 2023-04-04 2023-10-24 郑州大学 一种用于合成丙烯酸甲酯或甲基丙烯酸甲酯的高稳定性催化剂及其制备方法和应用

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US4357451A (en) 1980-05-21 1982-11-02 Phillips Petroleum Company Chemical dehydroxylation of silica
US4308172A (en) 1980-05-21 1981-12-29 Phillips Petroleum Company Chemical dehydroxylation of silica
US5583085A (en) 1994-06-13 1996-12-10 W. R. Grace & Co.-Conn. Preparation of dehydroxylated supports
JPH115030A (ja) * 1997-06-17 1999-01-12 Nippon Shokubai Co Ltd 酸化物触媒の製造法
GB9807498D0 (en) 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
JP2000279809A (ja) 1999-03-30 2000-10-10 Nippon Shokubai Co Ltd エポキシド製造用触媒及びエポキシドの製法
US6887822B2 (en) 2001-09-25 2005-05-03 Pq Corporation Method for making silica supported, crush-resistant catalysts
JP4385130B2 (ja) 2003-12-11 2009-12-16 独立行政法人産業技術総合研究所 チタン酸化物を含む無機複合体、及びその複合体を触媒に用いるプロピレンオキシドの製造方法
US7247594B2 (en) * 2005-04-13 2007-07-24 Chevron Phillips Chemical Co. Lp Catalysts for olefin polymerization
WO2007078134A1 (en) 2005-12-30 2007-07-12 Lg Chem. Ltd. Transition metal complexes and preparation methods thereof
EP2173485A1 (en) 2007-07-05 2010-04-14 Grace GmbH & Co. KG Method for making inorganic oxide supported catalysts
US8183173B2 (en) 2007-12-21 2012-05-22 Chevron Phillips Chemical Company Lp Fast activating catalyst
US7851645B2 (en) 2008-02-11 2010-12-14 Catalytic Distillation Technologies Process for continuous production of organic carbonates or organic carbamates and solid catalysts therefore
EP2493614A1 (de) 2009-10-28 2012-09-05 Bayer MaterialScience AG Katalysatoren und ihre verwendung
GB201011091D0 (en) 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters
WO2012036445A2 (ko) 2010-09-13 2012-03-22 한국화학연구원 선택산화탈황용 촉매 및 그의 제조방법
AU2011327947B2 (en) * 2010-11-11 2016-05-05 Lucite International Uk Limited A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor
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Also Published As

Publication number Publication date
MX2021011045A (es) 2021-10-13
BR112021017311A2 (pt) 2021-11-16
CA3132627A1 (en) 2020-09-17
JP2022524605A (ja) 2022-05-09
US20220126273A1 (en) 2022-04-28
US12311340B2 (en) 2025-05-27
SG11202109282TA (en) 2021-09-29
CN113631268A (zh) 2021-11-09
US20220193636A1 (en) 2022-06-23
CN113631268B (zh) 2025-08-08
GB201903452D0 (en) 2019-04-24
WO2020183196A1 (en) 2020-09-17
KR20210134782A (ko) 2021-11-10
EP3938101A1 (en) 2022-01-19
US12059669B2 (en) 2024-08-13

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