KR20210134782A - 에틸렌성 불포화 카르복실산 또는 에스테르의 제조를 위한 촉매 및 그 제조 방법 - Google Patents

에틸렌성 불포화 카르복실산 또는 에스테르의 제조를 위한 촉매 및 그 제조 방법 Download PDF

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Publication number
KR20210134782A
KR20210134782A KR1020217032858A KR20217032858A KR20210134782A KR 20210134782 A KR20210134782 A KR 20210134782A KR 1020217032858 A KR1020217032858 A KR 1020217032858A KR 20217032858 A KR20217032858 A KR 20217032858A KR 20210134782 A KR20210134782 A KR 20210134782A
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South Korea
Prior art keywords
titanium
silica support
catalyst
mol
modified silica
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KR1020217032858A
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English (en)
Korean (ko)
Inventor
아담 컬렌
Original Assignee
미쓰비시 케미컬 유케이 리미티드
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Application filed by 미쓰비시 케미컬 유케이 리미티드 filed Critical 미쓰비시 케미컬 유케이 리미티드
Publication of KR20210134782A publication Critical patent/KR20210134782A/ko
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04Alkali metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0209Impregnation involving a reaction between the support and a fluid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0217Pretreatment of the substrate before coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001Calcining
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03Monocarboxylic acids
    • C07C57/04Acrylic acid; Methacrylic acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicon Compounds (AREA)
KR1020217032858A 2019-03-13 2020-03-13 에틸렌성 불포화 카르복실산 또는 에스테르의 제조를 위한 촉매 및 그 제조 방법 Pending KR20210134782A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1903452.9 2019-03-13
GBGB1903452.9A GB201903452D0 (en) 2019-03-13 2019-03-13 A catalyst and a process for the production of ethylenically unsaturated carboxylic acids for esters
PCT/GB2020/050648 WO2020183196A1 (en) 2019-03-13 2020-03-13 A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters

Publications (1)

Publication Number Publication Date
KR20210134782A true KR20210134782A (ko) 2021-11-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020217032858A Pending KR20210134782A (ko) 2019-03-13 2020-03-13 에틸렌성 불포화 카르복실산 또는 에스테르의 제조를 위한 촉매 및 그 제조 방법

Country Status (11)

Country Link
US (2) US12059669B2 (https=)
EP (1) EP3938101A1 (https=)
JP (1) JP2022524605A (https=)
KR (1) KR20210134782A (https=)
CN (1) CN113631268B (https=)
BR (1) BR112021017311A2 (https=)
GB (1) GB201903452D0 (https=)
MX (1) MX2021011045A (https=)
SG (1) SG11202109282TA (https=)
TW (1) TW202045252A (https=)
WO (1) WO2020183196A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116920819A (zh) * 2023-04-04 2023-10-24 郑州大学 一种用于合成丙烯酸甲酯或甲基丙烯酸甲酯的高稳定性催化剂及其制备方法和应用

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US4218345A (en) 1979-01-15 1980-08-19 Chemplex Company Olefin polymerization catalyst of chromium and process of preparing it
US4357451A (en) 1980-05-21 1982-11-02 Phillips Petroleum Company Chemical dehydroxylation of silica
US4308172A (en) 1980-05-21 1981-12-29 Phillips Petroleum Company Chemical dehydroxylation of silica
US5583085A (en) 1994-06-13 1996-12-10 W. R. Grace & Co.-Conn. Preparation of dehydroxylated supports
JPH115030A (ja) * 1997-06-17 1999-01-12 Nippon Shokubai Co Ltd 酸化物触媒の製造法
GB9807498D0 (en) 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
JP2000279809A (ja) 1999-03-30 2000-10-10 Nippon Shokubai Co Ltd エポキシド製造用触媒及びエポキシドの製法
US6887822B2 (en) 2001-09-25 2005-05-03 Pq Corporation Method for making silica supported, crush-resistant catalysts
JP4385130B2 (ja) 2003-12-11 2009-12-16 独立行政法人産業技術総合研究所 チタン酸化物を含む無機複合体、及びその複合体を触媒に用いるプロピレンオキシドの製造方法
US7247594B2 (en) * 2005-04-13 2007-07-24 Chevron Phillips Chemical Co. Lp Catalysts for olefin polymerization
WO2007078134A1 (en) 2005-12-30 2007-07-12 Lg Chem. Ltd. Transition metal complexes and preparation methods thereof
EP2173485A1 (en) 2007-07-05 2010-04-14 Grace GmbH & Co. KG Method for making inorganic oxide supported catalysts
US8183173B2 (en) 2007-12-21 2012-05-22 Chevron Phillips Chemical Company Lp Fast activating catalyst
US7851645B2 (en) 2008-02-11 2010-12-14 Catalytic Distillation Technologies Process for continuous production of organic carbonates or organic carbamates and solid catalysts therefore
EP2493614A1 (de) 2009-10-28 2012-09-05 Bayer MaterialScience AG Katalysatoren und ihre verwendung
GB201011091D0 (en) 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters
WO2012036445A2 (ko) 2010-09-13 2012-03-22 한국화학연구원 선택산화탈황용 촉매 및 그의 제조방법
AU2011327947B2 (en) * 2010-11-11 2016-05-05 Lucite International Uk Limited A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor
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WO2013155982A1 (zh) 2012-04-20 2013-10-24 华东理工大学 一种负载型金属氧化物双活性中心乙烯聚合催化剂及其制备方法与应用
GB201217541D0 (en) * 2012-10-01 2012-11-14 Lucite Int Uk Ltd A process for production of a silica-supported alkali metal catalyst
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GB201506308D0 (en) * 2015-04-14 2015-05-27 Lucite Int Uk Ltd A process for the production of ethylenically unsaturated carboxylic acids or esters
WO2018029548A1 (en) * 2016-08-11 2018-02-15 Sasol South Africa (Pty) Limited A cobalt-containing catalyst composition
US10323109B2 (en) 2017-11-17 2019-06-18 Chevron Phillips Chemical Company Lp Methods of preparing a catalyst utilizing hydrated reagents

Also Published As

Publication number Publication date
MX2021011045A (es) 2021-10-13
BR112021017311A2 (pt) 2021-11-16
CA3132627A1 (en) 2020-09-17
JP2022524605A (ja) 2022-05-09
US20220126273A1 (en) 2022-04-28
US12311340B2 (en) 2025-05-27
SG11202109282TA (en) 2021-09-29
CN113631268A (zh) 2021-11-09
US20220193636A1 (en) 2022-06-23
CN113631268B (zh) 2025-08-08
GB201903452D0 (en) 2019-04-24
WO2020183196A1 (en) 2020-09-17
EP3938101A1 (en) 2022-01-19
US12059669B2 (en) 2024-08-13
TW202045252A (zh) 2020-12-16

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