CN113631268B - 用于生产烯属不饱和羧酸或羧酸酯的催化剂和工艺 - Google Patents

用于生产烯属不饱和羧酸或羧酸酯的催化剂和工艺

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Publication number
CN113631268B
CN113631268B CN202080020666.7A CN202080020666A CN113631268B CN 113631268 B CN113631268 B CN 113631268B CN 202080020666 A CN202080020666 A CN 202080020666A CN 113631268 B CN113631268 B CN 113631268B
Authority
CN
China
Prior art keywords
titanium
catalyst
silica support
support
modified silica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202080020666.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN113631268A (zh
Inventor
亚当·卡伦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical UK Ltd
Original Assignee
Mitsubishi Chemical UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical UK Ltd filed Critical Mitsubishi Chemical UK Ltd
Publication of CN113631268A publication Critical patent/CN113631268A/zh
Application granted granted Critical
Publication of CN113631268B publication Critical patent/CN113631268B/zh
Active legal-status Critical Current
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001—Calcining
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicon Compounds (AREA)
CN202080020666.7A 2019-03-13 2020-03-13 用于生产烯属不饱和羧酸或羧酸酯的催化剂和工艺 Active CN113631268B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1903452.9 2019-03-13
GBGB1903452.9A GB201903452D0 (en) 2019-03-13 2019-03-13 A catalyst and a process for the production of ethylenically unsaturated carboxylic acids for esters
PCT/GB2020/050648 WO2020183196A1 (en) 2019-03-13 2020-03-13 A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters

Publications (2)

Publication Number Publication Date
CN113631268A CN113631268A (zh) 2021-11-09
CN113631268B true CN113631268B (zh) 2025-08-08

Family

ID=66380284

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202080020666.7A Active CN113631268B (zh) 2019-03-13 2020-03-13 用于生产烯属不饱和羧酸或羧酸酯的催化剂和工艺

Country Status (11)

Country Link
US (2) US12059669B2 (https=)
EP (1) EP3938101A1 (https=)
JP (1) JP2022524605A (https=)
KR (1) KR20210134782A (https=)
CN (1) CN113631268B (https=)
BR (1) BR112021017311A2 (https=)
GB (1) GB201903452D0 (https=)
MX (1) MX2021011045A (https=)
SG (1) SG11202109282TA (https=)
TW (1) TW202045252A (https=)
WO (1) WO2020183196A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116920819A (zh) * 2023-04-04 2023-10-24 郑州大学 一种用于合成丙烯酸甲酯或甲基丙烯酸甲酯的高稳定性催化剂及其制备方法和应用

Citations (2)

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JPH115030A (ja) * 1997-06-17 1999-01-12 Nippon Shokubai Co Ltd 酸化物触媒の製造法
JP2000279809A (ja) * 1999-03-30 2000-10-10 Nippon Shokubai Co Ltd エポキシド製造用触媒及びエポキシドの製法

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US4357451A (en) 1980-05-21 1982-11-02 Phillips Petroleum Company Chemical dehydroxylation of silica
US4308172A (en) 1980-05-21 1981-12-29 Phillips Petroleum Company Chemical dehydroxylation of silica
US5583085A (en) 1994-06-13 1996-12-10 W. R. Grace & Co.-Conn. Preparation of dehydroxylated supports
GB9807498D0 (en) 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
US6887822B2 (en) 2001-09-25 2005-05-03 Pq Corporation Method for making silica supported, crush-resistant catalysts
JP4385130B2 (ja) 2003-12-11 2009-12-16 独立行政法人産業技術総合研究所 チタン酸化物を含む無機複合体、及びその複合体を触媒に用いるプロピレンオキシドの製造方法
US7247594B2 (en) * 2005-04-13 2007-07-24 Chevron Phillips Chemical Co. Lp Catalysts for olefin polymerization
WO2007078134A1 (en) 2005-12-30 2007-07-12 Lg Chem. Ltd. Transition metal complexes and preparation methods thereof
EP2173485A1 (en) 2007-07-05 2010-04-14 Grace GmbH & Co. KG Method for making inorganic oxide supported catalysts
US8183173B2 (en) 2007-12-21 2012-05-22 Chevron Phillips Chemical Company Lp Fast activating catalyst
US7851645B2 (en) 2008-02-11 2010-12-14 Catalytic Distillation Technologies Process for continuous production of organic carbonates or organic carbamates and solid catalysts therefore
EP2493614A1 (de) 2009-10-28 2012-09-05 Bayer MaterialScience AG Katalysatoren und ihre verwendung
GB201011091D0 (en) 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters
WO2012036445A2 (ko) 2010-09-13 2012-03-22 한국화학연구원 선택산화탈황용 촉매 및 그의 제조방법
AU2011327947B2 (en) * 2010-11-11 2016-05-05 Lucite International Uk Limited A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor
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JPH115030A (ja) * 1997-06-17 1999-01-12 Nippon Shokubai Co Ltd 酸化物触媒の製造法
JP2000279809A (ja) * 1999-03-30 2000-10-10 Nippon Shokubai Co Ltd エポキシド製造用触媒及びエポキシドの製法

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Also Published As

Publication number Publication date
MX2021011045A (es) 2021-10-13
BR112021017311A2 (pt) 2021-11-16
CA3132627A1 (en) 2020-09-17
JP2022524605A (ja) 2022-05-09
US20220126273A1 (en) 2022-04-28
US12311340B2 (en) 2025-05-27
SG11202109282TA (en) 2021-09-29
CN113631268A (zh) 2021-11-09
US20220193636A1 (en) 2022-06-23
GB201903452D0 (en) 2019-04-24
WO2020183196A1 (en) 2020-09-17
KR20210134782A (ko) 2021-11-10
EP3938101A1 (en) 2022-01-19
US12059669B2 (en) 2024-08-13
TW202045252A (zh) 2020-12-16

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