TW201331279A - 塗料用乾燥劑及使用其之塗料 - Google Patents
塗料用乾燥劑及使用其之塗料 Download PDFInfo
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- TW201331279A TW201331279A TW101145378A TW101145378A TW201331279A TW 201331279 A TW201331279 A TW 201331279A TW 101145378 A TW101145378 A TW 101145378A TW 101145378 A TW101145378 A TW 101145378A TW 201331279 A TW201331279 A TW 201331279A
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- Prior art keywords
- coating
- acid
- fatty acid
- desiccant
- resin
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- 239000003973 paint Substances 0.000 title abstract description 7
- 238000000576 coating method Methods 0.000 claims abstract description 81
- 239000011248 coating agent Substances 0.000 claims abstract description 78
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 10
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 5
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 36
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 35
- 239000000194 fatty acid Substances 0.000 claims description 35
- 229930195729 fatty acid Natural products 0.000 claims description 35
- 239000002274 desiccant Substances 0.000 claims description 33
- -1 fatty acid manganese salt Chemical class 0.000 claims description 32
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 150000001412 amines Chemical class 0.000 claims description 16
- 150000004665 fatty acids Chemical class 0.000 claims description 16
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 4
- GHKSKVKCKMGRDU-UHFFFAOYSA-N 2-(3-aminopropylamino)ethanol Chemical compound NCCCNCCO GHKSKVKCKMGRDU-UHFFFAOYSA-N 0.000 claims description 2
- LSYBWANTZYUTGJ-UHFFFAOYSA-N 2-[2-(dimethylamino)ethyl-methylamino]ethanol Chemical compound CN(C)CCN(C)CCO LSYBWANTZYUTGJ-UHFFFAOYSA-N 0.000 claims description 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims description 2
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
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- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 claims 2
- CWKVFRNCODQPDB-UHFFFAOYSA-N 1-(2-aminoethylamino)propan-2-ol Chemical compound CC(O)CNCCN CWKVFRNCODQPDB-UHFFFAOYSA-N 0.000 claims 1
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- 239000002184 metal Substances 0.000 abstract description 23
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- 229910017052 cobalt Inorganic materials 0.000 abstract description 15
- 239000010941 cobalt Substances 0.000 abstract description 15
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 14
- 150000001414 amino alcohols Chemical class 0.000 abstract 1
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- YRHYCMZPEVDGFQ-UHFFFAOYSA-N methyl decanoate Chemical compound CCCCCCCCCC(=O)OC YRHYCMZPEVDGFQ-UHFFFAOYSA-N 0.000 description 10
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
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- 239000011521 glass Substances 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
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- 239000000049 pigment Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
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- 239000003549 soybean oil Substances 0.000 description 4
- 235000012424 soybean oil Nutrition 0.000 description 4
- 235000015096 spirit Nutrition 0.000 description 4
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- 238000012360 testing method Methods 0.000 description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
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- YHFGMFYKZBWPRW-UHFFFAOYSA-N 3-methylpentane-1,1-diol Chemical compound CCC(C)CC(O)O YHFGMFYKZBWPRW-UHFFFAOYSA-N 0.000 description 1
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Abstract
本發明欲解決之課題係提供不使用對人體之影響有疑慮之鈷金屬皂，更進一步，可縮短重塗時之塗布間隔之塗料用乾燥劑。本發明之解決手段係一種塗料用乾燥劑，其特徵為含有脂肪酸錳鹽(A)及下述通式(1)所示之胺醇(B)，□(式中，R1及R2係分別獨立地表示氫原子或碳原子數為1至6之烷基；X1及X2係分別獨立地表示碳原子數為2至6之伸烷基；Y係表示-NR3-(惟，R3係表示氫原子或碳原子數為1至6之烷基)或氧原子)。
Description
本發明係關於使用氧化聚合型樹脂之塗料之乾燥促進劑的乾燥劑及使用其之塗料。
於含有氧化聚合型樹脂之塗料中，係有添加為使塗料乾燥之乾燥促進劑(乾燥劑)。作為所使用之乾燥劑，通常係為鈷、錳、鉛、鐵、鋅等之重金屬與多種之碳酸的金屬鹽(以下簡稱「金屬皂」)。此等之金屬皂之中，又以鈷金屬皂因具有優越之乾燥性能，而向來被用作主要之乾燥劑至今。
鈷金屬皂雖具有優越之乾燥性能，惟係有於國際癌症研究機關之致癌性風險一覧中被條列於「疑似對人有致癌性」之群組2B而有致癌性之疑慮的問題點、因金屬鈷為稀有金屬而供給不穩定，使鈷金屬皂於成本上較昂貴之問題點，係有需求一面更減少鈷金屬皂之使用量，並具有高度硬化性能之硬化促進劑。
於此，為達成較少之鈷金屬皂之使用量，有提案含有鈷金屬皂、錳金屬皂、以及選自二乙醇胺、二乙基乙醇胺、二丁基乙醇胺、正丁基乙醇胺之至少1種之胺醇之硬化促進劑(例如參照專利文獻1)。然而，係由於仍舊使用鈷金屬皂，而無法解決上述之致癌性的疑慮、原料供給不安及成本高的問題。
作為不使用鈷金屬之乾燥劑，係於前述專利文獻1揭示以前，已有提案併用錳皂與聯吡啶之乾燥劑(例如參
照專利文獻2)。
一般而言於塗飾塗料時，為防止塗布不均的發生，通常係將塗膜形成成分之濃度為稀的塗料進行重塗。重塗之際，若不將塗布之間隔拉開，則於重塗後之塗膜上會產生皺褶、縮褶。因此，揭示於前述專利文獻1或專利文獻2之含有乾燥劑的塗料，係於重塗之際必須空出1日程度之間隔，而有塗飾效率不佳之問題。又，亦有塗膜表面之光澤不充分之問題。
[專利文獻1]日本特開平6-172689號公報
[專利文獻2]日本特開2001-49102號公報
本發明欲解決之課題，係提供不使用對人體之影響有疑慮之鈷金屬皂，更進一步，可縮短重塗時之塗布間隔的塗料用乾燥劑。
本發明者們不斷致力研究之結果發現，以使用非鈷之脂肪酸錳鹽作為脂肪酸金屬鹽，並併用特定之胺醇，係可解決上述課題，而完成了本發明。
換言之，本發明係關於特徵為含有脂肪酸錳鹽(A)及下述通式(1)所示之胺醇(B)之塗料用乾燥劑及使用其之塗料。
(式中，R1及R2係分別獨立地表示氫原子或碳原子數為1至6之烷基；X1及X2係分別獨立地表示碳原子數為2至6之伸烷基；Y係表示-NR3-(惟，R3係表示氫原子或碳原子數為1至6之烷基)或氧原子)。
本發明之塗料用乾燥劑，可提供一面解決致癌性之疑慮、原料供給不安及成本高的問題，並可縮短重塗之時間之間隔的塗料。
本發明之塗料用乾燥劑，係含有脂肪酸錳鹽(A)及下述通式(1)所示之胺醇(B)之物。
前記脂肪酸錳鹽(A)，係脂肪酸之錳鹽，作為前述脂肪酸，可列舉辛酸、環烷酸、新癸酸、異壬酸、桐油酸、亞麻仁油酸、大豆油酸、樹脂酸、松油脂肪酸等。此等之脂肪酸錳鹽(A)係亦可單獨使用亦可作2種以上併用。
前記脂肪酸錳鹽(A)，係可藉由將脂肪酸作為可溶於水之鹽，一般係鈉鹽而溶解於水中，於此之中加入可溶於水之錳鹽，進行被稱為複分解之離子交換反應，藉由水洗、脫水、過濾而獲得。
前記胺醇(B)，係以下式(1)所示之化合物。本發明係藉由使用具有此下式(1)之構造之胺醇，而可發揮乾燥時間短暫且能夠防止因結皮而引起之皺摺或縮褶的優越乾燥性能。
前述一般式(1)所示之胺醇(B)之中，由可一面防止皺摺或縮褶，並更縮短乾燥時間來看，較佳為X1及X2係碳原子數各別為2至3之伸烷基者。
作為前述胺醇(B)之具體例，係可列舉2-[(2-二甲基胺乙基)甲基胺基]乙醇、2-(2-胺乙基)胺乙醇、1-(2-胺乙基)胺基-2-丙醇、2-(3-胺丙基胺基)乙醇、2-(2-二甲基胺乙氧基)乙醇等。尚，此等之胺醇(C)係亦可單獨使用亦可作2種以上併用。
為進一步提升乾燥性能，前述脂肪酸錳鹽(A)中之錳金屬(A)與前述胺醇(B)之以質量基準之摻合比(a)/(B)，係較佳為1/0.1至1/30之範圍，更佳為1/0.3至1/20之範圍
，較較佳為1/0.5至1/10之範圍。
尚，本發明者們認為於本發明中，上述胺醇(B)中之氮原子係配位於金屬(錳)，使金屬之電子狀態變化，提高活性而促進錳皂之氧化觸媒作用，於促進塗料之乾燥之同時，使自塗膜表面至內部均一地硬化，最終係藉由提升內部乾燥性，而使重塗性及塗膜之光澤變良好。
本發明之塗料用乾燥劑，係以藉由將前述脂肪酸錳鹽(A)及前述胺醇(B)以稀釋劑(C)稀釋，來作為處理性良好之溶液使用為佳。作為前述稀釋劑，可例示例如：甲苯、二甲苯、庚烷、己烷、礦油精等之烴系溶劑；甲醇、乙醇、丙醇、環己醇等之醇系溶劑；甲基乙基酮、甲基異丁基酮、環己酮等之酮系溶劑；丙醚、甲基賽路蘇、賽路蘇、丁基賽路蘇、甲基卡必醇等之醚系溶劑；己酸甲酯、癸酸甲酯、十二酸甲酯等之脂肪酸酯；大豆油、亜麻仁油、菜仔油、葵花油等之植物油脂；以下式(2)所示之脂肪酸酯(C1)等，此等之稀釋劑係亦可僅以1種類來使用，亦可作2種以上併用。
前述脂肪酸酯(C1)，係藉由使碳原子數為6至12之碳酸與碳原子數為1至3之醇進行酯化反應所得者，前述碳酸及醇之碳鏈係為直鏈狀或為分枝狀均無妨。
作為前述脂肪酸酯(C1)，可列舉例如：己酸甲酯、
庚酸甲酯、辛酸甲酯、壬酸甲酯、癸酸甲酯、十二酸甲酯、己酸乙酯、庚酸乙酯、辛酸乙酯、壬酸乙酯、癸酸乙酯、十二酸乙酯、己酸丙酯、庚酸丙酯、辛酸丙酯、壬酸丙酯、癸酸丙酯、十二酸丙酯等。此等之脂肪酸酯係亦可單獨使用亦可作2種以上併用。又，此等之脂肪酸酯之中，又以己酸甲酯、癸酸甲酯、十二酸甲酯因臭氣較少而較佳。特別以十二酸甲酯因可謀求兼具印刷印墨用乾燥劑之黏度減少與臭氣之低減而較佳。
又，為作為更低黏度且處理性優越之硬化促進劑，前述脂肪酸錳鹽(A)、胺醇(B)之合計量，與前述稀釋劑(C)之以質量基準的摻合比[(A)+(B)]/(C)，較佳為10/90至95/5之範圍，更佳為40/60至80/20之範圍，更較佳為20/80至90/10之範圍。
本發明之塗料，特徵為含有本發明之塗料用乾燥劑與氧化聚合型不飽和樹脂。
作為前述氧化聚合型不飽和樹脂，可列舉例如：氧化聚合硬化型醇酸樹脂、氧化聚合硬化型胺甲酸酯樹脂、氧化聚合硬化型改質環氧樹脂等。
作為上述氧化聚合硬化型醇酸樹脂，可列舉以多元酸成分、多元醇成分及油脂肪酸作為主要原料成分之酯系樹脂。
作為上述多元酸成分，主要係使用例如：苯二甲酐、異苯二甲酸、對苯二甲酸、四氫苯二甲酐、六氫苯二甲酐、丁二酸、反丁烯二酸、己二酸、癸二酸、順丁烯二酸酐等之二元酸，及此等酸之低級烷基酯化物。更進
一步可應需求使用：偏苯三甲酐、甲基環己烯三碳酸、苯均四酸二酐等之3價以上之多元酸；磺基苯二甲酸、磺基異苯二甲酸及此等之銨鹽、鈉鹽或低級烷基酯化物等。又，作為酸成分，以調整分子量等之目的，可併用苯甲酸、丁烯酸、對第三丁基苯甲酸等之一元酸。
作為前述多元醇成分，可列舉例如：乙二醇、二乙二醇、丙二醇、1,4-丁二醇、新戊二醇、3-甲基戊二醇、1,4-己二醇、1,6-己二醇等之二價醇。更進一步可應需求併用：丙三醇、三羥甲基乙烷、三羥甲基丙烷、新戊四醇等之3價以上之多元醇；具有聚氧乙烯基之多元醇等。此等之多元醇係可單獨，或混合2種以上使用。又，前述酸成分、醇成分之一部分係可以二羥甲基丙酸、含氧基三甲基乙酸、對羥基苯甲酸等；此等之酸之低級烷基酯；ε-己內酯等之內酯類等之含氧基酸成分取代。
作為前述油脂肪酸，可列舉例如：椰子油脂肪酸、大豆油脂肪酸、亞麻仁油脂肪酸、葵花油脂肪酸、松油脂肪酸、脫水蓖麻油脂肪酸、桐油脂肪酸等。醇酸樹脂之油鎖長為5至80質量%，特別是20至70質量%之範圍內，係由所得之塗膜之硬化性、強韌性、厚重感等方面觀之為適合。
又，作為醇成分之一部分，亦可使用：使用環氧化合物之部分酯化環氧化合物之環氧改質醇酸樹脂；於醇酸樹脂中導入順丁烯二酸酐而形成之順丁烯二酸醇酸樹脂；順丁烯二酸醇酸樹脂與含羥基之醇酸樹脂加成而形成之接枝化醇酸樹脂；使醇酸樹脂與苯乙烯、(甲基)丙
烯酸酯等之丙烯基單體予以接枝聚合之丙烯基改質醇酸樹脂等。
再者，亦可使用：藉由利用自為了資源之再生所回收的聚對苯二甲酸乙二酯(例如PET瓶)、產業廢棄物之聚對苯二甲酸乙二酯、以對苯二甲酸為主原料之聚對苯二甲酸乙二酯或聚對苯二甲酸丁二酯等之聚酯製品(膜、繊維、汽車零件、電子零件等)的製造時所產生之屑等而再生之以對苯二甲酸為主原料的聚酯樹脂(以下簡稱「再生PES」)，在上述醇成分與多元酸成分之混合物中，使此再生PES溶解而解聚合之同時，使其進行酯化反應獲得醇酸樹脂，或使該醇酸樹脂與順丁烯二酸酐反應而獲得順丁烯二酸醇酸樹脂、使該醇酸樹脂與不含乙烯性不飽和基之酸酐反應而獲得改質醇酸樹脂等。
以上詳述之氧化聚合硬化型醇酸樹脂，由硬化性及塗膜物性為良好之觀點点觀之，較佳為加登納黏度(25℃)為15至60斯托克之物。
作為前述胺甲酸酯樹脂，雖未特別限定，惟係可使用例如：使聚醇、將油脂與多元醇轉酯化之聚醇、及聚異氰酸酯，反應而得之胺甲酸酯樹脂。
作為上述聚異氰酸酯，可列舉例如：1,4-四亞甲基二異氰酸酯、1,6-六亞甲基二異氰酸酯、2,2,4-三甲基六亞甲基二異氰酸酯、2,8-二異氰酸甲基己酸酯等之脂肪族異氰酸酯類；3-異氰酸甲酯-3,5,5-三甲基環己基異氰酸酯、甲基環己基-2,4-二異氰酸酯等之脂環族二異氰酸酯類；二異氰酸甲苯酯、二異氰酸二苯甲烷、1,5-二異
氰酸萘酯、二異氰酸二苯甲基甲烷、二異氰酸四烷基二苯甲烷、4,4-二異氰酸二苯乙烷、1,3-二異氰酸苯酯等之芳香族二異氰酸酯類；氯化二異氰酸酯類、溴化二異氰酸酯類等，可以單獨或2種以上之混合物來使用此等。
作為前述聚醇，可列舉一般係使用於胺甲酸酯樹脂之製造的各種聚醇，例如：二乙二醇、丁二醇、己二醇、新戊二醇、雙酚A、環己烷二甲醇、三羥甲基丙烷、丙三醇、新戊四醇、聚乙二醇、聚丙二醇、聚酯聚醇、聚己內酯、聚四亞甲基醚二醇、聚硫醚聚醇、聚縮醛聚醇、聚丁二烯聚醇、呋喃二甲醇等，可以單獨或2種以上之混合物來使用此等。
作為將前述油脂與多元醇酯化之聚醇，可列舉例如：將碘價為7至200之油脂與三羥甲基丙烷、新戊四醇等之多元醇酯化之物，亦可使用例如三井化學股份有限公司製「XP1076E」、「XP1077E」、「XP1580E」、「FB20-50XB」等之市售品。
作為前述氧化聚合硬化型改質環氧樹脂，可列舉例如：將環氧樹脂、不飽和脂肪酸成分與含酸基之丙烯酸成分作為原料，藉由使此等反應而得之樹脂。樹脂原料之摻合，若相對於原料之合計重量100重量%，係環氧樹脂為30至50重量%、不飽和脂肪酸成分為25至40重量%及含酸基之丙烯酸成分為10至45重量%，則由硬化塗膜之物性優越之觀點觀之為較佳。
又，氧化聚合硬化型改質環氧樹脂之碘價，由可獲得良好之硬化性之觀點觀之，較佳為30至100，特佳為35
至90。
作為可使用作為原料之環氧樹脂，雖未特別限定，惟由改質容易且所得之硬化塗膜之性能優越之觀點觀之，較佳為雙酚A型環氧樹脂、氫化雙酚A型環氧樹脂、雙酚F型環氧樹脂等之雙酚型環氧樹脂。此等係亦可以單獨使用或亦可併用2種以上。
作為不飽和脂肪酸成分，係可使用天然或合成系之不飽和脂肪酸之任意者，例如可使用自桐油、亞麻仁油、蓖麻油、脫水蓖麻油、葵花油、松油、大豆油、椰子油所得之不飽和脂肪酸等。
又，作為酸基含有丙烯酸成分，可使用例如：(甲基)丙烯酸，與苯乙烯或(甲基)丙烯酸酯類等之不含酸基的丙烯酸單體之混合物等。作為後者之不含酸基之的烯酸單體，由可獲得優越之塗膜硬度之觀點觀之，較佳為苯乙烯。
氧化聚合硬化型改質環氧樹脂，係可依下述而得。首先自環氧樹脂與不飽和脂肪酸成分製造環氧酯樹脂。例如：藉由將環氧樹脂與不飽和脂肪酸成分於甲苯、二甲苯等之適當的溶劑中，使用縮合觸媒，並應需求於氮氣等之不活性氣體氛圍下，以150至250℃反應至成為期望之酸價而以獲得環氧酯樹脂。作為縮合觸媒，係可使用例如：二丁基錫氧化物、四正丁基銨溴化物等。
其次，將所得之環氧酯樹脂與前述含酸基之丙烯酸成分反應，而獲得氧化聚合硬化型改質環氧樹脂。環氧酯樹脂與酸基含有丙烯酸成分之反應，係可於聚合起始
劑存在下，於氮氣等之不活性氣體氛圍下，以80至150℃之溫度範圍進行。作為聚合起始劑，係可使用過氧化物、偶氮化合物等之各種之物，例如：能夠以相對於所使用之單體合計量的0.1至20質量份%之比例，使用Kayaku Akzo製「Kayabutyk B(烷基過氧酯系)」等。
以上詳述之氧化聚合型不飽和樹脂之中，在本發明特別又由便宜且取得容易，又，塗料之乾燥性(實用性)優越之觀點觀之，較佳為氧化聚合硬化型醇酸樹脂。
本發明之塗料，較佳為更進一步，含有有機溶劑。於此作為可使用之有機溶劑，可列舉例如：前述烴系溶劑、醇系溶劑、酮系溶劑、醚系溶劑。
本發明之塗料，係除上述之各成分以外，更進一步可應需求含有著色劑、稀釋劑、顏料分散劑、表面調整劑、紫外線吸收劑、消泡劑、增黏劑、沉降防止劑等之各種塗料用添加劑。
作為前述著色劑，可列舉碳黑、酞花青顏料、紅氧化鐵、偶氮顏料、煃吖啶酮顏料等。再者，作為稀釋劑，可列舉例如：甲苯、二甲苯、庚烷、己烷、礦油精等之烴系溶劑；甲醇、乙醇、丙醇、環己醇等之醇系溶劑；甲基乙基酮、甲基異丁基酮、環己酮等之酮系溶劑；丙醚、甲基賽路蘇、賽路蘇、丁基賽路蘇、甲基卡必醇等之醚系溶劑；己酸甲酯、癸酸甲酯、十二酸甲酯等之脂肪酸酯；大豆油、亜麻仁油、菜仔油、葵花油等之植物油脂等。
相對於前述塗料之本發明之乾燥劑之摻合量，未特
別限定，惟相對於氧化聚合型不飽和樹脂100質量份，較佳為使乾燥劑中之金屬成分之合計質量成為如0.005至1.5質量份之範圍。
以上詳述之本發明之塗料，係可藉由以常法於被塗物上塗布、乾燥及硬化而獲得塗膜。於此，作為可塗布本發明之塗料之基材(被塗物)可列舉例如鋼鐵等。又，作為塗布後之乾燥條件(硬化條件)，可列舉自然乾燥。
再者，因本發明之塗料係即便將塗膜變厚亦可展現優越之硬化性，於作為厚塗用塗料係尤其有用，具體而言，可使硬化塗膜之膜厚為1至500μm之範圍。因此，本發明之塗料於作為建築用塗料係有用。
以第1表所示之比例(質量份)摻合脂肪酸錳鹽(A)、胺醇(B)及稀釋劑(C)，製得塗料用乾燥劑1至5。
將環烷酸鈷12份及辛酸鋯38份溶解於礦油精50份，製得比較對照用塗料用乾燥劑1’。此乾燥劑係以呈現含鈷金屬皂之先前技術之金屬皂的平均水準之性能為目的而作成之物。
將環烷酸錳56份及2，2’-聯吡啶18份溶解於礦油精26份，製得比較對照用塗料用乾燥劑2’。
於將鈦白顏料(TAYCA股份有限公司製「JR-701」)1960g、塗料用樹脂「BECKOSOL P-470-70」(DIC股份有限公司製之於分子內具有氧化聚合型不飽和脂肪酸基之醇酸系樹脂)3340g、礦油精280g、結皮防止劑(甲基乙基酮肟)20g以三滾輪予以混輾而製得之混合物40g中，添加塗料用乾燥劑1，使相對於樹脂不揮發部分100份之錳金屬部分之比例成為如0.06%而配製本發明之塗料1。塗料1之乾燥測試、所得之塗膜之光澤度及重塗之測試係以下述方法進行。評價結果係如第2表所示。
將塗料使用3密耳之塗抹器塗布於玻璃板上後，利用乾燥時間記錄器(太佑機材股份有限公司製「型號No.404」)進行測試。測定係於恆溫恆濕室(25℃、50%RH)內進行。尚，將在玻璃板上塗布塗料後，藉由乾燥時間記錄器之針，由塗料開始乾燥而可觀察到之傷痕因塗料完全乾燥而無法觀察為止之時間作為塗料之乾燥時間。
於玻璃板上使用塗抹器塗上乾燥膜厚為152μm之塗膜，於溫度25度、濕度50%下乾燥7日後，依JIS K5600中之60°、20°鏡面光澤度測試之基準進行測試。
於玻璃板上使用塗抹器塗上152μm之塗膜，於溫度25度、濕度50%下之一定時間(4小時後、8小時後、1日後、2日後及3日後)後再使用塗抹器重塗152μm之塗膜，於溫度25度、濕度50%下，在塗重後乾燥7日後，以肉眼觀察塗膜表面之狀態。
◎：無異常
○：雖於塗面產生皺褶，惟在塗面並未產生縮褶。
×：於塗面產生皺褶之同時，在塗面亦產生縮褶。
除了使用第2表所示塗料用乾燥劑以外，與實施例6同樣地製得塗料2至5。與實施例6同樣地進行塗料之評價，將其結果示於第2表。
除了將使用塗料用乾燥劑1取代為添加比較對照用塗料用乾燥劑1’使相對於樹脂不揮發部分100份之鈷金屬部分的比例係成為如0.06%以外，與實施例6同樣地製得比較對照用塗料1’。與實施例6同樣地測定乾燥時間，將其結果示於第3表。
除了將使用塗料用乾燥劑1取代為添加比較對照用塗料用乾燥劑2’使相對於樹脂不揮發部分100份之錳金屬部分的比例係成為如0.06%以外，與實施例6同樣地製得比較對照用塗料2’。與實施例6同樣地測定乾燥時間，將其結果示於第3表。
Claims (4)
- 一種塗料用乾燥劑，其特徵為含有脂肪酸錳鹽(A)及以下述通式(1)所示之胺醇(B)，
- 如申請專利範圍第1項之塗料用乾燥劑，其中該胺醇(B)係選自包含2-[(2-二甲基胺乙基)甲基胺基]乙醇、2-(2-胺乙基)胺乙醇、1-(2-胺乙基)胺基-2-丙醇、2-(3-胺丙基胺基)乙醇及2-(2-二甲基胺乙氧基)乙醇之群組的至少1種。
- 如申請專利範圍第1或2項之塗料用乾燥劑，其中該脂肪酸錳鹽(A)之脂肪酸，係選自包含辛酸、新癸酸、異壬酸及環烷酸之群組的至少1種之脂肪酸。
- 一種塗料，其特徵為含有如申請專利範圍第1至3項中任一項之塗料用乾燥劑。
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| JP7183461B1 (ja) | 2022-03-15 | 2022-12-05 | 中国塗料株式会社 | 変性（メタ）アクリル樹脂系塗料組成物、積層塗膜、塗膜付き基材およびその製造方法 |
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