TW201124081A - Harmful organism-controlling composition and control method of harmful organisms - Google Patents
Harmful organism-controlling composition and control method of harmful organisms Download PDFInfo
- Publication number
- TW201124081A TW201124081A TW99136902A TW99136902A TW201124081A TW 201124081 A TW201124081 A TW 201124081A TW 99136902 A TW99136902 A TW 99136902A TW 99136902 A TW99136902 A TW 99136902A TW 201124081 A TW201124081 A TW 201124081A
- Authority
- TW
- Taiwan
- Prior art keywords
- present
- ester compound
- parts
- formula
- ester
- Prior art date
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
201124081 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種病蟲害防治組成物及病蟲害之防 治方法。 【先前技術】 式（I)表示之酯化合物：201124081 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a pest control composition and a method for controlling pests and diseases. [Prior Art] The ester compound represented by the formula (I):
(I) 為習知病蟲害防治製劑之有效成分（例如參見JP 57-123146A 及 CN 101306997A)。 另外，式（II)表示之酯化合物：(I) is an active ingredient of a conventional pest control preparation (see, for example, JP 57-123146A and CN 101306997A). Further, the ester compound represented by the formula (II):
亦為習知病蟲害防治製劑之有效成分（例如參見“ Zoku Iyakuhin no Kaihatsu, vol. 18, Noyaku no Kaihatsu 111 (The Second Series of Pharmaceutical Research andIt is also an active ingredient of conventional pest control preparations (see, for example, "Zoku Iyakuhin no Kaihatsu, vol. 18, Noyaku no Kaihatsu 111 (The Second Series of Pharmaceutical Research and
Development, vol. 18, Management and Development of Agrochemicals III)” , Hirokawa Publishing Company, 1993， p· 493-514)。 4 322445 201124081 然而，在某些情況中，依特定應用及所欲防治之病害 蟲而疋’對該已知製劑而言，仍需要具有較高㈣效果之 病蟲害防治製劑。 【發明内容】 發明所欲解決之問題 本發明之目的係提供一種對病蟲害具有優異防治效果 之病蟲害防治組成物及防治方法。 解決問題之方法 由於本案發明人致力研究，發現組合使用式（1)表示 之酯化合物及式（II)表示之酯化合物對病蟲害呈現優異防 治效果。據此，完成本發明。 因此’本發明提供：Development, vol. 18, Management and Development of Agrochemicals III)", Hirokawa Publishing Company, 1993, p. 493-514). 4 322445 201124081 However, in some cases, depending on the particular application and the pest to be controlled对该 'In view of the known preparations, there is still a need for a pest control preparation having a higher (four) effect. [Disclosure] Problems to be Solved by the Invention An object of the present invention is to provide a pest control composition having excellent control effects against pests and diseases. The present invention has been found to provide an excellent control effect on pests and diseases by using the ester compound represented by the formula (1) and the ester compound represented by the formula (II) in combination with the present invention. Thus, the present invention has been completed. 'The invention provides:
(1) 一種病蟲害防治組成物，包括式（丨）表示之酯化合物： ' F h3coh2c-~/~\(1) A pest control composition comprising an ester compound represented by the formula (丨): ' F h3coh2c-~/~\
F F (後文中稱為本發明酯化合物A)及式（n)表示之酯化合物 之組合：A combination of F F (hereinafter referred to as the ester compound A of the present invention) and an ester compound represented by the formula (n):
322445 201124081 (後文中稱為本發明酯化合物B)作為有效成分； (2) 根據上述第（1)項之病蟲害防治組成物（後文中稱為 本發明防治組成物），其中，該本發明酯化合物A與 該本發明g旨化合物B之重量比在5 0 : 1至1 : 5 0之範 圍。 (3) —種病蟲害之防治方法，包括對病蟲或病蟲棲息處施 用有效量之本發明酯化合物A及本發明酯化合物B之 組合；以及 (4) 一種本發明酯化合物A及本發明酯化合物B之組合以 防治病蟲害之用途。 本發明之效果 本發明防治組成物及防治方法對病蟲害呈現優異防治 效果。. 【實施方式】 本發明防治組成物之特徵在於包含本發明酯化合物A 及本發明醋化合物B兩者。 本發明酯化合物A例如可經由JP 57-123146A中所述 方法予以製備。 本發明酯化合物B例如可經由JP 49-054529A中所述 方法予以製備。 本發明酯化合物A及本發明酯化合物B基於在其環丙 烷環之兩個不對稱碳原子而各自具有異構物。在本發明中， 可以任何比例使用含有活性異構物之酯化合物。 本發明防治組成物對其顯示有防治效果的病蟲害之 6 322445 201124081 - 本發明酯化合物A及本發明酯化合物B基於在其環丙 -烷環之兩個不對稱碳原子而各自具有異構物。在本發明中， 可以任何比例使用含有活性異構物之酯化合物。 本發明防治組成物對其顯示有防治效果的病蟲害之 實例包含有害節肢動物例如昆蟲病蟲害及蜱蟎類（a c a『丨n e ) 病蟲害。其具體實例係如下列者。 鱗翅目（Lepidoptera)昆蟲病蟲害： 螟蛾（螟蛾科（Pyralidae))例如稻條螟（rice stem borer)(二化螟蛾、稻縱捲葉蟲 (rice leafroller)(稻縱捲葉野螟蛾（C/?即加 、及印度粉堪（Indian meal moth)(印度榖粉 螟蛾（/7<^/3//7^/7?£//7(^以//3));夜蛾（(^161：111〇1±)(夜蛾 科（Noctuidae))例如普通夜盜蟲（斜紋夜蛾而〆era hii/ra))、甜菜行軍蟲（beet armyworm)(甜菜葉蛾 (ex/gi/a))、稻行軍蟲（東方黏蟲（Psewc/a/ei/a separate))、及甘藍行軍螽（甘藍夜蛾（ga/ffestra Arass/cae));紋白蝶（粉蝶科（Pieridae))例如普通菜粉蝶 (紋白蝶（/VeWs /*即狀））；捲蛾（捲蛾科（Tortricidae))例 如姬捲葉蛾屬spp.);果蛾（fruitworm moth) (果姓蛾科（Carposinidae));潛蛾（潛蛾科（Lyonetiidae)); 毒蛾（毒蛾科（Lymantriidae));金翅夜蛾亞科（Plusiae); 地老虎屬（如roί/s spp.)例如地老虎（黄地老虎（如τοi/s 及小地老虎（小地老虎（处/Oi/s /psy/o/?));葉 蛾屬（Helicoverpa spp.);棉鈴蟲屬（Heliothis spp.); 7 322445 201124081 鑽石背蛾（小菜蛾（/VWe/Yazyyos^e/ya));直紋稻弄蝶（單 帶弄蝶（/¾獻ra ;製袋衣蛾（casemaking clothes moth)(衣蛾（77/?ea ;以及織網衣蛾（webbing clothes moth)(衣蛾（77此〇/3 Ws\se"/e//a))。 雙翅目（Diptera)昆蟲病蟲害： 蚊（蚊科（Calicidae))例如普遍蚊子（淡色庫蚊（心/狀 pipienspallens)、三斑家故{Culex tritaeniorhynchus)、 反南方家故{致务薄故{Culex quinquefasciatus)、.，後故風 (dei/es· spp.)例如黃熱蚊（埃及斑蚊（Jei/e·? aewpi/)、及亞 洲虎蚊（白線斑域XAedes aJbojn’ctus);按蚊屬（AnopheJes spp·)例如中華癔蚊（如即加/於;搖蚊（midges) (搖蚊科（Chironomidae));家繩（家蠅科（Muscidae))例如家 ^XmXMusca domesticaT)、黑、mXMusca bezzi)、敗職 小家廁繩（lesser housefly)(黃腹廄蠅（/a/7/?/a ;麗繩（麗繩科（Calliphordiae));麻繩（麻 蠅科（Sarcophag i dae ));花蠅（花繩科（Anthomy i i dae))例如 種繩（seedcornmaggot)(灰地種蠅、及蔥 蠅（onion maggot)(蔥蠅（刀;黑色清道夫蠅 (black scavenger flies)(黑题科（Sepidae));果蠅（果實 蠅科（Tephritidae);潛繩（潛繩科（Agromyzidae));小果题 (果蠅科（Drosophi lidae))例如普遍果蠅（野生果繩 (A/osojd/?27a ;蛾蚋（moth flies)(蛾蚋科 (Psychodidae));蚤繩（蚤繩科（Phoridae))例如蚤繩 8 322445 201124081 - (humpbacked fly)(東亞異蚤蠅（#e抑sa7ia - ;蚋（black flies)(蚋科（Simuliidae)); 馬繩（it科（Tabanidae));穩繩（整绳科（Stomoxyidae));以 及吸血小黑蚊（biting midges)(蠓科（Ceratopogonidae))。 網翅目（Dictyoptera)昆蟲病蟲害： 蟑螂（蜚蠊目（6181^81*丨86))例如德國蟑螂（德國蜚蠊 (及、煙褐蟑螂（黑胸大蠊 (Periplaneta fuliginosa))> {Periplaneta americana)) ' iPeriplaneta brwmea))、反東方緣辦l策方螌綠IBlatta oriental is)、。 膜翅目（Hymenoptera)昆蟲病蟲害： 蟻（犧科（Formicidae));馬蜂（胡蜂科（Vespidae)); 腫腿蜂（腫腿蜂科（Bethylidae));以及葉蜂（葉蜂科 ((Tenthredinidae))例如甘藍葉蜂（黃翅菜葉蜂 rosae)。 隱翅目（Aphaniptera)昆蟲病蟲害： 犬蚤（犬蚤canis))、貓蚤（貓蚤 {Ctenocephalides felis、）、认反 k§：{k§：(^Purex irritans'))。 蝨目（Anoplura)昆蟲病蟲害： 人蝨（人级（Pediculus humns))、毛鉍（陰赵 iPhthirus pubis、）、琢頭兹iPediculus humans capitisT)、认反k龍备ikl^XPediculus humanus 9 322445 201124081 corporis、）。 等翅目（I soptera)昆蟲病蟲害： 曰本散白蠘（Japanese subterranean termite)(黃胸 散白蟻（无e iyy spera )、以及台灣乳白蟻 (Formosan subterranean termite)(臺灣家白蟻 iCoptotermes formosamisy)。 半翅目（Hemiptera)昆蟲病蟲害： 飛蝨（飛蝨科（De 1 phac i dae ))例如小褐飛蝨（sma 11 brown planthopper)(^£ (Zaoi/eip/zaz striate!Jus))^ 褐稻飛蝨（褐飛蝨（W/aparraia )、及白背稻飛蝨 (白背飛蝨（5bg<3 ie/7a /£/rc//era));葉禪（1 eaf hopper)(浮 塵子科（Del tocephal idae))例如青稻葉蟬（黑尾葉蟬 iNephotettix cincticeps))、反台灣黃蹈葉蹲{二點 H 葉 蟬FiVesce/?·?));财蟲（财科（Aphididae)); 臭蟲（椿科（Pentatomidae));粉蝨（粉蝨科（Aleyrodidae)); 介殼蟲（軟介殼蟲科（Coccidae));臭蟲（cimices)例如（溫 帶臭蟲;軍配蟲（軍配蟲科 (Tingidae));以及木蝨（木蝨科（Psyliidae))。 鞘翅目（Coleoptera)昆蟲病蟲害： 玉米食根蟲（corn root worms)(葉甲屬 spp.))例如黑皮蠹（black carpet beetle)(姬鰹節蟲 (d i )、姬圓鰹節蟲（var i ed carpet beet 1 e)(小圓花皮蠹（如iArews·把rZ?a*sc/))、西部玉米食根 10 322445 201124081 J 方玉米食根蟲（十一星瓜葉甲（Diabrotica - undecimpunctata howardi));金龜子（金龜子科 (Scarabaeidae))例如綠金龜（cupreous chafer)(金銅金龜 (如〇财/3 a/jor從））、及大豆曱蟲（soybeans beetle)(榛姬 金亀Unomaia rufocuprea)) ·，象鼻螽（象鼻螽科 (Curculionidae))例如玉米象（maize weevil)(玉米象 (iSVipp/zWiAS從出肪/s))、稻水象甲（rice water weevi 1)(稻 水象甲 U/ssor/iopi/TAS 、棉鈐象曱（boll weev il)(棉鈴象曱（J/7 肌as s))、及綠豆象曱 (azuki bean weev i 1)(綠豆象（Ca/ c/zhe/Ls/s));擬步甲（darkling beetles)(擬步甲科 (Tenebrionidae))例如黃粉蟲（yel low mealworm)(黃粉蟲 ((7^/747*/〇肌》"如7·))、及赤擬榖盜（red flour beetle)(赤 疑数盜（TriboHum castaneu/π));金花&(金花螽料 (Chrysome 1 idae))例如稻泥蟲（稻負泥蟲（oryzae))、 黃條葉蚤（striped flea beetle)(黃條葉蚤（Phyllotreta striolata))、及黃守瓜（cucurbit leaf beetle)(黃守瓜 (如/acop/zara/e/z7ara7i’>s));穀斑皮橐（drugstore beetle) (竊蠢科（Anobiidae));食植瓢蟲屬（Epilachna spp.)例如 茄二十八星瓢蟲（twenty-eight-spotted ladybird)(茄二 十八瓢AiEpilachna vigintioctopunctata)).，输蠢& (powder post beetles)(粉蠹亞科（Lyctinae));偽粉蠹 (false powder post beetles)(長蠹蟲科（Bostrichidae)); 天牛（longhorn beetles)(天牛科（Cerambycidae));以及隱 11 322445 201124081 翅蟲（rove beetle)(蟻型隱翅蟲（Z^ei/e/7/s· /i/scipes))。 缪翅目（Thysanoptera)昆蟲病蟲害： 瓜薊馬（Melon thrips)(南黃薊馬 柑橘黃薊馬（yellow citrus thrips)(西方花薊馬 、以及花薊馬（黑腹薊馬 {Frankliniella intonsa)、。 直翅目（Orthoptera)昆轰病蟲害： 螻姑（埃姑科（Gryllotalpidae))、以及壇蟲（幢科 (Acrididae))。 碑瞒目（Acarina): 家居塵蜗（塵蜗科（Pyroglyphidae))例如美洲塵蜗 (Dermatophagoides farinae)、反歡洲塍織 iDermatophagoides ptrenyssnus) ·，输織{紛織科 (Acaridae))例如霉蜗（mold mite)(腐食赂蜗（yy/Op/i祕ί/5 iiae))、及橢圓斑白蟎（hs); 蜱蟎（G1 ycyphagid mi tes)例如食甜蟎（ privatus)、家 it 韵織（Glycyphagus domesticus) ' A 害今 鱗蟎（i/es ί/τ/c a〇r);肉食蟎（肉食蟎科 (Cheyletidae))例如馬六甲肉食蟎 /nalaccensis)、反肉食蟎（Cheyletus fortis) ·，細蛾 (Tarosonemid mites)(細蟎科（Tarsonemidae));嗜渣蟎 (Chortoglyphid mites)(嗜渣科（Chortoglyphidae));禽 刺蟎（Haplochthoniid mites)(禽刺蟎科 (Haplochthoniidae));葉蟎（葉蟎科（Tetranychidae))例 12 322445 201124081 ^ 如二點葉蜗（二斑葉蜗（7^ira/7_Kc/?£/s· w/·ί/cae))、神澤葉蜗 . (Kanzawa spider mite)(神澤葉瞒 如72Zaira/))、柑桔紅：fe知蛛（掛桔全爪蜗（/b/7077/i7/7iAS c/iW))、及歐洲紅蜗（European red mite)(榆全爪蜗 (Panonychus ulmi));碑（硬蜱科（Ixodidae))例如長角金 缉iHaemaphysalis longicornis) ’，认反擬寄 i 織 (parasitoid mites)(皮刺蜗科（Dermanyssidae))例如北 方禽蜗（northern fow 1 mi te)(禽刺蜗（<9/77i· s/k/a/T//»))、及禽紅蜗（poultry red mite)(雞皮刺蜗 {Dermanyssus galHnae、、。 特別地，本發明防治組成物對雙翅目昆蟲病蟲害呈現 優異的防治效果，且對蚊（蚊科）呈現更優異的防治效果。 在本發明防治組成物中，只要維持本發明之優異防治 效果，該本發明酯化合物A與該本發明酯化合物B之重量 比無具體限制。通常，該重量比在50 : 1至1 : 50之範圍， 較佳在10 : 1至1 : 10之範圍。 本發明防治組成物可為本發明酯化合物A與本發明酯 化合物B之單純混合物。然而，通常其係以多種調配物之 形式使用。該調配物之實例包含油性溶液、可乳化濃縮物、 可濕性粉末、懸浮濃縮物（例如水懸浮液及水性乳液）、微 膠囊調配物、粉劑、粒劑、錠劑、氣霧劑、二氧化碳調配 物、熱散發式（heating vaporization)調配物（例如防蚊卷 (mosquito coil)、電蚊片（electric mosquito mat)、及 液體吸收芯型殺蟲劑（fluid absorption wicking-type 13 322445 201124081 pesticide)、壓電型喷散殺蟲劑、熱燻蒸劑（heating fumigant)(例如自燃型燻蒸劑、化學反應型燻蒸劑、及多 孔陶瓷板燻蒸劑）、非熱式燻蒸劑（例如樹脂燻蒸劑、紙製 燻蒸劑、不織布燻蒸劑、織物燻蒸劑、及昇華鍵 (sublimation tablet))、喷霧調配物（例如煙霧劑）、直接 接觸型調配物（例如片狀型接觸式調配物、條狀型接觸式調 配物及網狀型接觸式調配物）、ULV調配物及毒舞。 舉例而言，可經由下列方法製備調配物。 (1) 將本發明酯化合物A及本發明酯化合物B與固體 載劑、液體載劑、氣體載劑或飼料混合，若有需要，加入 用於調配物之其他辅助劑例如界面活性劑。322445 201124081 (hereinafter referred to as the ester compound B of the present invention) as an active ingredient; (2) a pest control composition according to the above item (1) (hereinafter referred to as a control composition of the present invention), wherein the ester of the present invention The weight ratio of the compound A to the compound B of the present invention is in the range of from 50:1 to 1:50. (3) A method for controlling pests and diseases, comprising administering an effective amount of a combination of the ester compound A of the present invention and the ester compound B of the present invention to a pest or a pest infestation; and (4) an ester compound A of the present invention and the present invention The combination of ester compound B for the purpose of controlling pests and diseases. EFFECT OF THE INVENTION The control composition and the control method of the present invention exhibit excellent control effects on pests and diseases. [Embodiment] The control composition of the present invention is characterized by comprising both the ester compound A of the present invention and the vinegar compound B of the present invention. The ester compound A of the present invention can be produced, for example, by the method described in JP 57-123146A. The ester compound B of the present invention can be produced, for example, by the method described in JP 49-054529A. The ester compound A of the present invention and the ester compound B of the present invention each have an isomer based on two asymmetric carbon atoms of the cyclopropane ring. In the present invention, an ester compound containing an active isomer can be used in any ratio. The pest control of the present invention for controlling the composition thereof has a control effect 6 322445 201124081 - the ester compound A of the present invention and the ester compound B of the present invention are each based on two asymmetric carbon atoms of a cyclopropane ring thereof and each has an isomer . In the present invention, an ester compound containing an active isomer can be used in any ratio. Examples of pests and diseases in which the control composition of the present invention exhibits a control effect include harmful arthropods such as insect pests and mites (a c a "丨n e" pests and diseases. Specific examples thereof are as follows. Lepidoptera insect pests: 螟 moth (Pyralidae) such as rice stem borer (rice larvae, rice leafroller (rice leaf curler) (C/? Plus, and Indian meal moth (Indian meal moth (/7<^/3//7^/7?£//7(^//3)); night Moth ((^161:111〇1±) (Noctuidae) such as the common night larvae (Striata genus and 〆era hii/ra)), beet armyworm (beet army moth) /gi/a)), rice armyworm (Psewc/a/ei/a separate), and cabbage march (ga/ffestra Arass/cae); white butterfly (Pieridae) )) For example, the common cabbage butterfly (Wecome butterfly (/VeWs /*)); the moth (Tortricidae) such as the genus Spodoptera; the fruitworm moth (Carposinidae) ); the moth (Lyonetiidae); the poisonous moth (Lymantriidae); the golden-winged genus (Addiae); the genus genus (such as roί/s spp.) such as the tiger (the yellow tiger) (eg τοi/s and small tigers (small tigers) / at /Oi/s /p Sy/o/?)); Helicoverpa spp.; Heliothis spp.; 7 322445 201124081 Diamondback moth (/VWe/Yazyyos^e/ya); Butterfly (single-banded butterfly (/3⁄4 offering ra; casemaking clothes moth) (cloth moth (77/?ea; and webbing clothes moth) (cloth moth (77 this 〇 / 3 Ws\se"/e//a)) Diptera insect pests: Mosquitoes (Calicidae) such as common mosquitoes (Culex pipiens), Culex tritaeniorhynchus ), anti-Southern family, {Cuilex quinquefasciatus), ., then the wind (dei/es· spp.) such as yellow-hot mosquito (Egypt mosquito (Jei/e·? aewpi/), and Asian tiger Mosquito (XAedes aJbojn'ctus); Anophejes spp., such as the Chinese cockroach (such as jiajima; midges (Chironomidae); family rope (Muscaidae) (Muscidae)) such as home ^XmXMusca domesticaT), black, mXMusca bezzi), lesser housefly (yellow belly fly (/a/7/?/a; Lili (Calliphordiae) )); hemp rope Sarcophag i dae )); flower fly (Anthomy ii dae) such as seed rope (seedcornmaggot) (gray flies, and onion maggot (onion maggot) (knife; black scavenger (black scavenger) Flies) (Sepidae); fruit fly (Tephritidae; submarine (Agromyzidae); small fruit (Drosophi lidae) such as the general fruit fly (wild Fruit rope (A/osojd/?27a; moth flies (Psychodidae); reins (Phoridae) such as reins 8 322445 201124081 - (humpbacked fly) Fly (#e suppression sa7ia - ; black flies (Simuliidae); horse rope (it) (Tabanidae); steady rope (Stomoxyidae); and blood-sucking black mosquito (biting midges) ) (Ceratopogonidae). Dictyoptera insect pests and diseases: 蟑螂 (蜚蠊目(6181^81*丨86)), for example, German 蟑螂 (蜚蠊, 烟, eri, P (Periplaneta fuliginosa)> {Periplaneta Americana)) 'iPeriplaneta brwmea)), anti-Eastern edge, IBlatta oriental is). Hymenoptera insect pests and diseases: ants (Formicidae); wasps (Vespidae); swollen bee (Bethylidae); and leaf bee (Tenthredinidae) )) For example, Cabbage leaf bee (Aphididae rosae). Aphaniptera insect pests: canine (canis) (canis), cat ticks (Ctenocephalides felis), confession k§: { K§:(^Purex irritans')). Anoplura insect pests: human cockroach (Pediculus humns), cockroach (iPhthirus pubis), P头兹iPediculus humans capitisT), 反反k龙备ikl^XPediculus humanus 9 322445 201124081 corporis ,). Isoptera insect pests and diseases: Japanese subterranean termite (Yellow chest white termite (no e iyy spera), and Formosan subterranean termite (iCoptotermes formosamisy). Hemiptera insect pests: De phac i dae, such as sma 11 brown planthopper (Zaoi/eip/zaz striate! Jus) ^ brown rice planthopper (W/aparraia, and white-backed rice planthopper (White-backed planthopper (5bg<3 ie/7a /£/rc//era)); 1 eaf hopper (Del tocephalidae) )) For example, the green rice leafhopper (INephotettix cincticeps), the anti-Taiwan yellow leafhopper (2 points H leaf 蝉FiVesce/?·?)); the worm (Aphididae); bed bug (Aphididae) (Pentatomidae)); whitefly (Aleyrodidae); scale insect (Coccidae); cimices such as (temperate bed bug; army worm (Tingidae); and wood Sy (Psyliidae). Coleoptera insect pest: corn root worm (corn root worm) s) (Lepidoptera spp.)) For example, black carpet beetle (di 鲣 鲣 ( di var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var var Put rZ?a*sc/)), western corn root 10 322445 201124081 J square corn rootworm (Diabrotica - undecimpunctata howardi); chafer (Scarabaeidae) (such as green turtle) Cupreous chafer) (Golden copper tortoise (such as 〇财/3 a/jor)), and soybean locust (soybeans beetle) (榛oma金亀Unomaia rufocuprea)), 象 螽 (Curculionidae) Maize weevil (corn elephant (iSVipp/zWiAS from fat/s)), rice water weevi 1 (rice water weevil U/ssor/iopi/TAS, cotton aphid elephant (boll) Weev il) (cotton bell icon (J/7 muscle as s)), and mung bean symbol (azuki bean weev i 1) (mung bean elephant (Ca/ c/zhe/Ls/s)); ) (Tenebrionidae) such as yel low mealworm (tenmus ((7^/747*/〇肌)" as 7)), and red flour Beetle) (TriboHum castaneu) /π)); Golden Flower & (Chrysome 1 idae) such as rice worm (oryzae), striped flea beetle (Phyllotreta) Striolata)), and cucurbit leaf beetle (黄守瓜 (eg /acop/zara/e/z7ara7i'>s)); drugstore beetle (Anobiidae) Epilachna spp., such as twenty-eight-spotted ladybird (AiEpilachna vigintioctopunctata)., powder post beetles (powder post beetles) Lyctinae; false powder post beetles (Bostrichidae); longhorn beetles (Cerambycidae); and hidden 11 322445 201124081 Beetle) (Z. ei/e/7/s· /i/scipes). Thysanoptera insect pests and diseases: Melon thrips (yellow citrus thrips) (Western flower scorpion horse, and flower scorpion horse (Frankliniella intonsa), Orthoptera Kunming pests and diseases: Aunt (Gryllotalpidae) and algae (Acrididae). Acarina: Home dust worm (Pyroglyphidae) For example, Dermatophagoides farinae, iDermatophagoides ptrenyssnus, · Acaridae, such as mold mite (yy/Op/i secret ί/ 5 iiae)), and elliptic leukoplakia (hs); 蜱螨 (G1 ycyphagid mi tes) such as privatus, Glycyphagus domesticus ' A es 螨 螨 (i/es ί/τ /ca〇r); carnivorous carp (Cheyletidae) such as Malacca carcass / nalaccensis, Cheyletus fortis, Tarosonemid mites (Tarsonemidae); Chortoglyphid mites (Chortoglyphidae); avian hedgehog (Haploch) Thoniid mites) (Haplochthoniidae); leaf mites (Tetranychidae) example 12 322445 201124081 ^ Like two-point leaf worm (two variegated snails (7^ira/7_Kc/?£/s· w/· ί/cae)), 泽泽叶蜗. (Kanzawa spider mite) (神泽叶瞒如72Zaira/)), citrus red: fe known spider (hanging orange full claw worm (/b/7077/i7 /7iAS c/iW)), and the European red mite (Panonychus ulmi); the monument (Ixodidae) such as the long-horned golden dragonfly iHaemaphysalis longicornis) Send parasitoid mites (Dermanyssidae) such as northern fow 1 mi te (<9/77i·s/k/a/T//») And poultry red mite (Dermanyssus galHnae, ,. In particular, the control composition of the present invention exhibits an excellent control effect against dipteran insect pests and diseases, and exhibits superior control effects against mosquitoes (mosquitoes). In the control composition of the present invention, the weight ratio of the ester compound A of the present invention to the ester compound B of the present invention is not particularly limited as long as the excellent control effect of the present invention is maintained. Usually, the weight ratio is in the range of 50:1 to 1:50, preferably in the range of 10:1 to 1:10. The control composition of the present invention may be a simple mixture of the ester compound A of the present invention and the ester compound B of the present invention. However, it is usually used in the form of a plurality of formulations. Examples of the formulation include oily solutions, emulsifiable concentrates, wettable powders, suspension concentrates (such as aqueous suspensions and aqueous emulsions), microcapsule formulations, powders, granules, lozenges, aerosols, carbon dioxide Formulations, heating vaporization formulations (eg, mosquito coils, electric mosquito mats, and fluid absorption wicking-type 13 322445 201124081 pesticide) , piezoelectric spray insecticide, heating fumigant (such as self-ignition fumigant, chemical reaction fumigant, and porous ceramic plate fumigant), non-heat fumigant (such as resin fumigant, paper Fumigants, non-woven fumigants, fabric fumigants, and sublimation tablets, spray formulations (eg aerosols), direct contact formulations (eg sheet contact formulations, strip contacts) Formulations and mesh type contact formulations), ULV formulations and poison dances. For example, formulations can be prepared by the following methods: (1) Esterification of the present invention , Liquid carrier, gaseous carrier or a feed mixture composition A and B according to the present invention, the ester compound with a solid carrier, if necessary, addition of other adjuvants for formulation of, for example, surfactant.
(2) 將基材以本發明酯化合物A及本發明酯化合物B 浸潰。 (3) 將本發明S旨化合物A、本發明醋化合物b及基材混 合，接著模製。 這些調配物通常包含本發明酯化合物A及本發明g旨化 合物B之總量為0. 〇〇1至98重量0/〇。 用於調配物之固體載劑之實例包含細粉末及顆粒例 如黏土（例如高嶺土、矽藻土、膨潤土、富巴沙黏土 (Fubasami clay)及酸性白黏土）、合成性水合氧化;^夕、滑 石、陶竟、其他無機礦物（例如絹雲母、石英、硫、活性碳、 碳酸鈣、及水合氧化矽）及化學肥料（例如硫酸銨、磷酸銨、 硝酸銨、氣化銨及尿素）；及在常溫為固體材料（例如 2, 4, 6-三異丙基-1，3, 5-三噚烷、萘、對二氯苯、樟腦及金 14 322445 201124081 -剛石）；以及氈製品、纖維、布料、織物、薄片、紙、線狀 -物、泡沫、多孔性材料及複纖（multifilament)，其係由一 種或多種羊毛、絲、棉、麻、紙聚、合成樹脂(例：聚乙烯 樹脂諸如低密度聚乙烯、直鏈低密度聚乙烯、及高密度聚 乙烯；乙烯-乙烯酯共聚物諸如乙烯_醋酸乙烯酯共聚:； 乙烯-甲基丙烯酸酯共聚物諸如乙烯_甲基丙烯酸甲酯共聚 物、及乙烯-曱基丙稀酸乙醋共聚物；乙烯—内歸酸醋共聚 物諸如乙烯-丙烯酸曱酯共聚物、及乙烯-丙烯酸乙酯共聚 物；乙烯-乙烯基羧酸酯共聚物諸如乙烯-丙烯酸共聚物； 乙烯-四環十二碳烯共聚物；聚丙烯樹脂諸如丙烯均聚物、 及丙烯-乙烯共聚物；聚-4-甲基戊烯-1 ;聚丁烯_丨；聚丁 二烯；聚苯乙烯；丙烯腈-苯乙烯樹脂；苯乙烯彈性體諸如 丙烯腈-丁二烯-笨乙烯樹脂、苯乙烯-共軛二烯嵌段共聚 物、及氫化苯乙烯-共軛二烯嵌段共聚物；氟塑膠；丙烯酸 系樹脂諸如聚曱基丙埽酸曱酯；聚醯胺樹脂諸如尼龍6、 及尼龍66 ;聚酯樹脂諸如聚對苯二曱酸乙二酯、聚萘二甲 酸乙一S曰、聚對;^ —甲酸丁二醋、及聚對苯二曱酸伸環己 基二亞甲酯；聚碳酸酯；聚縮醛；聚丙烯砜；聚丙烯酸酯； 聚羥基苯曱酸酯；聚醚醯亞胺；聚酯碳酸酯；聚苯謎樹脂； 聚氣乙烯；聚偏二氯乙烯；聚胺酯；及多孔性樹脂諸如聚 胺酯泡洙、聚丙烯泡沫、及聚乙烯泡沫）、玻璃、金層及陶 瓷所組成。 液體載劑之實例包含芳香族烴類或脂肪族烴類（例如 二曱苯、甲苯、烷基萘、苯基二曱苯基乙烷、煤油、輕油、 322445 15 201124081 己烷、及環己烷）、函化烴類（例如氣苯、二氣曱烷、二氯 乙烷、及三氣乙烷）、醇類（例如甲醇、乙醇、異丙醇、丁 醇、己醇、苯曱醇、及乙二醇）、醚類（例如二乙醚、乙二 醇二曱醚、二乙二醇單曱醚、二乙二醇單乙醚、丙二醇單 甲醚、四氩呋喃、及二噚烷）、酯類（例如醋酸乙酯、及醋 酸丁酯）、酮類（例如丙酮、曱基乙基酮、曱基異丁基酮、 及環己酮）、腈類（例如乙腈、及異丁腈）、亞砜類（例如二 曱基亞颯）、缓醯胺類（acid amides)(例如Ν,Ν-二甲基甲 醯胺、Ν,Ν-二曱基乙醯胺、及Ν-甲基-吡咯啶酮）、碳酸烷 二醋（例如破酸丙二目旨）、植物油類（例如大豆油、及棉軒 油）、植物精油類（例如撥油、海索油、及檸檬油）及水。 氣體載劑之實例包含丁烷氣體、氟氯化碳氣體、液化 石油氣（LPG)、二曱醚、及二氧化碳。 界面活性劑之實例包含烧基硫酸S旨鹽類、烧基績酸鹽、 烷基芳基磺酸鹽、烷基芳基醚類、聚氧伸乙基化烷基芳基 醚類、聚乙二醇醚類、多元醇酯類、及糖醇衍生物。 用於調配物之其他輔助劑之實例包含黏結劑、分散 劑、及安定劑。其具體實例包含酪蛋白、明膠、多醣類（例 如澱粉、阿拉伯膠、纖維素衍生物、及藻酸）、木質素衍生 物、膨潤土、·、合成水溶性聚合物（例如聚乙烯醇、聚乙 烯吡咯啶酮、及聚丙烯酸）、ΒΗΤ(2, 6-二-第三丁基-4-曱基 盼）及ΒΗΑ(2 -第三丁基-4-甲氧基盼與3-第三丁基-4-曱氧 基盼之混合物）。 防蚊卷之基材之實例包含植物粉末（例如木粉、及除 16 322445 201124081 J 蟲菊）以及黏結劑（例如紅楠樟科（yifec/z//i/s - 之粉末、澱粉、及麩質）之混合物。 電蚊片之基材之實例包含經纏結、壓縮及壓製成平板 狀之棉絨、及經纏結、壓縮及壓製成平板狀之棉絨與紙漿 的混合細纖維。 自燃型燻蒸劑之基材之實例包含可燃的發熱劑，例如 硝酸鹽、亞硝酸鹽、胍鹽、氣酸鉀、硝化纖維素、乙基纖 維素、及木粉；熱分解促進劑，例如驗金屬鹽、驗土金屬 鹽、重鉻酸鹽、及鉻酸鹽；載氧劑，例如頌酸鉀；助燃劑， 例如三聚氰胺、及小麥澱粉；填料，例如矽藻土；以及黏 結劑，例如合成黏合劑。 . 化學反應型燻蒸劑之基材之實例包含發熱劑，例如驗 金屬之硫化物、多硫化物及硫氫化物、及氧化約；催化劑， 例如碳質材料、碳化鐵及活性黏土；有機發泡劑，例如偶 氮二甲醯胺、苯磺醯肼、二硝基五亞曱基四胺、聚苯乙烯 及聚胺酯；及填料，例如天然纖維及合成纖維。 用於例如樹脂燻蒸劑之樹脂之實例包含聚乙烯樹脂， 例如低密度聚乙烯、直鏈低密度聚乙烯、及高密度聚乙烯； 乙烯-乙烯酯共聚物，例如乙烯-醋酸乙烯酯共聚物；乙烯-曱基丙烯酸酯共聚物，例如乙烯-曱基丙烯酸曱酯共聚物、 及乙烯-甲基丙烯酸乙酯共聚物；乙烯-丙烯酸酯共聚物， 例如乙烯-丙烯酸曱酯共聚物、及乙烯-丙烯酸乙酯共聚 物；乙烯-乙烯基羧酸酯共聚物，例如乙烯-丙烯酸共聚物； 乙烯-四環十二碳烯共聚物；聚丙烯樹脂，例如丙烯均聚 17 322445 201124081 物、及丙稀-乙稀共聚物；聚_4_甲基戊烯七聚丁场七 聚丁二稀；聚苯乙稀；丙埽腈-笨乙豨樹脂；苯乙烯彈性體， 例如丙烤腈—丁二稀-笨乙稀樹脂、苯乙稀-共軛二稀嵌段北 聚物及虱化苯乙稀H麯段共聚物；氟塑膠；丙稀酸 系樹脂，例如聚曱基丙_曱@旨；聚_樹脂，例如尼龍 6、及尼龍66 ;聚s旨樹脂，例如聚對笨二甲酸乙二酉旨、聚 萘，甲酸乙二酷、聚對笨二甲酸丁二_、及聚對笨二甲酸 伸環己基二亞曱酯；聚碳酸酯；聚縮醛；聚丙烯碾；聚丙 稀酸醋；聚經基苯甲酸S旨；聚賴亞胺；㈣旨碳酸聚 苯醚樹脂；聚氣乙烯；聚偏二氣乙烯；及聚胺醋。這些基 .材可單獨使用或以其組合使用。另外，若有需要，可將塑 化劑，例如苯二曱酸酯（例如苯二甲酸二曱酯、及苯二甲酸 二辛酯）、己二酸酯、及硬酯酸加入這些基材。該樹脂燻蒸 劑係經由將本發明酯化合物A及本發明酯化合物b揉捏入 基材’接著經由射出成型、擠壓成型或模壓成型來模製而 製得。所得樹脂調配物可進行進一步加工例如模製或切 割，若有需要’加工成平板、薄膜、帶狀物、網狀物或細 繩之外型。這些樹脂調配物可被加工成，例如，動物頸圈、 動物耳標、平板製品、誘引繩及園藝樁柱（horticultural supports) ° 用於毒餌之基材之實例包含飼料成分，例如榖粉、植 物油、糖、及結晶纖維素；抗氧化劑’例如二丁基羥基曱 苯、及降二氫癒創木酸（nordihydroguaiaretic acid);防 腐劑，例如去氫乙酸；防兒童及寵物誤食劑，例如辣椒粉； 18 322445 201124081 及誘引病蟲害香料，例如乳酪香料、洋蔥香料、及花生油。 . 本發明之病蟲害之防治方法係經由將本發明防治組 成物施用至病蟲及/或病蟲棲息處（例如植物體、土壤、戶 外、及動物體）而進行。另外，本發明之病蟲害之防治方法 亦可經由將本發明酯化合物A及本發明酯化合物B施用至 病蟲及/或病蟲棲息處而進行。 具體而言，至於本發明防治組成物之應用方法，可由 下列方法例示，且這些方法可根據例如該防治組成物之形 式、及應用位置而予以適當地選擇。 (1) 將本發明防治組成物本身施用至病蟲及/或該病 蟲樓息處。 (2) 將本發明防治組成物以溶劑（例如水）稀釋，接著 施用至病蟲及/或該病蟲棲息處。 此情況中，通常，例如以可乳化濃縮物、可濕性粉末、 懸浮濃縮物或微膠囊製劑之形式之本發明防治組成物係經 稀釋，以使本發明酯化合物A及本發明酯化合物B之總濃 度成為0· 01至1000 ppm。 (3) 在病蟲棲息處加熱本發明防治組成物，以使有效 成分揮發。 在此情況中，本發明酯化合物A及本發明酯化合物B 之施用率及濃度可根據例如本發明防治組成物之形式、施 用時期、施用位置、施用方法、及傷害情況而適當地決定。 在利用供防治目的用之本發明防治組成物中，就本發 明酯化合物A及本發明酯化合物B之總量而言，當施用於 19 322445 201124081 空間時，施用率通常為0. 0001至1000 mg/m3，而當施用 於平面時，施用率為0. 0001至1000 mg/m2。熱散發式調 配物（例如防蚊卷及電蚊片）係根據該調配物之形式來適當 地加熱以使有效成分揮發而施用。非熱式燻蒸劑（例如樹脂 燻蒸劑、紙製燻蒸劑、錠劑、不織布燻蒸劑、織物燻蒸劑、 及片狀型調配物）例如可透過將其本身置於欲施用之空 間、或透過將該調配物朝向風而使用。 用於防治目的而施用本發明防治組成物之空間之實 例包含壁櫥、廚台、衣櫃、箱櫃、食櫃、洗手間、浴室、 倉庫、起居室、餐廳、車庫、和汽車内部。另外，該組成 物亦可施用於戶外開放空間。 當本發明防治組成物係用於家畜（例如牛、馬、豬、 綿羊、山羊及雞）及小型動物（例如狗、貓、大鼠及小鼠） 以達到防治外寄生蟲之目的時，可經獸醫領域中之已知方 法施加到所述動物。具體而言，當欲用於全身性防治時， 該調配物係藉由錠劑、飼料混合物、栓劑及注射劑（包含肌 内注射、皮下注射、靜脈注射及腹腔注射）之方式投予。另 一方面，當欲用於非全身性防治時，該調配物係藉由喷灑 油性溶液或水性溶液、澆注（pour-on)處理或滴注（spot -on) 處理、以洗髮精調配物來洗滌動物、或將樹脂調配物製成 的頸圈或耳標安裝於動物之方式來使用。本發明酯化合物 A及本發明S旨化合物B之總劑量通常係每1公斤（kg)動物 體重為0. 01至1000毫克（mg)之範圍。 本發明防治組成物可組合使用，或與其他成分混合， 20 322445 201124081 - 例如病蟲害防治劑諸如其他殺昆蟲劑、殺蟎劑、及拒避劑 . (repellents)、増效劑、及色素。 後文，將藉由調配例及試驗例更詳細說明本發明。但 本發明並不受限於該等實施例。 首先，敘述本發明防治組成物之調配例。在調配例 中，除非另行說明，否則所有“份數”皆以重量計。 調配例1(2) The substrate is impregnated with the ester compound A of the present invention and the ester compound B of the present invention. (3) The compound A of the present invention, the vinegar compound b of the present invention and a substrate are mixed and then molded. The total amount of the ester compound A of the present invention and the compound B of the present invention is from 0.1 to 98% by weight. Examples of solid carriers for formulations include fine powders and granules such as clay (e.g., kaolin, diatomaceous earth, bentonite, Fubasami clay, and acid white clay), synthetic hydration oxidation; , Tao Jing, other inorganic minerals (such as sericite, quartz, sulfur, activated carbon, calcium carbonate, and hydrated cerium oxide) and chemical fertilizers (such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ammonium sulfate and urea); Normal temperature is solid material (eg 2, 4, 6-triisopropyl-1,3,5-trioxane, naphthalene, p-dichlorobenzene, camphor and gold 14 322445 201124081 - rigid stone); and felt, fiber , cloth, fabric, sheet, paper, thread-like, foam, porous material and multifilament, which are made of one or more of wool, silk, cotton, hemp, paper, synthetic resin (eg polyethylene) Resins such as low density polyethylene, linear low density polyethylene, and high density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymer: ethylene-methacrylate copolymers such as ethylene_methacrylic acid Ester copolymer And an ethylene-mercaptoacetic acid ethyl acetate copolymer; an ethylene-endo-acid vinegar copolymer such as an ethylene-acrylic acid acrylate copolymer, and an ethylene-ethyl acrylate copolymer; an ethylene-vinyl carboxylate copolymer such as ethylene - acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resin such as propylene homopolymer, and propylene-ethylene copolymer; poly-4-methylpentene-1; polybutene oxime; Butadiene; polystyrene; acrylonitrile-styrene resin; styrene elastomer such as acrylonitrile-butadiene-stupid vinyl resin, styrene-conjugated diene block copolymer, and hydrogenated styrene-conjugated Diene block copolymer; fluoroplastic; acrylic resin such as decyl phthalate; polyamine resin such as nylon 6, and nylon 66; polyester resin such as polyethylene terephthalate, poly Naphthalene naphthalate, S-Pheptene, poly(p-butylic acid), and poly(p-benzoic acid) cyclohexyl dimethylene methyl ester; polycarbonate; polyacetal; polysulfone; polyacrylate; polyhydroxyl Benzoic acid ester; polyether quinone imine; polyester carbonate; polyphenylene resin; polyethylene gas; Vinylidene chloride; polyurethane; porous resin and a polyamine such as bubble-soo ester, polypropylene foam and polyethylene foam), glass, ceramic, and a gold layer formed. Examples of liquid carriers include aromatic hydrocarbons or aliphatic hydrocarbons (e.g., diphenylbenzene, toluene, alkylnaphthalene, phenyldiphenylene ethane, kerosene, gas oil, 322445 15 201124081 hexane, and cyclohexane). Alkanes, functional hydrocarbons (eg, benzene, dioxane, dichloroethane, and tri-ethane), alcohols (eg, methanol, ethanol, isopropanol, butanol, hexanol, benzofuran) And ethylene glycol), ethers (eg diethyl ether, ethylene glycol dioxime ether, diethylene glycol monoterpene ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, tetrahydrofuran, and dioxane) , esters (such as ethyl acetate, and butyl acetate), ketones (such as acetone, mercaptoethyl ketone, decyl isobutyl ketone, and cyclohexanone), nitriles (such as acetonitrile, and isobutyronitrile) ), sulfoxides (eg, dimercaptopurine), acid amides (eg, hydrazine, hydrazine-dimethylformamide, hydrazine, hydrazine-dimercaptoacetamide, and hydrazine-A) Base-pyrrolidone), alkyl carbonate diacetate (for example, acid-breaking propane), vegetable oils (such as soybean oil, and cotton oil), plant essential oils (such as oil, seaweed) Oil, and lemon oil) and water. Examples of the gaseous carrier include butane gas, carbon fluorocarbon gas, liquefied petroleum gas (LPG), dioxane, and carbon dioxide. Examples of the surfactant include sodium sulfonate, salt, alkyl aryl sulfonate, alkyl aryl sulfonate, polyoxyalkylene alkyl aryl ether, polyethyl b Glycol ethers, polyol esters, and sugar alcohol derivatives. Examples of other adjuvants for the formulation include a binder, a dispersant, and a stabilizer. Specific examples thereof include casein, gelatin, polysaccharides (for example, starch, gum arabic, cellulose derivatives, and alginic acid), lignin derivatives, bentonite, and synthetic water-soluble polymers (for example, polyvinyl alcohol, poly Vinyl pyrrolidone, and polyacrylic acid), hydrazine (2,6-di-t-butyl-4-indolyl) and hydrazine (2-tert-butyl-4-methoxy-prone and 3-third Butyl-4-oxime is expected to be a mixture). Examples of the substrate of the anti-mosquito roll include plant powder (for example, wood flour, and in addition to 16 322 445 201124081 J Cordyceps) and a binder (for example, yifec/z//i/s - powder, starch, and A mixture of gluten. Examples of the substrate of the electric mosquito sheet include a woven cotton sheet which is entangled, compressed and pressed into a flat shape, and a mixed fine fiber which is entangled, compressed and pressed into a flat cotton linters and pulp. Examples of the substrate of the self-igniting fumigant include a flammable heat generating agent such as nitrate, nitrite, strontium salt, potassium oxylate, nitrocellulose, ethyl cellulose, and wood powder; thermal decomposition accelerator, for example, a metal salt, a soil metal salt, a dichromate, and a chromate; an oxygen carrier such as potassium citrate; a combustion improver such as melamine, and wheat starch; a filler such as diatomaceous earth; and a binder such as a synthetic Adhesives. Examples of the substrate of the chemically reactive fumigant include a heat generating agent such as a metal sulfide, a polysulfide and a sulfur hydride, and an oxidation catalyst; a catalyst such as a carbonaceous material, iron carbide, and activated clay; Organic foaming agent, For example, azo dimethyl hydrazine, benzene sulfonium, dinitro pentamethylenetetramine, polystyrene, and polyurethane; and fillers such as natural fibers and synthetic fibers. Examples of resins for use in, for example, resin fumigants include Polyethylene resin, such as low density polyethylene, linear low density polyethylene, and high density polyethylene; ethylene-vinyl ester copolymer, such as ethylene-vinyl acetate copolymer; ethylene-mercapto acrylate copolymer, such as ethylene - anthracenyl acrylate copolymer, and ethylene-ethyl methacrylate copolymer; ethylene-acrylate copolymer, such as ethylene-decyl acrylate copolymer, and ethylene-ethyl acrylate copolymer; ethylene-vinyl carboxylate An acid ester copolymer, such as an ethylene-acrylic acid copolymer; an ethylene-tetracyclododecene copolymer; a polypropylene resin such as propylene homopolymer 17 322445 201124081, and a propylene-ethylene copolymer; Heptaene, seven-mer, butadiene, polystyrene, polystyrene, acetonitrile, styrene, styrene, styrene, styrene, styrene, styrene, styrene Conjugated dilute block And styrene styrene H-curve copolymer; fluoroplastic; acrylic acid resin, such as polyacrylic acid, 聚 旨 旨; poly _ resin, such as nylon 6, and nylon 66; poly s resin, such as poly For bismuth dicarboxylate, polynaphthalene, formic acid ethane condensate, poly(p-phenylene dicarboxylate), and poly(p-phenylene dicarboxylic acid) cyclohexyl diimide ester; polycarbonate; polyacetal; polypropylene Grinding; polyacrylic acid vinegar; polyperbenzoic acid S; polylysine; (d) carbonic acid polyphenylene ether resin; polyethylene; polyethylene gas; polyamine vinegar. These materials can be used alone Or used in combination. In addition, if necessary, plasticizers such as phthalic acid esters (such as dinonyl phthalate and dioctyl phthalate), adipates, and stearates can be used. An acid is added to the substrate. The resin fumigant is obtained by molding the ester compound A of the present invention and the ester compound b of the present invention into a substrate, followed by molding by injection molding, extrusion molding or press molding. The resulting resin formulation can be subjected to further processing such as molding or cutting, and if desired, processed into a flat sheet, film, ribbon, web or string. These resin formulations can be processed into, for example, animal collars, animal ear tags, flat articles, attracting ropes, and horticultural supports. Examples of substrates for baits include feed ingredients such as lotus root starch, vegetable oils. , sugar, and crystalline cellulose; antioxidants such as dibutyl hydroxy phthalic acid, and nordihydroguaiaretic acid; preservatives such as dehydroacetic acid; anti-child and pet ingestants, such as pepper Powder; 18 322445 201124081 and induce pests and diseases such as cheese spices, onion spices, and peanut oil. The method for controlling pests and diseases of the present invention is carried out by applying the control composition of the present invention to a pest and/or a pest habitat (e.g., plant body, soil, household, and animal body). Further, the method for controlling pests and diseases of the present invention can also be carried out by applying the ester compound A of the present invention and the ester compound B of the present invention to a pest and/or a pest habitat. Specifically, as for the application method of the control composition of the present invention, it can be exemplified by the following methods, and these methods can be appropriately selected depending on, for example, the form of the control composition and the application position. (1) The control composition of the present invention itself is applied to a pest and/or a pest. (2) The control composition of the present invention is diluted with a solvent (e.g., water), and then applied to a pest and/or a pest habitat. In this case, usually, the control composition of the present invention is, for example, in the form of an emulsifiable concentrate, a wettable powder, a suspension concentrate or a microcapsule preparation, which is diluted to give the ester compound A of the present invention and the ester compound B of the present invention. The total concentration is from 0.01 to 1000 ppm. (3) The composition of the present invention is heated at a pest habitat to volatilize the active ingredient. In this case, the application rate and concentration of the ester compound A of the present invention and the ester compound B of the present invention can be appropriately determined depending on, for example, the form of the control composition of the present invention, the application period, the application site, the administration method, and the injury condition. 0001至1000。 In the total amount of the ester compound A of the present invention and the ester compound B of the present invention, when applied to the space of 19 322445 201124081, the application rate is usually 0. 0001 to 1000 The application rate is from 0.0001 to 1000 mg/m2, when applied to a flat surface. The heat-spreading formulation (e.g., mosquito-repellent roll and electric mosquito-repellent sheet) is suitably heated according to the form of the formulation to administer the active ingredient. Non-heat fumigants (such as resin fumigants, paper fumigants, lozenges, non-woven fumigants, fabric fumigants, and sheet-like formulations), for example, may be placed in the space to be applied, or This formulation is used towards the wind. Examples of the space for applying the control composition of the present invention for control purposes include closets, kitchen counters, wardrobes, bins, food cabinets, restrooms, bathrooms, warehouses, living rooms, dining rooms, garages, and interiors of automobiles. Alternatively, the composition can be applied to an outdoor open space. When the control composition of the present invention is used for livestock (such as cattle, horses, pigs, sheep, goats, and chickens) and small animals (such as dogs, cats, rats, and mice) for the purpose of controlling ectoparasites, The animal is applied by methods known in the veterinary art. Specifically, when intended for systemic control, the formulation is administered by a lozenge, a feed mixture, a suppository, and an injection (including intramuscular injection, subcutaneous injection, intravenous injection, and intraperitoneal injection). On the other hand, when intended for non-systemic control, the formulation is prepared by spraying an oily solution or an aqueous solution, a pour-on treatment or a spot-on treatment, and a shampoo. The animal is used to wash the animal, or a collar or an ear tag made of a resin formulation is attached to the animal. The total dose of the ester compound A of the present invention and the compound B of the present invention is usually in the range of 0.01 to 1000 mg (mg) per 1 kg (kg) of animal body weight. The control composition of the present invention may be used in combination or mixed with other ingredients, 20 322445 201124081 - such as pest control agents such as other insecticides, acaricides, and repellents, deodorants, and pigments. Hereinafter, the present invention will be described in more detail by way of formulation examples and test examples. However, the invention is not limited to the embodiments. First, a formulation example of the control composition of the present invention will be described. In the formulation example, all "parts" are by weight unless otherwise stated. Matching example 1
將9份本發明酯化合物a及0.9份本發明酯化合物B 溶於37. 5份二甲苯及37. 5份N，N_二甲基曱醯胺中。於所 得溶液中加入9. 1份聚氧伸乙基笨乙烯基苯基醚及6份十 二烷基苯磺酸鈣，接著充分混合，獲得可乳化濃縮物。 調配例2 於20份本發明g旨化合物A及20份本發明g旨化合物b 中加入5份SORP〇l 5060(東邦化學工業公司（TOHO Chemical Industry Co.，Ltd.)之註冊商標），接著充分混 合。於所得混合物中加入32份CARPLEX #80(Shionogi & Co. ’ Ltd.之註冊商標’為合成性水合氧化矽細粉）及23 伤300篩目之;ε夕藻土，接著以果汁機混合，獲得可濕性粉 末。 調配例3 於3份本發明酯化合物Α及0. 3份本發明酯化合物Β 内加入5份合成性水合氧化矽細粉、5份十二烷基笨磺酸 鈉鹽、30份膨潤土及56 7份黏土，接著充分攪拌及混合。 然後，將適當用量的水加入所得混合物内。進一步搜拌現 21 322445 201124081 合物，以製粒機製粒，再經風乾，獲得顆粒調配物。 調配例4 以碾缽充分混合5份本發明酯化合物八、〇5份本發明 酯化合物B、1份合成性水合氧化矽細粉、i份作為絮凝劑 之 DORILES B(第一二共株式會社（Daiichi Sankyo C〇.,9份N,N-dimethyl decylamine is dissolved in 9 parts of xylene and 37.5 parts of N,N-dimethyl decylamine. To the resulting solution, 9.1 parts of polyoxyethylidene vinyl phenyl ether and 6 parts of calcium dodecylbenzenesulfonate were added, followed by thorough mixing to obtain an emulsifiable concentrate. Formulation Example 2 5 parts of SORP〇l 5060 (registered trademark of TOHO Chemical Industry Co., Ltd.) were added to 20 parts of the present invention, and 20 parts of the present invention. Mix well. To the resulting mixture, 32 parts of CARPLEX #80 (registered trademark of Shionogi & Co. 'ltd. is a synthetic hydrated cerium oxide fine powder) and 23 wounds of 300 mesh; 夕日藻土, followed by a juice blender , obtaining a wettable powder. Formulation Example 3 Into 3 parts of the ester compound of the present invention and 0.3 part of the ester compound of the present invention, 5 parts of synthetic hydrated cerium oxide fine powder, 5 parts of sodium dodecyl sulfonate, 30 parts of bentonite and 56 are added. 7 parts of clay, then thoroughly stirred and mixed. Then, an appropriate amount of water is added to the resulting mixture. Further, the 21 322445 201124081 compound was mixed, and the granules were granulated, and then air-dried to obtain a granule formulation. Formulation Example 4 5 parts of the ester compound of the present invention, 5 parts of the ester compound B of the present invention, 1 part of a synthetic hydrated cerium oxide fine powder, and 1 part of a DOFLES B as a flocculating agent were mixed with a milled mash. (Daiichi Sankyo C〇.,
Ltd.)之註冊商標）及7份黏土’接著以果汁機攪拌及混合。 於所得混合物内加入85. 5份切削黏土（cut clay)，接著充 分搜摔及混合，獲传粉劑調配物。 調配例5 將10份本發明醋化合物A、1份本發明g旨化合物β、 35份含有一半用量聚氧伸乙基烷基醚硫酸酯銨鹽之白碳、 及54份水之混合物經由濕式研磨法來細碎粒化，獲得粉劑 調配物。 調配例6 將0. 05份本發明酯化合物Α及0. 1份本發明酯化合物 B溶於1〇份二氣甲烷中，且所得溶液與89. 85份異烷烴溶 液（IS0PARM，埃克森（Exxon)化工公司之註冊商標）混合， 獲得油性溶液。 調配例7 將0. 1份本發明酯化合物A、0. 05份本發明酯化合物 B、及 49. 85 份 Neothiozole(Chuo Kasei CO.，Ltd.)置於 氣溶膠罐中。在附接氣溶膠閥後，裝填25份二曱醚及25 份LPG，接著振盪並進一步附接致動器（actuator) ’獲得 油性氣溶膠。 22 322445 201124081 - 調配例8 . 將0. 5份本發明酯化合物A、0. 05份本發明酯化合物 B、0. 01份BHT、5份二甲苯、3. 44份去臭煤油及1份乳化 劑（Atomos 300，Atomos化學公司之註冊商標）之混合物與 50份蒸餾水裝填入氣溶膠容器中，並附接閥部件。然後， 在加壓下將40份推進劑（LPG)經由閥裝填進氣溶膠容器 中，獲得水性氣溶膠。 調配例9 將一件0. 5公分（cm)厚、69公分長及0. 2公分寬具有 蜂巢結構之紙品從其一端捲起以製得直徑5.5公分及高 0. 2公分之圓筒形載體。將適當用量之經由使5份本發明 酷化合物A及0. 5份本發明醋化合物B溶於94. 5份丙酮中 所製得的溶液均勻地塗布到上述載體並經由風乾使丙酮揮 發，獲得紙製蒸發式調配物。 調配例10 將三維經編針織物（商標名：FUSION，產品型號： AKE69440，經銷商：Asahi Kasei Fibers Corporation， 厚度：4. 3公分，織物密度：321克/平方公尺（g/m2)，聚 醯胺所製）剪裁成5公分直徑之圓形。將適當用量之經由使 5份本發明酯化合物A及0. 5份本發明酯化合物B溶於94. 5 份丙酮中所製得的溶液均勻地塗布到上述圓形三維經編針 織物，並經由風乾使丙酮揮發，獲得編針織物蒸發式調配 物。 調配例11 23 322445 201124081 將97. 8份乙烯-曱基丙烯酸甲酯共聚物（甲基丙烯酸 曱酯含量：10重量％’ MFR=2[g/10 min. ])、2份本發明酯 化合物A及〇· 2份本發明酯化合物B之混合物在13〇°C使 用在相同方向旋轉之45 mm0雙螺桿擠出機熔融及揉合， 再進一步在15(TC使用40 mni0擠出機炼融及揉合，接著從 呈薄片外形之T鑄模擠出，再以冷卻輪冷卻，獲得樹脂蒸 發式調配物。 調配例12 將97. 8份乙烯-醋酸乙烯酯共聚物（醋酸乙烯酯含 量：10重量％ ’ MFR=2[g/10 min. ])、2份本發明酯化合物 A及0. 2份本發明酯化合物B之混合物在13(TC使用在相同 方向旋轉之45匪必雙螺桿擠出機熔融及揉合，再進一步 在150°C使用40 擠出機熔融及揉合，接著從呈薄片外 形之T鑄模擠出，再以冷卻輪冷卻，獲得樹脂蒸發式調配 物。 調配例13 將5份本發明酯化合物A及0. 5份本發明酯化合物B 溶於94. 5份丙酮，將適當量之所得溶液塗布到具有可摺疊 結構之紙（2000 cm2)，並經由風乾使丙酮揮發，獲得紙製 蒸發式調配物。 調配例14 經由使3份本發明酯化合物A及0. 3份本發明酯化合 物B溶於14. 6份丙酮而製得溶液。於此溶液内，加入0. 2 份氧化鋅、1.0份α澱粉及42. 8份偶氮二曱醯胺。另外， 24 322445 201124081 於其内加入38. 1份水，並揉合混合物，使用擠出機模製顆 粒外形，再乾燥以獲得顆粒。在其中央部份有鋁隔板分隔 之容器中，將該顆粒置於其上部空間，並將50克氧化鈣置 於其下部空間，獲得燻蒸劑。 調配例15 於0. 5份氧化鋅、2份α澱粉及97. 5份偶氮二甲醯胺 之混合物内加入水，並揉合混合物及使用擠出機模製顆粒 外形，再乾燥以獲得顆粒。然後，將2克顆粒均勻地浸潰 在0. 58克本發明酯化合物Α及0. 058克本發明酯化合物Β 於丙酮之溶液中，並乾燥以獲得顆粒。在其中央部份有鋁 隔板分隔之容器中，將該顆粒置於其上部空間，並將50 克氧化鈣置於其下部空間，獲得壎蒸劑。 調配例16 將0. 5克本發明酯化合物A及0. 05克本發明酯化合物 B溶於20毫升（mL)丙酮中，並將所得溶液加入99. 4克用 於防蚊卷之基材（呈4 : 3 : 3之比例的紅楠樟科之粉末、除 蟲菊及木粉之混合物）及0. 3克綠色色素之混合物内。充分 混合後，將120毫升水加入該混合物並充分揉合。模製及 乾燥所得混合物，獲得防蚊卷。 調配例17 經由混合10份本發明酯化合物A、1份本發明酯化合 物B、39. 5份乙醯化擰檬酸三丁酯、39. 5份己二酸異壬酯、 5份藍色色素及5份香料以製得溶液。將用於3.4公分x2. 1 公分且0. 22公分厚的電蚊片之基材（經纏結、壓縮及壓製 25 322445 201124081 成平板狀之棉絨與紙漿的混合細纖維）均勻地浸潰在上述 溶液，獲得電蚊片。 調配例18 經由使0. 1份本發明酯化合物A及0. 01份本發明酯化 合物B溶於99. 89份去臭煤油而製得溶液。將該溶液置於 氯乙烯容器，及將經加工以使其上半部可經由加熱器加熱 之液體吸收芯（經由以黏合劑固化無機粉末接著煅燒而製 得）插進該容器内，獲得一份用於液體吸收芯型蒸發式調配 物。 調配例19 將0. 2份本發明酯化合物A、0. 02份本發明酯化合物 B、及 49. 78 份 Neothiozole(Chuo Kasei CO.，Ltd.)置於 氣溶膠罐中。在附接氣溶膠閥後，裝填25份二曱醚及25 份LPG，接著振盪並進一步附接用於全内容物-注入型氣溶 膠之致動器，獲得氣溶膠調配物。 調配例20 於0. 2份本發明酯化合物A及0. 02份本發明酯化合物 B内加入99.78份二乙二醇單乙醚，接著充分混合，獲得 用於防治外寄生蟲之滴注調配物。 調配例21 將經由使3份本發明酯化合物A及0. 3份本發明酯化 合物B溶於96. 7份丙酮而製得溶液，並將1毫升溶液均勻 地塗布到經由在壓力（4 t/cm2)下模製4克2, 4, 6-三異丙 基-1，3, 5-三噚烷所得之盤形固體材料（3公分直徑及3毫 26 322445 201124081 - 米（mm)厚），接著乾燥獲得錠劑。 調配例22 在壓力下將〇· 2克本發明酯化合物a、〇 〇2克本發明 S曰化口物B、及4克2,4’6、三異丙基_13 5_三—烷之均勻 此口物抵製為盤形公分直徑及3毫米厚”獲得錠劑。 調配例23 將〇· 2克本發明酯化合物a、〇. 〇2克本發明酯化合物 B及4克2, 4, 6-三異丙基〜丨，3, 5_三噚烷之混合物置於5〇 毫升螺紋管，經加熱熔融然後冷卻至室溫，獲得錠劑。 接著’下列試驗例將顯示本發明防治組成物對病蟲害 具有優異防治效果。 在下列試驗例中’至於本發明酯化合物A，使用（1R)- 反式3-(2,2-二氯乙烯基）〜2,2-二甲基環丙烷羧酸 [2, 3, 5, 6-四氟-4-(曱氧基曱基）笨基]曱酯。 另外，至於本發明酯化合物B，使用（1R)_順式/反式 -2,2-二甲基_3_(2_曱基__1〜丙烯基）環丙烷羧酸（幻_2_曱 基4-側氧基-3-(2-丙炔基環戊烯基酯。 試驗例1 在下表1所示濃度下’經以給定量異烷烴溶劑（IS0PAR Μ ’埃克森化學公司之註冊商標）稀釋本發明酯化合物B而 製得油性溶液（後文中稱作為比較組成物（1)及（3))。同樣 地，在下表！所示濃度下，經以給定量異烷烴溶劑GS〇pAR Μ,’埃克森化學公司之註冊商標）稀釋本發明酯化合物a而 製得油性溶液（後文中稱作為比較組成物（2)及（4))。 322445 27 201124081 另外’在下表1所不有效成分之濃度下，經以給定量 異烷烴溶劑（ISOPAR M，埃克森化學公司之註冊商標）稀釋 本發明酯化合物A及本發明酯化合物B而製得油性溶液（後 文中稱作為本發明組成物（1)、（2)及（3))。 將10隻庫蚊（心/没(雌性）釋放至每邊70 公分的立方形箱中，並以喷搶（喷灑壓力：〇. 9 kg/cm2)從 該箱中央的小窗戶喷進0.7毫升本發明組成物（1)。在喷灑 後給定時間期間，調查擊落的昆蟲數目並計算擊落率 (knock down rate，KD率）。依照相同方法，使用本發明 組成物（2)和（3)及比較組成物（1)至（4)，計算在給定時間 期間後之KD率（2次）。 結果係顯示於表1。 表1 本發明酯化合物A 用量(W/V%) 本發明酯化合物B用 量(W/V%) 7分鐘後之KD 率⑻ 本發明組成物（1) 0.00313 0.00313 100 比較組成物（1) - 0.00313 20 比較組成物（2) 0.00313 - 20 本發明組成物(2) 0.00156 0.00313 50 本發明組成物(3) 0.00313 0.00156 50 比較組成物（3) - 0.00156 - 比較組成物（4) 0.00156 ——ιυ _— ^10 試驗例2 在下表2所示濃度下，以給定量本發明酯化合物 丙闕溶液均勻地處理用於防蚊卷之基材（經攪拌及混合呈 4 : 3 : 3之比例的紅楠樟科之粉末、除蟲菊及木粉之混合 322445 28 201124081 • 物，於其内加入水，充分揉合所得混合物，接著模製及乾 . 燥而獲得）並乾燥以獲得含有化合物之防蚊卷（後文中稱^ 為比較組成物（5))。同樣地，在下表2所示濃度下，使用 本發明醋化合物A而獲得防蚁卷（後文中稱作為比较纟且成 物（6)及（7))。 另外，在下表2所示濃度下，經以給定量丙_稀釋本 發明酯化合物A及本發明酯化合物B而獲得含有化合物之 防蚊卷（後文中稱作為本發明組成物（4)及（5))。 在每邊70公分的立方形箱中’將〇. 5克本發明組成 物（4)置於在其底部中央處設置之防蚊卷並點燃。在該防蚊 卷完全燃燒後，從該箱之入口的小窗釋放20隻庫蚊（雌 性）。在給定時間期間後，調查擊落的昆蟲數目並計算擊落 率（KD率）。依照相同方法，使用本發明組成物（5)及比較 組成物（5)至（7) ’計算在給定時間期間後之KD率（2次）。 結果係顯不於表2。 表2 本發明酯化合物B 用量（重量％) 7分鐘後之KD率 (%)The registered trademark of Ltd.) and 7 parts of clay' were then stirred and mixed with a blender. To the resulting mixture, 85. 5 parts of cut clay was added, followed by full drop and mixing to obtain a powder transfer formulation. Formulation Example 5 10 parts of the vinegar compound A of the present invention, 1 part of the compound of the present invention, β, 35 parts of a white carbon containing a half amount of polyoxyethylidene ether sulfate ammonium salt, and 54 parts of water are passed through a wet The grinding method is used to finely granulate to obtain a powder formulation. Formulation Example 6 The 0.05 part of the ester compound of the present invention and 0.1 part of the ester compound B of the present invention are dissolved in 1 part of di-methane, and the obtained solution is 89.85 parts of an isoparaffin solution (IS0PARM, Exxon). (Exxon) registered trademark of the chemical company) mixed to obtain an oily solution. Formulation Example 7 0.1 parts of the ester compound A of the present invention, 0.05 parts of the ester compound B of the present invention, and 49.85 parts of Neothiozole (Chuo Kasei CO., Ltd.) were placed in an aerosol can. After the aerosol valve was attached, 25 parts of dioxane and 25 parts of LPG were charged, followed by shaking and further attaching an actuator to obtain an oily aerosol. 22份。 The compound of the present invention, 0. 05 parts of the present ester compound A, 0.05 parts of the ester compound of the invention B, 0.01 parts of BHT, 5 parts of xylene, 3. 44 parts of deodorized kerosene and 1 part A mixture of an emulsifier (Atomos 300, a registered trademark of Atomos Chemical Co., Ltd.) was filled with 50 parts of distilled water into an aerosol container, and a valve member was attached. Then, 40 parts of propellant (LPG) was charged into the air sol container via a valve under pressure to obtain an aqueous aerosol. 5厘米的直径。 A sample of 0.5 cm (cm) thick, 69 cm long and 0. 2 cm wide with a honeycomb structure rolled up from one end to produce a diameter of 5.5 cm and a height of 0. 2 cm cylinder Shape carrier. A solution prepared by dissolving 5 parts of the present invention Cool Compound A and 0.5 part of the vinegar compound B of the present invention in 94.5 parts of acetone is uniformly applied to the above carrier and volatilized by air drying to obtain acetone. Paper evaporative formulation. Formulation Example 10 A three-dimensional warp knit fabric (trade name: FUSION, product model: AKE69440, dealer: Asahi Kasei Fibers Corporation, thickness: 4.3 cm, fabric density: 321 g/m 2 (g/m2), poly Made of guanamine) cut into a circle of 5 cm diameter. A solution prepared by dissolving 5 parts of the ester compound A of the present invention and 0.5 part of the ester compound B of the present invention in 94.5 parts of acetone is uniformly applied to the above-mentioned circular three-dimensional warp knit fabric by a suitable amount. Air drying causes the acetone to evaporate to obtain a knitted fabric evaporative formulation. Formulation Example 11 23 322445 201124081 17.8 parts of ethylene-methyl methacrylate copolymer (decyl methacrylate content: 10% by weight 'MFR=2 [g/10 min. ]), 2 parts of the ester compound of the present invention A and 〇· 2 parts of the mixture of the ester compound B of the invention are melted and kneaded at 13 ° C using a 45 mm 0 twin-screw extruder rotating in the same direction, and further smelted at 15 (TC using a 40 mni0 extruder) And a blend of the T-die of the sheet shape, and then cooled by a cooling wheel to obtain a resin evaporating formulation. Formulation Example 12 97.8 parts of ethylene-vinyl acetate copolymer (vinyl acetate content: 10 % by weight of 'MFR=2 [g/10 min. ]), 2 parts of the ester compound A of the invention and 0.2 part of the mixture of the ester compound B of the invention at 13 (TC used in the same direction of rotation 45 匪 twin-screw extrusion The machine was melted and kneaded, further melted and kneaded at 150 ° C using a 40 extruder, and then extruded from a T-die which was in the form of a sheet, and then cooled by a cooling wheel to obtain a resin evaporating formulation. 5份酮。 5 parts of the present ester compound A and 0. 5 parts of the present ester compound B dissolved in 94. 5 parts of acetone An appropriate amount of the obtained solution was applied to a paper having a foldable structure (2000 cm 2 ), and acetone was volatilized by air drying to obtain a paper evaporative formulation. Formulation Example 14 By making 3 parts of the present ester compound A and 0. 3份的azodiamine. In this solution, a solution of 0.2 parts of zinc oxide, 1.0 part of alpha starch and 42.8 parts of azodiamine is added. 24 322445 201124081 Add 38.1 parts of water, knead the mixture, mold the shape of the pellet using an extruder, and then dry to obtain granules. In the central part of the container separated by aluminum partition, the granules The mixture is placed in the upper space, and 50 g of calcium oxide is placed in the lower space to obtain a fumigant. Formulation Example 15 is a mixture of 0.5 parts of zinc oxide, 2 parts of α-starch, and 97.5 parts of azomethicin. 0 克本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本本The inventive ester compound is dissolved in a solution of acetone and dried to obtain granules 5克本发明的发明。 The invention is in the form of 0.5. The ester compound of the present invention is dissolved in 20 ml (mL) of acetone, and the resulting solution is added to 99.4 g of the substrate for anti-mosquito (in a ratio of 4:3:3). A mixture of powder of red nanaceae, a mixture of pyrethrum and wood flour, and a mixture of 0.3 g of green pigment. After thorough mixing, 120 ml of water was added to the mixture and fully kneaded. The resulting mixture was molded and dried to obtain an anti-mosquito roll. Formulation Example 17 By mixing 10 parts of the ester compound A of the present invention, 1 part of the ester compound B of the present invention, 39.5 parts of tributyl acetyl citrate, 39.5 parts of isodecyl adipate, 5 parts of blue The pigment and 5 parts of perfume were prepared to prepare a solution. The substrate of the electric mosquito sheet of 3.4 cm x 2.1 cm and 0.22 cm thick is uniformly impregnated with the entangled, compressed and pressed 25 322445 201124081 flat-shaped lint of pulp and pulp. In the above solution, an electric mosquito sheet was obtained. Formulation Example 18 A solution was prepared by dissolving 0.1 part of the ester compound A of the present invention and 0.01 part of the ester compound B of the present invention in 99.89 parts of deodorized kerosene. The solution is placed in a vinyl chloride container, and a liquid absorbent core processed by heating the upper half thereof via a heater (made by curing the inorganic powder with a binder and then calcining) is inserted into the container to obtain a solution. Parts are used in liquid absorbent core type evaporative formulations. Formulation Example 19 0.2 part of the ester compound A of the invention, 0.02 part of the ester compound B of the invention, and 49.78 parts of Neothiozole (Chuo Kasei CO., Ltd.) were placed in an aerosol can. After the aerosol valve was attached, 25 parts of dioxane and 25 parts of LPG were charged, followed by shaking and further attaching an actuator for a full content-injection type aerosol to obtain an aerosol formulation. Formulation Example 20 In the present invention, the ester compound A of the present invention and the 0.02 part of the ester compound B of the present invention are added with 99.78 parts of diethylene glycol monoethyl ether, followed by thorough mixing to obtain a drip formulation for controlling ectoparasites. . Formulation Example 21 A solution was prepared by dissolving 3 parts of the ester compound A of the present invention and 0.3 part of the ester compound B of the present invention in 96.7 parts of acetone, and uniformly coating 1 ml of the solution to the pressure (4 t /cm2) A disc-shaped solid material obtained by molding 4 g of 2,4,6-triisopropyl-1,3,5-trioxane (3 cm diameter and 3 mp 26 322445 201124081 - m (mm) thick ), followed by drying to obtain a tablet. Formulation Example 22 Under pressure, 2 g of the ester compound a of the present invention, 2 g of the S group of the present invention B, and 4 g of 2,4'6, triisopropyl _13 5 -tri-alkane The uniformity of the mouth is resisted to a disc-shaped cm diameter and a thickness of 3 mm" to obtain a tablet. Formulation Example 23 2 2 g of the ester compound a of the present invention, 〇. 2 g of the ester compound B of the present invention and 4 g of 2, A mixture of 4,6-triisopropyl-hydrazine, 3,5-trioxane was placed in a 5 ml-threaded tube, melted by heating and then cooled to room temperature to obtain a tablet. [The following test examples will show the present invention. The control composition has an excellent control effect on pests and diseases. In the following test examples, as for the ester compound A of the present invention, (1R)-trans 3-(2,2-dichlorovinyl)~2,2-dimethyl group was used. Cyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(decyloxyindolyl) decyl] oxime ester. Further, as for the ester compound B of the present invention, (1R)_cis/trans is used. -2,2-Dimethyl_3_(2_fluorenyl__1~propenyl)cyclopropanecarboxylic acid (Phantom _2-mercapto 4-oxo-3-(2-propynylcyclopentenyl) Ester. Test Example 1 A given amount of isoalkane solvent (I was given at the concentration shown in Table 1 below) S0PAR Μ 'registered trademark of Exxon Chemical Co., Ltd.) diluted the ester compound B of the present invention to obtain an oily solution (hereinafter referred to as comparative compositions (1) and (3)). Similarly, at the concentrations shown in the following table! An oily solution (hereinafter referred to as comparative composition (2) and (4)) is prepared by diluting the ester compound a of the present invention with a given amount of an isoparaffin solvent GS〇pAR®, a registered trademark of Exxon Chemical Co., Ltd. 322445 27 201124081 In addition, the ester compound A of the present invention and the ester compound B of the present invention were diluted with a given amount of an isoparaffin solvent (ISOPAR M, a registered trademark of Exxon Chemical Co., Ltd.) at a concentration of the inactive component of Table 1 below. An oily solution (hereinafter referred to as a composition (1), (2), and (3) of the present invention) was prepared. Ten Culex mosquitoes (heart/no (female) were released into a cubic box of 70 cm per side, And spray 0.7 ml of the composition of the invention (1) from a small window in the center of the box by spraying (spraying pressure: kg. 9 kg/cm2). During the given time after spraying, investigate the number of insects shot down and Calculate the knockdown rate (KD rate). According to the same party Using the compositions (2) and (3) of the present invention and the comparative compositions (1) to (4), the KD rate (2 times) after a given period of time was calculated. The results are shown in Table 1. Table 1 Inventive ester compound A Amount (W/V%) The amount of the ester compound B of the present invention (W/V%) KD rate after 7 minutes (8) The composition of the present invention (1) 0.00313 0.00313 100 Comparative composition (1) - 0.00313 20 Comparison Composition (2) 0.00313 - 20 Composition of the invention (2) 0.00156 0.00313 50 Composition of the invention (3) 0.00313 0.00156 50 Comparative composition (3) - 0.00156 - Comparative composition (4) 0.00156 - ιυ _- ^ 10 Test Example 2 The base material for anti-mosquito coils was uniformly treated with a given amount of the ester compound propionate solution of the present invention at a concentration shown in Table 2 below (the mixture was stirred and mixed to a ratio of 4:3:3). Mix of powder, pyrethrum and wood flour 322445 28 201124081 • Add water to the mixture, mix the mixture well, then dry and dry. Obtain and dry to obtain anti-mosquito containing compound (The following is called ^ as a comparative composition (5)). Similarly, the anti-ant roll (hereinafter referred to as comparative oxime and the products (6) and (7)) was obtained by using the vinegar compound A of the present invention at the concentrations shown in Table 2 below. Further, at a concentration shown in the following Table 2, a compound-containing anti-mosquito roll (hereinafter referred to as a composition (4) and (hereinafter referred to as a composition of the present invention) was obtained by diluting the ester compound A of the present invention and the ester compound B of the present invention in a given amount. 5)). In a cubic box of 70 cm on each side, 5 g of the composition (4) of the present invention was placed in an anti-mosquito coil set at the center of the bottom thereof and ignited. After the mosquito coil was completely burned, 20 Culex (female) were released from the small window at the entrance of the box. After a given period of time, the number of insects shot down was investigated and the shot rate (KD rate) was calculated. According to the same method, the KD rate (2 times) after a given period of time was calculated using the composition (5) of the present invention and the comparative compositions (5) to (7)'. The results are not shown in Table 2. Table 2 The amount of the ester compound B of the present invention (% by weight) KD rate after 7 minutes (%)
如上述 害防治組成物及病蟲蟲害具有優異效果之病蟲 322445 29 201124081 【圖式簡單說明】 無 【主要元件符號說明】Such as the above-mentioned pest control composition and pests and diseases have excellent effects of pests and diseases 322445 29 201124081 [Simple diagram description] None [Main component symbol description]
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009250305 | 2009-10-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201124081A true TW201124081A (en) | 2011-07-16 |
Family
ID=43952974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW99136902A TW201124081A (en) | 2009-10-30 | 2010-10-28 | Harmful organism-controlling composition and control method of harmful organisms |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JP5589712B2 (en) |
| CN (1) | CN102047903A (en) |
| AR (1) | AR079017A1 (en) |
| AU (1) | AU2010236006A1 (en) |
| BR (1) | BRPI1010406A2 (en) |
| MX (1) | MX2010011912A (en) |
| RU (1) | RU2010144519A (en) |
| TR (1) | TR201008916A2 (en) |
| TW (1) | TW201124081A (en) |
| ZA (1) | ZA201007754B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5652080B2 (en) * | 2009-10-30 | 2015-01-14 | 住友化学株式会社 | Pest control composition and pest control method |
| AU2011265562A1 (en) | 2011-01-12 | 2012-07-26 | Sumitomo Chemical Company, Limited | Method of controlling harmful arthropod, composition, and electrostatic spray device |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3170890D1 (en) * | 1980-12-17 | 1985-07-11 | Ici Plc | Fluorobenzyl cyclopropane carboxylates, their preparation, compositions comprising them and their use as insecticides |
| DE4030223A1 (en) * | 1990-09-25 | 1992-03-26 | Bayer Ag | PYRETHROID ACTIVE SUBSTANCE COMBINATIONS CONTAINING BENFLUTHRIN AND PRALLETHRIN |
| TW529911B (en) * | 1998-11-20 | 2003-05-01 | Sumitomo Chemical Co | Pyrethroid compounds and composition for controlling pest containing the same |
| JP4423863B2 (en) * | 2003-02-20 | 2010-03-03 | 住友化学株式会社 | Insecticide |
| JP2006298789A (en) * | 2005-04-18 | 2006-11-02 | Sumitomo Chemical Co Ltd | Vermin controlling agent |
| CN100545144C (en) * | 2008-04-29 | 2009-09-30 | 江苏扬农化工股份有限公司 | A kind of optically active pyrethroid coumpound and its production and application |
| CN101632376A (en) * | 2009-06-05 | 2010-01-27 | 江苏扬农化工股份有限公司 | Pest control repellent and method for preventing and killing pests |
-
2010
- 2010-09-22 JP JP2010211927A patent/JP5589712B2/en not_active Expired - Fee Related
- 2010-10-25 AU AU2010236006A patent/AU2010236006A1/en not_active Abandoned
- 2010-10-27 TR TR2010/08916A patent/TR201008916A2/en unknown
- 2010-10-28 TW TW99136902A patent/TW201124081A/en unknown
- 2010-10-28 AR ARP100103952 patent/AR079017A1/en unknown
- 2010-10-29 ZA ZA2010/07754A patent/ZA201007754B/en unknown
- 2010-10-29 MX MX2010011912A patent/MX2010011912A/en not_active Application Discontinuation
- 2010-10-29 RU RU2010144519/13A patent/RU2010144519A/en not_active Application Discontinuation
- 2010-10-29 BR BRPI1010406 patent/BRPI1010406A2/en not_active Application Discontinuation
- 2010-10-29 CN CN2010105312745A patent/CN102047903A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU2010236006A1 (en) | 2011-05-19 |
| JP2011116738A (en) | 2011-06-16 |
| TR201008916A2 (en) | 2011-05-23 |
| JP5589712B2 (en) | 2014-09-17 |
| CN102047903A (en) | 2011-05-11 |
| ZA201007754B (en) | 2011-08-31 |
| MX2010011912A (en) | 2011-04-29 |
| RU2010144519A (en) | 2012-05-10 |
| BRPI1010406A2 (en) | 2012-12-25 |
| AR079017A1 (en) | 2011-12-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW200917966A (en) | Pesticidal composition and method for controlling pests | |
| CN109195944A (en) | Ester compounds and application thereof | |
| TW201124081A (en) | Harmful organism-controlling composition and control method of harmful organisms | |
| ES2343724B1 (en) | PESTICIDE COMPOSITION. | |
| TW201035059A (en) | Ester compound and use thereof | |
| TWI687161B (en) | Ester compounds and use thereof | |
| TW201124082A (en) | Harmful organism-controlling composition and control method of harmful organisms | |
| TW201124080A (en) | Harmful organism-controlling composition and control method of harmful organisms | |
| JP5906723B2 (en) | Pest control composition and pest control method | |
| TW201121424A (en) | Harmful organism-controlling composition and control method of harmful organisms | |
| TW201124083A (en) | Harmful organism-controlling composition and control method of harmful organisms | |
| TW200934389A (en) | Cyclopropanecarboxylate and pest controlling composition containing the same | |
| TW201306749A (en) | Pesticidal composition and method for controlling pests | |
| KR20110047989A (en) | Harmful bio-control compositions and methods of controlling harmful organisms | |
| KR20110047990A (en) | Harmful bio-control compositions and methods of controlling harmful organisms | |
| TW201244632A (en) | Pest control composition and pest control method | |
| KR20110047986A (en) | Harmful bio-control compositions and methods of controlling harmful organisms | |
| TW201236567A (en) | Pesticidal composition and method for controlling pests | |
| TW201234968A (en) | Pesticidal composition and method for controlling pests | |
| TW200934388A (en) | Cyclopropanecarboxylate and pest controlling composition containing the same | |
| TW201304685A (en) | Pesticidal composition and method for controlling pests | |
| CN102550591A (en) | Pest control composition and method for controlling pests | |
| KR20110047991A (en) | Harmful bio-control compositions and methods of controlling harmful organisms | |
| TW201035019A (en) | Ester compound and use thereof | |
| KR20110047987A (en) | Harmful bio-control compositions and methods of controlling harmful organisms |