CN102550591A - Pest control composition and method for controlling pests - Google Patents

Abstract

The present invention provides a pest control composition and a method for controlling pests, wherein the composition comprises 2,2,3,3-tetramethyl cyclopropane methanoic acid[(2,3,5,6-tetrafluorine-4-(methoxy-methyl)phenyl)methyl]ester [a] and ester compound [b] represented by formula (I), wherein the mass ratio of [a]:[b] is 50/1-1/50.

Description

The method of insect control combination thing and Pest Control

Technical field

The present invention relates to the method for insect control combination thing and Pest Control.

Background technology

2,2,3,3-tetramethyl cyclopropane-carboxylic acid [(2,3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester can be used for insect control combination thing (referring to JP-ANo.2001-302591).

The ester compounds of representing through following formula:

(R wherein ¹Expression hydrogen atom, halogen atom, optional by the substituted C1-C3 alkyl of one or more halogen atoms, optional by the substituted C2-C3 thiazolinyl of one or more halogen atoms etc., n representes that 1 to 4 integer and X represent hydrogen atom or C1-C3 alkyl.) can be used as insect control combination thing (referring to, US6225495).

Summary of the invention

The purpose of this invention is to provide the insect control combination thing that can demonstrate out the color control effect to insect.The present invention relates to following invention.

[1] a kind of insect control combination thing, said composition comprises:

[a] 2,2,3,3-tetramethyl cyclopropane-carboxylic acid [(2,3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester with

The ester compounds of [b] passing type (I) expression,

(wherein, R ^aExpression hydrogen atom or methyl and R ^bExpression methyl or methoxy methyl),

[a]: the mass ratio of [b] is 50: 1 to 1: 50.

[2] according to [1] described composition, wherein the ester compounds of passing type (I) expression is 2,2-dimethyl-3-(1-acrylic) cyclopropane-carboxylic acid [(2,3; 5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester, 2,2-dimethyl-3-(1-acrylic) cyclopropane-carboxylic acid [(2,3; 5,6-tetrafluoro-4-aminomethyl phenyl) methyl] ester or 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid [(2; 3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester.

[3] according to [1] or [2] described composition, wherein said insect is diptera (dipterous) insect.

[4] according to each the described composition in [1] to [3], wherein said insect is fly (flies).

[5] a kind of method of Pest Control, said method comprises: each described composition in the basis [1] to [4] of effective dose is applied to the place that insect or insect perch.

[6] be used for the purposes of Pest Control according to each described composition in [1] to [4].

Hereinafter, respectively composition, [a] and [b] of [1] is called the present composition, compd A and compd B.

Embodiment

Present composition inclusion compound A and compd B.

Compd A is 2,2,3 of passing type (II) expression, 3-tetramethyl cyclopropane-carboxylic acid [(2,3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester.

Compd A can be through middle method preparations of describing such as JP-A No.2001-302591.

Compd B comprises 2,2-dimethyl-3-(1-acrylic) cyclopropane-carboxylic acid [(2,3,5; 6-tetrafluoro-4-(methoxy) phenyl) methyl] ester, 2,2-dimethyl-3-(1-acrylic) cyclopropane-carboxylic acid [(2,3; 5,6-tetrafluoro-4-aminomethyl phenyl) methyl] ester and 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid [(2; 3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester.

The method that compd B can pass through to describe among JP2006-63329 A1, the JP2001-11022 A1 etc. prepares.

As compd B, can use any compound of passing type (I) expression separately, also can use the mixture of two or more compounds.

Compd A and compd B have isomer, because they have asymmetric carbon, cyclopropane ring and carbon-to-carbon double bond.The compound that contains active isomer with arbitrary proportion can be used for the present invention.

In the present composition, the mass ratio of compd A and compd B is 50: 1 to 1: 50, preferred 20: 1 to 1: 20, and more preferably 20: 1 to 1: 10, more preferably 10: 1 to 1: 10 again.

The present composition has the control effect for the insect that comprises diptera (dipterous) insect.

Diptera (dipterous) insect comprises Dulicidae (mosquitoes), and (for example, Culex (Culices) is like Culex pipiens pallens (Culex pipiens pallens), Culex tritaeniorhynchus (Culex tritaeniorhynchus) and Culex quinquefasciatus (Culex quinquefasciatus); Aedes (Aedes spp.) is like Aedes aegypti (Aedesaegypti) and aedes albopictus (Aedes albopictus); Anopheles (Anopheles spp.) is like Anopheles sinensis (Anopheles sinensis); Chironomidae (Chironomidae)) and fly (flies) (housefly (Muscadomestica), north dwell housefly (Musca bezzi), false stable fly (Muscina stabulans), Fannia canicularis (Fannia canicularis), the different eye fly in East Asia (Megaselia spiracularis), Drosophila melanogaster (Drosophila melanogaster), Sepsidae (Sepsidae), Calliphoridae (Calliphorini) and Flesh flies (Sarcophagidae)).

Wherein, the present composition is preferably applied to diptera (dipterous) insect, more preferably fly (flies).

The present composition also has the working control effect to following arthropods (arthropods), and said arthropods (arthropods) comprising:

Pyralidae (Pyralidae) is like striped rice borer (Chilo suppressalis), cnaphalocrocis medinalls guenee (Cnaphalocrosis medinalis) and India paddy phycitid (Plodia interpunctella);

Noctuidae (Noctuidae) is like twill greedy noctuid (Spodoptera litura), mythimna separata (Pseudaletiaseparata) and tomato moth (Mamestra brassicae);

Sulfur butterfly (Pieridae) is like imported cabbageworm (Pieris rapae);

Tortricidae (Tortricidae) belongs to (Adoxophyes spp.) like Adoxophyes spp;

Moth fruit moth section (Carposinidae);

Lyonetid section (Lyonetiidae);

Inferior Euproctis flava (Artaxa subflava);

Gamma belongs to (Autographa sp.);

Ground Noctua (Agrotis spp.) insect such as white line dart moth of turnip (Agrotis segetum) and black cutworm (Agrotis ipsilon);

Bell Noctua (Helicoverpa spp.) insect;

Heliothis (Heliothis spp.) insect;

Rain moth section (Tineidae, clothes moths) is like diamond-back moth (Plutella Xylostella), straight burr rice hesperiidae (Parnara guttata), casemaking clothes moth (Tinea translucens) and curtain rain moth (Tineola bisselliella);

Blattaria (Blattodea) is like Groton bug (Blattella germanica), Peroplaneta fluligginosa (Periplaneta fuliginosa), American cockroach (Periplaneta americana), the big Lian of foxiness (Periplaneta brunnea) and oriental cockroach (Blatta orientalis);

Formicidae (Formicidae);

Vespidae (Vespidae);

Bethylidae (Bethylidae);

Swaflies (Tenthredinidae) is like Xinjiang cabbage sawfly (Athalia rosae);

Siphonaptera (Siphonaptera) is like ctenocephalides canis (Ctenocephalides canis), ctenocephalides felis (Ctenocephalides felis) and Pulex irritans (Pulex irritants);

Anoplura (Anoplura) is like humanlice (Pediculus humanus), hair lice (Phthirus pubis), head louse (Pediculus humanus capitis) and body louse (Pediculus humanus corporis);

Termitidae (termites) is like eastern subterranean termite (Reticulitermes speratus) and Taiwan formosanes (Coptotermes formosanus);

Delphacidae (Delphacidae) is like small brown rice planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens) and white back of the body rice fulgorid (Sogatella furcifera);

Angle top Cicadidae (Deltocephalidae) is like rice leafhopper (Nephotettix cincticeps) and nephotettix bipunctatus (Nephotettix virescens);

Aphidiadae (Aphididae);

Pentatomiddae (Pentatomidae);

Aleyrodidae (Aleyrodidae);

A red-spotted lizard section (Coccidae);

Cimicidae (cimices) is like bed bug (Cimex lectularius);

Tingidae (Tingidae);

Psyllidae (Psyllidae);

The chrysomelid genus of root firefly (Diabrotica spp.) is like black wool khapra beetle (Attagenus unicolor japonicusReitter), roundlet khapra beetle (Anthrenus verbasci (L.)), corn root firefly chrysomelid (Diabroticavirgifera virgifera) and cucumber 11 asterophyllite first food root subspecies (Diabrotica undecimpunctacahowardi);

Scarabaeidae (Scarabaeidae) is like bronze different beetle (Anomala cuprea) and polychrome different beetle (Anomala rufocuprea);

Curculionidae (weevils) as corn weevil (Sitophilus zeamais), rice water resemble (Lissorhoptrusoryzophilus), cotton boll resembles (Anthonomus grandis) and adzuki bean weevil (Callosobruchuyschienensis);

TRenebrionidae (Tenebrionidae) is like bloom first (Tenebrio molitor) and red flour beetle (Tribolium castaneum);

Chrysomelidae (Chrysomelidae) is like Oulema oryzae (Oulema oryzae), Phyllotreta striolata (Phyllotreta striolata) and aulacophora femoralis (Aulacophora femoralis);

Anobiidae (Anobiidae);

Epilachna genus (Epilachna spp.) is like ladybug of eggplant 28 stars (Epilachnavigintioctopunctata);

Lyctus brunneus Stephens (Lyctus brunneus);

Bostrichidae (Bostrychidae);

Cerambycidae (Cerambycidae);

Latent wing first section (Staphylinidae) is like Paederus fuscipes Curtis (Paederus fuscipes);

Thripidae (Thripidae) is like palm thrips (Thrips palmi), Frankliniella occidentalis (Frankliniellaoccidentalis), yellow chest thrips (Thrips hawaiiensis);

African mole cricket (Gryllotalpa africana);

Locust Superfamily (Acridioidea);

Pyroglyphidae (Pyroglyphidae) is like dust mite (Dermatophagoides farinae) and dermatophagoides pteronyssinus (Dermatophagoides ptrenyssnus);

Tyroglyphidae (Acaridae) is had a liking for flour mite (Aleuroglyphus ovatus) like tyrophagus putrescentiae (Tyrophagus putrescentiae) and ellipse;

Eat sweet mite section (Glycyphagidae) and eat sweet mite (Glycyphagus privatus), family food sweet mite (Glycyphagus domesticus) and family food sweet mite (Glycyphagus destructor) like secret;

Cheyletidae (Cheyletidae) is like Malacca cheyletid mite (Cheyletus malaccensis) and Meng Shi cheyletid mite (Cheyletus malaccesis);

Tarsonemidae (Tarsonemidae);

Have a liking for careless mite section (Chortoglyphidae);

Simple seam first mite (Haplochthonius simplex Willman);

Tetranychidae (Tetranychidae) is like Tetranychus urticae (Tetranychus urticae), refreshing Ze Shi tetranychid (Tetranychus kanzawai), panonychus citri (Panonychus citri) and panonychus ulmi (Panonychus ulmi);

Hard tick section (Ixodidae) is like haemaphysalis longicornis (Haemaphysalis longicornis);

Dermanyssidae (Dermanyssidae) is like northern fowl mite (Ornithonyssus sylvairum) and Dermanyssus gallinae (Dermanyssus gallinae).

The present composition can be the mixture former state of compd A and compd B, and it can also contain other components with the amount that does not make insect control deleterious.The present composition can be the preparation that contains except that compd A and other components the compd B.

Examples of formulations comprises: finish, emulsifiable concentrates, wetting powder, flowable (suspension concentrating agents, emulsion etc.), microcapsules, pulvis, granula, tablet, aerosol, carbon dioxide gas body preparation, heated volatile fumigant (insecticidal incense coil, electric insecticidal incense, imbibition core pattern heating fumigating agrochemical), piezoelectric type insecticide, smoking insecticide (spontaneous combustion type smoking insecticide, chemical reaction type smoking insecticide, porous ceramic plate smoking insecticide etc.), fumigant (no thermal evaporation) (resin fumigant, paper fumigant, nonwoven fumigant, knitting and weaving thing fumigant etc.), aerosol (aerosol etc.), ULV agent, contact insecticide (insect protected sheet, fly net) and poison bait.

Depend on dosage form, these preparations comprise compd A and the compd B that common total amount is 0.001 to 98 weight %.

Said preparation can prepare through for example following method:

(1) method that may further comprise the steps: compd A and compd B are mixed with solid carrier, liquid-carrier, gaseous carrier, bait etc.; And if desired; Be used for the adjuvant of preparation to wherein adding surfactant with other, process resulting mixture afterwards.

(2) method that may further comprise the steps: compd A and compd B are impregnated in the base material.

(3) method that may further comprise the steps: compd A, compd B and base material are mixed, afterwards this mixture is passed through mould process.

The instance of the solid carrier that in preparationization, uses comprises: by the fine powder and the granular materials of formations such as clay (kaolin, diatomite, bentonite, Fubasami clay, acid clay etc.), the hydrated silica that synthesizes, talcum, pottery, other inorganic minerals (sericite, quartz, sulphur, active carbon, calcium carbonate, hydrated SiO 2 etc.), chemical fertilizer (ammonium sulfate, ammonium phosphate, ammonium nitrate, ammonium chloride, urea etc.); Be the material (2 of solid at normal temperatures; 4; 6-triisopropyl-1; 3,5-three

alkane, naphthalene, paracide, camphor, adamantane etc.); And felt, fiber, cloth, knitted fabric, sheet material, paper, silk thread, foaming body, porous body and by one in the following or the multinomial multifilament of forming: hair, silk, cotton, fiber crops, paper pulp, synthetic resin (for example, polyvinyl resin such as low density polyethylene (LDPE), LLDPE, high density polyethylene (HDPE) etc.; Ethylene-vinyl ester copolymer such as vinyl-vinyl acetate copolymer; Ethylene-methyl acrylate copolymer such as ethylene-methyl methacrylate methyl terpolymer and ethylene-methyl methacrylate ethyl ester copolymer; Vinyl-acrylate copolymer such as ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; Vinyl-vinyl polymers of carboxylic acid such as ethylene-acrylic acid copolymer; Ethene-tetracyclododecen copolymer; Acrylic resin such as Noblen and propylene-ethylene copolymers; Gather-4-methylpentene-1, PB Polybutene-1, polybutadiene, polystyrene; Acrylonitrile-styrene resin; Styrene-the conjugated diene block copolymer of styrenic elastomer such as acrylonitrile-butadiene-styrene resin, styrene-conjugated diene block copolymer and hydrogenation; Fluororesin; Acrylic resin such as polymethyl methacrylate; Polyamide such as nylon 6 and nylon 66; Mylar such as PETG, PEN, polybutylene terephthalate (PBT) and polyeyclohexylenedimethylene terephthalate; The polyurethane of porous resin such as Merlon, polyacetals, polypropylene sulfone (polyacrylsulfone), polyarylate, hydroxybenzoic acid polyester, PEI, PEI, polyestercarbonate, polyphenylene oxide resin, polyvinyl chloride, polyvinylidene chloride, polyurethane, foaming, the polypropylene of foaming and the polyethylene of foaming), glass, metal and pottery.

The instance of liquid-carrier comprises: aromatics or aliphatic hydrocarbon (xylol, toluene, Fluhyzon, phenyl xylyl ethane, kerosene, light oil, hexane, cyclohexane etc.), halogenated hydrocarbons (chlorobenzene, carrene, dichloroethane, trichloroethanes etc.), alcohol (methyl alcohol, ethanol, isopropyl alcohol, butanols, hexanol, benzylalcohol, ethylene glycol etc.), ether (diethyl ether, glycol dimethyl ether, diethylene glycol monomethyl ether, carbitol, propane diols monomethyl ether, oxolane, two

alkane etc.), ester (ethyl acetate, butyl acetate etc.), ketone (acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), cyclohexanone etc.), nitrile (acetonitrile, isobutyronitrile etc.), sulfoxide (methyl-sulfoxide etc.), acid amides (N; Dinethylformamide, DMAC N,N, N-methyl-pyrrolidones etc.), alkylene carbonate class (propylene carbonate etc.), plant oil (soya-bean oil, cottonseed wet goods), plants essential oil (orange oil, oil of hyssop, lemon wet goods) and water.

The instance of gaseous carrier comprises: butane gas, Freon gas, liquefied petroleum gas (LPG), dimethyl ether and carbon dioxide.

The instance of surfactant comprises: the salt of alkyl sulfate, alkylsulfonate, alkylaryl sulfonates, alkyl aryl ether, polyoxyethylene thing, polyglycol ether, polyol ester and the sugar alcohol derivant of alkyl aryl ether.

Other auxiliary agents that are used for preparation comprise: sticking agent, dispersant and stabilizing agent; Particularly, casein, gelatin, polysaccharide (starch, gum Arabic, cellulose derivatives, alginic acid etc.), lignin derivative, bentonite, carbohydrate, synthetic water-soluble polymer (polyvinyl alcohol, PVP), polyacrylic acid etc.; BHT (2,6-two-tert-butyl group-4-methylphenol) and BHA (mixture of the 2-tert-butyl group-4-metoxyphenol and the 3-tert-butyl group-4-metoxyphenol).

The instance that is used for the base material of insecticidal incense coil comprises: plant powder (powder of promptly being processed by plant) is like the mixture of wood powder and perian insect powder pomace and adhesive such as Tabu powder (that is the powder of, being processed by red nanmu (Machilus thunbergii)), starch and gluten.

The instance of the base material of desinsection electric mat comprises: the plate object that obtains through the sclerosis cotton linters, and through the plate object of sclerosis cotton linters with the fibrillation acquisition of the mixture of paper pulp.

The instance of spontaneous combustion type base material comprises: burning exothermic agent such as nitrate, nitrite, guanidinesalt, potassium chlorate, nitrocellulose, ethyl cellulose and wood powder; Thermolysis promoter such as alkali metal salt, alkali salt, bichromate and chromate; The carrier of oxygen such as potassium nitrate; Comburant such as melamine and wheaten starch; Incremental agent such as diatomite; And adhesive such as synthetic adhesive.

The instance of the base material of chemical reaction type smoking insecticide comprises: exothermic agent such as alkali metal sulphide, polysulfide and sulfhydrate and calcium oxide; Catalyzer such as carbonaceous material, cementite and activated earth; Organic foaming agent such as Celogen Az, benzene sulfonyl hydrazide, dinitropentamethylenetetramine, polystyrene and polyurethane; And filler such as native fiber segment and synthetic fibers segment.

The instance of the base material of resin fumigant comprises: polyvinyl resin such as low density polyethylene (LDPE), LLDPE and high density polyethylene (HDPE); Ethylene-vinyl ester copolymer such as vinyl-vinyl acetate copolymer; Ethylene-methyl acrylate copolymer such as ethylene-methyl methacrylate methyl terpolymer and ethylene-methyl methacrylate ethyl ester copolymer; Vinyl-acrylate copolymer such as ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; Vinyl-vinyl polymers of carboxylic acid such as ethylene-acrylic acid copolymer; Ethene-tetracyclododecen copolymer; Acrylic resin such as acrylic polymers and propylene-ethylene copolymers; Gather-4-methylpentene-1, PB Polybutene-1, polybutadiene, polystyrene, acrylonitrile-styrene resin; Styrene-the conjugated diene block copolymer of styrenic elastomer such as acrylonitrile-butadiene-styrene resin, styrene-conjugated diene copolymer and hydrogenation; Fluororesin; Acrylic resin such as polymethyl methacrylate; Polyamide such as nylon 6 and nylon 66; Mylar such as PETG, PEN, polybutylene terephthalate (PBT) and polyeyclohexylenedimethylene terephthalate; Merlon, polyacetals, polypropylene sulfone, polyarylate, hydroxybenzoic acid polyester, PEI, polyestercarbonate, polyphenylene oxide resin, polyvinyl chloride, polyvinylidene chloride and polyurethane.

These base materials can use separately or use with its two or more mixture, and in these base materials, if desired, can add plasticizer such as phthalic acid ester (repefral, dioctyl phthalate etc.), adipic acid and stearic acid.Can through with compd A and compd B is mediated in the above-mentioned base material and afterwards through injection-molded, extrusion molding, dull and stereotyped pressing mold etc. to carrying out the molded resin fumigant that obtains through the material of mediating.

If desired, also can be further through as step such as molded, cutting resulting resin formulation is processed as definite shape such as plate, film, band, net and line.These resin formulation are processed into, and for example, Animal neck ring, animal ear tag, tablet, lure messenger or gardening to use post.

The instance of the base material of poison bait comprises: bait composition such as grain dust, vegetable oil, carbohydrate and avicel cellulose; Antioxidant such as dibutyl hydroxy toluene and NDGA; Preservative such as dehydroactic acid; Be used to the reagent such as the chilli powder that prevent that children and pet accident from ingesting; Insect attracts spices such as cheese spices, onion spice and peanut oil.

Method of the present invention comprises that the present composition with effective dose is applied to the place that insect or insect perch.

In this method, the present composition can be aforesaid preparation.

The insect that is applicable to this method is preferably diptera (dipterous) insect, more preferably fly.

The instance that uses fly is explained method of the present invention, but this method can be applicable to other insects except that fly with following identical mode.

The method of using the present composition comprises following method, these methods can depend on embodiment, to use the place etc. of said composition and suitably select.

(1) comprises the method for handling the place that fly or fly perch according to original state with the present composition.

(2) comprise the present composition is diluted with solvent such as water, and the method in the place of afterwards resulting solution spray to fly or fly being perched.

In method (2), preferably will comprise the present composition dilution that has been configured to emulsifiable concentrates, wetting powder, flowable, microcapsules etc., so that the total concentration of compd A and compd B finally is 0.01 to 1000ppm.

(3) comprise the heating present composition and the method that active component is volatilized in the place that fly perches.

In method (3), the amount of application of compd A and compd B and application concentration can depend on the present composition embodiment, its administration period, it uses place, its application process, injury situation etc. and confirms.

When the present composition was used for pandemic preparedness, its amount of application when being applied to the space, was generally 0.0001 to 1000mg/m in the amount of compd A and compd B ³, and when being applied to the plane, be generally 0.0001 to 1000mg/m ²In heat is volatilized using of fumigant such as insecticidal incense coil or electric mat, depend on its dosage form, active component passes through heated volatile.For example; Can through with its according to original state be placed in the space that will use; Perhaps air is blown the mode to the preparation, use fumigant (not having the heat volatilization), like resin formulation, made of paper dose, tablet, nonwoven preparation, knitting and weaving thing preparation or thin slice preparation.

Wherein using the space that the present composition is used for pandemic preparedness comprises: closet, wardrobe, hanging cupboard, cabinet drawer, cupboard, toilet, bathroom, broom closet, living room, dining room, warehouse and automotive interior.In addition, also can Pesticidal combination of the present invention be used in outdoor open space.

When Pesticidal combination of the present invention is used to control the vermin of domestic animal such as ox, horse, pig, sheep, goat, chicken etc. and meiofauna such as dog, cat, rat, mouse etc., can apply it on the animal through well-known method in the veterinary medicine.Particularly, be used to use the method for Pesticidal combination of the present invention following.For whole body control, Pesticidal combination is with following form administration, for example, tablet, with mixture, suppository or the injection (for example intramuscular dose, hypodermic injection agent, intravenous injection or lumbar injection agent) of feed.For non-whole body control; Pesticidal combination uses through following method: the form as with finish or water-based liquor is sprayed; Flow coat (pour-on) or spot printing with the form of finish or water-based liquor are handled; Wash animal with the hair washing preparation, perhaps the resin volatilizer with the form of necklace or ear tag is attached on the animal.When Pesticidal combination of the present invention during to animals administer, the total amount of ester compounds A and ester compounds B is usually 0.01 to 1, in the scope of 000mg/kg the weight of animals.

Embodiment

To illustrate in greater detail the present invention through following FORMULATION EXAMPLE and test example, but scope of the present invention is not limited to these embodiment.

At first, provide the FORMULATION EXAMPLE of the present composition.In these embodiment, only if outside clearly showing, umber all in mass.

In FORMULATION EXAMPLE, with (1R)-trans-2,2-dimethyl-3-(1-acrylic (E/Z=1/8)) cyclopropane-carboxylic acid [(2,3; 5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester is called compound B-11, with 2; 2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid [(2,3,5; 6-tetrafluoro-4-(methoxy) phenyl) methyl] ester is called compd B 2, and with (1R)-trans-2,2-dimethyl-3-(1-acrylic (E/Z=1/8)) cyclopropane-carboxylic acid [(2; 3,5,6-tetrafluoro-4-aminomethyl phenyl) methyl] ester is called compd B 3.

FORMULATION EXAMPLE 1

The compound B-11 of nine (9) parts compd As and 0.9 part is dissolved in 37.5 parts xylol and 37.5 parts N, in the dinethylformamide.Add 9.1 parts polyoxygenated ethylidene styryl phenyl ether and 6 parts calcium dodecyl benzene sulfonate to it, afterwards they are stirred and abundant the mixing to obtain emulsifiable concentrates.

FORMULATION EXAMPLE 2

Add 5 parts Solpol 5060 (registration mark of eastern nation's chemistry (Toho Chemical Industry Co.Ltd.)) to the compound B-11 of 20 parts compd As and 20 parts, afterwards it is fully mixed.Afterwards with 32 parts the Carplex#80 (registration mark of Shionogi (Shionogi & Co.Ltd.); The synthetic hydrated silica fine powder) and 23 parts 300 order diatomite add wherein, through juice-mixer (juice mixer) it is mixed to obtain wetting powder afterwards.

FORMULATION EXAMPLE 3

In the compound B-11 of 3 parts compd As and 0.3 part, add 5 parts synthetic hydrated silica fine powder, 5 parts neopelex, 30 parts bentonite and 56.7 parts clay, afterwards their are stirred and fully mix.Next the water that adds appropriate amount stirs and afterwards through the comminutor granulation, under ventilating, is dried to obtain granule afterwards.

FORMULATION EXAMPLE 4

Five (5) parts compd As, 0.5 part compound B-11,1 part synthetic hydrated silica fine powder, 1 part Driless B as flocculant (by three society (Sankyosha Co.Ltd) productions altogether) and 7 parts clay are fully mixed in mortar, pass through juice-mixer afterwards its stirring and mixing.Clay with 85.5 parts chopping adds wherein afterwards, afterwards their is stirred and fully mixes to obtain pulvis.

FORMULATION EXAMPLE 5

Ten (10) parts compd As, 1 part compound B-11, half amount of 35 parts are mixed for the water of the white carbon of polyoxyethylene alkyl ether ammonium sulfate and 54 parts, and pulverized well with the acquisition pulvis through the case of wet attrition method.

FORMULATION EXAMPLE 6

The compound B-11 of the compd A of zero point zero five (0.05) part and 0.1 part is dissolved in 10 parts the carrene; Isoparaffic solvent (Isopar M, the registration mark of exxon chemical company (Exxon Chemical Company)) with them and 89.85 parts mixes to obtain finish afterwards.

FORMULATION EXAMPLE 7

0. 1 (0.1) parts compd As, 0.05 part compound B-11 and 49.85 parts Neothiozol (are changed into (the Chuo Kasei Co. of Co., Ltd. by central authorities; Ltd.) manufacturing) in the aerosol container of packing into; Aerosol valve is installed on this jar; In the LPG tank filling with 25 parts dimethyl ether and 25 parts, afterwards it is shaken afterwards.Afterwards actuator is installed on this jar, obtains the oiliness aerosol.

FORMULATION EXAMPLE 8

To contain 0.5 part compd A, 0.05 part compound B-11,0.01 part BHT, 5 parts xylol, 3.44 parts the distilled water of mixture and 50 parts of emulsifier { Atmos 300 (registration mark of AtmosChemical Company) } of deodorized kerosine and 1 part packs in the aerosol container; This container is with valve part; And 40 parts propellant (LPG) is packed into wherein under pressure through this valve, obtain water-borne aerosol.

FORMULATION EXAMPLE 9

The paper products sheet that will have the honeycomb of 0.5cm (thickness) x69cm (length) x0.2cm (width) is rolled the carrier that has the near cylindrical of 5.5cm diameter and 0.2cm height with making from an end.The solution of the appropriate amount that the compound B-11 of compd A and 0.5 part that will be through 5 parts of dissolvings in 94.5 parts acetone prepares is coated to carrier equably, and the air dry acetone obtains the paper fumigant afterwards.

FORMULATION EXAMPLE 10

With three dimensional needle fabric (trade name: Fusion, model: AKE69440, dealer: Asahi Chemical Ind (Asahi Kasei Fibers Corporation), thickness: 4.3mm, basic weight: 321g/m ², process by polyamide) and cut into sub-circular with 5cm diameter.The solution of the appropriate amount that the compound B-11 of compd A and 0.5 part that will be through 5 parts of dissolvings in 94.5 parts acetone prepares is coated to the three dimensional needle fabric of cutting-out equably, and the acetone in the air drying composite obtains knitting and weaving thing fumigant afterwards.

FORMULATION EXAMPLE 11

Ethylene-methyl methacrylate methyl terpolymer (methyl methacrylate content: 10 weight % with 97 eight (97.8) weight portions; MFR=2 (g/10 minute)), the compound B-11 of 2 parts compd A and 0.2 part through

equidirectional rotation (co-rotation) double screw extruder 130 ℃ of following melt kneading; Through extruder further melt kneading under 150 ℃; Extrude from the T die and to be sheet shape; And, obtain the resin fumigant through the chill roll cooling.

FORMULATION EXAMPLE 12

Vinyl-vinyl acetate copolymer (vinyl acetate content: 10 weight % with 97 eight (97.8) weight portions; MFR=2 (g/10 minute)), the compound B-11 of 2 parts compd A and 0.2 part through equidirectional Rotating Double screw extruder 130 ℃ of following melt kneading; Through

extruder further melt kneading under 150 ℃; Extrude from the T die and to be sheet shape; And, obtain the resin fumigant through the chill roll cooling.

FORMULATION EXAMPLE 13

The compound B-11 of five (5) parts compd As and 0.5 part is dissolved in 94.5 parts the acetone.The resulting solution of appropriate amount is applied to the paper (2000cm with folding structure ²), the acetone in the air drying solution obtains the paper fumigant afterwards.

FORMULATION EXAMPLE 14

The compound B-11 of three (3) parts compd As and 0.3 part is dissolved in 14.6 parts the acetone to obtain solution.In resulting solution, add 0.2 part zinc oxide, 1.0 parts α starch and 42.8 parts Celogen Az and add 38.1 parts water afterwards.Resulting mixture is mediated and is made as through extruder die granular, be dried afterwards, obtain pellet.This pellet is contained in the upper space of the container that dividing wall that core processes through aluminium separates, and the calcium oxide of 50g is contained in the lower space of this container, obtain smoking insecticide.

FORMULATION EXAMPLE 15

0. 5 (0.5) parts zinc oxide, 2 parts α starch and 97.5 parts Celogen Az are mixed.To wherein adding entry and this mixture being mediated, the material of being mediated is made as granular, and dry through extruder die to obtain pellet.On this pellet of 2g, the acetone soln of the compound B-11 of the infiltration compd A that contains 0.58g and 0.058g equably, and dry afterwards with the acquisition pellet.This pellet is contained in the upper space of the container that dividing wall that core processes through aluminium separates, and the calcium oxide of 50g is contained in the lower space of this container, obtain smoking insecticide.

FORMULATION EXAMPLE 16

The compd A of 0. 5 (0.5) g and the compound B-11 of 0.05g are dissolved in the acetone of 20mL; The mosquito-repellent incense that resulting solution is added to 99.4g is with the mixture of carrier (Tabu powder: perian insect powder pomace: the weight ratio of wood powder is 4: 3: 3 a mixture) with the green colouring material of 0.3g; They are stirred and mixing equably; And the water with 120mL adds wherein afterwards, afterwards mixture is fully mediated.The material of being mediated is molded and dry to obtain mosquito-repellent incense.

FORMULATION EXAMPLE 17

Ten (10) parts compd As, 1 part compound B-11,39.5 parts acetyl tributyl citrate, 39.5 parts adipic acid ester in the different ninth of the ten Heavenly Stems, 5 parts blue dyes and 5 parts stacte are mixed to obtain solution.The electric mat that this solution is infiltrated up to equably 3.4cmx2.1cmx thickness 0.22cm is gone up with the acquisition electric mat with base material (becoming tabular the acquisition through fibrillation sclerosis with the mixture of cotton linters and paper pulp).

FORMULATION EXAMPLE 18

The compound B-11 of 0. 1 (0.1) parts compd As and 0.01 part is dissolved in 99.89 parts the deodorized kerosine, this solution is encased in the vinyl chloride container.Can the wick of its top heating (the inorganic powder sclerosis through will having adhesive and obtain its sintering) be inserted this container to obtain to be used for the parts of imbibition core pattern heated volatile fumigant through heater.

FORMULATION EXAMPLE 19

The compd A of point two (0.2) part, 0.02 part compound B-11 and 49.78 parts Neothiozol (are changed in Co., Ltd.'s (Chuo Kasei Co. Ltd.) produces) aerosol container of packing into by central authorities.Aerosol valve is installed on this jar.In the LPG tank filling with 25 parts dimethyl ether and 25 parts, afterwards it is shaken afterwards.The actuating agent that afterwards, will be used for total amount injection type aerosol is contained in jar goes up to obtain aerosol.

FORMULATION EXAMPLE 20

In the compound B-11 of 0.2 part compd A and 0.02 part, add 99.78 parts diethylene glycol monoethyl ether, afterwards their are stirred and fully mix to obtain to be used to control the some paint of the epizoon of animal.

FORMULATION EXAMPLE 21

With 2,4 of four (4) g, 6-triisopropyl-1,3,5-three

Alkane compression molding (4t/cm ²) to obtain discoid solid (diameter: 3cm, thickness: 3mm), and the solution of being made up of 3 parts compd A, 0.3 part the acetone of compound B-11 and 96.7 parts of 1mL provided to this solid equably, and dry afterwards to obtain tablet.

FORMULATION EXAMPLE 22

With 2,4 of the compound B-11 of the compd A of 0.2g, 0.02g and 4g, 6-triisopropyl-1,3,5-three

Homogeneous mixture compression molding (the 4t/cm of alkane ²) be discoid solid (diameter: 3cm, thickness: 3mm) obtain tablet.

FORMULATION EXAMPLE 23

With 2 of the compound B-11 of the compd A of point two (0.2) g, 0.02g and 4g; 4; 6-triisopropyl-1,3,5-three

alkane are packed in the 50mL screwed pipe; Heat fused, and be cooled to room temperature afterwards to obtain tablet.

FORMULATION EXAMPLE 24

The compd B 2 of nine (9) parts compd As and 0.9 part is dissolved in 37.5 parts xylol and 37.5 parts N, in the dinethylformamide.Add 9.1 parts polyoxygenated ethylidene styryl phenyl ether and 6 parts calcium dodecyl benzene sulfonate to it, and they are fully stirred and mix, obtain emulsifiable concentrates.

FORMULATION EXAMPLE 25

The Solpol 5060 (registration mark of eastern nation's chemistry (Toho Chemical Industry Co.Ltd.)) that in the compd B 2 of 20 parts compd As and 20 parts, adds 5 parts fully mixes it afterwards.Afterwards 32 parts Carplex#80 (registration mark of Shionogi (Shionogi & Co.Ltd.), synthetic hydrated silica fine powder) and 23 parts 300 order diatomite are added wherein, through juice-mixer it is mixed afterwards, obtain wetting powder.

FORMULATION EXAMPLE 26

In the compd B 2 of 3 parts compd As and 0.3 part, add 5 parts synthetic hydrated silica fine powder, 5 parts neopelex, 30 parts bentonite and 56.7 parts clay, afterwards their are stirred and fully mix.Next the water that adds appropriate amount stirs and through the comminutor granulation, under ventilating, is dried afterwards, obtains granule.

FORMULATION EXAMPLE 27

With five (5) parts compd As, 0.5 part 2,1 part of compd B the synthetic hydrated silica fine powder, 1 part the Driless B as flocculant (by three altogether societies (Sankyosha Co.Ltd) make) fully mix in mortar with 7 parts clay, pass through juice-mixer afterwards with its stirring and mixing.The clay that adds 85.5 parts chopping afterwards stirs them and fully mixing afterwards, obtains pulvis.

FORMULATION EXAMPLE 28

Ten (10) parts compd As, half amount of 2,35 parts of compd Bs of 1 part are mixed for the water of the white carbon of polyoxyethylene alkyl ether ammonium sulfate and 54 parts, pulverize well with the acquisition pulvis through the case of wet attrition method afterwards.

FORMULATION EXAMPLE 29

The compd B 2 of the compd A of zero point zero five (0.05) part and 0.1 part is dissolved in 10 parts the carrene and afterwards with isoparaffic solvent (the Isopar M of itself and 89.85 parts; The registration mark of Exxon chemistry (Exxon Chemical)) mixes, obtain finish.

FORMULATION EXAMPLE 30

0. 1 (0.1) parts compd As, 0.05 part compd B 2 and 49.85 parts Neothiozol (are changed in Co., Ltd.'s (Chuo Kasei Co. Ltd.) makes) aerosol container of packing into by central authorities.Aerosol valve is installed on this jar.In the LPG tank filling with 25 parts dimethyl ether and 25 parts, afterwards it is shaken afterwards.Actuator is installed on this jar, obtains the oiliness aerosol.

FORMULATION EXAMPLE 31

To pack in the aerosol container by 0.5 part compd A, 0.05 part the distilled water of BHT, 5 parts xylol, mixture that 3.44 parts the emulsifier { Atmos 300 (registration mark of Atmos ChemicalCompany) } of deodorized kerosine and 1 part constitutes and 50 parts of 2,0.01 part of compd B.Valve part is installed on this container, and under pressure, 40 parts propellant (LPG) is packed into wherein, obtain water-borne aerosol through this valve.

FORMULATION EXAMPLE 32

The paper products sheet that will have the honeycomb of 0.5cm (thickness) x69cm (length) x0.2cm (width) is rolled the carrier that has the near cylindrical of 5.5cm diameter and 0.2cm height with making from an end.The solution that the compd B 2 of the compd A that passes through in 94.5 parts acetone 5 parts of dissolvings of appropriate amount and 0.5 part prepare is applied to carrier equably, the acetone in the air drying solution afterwards, acquisition paper fumigant.

FORMULATION EXAMPLE 33

With three dimensional needle fabric (trade name: Fusion, model: AKE69440, retail trader: Asahi Chemical Ind (Asahi Kasei Fibers Corporation), thickness: 4.3mm, fabric weight (metsuke): 321g/m ², process by polyamide) and be cut into sub-circular with 5cm diameter.The solution that the compd B 2 of the compd A that passes through in 94.5 parts acetone 5 parts of dissolvings of appropriate amount and 0.5 part prepare is applied to the three dimensional needle fabric of cutting-out equably, and the acetone in the air drying solution is with acquisition knitting and weaving thing fumigant afterwards.

FORMULATION EXAMPLE 34

Ethylene-methyl methacrylate methyl terpolymer (methyl methacrylate content: 10 weight % with 97 eight (97.8) weight portions; MFR=2 (g/10 minute)); The compd B 2 of 2 parts compd A and 0.2 part through equidirectional Rotating Double screw extruder 130 ℃ of melt kneading; Through

extruder 150 ℃ of further melt kneading; Extrude from the T die and to be sheet shape; And, obtain the resin fumigant through the chill roll cooling.

FORMULATION EXAMPLE 35

Vinyl-vinyl acetate copolymer (vinyl acetate content: 10 weight % with 97 eight (97.8) weight portions; MFR=2 (g/10 minute)), the compd B 2 of 2 parts compd A and 0.2 part through equidirectional Rotating Double screw extruder 130 ℃ of melt kneading; Through

extruder 150 ℃ of further melt kneading; Extrude from the T die and to be sheet shape; And, obtain the resin fumigant through the chill roll cooling.

FORMULATION EXAMPLE 36

The compd B 2 of five (5) parts compd As and 0.5 part is dissolved in 94.5 parts the acetone.The resulting solution of appropriate amount is applied to the paper (2000cm with folding structure ²), the acetone in the air drying solution obtains the paper fumigant afterwards.

FORMULATION EXAMPLE 37

The compd B 2 of three (3) parts compd As and 0.3 part is dissolved in 14.6 parts the acetone to obtain solution.Afterwards 0.2 part zinc oxide, 1.0 parts α starch and 42.8 parts Celogen Az are added wherein; And the water that adds 38.1 parts further; And it is resulting mixture is mediated, be made as grain shape, and dry to obtain pellet through extruder die.This pellet is contained in the upper space of the container that dividing wall that core processes through aluminium separates, and the calcium oxide of 50g is contained in the lower space of this container, obtain smoking insecticide.

FORMULATION EXAMPLE 38

0. 5 (0.5) parts zinc oxide, 2 parts the Celogen Az of α starch and 97.5 parts are mixed, to wherein adding entry, and mixture is mediated, and will be made as granular, and dry through extruder die through the material of mediating to obtain pellet.On this pellet of 2g, the acetone soln of the compd B 2 of the infiltration compd A that contains 0.58g and 0.058g equably, and dry afterwards with the acquisition pellet.This pellet is contained in the upper space of the container that dividing wall that core processes through aluminium separates, and the calcium oxide of 50g is contained in the lower space of this container, obtain smoking insecticide.

FORMULATION EXAMPLE 39

The compd A of 0. 5 (0.5) g and the compd B 2 of 0.05g are dissolved in the acetone of 20mL; Resulting solution is added in the mixture of mosquito-repellent incense with the green colouring material of carrier (Tabu powder: perian insect powder pomace: the weight ratio of wood powder is 4: 3: 3 a mixture) and 0.3g that contains 99.4g; They are stirred equably and mix, the water of 120mL is added wherein, and this mixture is fully mediated; Afterwards that the material of mediating is molded and be dried, obtain mosquito-repellent incense.

FORMULATION EXAMPLE 40

Ten (10) parts compd As, 1 part acetyl tributyl citrate, 39.5 parts adipic acid ester in the different ninth of the ten Heavenly Stems, 5 parts blue dyes and 5 parts the stacte of 2,39.5 parts of compd Bs are mixed to obtain solution.The electric mat that this solution is infiltrated up to equably 3.4cmx2.1cmx0.22cm thickness obtains electric mat with on the base material (fibrillation through with the mixture of cotton linters and paper pulp is hardened to tabular).

FORMULATION EXAMPLE 41

The compd B 2 of 0. 1 (0.1) parts compd As and 0.01 part is dissolved in 99.89 parts the deodorized kerosine.Resulting solution is packed in the vinyl chloride container; And can the wick of its top heating (the inorganic powder sclerosis through will having adhesive and obtain its sintering) be inserted in this container through heater, obtain to be used for the parts of imbibition core pattern heated volatile fumigant.

FORMULATION EXAMPLE 42

The compd A of point two (0.2) part, 0.02 part compd B 2 and 49.78 parts Neothiozol (are changed in Co., Ltd.'s (Chuo Kasei Co. Ltd.) makes) aerosol container of packing into by central authorities.Aerosol valve is installed on this jar, and the LPG of 25 parts dimethyl ether and 25 parts is packed in this jar, afterwards it is shaken.The actuating agent that will be used for total amount injection type aerosol afterwards is contained in jar, obtains aerosol.

FORMULATION EXAMPLE 43

In the compd B 2 of 0.2 part compd A and 0.02 part, add 99.78 parts diethylene glycol monoethyl ether, afterwards their are stirred and fully mix, obtain to be used to control the spot printing preparation of the epizoon of animal.

FORMULATION EXAMPLE 44

With 2,4 of four (4) g, 6-triisopropyl-1,3,5-three

Alkane compression molding (4t/cm ²) to obtain discoid solid (diameter: 3cm, thickness: 3mm), and the solution of being made up of 3 parts compd A, 0.3 part the acetone of compd B 2 and 96.7 parts of 1mL provided to the disc solid equably, be dried afterwards, obtain tablet.

FORMULATION EXAMPLE 45

To contain 0.2g compd A, 0.02g compd B 2 and 4g 2,4,6-triisopropyl-1,3,5-three

Homogeneous mixture compression molding (the 4t/cm of alkane ²) be discoid solid (diameter: 3cm, thickness: 3mm), obtain tablet.

FORMULATION EXAMPLE 46

With 2 of the compd B 2 of the compd A of point two (0.2) g, 0.02g and 4g; 4; 6-triisopropyl-1,3,5-three

alkane are packed in the 50mL screwed pipe and heat fused; And be cooled to room temperature afterwards, obtain tablet.

FORMULATION EXAMPLE 47

The compd B 3 of nine (9) parts compd As and 0.9 part is dissolved in 37.5 parts xylol and 37.5 parts N, in the dinethylformamide.Add 9.1 parts polyoxygenated ethylidene styryl phenyl ether and 6 parts calcium dodecyl benzene sulfonate to it, afterwards it is fully stirred and mix, obtain emulsifiable concentrates.

FORMULATION EXAMPLE 48

In the compd B 3 of 20 parts compd As and 20 parts, add 5 parts Solpol 5060 (registration mark of eastern nation's chemistry (Toho Chemical Industry Co.Ltd.)), afterwards it is fully mixed.To wherein adding 32 parts Carplex#80 (registration mark of Shionogi (Shionogi & Co.Ltd.), synthetic hydrated silica fine powder) and 23 parts 300 order diatomite, through juice-mixer it is mixed afterwards, obtain wetting powder.

FORMULATION EXAMPLE 49

In the compd B 3 of 3 parts compd As and 0.3 part, add 5 parts synthetic hydrated silica fine powder, 5 parts neopelex, 30 parts bentonite and 56.7 parts clay, afterwards their are stirred and fully mix.Next the water with appropriate amount adds wherein and stirring afterwards.In addition resulting mixture is granulated through comminutor, under ventilating that this granular product is dry afterwards, obtain granule.

FORMULATION EXAMPLE 50

With five (5) parts compd As, 0.5 part 3,1 part of compd B the synthetic hydrated silica fine powder, 1 part the Driless B as flocculant (by three altogether societies (Sankyosha Co.Ltd) produce) fully mix in mortar with 7 parts clay, pass through juice-mixer afterwards with its stirring and mixing.Add the clay of 85.5 parts chopping to resulting mixture, afterwards their are stirred and fully mix, obtain pulvis.

FORMULATION EXAMPLE 51

Ten (10) parts compd As, half amount of 3,35 parts of compd Bs of 1 part are mixed for the water of the white carbon of polyoxyethylene alkyl ether ammonium sulfate and 54 parts, through the case of wet attrition method it is pulverized well the acquisition pulvis afterwards.

FORMULATION EXAMPLE 52

The compd B 3 of the compd A of zero point zero five (0.05) part and 0.1 part is dissolved in 10 parts the carrene; And isoparaffic solvent (Isopar M with resulting solution and 89.85 parts; The registration mark of Exxon chemistry (Exxon Chemical)) mixes, obtain finish.

FORMULATION EXAMPLE 53

0. 1 (0.1) parts compd As, 0.05 part compd B 3 and 49.85 parts Neothiozol (are changed in Co., Ltd.'s (Chuo Kasei Co. Ltd.) produces) aerosol container of packing into by central authorities, aerosol valve is installed on this jar.In the LPG tank filling with 25 parts dimethyl ether and 25 parts, afterwards it is shaken afterwards.Further, actuator is contained on this jar, obtains the oiliness aerosol.

FORMULATION EXAMPLE 54

To pack in the aerosol container by 0.5 part compd A, 0.05 part the BHT, 5 parts xylol, 3.44 parts emulsifier { Atmos 300 (registration mark of Atmos the ChemicalCompany) } mixture of forming and 50 parts the distilled water of deodorized kerosine and 1 part of 3,0.01 part of compd B.Afterwards that the valve part is mounted thereto, and under pressure, 40 parts propellant (LPG) is packed into wherein through valve, to obtain water-borne aerosol.

FORMULATION EXAMPLE 55

The paper products sheet that will have the honeycomb of 0.5cm (thickness) x69cm (length) x0.2cm (width) is rolled the carrier that has the near cylindrical of 5.5cm diameter and 0.2cm height with making from an end.The solution that the compd B 3 of the compd A that passes through in 94.5 parts acetone 5 parts of dissolvings of appropriate amount and 0.5 part prepare is applied on the carrier equably, the acetone in the air drying solution afterwards, acquisition paper fumigant.

FORMULATION EXAMPLE 56

With three dimensional needle fabric (trade name: Fusion, model: AKE69440, retail trader: Asahi Chemical Ind (Asahi Kasei Fibers Corporation), thickness: 4.3mm, fabric weight (metsuke): 321g/m ², process by polyamide) and cut into sub-circular with 5cm diameter.The solution of compd B 3 preparations of the compd A that passes through in 94.5 parts acetone 5 parts of dissolvings of appropriate amount and 0.5 part is applied to the three dimensional needle fabric of cutting-out equably, and the acetone in the air drying solution obtains knitting and weaving thing fumigant afterwards.

FORMULATION EXAMPLE 57

Ethylene-methyl methacrylate methyl terpolymer (methyl methacrylate content: 10 weight % with 97 eight (97.8) weight portions; MFR=2 (g/10 minute)), the compd B 3 of 2 parts compd A and 0.2 part through

equidirectional Rotating Double screw extruder 130 ℃ of melt kneading; Through

extruder 150 ℃ of further melt kneading; Extrude from the T die and to be sheet shape, and through the chill roll cooling to obtain the resin fumigant.

FORMULATION EXAMPLE 58

Vinyl-vinyl acetate copolymer (vinyl acetate content: 10 weight % with 97 eight (97.8) weight portions; MFR=2 (g/10 minute)), the compd B 3 of 2 parts compd A and 0.2 part through

equidirectional Rotating Double screw extruder 130 ℃ of melt kneading; Through

extruder 150 ℃ of further melt kneading; Extrude from the T die and to be sheet shape, and through the chill roll cooling to obtain the resin fumigant.

FORMULATION EXAMPLE 59

The compd B 3 of five (5) parts compd As and 0.5 part is dissolved in 94.5 parts the acetone.The resulting solution of appropriate amount is applied to the paper (2000cm with folding structure ²), the acetone in the air drying solution obtains the paper fumigant afterwards.

FORMULATION EXAMPLE 60

The compd B 3 of three (3) parts compd As and 0.3 part is dissolved in 14.6 parts the acetone to obtain solution.In resulting solution, add 0.2 part zinc oxide, 1.0 parts α starch and 42.8 parts Celogen Az, and add 38.1 parts water further, and mixture is mediated, be made as granular, and dry to obtain pellet through extruder die.In the upper space of the container that the dividing wall that letter part was processed through aluminium during this pellet was contained in is separated, and the calcium oxide of 50g is contained in the lower space of this container, obtains smoking insecticide.

FORMULATION EXAMPLE 61

0. 5 (0.5) parts zinc oxide, 2 parts α starch and 97.5 parts Celogen Az are mixed.To wherein adding entry and this mixture is mediated, and will be made as granularly through extruder die, be dried afterwards to obtain pellet through the material of mediating.On this pellet of 2g, the acetone soln of the compd B 3 of the infiltration compd A that contains 0.58g and 0.058g equably, and dry afterwards with the acquisition pellet.This pellet is contained in the upper space of the container that dividing wall that core processes through aluminium separates, and the calcium oxide of 50g is contained in the lower space of this container, obtain smoking insecticide.

FORMULATION EXAMPLE 62

The compd A of 0. 5 (0.5) g and the compd B 3 of 0.05g are dissolved in the acetone of 20mL.Resulting solution is added to contain 99.4g mosquito-repellent incense with the mixture of carrier (Tabu powder: perian insect powder pomace: the weight ratio of wood powder is 4: 3: 3 a mixture) with the green colouring material of 0.3g, afterwards it is stirred and evenly mixes.Water with 120mL adds wherein and kneading fully afterwards.Resulting kneading material is molded and dry, obtain mosquito-repellent incense.

FORMULATION EXAMPLE 63

Ten (10) parts compd As, 1 part acetyl tributyl citrate, 39.5 parts adipic acid ester in the different ninth of the ten Heavenly Stems, 5 parts blue dyes and 5 parts the stacte of 3,39.5 parts of compd Bs are mixed to obtain solution.With this solution infiltrate equably electric mat at 3.4cmx2.1cmx0.22cm thickness with base material (being hardened to tabular the acquisition) through fibrillation with cotton linters mixture and paper pulp on, obtain electric mat.

FORMULATION EXAMPLE 64

The compd B 3 of 0. 1 (0.1) parts compd As and 0.01 part is dissolved in 99.89 parts the deodorized kerosine; This solution is packed in the vinyl chloride container; And the wick (the inorganic powder sclerosis through will having adhesive and obtain its sintering) that the part above it can be through heater heating is inserted in this container, obtained to be used for the parts of imbibition core pattern heated volatile fumigant.

FORMULATION EXAMPLE 65

The compd A of point two (0.2) part, 0.02 part compd B 3 and 49.78 parts Neothiozol (are changed in Co., Ltd.'s (Chuo Kasei Co. Ltd.) produces) aerosol container of packing into by central authorities.Afterwards aerosol valve is installed on this jar, and the LPG of 25 parts dimethyl ether and 25 parts is packed in this jar, afterwards it is shaken.The actuating agent that will be used for total amount injection type aerosol further is installed in jar, obtains aerosol.

FORMULATION EXAMPLE 66

In the compd B 3 of 0.2 part compd A and 0.02 part, add 99.78 parts diethylene glycol monoethyl ether, and fully stir and mix, obtain to be used to control the some paint of the epizoon of animal.

FORMULATION EXAMPLE 67

With 2,4 of four (4) g, 6-triisopropyl-1,3,5-three

Alkane compression molding (4t/cm ²) to obtain discoid solid (diameter: 3cm, thickness: 3mm), and the solution of being made up of 3 parts compd A, 0.3 part the acetone of compd B 3 and 96.7 parts of 1mL provided to the disc solid equably, be dried afterwards, obtain tablet.

FORMULATION EXAMPLE 68

To contain 0.2g compd A, 0.02g compd B 3 and 4g 2,4,6-triisopropyl-1,3,5-three

Homogeneous mixture compression molding (the 4t/cm of alkane ²) be discoid solid (diameter: 3cm, thickness: 3mm), obtain tablet.

FORMULATION EXAMPLE 69

With 2 of the compd B 3 of the compd A of point two (0.2) g, 0.02g and 4g; 4; 6-triisopropyl-1,3,5-three alkane are packed in the screwed pipe of 50mL; Add hot melting furnace and be cooled to room temperature afterwards, obtain tablet.

Following Test Example shows that the present composition has outstanding control effect to insect.

In following Test Example, use 2,2,3,3-tetramethyl cyclopropane-carboxylic acid [(2,3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester is as compd A.

Use among following compound B-11, B2 and the B3 any as compd B.

Compound B-11:

(1R)-and trans-2,2-dimethyl-3-(1-acrylic (E/Z=1/8)) cyclopropane-carboxylic acid [(2,3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester

Compd B 2:

2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid [(2,3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester

Compd B 3:

(1R)-and trans-2,2-dimethyl-3-(1-acrylic (E/Z=1/8)) cyclopropane-carboxylic acid [(2,3,5,6-tetrafluoro-4-aminomethyl phenyl) methyl] ester

Test Example 1

Compd B is diluted with the finish (being called comparison thing (1) hereinafter respectively to (9)) shown in the preparation table 1 in the isoparaffic solvent (Isopar M, the registration mark of Exxon chemistry (ExxonChemical)) of specified rate.

Likewise, compd A is diluted with the finish (being called comparison thing (10) hereinafter to (12)) shown in the preparation table 1 in the isoparaffic solvent (Isopar M, the registration mark of Exxon chemistry (Exxon Chemical)) of specified rate.

Further, with compd A and compd B dilution finish (being called composition (1) hereinafter) in the isoparaffic solvent (Isopar M, the registration mark of Exxon chemistry (Exxon Chemical)) of specified rate to (15) to provide in the preparation table 1.

It is the cube indoor of 70cm that ten houseflies (housefly (Musca domestica)) (5 male and 5 female) are released in each limit.Use spray gun, spray the present composition (the 1) (expulsion pressure: 0.9kg/cm of 0.7ml from the fenestella of the porch of chamber ²).After spraying seven (7) minutes, the insects that number goes out to knock down, and (KD) rate is knocked down in calculating.

In using the present composition (2) to (15) and comparative composition (1) to (12) each replaces the present composition (1), carry out with above identical test, and calculate 7 minutes the rate of knockdown afterwards of spraying.Carry out 2 parallel determinations for test.

The result provides in table 1.

Table 1

Test Example 2

It is the cube indoor of 70cm that ten mosquitoes (Culex pipiens pallens (Culex pipiens pallens)) (10 female) are released in each limit.Use spray gun, spray the present composition (the 1) (expulsion pressure: 0.9kg/cm of 0.7ml from the fenestella of the porch of chamber ²).After spraying seven (7) minutes, the insects that number goes out to knock down, and (KD) rate is knocked down in calculating.

In using the present composition (2) to (15) and comparative composition (1) to (12) each replaces the present composition (1), carry out with above identical test, and calculate 7 minutes the rate of knockdown afterwards of spraying.Carry out 2 parallel determinations for test.

The result provides in table 2.

Table 2

	KD after 7 minutes leads (%)
		Composition (1)	75
Composition (2)	85
		Composition (3)	75
Composition (4)	70
		Composition (5)	70
Composition (6)	70
		Composition (7)	75
Composition (8)	70
		Composition (9)	65
Composition (10)	60
		Composition (11)	80
Composition (12)	75
		Composition (13)	90
Composition (14)	85
		Composition (15)	60
Compare thing (1)	30
		Compare thing (2)	20
Compare thing (3)	15
		Compare thing (4)	25
Compare thing (5)	15
		Compare thing (6)	10
Compare thing (7)	20
		Compare thing (8)	15
Compare thing (9)	5
		Compare thing (10)	30
Compare thing (11)	25
		Compare thing (12)	5

Industrial applicability

Because outstanding insect control effect, insect control combination thing of the present invention and agent for controlling noxious insect pests be Pest Control effectively, typically comprises diptera (dipterous) insect such as fly.

Claims (6)

1. insect control combination thing, said composition comprises:

[a] 2,2,3,3-tetramethyl cyclopropane-carboxylic acid [(2,3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester,

With

The ester compounds that [b] represented by formula (I),

[a]: the mass ratio of [b] is 50: 1 to 1: 50.

2. composition according to claim 1, wherein the ester compounds by formula (I) expression is 2,2-dimethyl-3-(1-acrylic) cyclopropane-carboxylic acid [(2,3; 5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester, 2,2-dimethyl-3-(1-acrylic) cyclopropane-carboxylic acid [(2; 3,5,6-tetrafluoro-4-aminomethyl phenyl) methyl] ester or 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid [(2; 3,5,6-tetrafluoro-4-(methoxy) phenyl) methyl] ester.

3. composition according to claim 1 and 2, wherein said insect are Diptera pest.

4. composition according to claim 1 and 2, wherein said insect are fly.

5. the method for a Pest Control, said method comprises: the composition according to claim 1 and 2 of effective dose is applied to the place that insect or insect perch.

6. the purposes that is used for Pest Control according to the composition of claim 1 or 2.