CN102475089A - Insecticidal composition and method for controlling insects - Google Patents
Insecticidal composition and method for controlling insects Download PDFInfo
- Publication number
- CN102475089A CN102475089A CN2011103894924A CN201110389492A CN102475089A CN 102475089 A CN102475089 A CN 102475089A CN 2011103894924 A CN2011103894924 A CN 2011103894924A CN 201110389492 A CN201110389492 A CN 201110389492A CN 102475089 A CN102475089 A CN 102475089A
- Authority
- CN
- China
- Prior art keywords
- ester compounds
- parts
- preparation
- formula
- pesticidal combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Disclosed is an insecticidal composition employing ester compounds shown in formula (I) and formula (II) as the active ingredients. The insecticidal composition has excellent insect-controlling effect.
Description
Technical field
The application requires the priority of Japanese patent application 2010-266204 (submission on November 30th, 2010), incorporates its full content into this paper at this.
The present invention relates to the method for Pesticidal combination (pesticidal composition) and Pest Control (pest).
Background technology
Ester compounds shown in the known formula (I):
It is the active component (for example EP0054360A2 and CN101306997A) of insecticide.
EP0054360A2 discloses as the formula I compound of insecticide (insecticides) and the composition that contains them:
R wherein
1And R
2Be methyl, halogenated methyl or halogen, X is O, S, S (O), SO
2Or NR
4, R wherein
4Be H, low alkyl group or low-grade carboxylic acid's acyl group (lower carboxylic acyl), R
3Be low alkyl group, low-grade alkenyl, phenyl or benzyl, in addition, when X is NR
4The time, R
3Can be H; And n is 1-4.
CN101306997A discloses the pyrethroid compound of the structure with formula A:
In formula A, said compound is the single optical isomer of dextrorotation, wherein R
1And R
2Be respectively identical halogen or different halogens.
Ester compounds shown in the known formula (II):
It also is the active component (for example GB1448228) of insecticide.
GB1448228 discloses the ester of formula:
R wherein
1Expression hydrogen or methyl; R
2Expression hydrogen or halogen or alkyl; R
3Expression hydrogen or halogen, alkyl (are worked as R
2Expression is itself and R during alkyl
2Different) or alkoxyl in contain at least 2 carbon atoms alkoxy carbonyl group (work as R
2During the expression methyl) or R
2And R
3Represent to have the ring alkylene basic ring of at least one bridged ring carbon-carbon double bond with the carbon atom that they connected; Prerequisite is that (a) has only the R of working as
1R during the expression methyl
2And R
3Represent hydrogen separately, and (b) work as R
1And R
2R when representing hydrogen separately
3Contain at least 2 carbon atoms; And R representes (a) hydrogen (or hydrochlorate or acyl halide derivative) or alkyl, the perhaps group of (b) following formula:
Yet, use situation and the insect of treating according to it through they control, under some situation, the insecticide with bigger control effect need be provided.
Summary of the invention
The object of the present invention is to provide insect is had the Pesticidal combination of excellent control effect and the method for Pest Control.
The inventor furthers investigate and finds and with ester compounds shown in ester compounds shown in the formula (I) and the formula (II) insect had excellent control effect.Therefore accomplish the present invention.
The present invention relates to following content:
[1] contain the Pesticidal combination (hereinafter referred to as " of the present invention Pesticidal combination ") of ester compounds (hereinafter referred to as " ester compounds B ") shown in ester compounds shown in the formula (I) (hereinafter referred to as " ester compounds A ") and the formula (II) as active component:
[2] according to the composition of above-mentioned [1], wherein the weight ratio of ester compounds A and ester compounds B is 300:1 to 1:300.
[3] method of Pest Control, it comprises that the habitat of perching to insect or insect uses ester compounds A and ester compounds B by total effective dose.
[4] combination of ester compounds A and ester compounds B is used for the purposes of Pest Control.
The invention effect
Said Pesticidal combination has excellent control effect to insect.
Embodiment
Said Pesticidal combination is characterised in that and contains ester compounds A and ester compounds B.
Ester compounds A can make through the for example method described in the EP0054360A2.
Ester compounds B can make through the for example method described in the GB1448228.
Ester compounds A and ester compounds B can form isomer, because have two asymmetric carbon atoms on the cyclopropane ring of these compounds respectively.In the present invention, the compound that contains these active isomers of any ratio all can be used as ester compounds A or ester compounds B.
This Pesticidal combination comprises harmful arthropods (anthropod) to its resultful insect, for example harmful insect and harmful Acarina (acarina).Its instantiation is described below:
Lepidoptera (Lepidoptera): Pyralidae (Pyralidae), for example striped rice borer (Chilo suppressalis), rice leaf roller (Cnaphalocrosis medinalis) and Indian meal moth (Plodia interpunctella); Noctuidae (Noctuidae), for example prodenia litura (Spodoptera litura), mythimna separata (Pseudaletia separata) and noctuid wild cabbage (Mamestra brassicae); Sulfur butterfly (Pieridae), for example cabbage butterfly (Pieris rapae crucivora); Tortricidae (Tortricidae), for example leaf roller belongs to (Adoxophyes spp.); Moth fruit moth section (Carposinidae); Lyonetid section (Lyonetiidae); Lymantriidae (Lymantriidae); Autographa spp (Antographa); Agrotis (Agrotis spp.), for example white line dart moth of turnip (Agrotis segetum) and black cutworm (Agrotis ipsilon); Bell Noctua (Helicoverpa spp.); Cotton Heliothis (Heliothis spp.); Diamond-back moth (Plutella xylostella); Straight burr rice hesperiidae (Parnara guttata); Bag casemaking clothes moth (Tinea pellionella); Casemaking clothes moth (Tineola bisselliella) etc.
Diptera (Diptera): Culex (Culex spp.), for example Culex pipiens pallens (Culex pipiens pallens), Culex tritaeniorhynchus (Culex tritaeniorhynchus) and Culex quinquefasciatus (Culex quinquefasciatus); Aedes (Aedes spp.), for example Aedes aegypti (Aedes aegypti) and aedes albopictus (Aedes albopictus); Anopheles (Anopheles spp.), for example Anopheles sinensis (Anopheles sinensis); Chironomidae (Chironomidae); Nuscidae (Muscidae), for example housefly (Musca domestica), Musca corvina, false stable fly (Muscina stabulans) and Fannia canicularis (Fannia canicularis); Calliphoridae (Calliphoridae); Flesh flies (Sarcophagidae); Anthomyiidae (Anthomyiidae), for example delia platura (Delia platura) and onion fly (Delia antiqua); Sepsidae (Sepsidae); Fruit Nuscidae (Tephritidae); Agromyzidae (Agromyzidae); Kunming Drosophilidae (Drosophilidae), for example fruit bat (Drosophia melanogaster); Moth files (Psychodidae); Phoridae (Phoridae), the for example different eye fly in East Asia (Megaselia spiracularis); Simulidae (Simuliidae); Tabanidae (Tabanidae); Sting Nuscidae (Stomoxyidae); Heleidae (Ceratopogonidae) etc.
Blattaria (Blattaria): Groton bug (Blattella germanica), Peroplaneta fluligginosa (Periplaneta fuliginosa), American cockroach (Periplaneta americana), the big Lian of foxiness (Periplaneta brunnea), oriental cockroach (Blatta orientalis) etc.
Hymenoptera (Hymenoptera): Formicidae (Formicidae), Vespidae (Vespidae), Bethylidae (Bethylidae), swaflies (Tenthredinidae), for example yellow-winged cabbage sawfly (Athalia rosae ruficornis) etc.
Latent wing order (Siphonaptera): ctenocephalides canis (Ctenocephalides canis), ctenocephalides felis (Ctenocephalides felis), Pulex irritants etc.
Anoplura (Anoplura): humanlice (Pediculus humanus), shame crab louse (Pthirus pubis), pediculus humanus capitis (Pediculus humanus capitis), pediculus humanus corporis (Pediculus humanus corporis) etc.
Isoptera (Isoptera): eastern subterranean termite (Reticulitermes speratus), coptotermes formosanus (Coptotermes formosanus) etc.
Semiptera (Hemiptera): Delphacidae (Delphacidae), for example small brown rice planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens) and white-backed planthopper (Sogatella furcifera); Deltocephalidae, for example rice leafhopper (Nephotettix cincticeps) and nephotettix bipunctatus (Nephotettix virescens); Aphidiadae (Aphididae); Pentatomiddae (Pentatomidae); Aleyrodidae (Aleyrodidae); Coccoidea (Coccoidae); Cimicidae (Cimicidae), for example bed bug (Cinex lectularius); Tingidae (Tingidae); Psyllidae (Psyllidae) etc.
Coleoptera (Coleoptera): black wool khapra beetle (Attagenus unicolor); Roundlet flower khapra beetle (Anthrenus verbasci); Corn rootworm (corn rootworms), for example western corn rootworm (Diabrotica virgifera) and Diabrotica undecimpunctaca howardi; Scarabaeidae (Scarabaeidae), for example Anomala cuprea Hope (Anomala cuprea) and red metal rutelian (Anomala rufocuprea); Culculionidae (Curculionidae); Corn weevil (Sitophilus zeamais) for example; Rice water weevil (Lissorhoptrus oryzophilus), cotton boll resemble (Anthonomus grandis grandis) and adzuki bean weevil (Callosobruchus chinensis); Intend worm first section (Tenebrionidae), for example yellow mealworm (Tenebrio molitor) and red flour beetle (Tribolium castaneum); Chrysomelidae (Chrysomelidae), Oulema oryzae (Oulema oryzae) for example, yellow bar leaf flea (Phyllotreta striolata) and aulacophora femoralis (Aulacophora femoralis); Anobiidae (Anobiidae); Ladybug belongs to (Epilachna spp.), for example ladybug of eggplant 28 stars (Henosepilachna vigintioctopunctata); Lyctidae (Lyctidae); Bostrichidae (Bostrychidae); Cerambycidae (Cerambycidae); Paederus fuscipes Curtis (Paederus fuscipes) etc.
Thrips (Thysanoptera): palm thrips (Thrips palmi), Frankliniella occidentalis (Frankliniella occidentalis), yellow chest thrips (Thrips hawaiiensis) etc.
Orthoptera (Orthoptera): Gryllotalpidae (Gryllotalpidae), sword angle locust section (Acrididae) etc.
Acarina (Acarina): ant mite section (Pyroglyphidae), for example dust mite (Dermatophagoides farinae) and dermatophagoides pteronyssinus (Dermatophagoides pteronyssinus); Tyroglyphidae (Acaridae), for example tyrophagus putrescentiae (Tyrophagus putrescentiae) and oval baking soda mite (Aleuroglyphus ovatus); Eat sweet mite section (Glycyphagidae), for example concealed sweet mite (Glycyphagus privatus), family sweet food mite (Glycyphagus domesticus) and family food sweet mite (Glycyphagus destructor); Cheyletidae (Cheyletidae), for example Malacca cheyletid mite (Cheyletus malaccensis) and Cheyletus moorei; Tarsonemidae (Tarsonemidae); Have a liking for slag mite section (Chortoglyphidae); Oribatei; Tetranychidae (Tetranychidae), Tetranychus urticae (Tetranychus urticae) for example, refreshing Ze Shi tetranychid (Tetranychus kanzawai), tangerine Panonychus citri (Panonychus citri) and elm Panonychus citri (Panonychus ulmi); Hard tick section (Ixodidae), for example haemaphysalis longicornis (Haemaphysalis longicornis); Dermanyssidae (Dermanyssidae), for example Ornithonyssus sylvairum and Dermanyssus galinae etc.
Pesticidal combination of the present invention especially has excellent control effect to diptera (Diptera).
Contained ester compounds A and the weight ratio of ester compounds B are generally 300:1 to 1:300 in the Pesticidal combination of the present invention, preferred 100:1 to 1:100, more preferably 1:15 to 1:70.
As Pesticidal combination of the present invention, its can ester compounds A and the simple mixtures of ester compounds B use, but it is used after being formulated into following any preparation usually.Said preparation comprises finish (oil formulation); Emulsifiable concentrate; Wettable powder; Concentrate (for example aqueous suspension concentrate and aqueous emulsion concentrate) can flow; Micro-capsule; Pulvis (dusts); Granule; Tablet; Aerosol; The carbonic acid gas preparation; Hot type volatility preparation (desinsection circle (insecticidal coil) for example; Electric heating insecticidal mat and hot type volatility preparation) with wick (absorbent wick); The piezo-electric type insecticidal preparation; Heating fumigating agent (for example spontaneous combustion type fumigant; Chemical reaction type fumigant and porous ceramic plate fumigant); Non-heating volatile preparation (resin volatility preparation for example; Paper volatility preparation; Nonwoven volatility preparation; Knitting (braided textile) volatility preparation and sublimability tablet); Smoke agent (for example aerosol); Directly (for example sheet contacts preparation to the contact preparation; Banded contact preparation and the netted preparation that contacts); ULV preparation and poison bait.
As the method for preparation, can carry out exemplary illustration to following method.
(1) ester compounds A and ester compounds B are mixed with solid carrier, liquid-carrier, carrier gas, bait etc., and in case of necessity to other auxiliary material that wherein adds surfactant and/or be used for preparation method for processing then.
(2) ester compounds A and ester compounds B are infiltrated in the method for base material.
(3) ester compounds A, ester compounds B and base material are mixed the method for carrying out molded or moulding then.
Such preparation comprises ester compounds A and the ester compounds B that total amount is generally 0.001-98wt%, although total amount depends on the type of preparation.
The solid carrier that is used for preparation comprises the micro mist and the particle of clay (for example kaolin, diatomite, bentonite, fubasami clay (fubasami clay) and acid clay), synthetic hydrated silica, talcum, pottery, other inorganic mineral (for example sericite, quartz, Sulfur, active carbon, calcium carbonate and hydrated SiO 2) and chemical fertilizer (for example ammonium sulfate, ammonium phosphate, ammonium nitrate, ammonium chloride and urea); It under the normal temperature material (for example 2 of solid; 4; 6-triisopropyl-1; 3,5-three
alkane, naphthalene, paracide, camphor and adamantane); With felt, fiber, cloth, knit goods, sheet (sheet), paper, yarn, foaming body, porous material and multifilament a kind of or more kinds of in the following material: wool, silk, cotton, flax, paper pulp, synthetic resin (for example polyvinyl resin, for example low density polyethylene (LDPE), LLDPE and high density polyethylene (HDPE); Ethylene-vinyl ester copolymer, for example ethylene-vinyl acetate copolymer; Ethylene-methyl acrylate copolymer, for example ethylene-methyl methacrylate methyl terpolymer and ethylene-methyl methacrylate ethyl ester copolymer; Vinyl-acrylate copolymer, for example ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; Ethylene-vinyl polymers of carboxylic acid, for example ethylene-acrylic acid copolymer; Ethene-tetracyclododecane copolymer; Acrylic resin, for example Noblen and propylene-ethylene copolymers; Gather-4-methylpentene-1, PB Polybutene-1, polybutadiene and polystyrene; Acrylonitrile-styrene resin; Styrene series elastomer, for example acrylonitrile-butadiene-styrene resin; Styrene-conjugated diene block copolymer and styrene-conjugated diene block copolymer hydrogenated products; Fluororesin; Acrylic resin for example gathers (methyl methacrylate); Polyamide, for example nylon 6 and nylon 66; Mylar, for example PETG, PEN, polybutylene terephthalate (PBT) and poly terephthalic acid hexamethylene two methylene esters; And porous resin, for example Merlon, polyacetals, polyacrylamide sulfone (polyacryl sulfone), polyacrylate, hydroxybenzoic acid polyester, PEI, polyestercarbonate, polyphenylene oxide resin, polyvinyl chloride, polyvinylidene chloride, polyurethane; Expansion type polyurethane, expansion type polypropylene and expansion type polyethylene), glass, metal, pottery etc.
Liquid-carrier comprises aromatic series or aliphatic hydrocarbon (for example xylol, toluene, Fluhyzon, phenyl xylyl ethane, kerosene, light oil, hexane and cyclohexane), halogenated hydrocarbon (for example chlorobenzene, carrene, dichloroethane and trichloroethanes), alcohols (for example methyl alcohol, ethanol, isopropyl alcohol, butanols, hexanol, benzylalcohol and ethylene glycol), ethers (for example diethyl ether, glycol dimethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, oxolane and two
alkane), ester class (for example ethyl acetate and butyl acetate), ketone (for example acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) and cyclohexanone), nitrile (for example acetonitrile and isobutyronitrile), sulfoxide class (for example dimethyl sulfoxide (DMSO)), amide-type (N for example; Dinethylformamide, DMAC N,N and N-Methyl pyrrolidone), alkylene carbonate class (for example propylene carbonate), vegetable oil (for example soybean oil and cottonseed oil), plants essential oil (for example orange-seed oil, hyssop oil and lemon oil) and water.
Carrier gas comprises butane gas, CFC gas, liquefied petroleum gas (LPG), dimethyl ether and carbonic acid gas.
Said surfactant comprises alkyl sulfate, alkyl sulfonic ester, alkyl aryl sulfonate, alkyl aryl ether and their polyoxyethylene product, polyglycol ether, polyol ester and sugar alcohol derivant.
Other auxiliary material that is used for preparation comprises adhesive, dispersant and stabilizing agent.Its instantiation is casein, gelatin, polysaccharide (for example starch, gum Arabic, cellulose derivatives and alginic acid), lignin derivative, bentonite, sugar, synthetic polymer [for example polyvinyl alcohol, polyvinylpyrrolidone and polyacrylic acid], BHT (2,6 di tert butyl 4 methyl phenol), BHA (mixture of the 2-tert-butyl group-4-metoxyphenol and the 3-tert-butyl group-4-metoxyphenol) etc.
The base material that is used for the desinsection circle comprises the mixture of former plant powder (for example wood powder and perian insect powder (pyrethrum marc)) and adhesive (for example Tabu powder, starch and seitan (gluten)).
The base material that is used for the electric heating insecticidal mat comprises the fibrillation squeeze board of cotton linters fibrillation squeeze board, cotton linters and pulp mixture.
The base material that is used for spontaneous combustion type fumigant comprises flammable exothermic agent (for example nitrate, nitrite, guanidinesalt, potassium chlorate, NC Nitroncellulose, ethyl cellulose and wood powder), thermolysis promoter (for example alkali metal salt, alkali salt, bichromate and chromate), oxygenate (for example potassium nitrate), combustion adjuvant (for example melamine and wheaten starch), incremental agent (extending agent) (for example diatomite) and adhesive (for example synthetic thickener).
The base material that is used for the chemical reaction type fumigant comprises exothermic agent (for example alkali-metal sulphide, polysulfide and sulfhydrate and calcium oxide), catalyzer (for example carbonaceous material, cementite and activated clay), organic foaming agent (for example Celogen Az, benzene sulfonyl hydrazide, dinitropentamethylenetetramine, polystyrene and polyurethane) and filler (for example native fiber sheet and synthetic fibers sheet).
Resin as the base material of resin volatility preparation etc. comprises polyvinyl resin, for example low density polyethylene (LDPE), LLDPE and high density polyethylene (HDPE); Ethylene-vinyl ester copolymer, for example ethylene-vinyl acetate copolymer; Ethylene-methyl acrylate copolymer, for example ethylene-methyl methacrylate methyl terpolymer and ethylene-methyl methacrylate ethyl ester copolymer; Vinyl-acrylate copolymer, for example ethylene-methyl acrylate copolymer and ethylene-ethyl acrylate copolymer; Ethylene-vinyl polymers of carboxylic acid, for example ethylene-acrylic acid copolymer; Ethene-tetracyclododecane copolymer; Acrylic resin, for example Noblen and propylene-ethylene copolymers; Gather-4-methylpentene-1, PB Polybutene-1, polybutadiene, polystyrene and acrylonitrile-styrene resin; Styrene series elastomer, for example acrylonitrile-butadiene-styrene resin; Styrene-conjugated diene copolymer and styrene-conjugated diene block copolymer hydrogenated products; Fluororesin; Acrylic resin for example gathers (methyl methacrylate); Polyamide, for example nylon 6 and nylon 66; Mylar, for example PETG, PEN, gather phthalic acid butanediol ester and poly terephthalic acid hexamethylene two methylene esters; And Merlon, polyacetals, polyacrylamide sulfone, polyacrylate, hydroxybenzoic acid polyester, PEI, polyestercarbonate, polyphenylene oxide resin, polyvinyl chloride, polyvinylidene chloride and polyurethane.These base materials can use separately or use with its mixture.In case of necessity, these base materials can comprise plasticizer, for example phthalic acid ester (for example repefral and dioctyl phthalate), adipate ester and stearic acid.Said resin volatility preparation can through with ester compounds A and ester compounds B and base material mentioned above is mediated and then through injection moulding, extrude, compacting etc. will mediate the molded or moulding of product and obtain.In case of necessity, can the gained resin formulation be pressed into plate, film, band, net, rope (string) etc. through steps such as molded or moulding, cuttings.Such resin formulation for example be pressed into arbitrarily animal with necklace, animal with ear tag, Formulation, lure leader tape (attracting strings) and gardening with pillar (horticultural stays).
The base material that is used for poison bait comprises that bait component (such as grain powder, vegetable oil, sugar and avicel cellulose), antioxidant (for example dibutyl hydroxy toluene and NDGA), preservative (for example dehydroactic acid), children or pet eat the spices (for example cheese spices, onion spice and peanut oil) that prevents agent (for example red pepper powder) and attract insect-insect by mistake.
In the method for the invention, the habitat through perching to insect or insect (plant, soil, indoor, animal etc.) uses Pesticidal combination of the present invention and comes Pest Control.In addition, use ester compounds A through the habitat of perching to insect or insect respectively by total effective dose and ester compounds B comes Pest Control.
Among this paper, " total effective dose " is meant the total amount of ester compounds A and ester compounds B, uses two kinds of compound controlled insects according to this amount.
The instantiation of using the method for Pesticidal combination of the present invention is following method.Can be according to the present invention Pesticidal combination form, use place etc. and suitably select application process.
(1) Pesticidal combination of the present invention itself is applied to the method for the habitat that insect or insect perch.
(2) with solvent for example water dilute the method that Pesticidal combination of the present invention is applied to the habitat that insect or insect perch then.
In method (2), be mixed with emulsifiable concentrate, wettable powder, the Pesticidal combination of the present invention of can flow concentrate, micro-capsule etc. usually the diluted total concentration of ester compounds A and ester compounds B that makes can be 0.01-1000ppm.
(3) in the habitat that insect perches Pesticidal combination of the present invention is heated to evaporate the method for active component.
In method (3), the application dosage of ester compounds A and ester compounds B and application concentration all can be according to the present invention the form of Pesticidal combination, when, where and how to use Pesticidal combination, the extent of damage waits is suitably confirmed.
When Pesticidal combination of the present invention was used to prevent epidemic disease, when being applied to the space, its application dosage was generally 0.0001-1000mg/m in the total amount of ester compounds A and ester compounds B
3When being applied to the plane, its application dosage is generally 0.0001-1000mg/m in the total amount of ester compounds A and ester compounds B
2Hot type volatility formulation example such as desinsection circle and electric heating insecticidal mat depend on that the type of these preparations is evaporated active component through heating and uses.Non-hot type volatility formulation example such as resin volatility preparation, paper volatility preparation, nonwoven volatility preparation, knitting volatility preparation and sublimability tablet can be for example through making them be statically placed in the space that they use or using through they are blown air.
Using Pesticidal combination of the present invention prevents epiphytotics space to comprise wardrobe, closet, drawout cubicle, cupboard, toilet, bathroom, hovel, living room, dining room, warehouse and Che Nei.In addition, Pesticidal combination of the present invention also can be used in the outdoor open space.
For example ox, horse, pig, sheep, goat, chicken etc. and small animal can be used it to said animal through known method in the veterinary medicine for example during on one's body epizoon such as dog, cat, rat, mouse when Pesticidal combination of the present invention is used to control domestic animal.Particularly, utilize the method for Pesticidal combination of the present invention as mentioned below.For whole body control, Pesticidal combination with tablet for example, with mixture, suppository or the injection of foodstuff (for example muscle is interior, subcutaneous, intravenous or intraperitoneal injection) administered.For non-whole body control, Pesticidal combination is for example to spray, to pour (pour-on) or spray (spot-on) processing, clean, perhaps with necklace or ear tag form the method that resin volatility preparation is worn on the animal used to animal with hair washing preparation (shampoo formulation) with finish or aqueous liquid preparation with finish or aqueous liquid preparation.When Pesticidal combination of the present invention was used to animal, total weight range of ester compounds A and ester compounds B was generally the 0.01-1000mg/kg the weight of animals.
In addition, in Pesticidal combination of the present invention, other insecticide for example insecticide and miticide, pest repellant, synergist, pigment etc. can mix with ester compounds A and ester compounds B or with ester compounds A and ester compounds B and use.
Embodiment
Utilize hereinafter described formulation example and Test Example that the present invention is described in further detail, but these formulation example and Test Example are not appreciated that restriction scope of the present invention.
At first, the preparation of exemplary illustration Pesticidal combination of the present invention.In formulation example and Test Example, except as otherwise noted, otherwise all umbers are mass fraction.
Formulation example 1
9 parts of ester compounds A and 0.9 part of ester compounds B are dissolved in 37.5 parts of xylol and 37.5 parts of N; In the mixture of dinethylformamide; To wherein adding 9.1 parts of polyoxyethylene styryl phenyl ethers and 6 parts of calcium dodecyl benzene sulfonates; The gained mixture is fully stirred and mixes, obtain emulsifiable concentrate.
Formulation example 2
(registrar entitling, Toho Chemical Co. Ltd.) fully mix, to wherein adding 32 parts of Carplex #80 (registrar entitling, Shionogi Co., Ltd. with 20 parts of ester compounds A, 20 parts of ester compounds B and 5 parts of Sorpol 5060; The synthetic hydrated silica micro mist) and 23 part of 300 order diatomite, and the gained mixture mixed in fruit juice mixer (juice mixer), obtain wettable powder.
Formulation example 3
5 parts of synthetic hydrated silica micro mists, 5 parts of neopelexes, 30 parts of bentonites and 56.7 parts of clays are added in the mixture of 3 parts of ester compounds A and 0.3 part of ester compounds B, the gained mixture is fully stirred and mixes.Add suitable quantity of water in gained mixture and further stirring thereafter.Particle diameter with comminutor adjustment gained stirs the mixture carries out through-flow drying then, obtains granule.
Formulation example 4
5 parts of ester compounds A, 0.5 part of ester compounds B, 1 part of synthetic hydrated silica micro mist, 1 part of Driless B as flocculant (by Sankyo Co., Ltd. produces) and 7 parts of clays are fully mixed in mortar, in fruit juice mixer, stir then and mixing.In the gained mixture, add 85.5 parts of cutting clays (cut clay), and the gained mixture is fully stirred and mixes, obtain pulvis.
Formulation example 5
10 parts of ester compounds A, 1 part of ester compounds B, 35 parts of white carbon (white carbon) and 54 parts of water that contain 50% polyoxyethylene alkyl ether ammonium sulfate are mixed, and pass through wet comminuting method, obtain pulvis the fine pulverizing of gained mixture.
Formulation example 6
0.05 part of ester compounds A and 0.1 part of ester compounds B are dissolved in 10 parts of carrene, and gained solution and 89.85 parts of isoparaffic solvents (Isopar M, registrar entitling, Exxon Chemical Co.) are mixed, obtain finish.
Formulation example 7
With 0.1 part of ester compounds A, 0.05 part of ester compounds B and 49.85 parts of Neochiozol (Chuokasei Co.; Ltd.) place aerosol container; Be said jar of installation aerosol valves, 25 parts of dimethyl ether and 25 parts of LPG are packed in said jar, shake said jar; Be said jar of installation of driver then, obtain the oiliness aerosol.
Formulation example 8
With 0.5 part of ester compounds A, 0.05 part of ester compounds B, 0.01 part of BHT, 5 parts of xylol, 3.44 parts of deodorized kerosines and 1 part of emulsifier { Atmos 300 (registrar entitling; Atlas Chemical Corp.) } and the mixture of 50 parts of distilled water place aerosol container; Be said container mounted valve portion; 40 parts of propellants (LPG) are compressed in the said container under pressure through said valve then, obtain water-borne aerosol.
Formulation example 9
Paper (paperwork) (thick 0.5cm, long 69cm, wide 0.2cm) with honey comb structure rolled from an end process diameter and be 5.5cm, highly be the columniform basically carrier of 0.2cm.The 5 parts of ester compounds A and the solution of 0.5 part of ester compounds B in 94.5 parts of acetone of appropriate amount are coated on the above-mentioned carrier equably, and the air-dry then acetone of removing obtains paper volatility preparation.
Formulation example 10
With three dimensional needle fabric (trade name: Fusion, model: AKE69440, dealer: Asahi Kasei Fibers Corp., thickness: 4.3mm, Unit Weight: 321g/m
2Process by polyamide) be cut into the circular basically sheet that diameter is 5cm.The 5 parts of ester compounds A and the solution of 0.5 part of ester compounds B in 94.5 parts of acetone of appropriate amount are coated on the above-mentioned three dimensional needle fabric equably, and the air-dry then acetone of removing obtains knitting volatility preparation.
Formulation example 11
Utilize the 45-mmf parallel dual-screw extruding machine under 130 ℃ with 97.8 parts by weight of ethylene-methylmethacrylate copolymer (methyl methacrylate content: 10wt%; MFR=2 [g/10min]), 2 parts of ester compounds A and 0.2 part of ester compounds B melt kneading; Further utilize the 40-mmf extruder under 150 ℃ with they melt kneading; To mediate product through T-die and be extruded into tablet, with chill roll said tablet cooled off then, obtain resin volatility preparation.
Formulation example 12
Utilize the 45-mmf parallel dual-screw extruding machine under 130 ℃ with 97.8 parts by weight of ethylene-vinyl acetate co-polymer (vinyl acetate content: 10wt%; MFR=2 [g/10min]), 2 parts of ester compounds A and 0.2 part of ester compounds B melt kneading; Further utilize the 40-mmf extruder under 150 ℃ with they melt kneading; To mediate product through T-die and be extruded into tablet, with chill roll said tablet cooled off then, obtain resin volatility preparation.
Formulation example 13
5 parts of ester compounds A and 0.5 part of ester compounds B are dissolved in 94.5 parts of acetone.The gained solution of appropriate amount is coated in the paper (2000cm with folding structure
2) on, and the air-dry acetone of removing, obtain paper volatility preparation.
Formulation example 14
3 parts of ester compounds A and 0.3 part of ester compounds B be dissolved in 14.6 parts of acetone obtain solution.In this solution, add 0.2 part of zinc oxide, 1.0 parts of pregelatinized starchs and 42.8 parts of Celogen Azs, then to wherein adding 38.1 parts of water.The gained mixture is mediated, be shaped to granule with extruder, dry then.The granule that will contain above-mentioned The compounds of this invention is placed on the upper space of the container that the middle part separated by the aluminium dividing plate, and the 50g calcium oxide is placed on the lower space of said container.Thus, obtain fumigant.
Formulation example 15
0.5 part of zinc oxide, 2 parts of pregelatinized starchs and 97.5 parts of Celogen Azs are mixed and the gained mixture is mediated with water.Make the kneading product be shaped to particle and dry with extruder.2g uniform particles ground is infiltrated contain the acetone soln of 0.58g ester compounds A and 0.058g ester compounds B, dry then.Thus obtained particle is placed on the upper space of the container that the middle part separated by the aluminium dividing plate, and the 50g calcium oxide is placed on the lower space of said container.Thus, obtain fumigant.
Formulation example 16
0.5g ester compounds A and 0.05g ester compounds B are dissolved in the 20ml acetone; Gained solution is added in the mixture that 99.4g kills mosquito circle (mosquito coil) carrier (mixture of Tabu powder, Dalmatian chrysanthemum and wood powder, weight ratio are 4:3:3) and 0.3g viridine green, evenly stir and mix the gained mixture; To wherein adding 120ml water; The gained mixture is fully mediated, and it is molded and dry to mediate mixture then, obtains the desinsection circle.
Formulation example 17
Making area is that 3.4cm * 2.1cm and thickness are that the electricity pad of 0.22cm infiltrates through mixing 10 parts of ester compounds A, 1 part of ester compounds B, 39.5 parts of acetyl tributyl citrates, 39.5 parts of adipic acid esters in the different ninth of the ten Heavenly Stems, 5 parts of blue pigments and 5 parts of solution that spices obtains with base material (making the fibrillation of the mixture of cotton linters and paper pulp solidify the plate that obtains) equably, obtains the electric heating insecticidal mat.
Formulation example 18
0.1 part of ester compounds A and 0.01 part of ester compounds B are dissolved in 99.89 parts of deodorized kerosines; Gained solution is placed the container of processing by vinyl chloride; And an end of wick (through making inorganic powder and adhesive and will solidifying that powder baking obtains) is inserted the other end that makes said core in the said container can heat with heater, obtain having the hot type volatility preparation part of wick.
Formulation example 19
With 0.2 part of ester compounds A, 0.02 part of ester compounds B and 49.78 parts of Neochiozol (Chuokasei Co.; Ltd.) place aerosol container; Be said jar of installation aerosol valves, 25 parts of dimethyl ether and 25 parts of LPG are packed in said jar, shake said jar; For said jar the driver that is used for whole-jetting type aerosol is installed then, is obtained aerosol.
Formulation example 20
99.78 parts of diethylene glycol monoethyl ethers are added in the mixture of 0.2 part of ester compounds A and 0.02 part of ester compounds B, the gained mixture is fully stirred and mixes, obtain being used to control the parasitic spray of animal body surface and drip (spot-on) treatment agent.
Formulation example 21
The solution that 1mL is made up of 3 parts of ester compounds A, 0.3 part of ester compounds B and 96.7 parts of acetone is coated in through at pressure (4t/cm equably
2) lower mould 4000mg 2,4,6-triisopropyl-1,3,5-three
Alkane and the plate-like solid content that obtains (diameter: 3cm, thickness: then that solid content is dry 3mm), obtain tablet.
Formulation example 22
At pressure (4t/cm
2) under with 0.2g ester compounds A, 0.02g ester compounds B and 4g 2,4,6-triisopropyl-1,3,5-three
The homogeneous mixture of alkane is molded as dish (diameter: 3cm, thickness: 3mm), obtain tablet.
Formulation example 23
With 0.2g ester compounds A, 0.02g ester compounds B and 4g 2; 4,6-triisopropyl-1,3; 5-three
alkane places the 50mL screwed pipe; Make their fusings through heating, then they are cooled to room temperature, obtain tablet.
Hereinafter Test Example proof Pesticidal combination of the present invention has excellent control effect to insect.
In the Test Example hereinafter, [2,3,5,6-tetrafluoro-4-(methoxy) phenyl] methyl=(1R)-and trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester is as ester compounds A.
In addition, 3-phenoxy benzyl=3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester is as ester compounds B.
Test Example 1
A certain amount of ester compounds B is dissolved in the finish that preparation has concentration shown in the table 1 in the isoparaffic solvent (Isopar M, registrar entitling, Exxon Chemical Co.).Hereinafter these finishes are called comparative composition (1)-(3).Equally, a certain amount of ester compounds A is dissolved in the finish that preparation has concentration shown in the table 1 in the isoparaffic solvent (Isopar M, registrar entitling, Exxon Chemical Co.).Hereinafter this finish is called comparative composition (4).
As Pesticidal combination of the present invention, a certain amount of ester compounds A and ester compounds B are dissolved in the finish for preparing the active component that contains concentration shown in the table 1 in the isoparaffic solvent (Isopar M, registrar entitling, Exxon Chemical Co.).Hereinafter these finishes are called the present composition (1)-(3).
10 mosquitoes (Culex pipiens pallens (Culex pipiens pallens)) (10 female) are put in a suitable place to breed in the length of side is the cube container of 70cm.With the wicket sprinkling 0.7ml present composition (the 1) (spray pressure: 0.9kg/cm of spray gun from said container entrance
2).Sprayed back 7 minutes, the insect of knocking down is counted, and calculate (KD, knocking-down) rate of knocking down.
Each composition in utilizing the present composition (2) and (3) and comparative composition (1)-(4) substitutes the present composition (1), carries out test same as above, and calculates and spray back 7 minutes rate of knockdown.Said test all repeats 2 times.
The result is as shown in table 1.
Table 1
| ? | Ester compounds A content (w/v %) | Ester compounds B content (w/v %) | KD leads (%) after 7 minutes |
| The present composition (1) | 0.00313 | 0.2 | 85 |
| The present composition (2) | 0.00313 | 0.1 | 70 |
| The present composition (3) | 0.00313 | 0.05 | 60 |
| Comparative composition (1) | - | 0.2 | 20 |
| Comparative composition (2) | - | 0.1 | 10 |
| Comparative composition (3) | - | 0.05 | 5 |
| Comparative composition (4) | 0.00313 | - | 20 |
Industrial applicability
According to the present invention, provide insect is had the Pesticidal combination of excellent control effect and the method for Pest Control.
Claims (4)
1. contain ester compounds shown in ester compounds shown in the formula (I) and the formula (II) as the Pesticidal combination of active component:
2. composition according to claim 1, the weight ratio of ester compounds is 300:1 to 1:300 shown in ester compounds shown in its Chinese style (I) and the formula (II).
3. the method for Pest Control, it comprises that the habitat of perching to insect or insect uses ester compounds shown in ester compounds shown in the formula (I) and the formula (II) by total effective dose:
4. the combination of ester compounds shown in ester compounds shown in the formula (I) and the formula (II) is used for the purposes of Pest Control:
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010266204 | 2010-11-30 | ||
| JP2010-266204 | 2010-11-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102475089A true CN102475089A (en) | 2012-05-30 |
Family
ID=46087957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103894924A Pending CN102475089A (en) | 2010-11-30 | 2011-11-30 | Insecticidal composition and method for controlling insects |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JP2012131777A (en) |
| CN (1) | CN102475089A (en) |
| AR (1) | AR084405A1 (en) |
| AU (1) | AU2011250708A1 (en) |
| BR (1) | BRPI1107038A2 (en) |
| MX (1) | MX2011012771A (en) |
| RU (1) | RU2011148621A (en) |
| TR (1) | TR201111809A2 (en) |
| TW (1) | TW201234968A (en) |
| ZA (1) | ZA201108574B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008123574A2 (en) * | 2007-03-30 | 2008-10-16 | Sumitomo Chemical Company, Limited | Pesticidal composition and method for controlling harmful insects |
| CN101543225A (en) * | 2009-05-15 | 2009-09-30 | 江苏扬农化工股份有限公司 | Insecticide mother liquor and use thereof |
| CN101632376A (en) * | 2009-06-05 | 2010-01-27 | 江苏扬农化工股份有限公司 | Pest control repellent and method for preventing and killing pests |
| US20100210698A1 (en) * | 2007-09-05 | 2010-08-19 | Yoshito Tanaka | Pesticidal composition and method for controlling pests |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5352891B2 (en) * | 2006-06-29 | 2013-11-27 | 住友化学園芸株式会社 | Pest repellent |
| JP3909717B1 (en) * | 2006-07-04 | 2007-04-25 | 大日本除蟲菊株式会社 | Flies and mosquito coils |
| JP5326318B2 (en) * | 2007-03-30 | 2013-10-30 | 住友化学株式会社 | Pest control aerosol composition |
| JP5225202B2 (en) * | 2008-06-10 | 2013-07-03 | 住友化学株式会社 | Pest control composition and pest control method |
| CN101524084B (en) * | 2009-04-30 | 2012-11-07 | 江苏扬农化工股份有限公司 | Muscicide incense and preparation method and application thereof |
| CN101669504B (en) * | 2009-10-21 | 2012-11-28 | 江苏扬农化工股份有限公司 | Pesticide mother solution, preparation method and application thereof |
-
2011
- 2011-11-10 AU AU2011250708A patent/AU2011250708A1/en not_active Abandoned
- 2011-11-22 ZA ZA2011/08574A patent/ZA201108574B/en unknown
- 2011-11-22 TW TW100142729A patent/TW201234968A/en unknown
- 2011-11-24 JP JP2011255831A patent/JP2012131777A/en active Pending
- 2011-11-25 AR ARP110104399 patent/AR084405A1/en unknown
- 2011-11-29 RU RU2011148621/13A patent/RU2011148621A/en not_active Application Discontinuation
- 2011-11-29 TR TR2011/11809A patent/TR201111809A2/en unknown
- 2011-11-30 MX MX2011012771A patent/MX2011012771A/en not_active Application Discontinuation
- 2011-11-30 CN CN2011103894924A patent/CN102475089A/en active Pending
- 2011-11-30 BR BRPI1107038-2A patent/BRPI1107038A2/en not_active Application Discontinuation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008123574A2 (en) * | 2007-03-30 | 2008-10-16 | Sumitomo Chemical Company, Limited | Pesticidal composition and method for controlling harmful insects |
| US20100210698A1 (en) * | 2007-09-05 | 2010-08-19 | Yoshito Tanaka | Pesticidal composition and method for controlling pests |
| CN101543225A (en) * | 2009-05-15 | 2009-09-30 | 江苏扬农化工股份有限公司 | Insecticide mother liquor and use thereof |
| CN101632376A (en) * | 2009-06-05 | 2010-01-27 | 江苏扬农化工股份有限公司 | Pest control repellent and method for preventing and killing pests |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2011148621A (en) | 2013-06-10 |
| BRPI1107038A2 (en) | 2013-03-26 |
| TR201111809A2 (en) | 2012-06-21 |
| MX2011012771A (en) | 2012-05-30 |
| ZA201108574B (en) | 2012-07-25 |
| AR084405A1 (en) | 2013-05-15 |
| JP2012131777A (en) | 2012-07-12 |
| AU2011250708A1 (en) | 2012-06-14 |
| TW201234968A (en) | 2012-09-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101169817B1 (en) | Pyrethroid Pesticide | |
| EP2197281B1 (en) | Pesticidal composition and method for controlling pests | |
| WO2009031692A2 (en) | Pesticidal composition and method for controlling pests | |
| CN104023537B (en) | Pest control composition | |
| CN104010507A (en) | Pest Control Composition | |
| CN102475090A (en) | Pesticide composition and method for controlling pests | |
| CN102047902A (en) | Harmful organism-controlling composition and control method of harmful organism | |
| CN102047903A (en) | Pest control composition and pest control method | |
| CN102475089A (en) | Insecticidal composition and method for controlling insects | |
| CN103442573A (en) | Pest control composition and pest control method | |
| CN102475088A (en) | Pesticide composition and method for controlling pests | |
| CN102475091A (en) | Pesticide composition and method for controlling pests | |
| CN102047900A (en) | Harmful organism-controlling composition and control method of harmful organism | |
| KR20120059397A (en) | Pesticidal composition and method for controlling pests | |
| CN102047899A (en) | Pest control composition and pest control method | |
| CN102550591A (en) | Pest control composition and method for controlling pests | |
| CN102550592A (en) | Pest control composition and pest control method | |
| KR20120059396A (en) | Pesticidal composition and method for controlling pests | |
| KR20120059389A (en) | Pesticidal composition and method for controlling pests | |
| KR20120059390A (en) | Pesticidal composition and method for controlling pests | |
| CN102047901A (en) | Pest control composition and pest control method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C05 | Deemed withdrawal (patent law before 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120530 |