TW201124082A - Harmful organism-controlling composition and control method of harmful organisms - Google Patents
Harmful organism-controlling composition and control method of harmful organisms Download PDFInfo
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201124082 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種病蟲害防治組成物及病蟲害之防 治方法。 【先前技術】 式（I)表示之醋化合物：201124082 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a pest control composition and a method for controlling pests and diseases. [Prior Art] The vinegar compound represented by the formula (I):
(I)(I)
為習知病蟲害防治製劑之有效成分（例如參見JP 57-123146A 及 CN 101306997A)。It is an active ingredient of a conventional pest control preparation (see, for example, JP 57-123146A and CN 101306997A).
另外，式（II)表示之酯化合物：Further, the ester compound represented by the formula (II):
(II) 亦為習知病蟲害防治製劑之有效成分（例如參見“Zoku(II) is also an active ingredient of conventional pest control preparations (see, for example, "Zoku"
Iyakuhin no Kaihatsu, vol. 18，Noyaku no Kaihatsu III (The Second Series of Pharmaceutical Research andIyakuhin no Kaihatsu, vol. 18, Noyaku no Kaihatsu III (The Second Series of Pharmaceutical Research and
Development, vol. 18， Management and Development of Agrochemicals III)” ， Hirokawa Publishing Company, 1993， p. 493-514)。 然而，在某些情況中，依特定應用及所欲防治之病害 4 322447 201124082 . 蟲而定，對該已知製劑而言，仍需要具有較高防治效果之 _ 病蟲害防治製劑。 【發明内容】 發明所欲解決之問題 本發明之目的係提供一種對病蟲害具有優異防治效果 之病蟲害防治組成物及病蟲害之防治方法。 解決問題之方法 由於本案發明人致力研究的結果，發現組合使用式（I) 表示之酯化合物及式（II)表示之酯化合物對病蟲害呈現優 異防治效果。據此，完成本發明。 因此，本發明提供： (1) 一種病蟲害防治組成物，包括式（I)表示之酯化合 物：Development, vol. 18, Management and Development of Agrochemicals III)", Hirokawa Publishing Company, 1993, p. 493-514). However, in some cases, depending on the particular application and the disease to be treated 4 322447 201124082 . Therefore, for the known preparation, there is still a need for a pest control preparation having a high control effect. SUMMARY OF THE INVENTION Problems to be Solved by the Invention The object of the present invention is to provide a pest control with excellent control effects against pests and diseases. The method for controlling the composition and the pests and diseases. The method for solving the problem. As a result of the research conducted by the inventors of the present invention, it has been found that the combination of the ester compound represented by the formula (I) and the ester compound represented by the formula (II) exhibits an excellent control effect against pests and diseases. The present invention has been completed. Accordingly, the present invention provides: (1) A pest control composition comprising an ester compound represented by the formula (I):
(I) (後文中稱為本發明酯化合物A)及式（11)表示之酯化合物 之組合：A combination of (I) (hereinafter referred to as the ester compound A of the present invention) and an ester compound represented by the formula (11):
(後文中稱為本發明酯化合物B)作為有效成分； 5 322447 201124082 (2 )根據上述第（1)項之病蟲害防治組成物（後文中稱為本 發明防治組成物），其中，該本發明酯化合物A與該本 發明醋化合物B之重量比在300:1至1:300之範圍。 (3) —種病蟲害之防治方法，包括對病蟲或病蟲棲息處施 用有效量之本發明酯化合物A及本發明酯化合物B之 組合；以及 (4) 一種本發明酯化合物A及本發明酯化合物B之組合以 防治病蟲害之用途。 本發明之效果 本發明防治組成物及防治方法對病蟲害呈現優異防治 效果。 【實施方式】 本發明防治組成物之特徵在於包含本發明酯化合物A 及本發明酯化合物B兩者。 本發明酯化合物A例如可經由JP 57-123146A中所述 方法予以製備。 本發明酯化合物B例如可經由JP 53-91125A中所述方 法予以製備。 本發明酯化合物A及本發明酯化合物B基於在其環丙 烷環之兩個不對稱碳原子而各自可具有異構物。在本發明 中，可以任何比例使用含有活性異構物之酯化合物。 本發明防治組成物對其顯示有防治效果的病蟲害之 實例包含有害節肢動物例如昆蟲病蟲害及蜱蟎類（acarine) 病蟲害。其具體實例係如下列者。 6 322447 201124082 鱗翅目（Lepidoptera)昆蟲病蟲害： 模蛾（填蛾科（Pyralidae))例如稻條堵（rice stem borer)(二化模蛾•si/ppressa/is))、稻縱捲葉蟲 (rice leafroller)(稻縱捲葉野煩蛾 ζζ^ί///?3//5〇)、及印度粉模（Indian meal moth)(印度穀粉 模蛾（/70〇^//?化77?£/77(?仏//3));夜蛾（(^161：111〇1：11)(夜蛾 科（Noctuidae))例如普通夜盜蟲（斜紋夜蛾 7/ί£ΛΓ3))、甜菜行軍蟲（beet armyworm)(甜菜葉蛾 (Spodop tera ex i gua))、稻行軍 A(東方黏螽（Pseudaietia separak))、及甘藍行軍蟲（甘藍夜蛾 ;紋白蝶（粉蝶科（Pieridae))例如普通菜粉蝶 (紋白蝶（P/eWs rapae));捲蛾（捲蛾科（Tortricidae))例 如姬捲葉蛾屬 spp.);果蛾（fruitworm moth) (果姓蛾科（Carposinidae));潛蛾（潛蛾科（Lyonetiidae)); 毒蛾（毒蛾科（Lymantriidae));金翅夜蛾亞科（Plusiae); 地老虎屬（如roii·5 spp.)例如地老虎（黄地老虎 segetum))反小地老免（小地老免（Agrotis ipsi Jon)) ·，葉 蛾屬（Helicoverpa spp.);棉鈴蟲屬（Heliothis spp.); 鑽石背蛾（小菜蛾;直紋稻弄蝶（單 帶弄蝶仰iiaia);製袋衣蛾（casemaking clothes moth)(衣蛾（T7/7ea ;以及織網衣蛾（webbing clothes moth)(衣蛾（77/?eo/a 。 雙翅目（Diptera)昆蟲病蟲害： 蚊（蚊科（Calicidae))例如普遍蚊子（淡色庫蚊（Q//伙 7 322447 201124082 pipiens pal lens)、三微家故{Culex tritaeniorhynchus)、 及南方家蚊（致倦庫蚊（a ti/s));斑蚊屬 (det/es spp.)例如黃熱蚊（埃及斑蚊（Jei/es· aegypi/)、及亞 洲免蚊（白線斑故（Aedes albopictus) ·，按蚊屬（Anopheles spp·)例如中華癌蚊;搖蚊（midges) (搖蚊科（Chironomidae));家繩（家繩科（Muscidae))例如家 繩（家繩（如>sca 、黑家蠅（#£Asca Z?ew/)、嚴腐 繩（false stable fly)(廠腐蠅（#£/sc//?a siaZii^a/Ls·))、及 小家廁繩（lesser housefly)(黃腹廄織（/a77/?ya ca/^az/aris));麗蠅（麗蠅科（Calliphordiae));麻蠅（麻 繩科（Sarcophagidae));花繩（花繩科（Anthomyiidae))例如 種繩（seedcornmaggot)(灰地種繩（/)e7/ap/ai£Ara))、及蔥 *i(onion maggot)(蔥繩;黑色清道夫繩 (black scavenger flies)(黑繩科（Sepidae));果繩（果實 绳科（Tephritidae);潛繩（潛绳科（Agromyzidae));小果繩 (果繩科（Drosophi lidae))例如普遍果繩（野生果繩 (历"osop/zy/a ;蛾蚋（moth flies)(蛾納科 (Psychodidae));蚤蠅（蚤繩科（Phoridae))例如蛋繩 (humpbacked fly)(東亞異蚤繩（ife卵"a •sp/raa/iaWs));蚋（black flies)(蚋科（Simuliidae)); 馬绳（it科（Tabanidae));穩蠅（螫繩科（Stomoxyidae));以 及吸血小黑蚊（biting midges)(蠓科（Ceratopogonidae))。 網翅目（Dictyoptera)昆蟲病蟲害： 蟑螂（斐蠊目（B1 attariae))例如德國蟑螂（德國蜚祿 8 322447 201124082 (及、煙褐蟑螂（黑胸大嫌 /i/Yyg/nosa))、美洲蟑螂（美洲斐嫌 a/z/ericana))、棕色蟑螂（棕色斐罐 (/^Wp7ay7eia 6/7//7/7從））、及東方蟑螂（東方蜚蠊（方 orientalisT)。 膜翅目（Hymenoptera)昆蟲病蟲害： 蟻（蟻科（Formicidae));馬蜂（胡蜂科（vespidae)); 腫腿蜂（腫腿蜂科（Bethylidae));以及葉蜂（葉蜂科 ((Tenthredinidae))例如甘藍葉蜂（黃翅菜葉蜂 rosae) ° 隱翅目（Aphaniptera)昆A病蟲害： 犬蛋{X§：{Ctenocephalides canis)) -iCtenocephalides felis)、、认反备{Purex irritans)、。 兹目（Anoplura)昆蟲病A害： 人裂（人级（Fedicu〗us humans))、毛叙（陰赵 {Phthirus pubis))、琢為X琢為XPedicuius humans capitis))、认反k後後為XPediculus humanus corporis、）。 等翅目（Isoptera)昆蟲病蟲害： 曰本散白蟻（Japanese subterranean termite)(黃胸 l 白緣XReticul itermes speratus)、、认反匀灣 ％白兔 (Formosan subterranean termite)(臺灣家白蟻 (Cop to termes formosanusy)。 9 322447 201124082 半翅目（Hemiptera)昆蟲病蟲害： 飛兹（飛蟲科（〇61〇113(^(136))例如小褐飛兹（3111311 brown ^l^ntho^ev){Μ ^{Laodelphax striatellus))^ 褐稻飛兹（褐飛兹（W/aparraia /wgens))、及白背稻飛益 (白背飛盘（5bga/i/rc//e/*a));葉蟬（1 eafhopper)(浮 塵子科（Del tocephal idae))例如青稻葉禪（黑尾葉蟬 INephotettix cincticeps))、反刍 Μ 黃稻葉蹲{二點 H 案 蟬ry/'esce/?·?));財蟲（财科（Aphididae)); 臭蟲（椿科（Pentatomidae));粉蝨（粉蝨科（Aleyrodidae)); 介殼蟲（軟介殼蟲科（Coccidae));臭蟲（cimices)例如（溫 帶臭蟲/eciiz/aWi/s));軍配蟲（軍配蟲科 (Tingidae));以及木兹（木盘科（Psyliidae))。 鞘翅目（Coleoptera)昆蟲病蟲害： 玉米食根蟲（corn root worms)(葉甲屬（/>/aZ?/O"ca spp_))例如黑皮蠢（black carpet beetle)(姬經節蟲 (diia获/apc^/ciAS))、姬圓經節蟲（varied carpet beet 1 e)(小圓花皮蠢（如FerZ?asc/))、西部玉米食根 方玉米食根蟲（Η —星瓜葉曱（Diabrotica undecimpunctata howardi));金龜子（金龜子科 (Scarabaeidae))例如綠金龜（cupreous chafer)(金銅金龜 (如⑽沒/习、及大豆甲蟲（soybeans beetle)(榛姬 金龜ri/Zbci/prea));象鼻蟲（象鼻蟲科 (Curculionidae))例如玉米象（maize weevil)(玉米象 10 322447 201124082 廳is))、稻水象曱（rice water weevil)(稻 水象甲（Z/5\sar^o/?i/7/s 〇Γ7ζ〇ΐρ/7//ί/5))、棉鈴象曱（bol 1 weevil)(棉鈴象曱（如i/7c>77〇卵s ^ra/2i/ys))、及綠豆象曱 (azuki bean weev i 1)(綠豆象（G/ c/zi/je/^ys));擬步甲（darkling beetles)(擬步甲科 (Tenebrionidae))例如黃粉蟲（yel low mealworm)(黃粉蟲 ((、及赤擬榖盜（red flour beetle)(赤 擬穀盜（7WZ?c>"i/i77 cadaneiM));金花蟲（金花蟲科 (Chrysome 1 i dae ))例如稻泥蟲（稻負泥蟲（伙/_/己历3 oryzae))、 黃條葉蚤（striped flea beetle)(黃條葉蚤（Phyllotreta striolata))、及黃守瓜（cucurbit leaf beetle)(黃守瓜 U"/acop/?ora/e/»ora//s));穀斑皮蠢（drugstore beetle) (竊蠹科（Anobiidae));食植瓢蟲屬（Epilachna spp.)例如 茄二十八星瓢蟲（twenty-e i gh t-spot ted 1 adyb i rd)(茄二 十八i瓢&(Epilachna vigintioctopunctata)).，粉毚& (powder post beetles)(粉蠹亞科（Lyctinae));偽粉蠹 (false powder post beetles)(長蠹蟲科（Bostrichidae)); 天牛（longhorn beetles)(天牛科（Cerambycidae));以及隱 翅蟲（rove beetle)(蟻型隱翅蟲（PaecferiAs /iAscipes)；)。 纓翅目（Thysanoptera)昆蟲病蟲害： 瓜薊馬（Melon thrips)(南黃薊馬历/))、 柑橘黃薊馬（yellow citrus thrips)(西方花莉馬 、以及花薊馬（黑腹刻馬 {Frankliniella intonsa、）。 322447 11 201124082 直翅目（Orthoptera)昆蟲病蟲害： 螻姑（樓姑科（Gryllotalpidae))、以及殖蟲（殖科 (Acrididae)) ° 碑瞒目（Acarina): 家居塵蟎（塵蜗科（Pyroglyphidae))例如美洲塵蜗 QDermatophagoides farinae)、反欲辦魯織 {Dermatophagoides ptrenyssnus) ’，驗織{输織料 (Acaridae))例如霉蜗（mold mite)(腐食胳蜗 p£/tresce/7i_/ae))、及摘圓斑白蜗; 蜱蜗（G1 ycyphag i d m i tes )例如食甜蜗（ privatus)、家 it 辨蟎 QGlycyphagus domesticus)、反苇今 鱗蟎（雖γ/s irwcbar);肉食蟎（肉食蟎科 (Cheyletidae))例如馬六曱肉食蜗（C力印 malaccensis)、反肉食蟎（Cheyletus fortis) ·，細瞒 (Tarosonemid mites)(細蟎科（Tarsonemidae));嗜渣蟎 (Chortoglyphid mites)(嗜渣科（Chortoglyphidae));禽 刺蟎（Haplochthoniid mites)(禽刺蟎科 (Haplochthoniidae));葉蟎（葉蟎科（Tetranychidae))例 如二點葉蜗（二斑葉蜗（Tewri/cae))、神澤葉蜗 (Kanzawa spider mite)(神澤葉蟎(hereinafter referred to as the ester compound B of the present invention) as an active ingredient; 5 322447 201124082 (2) The pest control composition according to the above item (1) (hereinafter referred to as the control composition of the present invention), wherein the present invention The weight ratio of the ester compound A to the vinegar compound B of the present invention is in the range of from 300:1 to 1:300. (3) A method for controlling pests and diseases, comprising administering an effective amount of a combination of the ester compound A of the present invention and the ester compound B of the present invention to a pest or a pest infestation; and (4) an ester compound A of the present invention and the present invention The combination of ester compound B for the purpose of controlling pests and diseases. EFFECT OF THE INVENTION The control composition and the control method of the present invention exhibit excellent control effects on pests and diseases. [Embodiment] The control composition of the present invention is characterized by comprising both the ester compound A of the present invention and the ester compound B of the present invention. The ester compound A of the present invention can be produced, for example, by the method described in JP 57-123146A. The ester compound B of the present invention can be produced, for example, by the method described in JP 53-91125A. The ester compound A of the present invention and the ester compound B of the present invention each may have an isomer based on two asymmetric carbon atoms of the cyclopropane ring. In the present invention, an ester compound containing an active isomer can be used in any ratio. Examples of pests and diseases in which the composition of the present invention exhibits a control effect include harmful arthropods such as insect pests and acarine pests and diseases. Specific examples thereof are as follows. 6 322447 201124082 Lepidoptera insect pests: Moth (Pyralidae) such as rice stem borer (salt moth • si/ppressa/is), rice leaf curler ( Rice leafroller) (Indian rice meal moth) (Indian meal moth) (Indian meal moth) (/70〇^//?? 77? £/77(?仏//3)); Noctuidae ((^161:111〇1:11) (Noctuidae), such as the common night larvae (Striata genus 7/ί£ΛΓ3), Beet armyworm (Spodop tera ex i gua), rice march A (Pseudaietia separak), and cabbage marching insect (Brassica californica; white butterfly (Pieridae) For example, the common cabbage butterfly (P/eWs rapae); the moth (Tortricidae) such as the genus Spodoptera; the fruitworm moth (Carposinidae); the moth (Lyonetiidae); a poisonous moth (Lymantriidae); a genus of the genus Plusiae; a genus of the genus (such as roii·5 spp.) such as the tiger (segetum) Small land old (small land old (Agrotis ipsi Jon)), Helicoverpa spp.; Heliothis spp.; Diamondback moth (Plutella xylostella; Straight-grained rice butterfly (single-banded butterfly iiaia); Casemaking clothes moth (Tattoo moth (T7/7ea; and webbing clothes moth) (cloth moth (77/?eo/a. Diptera insect pest): Mosquito (Mosquito (Calicidae) )) for example, common mosquitoes (K. sylvestris (Q//7 322447 201124082 pipiens pal lens), Sanweijia{Culex tritaeniorhynchus), and southern house mosquitoes (A ti/s); Genus (det/es spp.) such as yellow-heated mosquitoes (Jei/es aegypi/), and Asian mosquito-free (Aedes albopictus), Anopheles spp., such as Chinese cancer Mosquito; midges (Chironomidae); home rope (Muscidae) such as house rope (home rope (eg >sca, black housefly (#£Asca Z?ew/) , false stable fly (factory fly (#£/sc//?a siaZii^a/Ls·)), and lesser housefly (yellow belly weaving (/a77/? Ya ca/^az/aris)); Blowfly Calliphordiae)); flies (Sarcophagidae); flower rope (Anthomyiidae) such as seed rope (seedcornmaggot) (ash ground rope (/) e7/ap/ai£Ara), and onion *i (onion maggot) (black onion rope; black scavenger flies (Sepidae); fruit rope (Tephritidae); submarine (Agromyzidae); small Fruit rope (Drosophi lidae) such as the popular fruit rope (wild fruit rope (calendar "osop/zy/a; moth flies (Psychodidae); ticks (reel) (Phoridae)) such as humpbacked fly (East Asian isopod (ife egg "a • sp/raa/iaWs)); black flies (Simuliidae); horse rope (it family ( Tabanidae)); Stables (Stomoxyidae); and biting midges (Ceratopogonidae). Dictyoptera insect pests and diseases: 蟑螂 (B1 attariae) such as German 蟑螂 (German 8 8 322447 201124082 (and, smoky brown cockroach (black chest suspicion / i / Yyg / nosa)), the Americas蟑螂 (America is suspected of a/z/ericana)), brown 蟑螂 (brown vat (/^Wp7ay7eia 6/7//7/7 from)), and Oriental 蟑螂 (Oriental 蜚蠊 (square orientalisT). Hymenoptera (Hymenoptera) insect pests: ants (Formicidae); wasps (vespidae); swollen bee (Bethylidae); and leaf bee (Tenthredinidae), for example Cabbage leaf bee (Hymenoptera rosae) ° Aphaniptera Kun A pest: Canine egg {X§: {Ctenocephalides canis) -iCtenocephalides felis), 反反备{Purex irritans),. Anoplura Insect Disease A: Human crack (Fedicu us humans), Mao Xu (Phthirus pubis), X琢 is XPedicuius humans capitis)), after recognizing k For XPediculus humanus corporis,). Isoptera insect pests and diseases: Japanese subterranean termite (XReticul itermes speratus), and Formosan subterranean termite (Cop to termes) Formosanusy) 9 322447 201124082 Hemiptera insect pests and diseases: Feizi (Flying worms (〇61〇113(^(136))) eg Xiao Brownez (3111311 brown ^l^ntho^ev) {Μ ^ {Laodelphax striatellus))^ Brown Rice Fitz (W/aparraia /wgens), and Whiteback Rice Fly (White Back Frisbee (5bga/i/rc//e/*a)); e (1 eafhopper) (Del tocephal idae), such as the green rice leaf bud (INephotettix cincticeps), ruminant yellow rice leaf 蹲 {two H case ry / 'esce /? ·?)); Aphididae; Aphididae (Pentatomidae); Aphididae (Aleyrodidae); Scale insect (Coccidae); cimices such as temperate bed bugs /eciiz/aWi/s)); Army worm (Tingidae); and Muzi (Psyliidae). Coleoptera insect pests: corn root worms (/>/aZ?/O"ca spp_) such as black carpet beetle Diia/apc^/ciAS)), variegated carpet beet 1 e (small round flower skin stupid (such as FerZ?asc/)), western corn roots corn rootworm (Η-star) Diabrotica undecimpunctata howardi); Scarabaeidae, such as the cupreous chafer (golden copper turtle (such as (10) no / ha, and soybean beetle (soybeans beetle) (榛姬金龟ri/Zbci/ Prea)); weevil (Curculionidae) such as maize weevil (corn elephant 10 322447 201124082 hall is)), rice water weevil (rice water weevil) /5\sar^o/?i/7/s 〇Γ7ζ〇ΐρ/7//ί/5)), cotton boll symbol (bol 1 weevil) (cotton bell icon (such as i/7c>77〇 eggs s ^ Ra/2i/ys)), and azuki bean weev i 1 (glyph elephant (G/ c/zi/je/^ys)); darkling beetles (Tenebrionidae) )) for example, yel low mealworm (yellow mealworm ((, and Red flour beetle (7WZ?c>"i/i77 cadaneiM); Golden flower worm (Chrysome 1 i dae) such as rice worm (rice negative) Mud worm (gang / _ / 3 calendar / oryzae)), striped flea beetle (Phyllotreta striolata), and cucurbit leaf beetle (黄守瓜 U" / Acop/?ora/e/»ora//s)); drugstore beetle (Anobiidae); Epilachna spp. (twenty-e i gh t-spot ted 1 adyb i rd) (Epilachna vigintioctopunctata), powder post & (powder post beetles) (Lyctinae); False powder post beetles (Bostrichidae); longhorn beetles (Cerambycidae); and rove beetle (PaecferiAs / iAscipes);). Thysanoptera insect pests and diseases: Melon thrips (Southern Yellow Horses)/, yellow citrus thrips (Western flower Lima, and flower horses (black belly horses) {Frankliniella intonsa,) 322447 11 201124082 Orthoptera insect pests: Aunt Gu (Gryllotalpidae), and the genus (Acrididae) ° Acarina: Home dust mites (Pyroglyphidae), for example, QDermatophagoides farinae, Dermatophagoides ptrenyssnus, 'Acaridae', such as mold mite (forged food) /tresce/7i_/ae)), and picking white-spotted snails; G1 ycyphag idmi tes such as privatus, QGlycyphagus domesticus, and 螨 ir irwcbar Carpivore (Cheyletidae) such as the horse scorpion carnivorous snail (C. malaccensis), anti-carnivorous scorpion (Cheyletus fortis), and the genus (Tarosonemid mites) (Tarsonemidae); Chortoglyphid mites (Chorto) Glyphidae)); Haplochthoniid mites (Haplochthoniidae); leaf mites (Tetranychidae) such as the two-point leaf worm (Tewri/cae), the god Kanzawa spider mite
如7?別财/))、柑桔紅蜘蛛（柑桔全爪蟎（作加耶c/?£AS c/iW))、及歐洲紅蟎（European red mite)(榆全爪蟎 · (Panonychus ulmi));蜱（硬蜱科（Ix〇didae))例如長角血 缉CHaemaphysalis longicornis) ·，v人及後寄 ^_織 12 322447 201124082 ' (Parasit〇id mites)(皮刺蜗科（Dermanyssidae))例如北 方禽蜗（northern fowl mite)(禽刺蜗（0/77 、及禽紅蜗（poultry red mite)(雞皮刺蜗 {Dermanyssus gallinaeT)。 特別地，本發明防治組成物對雙翅目昆蟲病蟲害呈現 優異的防治效果，且對蚊（蚊科）呈現更優異的防治效果。 在本發明防治組成物中，只要維持本發明之優異防治 效果，該本發明酯化合物A與該本發明酯化合物B之重量 比無具體限制。通常，該重量比在300 : 1至1 : 300之範 圍，較佳在100 : 1至1 : 100之範圍。 本發明防治組成物可為本發明醋化合物A與本發明g旨 化合物B之單純混合物。然而，通常其係以多種調配物之 形式使用。該調配物之實例包含油性溶液、可乳化濃縮物、 可濕性粉末、懸浮濃縮物（例如水懸浮液及水性乳液）、微 膠囊調配物、粉劑、粒劑、鍵劑、氣霧劑、二氧化碳調配 物、熱散發式（heating vaporization)調配物（例如防蚊卷 (mosquito coil)、電蚊片（electric mosquito mat)、及 液體吸收芯型殺蟲劑（fluid absorption wicking-type pesticide)、壓電型喷散殺蟲劑、熱燦蒸劑（heating fumigant)(例如自燃型燻蒸劑、化學反應型燻蒸劑、及多 孔陶瓷板燻蒸劑）、非熱式燻蒸劑（例如樹脂燻蒸劑、紙製 燻蒸劑、不織布燻蒸劑、織物燻蒸劑、及昇華錠 (sublimation tablet))、噴霧調配物（例如煙霧劑）、直接 接觸型調配物（例如片狀型接觸式調配物、條狀型接觸式調 13 322447 201124082 配物及網狀型接觸式調配物）、ULV調配物及毒餺。 舉例而言’可經由下列方法製備調配物。 (1) 將本發明酯化合物A及本發明酯化合物B與固體 載劑、液體載劑、氣體載劑或飼料混合，若有需要，加入 用於调配物之其他輔助劑例如界面活性劑。 (2) 將基材以本發明酯化合物a及本發明酯化合物B 浸潰。 (3) 將本發明酯化合物a、本發明酯化合物B及基材混 合，接著模製。 這些調配物通常包含本發明酯化合物A及本發明酯化 合物B之總量為〇. 〇〇1至98重量％。 用於調配物之固體載劑之實例包含細粉末及顆粒例 如黏土（例如高嶺土、矽藻土、膨潤土、富巴沙黏土 (Fubasami clay)及酸性白黏土）、合成性水合氧化矽、滑 石、陶瓷、其他無機礦物（例如絹雲母、石英、硫、活性碳、 碳酸鈣、及水合氧化矽）及化學肥料（例如硫酸録、磷酸敍、 硝酸銨、氯化銨及尿素）；及在常溫為固體材料（例如 2,4, 6-三異丙基-1，3, 5-三噚烷、萘、對二氣苯、樟腦及金 剛石）；以及氈製品、纖維、布料、織物、薄片、紙、線狀 物、泡沫、多孔性材料及複纖（multifilament)，其係由一 種或多種羊毛、絲、棉、麻、紙漿、合成樹脂（例如聚乙烯 樹脂諸如低密度聚乙烯、直鏈低密度聚乙烯、及高密度聚 乙烯；乙烯-乙烯酯共聚物諸如乙烯-醋酸乙烯酯共聚物； 乙烯-甲基丙烯酸酯共聚物諸如乙烯-甲基丙烯酸甲酯共聚 14 322447 201124082 -物;、及乙婦-甲基丙稀酸乙醋共聚物；乙烯—Μ酸醋共聚 • 物諸如乙稀-丙稀酸甲s旨共聚物、及乙烯-丙歸峻乙醋共聚 物；乙烯—乙烯基綾酸酯共聚物諸如乙烯-丙烯釀共^物； 乙稀-四環十二碳埽共聚物；聚丙烯樹脂諸如内歸均^物、 及丙烯~乙烯共聚物；聚-4-甲基戊烯_1 ;聚丁烯勺；聚丁 一烯，聚苯乙烯；丙烯腈-苯乙烯樹脂；苯乙烯彈性體諸如 丙烯腈~丁二烯'笨乙烯樹脂、苯乙烯-共軛二烯嵌段共聚 物、及氫化苯乙烯-共軛二烯嵌段共聚物；氟塑膠；丙烯酸 系樹脂諸如聚曱基丙烯酸甲酯；聚醯胺樹脂諸如尼龍6、 及尼龍66 ;聚酯樹脂諸如聚對苯二甲酸乙二酯、聚萘二甲 酉文乙一酉曰、聚對本二曱酸丁二醋、及聚對苯二甲酸伸環己 基一亞甲酯；聚碳酸酯；聚縮醛；聚丙烯砜；聚丙烯酸酯； 聚羥基笨甲酸酯；聚醚醯亞胺；聚酯碳酸酯；聚苯醚樹脂； 聚氯乙婦，聚偏二氯乙烯；聚胺酯；及多孔性樹脂諸如聚 胺酉a泡沫、聚丙烯泡沫、及聚乙烯泡沫）、玻璃、金屬及陶 瓷所組成。 —^體_之實例包含芳香族烴類或脂肪族烴類（例如 一甲笨、甲笨、烧基萘、苯基二甲苯基乙烷、煤油、輕油、 己烧及環己烧）、_化烴類（例如氣苯、二氯甲烧、二氯 ^烷及一氯乙烷）、醇類（例如甲醇、乙醇、異丙醇、丁 醇己醇笨甲醇、及乙二醇）、醚類（例如二乙醚、乙二 醇来甲醚、一乙二醇單曱醚、二乙二醇單乙醚、丙二醇單 二軋匕四氫呋喃、及二噚烷）、酯類（例如醋酸乙酯、及醋 曰）酮類（例如丙酮、甲基乙基酮、甲基異丁基酮、 15 322447 201124082 及環己酮）、腈類（例如乙腈、及異丁腈）、亞砜類（例如二 曱基亞石風）、敌醯胺類（acid amides)(例如N，N-二曱基曱 酿胺、N，N~二曱基乙醯胺、及N-甲基-β比11各咬_)、碳酸烧 二酯（例如碳酸丙二酯）、植物油類（例如大豆油、及棉籽 油）、植物精油類（例如橙油、海索油、及檸檬油）及水。 氣體裁劑之實例包含丁烷氣體、氟氯化碳氣體、液化 石油氣（LPG)、二甲醚、及二氧化碳。 界面活性劑之實例包含烷基硫酸酯鹽類、烷基磺酸 鹽、烷基芳基磺酸鹽、烷基芳基醚類、聚氧伸乙基化烷基 芳基醚類、聚乙二醇醚類、多元醇酯類、及糖醇衍生物。 用於調配物之其他輔助劑之實例包含黏結劑、分散 劑、及安定劑。其具體實例包含酪蛋白、明膠、多醣類（例 如澱粉、阿拉伯膠、纖維素衍生物、及藻酸）、木質素衍生 物、膨潤土、醣、合成水溶性聚合物（例如聚乙烯醇、聚乙 烯吡咯啶酮、及聚丙烯酸）、ΒΗΤ(2, 6_二-第三丁基_4_曱基 紛）及ΒΗΑ(2-第三丁基_4_曱氧基酚與3_第三丁基_4一曱氧 基酚之混合物）。 防蚊卷之基材之實例包含植物粉末（例如木粉、及除 蟲菊）以及黏結劑（例如紅楠樟科7仍 thunbergi i) 之粉末、澱粉、及麩質）之混合物。 電蚊片之基材之實例包含經纏結、壓縮及壓製成平板 狀之棉滅、及經纏結、壓縮及壓製成平板狀之棉絨與紙漿 的混合細纖維。 自燃变燦蒸劑之基材之實例包含可燃的發熱劑 ，例如 16 322447 201124082 硝酸鹽、亞硝酸鹽、胍鹽、氣酸鉀、硝化纖維素、乙基纖 維素、及木粉；熱分解促進劑，例如驗金屬鹽、驗土金屬 鹽、重鉻酸鹽、及鉻酸鹽；載氧劑，例如确酸鉀；助燃劑， 例如三聚氰胺、及小麥澱粉；填料，例如矽藻土；以及黏 結劑，例如合成黏合劑。 化學反應型燻蒸劑之基材之實例包含發熱劑，例如驗 金屬之硫化物、多硫化物及硫氫化物、及氧化#5;催化劑， 例如碳質材料、碳化鐵及活性黏土；有機發泡劑，例如偶 氮二曱醯胺、苯磺醯肼、二硝基五亞曱基四胺、聚苯乙烯 及聚胺酯；及填料，例如天然纖維及合成纖維。 用於例如樹脂燦蒸劑之樹脂之實例包含聚乙浠樹 脂，例如低密度聚乙烯、直鏈低密度聚乙烯、及高密度聚 乙烯；乙烯-乙烯酯共聚物，例如乙烯-醋酸乙烯酯共聚物； 乙烯-曱基丙烯酸酯共聚物，例如乙烯-曱基丙烯酸曱酯共 聚物、及乙烯-曱基丙烯酸乙酯共聚物；乙烯-丙烯酸酯共 聚物，例如乙烯-丙烯酸曱酯共聚物、及乙烯-丙烯酸乙酯 共聚物；乙烯-乙烯基羧酸酯共聚物，例如乙烯-丙烯酸共 聚物；乙烯-四環十二碳烯共聚物；聚丙烯樹脂，例如丙烯 均聚物、及丙烯-乙烯共聚物；聚-4-曱基戊烯-1 ;聚丁烯 -1 ;聚丁二烯；聚苯乙烯；丙烯腈-苯乙烯樹脂；苯乙烯彈 性體，例如丙烯腈-丁二烯-苯乙烯樹脂、苯乙烯-共輛二烯 嵌段共聚物及氫化苯乙烯-共軛二烯嵌段共聚物；氟塑膠； 丙烯酸系樹脂，例如聚曱基丙烯酸曱酯；聚醯胺樹脂，例 如尼龍6及尼龍66;聚酯樹脂，例如聚對苯二曱酸乙二酯、 17 322447 201124082 聚萘二曱酸乙二酯、聚對苯二曱酸丁二酯、及聚對苯二甲 酸伸環己基一亞甲酯；聚碳酸酯；聚縮酸；聚丙烯硬；聚 丙烯酸酯；聚羥基苯曱酸酯；聚醚醯亞胺；聚酯碳酸酯； 聚苯醚樹脂，聚氣乙烯；聚偏二氣乙烯；及聚胺酯。這些 基材可單獨使用或以其組合使用。另外，若有需要，可將 塑化劑，例如本二甲酸醋（例如苯二甲酸二甲醋、及苯二甲 酸二辛酯）、己二酸酯、及硬酯酸加入這些基材。該樹脂燻 蒸劑係經由將本發明酯化合物A及本發明酯化合物B揉捏 入基材，接著經由射出成型、擠壓成型或模壓成型來模製 而製得。所得樹脂調配物可進行進一步加工例如模製或切 割，若有需要，加工成平板、薄膜、帶狀物、網狀物或細 繩之外型。這些樹脂調配物可被加工成，例如，動物頸圈、 動物耳“、平板製品、誘引繩及園藝樁柱（h〇rticuiturai supports) ° 用於毒餌之基材之實例包含飼料成分，例如榖粉、植 物油、糖、及結晶纖維素；抗氧化劑，例如二丁基羥基曱 本、及降二氫癒創木酸（nordihydroguaiaretic acid);防 腐劑，例如去氫乙酸；防兒童及寵物誤食劑，例如辣椒粉； 及誘引病蟲害香料’例如乳路香料、洋,蔥香料、及花生油。 本發明之病蟲害之防治方法係經由將本發明防治組 成物施用至病蟲及/或病蟲棲息處（例如植物體、土壤、戶 外、及動物體）而進行。另外，本發明之病蟲害之防治方法 亦可經由將本發明酯化合物A及本發明酯化合物B施用至 病蟲及/或病蟲棲息處而進行。 18 322447 201124082 • 具體而言’至於本發明防治組成物之應用方法，可由 下列方法例示’且這些方法可根據例如該防治組成物之形 式、及應用位置而予以適當地選擇。 (1) 將本發明防治組成物本身施用至病蟲及/或該病 蟲樓息處。 (2) 將本發明防治組成物以溶劑（例如水）稀釋，接著 施用至病蟲及/或該病蟲棲息處。 此情況中，通常，例如以可乳化濃縮物、可濕性粉末、 懸浮濃縮物或微膠囊製劑之形式之本發明防治組成物係經 稀釋’以使本發明酯化合物A及本發明酯化合物b之總濃 度成為0. 01至l〇〇〇ppm。 (3) 在病蟲棲息處加熱本發明防治組成物，以使有效 成分揮發。 在此情況中’本發明酯化合物A及本發明酯化合物B 之施用率及濃度可根據例如本發明防治組成物之形式、施 用時期、施用位置、施用方法、及傷害情況而適當地決定。 在利用供防治目的用之本發明防治組成物中，就本發 明醋化合物A及本發明酯化合物b之總量而言，當施用於 空間時’施用率通常為〇· 〇〇〇1至1000 mg/m3，而當施用 於平面時，施用率為〇. 0001至1〇〇〇 mg/mi熱散發式調 配物（例如防蚊卷及電蚊片）係根據該調配物之形式來適當 地加熱以使有效成分揮發而施用。非熱散發式燦蒸劑（例如 樹脂燻蒸劑、紙製燻蒸劑、錠劑、不織布燻蒸劑、織物燻 蒸劑、及片狀型調配物）例如可透過將其本身置於欲施用之 19 322447 201124082 空間、或透過將該調配物朝向風而使用。 用於防治目的而施用本發明防治組成物之空間之實 例包含壁櫥、廚台、衣櫃、箱櫃、食櫃、洗手間、浴室、 倉庫、起居室、餐廳、車庫、和汽車内部。另外，該組成 物亦可施用於戶外開放空間。 當本發明防治組成物係用於家畜（例如牛、馬、豬、 綿羊、山羊及雞）及小型動物（例如狗、貓、大鼠及小鼠） 以達到防治外寄生蟲之目的時，可經獸醫領域中之已知方 法施加到所述動物。具體而言，當欲用於全身性防治時， 該調配物係藉由錠劑、飼料混合物、栓劑及注射劑（包含肌 内注射、皮下注射、靜脈注射及腹腔注射）之方式投予。另 一方面，當欲用於非全身性防治時，該調配物係藉由喷灑 油性溶液或水性溶液、洗注（pour-on)處理或滴注（spot -on) 處理、以洗髮精調配物來洗滌動物、或將樹脂調配物製成 的頸圈或耳標安裝於動物之方式來使用。本發明酯化合物 A及本發明醋化合物B之總劑量通常係每1公斤（kg)動物 體重為0. 01至1000毫克（mg)之範圍。 本發明防治組成物可組合使用，或與其他成分混合， 例如病蟲害防治劑諸如其他殺昆蟲劑、殺蟎劑、及拒避劑 (repellents)、增效劑、及色素。 後文，將藉由調配例及試驗例更詳細說明本發明。但 本發明並不受限於該等實施例。 首先，敘述本發明防治組成物之調配例。在調配例中， 除非另行說明，否則所有“份數”皆以重量計。 20 322447 201124082 調配例1 將9份本發明酯化合物A及〇. 9份本發明酯化合物b 溶於37· 5份二甲苯及37.5份N，N-二曱基曱醯胺中。於所 得溶液中加入9. 1份聚氧伸乙基苯乙烯基苯基醚及6份十 二烧基笨磺酸鈣’接著充分混合，獲得可乳化濃縮物。 調配例2 於2〇份本發明酯化合物a及20份本發明醋化合物β 中加入5份S0RP0L 5060(東邦化學工業公司（ΤΟΗΟSuch as 7? Do not make money /)), citrus red spider (citrus full claw 作 (for Gaya c /? £ AS c / iW)), and European red mite (榆 螨 螨 ( ( Panonychus ulmi)); 蜱 (Ix〇didae) such as the long-horned blood clam (Caemaphysalis longicornis) ·, v people and post ^ woven 12 322447 201124082 ' (Parasit〇id mites) Dermanyssidae)) for example, northern fowl mite (0/77, and poultry red mite (Dermanyssus gallinaeT). In particular, the control composition of the present invention is double-winged The insect insect pests exhibit excellent control effects and exhibit superior control effects against mosquitoes (mosquitoes). In the control composition of the present invention, the ester compound A of the present invention and the present invention are maintained as long as the excellent control effect of the present invention is maintained. The weight ratio of the ester compound B is not particularly limited. Usually, the weight ratio is in the range of 300:1 to 1:300, preferably in the range of 100:1 to 1:100. The control composition of the present invention may be the vinegar compound of the present invention. A is a simple mixture of the present invention and the compound B. However, it is usually a plurality of In the form of a substance, examples of the formulation include an oily solution, an emulsifiable concentrate, a wettable powder, a suspension concentrate (for example, an aqueous suspension and an aqueous emulsion), a microcapsule formulation, a powder, a granule, a key, Aerosol, carbon dioxide formulation, heating vaporization formulation (eg, mosquito coil, electric mosquito mat, and fluid absorption wicking-type) Pesticide, piezoelectric spray insecticide, heating fumigant (such as self-ignition fumigant, chemical reaction fumigant, and porous ceramic plate fumigant), non-heat fumigant (such as resin fumigation) Agents, paper fumigants, non-woven fumigants, fabric fumigants, and sublimation tablets, spray formulations (eg aerosols), direct contact formulations (eg sheet contact formulations, strips) Type contact type 13 322447 201124082 Formulation and mesh type contact formulation), ULV formulation and toadstool. For example, the formulation can be prepared by the following method. (1) The ester compound A of the present invention and the ester compound B of the present invention are mixed with a solid carrier, a liquid carrier, a gas carrier or a feed, and if necessary, other adjuvants such as a surfactant for the formulation are added. (2) The substrate is impregnated with the ester compound a of the present invention and the ester compound B of the present invention. (3) The ester compound a of the present invention, the ester compound B of the present invention and a substrate are mixed and then molded. These formulations usually comprise the total amount of the ester compound A of the present invention and the ester compound B of the present invention of from 0.1 to 98% by weight. Examples of solid carriers for formulations include fine powders and granules such as clay (e.g., kaolin, diatomaceous earth, bentonite, Fubasami clay, and acid white clay), synthetic hydrated cerium oxide, talc, ceramics. , other inorganic minerals (such as sericite, quartz, sulfur, activated carbon, calcium carbonate, and hydrated cerium oxide) and chemical fertilizers (such as sulphuric acid, phosphoric acid, ammonium nitrate, ammonium chloride and urea); and solid at room temperature Materials (eg 2,4,6-triisopropyl-1,3,5-trioxane, naphthalene, p-halobenzene, camphor and diamond); and felts, fibers, fabrics, fabrics, sheets, paper, Linear, foam, porous material and multifilament, which are made of one or more of wool, silk, cotton, hemp, pulp, synthetic resin (eg polyethylene resin such as low density polyethylene, linear low density poly Ethylene, and high density polyethylene; ethylene-vinyl ester copolymer such as ethylene-vinyl acetate copolymer; ethylene-methacrylate copolymer such as ethylene-methyl methacrylate copolymer 14 322447 201124082 - And ethylene-methyl acrylate copolymer; ethylene-capric acid vinegar copolymer; such as ethylene-acrylic acid methyl s copolymer, and ethylene-propylene acetonitrile copolymer; ethylene-ethylene a phthalic acid ester copolymer such as an ethylene-propylene pulverized copolymer; an ethylene-tetracyclododeca ruthenium copolymer; a polypropylene resin such as an internal homogenate, and a propylene-ethylene copolymer; poly-4-methyl Pentene-1; polybutene spoon; polybutene, polystyrene; acrylonitrile-styrene resin; styrene elastomer such as acrylonitrile-butadiene' stupid vinyl resin, styrene-conjugated diene Segment copolymer, and hydrogenated styrene-conjugated diene block copolymer; fluoroplastic; acrylic resin such as polymethyl methacrylate; polyamine resin such as nylon 6, and nylon 66; polyester resin such as poly pair Ethylene phthalate, polynaphthyl phthalate, poly-p-butyl diacetate, and poly(trimethylene terephthalate); polycarbonate; polyacetal; polypropylene Sulfone; polyacrylate; polyhydroxy benzoate; polyether oximine; polyester carbonate; polyphenylene ether resin; Polyvinylidene chloride; polyurethane; porous resin and a polyamine such as a unitary foam, polypropylene foam and polyethylene foam), glass, metals and ceramics composed. Examples of the invention include aromatic hydrocarbons or aliphatic hydrocarbons (for example, a phenyl group, a stupid, a naphthyl, a phenyl dimethyl benzene, a kerosene, a light oil, a hexane, and a cyclohexane), _ hydrocarbons (such as gas benzene, methylene chloride, dichlorosilane and monochloroethane), alcohols (such as methanol, ethanol, isopropanol, butanol, methanol, and ethylene glycol), Ethers (eg diethyl ether, ethylene glycol to methyl ether, monoethylene glycol monoterpene ether, diethylene glycol monoethyl ether, propylene glycol mono-distilled tetrahydrofuran, and dioxane), esters (eg ethyl acetate, And acetophenone) ketones (such as acetone, methyl ethyl ketone, methyl isobutyl ketone, 15 322447 201124082 and cyclohexanone), nitriles (such as acetonitrile, and isobutyronitrile), sulfoxides (such as two曱基亚石风), acid amides (such as N,N-dimercaptoamine, N,N-didecylacetamide, and N-methyl-β ratio 11 bites _), carbonic acid diesters (such as propylene carbonate), vegetable oils (such as soybean oil, and cottonseed oil), plant essential oils (such as orange oil, hysoe oil, and lemon oil) and water. Examples of the gas trimming agent include butane gas, carbon fluorocarbon gas, liquefied petroleum gas (LPG), dimethyl ether, and carbon dioxide. Examples of the surfactant include alkyl sulfate salts, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers, polyoxyethylated alkyl aryl ethers, polyethylene Alcohol ethers, polyol esters, and sugar alcohol derivatives. Examples of other adjuvants for the formulation include a binder, a dispersant, and a stabilizer. Specific examples thereof include casein, gelatin, polysaccharides (for example, starch, gum arabic, cellulose derivatives, and alginic acid), lignin derivatives, bentonite, sugar, synthetic water-soluble polymers (for example, polyvinyl alcohol, poly Vinyl pyrrolidone, and polyacrylic acid), hydrazine (2,6-di-t-butyl-4-methyl-fluorenyl) and hydrazine (2-tert-butyl-4-yloxyphenol and 3_third a mixture of butyl-4-methoxyphenol). Examples of the substrate of the anti-mosquito roll include a mixture of a plant powder (e.g., wood flour, and pyrethrum) and a binder (e.g., a powder of starch, starch, and gluten). Examples of the substrate of the mosquito-repellent sheet include a woven fiber which is entangled, compressed, and pressed into a flat shape, and a mixed fine fiber which is entangled, compressed, and pressed into a flat cotton lint and pulp. Examples of the substrate of the self-igniting and flavoring fuming agent include a flammable heat generating agent, for example, 16 322447 201124082 nitrate, nitrite, strontium salt, potassium oxylate, nitrocellulose, ethyl cellulose, and wood powder; thermal decomposition promotion Agents such as metal salts, soil metal salts, dichromates, and chromates; oxygen carriers such as potassium sulphate; combustion improvers such as melamine, and wheat starch; fillers such as diatomaceous earth; Agents such as synthetic binders. Examples of the substrate of the chemical reaction type fumigant include a heat generating agent such as a metal sulfide, a polysulfide and a sulfur hydride, and an oxidation #5; a catalyst such as a carbonaceous material, iron carbide, and activated clay; organic foaming Agents such as azodiamine, benzenesulfonamide, dinitropentamethylenetetramine, polystyrene and polyurethane; and fillers such as natural fibers and synthetic fibers. Examples of the resin used for, for example, a resin fumigant include polyethylene oxide resins such as low density polyethylene, linear low density polyethylene, and high density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymerization. An ethylene-mercapto acrylate copolymer, such as an ethylene-mercapto methacrylate copolymer, and an ethylene-ethyl methacrylate copolymer; an ethylene-acrylate copolymer, such as an ethylene-acrylic acid acrylate copolymer, and Ethylene-ethyl acrylate copolymer; ethylene-vinyl carboxylate copolymer, such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resin, such as propylene homopolymer, and propylene-ethylene Copolymer; poly-4-mercaptopentene-1; polybutene-1; polybutadiene; polystyrene; acrylonitrile-styrene resin; styrene elastomer, such as acrylonitrile-butadiene-benzene Vinyl resin, styrene-co-diene block copolymer and hydrogenated styrene-conjugated diene block copolymer; fluoroplastic; acrylic resin, such as polydecyl methacrylate; polyamine resin, such as nylon 6 and nylon 66; polyester Lipids, such as polyethylene terephthalate, 17 322447 201124082 polyethylene naphthalate, butylene terephthalate, and poly(p-phenylene terephthalate); Carbonate; polycondensate; polypropylene hard; polyacrylate; polyhydroxybenzoic acid ester; polyether quinone imine; polyester carbonate; polyphenylene ether resin, polyethylene ethylene; polyvinylidene ethylene; . These substrates may be used singly or in combination. Further, if necessary, a plasticizer such as the present dicarboxylic acid vinegar (e.g., dimethyl phthalate, and dioctyl phthalate), adipate, and stearic acid may be added to these substrates. The resin fumigant is obtained by kneading the ester compound A of the present invention and the ester compound B of the present invention into a substrate, followed by molding by injection molding, extrusion molding or press molding. The resulting resin formulation can be subjected to further processing such as molding or cutting, and if desired, to a flat sheet, film, ribbon, web or string. These resin formulations can be processed into, for example, animal collars, animal ears, flat products, attracting ropes, and gardening piles (h〇rticuiturai supports). Examples of substrates for baits include feed ingredients such as tantalum powder. , vegetable oils, sugars, and crystalline cellulose; antioxidants such as dibutyl hydroxy guanidine, and nordihydroguaiaretic acid; preservatives such as dehydroacetic acid; anti-child and pet ingestants, For example, paprika; and attracting pests and fragrances such as milk curd, ocean, onion flavor, and peanut oil. The pest control method of the present invention is applied to the pest and/or pest habitat by applying the control composition of the present invention (for example) The method for controlling pests and diseases of the present invention can also be carried out by applying the ester compound A of the present invention and the ester compound B of the present invention to a pest and/or a pest habitat. 18 322447 201124082 • Specifically, as for the application method of the control composition of the present invention, it can be exemplified by the following methods and the methods can be based on, for example, The form and the application position of the control composition are appropriately selected. (1) The control composition of the present invention itself is applied to the pests and/or the pests and the like. (2) The composition of the present invention is controlled by The solvent (for example, water) is diluted and then applied to the pest and/or the pest habitat. In this case, usually, for example, in the form of an emulsifiable concentrate, a wettable powder, a suspension concentrate or a microcapsule preparation The composition of the present invention is diluted so that the total concentration of the ester compound A of the present invention and the ester compound b of the present invention is from 0.01 to 1 ppm. (3) heating the composition of the present invention in the habitat of the pest, In order to volatilize the active ingredient. In this case, the application rate and concentration of the ester compound A of the present invention and the ester compound B of the present invention may be, for example, according to the form of the control composition of the present invention, the application period, the application site, the application method, and the injury condition. With appropriate control. In the control composition of the present invention for use for control purposes, the application rate is usually "when applied to space" in terms of the total amount of the vinegar compound A of the present invention and the ester compound b of the present invention. 〇·〇〇〇1 to 1000 mg/m3, and when applied to a flat surface, the application rate is 〇. 0001 to 1〇〇〇mg/mi heat-distributing formulation (eg, mosquito-repellent and electric mosquito) Appropriately heated according to the form of the formulation to volatize the active ingredient. Non-heat-spreading type steaming agent (for example, resin fumigant, paper fumigant, lozenge, non-woven fumigant, fabric fumigant, and flake The formulation may be used, for example, by placing itself in the space of 19 322447 201124082 to be applied, or by directing the formulation toward the wind. Examples of the space for applying the control composition of the present invention for control purposes include a closet, a kitchen Desk, wardrobe, bins, pantry, washroom, bathroom, warehouse, living room, dining room, garage, and car interior. Alternatively, the composition can be applied to an outdoor open space. When the control composition of the present invention is used for livestock (such as cattle, horses, pigs, sheep, goats, and chickens) and small animals (such as dogs, cats, rats, and mice) for the purpose of controlling ectoparasites, The animal is applied by methods known in the veterinary art. Specifically, when intended for systemic control, the formulation is administered by a lozenge, a feed mixture, a suppository, and an injection (including intramuscular injection, subcutaneous injection, intravenous injection, and intraperitoneal injection). On the other hand, when intended for non-systemic control, the formulation is prepared by spraying an oily solution or an aqueous solution, a pour-on treatment or a spot-on treatment, and a shampoo. The formulation is used to wash the animal or to attach a collar or ear tag made of the resin formulation to the animal. The total dose of the ester compound A of the present invention and the vinegar compound B of the present invention is usually in the range of 0.01 to 1000 mg (mg) per 1 kg (kg) of animal body weight. The control composition of the present invention may be used in combination or mixed with other ingredients such as pest control agents such as other insecticides, acaricides, repellents, synergists, and pigments. Hereinafter, the present invention will be described in more detail by way of formulation examples and test examples. However, the invention is not limited to the embodiments. First, a formulation example of the control composition of the present invention will be described. In the formulation examples, all "parts" are by weight unless otherwise stated. 20 322447 201124082 Formulation Example 1 9 parts of the ester compound A of the present invention and 9 parts of the ester compound b of the present invention were dissolved in 37. 5 parts of xylene and 37.5 parts of N,N-didecylguanamine. To the resulting solution, 9.1 parts of polyoxyethylidene phenyl ether and 6 parts of calcium dodecyl sulfonate were added, followed by thorough mixing to obtain an emulsifiable concentrate. Formulation Example 2 5 parts of S0RP0L 5060 (Toho Chemical Industry Co., Ltd.) were added to 2 parts of the ester compound a of the present invention and 20 parts of the vinegar compound β of the present invention.
Chemical industry Co·，Ltd.)之註冊商標）’接著充分混 合。於所得混合物中加入32份CARPLEX #80(Shionogi & c〇· ’ Ltd.之註冊商標，為合成性水合氧化矽細粉）及份 300筛目之矽藻土，接著以果汁機混合，獲得可濕性粉末。 調配例3The registered trademark of Chemical industry Co., Ltd.) is then thoroughly mixed. To the resulting mixture, 32 parts of CARPLEX #80 (registered trademark of Shionogi & c〇· ' Ltd., which is a synthetic hydrated cerium oxide fine powder) and 300 parts of diatomaceous earth were added, followed by mixing with a juice machine. Wettable powder. Matching example 3
於3份本發明酯化合物a及〇 3份本發明酯化合物B 醆入5份合成性水合氧化矽細粉、5份十二烷基苯磺酸 =、30份膨潤土及56. 7份黏土，接著充分㈣及混合。 ^ 將適當用量的水加入所得混合物内。進一步攪拌混 :物’以製粒機製粒，再經風乾，獲得顆 調配例4 护」料充分混合5份本發明8旨化合物A、G. 5份本發明 之B、1份合成性水合氧切細粉、1份作為絮凝劑 ^ Riles B(i^^#^t^(Dai.ch〇 Sanky〇 c〇<> j之註冊商標）及7份黏土，接料果汁機猜及混合。 ;1¾合物内加入85.5份切削黏土㈣咖），接著充 322447 21 201124082 分攪拌及混合，獲得粉劑調配物。 調配例5 將10份本發明酯化合物A、1份本發明酯化合物B、 35份含有一半用量聚氧伸乙基烷基醚硫酸酯銨鹽之白碳、 及54份水之混合物經由濕式硏磨法來細碎粒化，獲得粉劑 調配物。 調配例6 將0. 05份本發明酯化合物A及0. 1份本發明酯化合物 B溶於10份二氯曱烷中，且所得溶液與89. 85份異烷烴溶 液（ISOPARM，埃克森(Exxon)化工公司之註冊商標）混合， 獲得油性溶液。 調配例7 將0. 1份本發明酯化合物A、0. 05份本發明酯化合物 B、及 49. 85 份 Neothiozole(Chuo Kasei CO.，Ltd.)置於 氣溶膠罐中。在附接氣溶膠閥後，裝填25份二甲醚及25 份LPG，接著振盪並進一步附接致動器（actuator)，獲得 油性氣溶膠。 調配例8 將0. 5份本發明酯化合物A、0. 05份本發明酯化合物 B、0. 01份BHT、5份二曱苯、3. 44份去臭煤油及1份乳化 劑（Atomos 300，Atomos化學公司之註冊商標）之混合物與 50份蒸餾水裝填入氣溶膠容器中，並附接閥部件。然後， 在加壓下將40份推進劑（LPG)經由閥裝填進氣溶膠容器 中，獲得水性氣溶膠。 22 322447 201124082 調配例9 將件〇. 5公分（cm)厚、69公分長及〇. 2公分寬具有 蜂巢結構之紙品從其一端捲起以製得直徑5 5公分及高 0. 2公分之圓筒形載體。將適當用量之經由使5份本發明 醋化合物A及〇. 5份本發明酯化合物b溶於94. 5份丙酮中 所製付的溶液均勻地塗布到上述載體並經由風乾使丙酮揮 發’獲传紙製蒸發式調配物。 調配例10 將二維經編針織物（商標名：FUSION，產品型號： AKE69440 ’ 經銷商· Asahi Kasei Fibers Corporation.， 厚度：4. 3公分，織物密度：321公克/平方公尺（g/m2)， 聚酿胺所製）剪裁成5公分直徑之圓形。將適當用量之經由 使5份本發明酯化合物a及〇. 5份本發明酯化合物b溶於 94. 5份丙_中所製得的溶液均勻地塗布到上述圓形三維 經編針織物’並經由風乾使丙酮揮發，獲得編針織物蒸發 式調配物。 調配例11 將97.8份乙烯-甲基丙烯酸曱酯共聚物（甲基丙烯酸 曱醋含量：10重量％，MFR=2[g/1〇 min. D、2份本發明酯 化合物A及〇. 2份本發明酯化合物b之混合物在130¾使 用在相同方向旋轉之45 mm0雙螺桿擠出機熔融及揉合， 再進一步在150 C使用40 mm0擠出機溶融及揉合，接著從 呈薄片外形之T鑄模擠出，再以冷卻輪冷卻’獲得樹脂蒸 發式調配物。 23 322447 201124082 調配例12 將97.8份乙烯-醋酸乙烯酯共聚物（醋酸乙烯酯含 量：10重量％，MFR=2[g/10 min. ])、2份本發明酯化合物 A及0. 2份本發明酯化合物B之混合物在130°C使用在相同 方向旋轉之45匪0雙螺桿擠出機熔融及揉合，再進一步 在150°C使用40丽擠出機熔融及揉合，接著從呈薄片外 形之T鑄模擠出，再以冷卻輪冷卻，獲得樹脂蒸發式調配 物。 調配例13 將5份本發明酯化合物A及0. 5份本發明酯化合物B 溶於94. 5份丙酮，將適當量之所得溶液塗布到具有可摺疊 結構之紙（2000 cm2)，並經由風乾使丙酮揮發，獲得紙製 蒸發式調配物。 調配例14 經由使3份本發明酯化合物A及0.3份本發明酯化合 物B溶於14. 6份丙酮而製得溶液。於此溶液内，加入0. 2 份氧化鋅、1. 0份α澱粉及42. 8份偶氮二曱醯胺。另外， 於其内加入38. 1份水，並揉合混合物，使用擠出機模製顆 粒外形，再乾燥以獲得顆粒。在其中央部份有鋁隔板分隔 之容器中，將該顆粒置於其上部空間，並將50克氧化鈣置 於其下部空間，獲得燻蒸劑。 調配例15 於0.5份氧化辞、2份α澱粉及97. 5份偶氮二曱醯胺 之混合物内加入水，並揉合混合物及使用擠出機模製顆粒 24 322447 201124082 外形，再乾燥以獲得顆粒。然後，將2克顆粒均勻地浸潰 在0. 58克本發明酯化合物A及0. 058克本發明酯化合物B 於丙酮之溶液中，並乾燥以獲得顆粒。在其中央部份有鋁 隔板分隔之容器中，將該顆粒置於其上部空間，並將50 克氧化鈣置於其下部空間，獲得燻蒸劑。 調配例16 將0. 5克本發明酯化合物A及0. 05克本發明酯化合物 B溶於20毫升（mL)丙酮中，並將所得溶液加入99.4克用 於防蚊卷之基材（呈4 ·· 3 ·· 3之比例的紅楠樟科之粉末、除 蟲菊及木粉之混合物）及0.3克綠色色素之混合物内。充分 混合後，將120毫升水加入該混合物並充分揉合。模製及 乾燥所得混合物，獲得防蚊卷。 調配例17 經由混合10份本發明酯化合物A、1份本發明酯化合 物B、39. 5份乙醯化檸檬酸三丁酯、39. 5份己二酸異壬酯、 5份藍色色素及5份香料以製得溶液。將用於3. 4公分x2. 1 公分且0. 22公分厚的電蚊片之基材（經纏結、壓縮及壓製 成平板狀之棉絨與紙漿的混合細纖維）均勻地浸潰在上述 溶液，獲得電蚊片。 調配例18 經由使0. 1份本發明酯化合物A及0. 01份本發明酯化 合物B溶於99. 89份去臭煤油而製得溶液。將該溶液置於 氯乙烯容器，及將經加工以使其上半部可經由加熱器加熱 之液體吸收芯（經由以黏合劑固化無機粉末接著煅燒而製 25 322447 201124082 得）插進該容器内，獲得一份用於液體吸收芯型蒸發式調配 物。 調配例19 將0. 2份本發明酯化合物A、0. 02份本發明酯化合物 B、及 49. 78 份 Neothiozole(Chuo Kasei CO.，Ltd.)置於 氣溶膠罐中。在附接氣溶膠閥後，裝填25份二曱醚及25 份LPG，接著振盪並進一步附接用於全内容物-注入型氣溶 膠之致動器，獲得氣溶膠調配物。 調配例20 於0. 2份本發明酯化合物A及0. 02份本發明酯化合物 B内加入99. 78份二乙二醇單乙醚，接著充分混合，獲得 用於防治外寄生蟲之滴注調配物。 調配例21 將經由使3份本發明酯化合物A及0.3份本發明酯化 合物B溶於96. 7份丙酮而製得溶液，並將1毫升溶液均勻 地塗布到經由在壓力（4t/cm2)下模製4克2, 4, 6-三異丙基 -1，3, 5-三噚烷所得之盤形固體材料（3公分直徑及3毫米 (mm)厚），接著乾燥獲得錠劑。 調配例2 2 在壓力下將0. 2克本發明酯化合物A、0. 02克本發明 酯化合物B、及4克2, 4, 6-三異丙基-1,3,5-三卩等烧之均勻 混合物模製為盤形（3公分直徑及3毫米厚），獲得錠劑。 調配例2 3 將0. 2克本發明酯化合物A、0. 02克本發明酯化合物 26 322447 201124082 • 4克2’4’6_三異丙基、1，3,5-三曙烧之混合物置於50 •毫升歡管，經加熱溶融然後冷卻至室溫，獲得錠劑。 接著下列試驗例將_示本發明防治組成物對病蟲害 具有優異防治效果。 在下列試驗财，至於本發_化合物A，使用⑽-反式-3-(2,2-二氯乙稀基）、2,2_二曱基環丙院叛酸 [2, 3, 5, 6-四氟_4-(甲氧基甲基）苯基]曱酯。 另外，至於本發明酯化合物B，使用（1R)-順式/反式 -2’2~二曱基-3-(2-甲基-!、丙炔基）環丙烧減3苯氧基 苯甲g旨。 試驗例1 在下表1所不濃度下’經以給定量異烷烴溶劑（IS〇pAR Μ，埃克森化學公司之註冊商標）稀釋本發明酯化合物B而 製得油性溶液（後文中稱作為比較組成物（丨））。同樣地，在 下表1所示濃度下，經以給定量異烷烴溶劑（is〇parm，埃 克森化學公司之註冊商標）稀釋本發明酯化合物A而製得 油性溶液（後文中稱作為比較組成物（2 )及（3 ))。 另外，在下表1所示有效成分之濃度下，經以給定量 異烧煙溶劑（ISOPAR M，埃克森化學公司之註冊商標）稀釋 本發明酯化合物A及本發明酯化合物B而製得油性溶液（後 文中稱作為本發明組成物（1)及（2))。 將10隻庫蚊pipie/3s)(雌性）釋放至每邊 公分的立方形箱中’並以喷槍（喷灑壓力：0 9 kg/cm2)從 該箱中央的小窗戶喷進0.7毫升本發明組成物（丨）。在喷激 322447 27 201124082 後給定時間期間，調查擊落的昆蟲數目並計算擊落率 (knock down rate，KD率）。依照相同方法，使用本發明 組成物（2)及比較組成物（1)、（2)及（3)，計算在給定時間 期間後之KD率（2次）。 結果係顯示於表1。 表1 本發明酯化合物A 用量（W/V%) 本發明酯化合物B 用量(WA%) 7分鐘後之KD率 (%) 本發明組成物（1) 0.00313 0.2 80 比較組成物（1) - 0.2 10 比較組成物（2) 0.00313 - 20 本發明組成物（2) 0.00156 0.2 60 比較組成物（3) 0.00156 - 10 如上述，本發明可提供對病蟲害具有優異效果之病蟲 害防治組成物及病蟲害防治方法。 【圖式簡單說明】 無 【主要元件符號說明】 無 28 322447份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份的份份Then fully (four) and mix. ^ Add the appropriate amount of water to the resulting mixture. Further stirring and mixing: the material is granulated by the granulation mechanism, and then air-dried to obtain the granules, and the mixture is mixed with 5 parts of the present invention. The compound A, G. 5 parts of the present invention B, 1 part of synthetic hydrated oxygen Cut fine powder, 1 part as flocculant ^ Riles B (i^^#^t^(Dai.ch〇Sanky〇c〇<> j registered trademark) and 7 parts of clay, picking juice machine guess and mix Add 85.5 parts of cutting clay (4) coffee to the 13⁄4 compound, then add 322447 21 201124082 to mix and mix to obtain a powder formulation. Formulation Example 5 10 parts of the ester compound A of the present invention, 1 part of the ester compound B of the present invention, 35 parts of a white carbon containing a half amount of polyoxyethylidene ether sulfate ammonium salt, and 54 parts of water were passed through a wet type. The honing method is used to finely granulate and obtain a powder formulation. Formulation Example 6 0.05 parts of the ester compound A of the invention and 0.1 part of the ester compound B of the invention are dissolved in 10 parts of dichloromethane, and the resulting solution is combined with 89.85 parts of isoparaffin solution (ISOPARM, Exxon). (Exxon) registered trademark of the chemical company) mixed to obtain an oily solution. Formulation Example 7 0.1 parts of the ester compound A of the present invention, 0.05 parts of the ester compound B of the present invention, and 49.85 parts of Neothiozole (Chuo Kasei CO., Ltd.) were placed in an aerosol can. After attaching the aerosol valve, 25 parts of dimethyl ether and 25 parts of LPG were charged, followed by shaking and further attaching an actuator to obtain an oily aerosol.份份例例8 0. 5 parts of the present ester compound A, 0.05 parts of the present invention ester compound B, 0.01 part of BHT, 5 parts of diphenylbenzene, 3.44 parts of deodorized kerosene and 1 part of emulsifier (Atomos 300, a registered trademark of Atomos Chemical Co., Ltd.) is filled with 50 parts of distilled water into an aerosol container and attached to the valve member. Then, 40 parts of propellant (LPG) was charged into the air sol container via a valve under pressure to obtain an aqueous aerosol. 2厘米分分。 The 例 公 5 5 5 5 5 5 5 5 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公 公Cylindrical carrier. A suitable amount of a solution prepared by dissolving 5 parts of the vinegar compound A of the present invention and 5 parts of the ester compound b of the present invention in 94.5 parts of acetone is uniformly applied to the above carrier and volatilized by air drying. Paper transfer evaporative formulation. Formulation Example 10 A two-dimensional warp knit fabric (trade name: FUSION, product model: AKE69440' dealer. Asahi Kasei Fibers Corporation., thickness: 4.3 cm, fabric density: 321 g/m2 (g/m2) , made of polyamine, cut into a circle of 5 cm diameter. A solution prepared by dissolving 5 parts of the ester compound a of the present invention and 5 parts of the ester compound b of the present invention in 94.5 parts of C-form is uniformly applied to the above-mentioned circular three-dimensional warp knit fabric' The acetone was volatilized by air drying to obtain a knitted fabric evaporative formulation. Formulation Example 11 97.8 parts of an ethylene-methyl methacrylate copolymer (methacrylic acid vinegar content: 10% by weight, MFR = 2 [g / 1 〇 min. D, 2 parts of the present ester compound A and 〇. 2) A mixture of the ester compounds b of the present invention is melted and kneaded at 1303⁄4 using a 45 mm0 twin-screw extruder rotating in the same direction, and further melted and kneaded at 150 C using a 40 mm0 extruder, followed by a sheet shape. T mold extrusion, and then cooling with a cooling wheel to obtain a resin evaporation formulation. 23 322447 201124082 Formulation Example 12 97.8 parts of ethylene-vinyl acetate copolymer (vinyl acetate content: 10% by weight, MFR = 2 [g / 10 min. ]), 2 parts of the ester compound A of the invention and 0.2 part of the ester compound B of the invention are melted and kneaded at 130 ° C using a 45 匪 0 twin-screw extruder rotating in the same direction, and further Melt and knead at 150 ° C using a 40 liter extruder, followed by extrusion from a T-die in a sheet shape, followed by cooling with a cooling wheel to obtain a resin evaporating formulation. Formulation Example 13 5 parts of the ester compound A of the present invention And 5 parts of acetone, which will be dissolved in 94. 5 parts of acetone. The equivalent solution was applied to a paper having a foldable structure (2000 cm2), and acetone was volatilized by air drying to obtain a paper evaporative formulation. Formulation Example 14 By making 3 parts of the ester compound A of the present invention and 0.3 part of the ester of the present invention The solution of the compound B is dissolved in 14. 6 parts of acetone. In this solution, 0.2 parts of zinc oxide, 1.0 part of alpha starch and 42.8 parts of azodiamine are added. Adding 38.1 parts of water, kneading the mixture, molding the shape of the granules using an extruder, and drying to obtain granules. The granules are placed in the upper space in a container having a central partition separated by an aluminum partition. 50 g of calcium oxide was placed in the lower space to obtain a fumigant. Formulation Example 15 Water was added to a mixture of 0.5 parts of oxidation, 2 parts of alpha starch and 97.5 parts of azodiamine, and the mixture was kneaded. And the emulsified product of the present invention is used to form the granules of the present invention. In a solution of acetone and dried to obtain granules. a gram of the ester compound A of the present invention, and a mixture of 0.5 g of the present invention, and a gram of the oxidized calcium is placed in the lower space, and a fumigant is obtained. 0. 05 g of the ester compound B of the present invention is dissolved in 20 ml (mL) of acetone, and the resulting solution is added to 99.4 g of a substrate for anti-mosquito (a ratio of 4 ···3 ··3) a mixture of powder, pyrethrum and wood flour) and 0.3 g of green pigment. After thorough mixing, 120 ml of water was added to the mixture and fully kneaded. The resulting mixture was molded and dried to obtain an anti-mosquito roll. Formulation Example 17 By mixing 10 parts of the ester compound A of the present invention, 1 part of the ester compound B of the present invention, 39.5 parts of tributyl citrate, 39.5 parts of isodecyl adipate, 5 parts of blue pigment And 5 parts of perfume to prepare a solution. The substrate of the electric mosquito sheet (3.4 mm cm and 0.22 cm thick) of the electric mosquito sheet (the mixed fine fiber which is entangled, compressed and pressed into a flat cotton lint and pulp) is uniformly impregnated in the The above solution was used to obtain an electric mosquito sheet. Formulation Example 18 A solution was prepared by dissolving 0.1 part of the ester compound A of the present invention and 0.01 part of the ester compound B of the present invention in 99.89 parts of deodorized kerosene. The solution is placed in a vinyl chloride container, and a liquid absorbent core (obtained by curing the inorganic powder with a binder and then calcining 25 322447 201124082) processed in the upper half thereof is inserted into the container. , obtain a liquid absorption type evaporative formulation. Formulation Example 19 0.2 part of the ester compound A of the invention, 0.02 part of the ester compound B of the invention, and 49.78 parts of Neothiozole (Chuo Kasei CO., Ltd.) were placed in an aerosol can. After the aerosol valve was attached, 25 parts of dioxane and 25 parts of LPG were charged, followed by shaking and further attaching an actuator for a full content-injection type aerosol to obtain an aerosol formulation. Formulation Example 20 In the present invention, the ester compound A of the present invention and the 0.02 part of the ester compound B of the present invention are added to 99.78 parts of diethylene glycol monoethyl ether, followed by thorough mixing to obtain a drip for controlling ectoparasites. Formulation. Formulation Example 21 A solution was prepared by dissolving 3 parts of the ester compound A of the present invention and 0.3 part of the ester compound B of the present invention in 96.7 parts of acetone, and uniformly coating 1 ml of the solution to the pressure (4 t/cm 2 ). A disk-shaped solid material (3 cm diameter and 3 mm (mm) thick) obtained by molding 4 g of 2,4,6-triisopropyl-1,3,5-trioxane was molded, followed by drying to obtain a tablet. Formulation Example 2 2 Under pressure, 0.2 g of the ester compound A of the invention, 0.02 g of the ester compound B of the invention, and 4 g of 2,4,6-triisopropyl-1,3,5-trimium The homogeneous mixture which was fired was molded into a disk shape (3 cm diameter and 3 mm thick) to obtain a tablet. Formulation Example 2 3 0. 2 g of the ester compound A of the invention, 0.02 g of the ester compound of the invention 26 322447 201124082 • 4 g of 2'4'6_triisopropyl, 1,3,5-triazine The mixture was placed in a 50 ml tube, heated to melt and then cooled to room temperature to obtain a tablet. Next, the following test examples show that the control composition of the present invention has an excellent control effect on pests and diseases. In the following test, as for the hair _ compound A, use (10)-trans-3-(2,2-dichloroethylene), 2,2-didecyl ring propyl phenolic acid [2, 3, 5 , 6-tetrafluoro- 4-(methoxymethyl)phenyl]decyl ester. Further, as for the ester compound B of the present invention, (1R)-cis/trans-2'2-didecyl-3-(2-methyl-!, propynyl)cyclopropane is used to reduce the 3 phenoxy group. Benzyl g. Test Example 1 An oily solution was prepared by diluting the ester compound B of the present invention with a given amount of an isoparaffin solvent (IS〇pAR®, registered trademark of Exxon Chemical Co., Ltd.) at a concentration not shown in Table 1 below (hereinafter referred to as a comparison) Composition (丨)). Similarly, an oily solution (hereinafter referred to as a comparative composition) was prepared by diluting the ester compound A of the present invention with a given amount of an isoparaffin solvent (is〇parm, registered trademark of Exxon Chemical Co., Ltd.) at the concentrations shown in Table 1 below. (2) and (3)). Further, the ester compound A of the present invention and the ester compound B of the present invention were diluted with a given amount of the iso-smouldering solvent (ISOPAR M, registered trademark of Exxon Chemical Co., Ltd.) at a concentration of the active ingredient shown in Table 1 below to prepare an oily property. A solution (hereinafter referred to as a composition (1) and (2) of the present invention). 10 Culex pipi/3s) (female) was released into a cubic box per centimeter' and sprayed with a spray gun (spray pressure: 0 9 kg/cm2) from a small window in the center of the box into 0.7 ml. Invention composition (丨). During the given time after spraying 322447 27 201124082, the number of insects shot down was investigated and the knockdown rate (KD rate) was calculated. According to the same method, the KD rate (2 times) after a given period of time was calculated using the composition (2) of the present invention and the comparative compositions (1), (2) and (3). The results are shown in Table 1. Table 1 The amount of the ester compound A of the present invention (W/V%) The amount of the ester compound B of the present invention (WA%) KD rate after 7 minutes (%) The composition of the present invention (1) 0.00313 0.2 80 Comparative composition (1) - 0.2 10 Comparative composition (2) 0.00313 - 20 Composition of the present invention (2) 0.00156 0.2 60 Comparative composition (3) 0.00156 - 10 As described above, the present invention can provide a pest control composition and pest control which have excellent effects on pests and diseases. method. [Simple diagram description] None [Main component symbol description] None 28 322447
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009250307 | 2009-10-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201124082A true TW201124082A (en) | 2011-07-16 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW99136904A TW201124082A (en) | 2009-10-30 | 2010-10-28 | Harmful organism-controlling composition and control method of harmful organisms |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JP5598204B2 (en) |
| CN (1) | CN102047902A (en) |
| AR (1) | AR079019A1 (en) |
| AU (1) | AU2010236005A1 (en) |
| BR (1) | BRPI1010449A2 (en) |
| MX (1) | MX2010011911A (en) |
| RU (1) | RU2010144522A (en) |
| TR (1) | TR201008914A2 (en) |
| TW (1) | TW201124082A (en) |
| ZA (1) | ZA201007756B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5652080B2 (en) * | 2009-10-30 | 2015-01-14 | 住友化学株式会社 | Pest control composition and pest control method |
| AU2011265562A1 (en) | 2011-01-12 | 2012-07-26 | Sumitomo Chemical Company, Limited | Method of controlling harmful arthropod, composition, and electrostatic spray device |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0054360B1 (en) * | 1980-12-17 | 1985-06-05 | Imperial Chemical Industries Plc | Fluorobenzyl cyclopropane carboxylates, their preparation, compositions comprising them and their use as insecticides |
| JP3909717B1 (en) * | 2006-07-04 | 2007-04-25 | 大日本除蟲菊株式会社 | Flies and mosquito coils |
| JP5326318B2 (en) * | 2007-03-30 | 2013-10-30 | 住友化学株式会社 | Pest control aerosol composition |
| CN101543225B (en) * | 2009-05-15 | 2012-06-27 | 江苏扬农化工股份有限公司 | Insecticide mother liquor and use thereof |
| CN101632381B (en) * | 2009-06-04 | 2013-07-03 | 江苏扬农化工股份有限公司 | Pesticide aerosol |
-
2010
- 2010-09-22 JP JP2010211929A patent/JP5598204B2/en not_active Expired - Fee Related
- 2010-10-25 AU AU2010236005A patent/AU2010236005A1/en not_active Abandoned
- 2010-10-27 TR TR2010/08914A patent/TR201008914A2/en unknown
- 2010-10-28 AR ARP100103954 patent/AR079019A1/en unknown
- 2010-10-28 TW TW99136904A patent/TW201124082A/en unknown
- 2010-10-28 BR BRPI1010449 patent/BRPI1010449A2/en not_active IP Right Cessation
- 2010-10-29 MX MX2010011911A patent/MX2010011911A/en not_active Application Discontinuation
- 2010-10-29 CN CN2010105312872A patent/CN102047902A/en active Pending
- 2010-10-29 ZA ZA2010/07756A patent/ZA201007756B/en unknown
- 2010-10-29 RU RU2010144522/13A patent/RU2010144522A/en not_active Application Discontinuation
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| Publication number | Publication date |
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| BRPI1010449A2 (en) | 2012-11-27 |
| TR201008914A2 (en) | 2011-05-23 |
| ZA201007756B (en) | 2011-08-31 |
| RU2010144522A (en) | 2012-05-10 |
| JP2011116740A (en) | 2011-06-16 |
| AR079019A1 (en) | 2011-12-21 |
| JP5598204B2 (en) | 2014-10-01 |
| CN102047902A (en) | 2011-05-11 |
| AU2010236005A1 (en) | 2011-05-19 |
| MX2010011911A (en) | 2011-04-29 |
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