CN101632381B - Pesticide aerosol - Google Patents
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- CN101632381B CN101632381B CN 200910143578 CN200910143578A CN101632381B CN 101632381 B CN101632381 B CN 101632381B CN 200910143578 CN200910143578 CN 200910143578 CN 200910143578 A CN200910143578 A CN 200910143578A CN 101632381 B CN101632381 B CN 101632381B
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- 239000000443 aerosol Substances 0.000 title claims abstract description 48
- 239000000575 pesticide Substances 0.000 title abstract 2
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 239000002728 pyrethroid Substances 0.000 claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 239000003380 propellant Substances 0.000 claims abstract description 8
- 241000238631 Hexapoda Species 0.000 claims description 40
- 241000255925 Diptera Species 0.000 claims description 8
- 239000001273 butane Substances 0.000 claims description 8
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 8
- -1 3-benzyloxy phenoxy Chemical group 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 241000607479 Yersinia pestis Species 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 4
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 2
- 244000189548 Chrysanthemum x morifolium Species 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 2
- 239000003915 liquefied petroleum gas Substances 0.000 claims description 2
- 238000009835 boiling Methods 0.000 description 28
- 238000002360 preparation method Methods 0.000 description 22
- 230000000694 effects Effects 0.000 description 11
- 230000000749 insecticidal effect Effects 0.000 description 9
- 229960000490 permethrin Drugs 0.000 description 8
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 8
- 231100000225 lethality Toxicity 0.000 description 4
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 241000257159 Musca domestica Species 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229960003536 phenothrin Drugs 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 2
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
- CNPVJWYWYZMPDS-UHFFFAOYSA-N 2-methyldecane Chemical compound CCCCCCCCC(C)C CNPVJWYWYZMPDS-UHFFFAOYSA-N 0.000 description 2
- 241000144210 Culex pipiens pallens Species 0.000 description 2
- LVZWSLJZHVFIQJ-UHFFFAOYSA-N Cyclopropane Chemical compound C1CC1 LVZWSLJZHVFIQJ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- 229960005199 tetramethrin Drugs 0.000 description 2
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 1
- FJDPATXIBIBRIM-QFMSAKRMSA-N (1R)-trans-cyphenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 FJDPATXIBIBRIM-QFMSAKRMSA-N 0.000 description 1
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Natural products CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 description 1
- AEXMKKGTQYQZCS-UHFFFAOYSA-N 3,3-dimethylpentane Chemical compound CCC(C)(C)CC AEXMKKGTQYQZCS-UHFFFAOYSA-N 0.000 description 1
- 241000256113 Culicidae Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a pesticide aerosol which contains a component A: 0.01-1 percent in weight of pyrethroid compound with formula (1); a component B: 0.01-1 percent in weight of one or a plurality of other pyrethroid compounds; a component C: 0.1-70 percent in weight of solvent; and a component D: 28-99.88 percent in weight of propellant.
Description
Technical field
The present invention relates to a kind of insect aerosol.
Background technology
Pyrethroid coumpound can be used for the control mosquito, and has higher insecticidal activity, and this is widely known by the people.In CN101306997A, disclose formula (1) pyrethroid compound the preparation method and as the purposes of insecticide, how with its better application in insecticidal preparation, be a problem that presses for solution.
The present inventor finds that through further investigation the pyrethroid compound of formula (1) with the two kinds of effects of knocking down and cause death to mosquito, is fit to be applied to insect aerosol simultaneously.Simultaneously, what be worth that we pay special attention to is, in the various stereoisomers of pyrethroid compound of formula (1), activity is the highest so that No. 1 carbon atom is the R configuration on the cyclopropane plane.From the angle of environmental protection, use highly active single optical isomer can under the prerequisite that does not reduce drug effect, reduce the dose that need use, thereby reduce the toxicity to non-target organism, improve safety, reduce the left drug environmental pollution.
The present invention is just under above-mentioned technical background, and the pyrethroid compound that has proposed a kind of formula (1) the particularly active isomer of its 1R configuration is the insect aerosol of main component.
Summary of the invention
Purpose of the present invention is the insect aerosol of main active with regard to providing a kind of pyrethroid compound with formula (1), this aerosol has very good control efficiency to sanitary insect pests such as mosquito, fly or Groton bugs, and the present invention simultaneously also provides preparation method and its application aspect pest control of this insect aerosol.
The objective of the invention is to be achieved through the following technical solutions:
The invention provides a kind of insect aerosol, described aerosol comprises the pyrethroid compound of the formula (1) of component A:0.01-1% weight, B component: other pyrethroid coumpound of one or more of 0.01-1% weight, the propellant of the solvent of component C:0.1-70% weight and component D:28-99.88% weight.
Among the present invention, pyrethroid compound (1) is because having asymmetric carbon atom to have stereoisomer on the cyclopropane plane, the present invention can be the mixture of its any active isomer or its stereoisomer, be preferably 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester; 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester; 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, cis-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester.These compounds are known, perhaps can prepare by known method.
Pyrethroid in the B component is 3-benzyloxy phenoxy base chrysanthemum monocarboxylate (phenothrin), 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic)-cyclopropane-carboxylic acid cyano group (3-Phenoxyphenyl) methyl esters (cyphenothrin), 3-phenoxy benzyl-2,2-dimethyl-3-(2, the 2-dichloroethylene)-cyclopropanecarboxylcompound (permethrin), (R, S)-alpha-cyano-3-phenoxy benzyl (1R, 3R)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester (beta-cypermethrin) or alpha-cyano-3-phenoxy benzyl (IRS) cis-3-(2, the 2-dibromo vinyl)-2, one or more in the 2-dimethyl cyclopropane carboxylic acid ester (decis).
The solvent of component C is D60, D80, the D110 solvent wet goods alkane solvents of C10-18; Water; One or more mixture such as the small molecular alcohol kind solvent of C2-C8.
The concrete example of this kind solvent comprises water (100 ℃ of boiling points), n-butanol (117.9 ℃ of boiling points), sec-butyl alcohol (99.5 ℃ of boiling points), the tert-butyl alcohol (82.3 ℃ of boiling points), normal propyl alcohol (97.2 ℃ of boiling points), isopropyl alcohol (82.4 ℃ of boiling points), ethanol (78.3 ℃ of boiling points), hexane (69 ℃ of boiling points), heptane (98.4 ℃ of boiling points), dimethyl pentane (60 ℃ of boiling points), 2,2-dimethylbutane (50 ℃ of boiling points), octane (125 ℃ of boiling points), nonane (149.5 ℃ of boiling points), decane (174 ℃ of boiling points), hendecane (195.9 ℃ of boiling points), 12 carbon alkane (216 ℃ of boiling points), tridecane (235.4 ℃ of boiling points), tetradecane (253.7 ℃ of boiling points), D30 (Exxon Mobil petrochemical corporation (complex), 141 ℃~159 ℃ of boiling points), D40 (Exxon Mobil petrochemical corporation (complex), 168 ℃~193 ℃ of boiling points), D60 (Exxon Mobil petrochemical corporation (complex), 186 ℃~201 ℃ of boiling points), D80 (Exxon Mobil petrochemical corporation (complex), 206 ℃~243 ℃ of boiling points), D110 (Exxon Mobil petrochemical corporation (complex), 249 ℃~267 ℃ of boiling points), Isopar-E (Exxon Mobil petrochemical corporation (complex), 115 ℃~140 ℃ of boiling points), Isopar-G (Exxon Mobil petrochemical corporation (complex), 167 ℃~176 ℃ of boiling points), Isopar-H (Exxon Mobil petrochemical corporation (complex), 179 ℃~188 ℃ of boiling points), Isopar-L (Exxon Mobil petrochemical corporation (complex), 186 ℃~201 ℃ of boiling points), Isopar-M (Exxon Mobil petrochemical corporation (complex), 223 ℃~253 ℃ of boiling points) etc.In being provided, the uniform homogeneous blend of water base aerosol-type also can add a kind of alcohol as solvent.
With above-mentioned A, B, the synergist that C component and according to circumstances can selecting is added, aromatic, bactericide, phenol type stabilizing agent for example BHT and BHA etc. in room temperature or be heated under 30~60 ℃ and mix, add one be equipped with a valve the jar in, and under pressure, add D component propellant in the jar by this valve and make an insecticidal aerosol jar, the propellant of wherein said D component is generally elected liquefied petroleum gas, third butane, dimethyl ether or compressed air as, preferred third butane.
When insect aerosol of the present invention is used in the habitat of insect, by-pass valve control is opened, under the pressure effect of propellant, produce high velocity air, jar is included the soup aerosol dispersion of active ingredient and the gasification of propellant, the small liquid pearl that contains effective insecticidal constituent of formation is suspended in the air, with mosquito, fly, sanitary insect pests such as Groton bug contact, and reach the purpose of quick kill pests.
Through experiment, proved that insect aerosol of the present invention has remarkable prevention effect to housefly, Culex pipiens pallens, Groton bug etc.
Embodiment
Explain technical scheme of the present invention and effect in detail with the form of embodiment below, but the present invention is not limited to following examples.
Preparation embodiment 1.
Be heated under 40 ℃ 2,3,5 of 0.05 weight portion, 6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester and 0.2 weight portion chlorine ester, and the D80 oil miscible solvent of 39.75 weight portions lumps together a kind of insecticidal preparation of preparation.The preparation that obtains is put into the aerosol jar, on jar a valve is housed, and injects 60.0 weight portions, third butane adding to depress by this valve, to obtain a kind of insect aerosol I, wherein contain 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester 0.05w/w%, permethrin 0.2w/w%.
Preparation embodiment 2.
Be heated under 40 ℃ 2,3,5 of 0.06 weight portion, 6-tetrafluoro-4-methoxyl methyl benzyl-1R, cis-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester and 0.2 weight portion permethrin, and the D80 oil miscible solvent of 39.74 weight portions lumps together a kind of insecticidal preparation of preparation.The preparation that obtains is put into the aerosol jar, on jar a valve is housed, and injects 60.0 weight portions, third butane adding to depress by this valve, to obtain a kind of insect aerosol II, wherein contain 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, cis-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester 0.06w/w%, permethrin 0.2w/w%.
Preparation embodiment 3.
Be heated under 40 ℃ 2 of 0.04 weight portion, 3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester and 0.1 weight portion permethrin, 0.1 the weight portion phenothrin, and the D60 oil miscible solvent of 29.76 weight portions lumps together a kind of insecticidal preparation of preparation.The preparation that obtains is put into the aerosol jar, on jar a valve is housed, and inject 70.0 weight portions, third butane adding to depress by this valve, to obtain a kind of insect aerosol III, wherein contain 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester 0.04w/w%, permethrin 0.1w/w%, phenothrin 0.1w/w%.
Reference example 1.
At the tetramethrin and the 0.3 weight portion permethrin that are heated under 40 ℃ 0.4 weight portion, and the D80 oil miscible solvent of 39.3 weight portions lumps together a kind of insecticidal preparation of preparation.The preparation that obtains is put into the aerosol jar, on jar a valve is housed, and inject 60.0 weight portions, third butane adding to depress by this valve, to obtain a kind of insect aerosol IV, wherein contain tetramethrin 0.4w/w%, permethrin 0.3w/w%.
Reference example 2.
Be heated under 40 ℃ 2,3,5 of 0.05 weight portion, 6-tetrafluoro-4-methoxyl methyl benzyl-1R-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, and the D80 oil miscible solvent of 39.95 weight portions lumps together a kind of insecticidal preparation of preparation.The preparation that obtains is put into the aerosol jar, on jar a valve is housed, and inject 60.0 weight portions, third butane adding to depress by this valve, to obtain a kind of insect aerosol V, wherein contain 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester 0.05w/w%.
Detect embodiment 1
With the present invention prepare embodiment 1,2 and reference example 1,2 carry out to mosquito fly, the test of the indoor harmacological effect of Groton bug according to GB13917.2-92.The examination worm is Culex pipiens pallens, and the 2-3 days female mosquitos of not sucking blood in back sprout wings; Housefly, the 4th day adult in back sprouts wings; Groton bug, the back adult in 2 age in week that sprouts wings, male and female half and half.Adopt airtight drum device.Detailed process is as follows: will put into cylinder for the examination insect; after waiting to try worm recovery normal activity; metered injection 1g medicament from insect aerosol jar of the present invention; extracting baffle plate behind the 1min out makes the examination worm contact with medicament; down and out examination borer population is recorded in timing immediately, and opening entry at regular intervals; to all be transferred in the dependent insect cage of cleaning for the examination worm behind the 20min, check dead examination borer population behind the 24h.Wherein Groton bug is checked the 72h lethality.The results are shown in following table:
The above-mentioned insect aerosol of table 1. is to the effect of mosquito
Aerosol | KT50(min) | 24h lethality (%) |
Insect aerosol I | 1.6 | 100 |
Insect aerosol II | 1.5 | 100 |
The insect aerosol IV | 3.3 | 95 |
Insect aerosol V | 2.9 | 70 |
The above-mentioned insect aerosol of table 2. is to the effect of housefly
Aerosol | KT50(min) | 24h lethality (%) |
Insect aerosol I | 1.3 | 100 |
Insect aerosol II | 1.3 | 100 |
The insect aerosol IV | 2.9 | 90 |
Insect aerosol V | 2.3 | 65 |
The above-mentioned insect aerosol of table 3. is to the effect of Groton bug
Aerosol | KT50(min) | 72h lethality (%) |
Insect aerosol I | 3.2 | 100 |
Insect aerosol II | 3.3 | 100 |
The insect aerosol IV | 5.9 | 90 |
Insect aerosol V | 5.6 | 70 |
The result shows: the insect aerosol of the present invention's preparation has the good activity of knocking down and cause death, and to mosquito, fly, Groton bug have good insect killing effect.
Claims (2)
1. insect aerosol, it is characterized in that this aerosol comprises the pyrethroid compound of the formula of component A:0.01-1% weight (1), B component: other pyrethroid coumpound of one or more of 0.01-1% weight, the propellant of the solvent of component C:0.1-70% weight and component D:28-99.88% weight; Other pyrethroid coumpound in the described B component is 3-benzyloxy phenoxy base chrysanthemum monocarboxylate, 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic)-cyclopropane-carboxylic acid cyano group (3-Phenoxyphenyl) methyl esters, 3-phenoxy benzyl-2,2-dimethyl-3-(2, the 2-dichloroethylene)-cyclopropanecarboxylcompound, (R, S)-alpha-cyano-3-phenoxy benzyl (1R, 3R)-and 3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester or decis;
The stereochemical structure of the pyrethroid compound chrysanthemumic acid part three-membered ring of described formula (1) expression is 1R, trans or 1R, cis, the compound of formula (1) expression is 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester or 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, cis-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester;
The solvent of described component C is one or more mixture of the small molecular alcohol kind solvent of the alkane solvents of C10-18 or C2-C8;
The propellant of described component D is selected from liquefied petroleum gas, third butane, dimethyl ether or compressed air.
2. the application of the described insect aerosol of claim 1 aspect control mosquito, fly or Groton bug sanitary insect pest.
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CN 200910143578 CN101632381B (en) | 2009-06-04 | 2009-06-04 | Pesticide aerosol |
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CN 200910143578 CN101632381B (en) | 2009-06-04 | 2009-06-04 | Pesticide aerosol |
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CN101632381B true CN101632381B (en) | 2013-07-03 |
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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JP5598204B2 (en) * | 2009-10-30 | 2014-10-01 | 住友化学株式会社 | Pest control composition and pest control method |
US20120241532A1 (en) * | 2011-03-24 | 2012-09-27 | Palkki Kent M | Pyrethrin Based Repellant |
CN102239877B (en) * | 2011-05-16 | 2014-08-27 | 江苏扬农化工股份有限公司 | Insecticide spray and application thereof |
CN102308843A (en) * | 2011-09-21 | 2012-01-11 | 江苏扬农化工股份有限公司 | Complex long-acting insecticidal spraying agent and application thereof |
CN102870773A (en) * | 2012-10-18 | 2013-01-16 | 江苏扬农化工股份有限公司 | Pesticidal spray |
CN104351174A (en) * | 2012-10-18 | 2015-02-18 | 江苏扬农化工股份有限公司 | Insecticide spray |
CN111771883A (en) * | 2019-12-09 | 2020-10-16 | 湖南省九喜日化有限公司 | High-efficiency insecticidal aerosol and preparation method thereof |
CN111771915A (en) * | 2019-12-09 | 2020-10-16 | 湖南省九喜日化有限公司 | Insecticidal aerosol and preparation method thereof |
CN113207876B (en) * | 2021-05-19 | 2023-03-31 | 中山榄菊日化实业有限公司 | Water-based insecticidal aerosol and preparation method thereof |
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JP2001213704A (en) * | 2000-02-01 | 2001-08-07 | Sumitomo Chem Co Ltd | Gel like pest-controlling composition |
CN1669429A (en) * | 2004-03-17 | 2005-09-21 | 住友化学株式会社 | Insect disinfestation composition |
CN101381306A (en) * | 2008-10-14 | 2009-03-11 | 江苏扬农化工股份有限公司 | Pyrethroid compounds and application |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2001213704A (en) * | 2000-02-01 | 2001-08-07 | Sumitomo Chem Co Ltd | Gel like pest-controlling composition |
CN1669429A (en) * | 2004-03-17 | 2005-09-21 | 住友化学株式会社 | Insect disinfestation composition |
CN101381306A (en) * | 2008-10-14 | 2009-03-11 | 江苏扬农化工股份有限公司 | Pyrethroid compounds and application |
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