TW201124083A

TW201124083A - Harmful organism-controlling composition and control method of harmful organisms

Info

Publication number: TW201124083A
Application number: TW99136909A
Authority: TW
Inventors: Masayo Sugano; Yoshito Tanaka
Original assignee: Sumitomo Chemical Co
Priority date: 2009-10-30
Filing date: 2010-10-28
Publication date: 2011-07-16
Also published as: MX2010011915A; JP5589713B2; AR079018A1; RU2010144520A; ZA201007755B; AU2010236008A1; BRPI1010467A2; JP2011116739A; CN102047901A; TR201008913A2

Abstract

Disclosed is a pest control composition having an excellent controlling effect on pests, which comprises a combination of an ester compound represented by the formula (I): and an ester compound represented by the formula (II):

Description

201124083 六、發明說明：【發明所屬之技術領域】本發明係關於一種病蟲害防治組成物及病蟲害之防治方法。【先前技術】式（I)表示之酯化合物：201124083 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a pest control composition and a method for controlling pests and diseases. [Prior Art] The ester compound represented by the formula (I):

F F Ο 為習知病蟲害防治製劑之有效成分（例如參見J P 57-123146A 及 CN 101306997A)。另外，式（II)表示之S旨化合物：F F Ο is an active ingredient of a conventional pest control preparation (see, for example, J P 57-123146A and CN 101306997A). In addition, the formula (II) represents the compound of S:

F F Ο 亦為習知病蟲害防治製劑之有效成分（例如參見JP 2004-2363 A)。然而，在某些情況中，依特定應用及所欲防治之病害蟲而定，對該已知製劑而言，仍需要具有較高防治效果之病蟲害防治製劑。【發明内容】發明所欲解決之問題 4 322446 201124083 本發明之目的係提供一種對病蟲害具有優異防治效果之病蟲害防治組成物及病蟲害之防治方法。解決問題之方法由於本案發明人致力研究的結果，發現組合使用式（I) 表示之酯化合物及式（II)表示之酯化合物對病蟲害呈現優異防治效果。據此，完成本發明。因此，本發明提供： (1) 一種病蟲害防治組成物，包括式（I)表示之酯化合F F Ο is also an active ingredient in conventional pest control formulations (see, for example, JP 2004-2363 A). However, in some cases, depending on the particular application and the pest to be controlled, there is still a need for a pest control preparation having a high control effect for the known preparation. SUMMARY OF THE INVENTION Problems to be Solved by the Invention 4 322446 201124083 The object of the present invention is to provide a pest control composition and a method for controlling pests and diseases which have excellent control effects against pests and diseases. Solution to Problem As a result of intensive studies by the inventors of the present invention, it has been found that the combination of the ester compound represented by the formula (I) and the ester compound represented by the formula (II) exhibits an excellent control effect against pests and diseases. Accordingly, the present invention has been completed. Accordingly, the present invention provides: (1) A pest control composition comprising the ester compound represented by the formula (I)

(後文中稱為本發明酯化合物A)及式（II)表示之酯化合物之組合：(hereinafter referred to as ester compound A of the present invention) and a combination of ester compounds represented by formula (II):

(後文中稱為本發明酯化合物B)作為有效成分； (2 )根據上述第（1)項之病蟲害防治組成物（後文中稱為本發明防治組成物），其中，該本發明酯化合物A與該本發明酯化合物B之重量比在50 : 1至1 : 50之範圍。 (3 ) —種病蟲害之防治方法，包括對病蟲或病蟲^棲息處施 5 322446 201124083 用有效量之本發明酯化合物A及本發明酯化合物B之組合；以及 (4) 一種本發明酯化合物A及本發明酯化合物8之組合以防治病蟲害之用途。本發明之效果本發明防治組成物及防治方法對病蟲害呈現優異防治效果。【實施方式】本發明防治組成物之特徵在於包含本發明酯化合物A 及本發明酯化合物B兩者。本發明酯化合物A例如可經由Jp 57_123146A中所述方法予以製備。本發明酯化合物B例如可經由jp 2〇〇4-2363A中所述方法予以製備。本發明酯化合物A及本發明酯化合物b基於在其環丙烷環之兩個不對稱碳原子而各自具有異構物。在本發明中，可以任何比例使用含有活性異構物之酯化合物。本發明防治組成物對其顯示有防治效果的病蟲害之實例包含有害郎肢動物例如見蟲病蟲害及碑蜗類（acar i ne ) 病蟲害。其具體實例係如下列者。鱗翅目（Lepidoptera)昆蟲病蟲害：模蛾（填蛾科（Pyralidae))例如稻條模（rice stem borer)(二化嗅蛾（a/h si仰、稻縱捲葉蟲 (I* i ce 1 ea f ro 11 er )(稻縱捲葉野螟蛾（。^ 6 322446 201124083 、及印度粉模（Indian meal moth)(印度榖粉模蛾（/Wia y/2ie/7?i/72cie//a));夜蛾（owlet moth)(夜蛾科（Noctuidae))例如普通夜盜蟲（斜紋夜蛾 //iwra))、甜菜行軍蟲（beet armyworm)(甜菜葉蛾 {Spodoptera exigua))、稻行萆蟲X東方黏 A (Pseuda 1 etia separate))、及甘i行軍螽（甘籃夜蛾CMa/nestra 々rass/cae));紋白蝶（粉蝶科（Pieridae))例如普通菜粉蝶 (紋白蝶（戶/eWs rapae));捲蛾（捲蛾科（Tortricidae))例如姬捲葉蛾屬spp.);果蛾（fruitworm moth) (果蛀蛾科（Carposinidae));潛蛾（潛蛾科（Lyonetiidae)); 毒蛾（毒蛾科（Lymantriidae));金翅夜蛾亞科（Plusiae); 地老虎屬（如·7Ό"5 spp.)例如地老虎（黄地老虎（如 segeii/zz/))及小地老虎（小地老虎（处/仰//⑽））；葉蛾屬（Helicoverpa spp.);棉鈴蟲屬（Heliothis spp.); 鑽石背蛾（小菜蛾;直紋稻弄蝶（單帶弄蝶（/¾側ra 沿/Uah);製袋衣蛾（casemaking clothes moth)(衣蛾（77/7從 ;以及織網衣蛾（webbing clothes moth)(衣蛾（77/7eok Z?y>sse///e7h))。雙翅目（Diptera)昆蟲病蟲害：蚊（蚊科（Calicidae))例如普遍蚊子（淡色庫蚊（α/α pipienspallens)、三斑家故QCulex tritaeniorhynchus)、反南方家故{致儀亀故{Culex quinquefasciatus、）.，微故爆 (Jec/es spp·)例如黃熱蚊（埃及斑蚊（知办s a從叩以）、及亞洲虎蚊（白線斑蚊（如办5 3/Ζ?ο/?_/ί7加s);按蚊屬（如 7 322446 201124083 spp.)例如中華癌蚊;搖蚊（midges) (搖蚊科（Chironomidae));家蠅（家蠅科（Muscidae))例如家竭X 家竭XMusca domesticay)、禀、家竭XMusca bezzi)、版賊繩（false stable fly)(廄腐繩（MAscha 、及小家廁蠅（lesser housefly)(黃腹廄蠅（/3/277/3 can/ci/yaWs));麗繩（麗繩科（Calliphordiae));麻繩（麻蠅科（Sarcophagi dae ));花蠅（花蠅科（Anthomy i i dae))例如種繩（seedcornmaggot)(灰地種繩加ra))、及惠蠅（onion maggot)(蔥蠅仰））；黑色清道夫繩 (black scavenger flies)(黑蠅科（Sepidae));果蠅（果實繩科（Tephritidae);潛繩（潛繩科（Agromyzidae));小果織 (果繩科（Drosophilidae))例如普遍果繩（野生果繩 ;蛾蚋（m〇th flies)(蛾蚋科 (Psychodidae));蚤蠅（蚤蠅科（Phoridae))例如蚤蠅 (humpbacked fly)(東亞異蚤蠅 ;蚋（black flies)(蚋科（Simuliidae)); 馬蠅（虻科（Tabanidae));穩蠅（螫蠅科（Stomoxyidae));以及吸血小黑蚊（biting midges)(蠓科（Ceratopogonidae))。網翅目（Dictyoptera)昆蟲病蟲害：蟑螂（蜚蠊目（Blattariae))例如德國蟑螂（德國蜚蠊 (BJatteUa ger/nani_ca))、煙褐蟑螂（黑胸大蠊 /i//2>y/2〇s<9))、美洲蟑螂（美洲蜚蠊、棕色蟑螂（棕色蜚蠊 (Peri’pJaneta brun/iea))、及東方蟑螂（東方蜚蠊(jjatta 322446 201124083 orientalis'))。膜翅目（Hymenoptera)昆蟲病蟲害：蟻（蟻科（Formicidae));馬蜂（胡蜂科（veSpidae)); 腫腿蜂（腫腿蜂科（Bethylidae));以及葉蜂（葉蜂科 ((Tenthredinidae))例如甘藍葉蜂（黃翅菜葉蜂 rosae) ° 隱翅目（Aphaniptera)昆蟲病蟲害：欠蚤{欠蚤iCtenocephalides canis))、貓蚤{貓 (Ctenocephalides felisY)、认反 irritans')、。兹目（Anoplura)昆蟲病蟲害：欠蝨ί人鉍（Pediculus humans))、毛致（陰级 (Phthirus pubis))、頭鉍（頭鉍（Pediculus humans capitis))、认反 A後裂後襄（Pedi cuius humanus corporis、）。等翅目（Isoptera)昆蟲病蟲害：曰本散白蟻（Japanese subterranean termite)(黃胸 l白缚XReticul itermes speratus))、认反台灣％白氣 (Formosan subterranean termite)(臺灣家白蟻 {Coptotermes fonnosanus))。半翅目（Hemiptera)昆蟲病蟲害：飛兹（飛蟲科（Delphacidae))例如小褐飛兹（smal 1 brown p 1 anthopper)(斑飛兹（Zaoi/e/p/zai sir/a ie/)、褐稻飛蟲（褐飛益（Wb )、及白背稻飛兹 9 322446 201124083 (白背飛兹（/f/rd/era));葉禪（1 eaf hopper)(浮塵子科（Deltocephal idae))例如青稻葉禪（黑尾葉蟬 iNephotettix cincticepsT)、反台Μ智稻葉碑ί二點禀、民葉蟬Wresce/3S〇);财轰（财科（Aphididae)); 臭蟲（椿科（Pentatomidae));粉兹（粉兹科（Aleyrodidae)); 介殼蟲（軟介殼蟲科（Coccidae));臭蟲（cimices)例如（溫帶臭嘉（〔/撕义/eciw/arii/>s));軍配蟲（軍配蟲科 (Tingidae));以及木盘（木兹科（Psyliidae))。鞘翅目（Coleoptera)昆蟲病蟲害：玉米食根蟲（corn root worms)(葉曱屬（及ZaZ?/Oi/ca spp.))例如黑皮蠢（black carpet beetle)(姬經節蟲㈠亡iageniAs )、姬圓經節蟲（varied carpet beet 1 e)(小圓花皮蠹)、西部玉米食根蟲（玉米根葉甲（Diabrotica virgifera virgifera))、及南方玉米食根蟲（Η —星瓜葉曱（Diabrotica undecimpunctata howardi));金龜子（金龜子科 (Scarabaeidae))例如綠金龜（cupreous chafer)(金銅金龜廳/a a/p_rea))、及大豆曱蟲（soybeans beetle)(棒姬金龜/7//bcwprea));象鼻蟲（象鼻蟲科 (Curculionidae))例如玉米象（maize weevil)(玉米象 (Sj top/n· Jus zea/MJ's))、稻水象 ψ (rice water weevil)(稻水象甲（Zissor/zqpi/T/s oryzc»p/?i/i/5〇)、棉鈴象甲（bol 1 WeeV il)(棉鈴象甲（4/7 i/7〇73C>/Z7i/S wa/7i/y s))、及綠豆象甲 (azuk i bean weev i 1)(綠豆象（Ca/ 10 322446 201124083 以“⑸幻··?));擬步甲（darkling beetles)(擬步曱科 (Tenebrionidae))例如黃粉蟲（yellow mealworm)(黃粉蟲 ((7b/7eZ?Wo/»a//ior))、及赤擬穀盜（red flour beetle)(赤擬穀盜（Trib〇nu/n castaneu/π)) ·，金花(金花科 (Chrysome 1 i dae ))例如稻泥蟲（稻負泥蟲（oryzae))、黃條葉蚤（striped flea beetle)(黃條葉蚤（Phyllotreta striolata))、及黃守瓜（cucurbit leaf beetle)(黃守瓜 (如/e/sora/is));榖斑皮蠹（drugstore beetle) (竊橐科（Anobiidae));食植瓢蟲屬（Epilachna spp.)例如茄二十八星瓢蟲（twenty-eight-spotted ladybird)(茄二十八L·瓢AiEpilachna vigintioctopunctata')、.，粉毚A (powder post beetles)(粉蠹亞科（Lyctinae));偽粉蠹 (false powder post beetles)(長蠢蟲科（Bostrichidae)); 天牛（longhorn beetles)(天牛科（Cerambycidae));以及隱翅蟲（rove beetle)(蟻型隱翅蟲。缨翅目（Thysanoptera)昆蟲病蟲害：瓜薊馬（Melon thrips)(南黃薊馬（TTzWpspah/y))、柑橘黃薊馬（yellow citrus thrips)(西方花15馬 {Frankliniella occidentalisY)、认反良燊馬氩徵馬 {Frankliniella intonsay)。直翅目（Orthoptera)昆蟲病蟲害：樓蛄（螻蛄科（Gryllotalpidae))、以及蝗蟲（蝗科 (Acrididae)) ° 碑蜗目（Acarina): 11 322446 201124083 家居塵蜗（塵蜗科（Pyroglyphidae))例如美洲塵蜗 (Dermatophagoides farinae)、反歡洲亀織 iDermatophagoides ptrenyssnus') ·，粉織{綸織势 (Acaridae))例如霉蟎（m〇ld mite)(腐食酪蟎 putrescentiae))、反橢凰斑白蟎（Aleuroglyphus ovatus).，蜱蟎（G1 ycyphag i d m i t e s )例如食甜蟎（ privatus)、家食辨端（Glycyphagus domesticus)、反害 1 鱗蟎ί/esi/T/c仏or);肉食蟎（肉食蟎科 (Cheyletidae))例如馬六曱肉食蜗 malaccensis)、A 肉 I蟎iCheyletus fortis).，細端 (Tarosonemid mites)(細蜗科（Tarsonemidae));嗜渣蜗 (Chortoglyphid mites)(嗜渣科（Chortoglyphidae));禽刺瞒（Haplochthoniid mites)(禽刺蜗科 (Haplochthoniidae));葉蟎（葉蟎科（Tetranychidae))例如二點葉蜗（二斑葉蜗（ί/r ί/cae))、神澤葉瞒(hereinafter referred to as the ester compound B of the present invention) as an active ingredient; (2) a pest control composition according to the above item (1) (hereinafter referred to as a control composition of the present invention), wherein the ester compound A of the present invention The weight ratio to the ester compound B of the present invention is in the range of from 50:1 to 1:50. (3) A method for controlling pests and diseases, comprising applying a combination of an effective amount of the ester compound A of the present invention and the ester compound B of the present invention to a pest or a pest; 5, an ester of the present invention; and (4) an ester of the present invention The combination of Compound A and the ester compound 8 of the present invention for controlling pests and diseases. EFFECT OF THE INVENTION The control composition and the control method of the present invention exhibit excellent control effects on pests and diseases. [Embodiment] The control composition of the present invention is characterized by comprising both the ester compound A of the present invention and the ester compound B of the present invention. The ester compound A of the present invention can be produced, for example, by the method described in Jp 57-123146A. The ester compound B of the present invention can be produced, for example, by the method described in jp 2〇〇4-2363A. The ester compound A of the present invention and the ester compound b of the present invention each have an isomer based on two asymmetric carbon atoms of the cyclopropane ring. In the present invention, an ester compound containing an active isomer can be used in any ratio. Examples of pests and diseases in which the control composition of the present invention exhibits a control effect include harmful larval animals such as insect pests and diseases and acar i ne disease pests. Specific examples thereof are as follows. Lepidoptera insect pests: Moth moth (Pyralidae) such as rice stem borer (a scented moth (a/h si, rice leaf curler (I* i ce 1) Ea f ro 11 er ) (Rice volcano moth (.^ 6 322446 201124083, and Indian meal moth (Indian meal moth (/Wia y/2ie/7?i/72cie// a)); owlet moth (Noctuidae), such as the common night larvae (Sp. cerevisiae / iwra), beet armyworm (Spodoptera exigua), Pseuda 1 etia separate), and ii marching 螽 (CMa/nestra 々rass/cae)); white butterfly (Pieridae) such as common cabbage butterfly (white butterfly) (household/eWs rapae)); the moth (Tortricidae) such as the genus Spodoptera; the fruitworm moth (Carposinidae); the moth (Lyonetiidae) )); a poisonous moth (Lymantriidae); a golden-winged genus (Addiae); a genus of the genus (such as · 7Ό"5 spp.) such as a tiger (a yellow tiger (such as segeii/zz/)) and Small tiger (small Tiger (Hang/Yang//(10))); Helicoverpa spp.; Heliothis spp.; Diamondback moth (Plutella xylostella; Straight-grained rice butterfly (single-banded butterfly (/3⁄4 side) Ra along /Uah); casemaking clothes moth (clothing moth (77/7 from; and webbing clothes moth) (77/7eok Z?y>sse///e7h )) Diptera insect pests: Mosquitoes (Calicidae) such as the common mosquitoes (α/α pipienspallens, QCulex tritaeniorhynchus), anti-Southern family Therefore, {Culex quinquefasciatus,).,Jec/es spp·, for example, yellow-hot mosquitoes (Aedes aegypti (known as sa from 叩), and Asian tiger mosquitoes (white-lined mosquitoes (such as 5 3/Ζ ?ο/?_/ί7 plus s); Anopheles (eg 7 322446 201124083 spp.) such as Chinese cancer mosquito; Chimeromy (Chironomidae); Musca domestica (Muscidae) For example, XMusca domesticay), M, XMusca bezzi), false stable fly (MAscha, and lesser housefly) 3/277/3 c An/ci/yaWs)); Lili (Calliphordiae); hemp rope (Sarcophagi dae); flower fly (Anthomy ii dae) such as seed rope (seedcornmaggot) (ash Ground rope plus ra)), and onion maggot (onion maggot) (black scavenger flies) (Sepidae); fruit fly (Tephritidae); Dive rope (Agromyzidae); small fruit weave (Drosophilidae) such as the popular fruit rope (wild fruit rope; m〇th flies (Psychodidae); Phoridae, such as a humpbacked fly (East Asian scorpion flies; black flies (Simuliidae); horse flies (Tabanidae); sting flies (Symphaeidae) Stomoxyidae)); and biting midges (Ceratopogonidae). Dictyoptera insect pests and diseases: lat (Blattariae) such as German 蟑螂 (BJatte Ua ger / nani_ca), 蟑螂 brown 蟑螂 (black breasted 蠊 / i / /2 gt; y / 2 〇s<9)), American cockroach (American cockroach, brown cockroach (Peri'pJaneta brun/iea), and Oriental cockroach (Jjatta 322446 201124083 orientalis')). Hymenoptera ( Hymenoptera) insect pests: ants (Formicidae); wasps (veSpidae); swollen bee (Bethylidae); and leaf bee (Tenthredinidae) such as cabbage Leaf bee (Aephetera rosae) ° Aphaniptera insect pests: C 蚤蚤蚤蚤蚤蚤蚤蚤蚤蚤蚤蚤蚤蚤蚤猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫猫Anoplura insect pests and diseases: Pediculus humans, Phthirus pubis, Pediculus humans capitis, and anti-A posterior fissure Pedi cuius humanus corporis,). Isoptera insect pests and diseases: Japanese subterranean termite (XReticul itermes speratus), and Formosan subterranean termite (Coptotermes fonnosanus) . Hemiptera insect pests and diseases: Delphacidae such as smal 1 brown p 1 anthopper (Zaoi/e/p/zai sir/a ie/) , Brown Rice Fly (Wb), and White Backed Rice 9 322446 201124083 (Whitebacked (/f/rd/era)); 1 eaf hopper (Deltocephal idae) )) For example, the green rice leaf zen (black-tailed leaf 蝉iNephotettix cincticepsT), the anti-Taiwan zhi rice leaf ί 二 two points 民, the 蝉叶蝉Wresce/3S〇); 财 ( (Aphididae); Pentatomidae)); Pink (Aleyrodidae); Scale insect (Coccidae); cimices such as (temperate stinking ([/ tearing/eciw/arii/>s) ); Army worm (Tingidae); and wood plate (Psyliidae). Coleoptera insect pests: corn root worms (Acacia (and ZaZ? /Oi/ca spp.)) For example, black carpet beetle (Jibu worm (1) iageniAs), variegated carpet beet 1 e (small round flower scorpion), western corn food Rootworm Diabrotica virgifera virgifera), and southern corn rootworm (Diabrotica undecimpunctata howardi); scarab (Scarabaeidae) such as cupreous chafer (golden bronze turtle hall) /aa/p_rea)), and soybean mites (soybeans beetle) (Colculidae/7//bcwprea); weevil (Curculionidae) such as maize weevil (corn elephant ( Sj top/n· Jus zea/MJ's)), rice water weevil (Zissor/zqpi/T/s oryzc»p/?i/i/5〇), cotton boll weevil (bol 1 WeeV il) (cotton bell weevil (4/7 i/7〇73C>/Z7i/S wa/7i/ys)), and mung bean weevil (azuk i bean weev i 1) (mung bean elephant (Ca/ 10 322446 201124083 by "(5) 幻··?)); darkling beetles (Tenebrionidae) such as yellow mealworm (Yellow mealworm ((7b/7eZ?Wo/» a//ior)), and red flour beetle (Trib〇nu/n castaneu/π) ·, Golden flower (Chrysome 1 i dae) such as rice Mud worm (oryzae), striped stripe (striped fl Ea beetle) (Phyllotreta striolata), and cucurbit leaf beetle (黄守瓜 (eg /e/sora/is)); store 蠹 dr (drugstore beetle) (Anobiidae)); Epilachna spp., such as twenty-eight-spotted ladybird (AiEpilachna vigintioctopunctata), . Powder post beetles) (Lyctinae); false powder post beetles (Bostrichidae); longhorn beetles (Cerambycidae); Rove beetle (ant type cryptocephalus). Thysanoptera insect pests: Melon thrips (TTzWpspah/y), yellow citrus thrips (Western flower 15 horse {Frankliniella occidentalisY), reciprocal燊 arrogant horse {Frankliniella intonsay). Orthoptera insect pests and diseases: Floor 蛄 (Gryllotalpidae), and Locust (Acrididae) ° Acarina: 11 322446 201124083 Household dust worm (Pyroglyphidae) For example, Dermatophagoides farinae, iDermatophagoides ptrenyssnus'), powder weaving (Acaridae) such as m〇ld mite (putrescentiae), anti-ellipse Aleuroglyphus ovatus., G1 ycyphag idmites such as privatus, Glycyphagus domesticus, anti-harm 1 scale ί/esi/T/c仏or; meat 螨(Cheyletidae), for example, Malaccensis, A meat I螨iCheyletus fortis, Tarosonemid mites (Tarsonemidae); Chortoglyphid mites Chortoglyphidae); Haplochthoniid mites (Haplochthoniidae); Leaf mites (Tetranychidae) such as two-point leaf worm (two-spotted snail (ί/r ί/) Cae)), esoteric 瞒

(Kanzawa spider mite)(神澤葉蟎（reira/ycZ/iAS 、相桔紅给蛛（掛桔全爪蜗 c/tr/))、及歐洲紅蜗（European red mite)(榆全爪瞒 (Panonychus ulmi));蜱（硬蜱科（Ixodidae))例如長角血缉Ulaemaphysalis longicornis)，，认反後寄!L·織 (parasitoid mites)(皮刺蜗科（Dermanyssidae))例如北方禽蟎（northern fowl mite)(禽刺蟎 •s/k/ari//»))、及禽紅蟎（poultry red mite)(雞皮刺蟎 (Dermanyssus gallinae))。 12 322446 201124083 特別地，本發明防治組成物對雙翅目昆蟲病蟲害呈現優異的防治效果，且對蚊（蚊科）呈現更優異的防治效果。在本發明防治組成物中，只要維持本發明之優異防治效果，該本發明自旨化合物A與該本發明醋化合物B之重量比無具體限制。通常，該重量比在50 : 1至1 : 50之範圍，較佳在10 : 1至1 : 10之範圍。本發明防治組成物可為本發明酯化合物A與本發明酯化合物B之單純混合物。然而，通常其係以多種調配物之形式使用。該調配物之實例包含油性溶液、可乳化濃縮物、可濕性粉末、懸浮濃縮物（例如水懸浮液及水性乳液）、微膠囊調配物、粉劑、粒劑、錠劑、氣霧劑、二氧化碳調配物、熱散發式（heating vaporization)調配物（例如防蚊卷 (mosquito coi 1 )、電蚊片（electric mosquito mat)、及液體吸收芯型殺蟲劑（fluid absorption wicking-type pesticide)、壓電型喷散殺蟲劑、熱燻蒸劑（heating fumigant)(例如自燃型燻蒸劑、化學反應型燻蒸劑、及多孔陶瓷板燻蒸劑）、非熱式燻蒸劑（例如樹脂燦蒸劑、紙製燻蒸劑、不織布燦蒸劑、織物燻蒸劑、及昇華錠 (sub 1 imation tab 1 et))、喷霧調配物（例如煙霧劑）、直接接觸型調配物（例如片狀型接觸式調配物、條狀型接觸式調配物及網狀型接觸式調配物）、ULV調配物及毒餌。舉例而言，可經由下列方法製備調配物。 (1)將本發明酯化合物A及本發明酯化合物B與固體載劑、液體載劑、氣體載劑或飼料混合，若有需要，加入 13 322446 201124083 用於調配物之其他輔助劑例如界面活丨生@ (2) 將基材以本發明酯化合物a κ i(Kanzawa spider mite) (Reira/ycZ/iAS, phase orange red to spider (hanging orange full claw c/tr/)), and European red mite (European red mite) Panonychus ulmi)); 蜱 (Ixodidae), such as the long-horned blood scorpion Ulaemaphysalis longicornis), after confession and sent! L. woven (parasitoid mites) (Dermanyssidae), such as northern fowl ( Northern fowl mite), poultry red mite (Dermanyssus gallinae). 12 322446 201124083 In particular, the control composition of the present invention exhibits an excellent control effect against dipteran insect pests and diseases, and exhibits superior control effects against mosquitoes (mosquitoes). In the control composition of the present invention, the weight ratio of the present invention to the vinegar compound B of the present invention is not particularly limited as long as the excellent control effect of the present invention is maintained. Usually, the weight ratio is in the range of 50:1 to 1:50, preferably in the range of 10:1 to 1:10. The control composition of the present invention may be a simple mixture of the ester compound A of the present invention and the ester compound B of the present invention. However, it is usually used in the form of a plurality of formulations. Examples of the formulation include oily solutions, emulsifiable concentrates, wettable powders, suspension concentrates (such as aqueous suspensions and aqueous emulsions), microcapsule formulations, powders, granules, lozenges, aerosols, carbon dioxide Formulations, heat vaporization formulations (eg, mosquito coi 1 , electric mosquito mats, and fluid absorption wicking-type pesticides, pressure) Electric spray insecticide, heating fumigant (such as self-ignition fumigant, chemical reaction fumigant, and porous ceramic plate fumigant), non-heat fumigant (such as resin fumigant, paper) Fumigants, non-woven steaming agents, fabric fumigants, sub-imaging tabs, spray formulations (eg aerosols), direct contact formulations (eg sheet-type contact formulations, Strip-type contact formulation and mesh-type contact formulation), ULV formulation and poison bait. For example, a formulation can be prepared by the following method: (1) The ester compound A of the present invention and the present invention The ester compound B is mixed with a solid carrier, a liquid carrier, a gas carrier or a feed, and if necessary, 13 322446 201124083 is used for other adjuvants of the formulation such as interfacial activity @ (2) The substrate is used in the present invention. Ester compound a κ i

Λ及本發明酯化合物B 浸潰。 (3) 將本發明酯化合物A、本發日日& 赞明酯化合物Β及基材混合，接著模製。這些調配物通常包含本發明醋彳Η 曰化合物Α及本發明酯化合物B之總量為0. 001至98重量％。用於調配物之固體載劑之實例包含細粉末及顆粒例如黏土（例如咼嶺土、石夕藻土、膨湖丄门土、富巴沙黏土 (Fubasami clay)及酸性白黏土）、入曰成性水合氧化矽、滑石、陶瓷、其他無機礦物（例如絹φ视农w、石英、硫、活性磁、碳酸鈣、及水合氧化矽）及化學肥料r& m例如硫酸銨、磷酸銨、硝酸銨、氯化銨及尿素）；及在常溫盔義為固體材料（例如 2, 4, 6-三異丙基-1，3, 5-三噚烷、萘、對- 對一氯本、棒腦及金剛石）；以及氈製品、纖維、布料、織早自汉瓴 W 蹲月、矣氏、線^狀^ 物、泡沫、多孔性材料及複纖（multifilament)，其係由一種或多種羊毛、絲、棉、麻、紙毁、合成_(_聚乙稀樹脂諸如低密度聚乙烯、直鏈低密度聚乙烯、及高密度聚乙烯；乙烯-乙烯酯共聚物諸如乙烯_醋酸乙烯酯共聚物· 乙烯-曱基丙烯酸酿共聚物諸如乙烯-甲基丙烯二曱醋共聚物、及乙烯-甲基丙烯酸乙酯共聚物；乙烯，烯酸：：聚物諸如乙烯-丙烯酸曱酯共聚物、及乙烯〜丙烯酸乙聚物；乙烯-乙烯基綾酸酯共聚物諸如乙烯__丙烯醆共聚物；乙烯—四環十二碳烯共聚物；聚丙烯樹脂諸如丙烯均聚物、 322446 14 201124083 及丙浠-乙烯共聚物；聚_4_曱基戊烯_ι ;聚丁稀_ι ;聚丁一稀，聚本乙烯，丙稀腈-苯乙稀樹脂；苯乙烯彈性體諸如丙稀腈-丁一稀-苯乙稀樹脂、苯乙稀-共概二稀欲段共聚物、及氫化苯乙烯-共輕二稀嵌段共聚物；氟塑膠；丙稀酸系樹脂諸如聚甲基丙烯酸甲酯；聚醯胺樹脂諸如尼龍6、及尼龍66 ;聚酯樹脂諸如聚對苯二曱酸乙二酯、聚萘二甲酸乙二酯、聚對苯二曱酸丁二酯、及聚對笨二曱酸伸環己基二亞甲酯；聚碳酸酯；聚縮醛；聚丙烯砜；聚丙烯酸酯；聚經基苯甲酸醋；聚醚醯亞胺；聚酯碳酸酯；聚苯醚樹脂； 1氣乙婦，聚偏一亂乙婦，聚胺S旨；及多孔性樹脂諸如聚胺酯泡沐、聚丙烯泡珠、及聚乙稀泡沫）、玻璃、金屬及陶瓷所組成。液體載劑之實例包含芳香族烴類或脂肪族烴類（例如二甲苯、曱笨、烷基萘、苯基二曱苯基乙烷、煤油、輕油、己烷、及環己烷）、函化烴類（例如氣苯、二氣曱烷、二氯乙烷、及三氯乙烷）、醇類（例如曱醇、乙醇、異丙醇、丁醇、己醇、本曱醇、及乙一醇）、峻類（例如二乙趟、乙二醇二曱醚、二乙二醇單曱醚、二乙二醇單乙醚、丙二醇單曱醚、四氫呋喃、及二卩萼烷）、酯類（例如醋酸乙酯、及醋酸丁酯）、酮類（例如丙酮、甲基乙基酮、甲基異丁美嗣、及環己酮）、腈類（例如乙腈、及異丁腈）、亞砜類.(例如二曱基亞砜）、羧醯胺類（acid amides)(例如N，N-二甲基甲蕴胺、N，N-二曱基乙醯胺、及N-曱基-吡咯啶_)、碳"酸烧二酯（例如碳酸丙二酯）、植物油類（例如大豆油、及棉籽 322446 15 201124083 油）、植物精油類（例如橙油、海索油、及檸檬油）及水。氣體載劑之實例包含丁烷氣體、氟氣化碳氣體、液化石油氣（LPG)、二曱醚、及二氧化碳。界面活性劑之實例包含烷基硫酸酯鹽類、烷基磺酸鹽、烷基芳基磺酸鹽、烷基芳基醚類、聚氧伸乙基化烷基芳基醚類、聚乙二醇醚類、多元醇酯類、及糖醇衍生物。用於調配物之其他輔助劑之實例包含黏結劑、分散劑、及安定劑。其具體實例包含酪蛋白、明膠、多醣類（例如澱粉、阿拉伯膠、纖維素衍生物、及藻酸）、木質素衍生物、膨潤土、醣、合成水溶性聚合物（例如聚乙烯醇、聚乙烯吡咯啶酮、及聚丙烯酸）、BHT(2, 6-二-第三丁基-4-甲基酚）及BHA(2-第三丁基-4-曱氧基酚與3-第三丁基-4-曱氧基紛之混合物）。防蚊卷之基材之實例包含植物粉末（例如木粉、及除蟲軔）以及黏結劑（例如紅摘樟科（处以/iws /) 之粉末、澱粉、及麩質）之混合物。電蚊片之基材之實例包含經纏結、壓縮及壓製成平板狀之棉絨、及經纏結、壓縮及壓製成平板狀之棉絨與紙漿的混合細纖維。自燃塑燻蒸劑之基材之實例包含可燃的發熱劑，例如硝酸鹽、亞硝酸鹽、胍鹽、氯酸鉀、硝化纖維素、乙基纖維素、及木粉；熱分解促進劑，例如鹼金屬鹽、鹼土金屬鹽、重鉻酸鹽、及鉻酸鹽；载氧劑，例如硝酸鉀；助燃劑，例如三聚氰胺、及小麥澱粉；填料，例如矽藻土；以及黏 16 322446 201124083 結劑，例如合成黏合劑。化學反應型燻蒸劑之基材之實例包含發熱劑，例如鹼金屬之硫化物、多硫化物及硫氳化物、及氧化辦；催化劑，例如碳質材料、碳化鐵及活性黏土；有機發泡劑，例如偶氮二曱醯胺、苯磺醯肼、二硝基五亞甲基四胺、聚苯乙烯及聚胺酯；及填料，例如天然纖維及合成纖維。用於例如樹脂壎蒸劑之樹脂之實例包含聚乙烯樹脂，例如低密度聚乙烯、直鏈低密度聚乙烯、及高密度聚乙烯；乙烯-乙烯酯共聚物，例如乙烯-醋酸乙烯酯共聚物；乙烯-曱基丙烯酸酯共聚物，例如乙烯-曱基丙烯酸曱酯共聚物、及乙烯-甲基丙烯酸乙酯共聚物；乙烯-丙烯酸酯共聚物，例如乙烯-丙烯酸曱酯共聚物、及乙烯-丙烯酸乙酯共聚物；乙烯-乙烯基羧酸酯共聚物，例如乙烯-丙烯酸共聚物；乙烯-四環十二碳烯共聚物；聚丙烯樹脂，例如丙烯均聚物、及丙烯-乙烯共聚物；聚-4-甲基戊烯-1 ;聚丁烯-1 ; 聚丁二烯；聚苯乙烯；丙烯腈-苯乙烯樹脂；苯乙烯彈性體，例如丙烯腈-丁二烯-苯乙烯樹脂、苯乙烯-共軛二烯嵌段共聚物及氩化苯乙烯-共軛二烯嵌段共聚物；氟塑膠；丙烯酸系樹脂，例如聚曱基丙烯酸曱酯；聚醯胺樹脂，例如尼龍 6及尼龍66 ;聚酯樹脂，例如聚對苯二曱酸乙二酯、聚萘二曱酸乙二酯、聚對苯二甲酸丁二酯、及聚對苯二曱酸伸環己基二亞曱酯；聚碳酸酯；聚縮醛；聚丙烯砜；聚丙烯酸酯；聚羥基苯曱酸酯；聚醚醯亞胺；聚酯碳酸酯；聚苯醚樹脂；聚氯乙烯；聚偏二氣乙烯；及聚胺酯。這些基材 17 322446 201124083 可單獨使用或以其組合使用。另外，若有需要，可將塑化劑’例如苯二甲酸酯（例如苯二曱酸二甲酯、及苯二甲酸二辛酯）、己二酸酯、及硬酯酸加入這些基材。該樹脂燻蒸劑係經由將本發明酯化合物A及本發明酯化合物b揉捏入基材，接著經由射出成型、擠壓成型或模壓成型來模製而製得。所得樹脂調配物可進行進一步加工例如模製或切割，若有需要，加工成平板、薄膜、帶狀物、網狀物或細繩之外型》這些樹脂調配物可被加工成，例如，動物頸圈、動物耳標、平板製品、誘引繩及園藝播柱（horticultural supports) ° 用於毒If之基材之實例包含飼料成分，例如榖粉、植物油、糖、及結晶纖維素；抗氧化劑，例如二丁基經基曱苯、及降二氫癒創木酸（nordihydroguaiaretic acid);防腐劑，例如去氫乙酸；防兒童及寵物誤食劑，例如辣椒粉；及誘引病蟲害香料’例如乳赂香料、洋蔥香料、及花生油。本發明之病蟲害之防治方法係經由將本發明防治組成物施用至病蟲及/或病蟲棲息處（例如植物體、土壤、戶外、及動物體）而進行。另外’本發明之病蟲害之防治方法亦可經由將本發明酯化合物A及本發明酯化合物B施用至病蟲及/或病蟲棲息處而進行。具體而言，至於本發明防治組成物之應用方法，可由下列方法例示’且這些方法可根據例如該防治組成物之形式、及應用位置而予以適當地選擇。 (1)將本發明防治組成物本身施用至病蟲及/或該病 18 322446 201124083 蟲樓息處。 (2) 將本發明防治組成物以溶劑（例如水）稀釋，接著施用至病蟲及/或該病蟲棲息處。此情況中，通常，例如以可乳化濃縮物、可濕性粉末、懸浮濃縮物或微膠囊製劑之形式之本發明防治組成物係經稀釋，以使本發明酯化合物A及本發明酯化合物b之總度成為0.01至l〇〇0ppme 、、展 (3) 在病蟲棲息處加熱本發明防治組成物，以使成分揮發。在此情況中，本發明酯化合物A及本發明酯化合物B 之施用率及/辰度可根據例如本發明防治組成物之形式、施用時期、施用位置、施用方法、及傷害情況而適當地決定二在利用供防治目的用之本發明防治組成物中，就本發明酯化合物A及本發明酯化合物B之總量而言，當施用於空間時，施用率通常為〇. 〇〇〇〗至1000 mg/m3，而當施用於平面時’施用率為0.0001至1〇〇〇 mg/m2。熱散發式調配物（例如防蚊卷及電蚊片）係根據該調配物之形式來適當地加熱以使有效成分揮發而施用。非熱散發式燻蒸劑（例如樹脂燻蒸劑、紙製燦蒸劑、錠劑、不織布燻蒸劑、織物壎蒸劑、及片狀型調配物）例如可透過將其本身置於欲施用之空間、或透過將該調配物朝向風而使用。用於防治目的而施用本發明防治組成物之空間之實例包含壁櫥、廚台、衣櫃、箱櫃、食櫃、洗手間、浴室、倉庫、起居室、餐廳、車庫、和汽車内部。另外，該紕成 322446 19 201124083 物亦可施用於戶外開放空間。當本發明防治組成物係用於家畜（例如牛、馬、豬、綿羊、山羊及雞）及小型動物（例如狗、貓、大鼠及小鼠）以達到防治外寄生蟲之目的時，可經獸醫領域中之已知方法施加到所述動物。具體而言，當欲用於全身性防治時，該調配物係藉由錠劑、飼料混合物、拴劑及注射劑（包含肌内注射、皮下注射、靜脈注射及腹腔注射）之方式投予。另一方面，當欲用於非全身性防治時，該調配物係藉由喷灑油性溶液或水性溶液、澆注（P〇Ur-〇n)處理或滴注（sp〇t_〇n) 處理、以洗髮精調配物來洗滌動物、或將樹脂調配物製成的頸圈或耳標安裝於動物之方式來使用。本發明酯化合物 A及本發明酯化合物B之總劑量通常係每1公斤（kg)動物體重為0. 01至1000毫克（mg)之範圍。本發明防治組成物可組合使用’或與其他成分混合，例如病蟲害防治劑諸如其他殺昆!&劑、殺蜗劑、及拒避劑 (repellents)、增效劑、及色素。後文，將藉由調配例及試驗例更詳細說明本發明。但本發明並不受限於該等實施例。首先，敘述本發明防治組成物之調配例。在調配例中’ 除非另行說明，否則所有“份數”皆以重量計。調配例1 將9份本發明酯化合物A及〇. 9份本發明酯化合物B 溶於37. 5份二甲苯及37. 5份N，N-二甲基甲醯胺中。於所得溶液中加入9. 1份聚氧伸乙基苯乙烯基苯基醚及6份十 20 322446 201124083 二烷基笨磺酸鈣，接著充分混合，獲得可乳化濃縮物。調配例2 於20份本發明醋化合物A及20份本發明醋化合物B 中加入5份S0RP0L 5060(東邦化學工業公司（T〇H〇The ester compound B of the present invention is impregnated. (3) The ester compound A of the present invention, the present day & tributary ester compound hydrazine and a substrate are mixed and then molded. 001至98重量百分比。 The total amount of the present invention is generally from 0. 001 to 98% by weight of the total amount of the acetonide hydrazine compound of the present invention and the ester compound B of the present invention. Examples of the solid carrier used in the formulation include fine powders and granules such as clay (e.g., glutinous earth, shixia, benthusui, fubasami clay, and acid white clay), Hydrated cerium oxide, talc, ceramics, other inorganic minerals (such as 绢φ视农w, quartz, sulfur, activated magnetic, calcium carbonate, and hydrated cerium oxide) and chemical fertilizers r& m such as ammonium sulfate, ammonium phosphate, nitric acid Ammonium, ammonium chloride and urea); and solid materials in the normal temperature helmet (for example, 2, 4, 6-triisopropyl-1,3,5-trioxane, naphthalene, p-p-chlorobenzene, rod Brain and diamond); and felts, fibers, fabrics, weaving from the Han dynasty W 蹲 month, 矣, wire ^, ^, foam, porous material and multifilament, which are made of one or more kinds of wool , silk, cotton, hemp, paper ruin, synthesis _ (_ polyethylene resin such as low density polyethylene, linear low density polyethylene, and high density polyethylene; ethylene-vinyl ester copolymer such as ethylene - vinyl acetate copolymer · Ethylene-mercaptoacrylic styrene copolymer such as ethylene-methyl propylene Anthracene vinegar copolymer, and ethylene-ethyl methacrylate copolymer; ethylene, olefinic acid::polymer such as ethylene-decyl acrylate copolymer, and ethylene-acrylic acid ethomer; ethylene-vinyl phthalate copolymer For example, ethylene__acryl oxime copolymer; ethylene-tetracyclododecene copolymer; polypropylene resin such as propylene homopolymer, 322446 14 201124083 and propylene-ethylene copolymer; poly_4_decylpentene_ ; polybutylene _ι; polybutylene, polyethylene, acrylonitrile-styrene resin; styrene elastomer such as acrylonitrile-butyl- styrene-styrene resin, styrene-ethylene Rare-segment copolymer, and hydrogenated styrene-co-diethylene dilute block copolymer; fluoroplastic; acrylic resin such as polymethyl methacrylate; polyamine resin such as nylon 6, and nylon 66; polyester Resins such as polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, and poly(p-dibenzoic acid) cyclohexyl dimethylene methyl ester; polycarbonate; Acetal; polysulfone; polyacrylate; polybenzoic acid vinegar; polyether phthalimide; polyester carbonate; Ether resin; gas 1 B women, women polyvinylidene a disorder B, S polyamine purpose; porous resin and a polyamine such as Mu ester foam, polypropylene foam beads, and polyethylene foam), glass, metals and ceramics composed. Examples of the liquid carrier include aromatic hydrocarbons or aliphatic hydrocarbons (e.g., xylene, hydrazine, alkylnaphthalene, phenyl diphenyl phenylethane, kerosene, gas oil, hexane, and cyclohexane), Functionalized hydrocarbons (eg, benzene, dioxane, dichloroethane, and trichloroethane), alcohols (eg, sterols, ethanol, isopropanol, butanol, hexanol, decyl alcohol, and Ethyl alcohol), class (such as diethyl hydrazine, ethylene glycol dioxime ether, diethylene glycol monoterpene ether, diethylene glycol monoethyl ether, propylene glycol monoterpene ether, tetrahydrofuran, and dioxane), esters (e.g., ethyl acetate and butyl acetate), ketones (such as acetone, methyl ethyl ketone, methyl isobutyl methacrylate, and cyclohexanone), nitriles (such as acetonitrile, and isobutyronitrile), sulfoxide Classes (eg, dimethyl sulfoxide), acid amides (eg, N,N-dimethylmethanamine, N,N-dimercaptoacetamide, and N-mercapto-pyrrole) Acridine_), carbon " acid diester (such as propylene carbonate), vegetable oils (such as soybean oil, and cottonseed 322446 15 201124083 oil), plant essential oils (such as orange oil, hessian Oil, and lemon oil) and water. Examples of the gaseous carrier include butane gas, fluorine gasified carbon gas, liquefied petroleum gas (LPG), dioxane, and carbon dioxide. Examples of the surfactant include alkyl sulfate salts, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers, polyoxyethylated alkyl aryl ethers, polyethylene Alcohol ethers, polyol esters, and sugar alcohol derivatives. Examples of other adjuvants for the formulation include a binder, a dispersant, and a stabilizer. Specific examples thereof include casein, gelatin, polysaccharides (for example, starch, gum arabic, cellulose derivatives, and alginic acid), lignin derivatives, bentonite, sugar, synthetic water-soluble polymers (for example, polyvinyl alcohol, poly Vinyl pyrrolidone, and polyacrylic acid), BHT (2,6-di-t-butyl-4-methylphenol) and BHA (2-tert-butyl-4-methoxyphenol and 3-third a mixture of butyl-4-methoxy groups). Examples of the substrate of the anti-mosquito roll include a mixture of a plant powder (e.g., wood flour, and a mites) and a binder (e.g., a powder of the red picking family (/iws/), starch, and gluten). Examples of the substrate of the mosquito-repellent sheet include a woven fabric which is entangled, compressed, and pressed into a flat shape, and a mixed fine fiber which is entangled, compressed, and pressed into a flat cotton lint and pulp. Examples of the substrate of the self-igniting plastic fumigant include a flammable heat generating agent such as nitrate, nitrite, cerium salt, potassium chlorate, nitrocellulose, ethyl cellulose, and wood powder; a thermal decomposition accelerator such as an alkali metal salt , alkaline earth metal salts, dichromates, and chromates; oxygen carriers, such as potassium nitrate; combustion improvers, such as melamine, and wheat starch; fillers, such as diatomaceous earth; and viscous 16 322446 201124083, such as synthesis Adhesive. Examples of the substrate of the chemical reaction type fumigant include a heat generating agent such as an alkali metal sulfide, a polysulfide and a sulfonium compound, and an oxidation plant; a catalyst such as a carbonaceous material, iron carbide and activated clay; and an organic foaming agent; For example, azodiamine, benzenesulfonamide, dinitropentamethylenetetramine, polystyrene and polyurethane; and fillers such as natural fibers and synthetic fibers. Examples of the resin used for, for example, a resin purifying agent include polyethylene resins such as low density polyethylene, linear low density polyethylene, and high density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymer An ethylene-mercapto acrylate copolymer such as an ethylene-mercapto methacrylate copolymer, and an ethylene-ethyl methacrylate copolymer; an ethylene-acrylate copolymer such as an ethylene-acrylic acid acrylate copolymer, and ethylene; - ethyl acrylate copolymer; ethylene-vinyl carboxylate copolymer, such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resin, such as propylene homopolymer, and propylene-ethylene copolymer Poly-4-methylpentene-1; polybutene-1; polybutadiene; polystyrene; acrylonitrile-styrene resin; styrene elastomer, such as acrylonitrile-butadiene-styrene Resin, styrene-conjugated diene block copolymer and argon styrene-conjugated diene block copolymer; fluoroplastic; acrylic resin, such as polydecyl methacrylate; polyamine resin, such as nylon 6 and nylon 66; polyester a fat, such as polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, and poly(terephthalic acid) cyclohexyl di decylene ester; polycarbonate; Polyacetal; polysulfone; polyacrylate; polyhydroxybenzoic acid ester; polyether quinone imine; polyester carbonate; polyphenylene ether resin; polyvinyl chloride; polyvinylidene gas; and polyurethane. These substrates 17 322446 201124083 can be used alone or in combination. In addition, if necessary, plasticizers such as phthalic acid esters (such as dimethyl phthalate and dioctyl phthalate), adipates, and stearic acid can be added to these substrates. . The resin fumigant is obtained by kneading the ester compound A of the present invention and the ester compound b of the present invention into a substrate, followed by molding by injection molding, extrusion molding or press molding. The resulting resin formulation can be subjected to further processing such as molding or cutting, if desired, to a flat sheet, film, ribbon, web or string. These resin formulations can be processed into, for example, animals. Collars, animal ear tags, flat products, attracting ropes, and horticultural supports ° Examples of substrates for poisoning include feed ingredients such as lotus root starch, vegetable oil, sugar, and crystalline cellulose; antioxidants, For example, dibutyl benzoquinone, and nordihydroguaiaretic acid; preservatives such as dehydroacetic acid; anti-child and pet ingestants, such as paprika; and induced pests and fragrances such as breast Spices, onion flavors, and peanut oil. The method for controlling pests and diseases of the present invention is carried out by applying the control composition of the present invention to pests and/or pest habitats (e.g., plant bodies, soils, households, and animal bodies). Further, the method for controlling pests and diseases of the present invention can also be carried out by applying the ester compound A of the present invention and the ester compound B of the present invention to a pest and/or a pest habitat. Specifically, as for the application method of the control composition of the present invention, it can be exemplified by the following methods' and these methods can be appropriately selected depending on, for example, the form of the control composition and the application position. (1) Applying the control composition of the present invention itself to a pest and/or the disease 18 322446 201124083 Insects. (2) The control composition of the present invention is diluted with a solvent (e.g., water), and then applied to a pest and/or a pest habitat. In this case, usually, the control composition of the present invention is, for example, in the form of an emulsifiable concentrate, a wettable powder, a suspension concentrate or a microcapsule preparation, which is diluted so that the ester compound A of the present invention and the ester compound of the present invention b The total degree is 0.01 to 10 ppme, and (3) the composition of the present invention is heated in the habitat of the pest to cause the components to volatilize. In this case, the application rate and/or degree of the ester compound A of the present invention and the ester compound B of the present invention can be appropriately determined according to, for example, the form of the control composition of the present invention, the application period, the application site, the administration method, and the injury condition. 2. In the control composition of the present invention for use in control, for the total amount of the ester compound A of the present invention and the ester compound B of the present invention, when applied to a space, the application rate is usually 〇. 〇〇〇 1000 mg/m3, and the application rate was 0.0001 to 1 mg/m2 when applied to a flat surface. The heat-spreading formulation (e.g., mosquito-repellent roll and electric mosquito-repellent sheet) is suitably heated according to the form of the formulation to administer the active ingredient. Non-thermal fumigant fumigants (eg, resin fumigants, paper fumigants, lozenges, non-woven fumigants, fabric fumigants, and sheet-like formulations) can be placed, for example, by placing themselves in the space to be applied, Or by using the formulation towards the wind. Examples of the space for applying the control composition of the present invention for control purposes include closets, kitchen counters, wardrobes, bins, food cabinets, restrooms, bathrooms, warehouses, living rooms, dining rooms, garages, and interiors of automobiles. In addition, the 纰 322446 19 201124083 can also be applied to outdoor open spaces. When the control composition of the present invention is used for livestock (such as cattle, horses, pigs, sheep, goats, and chickens) and small animals (such as dogs, cats, rats, and mice) for the purpose of controlling ectoparasites, The animal is applied by methods known in the veterinary art. Specifically, when intended for systemic control, the formulation is administered by a lozenge, a feed mixture, an elixir, and an injection (including intramuscular injection, subcutaneous injection, intravenous injection, and intraperitoneal injection). On the other hand, when intended for non-systemic control, the formulation is treated by spraying an oily solution or an aqueous solution, pouring (P〇Ur-〇n) treatment or dripping (sp〇t_〇n) The shampoo formulation is used to wash the animal, or the collar or ear tag made of the resin formulation is used in an animal. The total dose of the ester compound A of the present invention and the ester compound B of the present invention is usually in the range of 0.01 to 1000 mg (mg) per 1 kg (kg) of animal body weight. The control composition of the present invention may be used in combination or mixed with other ingredients such as pest control agents such as other killing agents & agents, smoldering agents, and repellents, synergists, and coloring agents. Hereinafter, the present invention will be described in more detail by way of formulation examples and test examples. However, the invention is not limited to the embodiments. First, a formulation example of the control composition of the present invention will be described. In the formulation example, all "parts" are by weight unless otherwise stated.份份份份。 9 parts of the ester compound A of the present invention and 9 parts of the ester compound B of the present invention dissolved in 37.5 parts of xylene and 37.5 parts of N, N-dimethylformamide. To the resulting solution, 9.1 parts of polyoxyethylidene phenyl ether and 6 parts of 10 20 322446 201124083 dialkyl stearate sulfonate were added, followed by thorough mixing to obtain an emulsifiable concentrate. Formulation Example 2 Into 20 parts of the vinegar compound A of the invention and 20 parts of the vinegar compound B of the invention, 5 parts of S0RP0L 5060 (Tongbang Chemical Industry Co., Ltd. (T〇H〇)

Chemical industry Co.，Ltd.)之註冊商標），接著充分混合。於所得混合物中加入32份CARPLEX #8〇(Shi〇n〇gi &A registered trademark of Chemical industry Co., Ltd.), followed by thorough mixing. Add 32 parts of CARPLEX #8〇(Shi〇n〇gi &

Co.’Ltd.之註冊商標，為合成性水合氧化矽細粉）及23份 3 0 0筛目之矽藻土，接著以果汁機混合，獲得可濕性粉末。調配例3 於3份本發明酯化合物A及〇.3份本發明酯化合物B 内加入5份合成性水合氧化矽細粉、5份十二烷基苯磺酸鈉鹽、30份膨潤土及56. 7份黏土，接著充分攪拌及混合。然後，將適g用里的水加入所得混合物内。進一步擾拌混合物，以製粒機製粒，再經風乾，獲得顆粒調配物。調配例4 以碾缽充分混合5份本發明酯化合物A、〇. 5份本發明酉曰化合物B、1伤合成性水合氧化石夕細粉、1份作為絮凝劑之 DORILES B(第一三共株式會社（Daiich〇 Sanky〇 c〇.，The registered trademark of Co.' Ltd. is a synthetic hydrated cerium oxide fine powder) and 23 parts of 300 mesh diatomaceous earth, followed by mixing with a juice machine to obtain a wettable powder. Formulation Example 3 Into 3 parts of the ester compound A of the present invention and 3 parts of the ester compound B of the present invention, 5 parts of synthetic hydrated cerium oxide fine powder, 5 parts of sodium dodecylbenzenesulfonate, 30 parts of bentonite and 56 are added. 7 parts of clay, then thoroughly stirred and mixed. Then, water in the appropriate amount is added to the resulting mixture. The mixture was further agitated to pellet the granules and then air dried to obtain a granule formulation. Formulation Example 4 5 parts of the ester compound A of the present invention were thoroughly mixed with mash. 5 parts of the bismuth compound B of the present invention, 1 synthetic hydrated oxidized oxidized stone powder, and 1 part of DORILES B as a flocculating agent (first three) Co., Ltd. (Daiich〇Sanky〇c〇.,

Ltd.)之註冊商標）及7份黏土，接著以果汁機授拌及混合。於所得混合物内加入85. 5份切削黏土（cut clay)，接著充分授摔及混合’獲得粉劑調配物。調配例5 將10份本發明酯化合物A、1份本發明酯化合物b、 35份含有一半用量聚氧伸乙基烷基醚硫酸酯銨鹽之白碳、 21 322446 201124083 及54份水之混合物經由濕式硏磨法來細碎粒化，獲得粉劑調配物。調配例6 將0. 05份本發明酯化合物A及0. 1份本發明酯化合物 B溶於10份二氯甲烷中，且所得溶液與89. 85份異烷烴溶液（ISOPARM，埃克森（Exxon)化工公司之註冊商標）混合，獲得油性溶液。調配例7 將0. 1份本發明酯化合物A、0. 05份本發明酯化合物 B、及 49. 85 份 Neothiozole(Chuo Kasei CO.，Ltd.)置於氣溶膠罐中。在附接氣溶膠閥後，裝填25份二曱醚及25 份LPG，接著振蘯並進一步附接致動器（actuator)，獲得油性氣溶膠。調配例8 將0. 5份本發明酯化合物A、0. 05份本發明酯化合物 B、0. 01份BHT、5份二甲苯、3. 44份去臭煤油及1份乳化劑（Atomos 300，Atomos化學公司之註冊商標）之混合物與 50份蒸餾水裝填入氣溶膠容器中，並附接閥部件。然後，在加壓下將40份推進劑（LPG)經由閥裝填進氣溶膠容器中，獲得水性氣溶膠。調配例9 將一件0. 5公分（cm)厚、69公分長及0. 2公分寬具有蜂巢結構之紙品從其一端捲起以製得直徑5.5公分及高 0. 2公分之圓筒形載體。將適當用量之經由使5份本發明 22 322446 201124083 H A及〇. 5份本發明酿化合物B溶於94· 5份丙酮中溶液均勻地塗布到上述載體並經由風乾使丙綱揮發’獲得紙製蒸發式調配物。調配例10 將二維經編針織物（商標名：FUSION，產品型號： AKE69440，經銷商：Asahi Kasei 恤⑽ c〇rp〇加i⑽，厚度：4.3公分，織物密度：321公克/平方公尺4、2)，聚醢胺所製）剪裁成5公分直徑之圓形^將適當用量之經由使5份本發明酯化合物a及〇· 5份本發明酯化合物b溶於 94.5份丙_中所製得的溶液均勻地塗布到上述圓形三維經編針織物’並經由風乾使丙酮揮發，獲得編針織物蒸發式調配物。調配例11 將97.8份乙烯-甲基丙烯酸曱酯共聚物（甲基丙烯酸甲醋含量U0重量％’MFR=2[g/1() _.])、2份本發明醋化合物A及〇.2份本發明酯化合物B之混合物在13〇。〇使用在相同方向旋轉之45 min0雙螺桿擠出機熔融及揉合，再進一步在15(TC使用4〇min0擠出機熔融及揉合，接著從呈薄片外形之T鑄模擠出，再以冷卻輪冷卻，獲得樹脂蒸發式調配物。 '' 調配例12 將97. 8份乙烯-醋酸乙烯酯共聚物（醋酸乙烯酯含篁· 10重量°/Q，MFR=2[g/10 min· ])、2份本發明酯化合物 A及0. 2份本發明酯化合物b之混合物在丨3〇〇c使用在相同 322446 23 201124083 方向旋轉之45 ιηιηςύ雙螺桿擠出機熔融及揉合，再進一步在150°C使用40mm4擠出機熔融及揉合，接著從呈薄片外形之T鑄模擠出，再以冷卻輪冷卻，獲得樹脂蒸發式調配物。調配例13 將5份本發明酯化合物A及0. 5份本發明酯化合物B 溶於94. 5份丙酮，將適當量之所得溶液塗布到具有可摺疊結構之紙（2000 cm2)，並經由風乾使丙酮揮發，獲得紙製蒸發式調配物。調配例14 經由使3份本發明酯化合物A及0. 3份本發明酯化合物B溶於14. 6份丙酮而製得溶液。於此溶液内，加入0.2 份氧化鋅、1.0份α澱粉及42. 8份偶氮二曱醯胺。另外，於其内加入38. 1份水，並揉合混合物，使用擠出機模製顆粒外形，再乾燥以獲得顆粒。在其中央部份有鋁隔板分隔之容器中，將該顆粒置於其上部空間，並將50克氧化鈣置於其下部空間，獲得燻蒸劑。調配例15 於0.5份氧化鋅、2份α澱粉及97. 5份偶氮二甲醯胺之混合物内加入水，並揉合混合物及使用擠出機模製顆粒外形，再乾燥以獲得顆粒。然後，將2克顆粒均勻地浸潰在0. 58克本發明酯化合物Α及0. 058克本發明酯化合物Β 於丙酮之溶液中，並乾燥以獲得顆粒。在其中央部份有鋁隔板分隔之容器中，將該顆粒置於其上部空間，並將50 24 322446 201124083 克氧化鈣置於其下部空間，獲得燻蒸劑。調配例16 將0. 5克本發明酯化合物A及0. 05克本發明酯化合物 B溶於20毫升（mL)丙酮中，並將所得溶液加入99. 4克用於防蚊卷之基材（呈4 : 3 : 3之比例的紅楠樟科之粉末、除蟲菊及木粉之混合物）及0. 3克綠色色素之混合物内。充分混合後，將120毫升水加入該混合物並充分揉合。模製及乾燥所得混合物，獲得防蚊卷。調配例17 經由混合10份本發明酯化合物A、1份本發明酯化合物B、39. 5份乙醯化檸檬酸三丁酯、39. 5份己二酸異壬酯、 5份藍色色素及5份香料以製得溶液。將用於3.4公分x2. 1 公分且0.22公分厚的電蚊片之基材（經纏結、壓縮及壓製成平板狀之棉絨與紙漿的混合細纖維）均勻地浸潰在上述溶液，獲得電蚊片。調配例18 經由使0. 1份本發明酯化合物A及0. 01份本發明酯化合物B溶於99. 89份去臭煤油而製得溶液。將該溶液置於氯乙烯容器，及將經加工以使其上半部可經由加熱器加熱之液體吸收芯（經由以黏合劑固化無機粉末接著煅燒而製得）插進該容器内，獲得一份用於液體吸收芯型蒸發式調配物。調配例19 將0. 2份本發明酯化合物A、0. 02份本發明酯化合物 25 322446 201124083 B、及 49. 78 份 Neothiozole(Chuo Kasei CO.，Ltd.)置於氣溶膠罐中。在附接氣溶膠閥後，裝填25份二曱醚及25 份LPG，接著振盪並進一步附接用於全内容物-注入型氣溶膠之致動器，獲得氣溶膠調配物。調配例20 於0. 2份本發明酯化合物A及0. 02份本發明酯化合物 B内加入99.78份二乙二醇單乙醚，接著充分混合，獲得用於防治外寄生蟲之滴注調配物。調配例21 將經由使3份本發明酯化合物A及0. 3份本發明酯化合物B溶於96. 7份丙酮而製得溶液，並將1毫升溶液均勻地塗布到經由在壓力（4t/cm2)下模製4克2, 4, 6-三異丙基 -1，3, 5-三噚烷所得之盤形固體材料（3公分直徑及3毫米 (mm)厚），接著乾燥獲得錠劑。調配例22 在壓力下將0. 2克本發明酯化合物A、0. 02克本發明酯化合物B、及4克2, 4, 6-三異丙基-1，3, 5-三噚烷之均勻混合物模製為盤形（3公分直徑及3毫米厚），獲得錠劑。調配例23 將0.2克本發明酯化合物A、0. 02克本發明酯化合物 B及4克2, 4, 6-三異丙基-1，3, 5-三噚烷之混合物置於50 毫升螺紋管，經加熱熔融然後冷卻至室溫，獲得錠劑。接著，下列試驗例將顯示本發明防治組成物對病蟲害具有優異防治效果。 26 322446 201124083 在下列試驗例中，至於本發明醋化合物A，使用（⑻_ 反式-3-(2,2-二氯乙烯基）、2,2-二甲基環丙烧紐 [2, 3’5’6-四氧基甲基）苯基]甲醋。另外，至於本發明酯化合物B，使用3-(2-氰基-1-丙炔基[Ε/Ζ=1/9])-2, 2-二甲基環丙㈣酸[2, 3, 5, 6_四氟 -4-(甲氧基甲基）笨基]甲自旨。試驗例1 在下表1所不滚度下’經以給定量異烧烴溶劑（IS〇pAR Μ ’埃克森化學公司之註冊商標）稀釋本發明醋化合物B而製得油性浴液（後文中稱作為比較組成物G)) 。同樣地，在下表1所不濃度下，經以給定量異烷烴溶劑（IS〇pARM，埃克森化學公司之s主冊商標）稀釋本發明酯化合物A而製得油性溶液（後文中稱作為比較組成物（2)及（3))。另外，在下表1所示有效成分之濃度下，經以給定量異烷烴溶劑（ISOPAR M，埃克森化學公司之註冊商標）稀釋本發明酯化合物A及本發明酯化合物b而製得油性溶液（後文中稱作為本發明組成物（1)及（2))。將10隻庫蚊(雌性）釋放至每邊70 公分的立方形箱中，並以喷槍（喷灑壓力：〇. 9 kg/cm2)從該箱中央的小窗戶喷進0· 7毫升本發明組成物（1)。在喷灑後給定時間期間，調查擊落的昆蟲數目並計算擊落率 (knock down rate，KD率）。依照相同方法，使用本發明組成物（2)及比較組成物（1)、（2)及（3)，計算在給定時間期間後之KD率（2次）。 27 322446 201124083 結果係顯示於表1。表1 本發明酯化合物A 用量(W/V%) 本發明酯化合物B用量(W/V%) 7分鐘後之KD 率⑻ 本發明組成物（1) 0.00313 0.00156 100 比較組成物（1) - 0.00156 50 比較組成物（2) 0.00313 — 20 本發明組成物（2) 0.00156 0.00156 80 比較組成物（3) 0.00156 - 10 如上述，本發明可提供對病蟲害具有優異效果之病蟲害防治組成物及病蟲害防治方法。【圖式簡單說明】無【主要元件符號說明】無 28 322446The registered trademark of Ltd.) and 7 parts of clay are then mixed and mixed with a juice machine. To the resulting mixture, 85. 5 parts of cut clay was added, followed by full dropping and mixing to obtain a powder formulation. Formulation Example 5 10 parts of the ester compound A of the present invention, 1 part of the ester compound b of the invention, 35 parts of white carbon containing half of the amount of polyoxyethylidene ether sulfate ammonium salt, 21 322446 201124083 and 54 parts of water mixture Fine granulation was carried out by a wet honing method to obtain a powder formulation. Formulation Example 6 0.05 parts of the ester compound A of the invention and 0.1 part of the ester compound B of the invention are dissolved in 10 parts of dichloromethane, and the resulting solution is combined with 89.85 parts of isoparaffin solution (ISOPARM, Exxon ( Exxon) registered trademark of the chemical company) mixed to obtain an oily solution. Formulation Example 7 0.1 parts of the ester compound A of the present invention, 0.05 parts of the ester compound B of the present invention, and 49.85 parts of Neothiozole (Chuo Kasei CO., Ltd.) were placed in an aerosol can. After attaching the aerosol valve, 25 parts of dimethyl ether and 25 parts of LPG were charged, followed by shaking and further attaching an actuator to obtain an oily aerosol. Formulation Example 8 0.5 parts of the ester compound A of the present invention, 0.05 parts of the ester compound B of the present invention, 0.01 part of BHT, 5 parts of xylene, 3.44 parts of deodorized kerosene and 1 part of emulsifier (Atomos 300) A mixture of the registered trademark of Atomos Chemical Company) was filled with 50 parts of distilled water into an aerosol container and attached to the valve member. Then, 40 parts of propellant (LPG) was charged into the air sol container via a valve under pressure to obtain an aqueous aerosol. 5厘米的直径。 A sample of 0.5 cm (cm) thick, 69 cm long and 0. 2 cm wide with a honeycomb structure rolled up from one end to produce a diameter of 5.5 cm and a height of 0. 2 cm cylinder Shape carrier. A suitable amount is obtained by uniformly coating 5 parts of the present invention 22 322446 201124083 HA and 5 parts of the inventive brewing compound B in 94·5 parts of acetone to the above carrier and evaporating the propyl group by air drying. Evaporative formulation. Formulation Example 10 Two-dimensional warp knit fabric (trade name: FUSION, product model: AKE69440, dealer: Asahi Kasei shirt (10) c〇rp〇 plus i (10), thickness: 4.3 cm, fabric density: 321 g / m ^ 4 4 2), made of polyamine, cut into a circle of 5 cm in diameter. The appropriate amount is prepared by dissolving 5 parts of the ester compound a of the present invention and 5 parts of the ester compound b of the present invention in 94.5 parts of propylene. The resulting solution was uniformly applied to the above-mentioned circular three-dimensional warp knit fabric' and the acetone was volatilized by air drying to obtain a knitted fabric evaporative formulation. Formulation Example 11 97.8 parts of ethylene-methacrylate methacrylate copolymer (methyl methacrylate content U0% by weight 'MFR=2 [g/1 () _.)), 2 parts of the vinegar compound A and bismuth of the present invention. A mixture of 2 parts of the ester compound B of the present invention was 13 Torr.熔融 Melt and knead using a 45 min0 twin-screw extruder rotating in the same direction, and further melt and knead at 15 (TC using a 4 〇 min0 extruder, followed by extrusion from a T-die in a sheet shape, and then The cooling wheel was cooled to obtain a resin evaporating formulation. '' Formulation Example 12 97.8 parts of ethylene-vinyl acetate copolymer (vinyl acetate containing 重量·10 weight °/Q, MFR=2 [g/10 min· ]), 2 parts of the ester compound A of the present invention and 0.2 part of the ester compound b of the present invention are melted and kneaded at 丨3〇〇c using a 45 ιηιηςύ twin-screw extruder rotating in the same direction of 322446 23 201124083, and then Further, it was melted and kneaded at 150 ° C using a 40 mm 4 extruder, and then extruded from a T-die which was in the form of a sheet, and then cooled by a cooling wheel to obtain a resin evaporating formulation. Formulation Example 13 5 parts of the ester compound A of the present invention And 0.5 parts of the ester compound B of the present invention is dissolved in 94.5 parts of acetone, an appropriate amount of the obtained solution is applied to a paper having a foldable structure (2000 cm 2 ), and acetone is volatilized by air drying to obtain a paper evaporation type. Formulation Example 14 by esterifying 3 parts of the present invention And a solution of 0.2 parts of azodiamine. In this solution, 0.2 parts of zinc oxide, 1.0 part of alpha starch and 42.8 parts of azodiamine are added. In addition, 38. 1 part of water was added thereto, and the mixture was kneaded, and the shape of the pellet was molded using an extruder, followed by drying to obtain granules. The granules were placed in a container separated by an aluminum partition at a central portion thereof. The mixture was placed in the upper space, and 50 g of calcium oxide was placed in the lower space to obtain a fumigant. Formulation Example 15 was added to a mixture of 0.5 parts of zinc oxide, 2 parts of α-starch, and 97.5 parts of azomethicin. The emulsified ester ester of the present invention and 0. 58 g of the ester of the present invention are 0. 58 g of the ester compound of the present invention and 0. 58 g of the ester of the present invention. The ester of the present invention is further immersed in an amount of 0. The compound is kneaded in a solution of acetone and dried to obtain granules. In a container having a central partition separated by an aluminum partition, the granule is placed in its upper space, and 50 24 322446 201124083 g of calcium oxide is placed in the lower portion thereof. The gram of the present invention is esterified. A and 0. 05 g of the ester compound B of the present invention is dissolved in 20 ml (mL) of acetone, and the resulting solution is added to 99.4 g of the substrate for anti-mosquito (in a ratio of 4:3:3) a mixture of powder, pyrethrum and wood powder of cockroach and a mixture of 0.3 g of green pigment. After thorough mixing, 120 ml of water is added to the mixture and fully kneaded. The resulting mixture is molded and dried to obtain protection. The formulation of Example 17 is carried out by mixing 10 parts of the ester compound A of the invention, 1 part of the ester compound B of the invention, 39.5 parts of tributyl citrate, 39.5 parts of isodecyl adipate, 5 parts. A blue pigment and 5 parts of perfume were used to prepare a solution. A substrate for an electric mosquito sheet of 3.4 cm x 2 cm and 0.22 cm thick (mixed fine fibers entangled, compressed and pressed into a flat cotton lint and pulp) was uniformly impregnated in the above solution to obtain Electric mosquito tablets. Formulation Example 18 A solution was prepared by dissolving 0.1 part of the ester compound A of the present invention and 0.01 part of the ester compound B of the present invention in 99.89 parts of deodorized kerosene. The solution is placed in a vinyl chloride container, and a liquid absorbent core processed by heating the upper half thereof via a heater (made by curing the inorganic powder with a binder and then calcining) is inserted into the container to obtain a solution. Parts are used in liquid absorbent core type evaporative formulations. Formulation Example 19 0.2 part of the present ester compound A, 0.02 part of the ester compound of the invention 25 322446 201124083 B, and 49.78 parts of Neothiozole (Chuo Kasei CO., Ltd.) were placed in an aerosol can. After the aerosol valve was attached, 25 parts of dioxane and 25 parts of LPG were charged, followed by shaking and further attaching an actuator for a full content-injection type aerosol to obtain an aerosol formulation. Formulation Example 20 In the present invention, the ester compound A of the present invention and the 0.02 part of the ester compound B of the present invention are added with 99.78 parts of diethylene glycol monoethyl ether, followed by thorough mixing to obtain a drip formulation for controlling ectoparasites. . Formulation Example 21 A solution was prepared by dissolving 3 parts of the ester compound A of the present invention and 0.3 part of the ester compound B of the present invention in 96.7 parts of acetone, and uniformly coating 1 ml of the solution to the pressure (4t/). Cm2) A disc-shaped solid material (3 cm diameter and 3 mm (mm) thick) obtained by molding 4 g of 2,4,6-triisopropyl-1,3,5-trioxane, followed by drying to obtain an ingot Agent. Formulation Example 22 Under pressure, 0.2 g of the ester compound A of the invention, 0.02 g of the ester compound B of the invention, and 4 g of 2,4,6-triisopropyl-1,3,5-trioxane The homogeneous mixture was molded into a disk shape (3 cm diameter and 3 mm thick) to obtain a tablet. Formulation Example 23 0.2 g of the ester compound A of the present invention, 0.02 g of the ester compound B of the present invention and 4 g of a mixture of 2,4,6-triisopropyl-1,3,5-trioxane were placed in 50 ml. The threaded tube was melted by heating and then cooled to room temperature to obtain a tablet. Next, the following test examples will show that the control composition of the present invention has an excellent control effect on pests and diseases. 26 322446 201124083 In the following test examples, as for the vinegar compound A of the present invention, ((8)_trans-3-(2,2-dichlorovinyl), 2,2-dimethylcyclopropanol [2, 3] was used. '5'6-Tetraoxymethyl)phenyl]methine. Further, as for the ester compound B of the present invention, 3-(2-cyano-1-propynyl[Ε/Ζ=1/9])-2,2-dimethylcyclopropane(tetra) acid [2, 3, 5, 6_tetrafluoro-4-(methoxymethyl) stupid] A. Test Example 1 An oily bath was prepared by diluting the vinegar compound B of the present invention with a given amount of an isothermal hydrocarbon solvent (IS〇pAR® 'registered trademark of Exxon Chemical Co., Ltd.) in the following Table 1 (hereinafter) Said as a comparative composition G)). Similarly, an oily solution was prepared by diluting the ester compound A of the present invention with a given amount of an isoparaffin solvent (IS〇pARM, the s main product trademark of Exxon Chemical Co., Ltd.) at a concentration not shown in Table 1 below (hereinafter referred to as Compare compositions (2) and (3)). Further, an oily solution was prepared by diluting the ester compound A of the present invention and the ester compound b of the present invention in a given amount of an isoparaffin solvent (ISOPAR M, registered trademark of Exxon Chemical Co., Ltd.) at a concentration of the active ingredient shown in Table 1 below. (hereinafter referred to as compositions (1) and (2) of the present invention). 10 Culex (female) were released into a cubic box of 70 cm on each side, and sprayed with a spray gun (spray pressure: 〇. 9 kg/cm2) from a small window in the center of the box. Invention composition (1). During the given time after spraying, the number of insects shot down was investigated and the knock down rate (KD rate) was calculated. According to the same method, the KD rate (2 times) after a given period of time was calculated using the composition (2) of the present invention and the comparative compositions (1), (2) and (3). 27 322446 201124083 The results are shown in Table 1. Table 1 The amount of the ester compound A of the present invention (W/V%) The amount of the ester compound B of the present invention (W/V%) The KD rate after 7 minutes (8) The composition of the present invention (1) 0.00313 0.00156 100 Comparative composition (1) - 0.00156 50 Comparative composition (2) 0.00313 - 20 Composition of the present invention (2) 0.00156 0.00156 80 Comparative composition (3) 0.00156 - 10 As described above, the present invention can provide pest control compositions and pest control which have excellent effects on pests and diseases method. [Simple diagram description] None [Main component symbol description] None 28 322446

Claims

201124083 VII. Scope of application for patents: 1. A pest control composition, including ester compounds represented by formula (丨):

And a combination of ester compounds represented by formula (11): (I)

As an active ingredient. 2. The pest control composition according to claim 1, wherein the weight ratio of the ester compound represented by the formula (I) to the ester compound represented by the formula (Π) is from 50:1 to 1:50. range. 3. A method for controlling pests and diseases, comprising applying an effective amount of an ester compound represented by the formula (I) to a pest or a pest habitat:

And a combination of vinegar compounds represented by formula (11): (I) 1 322446 (II) 201124083 (II)

4. A combination of the use of the ester compound represented by the formula (I)

And a combination of the compounds represented by the formula (11): (I) h3coh2c

(μ) Used to control pests and diseases. 2 322446 201124083 IV. Designated representative map: There is no schema in this case (1) The representative representative figure of this case is: (). (2) A brief description of the symbol of the representative figure: 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention:

(I)

322446