TW201124080A - Harmful organism-controlling composition and control method of harmful organisms - Google Patents
Harmful organism-controlling composition and control method of harmful organisms Download PDFInfo
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201124080 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種病蟲害防治組成物及病蟲害之防 治方法。 【先前技術】 式（I)表示之s旨化合物：201124080 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a pest control composition and a method for controlling pests and diseases. [Prior Art] Compounds represented by formula (I):
(I) 為習知病蟲害防治製劑之有效成分（例如參見JP 57-123146A 及 CN 101306997A)。 另外，式（11)表示之酯化合物：(I) is an active ingredient of a conventional pest control preparation (see, for example, JP 57-123146A and CN 101306997A). Further, the ester compound represented by the formula (11):
亦為習知病蟲害防治製劑之有效成分（例如參見JP 60-9715B)。 然而，在某些情況中，依特定應用及所欲防治之病害 蟲而定，對該已知製劑而言，仍需要具有較高防治效果之 病蟲害防治製劑。 【發明内容】 發明所欲解決之問題 4 322448 201124080 本發明之目的係提供-種對病蟲害具有優異防治效果 之病蟲害防治組成物及病蟲害之防治方法。 解決問題之方法 由於本案發明人致力研究的結果，發現組合使用式⑴ 表示之ia化合物及式（H)表示之酯化合物對病蟲害呈現優 異防治效果。據此，完成本發明。 因此，本發明提供： (1) 一種病蟲害防治組成物，包括式（1)表示之酯化合 物：It is also an active ingredient of conventional pest control preparations (see, for example, JP 60-9715B). However, in some cases, depending on the particular application and the pest to be controlled, there is still a need for a pest control preparation having a high control effect for the known preparation. SUMMARY OF THE INVENTION Problems to be Solved by the Invention 4 322448 201124080 The object of the present invention is to provide a pest control composition and a pest control method which have excellent control effects against pests and diseases. Solution to Problem As a result of intensive research by the inventors of the present invention, it has been found that the combination of the ia compound represented by the formula (1) and the ester compound represented by the formula (H) exhibits an excellent control effect against pests and diseases. Accordingly, the present invention has been completed. Accordingly, the present invention provides: (1) A pest control composition comprising the ester compound represented by the formula (1):
(後文中稱為本發明酯化合物A)及式（π)表示之酯化合物 之組合：(hereinafter referred to as the ester compound A of the present invention) and a combination of ester compounds represented by the formula (π):
(後文中稱為本發明酯化合物β)作為有效成分； (2) 根據上述第（1)項之病蟲害防治組成物（後文中稱為本 發明防治組成物）’其中，該本發明酯化合物Α與該本 發明醋化合物B之重量比在5〇 : 1至1 : 50之範圍。 (3) —種病蟲害之防治方法，其包括對病蟲或病蟲棲息處 5 322448 / 201124080 A及本發明酯化合物b 施用有效量之本發明酯化合物 之級合；以及 酉旨化合物B之組合以 (4) 一種本發明酯化合物a及本發明 防治病蟲害之用途。 本發明之致果 本發日請治組成物及㈣转對㈣害呈現優異防治 效果。 【實施方式] ^發日諸治組成物之特徵在於包含本發则旨化合物A 及本發明酯化合物Β兩者。 本發明醋化合物Α例如可經由Jp 57_123遍中所述 方法予以製備。 本發明酯化合物B例如可經由jP 6〇_9715B中所述方 法予以製備。 本發明酯化合物A及本發明酯化合物B基於在其環丙 烷環之兩個不對稱碳原子而各可具有異構物。在本發明中， 可以任何比例使用含有活性異構物之酯化合物。 本發明防治組成物對其顯示有防治效果的病蟲害之 實例包含有害節肢動物例如昆蟲病蟲害及蜱蟎類（acarine) 病蟲害。其具體實例係如下列者。 鱗翅目（Lepidoptera)昆蟲病蟲害： 模蛾（填蛾科（Pyra! idae))例如稻條模（rice stem b〇rer)(— 化模蛾、稻縱捲葉蟲 (r i ce 1 eaf ro 11 er)(稻縱捲葉野螟蛾（心即如$ 6 322448 / 201124080 、及印度粉模（Indian meal moth)(印度穀粉 模蛾（/7<9^//3/77仏77?£/7^化//3));夜蛾（(^161：111〇1±)(夜蛾 科（Noctuidae))例如普通夜盜蟲（斜紋夜峨（Spoi/opkra //hra))、甜菜行軍蟲（beet armyworm)(甜菜葉蛾 (Spodoptera exigua))、稻行軍 A(東方黏 A(Pseudaletia separa ie))、及甘藍行軍蟲（甘藍夜蛾（ira △ra^ycae));紋白蝶（粉蝶科（Pieridae))例如普通菜粉蝶 (紋白蝶（/^er/s rapae));捲蛾（捲蛾科（Tortricidae))例 如姬捲葉蛾屬 spp.);果蛾（fruitworm moth) (果姓蛾科（Carposinidae));潛蛾(潛蛾科（Lyonetiidae)); 毒蛾（毒蛾科（Lymantriidae));金翅夜蛾亞科（Plusiae); 地老虎屬（如TO"·? spp.)例如地老虎（黄地老虎 segetu/n))反小地老肐（小地老虎（Agrotis ipsiJon));葉 蛾屬（Helicoverpa spp.);棉鈴蟲屬（Heliothis spp.); 鑽石背蛾（小菜蛾;直紋稻弄蝶（單 帶弄蝶（/¾咖ra ;製袋衣蛾（casemaking clothes moth)(衣蛾（T7/7ea ;以及織網衣蛾（webbing clothes raoth)(衣蛾（77/?eo/a 。 雙翅目（Diptera)昆蟲病蟲害： 蚊（蚊科（Calicidae))例如普遍蚊子（淡色庫蚊（心7己尤 pipienspallens、、^M^^i^XCulextritaeniorhynchiis、、 及南方家蚊（致倦庫蚊Wex iws));斑蚊屬 (defies spp.)例如黃熱蚊（埃及斑蚊（如des aew〆/)、及亞 洲免蚊（白線斑蚊（Aedes aJbopictus) ·，按蚊屬（AnopheJes 7 322448 201124080 spp.)例如中華癔蚊5/7^775/5);搖蚊（midges) (搖蚊科（Chironomidae));家蠅（家蠅科（Muscidae))例如家 缚X 家織(Jfusca domestica))、票、家竭XMusca bezzi)、敗藤 竭（false stable fly)(廄腐罐（#似(^/2<9 、及 小家廁题（lesser housefly)(黃腹廄蠅（/^/7/3/a ca/j/az/ar/s));麗繩（麗绳科（Calliphordiae));麻繩（麻 繩科（Sarcophagidae));花蠅（花繩科（Anthomyiidae))例如 種蠅（seedcornmaggot)(灰地種繩、及蔥 蠅（onion maggot)(蔥蠅;黑色清道夫繩 (black scavenger flies)(黑蠅科（Sepidae));果蠅（果實 蠅科（Tephritidae);潛蠅（潛蠅科（Agromyzidae));小果蠅 (果織科（Drosophilidae))例如普遍果蠅（野生果繩 ;蛾蚋（moth flies)(蛾蚋科 (Psychodidae));蚤蠅（蚤蠅科（Phoridae))例如蚤繩 (humpbacked fly)(東亞異蚤 •s/?y/^a/7aWs));蚋（black flies)(蚋科（Simuliidae)); 馬蠅（虻科（Tabanidae));穩蠅（螫蠅科（Stomoxyidae));以 及吸血小黑蚊（biting midges)(蠓科（Ceratopogonidae))。 網翅目（Dictyoptera)昆蟲病蟲害： 蟑螂（蜚蠊目（Blattariae))例如德國蟑螂（德國裴蠊 (Blattella germanica))、煙竭缚娜（黑胸大療 (Perip/a/jeia 、美洲蟑螂（美洲斐蠊 (Per/p/a/je)、棕色蟑螂（標色斐蠊 (Periplaneta brunnea))、反良方蹲辦（良方豐碡^B】atta 322448 201124080 orientalist)。 膜翅目（Hymenoptera)昆蟲病蟲害： 蟻（蟻科（Formicidae));馬蜂（胡蜂科（Vespidae)); 腫腿蜂（腫腿蜂科（Bethylidae));以及葉蜂（葉蜂科 ((Tenthredinidae))例如甘藍葉蜂（黃翅菜葉蜂（（Ji/za/ia rosae) ° 隱翅目（Aphaniptera)昆蟲病蟲害： ^§:i^3riCtenocepfialidescaiiis))、^K^§： {Ctenocephalides felis))、备{Purex irritansT)。 盘目（Anoplura)昆蟲病蟲害. 尺蟲Xk级 QPediculus humans))、毛赵（瘡级 (Phthirus pubis))、頭裂{琢备{Pediculus Inmans capitis)、、认 BlK後後^XPediculus hwnanus corporis))。 等翅目（Isoptera)昆蟲病蟲害： 曰本散白蟻（Japanese subterranean termite)(黃胸 散白蟻（办fycw// ier/Hes1 speraii/s))、以及台灣乳白蠛 (Formosan subterranean termite)(臺灣家白蟻 ICoptotermes formosanusY)。 半翅目（Hemiptera)昆蟲病蟲害： 飛盘（飛蝨科（Delphacidae))例如小褐飛蝨（smal 1 brown planthopper)($a striatellus))^ 褐稻飛兹（褐飛益ia )、及白背稻飛兹 9 322448 201124080 (白背飛兹（5bga /iAn://era));葉蟬（1 eaf hopper )(浮 塵子科（Deltocephalidae))例如青稻葉蟬（黑尾葉蟬 、及台灣青稻葉禪（二點黑尾葉 蟬（^印/?0^以/义1^/*615<^7715));財蟲（財科（人卩111(1丨(186)); 臭蟲（椿科（Pentatomidae));粉盘（粉蟲科（Aleyrodidae)); 介殼蟲（軟介殼蟲科（Coccidae));臭蟲（cimices)例如（溫 帶臭蟲（67历ez /eciw/ar/t/s));軍配蟲（軍配蟲科 (Tingidae));以及木蝨（木蝨科（Psyliidae))。 勒翅目（Coleoptera)昆蟲病蟲害： 玉米食根蟲（corn root worms)(葉甲屬 * spp.))例如黑皮蠹（black carpet beetle)(姬經節嘉 /apoyj/ci/sO)、姬圓經節蟲（varied carpet bee11 e )(小圓花皮蠹“/2 iArei/s FerZ^sc/))、西部玉米食根 方玉米食根蟲（Η —星瓜葉曱（Diabrotica undecimpunctata howardi));金龜子（金龜子科 (Scarabaeidae))例如綠金龜（cupreous chafer)(金銅金龜 (如⑽a/a 、及大豆曱蟲（soybeans beetle)(榛姬 金龜XAnomaL· rufocuprea));象鼻蟲X象鼻蟲 (Curculionidae))例如玉米象（maize weevil)(玉米象 (5"i、稻水象甲（rice water weevil)(稻 水象甲（Zyssar/zop^nAS aryzop/?2V£/s))、棉鈴象曱（bo 11 weev il)(棉鈐象甲（J/7泣〇77〇航/s· )、及綠豆象甲 (azuki bean weev i 1)(綠豆象（Ca/ 10 322448 201124080 ;擬步曱（darkling beetles)(擬步甲科 (Tenebrionidae))例如黃粉蟲（ye 11 ow mea 1 worm)(黃粉蟲 肌、及赤擬榖盜（red f lour beetle)(赤 擬穀盜caWawei//»));金花蟲（金花蟲科 (Chrysome 1 idae))例如稻泥蟲（稻負泥蟲（瓜3 or/zae))、 黃條葉蚤（striped flea beetle)(黃條葉蚤（Phyllotreta striolata))、及黃守瓜（cucurbit leaf beetle)(黃守瓜 肌;穀斑皮蠹（drugstore beetle) (竊蠹科（Anobiidae));食植瓢蟲屬（Epilachna spp.)例如 茄二十八星瓢蟲（twenty-eight-spotted ladybird)(茄二 十八星瓢蟲（你/yac/wa ;粉蠹蟲 (powder post beetles)(粉蠢亞科（Lyctinae));偽粉蠹 (false powder post beetles)(長蠹蟲科（Bostrichidae)); 天牛（longhorn beetles)(天牛科（Cerambycidae));以及隱 翅蟲（rove beetle)(蟻型隱翅蟲/iAscipes))。 纓翅目（Thysanoptera)昆蟲病蟲害： 瓜薊馬（Melon thrips)(南黃薊馬（TAr/pspa/见〇)、 柑橘黃薊馬（yellow citrus thrips)(西方花莉馬 、以及花薊馬（黑腹薊馬 {Frankliniella intonsa)) 〇 直翅目（Orthoptera)昆蟲病蟲害： 螻蛄（螻姑科（Gryllotalpidae))、以及壇蟲〇皇科 (Acrididae)) ° 蜱蜗目（Acarina): 322448 201124080 家居塵蟎（塵蟎科（Py rog 1 y ph i dae ))例如美洲塵蜗 {Dermatophagoides farinae')、及歡洲备織 {Dermatophagoides ptrenyssnus).，紛織{翁織势 (Acaridae))例如霉蟎（mold mite)(腐食酪蟎 pi/tresceyji/ae))、及橢圓斑白蟎; 蜱蜗（G1 ycyphag i d m i te s)例如食甜蜗（f/ycypAagi/s privatus)、家食甜蛾（Glycyphagus domesticus)、反害今 鱗蟎（i貧or);肉食蟎（肉食蜗科 (Cheyletidae))例如馬六曱肉食蟎（CfteWeii/s malaccensis)、反肉食蛾（Cheyletus fortis) ·，細織 (Tarosonemid mites)(細蟎科（Tarsonemidae));嗜渣蟎 (Chortoglyphid mites)(嗜渣科（Chortoglyphidae));禽 刺蜗（Haplochthoniid mites)(禽刺蜗科 (Haplochthoniidae));葉蟎（葉蟎科（Tetranychidae))例 如二點葉蟎（二斑葉蜗（7eira/7/c/ws·)、神澤葉蜗 (Kanzawa spider mite)(神澤葉蟎 财y))、柑桔紅換蛛（柑桔全爪蜗（pa/jo/j/c/ziAs c/tr?·))、及歐洲紅蜗（European red mite)(榆全爪蜗 (Panonychus ulmi));蜱（硬蜱科（Ixodidae))例如長角血 辦{Haemaphysalis longicornis).，认反後寄!k織 (parasitoid mites)(皮刺蟎科（Dermanyssidae))例如北 方禽蜗（northern fow 1 mite)(禽刺蜗（On/i/zo/zyssi/s 、及禽紅蜗（poultry red mite)(雞皮刺蜗 iDermanyssus gal 1 inaeY)。 12 322448 201124080 特別地，本發明防治組成物對雙翅目昆蟲病毒害呈現 優異的防治效果，且對蚊（蚊科）呈現更優異的防治效果。 在本發明防治組成物中，只要維持本發明之優異防治 效果’該本發明酯化合物A與該本發明酯化合物B之重量 比無具體限制。通常，該重量比在50 : 1至1 : 50之範圍， 較佳在10 : 1至1 : 1〇之範圍。 本發明防治組成物可為本發明酯化合物A與本發明酉旨 化合物B之單純混合物。然而，通常其係以多種調配物之 形式使用。該調配物之實例包含油性溶液、可乳化濃縮物、 可濕性粉末、懸浮濃縮物（例如水懸浮液及水性乳液）、微 膠囊s周配物、粉劑、粒劑、鍵劑、氣霧劑、二氧化碳調配 物、熱散發式（heating vaporization)調配物（例如防蚊卷 (mosquito coil)、電蚊片（electric mosquito mat)、及 液體吸收芯型殺蟲劑（fluid absorption wicking-type pesticide)、壓電型噴散殺蟲劑、熱燻蒸劑（heating fumigant)(例如自燃型燻蒸劑、化學反應型燻蒸劑、及多 孔陶瓷板燻蒸劑）、非熱式燻蒸劑（例如樹脂壎蒸劑、紙製 燻蒸劑、不織布燻蒸劑、織物燻蒸劑、及昇華錠 (sublimation tablet))、喷霧調配物（例如煙霧劑）、直接 接觸型調配物（例如片狀型接觸式調配物、條狀型接觸式調 配物及網狀型接觸式調配物）、ULV調配物及毒餌。 舉例而言，可經由下列方法製備調配物。 (1)將本發明酯化合物A及本發明酯化合物B與固體 載劑、液體載劑、氣體載劑或飼料混合，若有需要，加入 13 322448 201124080 用於調配物之其他輔助劑例如界面活性劑。 (2)將基材以本發_化合物A及本發_化合物β 浸潰。 ⑶將本發_化合物A、本發明㈣合物B及基材混 合，接著模製。 1^二-周配物通吊包含本發明酉旨化合物A及本發明酯化 合物β之總1為0·〇〇1至98重量 用於調配物之固體載劑之實例包含細粉末及顆粒例 如黏土（例如高嶺土、石夕藻土、膨潤土、富巴沙黏土 (Fubasami clay)及酸性白黏土） 田 s成性水合氧化石夕、滑 石、陶瓷、其他無機礦物（例如絹雲 — 碳酸辦、及水合氧化石夕）及化學肥料 央硫、/舌性碳、 硝酸敍、氯化銨及尿素）；及在常叫如琉酸録、麟酸銨、 2, 4, 6-三異丙基-1，3, 5一三曙燒、蔡=體材料（例如 剛石）；以及氈製品、纖維、布料、織=二氣笨、樟腦及金 物、泡沫、多孔性材料及複纖薄片、紙、線狀 種或多種羊毛、絲、棉、麻、崎、合’其係由一 樹脂諸如低密度聚乙烯、直鏈低密度聚^旨（例如聚乙烯 乙烯；乙烯-乙烯酉旨共聚物諸如乙婦―錯酸祕及高密度聚 乙烯-曱基丙烯酸醋共聚物諸如乙稀、酉θ共聚物’ 物、及乙歸-甲基丙烯酸乙酯共聚物；乙土豕稀酸甲醋共來 物諸如乙烯-丙稀酸甲醋共聚物、及乙埽曰共聚 物，乙稀-乙埽基驗醋共聚物諸如乙缔^婦酸共聚物； 乙烯-四％十一碳缚共聚物；聚丙稀樹脂諸如两歸均聚物、 322448 14 201124080 及丙烯-乙烯共聚物；聚-4-曱基戊烯-1 ;聚丁烯-1 ;聚丁 二烯；聚苯乙烯；丙烯腈-苯乙烯樹脂；苯乙烯彈性體諸如 丙烯腈-丁二烯-苯乙烯樹脂、苯乙烯-共軛二烯嵌段共聚 物、及氫化苯乙烯-共軛二烯嵌段共聚物；氟塑膠；丙烯酸 系樹脂諸如聚曱基丙烯酸曱酯；聚醯胺樹脂諸如尼龍6、 及尼龍66 ;聚酯樹脂諸如聚對苯二曱酸乙二酯、聚萘二曱 酸乙二酯、聚對苯二甲酸丁二酯、及聚對苯二甲酸伸環己 基二亞曱酯；聚碳酸酯；聚縮醛；聚丙烯砜；聚丙烯酸酯； 聚羥基苯曱酸酯；聚醚醯亞胺；聚酯碳酸酯；聚苯醚樹脂； 聚氯乙烯；聚偏二氣乙烯；聚胺酯；及多孔性樹脂諸如聚 胺酯泡沫、聚丙烯泡沫、及聚乙烯泡沫）、玻璃、金屬及陶 究所組成。 液體載劑之實例包含芳香族烴類或脂肪族烴類（例如 二曱苯、曱苯、烧基萘、苯基二曱苯基乙院、煤油、輕油、 己烷、及環己烷）、鹵化烴類（例如氯苯、二氯甲烷、二氣 乙烷、及三氯乙烷）、醇類（例如曱醇、乙醇、異丙醇、丁 醇、己醇、苯曱醇、及乙二醇）、醚類（例如二乙醚、乙二 醇二曱醚、二乙二醇單曱醚、二乙二醇單乙醚、丙二醇單 曱醚、四氫呋喃、及二卩等烷）、酯類（例如醋酸乙酯、及醋 酸丁酯）、酮類（例如丙酮、甲基乙基酮、曱基異丁基酮、 及環己酮）、腈類（例如乙腈、及異丁腈）、亞砜類（例如二 曱基亞颯）、竣醯胺類（acid amides)(例如N，N-二曱基曱 醯胺、N，N-二曱基乙醢胺、及N-曱基-吡咯啶酮）、碳酸烷 二酉旨（例如碳_酸丙二醋）、植物油類（例如大豆油、及棉杆 15 322448 201124080 油）、植物精油類（例如橙油、海索油、及棒檬油）及水。 氣體載劑之實例包含丁烷氣體、氟氯化碳氣體、液化 石油氣（LPG)、二曱醚、及二氧化碳。 界面活性劑之實例包含烷基硫酸酯鹽類、烷基磺酸 鹽、烧基芳基續酸鹽、烧基芳基醚類、聚氧伸乙基化统基 芳基醚類、聚乙二醇醚類、多元醇酯類、及糖醇衍生物。 用於調配物之其他輔助劑之實例包含黏結劑、分散 劑、及安定劑。其具體實例包含酪蛋白、明膠、多醣類（例 如澱粉、阿拉伯膠、纖維素衍生物、及藻酸）、木質素衍生 物、膨潤土、醣、合成水溶性聚合物（例如聚乙烯醇、聚乙 烯吡咯啶酮、及聚丙烯酸）、ΒΗΤ(2, 6-二-第三丁基-4-曱基 酚）及ΒΗΑ(2-第三丁基-4-曱氧基酚與3-第三丁基-4-甲氧 基酚之混合物）。 防蚊卷之基材之實例包含植物粉末（例如木粉、及除 蟲菊）以及黏結劑（例如紅械樟科（M/ / ws ίΛί//?/ ) 之粉末、澱粉、及麩質）之混合物。 電蚊片之基材之實例包含經纏結、壓縮及壓製成平板 狀之棉絨、及經纏結、壓縮及壓製成平板狀之棉絨與紙漿 的混合細纖維。 自燃塑燻蒸劑之基材之實例包含可燃的發熱劑，例如 硝酸鹽、亞硝酸鹽、脈鹽、氯酸鉀、硝化纖維素、乙基纖 維素、及木粉；熱分解促進劑，例如鹼金屬鹽、鹼土金屬 鹽、重鉻酸鹽、及鉻酸鹽；載氧劑，例如硝酸鉀；助燃劑， 例如三聚氰胺、及小麥澱粉；填料，例如矽藻土；以及黏 16 322448 201124080 結劑，例如合成黏合劑。 化學反應型燻蒸劑之基材之實例包含發熱劑，例如驗 金屬之硫化物、多硫化物及硫氫化物、及氧化約；催化劑， 例如碳質材料、碳化鐵及活性黏土；有機發泡劑，例如偶 氮二曱醯胺、苯磺醯肼、二硝基五亞曱基四胺、聚苯乙烯 及聚胺酯；及填料，例如天然纖維及合成纖維。 用於例如樹脂燻蒸劑之樹脂之實例包含聚乙烯樹 脂，例如低密度聚乙烯、直鏈低密度聚乙烯、及高密度聚 乙烯；乙烯-乙烯酯共聚物，例如乙烯-醋酸乙烯酯共聚物； 乙烯-曱基丙烯酸酯共聚物，例如乙烯-甲基丙烯酸曱酯共 聚物、及乙烯-曱基丙烯酸乙酯共聚物；乙烯-丙烯酸酯共 聚物，例如乙烯-丙烯酸甲酯共聚物、及乙烯-丙烯酸乙酯 共聚物；乙烯-乙烯基羧酸酯共聚物，例如乙烯-丙烯酸共 聚物；乙稀-四環十二碳烯共聚物；聚丙婦樹脂，例如丙浠 均聚物、及丙烯-乙烯共聚物；聚-4-曱基戊烯-1 ;聚丁烯 -1 ;聚丁二烯；聚苯乙烯；丙烯腈-苯乙烯樹脂；苯乙烯彈 性體，例如丙烯腈-丁二烯-苯乙烯樹脂、苯乙烯-共軛二烯 嵌段共聚物及氫化苯乙烯-共軛二烯嵌段共聚物；氟塑膠； 丙烯酸系樹脂，例如聚曱基丙烯酸曱自旨；聚si胺樹脂，例 如尼龍6及尼龍66;聚酯樹脂，例如聚對苯二曱酸乙二酯、 聚萘二曱酸乙二酯、聚對苯二曱酸丁二酯、及聚對苯二曱 酸伸環己基二亞甲酯；聚碳酸酯；聚縮醛；聚丙烯砜；聚 丙烯酸酯；聚羥基苯曱酸酯；聚醚醯亞胺；聚酯碳酸酯； 聚苯醚樹脂；聚氣乙烯；聚偏二氣乙烯；及聚胺酯。這些 17 322448 201124080 基材可單獨使用或以其組合使用。另外，若有需要，可將 塑化劑’例如苯二甲酸酯（例如苯二甲酸二甲酯、及苯二甲 酸二辛酯）、己二酸酯、及硬酯酸加入這些基材。該樹脂壤 蒸劑係經由將本發明酯化合物A及本發明酯化合物b揉捏 入基材，接著經由射出成型、擠壓成型或模壓成型來模製 而製得。所得樹脂調配物可進行進一步加工例如模製或切 割，若有需要，加工成平板、薄膜、帶狀物、網狀物或細 繩之外型。這些樹脂調配物可被加工成，例如，動物頸圈、 動物耳標、平板製品、誘引繩及園藝樁柱（horticultural supports) ° 用於毒餌之基材之實例包含飼料成分，例如榖粉、植 物油、糖、及結晶纖維素；抗氧化劑，例如二丁基羥基甲 苯、及降二氫癒創木酸（nordihydroguaiaretic acid);防 腐劑，例如去氩乙酸；防兒童及寵物誤食劑，例如辣椒粉； 及誘引病蟲害香料，例如乳路香料、洋蒽香料、及花生油。 本發明之病蟲害之防治方法係經由將本發明防治組 成物施用至病蟲及/或病蟲棲息處（例如植物體、土壤、戶 外、及動物體）而進行。另外，本發明之病蟲害之防治方法 亦可經由將本發明酯化合物A及本發明酯化合物B施用至 病蟲及/或病蟲棲息處而進行。 具體而言，至於本發明防治組成物之應用方法，可由 下列方法例示，且這些方法可根據例如該防治組成物之形 式、及應用位置而予以適當地選擇。 (1)將本發明防治組成物本身施用至病蟲及/或該病 18 322448 201124080 蟲棲息處。 (2) 將本發明防治組成物以溶劑（例如水）稀釋 施用至病蟲及/或該病蟲棲息處。 此情況中’通常，例如以可乳化濃縮物、可濕性粉東 懸浮濃縮物或微膠囊製社形式之本發明防治組成物係rt、 稀釋，以使本發明酉旨化合物A及本發明醋化合物b之 度成為0.01至10〇〇ppme 〜氣 (3) 在病蟲棲息處加熱本發明防治組成物，以使有效 成分揮發。 ’ 在此情況中，本發明酯化合物A及本發明酯化合物B 之施用率及濃度可根據例如本發明防治組成物之形式、施 用時期、施用位置、施用方法、及傷害情況而適當地決定。 在利用供防治目的用之本發明防治組成物中，就本發 明酯化合物A及本發明酯化合物B之總量而言，當施用於 空間時，施用率通常為〇· 〇〇〇1至1〇〇〇 mg/m3，而當施用 於平面時，施用率為0.0001至1000 mg/m2。熱散發式調 配物（例如防蚊卷及電蚊片）係根據該調配物之形式來適當 地加熱以使有效成分揮發而施用。非熱散發式燻蒸劑（例如 樹脂燦蒸劑、紙製燻蒸劑、錠劑、不織布燻蒸劑、織物燻 蒸劑、及片狀型調配物）例如可透過將其本身置於欲施用之 空間、或透過將該調配物朝向風而使用。 用於防治目的而施用本發明防治組成物之空間之實 例包含壁櫥、廚台、衣櫃、箱櫃、食櫃、洗手間、浴室、 倉庫、起居室、餐廳、車庫、和汽車内部。另外，該組成 19 322448 201124080 物亦可施用於戶外開放空間。 當本發明防治組成物係用於家畜（例如牛、馬、豬、 綿羊、山羊及雞）及小型動物（例如狗、貓、大鼠及小鼠） 以達到防治外寄生蟲之目的時’可經獸醫領域中之已知方 法施加到所述動物。具體而言’當欲用於全身性防治時， 該調配物係藉由錠劑、飼料混合物、栓劑及注射劑（包含肌 内注射、皮下注射、靜脈注射及腹腔注射）之方式投予。另 一方面，當欲用於非全身性防治時，該調配物係藉由喷灑 油性溶液或水性溶液、澆注（P〇ur-〇n)處理或滴注（spot-on) 處理、以洗髮精調配物來洗滌動物、或將樹脂調配物製成 的頸圈或耳標安裝於動物之方式來使用。本發明酯化合物 A及本發明酯化合物B之總劑量通常係每1公斤（kg)動物 體重為0. 01至1000毫克（mg)之範圍。 本發明防治組成物可組合使用’或與其他成分混合， 例如病蟲害防治劑諸如其他殺昆蟲劑、殺蟎劑、及拒避劑 (repellents)、增效劑、及色素。 後文，將藉由調配例及試驗例更詳鈿說明本發明。但 本發明並不受限於該等實施例。 首先，敘述本發明防治組成物之調配例。在調配例中， 除非另行說明，否則所有“份數”皆以重量計。 調配例1 將9份本發明酯化合物A及0. 9份本發明酯化合物β 溶於37· 5份二甲苯及37· 5份Ν，Ν-二甲基曱醯胺中。於所 得溶液中加入9. 1份聚氧伸乙基苯乙烯基苯基趟及6份十 322448 20 201124080 二烧基苯確酸約’接著充分混合’獲得可乳化濃縮物。 調配例2 於20份本發明S旨化合物A及20份本發明g旨化合物β 中加入5份S0RP0L 5060(東邦化學工業公司（T〇H〇(hereinafter referred to as the ester compound β of the present invention) as an active ingredient; (2) a pest control composition according to the above item (1) (hereinafter referred to as a control composition of the present invention) wherein the ester compound of the present invention is Α The weight ratio to the vinegar compound B of the present invention is in the range of 5 〇:1 to 1:50. (3) A method for controlling pests and diseases, which comprises applying an effective amount of the ester compound of the present invention to a pest or a pest inhabitant 5 322448 / 201124080 A and an ester compound b of the present invention; and a combination of the compound B (4) An ester compound of the invention and the use of the invention for controlling pests and diseases. The result of the present invention is to treat the composition on the day of the present day and (4) to turn to the (four) harm to present an excellent control effect. [Embodiment] The composition of the present invention is characterized by comprising both the compound A of the present invention and the ester compound of the present invention. The vinegar compound hydrazine of the present invention can be produced, for example, by the method described in Jp 57-123. The ester compound B of the present invention can be produced, for example, by the method described in jP 6〇_9715B. The ester compound A of the present invention and the ester compound B of the present invention may each have an isomer based on two asymmetric carbon atoms of the cyclopropane ring. In the present invention, an ester compound containing an active isomer can be used in any ratio. Examples of pests and diseases in which the composition of the present invention exhibits a control effect include harmful arthropods such as insect pests and acarine pests and diseases. Specific examples thereof are as follows. Lepidoptera insect pests: Moth (Pyra! idae) such as rice stem b〇rer (- model moth, rice leaf curler (ri ce 1 eaf ro 11 er (Rapese lobes) (hearts such as $6 322448 / 201124080, and Indian meal moth (Indian meal moth (/7<9^//3/77仏77?£/7 ^化//3)); Noctuidae ((^161:111〇1±) (Noctuidae)) such as ordinary night larvae (Spoi/opkra //hra), beet armyworm (beet armyworm) (Spodoptera exigua), rice march A (Pseudaletia separa ie), and cabbage marching worm (Brassica californica (ira △ra^ycae)); Pieridae)) For example, the common cabbage butterfly (/^er/s rapae); the moth (Tortricidae) such as the genus Spodoptera; the fruitworm moth (Carposinidae) )); the moth (Lyonetiidae); the poisonous moth (Lymantriidae); the golden-winged genus (Addiae); the genus (such as TO"·? spp.) such as the tiger (yellow) Ground tiger segetu/n)) anti-small old Agrotis ipsiJon); Helicoverpa spp.; Heliothis spp.; Diamondback moth (Plutella xylostella; Straight-grained rice butterfly (single-banded butterfly (/3⁄4 calra; Casemaking clothes moth (Tattoo moth (T7/7ea; and webbing clothes raoth) (cloth moth (77/?eo/a. Diptera insect pest): mosquito (mosquito Calicidae, for example, is a common mosquito (Culex pipiens) (heart 7 pipienspallens, ^M^^i^XCulextritaeniorhynchiis, and southern house mosquitoes (Wex iws)); defies spp. For example, yellow-hot mosquitoes (Aegypti mosquitoes (such as des aew〆/), and Asian mosquito-free mosquitoes (Aedes aJbopictus), Anopheles (AnopheJes 7 322448 201124080 spp.) such as Chinese sturgeon 5/7^ 775/5); midges (Chironomidae); Musca domestica (Muscidae) such as Jfusca domestica, tickets, home XMusca bezzi, defeat False stable fly (# ( (^/2<9, and lesser housefly) (/^/7/3/a ca/j/az/ Ar/s)); Li Sheng (Li Calliphordiae; Sarcophagidae; Anthemyiidae, such as seed cornmag (seedcornmaggot) Black scavenger flies (Sepidae); fruit flies (Tephritidae; larvae (Agromyzidae); small fruit flies (Drosophilidae) eg Common fruit flies (wild fruit rope; moth flies (Psychodidae); ticks (Phoridae) such as humpbacked fly (East Asia 蚤/s/?y/ ^a/7aWs)); black flies (Simuliidae); horsefly (Tabanidae); stray (Stomoxyidae); and biting midges (Ceratopogonidae). Dictyoptera insect pests and diseases: lat (Blattariae) such as German 蟑螂 (Blattella germanica), 烟竭娜 (Perip/a/jeia, American 蟑螂 ( Filipino (Per/p/a/je), brown cockroach (Periplaneta brunnea), anti-prefective 蹲 良 (良方丰碡^B) atta 322448 201124080 orientalist). Hymenoptera (Hymenoptera) Insect pests and diseases: ants (Formicidae); wasps (Vespidae); swollen bee (Bethylidae); and leaf bee (Tenthredinidae) such as cabbage leaves Bee (Ji/za/ia rosae) ° Aphaniptera insect pests: ^§:i^3riCtenocepfialidescaiiis)), ^K^§: {Ctenocephalides felis), and {Purex irritansT Anoplura insect pests and diseases. Jp-class QPediculus humans)), Mao (Phthirus pubis), head crack {Pediculus Inmans capitis), after recognition of BlK ^ XPediculus hwnanus corporis )). Isoptera insect pests: Japanese subterranean termite (yellow-breasted termites (fycw//ier/Hes1 speraii/s)), and Formosan subterranean termite (Taiwanese termites) ICoptotermes formosanusY). Hemiptera insect pests: Frisbee (Delphacidae) such as smal 1 brown planthopper ($a striatellus)) brown rice fly (Brown fly ia), and white back rice飞兹9 322448 201124080 (5bga /iAn://era); 1 eaf hopper (Deltocephalidae) such as green leafhopper (black-tailed spider mites) and Taiwan green rice leaf zen (Two points of black-tailed leafhoppers (^印/?0^//1^/*615<^7715)); worms (Finance 卩111(1丨(186)); bed bugs Pentatomidae)); powder plate (Aleyrodidae); scale insect (Coccidae); cimices such as (temperate bed bug (67 calendar ez /eciw/ar/t/s)); Army worm (Tingidae); and hibiscus (Psyliidae). Coleoptera insect pests: corn root worms (Sp. genus * spp.) For example, black carpet beetle (jijing festival / apoyj / ci / sO), variegated butterfly bee11 e (small round flower skin 蠹 "/2 iArei / s FerZ ^ sc /) ), western corn roots corn rootworm (Η - Diabrotica undecimpunctata howardi); Scarabaeidae, such as the cupreous chafer (golden copper turtle (such as (10) a/a, and soybean aphid (Soybeans beetle) (榛姬金龟XAnomaL· Rufocuprea)); weevil (Curculionidae) such as maize weevil (5"i, rice water weevil (rice water weevil (Zyssar/zop^nAS) Aryzop/?2V£/s)), boll wee il (bo 11 weev il) (cotton weevil (J/7 weeping 77 〇 / / s · ), and mung bean wee (azuki bean weev i 1) ( Mung bean (Ca/ 10 322448 201124080; darkling beetles (Tenebrionidae), such as ye 11 ow mea 1 worm (the yellow worm worm, and the red thief (red) f lour beetle); (Chrysome 1 idae) such as rice worm (rice worm ( melon 3 or / zae)), yellow strip Striped flea beetle (Phyllotreta striolata), and cucurbit leaf beetle (yellow squash); drugstore beetle (Anobii) Dae)); Epilachna spp., such as twenty-spotted ladybird (Twenty-eight-spotted ladybird) (you /yac/wa; powder aphid (powder post) Beetles (Lyctinae); false powder post beetles (Bostrichidae); longhorn beetles (Cerambycidae); and stag beetles ( Rove beetle) (ant genus genus / iAscipes)). Thysanoptera insect pests and diseases: Melon thrips (TAr/pspa/ see 〇), yellow citrus thrips (Western flower limus, and flower 蓟 horse ( Orthoptera insect pests and diseases: G (Gryllotalpidae), and the genus Acrididae ° ° Acarina: 322448 201124080 Home Dust mites (Py rog 1 y ph i dae), such as the American dust worm (Dermatophagoides farinae'), and the eucalyptus (Dermatophagoides ptrenyssnus), woven {Acaridae) such as mold (mold mite) (corrosive casein pi/tresceyji/ae)), and elliptic leukoplakia; G1 ycyphag idmi te s such as sweet worm (f/ycypAagi/s privatus), house-feeding sweet moth (Glycyphagus domesticus ), against the current scales (i poor or); carnivores (Cheyletidae) such as CfteWeii / s malaccensis, Cheyletus fortis, fine weaving (Tarosonemid mites ) (Tarsonemidae); Chortoglyphid mites ( Chortoglyphidae); Haplochthoniid mites (Haplochthoniidae); leaf mites (Tetranychidae) such as two-spotted spider mites (two snails (7 eira/7/c) /ws·), Kanzawa spider mite (神泽叶螨财 y)), citrus red for spider (citrus full claw (pa/jo/j/c/ziAs c/tr?·)) And European red mite (Panonychus ulmi); 蜱 (Ixodidae), such as the long-horned blood (Haemaphysalis longicornis), after the reversal! k-woven (parasitoid Mites) (Dermanyssidae) such as northern fow 1 mite (On/i/zo/zyssi/s, and poultry red mite (chicken skin thorn iDermanyssus) Gal 1 inaeY). 12 322448 201124080 In particular, the control composition of the present invention exhibits an excellent control effect against the virus of Diptera insects, and exhibits superior control effects against mosquitoes (Mosquitoes). In the control composition of the present invention, the weight ratio of the ester compound A of the present invention to the ester compound B of the present invention is not particularly limited as long as the excellent control effect of the present invention is maintained. Usually, the weight ratio is in the range of 50:1 to 1:50, preferably in the range of 10:1 to 1:1. The control composition of the present invention may be a simple mixture of the ester compound A of the present invention and the compound B of the present invention. However, it is usually used in the form of a plurality of formulations. Examples of the formulation include an oily solution, an emulsifiable concentrate, a wettable powder, a suspension concentrate (for example, an aqueous suspension and an aqueous emulsion), a microcapsule s weekly formulation, a powder, a granule, a key, an aerosol , a carbon dioxide formulation, a heat vaporization formulation (eg, a mosquito coil, an electric mosquito mat, and a fluid absorption wicking-type pesticide, Piezoelectric spray-spraying insecticide, heating fumigant (such as self-ignition fumigant, chemical reaction fumigant, and porous ceramic plate fumigant), non-heat fumigant (such as resin steaming agent, paper) Fumigants, non-woven fumigants, fabric fumigants, and sublimation tablets, spray formulations (eg aerosols), direct contact formulations (eg sheet contact formulations, strip contacts) Formulations and mesh type contact formulations), ULV formulations and baits. For example, formulations can be prepared by the following methods: (1) The ester compound A of the present invention and the ester of the present invention Compound B is mixed with a solid carrier, a liquid carrier, a gaseous carrier or a feed, and if necessary, 13 322448 201124080 is added to other adjuvants such as surfactants for the formulation. (2) The substrate is formulated as a compound. A and the present invention _ compound β is impregnated. (3) The present invention, the compound A, the compound (tetra) compound B, and the substrate are mixed and then molded. The 1^ two-week ligand is suspended and comprises the compound A of the present invention. The total amount of the ester compound β of the present invention is from 0.1 to 98 by weight. Examples of the solid carrier for the formulation include fine powders and granules such as clay (for example, kaolin, shishan, bentonite, and fuba sand) Fubasami clay) and acid white clay) Field hydrated oxidized oxidized stone, talc, ceramics, other inorganic minerals (such as Jinyun - Carbonate, and hydrated oxidized stone) and chemical fertilizers, central sulfur, / tongue carbon, nitrate , ammonium chloride and urea); and often called citrate, ammonium linonic acid, 2, 4, 6-triisopropyl-1,3,5-three lanthanum, Cai = body material (such as gangue ); and felt, fiber, cloth, weaving = two gas stupid, camphor and gold, bubble , porous materials and multifilament flakes, paper, linear seeds or a variety of wool, silk, cotton, hemp, saki, combined with a resin such as low density polyethylene, linear low-density polymerization (such as polyethylene Ethylene; ethylene-vinyl oxime copolymer such as M-wine acid and high-density polyethylene-mercapto acrylate copolymer such as ethylene, 酉θ copolymer, and ethyl methacrylate copolymer B. sulphate dilute sulphuric acid co-solvent such as ethylene-acrylic acid methyl vinegar copolymer, and acetamethylene copolymer, ethylene-acetonitrile acetal copolymer such as ethylene conjugated copolymer; ethylene - Four% eleven carbon-bonded copolymer; polypropylene resin such as two-homogen homopolymer, 322448 14 201124080 and propylene-ethylene copolymer; poly-4-decylpentene-1; polybutene-1; polybutadiene Polystyrene; acrylonitrile-styrene resin; styrene elastomer such as acrylonitrile-butadiene-styrene resin, styrene-conjugated diene block copolymer, and hydrogenated styrene-conjugated diene Segment copolymer; fluoroplastic; acrylic resin such as polydecyl acrylate; polyamine resin such as Dragon 6, and nylon 66; polyester resin such as polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, and polybutylene terephthalate Decyl ester; polycarbonate; polyacetal; polysulfone; polyacrylate; polyhydroxybenzoic acid ester; polyether phthalimide; polyester carbonate; polyphenylene ether resin; polyvinyl chloride; Ethylene; polyurethane; and porous resins such as polyurethane foam, polypropylene foam, and polyethylene foam), glass, metal and ceramics. Examples of the liquid carrier include aromatic hydrocarbons or aliphatic hydrocarbons (for example, diphenylbenzene, anthracene, alkyl naphthalene, phenyl diphenylene phenylene, kerosene, gas oil, hexane, and cyclohexane). , halogenated hydrocarbons (such as chlorobenzene, methylene chloride, di-ethane, and trichloroethane), alcohols (such as decyl alcohol, ethanol, isopropanol, butanol, hexanol, benzoanol, and B) Glycols, ethers (eg, diethyl ether, ethylene glycol dioxime ether, diethylene glycol monoterpene ether, diethylene glycol monoethyl ether, propylene glycol monoterpene ether, tetrahydrofuran, and dioxane), esters ( For example, ethyl acetate and butyl acetate), ketones (such as acetone, methyl ethyl ketone, decyl isobutyl ketone, and cyclohexanone), nitriles (such as acetonitrile, and isobutyronitrile), sulfoxide Classes (eg, dimercaptopurine), acid amides (eg, N,N-didecylguanamine, N,N-dimercaptoacetamide, and N-decyl-pyrrolidine) Ketone), alkyl carbonate (for example, carbonic acid propylene glycol), vegetable oils (such as soybean oil, and cotton stalk 15 322448 201124080 oil), plant essential oils (such as orange oil, sea Soap oil, and lemon oil) and water. Examples of the gaseous carrier include butane gas, carbon fluorocarbon gas, liquefied petroleum gas (LPG), dioxane, and carbon dioxide. Examples of the surfactant include alkyl sulfate salts, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers, polyoxyethylated aryl ethers, polyethylene Alcohol ethers, polyol esters, and sugar alcohol derivatives. Examples of other adjuvants for the formulation include a binder, a dispersant, and a stabilizer. Specific examples thereof include casein, gelatin, polysaccharides (for example, starch, gum arabic, cellulose derivatives, and alginic acid), lignin derivatives, bentonite, sugar, synthetic water-soluble polymers (for example, polyvinyl alcohol, poly Vinyl pyrrolidone, and polyacrylic acid), hydrazine (2,6-di-t-butyl-4-nonylphenol) and hydrazine (2-tert-butyl-4-methoxyphenol) and 3-third a mixture of butyl-4-methoxyphenol). Examples of the substrate of the anti-mosquito roll include plant powders (such as wood flour, and pyrethrum) and binders (such as powders, starches, and gluten of the genus (M/ / ws ίΛί//?)) a mixture. Examples of the substrate of the mosquito-repellent sheet include a woven fabric which is entangled, compressed, and pressed into a flat shape, and a mixed fine fiber which is entangled, compressed, and pressed into a flat cotton lint and pulp. Examples of the substrate of the self-igniting plastic fumigant include a flammable heat generating agent such as nitrate, nitrite, pulverized salt, potassium chlorate, nitrocellulose, ethyl cellulose, and wood powder; a thermal decomposition accelerator such as an alkali metal salt Alkaline earth metal salt, dichromate, and chromate; oxygen carrier, such as potassium nitrate; combustion improver, such as melamine, and wheat starch; filler, such as diatomaceous earth; and viscous 16 322448 201124080, such as synthesis Adhesive. Examples of the substrate of the chemical reaction type fumigant include a heat generating agent such as a metal sulfide, a polysulfide and a sulfur hydride, and an oxidation catalyst; a catalyst such as a carbonaceous material, iron carbide and activated clay; an organic foaming agent; For example, azodiamine, benzenesulfonamide, dinitropentamethylenetetramine, polystyrene and polyurethane; and fillers such as natural fibers and synthetic fibers. Examples of the resin used for, for example, a resin fumigant include polyethylene resins such as low density polyethylene, linear low density polyethylene, and high density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymer; Ethylene-mercapto acrylate copolymers, such as ethylene-methyl methacrylate copolymers, and ethylene-ethyl methacrylate copolymers; ethylene-acrylate copolymers, such as ethylene-methyl acrylate copolymers, and ethylene- Ethyl acrylate copolymer; ethylene-vinyl carboxylate copolymer, such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; polypropylene resin, such as propylene homopolymer, and propylene-ethylene Copolymer; poly-4-mercaptopentene-1; polybutene-1; polybutadiene; polystyrene; acrylonitrile-styrene resin; styrene elastomer, such as acrylonitrile-butadiene-benzene a vinyl resin, a styrene-conjugated diene block copolymer, and a hydrogenated styrene-conjugated diene block copolymer; a fluoroplastic; an acrylic resin such as polyacrylonitrile acrylate; a polysiamine resin, for example Nylon 6 and nylon 66; Resins, such as polyethylene terephthalate, polyethylene naphthalate, butylene dibutyl terephthalate, and poly(p-benzoic acid) cyclohexyl dimethylene methyl ester; polycarbonate Polyacetal; polysulfone; polyacrylate; polyhydroxybenzoic acid ester; polyether quinone imine; polyester carbonate; polyphenylene ether resin; polyethylene; polyvinylidene; These 17 322448 201124080 substrates can be used alone or in combination. Further, if necessary, a plasticizer such as phthalic acid ester (e.g., dimethyl phthalate, and dioctyl phthalate), adipate, and stearic acid may be added to these substrates. The resin soiling agent is obtained by kneading the ester compound A of the present invention and the ester compound b of the present invention into a substrate, followed by molding by injection molding, extrusion molding or press molding. The resulting resin formulation can be subjected to further processing such as molding or cutting, and if desired, to a flat sheet, film, ribbon, web or string. These resin formulations can be processed into, for example, animal collars, animal ear tags, flat articles, attracting ropes, and horticultural supports. Examples of substrates for baits include feed ingredients such as lotus root starch, vegetable oils. , sugar, and crystalline cellulose; antioxidants such as dibutylhydroxytoluene, and nordihydroguaiaretic acid; preservatives such as de-argonic acid; anti-child and pet ingestants, such as paprika ; and attract pests and diseases, such as milk road spices, artichoke spices, and peanut oil. The method for controlling pests and diseases of the present invention is carried out by applying the control composition of the present invention to pests and/or pest habitats (e.g., plant bodies, soils, households, and animal bodies). Further, the method for controlling pests and diseases of the present invention can also be carried out by applying the ester compound A of the present invention and the ester compound B of the present invention to a pest and/or a pest habitat. Specifically, as for the application method of the control composition of the present invention, it can be exemplified by the following methods, and these methods can be appropriately selected depending on, for example, the form of the control composition and the application position. (1) Applying the control composition of the present invention itself to a pest and/or the disease 18 322448 201124080 Insect habitat. (2) The control composition of the present invention is diluted with a solvent (e.g., water) and applied to a pest and/or a pest habitat. In this case, 'the usual control composition rt is diluted, for example, in the form of an emulsifiable concentrate, a wettable powder, or a microcapsule, to dilute the compound of the present invention and the vinegar of the present invention. The degree of the compound b is 0.01 to 10 〇〇 ppme to gas (3) The composition of the present invention is heated in the habitat of the pest to evaporate the active ingredient. In this case, the application rate and concentration of the ester compound A of the present invention and the ester compound B of the present invention can be appropriately determined depending on, for example, the form of the control composition of the present invention, the application period, the application site, the administration method, and the injury condition. In the control composition of the present invention for use in control, for the total amount of the ester compound A of the present invention and the ester compound B of the present invention, when applied to a space, the application rate is usually 〇·〇〇〇1 to 1 〇〇〇mg/m3, and when applied to a flat surface, the application rate is 0.0001 to 1000 mg/m2. The heat-spreading formulation (e.g., mosquito-repellent roll and electric mosquito-repellent sheet) is suitably heated according to the form of the formulation to administer the active ingredient. Non-heat-dissipating fumigants (eg, resin fumigants, paper fumigants, lozenges, nonwoven fumigants, fabric fumigants, and sheet-like formulations), for example, may be placed in the space to be applied, or It is used by facing the formulation toward the wind. Examples of the space for applying the control composition of the present invention for control purposes include closets, kitchen counters, wardrobes, bins, food cabinets, restrooms, bathrooms, warehouses, living rooms, dining rooms, garages, and interiors of automobiles. In addition, the composition 19 322448 201124080 can also be applied to outdoor open spaces. When the control composition of the present invention is used for livestock (such as cattle, horses, pigs, sheep, goats, and chickens) and small animals (such as dogs, cats, rats, and mice) for the purpose of controlling ectoparasites The animal is applied by methods known in the veterinary art. Specifically, when formulated for systemic control, the formulation is administered by a lozenge, a feed mixture, a suppository, and an injection (including intramuscular injection, subcutaneous injection, intravenous injection, and intraperitoneal injection). On the other hand, when intended for non-systemic control, the formulation is washed by spraying an oily solution or an aqueous solution, pouring (P〇ur-〇n) treatment or spot-on treatment. A hair styling formulation is used to wash the animal, or a collar or ear tag made of the resin formulation is attached to the animal. The total dose of the ester compound A of the present invention and the ester compound B of the present invention is usually in the range of 0.01 to 1000 mg (mg) per 1 kg (kg) of animal body weight. The control composition of the present invention may be used in combination or mixed with other ingredients such as pest control agents such as other insecticides, acaricides, and repellents, synergists, and pigments. Hereinafter, the present invention will be described in more detail by way of formulation examples and test examples. However, the invention is not limited to the embodiments. First, a formulation example of the control composition of the present invention will be described. In the formulation examples, all "parts" are by weight unless otherwise stated. Formulation Example 1 9 parts of the ester compound A of the present invention and 0.9 parts of the ester compound β of the present invention were dissolved in 37·5 parts of xylene and 3·7 parts of hydrazine, hydrazine-dimethyl decylamine. To the resulting solution was added 9.1 parts of polyoxyethylidene phenyl hydrazine and 6 parts of dec. 322448 20 201124080 dialkyl phthalic acid about 'and then thoroughly mixed' to obtain an emulsifiable concentrate. Formulation Example 2 To 20 parts of the S compound of the present invention and 20 parts of the compound β of the present invention, 5 parts of S0RP0L 5060 (Tung Hau Chemical Industry Co., Ltd. (T〇H〇) was added.
Chemical Industry Co·，Ltd.)之註冊商標），接著充分混 合。於所得混合物中加入32份CARPLEX #80(Shion〇gi &A registered trademark of Chemical Industry Co., Ltd.), followed by thorough mixing. Add 32 parts of CARPLEX #80 (Shion〇gi &
Co., Ltd.之5主冊商標，為合成性水合氧化石夕細粉）及μ份 300篩目之矽藻土，接著以果汁機混合，獲得可濕性粉末。 調配例3 於3份本發明酯化合物A及0.3份本發明酯化合物b 内加入5份合成性水合氧化矽細粉、5份十二烷基苯磺酸 鈉鹽、30份膨潤土及56 7份黏土，接著充分攪拌及混合。 然後’將適當用量的水加入所得混合物内。進一步擾摔混 合物，以製粒機製粒，再經風乾，獲得顆粒調配物。 調配例4 以礙蛛充分混合5份本發明S旨化合物A、0. 5份本發明 酉曰化合物B、1份合成性水合氧化矽細粉、丨份作為絮凝劑 之 DORILES B(第一三共株式會社（Daiicho Sankyo Co.，Co., Ltd.'s 5 main volume trademarks are synthetic hydrated oxidized oxidized stone fine powder) and μ parts of 300 mesh diatomaceous earth, followed by mixing with a juice machine to obtain a wettable powder. Formulation Example 3 Into 3 parts of the ester compound A of the present invention and 0.3 part of the ester compound b of the present invention, 5 parts of synthetic hydrated cerium oxide fine powder, 5 parts of sodium dodecylbenzenesulfonate, 30 parts of bentonite and 56 7 parts are added. Clay, then thoroughly stirred and mixed. Then, an appropriate amount of water is added to the resulting mixture. The mixture is further disturbed, granulated by a granulation mechanism, and then air-dried to obtain a granule formulation. Formulation Example 4 In order to thoroughly mix 5 parts of the present invention, a compound A, 0.5 part of the present invention, a compound B, 1 part of a synthetic hydrated cerium oxide fine powder, and a part of a flocculant DORILES B (first three Daiichiho Sankyo Co.,
Ltd.)之註冊商標）及7份黏土，接著以果汁機攪拌及混合。 於所得混合物内加入85· 5份切削黏土（cut clay)，接著充 分攪拌及混合，獲得粉劑調配物。 調配例5 將1〇份本發明酯化合物A、1份本發明酯化合物B、 35份含有一半用量聚氧伸乙基烷基醚硫酸酯銨鹽之白碳、 322448 21 201124080 及54份水之混合物經由濕式硏磨法來細碎粒化，獲得粉劑 調配物。 調配例6 將0. 05份本發明酯化合物A及0. 1份本發明酯化合物 B溶於10份二氣曱烷中，且所得溶液與89. 85份異烷烴溶 液（IS0PARM，埃克森（Exxon)化工公司之註冊商標）混合， 獲得油性溶液。 調配例7 將0. 1份本發明酯化合物A、0. 05份本發明酯化合物 B、及 49. 85 份 Neothiozole(Chuo Kasei CO.，Ltd.)置於 氣溶膠罐中。在附接氣溶膠閥後，裝填25份二曱醚及25 份LPG，接著振盪並進一步附接致動器（actuator)，獲得 油性氣溶膠。 調配例8 將0. 5份本發明酯化合物A、0. 05份本發明酯化合物 B、0. 01份BHT、5份二曱苯、3. 44份去臭煤油及1份乳化 劑（Atomos 300，Atomos化學公司之註冊商標）之混合物與 50份蒸餾水裝填入氣溶膠容器中，並附接閥部件。然後， 在加壓下將40份推進劑（LPG)經由閥裝填進氣溶膠容器 中，獲得水性氣溶膠。 調配例9 將一件0. 5公分（cm)厚、69公分長及0. 2公分寬具有 蜂巢結構之紙品從其一端捲起以製得直徑5.5公分及高 0. 2公分之圓筒形載體。將適當用量之經由使5份本發明 22 322448 201124080 酉曰化。物A及〇· 5份本發明酯化合物B溶於94 5份丙酮中 所製得的溶㈣勻地塗布到上述《並經由風乾使丙酮揮 發，獲得紙製蒸發式調配物。 調配例10 將二維經編針織物（商標名：FUSION，產品型號. AKE69440，蠖鑪翕.Λ p . ^ 銷商· Asahi Kasei Fibers Corporation， 厚度：4·3公分，織物密度：321公克/平方公尺（g/m2)， 聚醯胺所製）剪裁成5公分直徑之圓形。將適當用量之經由 使5伤本發明g旨化合物A及〇·5份本發明醋化合物b溶於 9 4 · 5份叫中所製得的溶液均勻地塗布到上述圓形三維 、’編十我物並經由風乾使丙酮揮發，獲得編針織物蒸發 式調配物。 、、χ 調配例11 將97.8份乙烯-曱基丙烯酸甲酯共聚物（甲基丙烯酸 甲酯含篁：1〇重量％，MFR=2[g/1〇 min. ])、2份本發明酯 化cr物A及〇. 2份本發明酯化合物B之混合物在13〇。〇使 用在相同方向旋轉之45 雙螺桿擠出機熔融及揉合， 再進一步在15〇。〇使用40 min0擠出機熔融及揉合，接著從 呈薄片外形之T鑄模擠出，再以冷卻輪冷卻，獲得樹脂蒸 發式調配物。 調配例12 將97.8份乙烯-醋酸乙烯酯共聚物（醋酸乙烯酯含 量· 10重量％，MFR=2[g"〇 min. ])、2份本發明酯化合物 A及〇. 2份本發明酯化合物B之混合物在i3〇〇c使用在相同 23 322448 201124080 方向旋轉之45 mm 0雙螺桿擠出機溶融及揉合，再進一步 在15(TC使用擠出機熔融及揉合，接著從呈薄片外 形之T鑄模擠出，再以冷卻輪冷卻，獲得樹脂蒸發式調配 物。 調配例13 將5份本發明酯化合物A及0. 5份本發明酯化合物B 溶於94. 5份丙酮，將適當量之所得溶液塗布到具有可摺疊 結構之紙（2000 cm2)，並經由風乾使丙酮揮發，獲得紙製 蒸發式調配物。 調配例14 經由使3份本發明酯化合物A及0. 3份本發明酯化合 物B溶於14. 6份丙酮而製得溶液。於此溶液内，加入0. 2 份氧化辞、1. 0份α澱粉及42. 8份偶氮二曱醯胺。另外， 於其内加入38. 1份水，並揉合混合物，使用擠出機模製顆 粒外形，再乾燥以獲得顆粒。在其中央部份有鋁隔板分隔 之容器中，將該顆粒置於其上部空間，並將50克氧化鈣置 於其下部空間，獲得燻蒸劑。 調配例15 於0. 5份氧化鋅、2份α澱粉及97. 5份偶氮二曱醯胺 之混合物内加入水，並揉合混合物及使用擠出機模製顆粒 外形，再乾燥以獲得顆粒。然後，將2克顆粒均勻地浸潰 在0.58克本發明酯化合物Α及0.058克本發明酯化合物Β 於丙酮之溶液中，並乾燥以獲得顆粒。在其中央部份有鋁 隔板分隔之容器中，將該顆粒置於其上部空間，並將50 24 322448 201124080 ' 克氧化鈣置於其下部空間，獲得燻蒸劑。 調配例16 將0. 5克本發明酯化合物A及0. 05克本發明酯化合物 B溶於20毫升（mL)丙酮中，並將所得溶液加入99. 4克用 於防蚊卷之基材（呈4 : 3 : 3之比例的紅楠樟科之粉末、除 蟲菊及木粉之混合物）及0. 3克綠色色素之混合物内。充分 混合後，將120毫升水加入該混合物並充分揉合。模製及 乾燥所得混合物，獲得防蚊卷。 調配例17 經由混合10份本發明酯化合物A、1份本發明酯化合 物B、39. 5份乙醯化檸檬酸三丁酯、39. 5份己二酸異壬酯、 5份藍色色素及5份香料以製得溶液。將用於3.4公分x2. 1 公分且0. 22公分厚的電蚊片之基材（經纏結、壓縮及壓製 成平板狀之棉絨與紙漿的混合細纖維）均勻地浸潰在上述 溶液，獲得電蚊片。 調配例18 經由使0. 1份本發明酯化合物A及0. 01份本發明酯化 合物B溶於99. 89份去臭煤油而製得溶液。將該溶液置於 氣乙烯容器，及將經加工以使其上半部可經由加熱器加熱 之液體吸收芯（經由以黏合劑固化無機粉末接著煅燒而製 得）插進該容器内，獲得一份用於液體吸收芯型蒸發式調配 物。 調配例19 將0. 2份本發明酯化合物A、0. 02份本發明酯化合物 25 322448 201124080 B、及 49. 78 份 Ne〇thiozole(Chuo Kasei CO.，Ltd、m ^ u. J置於 氣溶膠罐中。在附接氣溶膠閥後，裝填25份二甲喊及25 份LPG’接著振盪並進一步附接用於全内容物注入型々々 膠之致動器，獲得氣溶膠調配物。 調配例20 於〇· 2份本發明酯化合物A及〇. 02份本發明酯化人 B内加入"· 78份二乙二醇單乙趟，接著充分混合，雅= 用於防治外寄生蟲之滴注調配物。 得 調配例21 合 將經由使3份本發明醋化合物A及〇3份本Ltd.) and 7 parts of clay, then stirred and mixed with a blender. To the resulting mixture, 85 5 parts of cut clay was added, followed by thorough stirring and mixing to obtain a powder formulation. Formulation Example 5 1 part of the ester compound A of the present invention, 1 part of the ester compound B of the present invention, 35 parts of white carbon containing a half amount of polyoxyethylidene ethyl ether sulfate ammonium salt, 322448 21 201124080 and 54 parts of water The mixture was finely granulated by a wet honing method to obtain a powder formulation. Formulation Example 6 0.05 parts of the ester compound A of the present invention and 0.1 part of the ester compound B of the present invention are dissolved in 10 parts of dioxane, and the resulting solution is combined with 89.85 parts of an isoparaffin solution (IS0PARM, Exxon). (Exxon) registered trademark of the chemical company) mixed to obtain an oily solution. Formulation Example 7 0.1 parts of the ester compound A of the present invention, 0.05 parts of the ester compound B of the present invention, and 49.85 parts of Neothiozole (Chuo Kasei CO., Ltd.) were placed in an aerosol can. After attaching the aerosol valve, 25 parts of dioxane and 25 parts of LPG were charged, followed by shaking and further attaching an actuator to obtain an oily aerosol.份份例例8 0. 5 parts of the present ester compound A, 0.05 parts of the present invention ester compound B, 0.01 part of BHT, 5 parts of diphenylbenzene, 3.44 parts of deodorized kerosene and 1 part of emulsifier (Atomos 300, a registered trademark of Atomos Chemical Co., Ltd.) is filled with 50 parts of distilled water into an aerosol container and attached to the valve member. Then, 40 parts of propellant (LPG) was charged into the air sol container via a valve under pressure to obtain an aqueous aerosol. 5厘米的直径。 A sample of 0.5 cm (cm) thick, 69 cm long and 0. 2 cm wide with a honeycomb structure rolled up from one end to produce a diameter of 5.5 cm and a height of 0. 2 cm cylinder Shape carrier. The appropriate amount is used to deuterize 5 parts of the invention 22 322448 201124080. The mixture of the A and 〇·5 parts of the ester compound B of the present invention dissolved in 94 parts of acetone was uniformly applied to the above-mentioned "wax was evaporated by air drying to obtain a paper-evaporated formulation. Formulation Example 10 A two-dimensional warp knit fabric (trade name: FUSION, product model number. AKE69440, 蠖 furnace 翕.Λ p. ^ dealer, Asahi Kasei Fibers Corporation, thickness: 4·3 cm, fabric density: 321 g/sq. Metric (g/m2), made of polyamine, is cut into a circle of 5 cm diameter. Applying a suitable amount to a solution prepared by dissolving 5 parts of the present invention, a compound A, and 5 parts of the vinegar compound b of the present invention, dissolved in 9 4 5 parts, is uniformly applied to the above-mentioned circular three-dimensional, '10 I and the acetone were volatilized by air drying to obtain a knitted fabric evaporative formulation. , χ Formulation Example 11 97.8 parts of ethylene-methyl methacrylate copolymer (methyl methacrylate containing hydrazine: 1% by weight, MFR = 2 [g / 1 〇 min.]), 2 parts of the ester of the present invention The mixture of Cr and A. 2 parts of the ester compound B of the present invention is 13 Torr. The crucible was melted and kneaded using a 45 twin-screw extruder rotating in the same direction, and further at 15 Torr.熔融 Melt and knead using a 40 min0 extruder, followed by extrusion from a T-shaped mold, and cooling with a cooling wheel to obtain a resin evaporated formulation. Formulation Example 12 97.8 parts of ethylene-vinyl acetate copolymer (vinyl acetate content · 10% by weight, MFR = 2 [g " 〇min.]), 2 parts of the ester compound A of the present invention and 2 parts of the ester of the present invention The mixture of compound B was melted and kneaded in i3〇〇c using a 45 mm 0 twin-screw extruder rotating in the same 23 322448 201124080 direction, and further melted and kneaded at 15 (TC using an extruder, followed by thinning 5份的酮的,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份份含胺胺。 In addition, the ester compound B is dissolved in 14. 6 parts of acetone to prepare a solution. In this solution, the addition of 0.2 parts of oxidation, 1.0 part of alpha starch and 42.8 parts of azodiamine. Adding 38.1 parts of water thereto, and kneading the mixture, molding the granules using an extruder The shape is dried again to obtain granules. In a container having a central partition separated by an aluminum partition, the granule is placed in the upper space, and 50 g of calcium oxide is placed in the lower space thereof to obtain a fumigant. Water is added to a mixture of 0.5 parts of zinc oxide, 2 parts of alpha starch and 97.5 parts of azodiamine, and the mixture is kneaded and the shape of the particles is molded using an extruder, followed by drying to obtain granules. 2 g of the granules were uniformly impregnated in 0.58 g of the ester compound of the present invention and 0.058 g of the ester compound of the present invention in a solution of acetone, and dried to obtain granules, in which the central portion was partitioned by an aluminum separator. 5克本发明的发明。 The invention, the granules are placed in the upper space, and 50 24 322448 201124080 ' gram of calcium oxide is placed in the lower space, the fumigant is obtained. The ester compound B is dissolved in 20 ml (mL) of acetone, and the resulting solution is added to 99.4 g of the substrate for the anti-mosquito roll (a powder of the red nanaceae family, pyrethrum in a ratio of 4:3:3). And a mixture of wood powder and 0.3 g of green pigment. After mixing, 120 ml of water was added to the mixture and thoroughly kneaded. The resulting mixture was molded and dried to obtain an anti-mosquito roll. Formulation Example 17 By mixing 10 parts of the ester compound A of the present invention, 1 part of the ester compound B, 39 of the present invention 5份为2. 1厘米和0. 22。 5 parts of acetylated butyl citrate, 39.5 parts of isodecyl adipate, 5 parts of blue pigment and 5 parts of the fragrance to prepare a solution. Will be used for 3.4 cm x 2. 1 cm and 0. 22 The base of the thick electric mosquito sheet (the mixed fine fiber which is entangled, compressed and pressed into a flat cotton lint and pulp) is evenly impregnated in the above solution to obtain an electric mosquito sheet. Formulation Example 18 A solution was prepared by dissolving 0.1 part of the ester compound A of the present invention and 0.01 part of the ester compound B of the present invention in 99.89 parts of deodorized kerosene. The solution is placed in a gas-ethylene container, and a liquid-absorbent core processed by heating the upper half thereof via a heater (made by curing the inorganic powder with a binder and then calcining) is inserted into the container to obtain a Parts are used in liquid absorbent core type evaporative formulations. Formulation Example 19 0.2 part of the present ester compound A, 0.02 part of the present invention ester compound 25 322448 201124080 B, and 49.78 parts of Ne〇thiozole (Chuo Kasei CO., Ltd, m ^ u. J In an aerosol can. After attaching the aerosol valve, fill 25 parts of dimethyl shim and 25 parts of LPG' and then oscillate and further attach the actuator for the full content injection type silicone to obtain an aerosol formulation. Formulation Example 20 In 2 parts of the ester compound A of the present invention and 〇. 02 parts of the esterified human B of the present invention, " 78 parts of diethylene glycol monoethyl hydrazine, followed by thorough mixing, ya = for control Inoculum formulation of the parasite. Formulation 21 will be passed through 3 parts of the vinegar compound A and 〇3 copies of the present invention.
地塗:溶於96.7份丙酮而製得溶液，並將1毫升C 、到經由在壓力（4t/cm2)下模製4克2,4,6〜三異丙二 ，’三噚烷所得之盤形固體材料（3公 = (咖)厚），接著乾燥獲得_。 直仏及3亳米 調配例22 龜化將G·2克本發㈣化合w、g.q2克本發明 口物B、及4克2, 4, 6〜三異丙 成合物模製為盤形(3公分直徑及3毫乎厚)f烷之均句 調配例23 旦仫及d毫水厚），獲得錠劑。 bJ 〇.2克本發明醋化合物a、〇.〇2克本發明醋化合物 毫升缚心4’ 6~三異丙基〜1，3, 5''三辦之混合物置於 接經加熱溶融然後冷卻至室溫，獲得錠劑。 具有優異防ΚΙ娜㈣示本發明防治組成物對病蟲害 322448 26 201124080 在下列試驗例中，至於本發明酯化合物A，使用（1R)-反式-3〜（2, 2-二氯乙烯基）-2, 2-二曱基環丙烷羧酸 [2, 3, 5, 6-四氟-4-(甲氧基曱基）苯基]甲酯。 另外，至於本發明酯化合物B，使用（1R)-順式/反式 -2, 2-二曱基-3-(2-甲基-1-丙炔基）環丙烧羧酸[2, 5-二侧 氧基-3·~(2-丙炔基）-1-味唾咬基]甲酯。 試驗例1 在下表1所示濃度下，經以給定量異烧烴溶劑（IS0PAR Μ，埃克森化學公司之註冊商標）稀釋本發明酯化合物Β而 製得油性溶液（後文中稱作為比較組成物（1)及（3))。同樣 地’在下表1所示濃度下，經以給定量異烷烴溶劑（IS0PAR Μ ’埃克森化學公司之註冊商標）稀釋本發明酯化合物A而 製得油性溶液（後文中稱作為比較組成物（2 )及（4 ))。 另外，在下表1所示有效成分之濃度下，經以給定量 異烧煙溶劑（ISOPAR M，埃克森化學公司之註冊商標）稀釋 本發明酯化合物A及本發明酯化合物B而製得油性溶液（後 文中稱作為本發明組成物（1)、（2)及（3))。 將10隻家绳i/o/z/esi/ca) (5隻雄性及5隻雌性） 釋放至每邊70公分的立方形箱中，並以喷槍（喷灑壓力： 0.9 kg/cm2)從該箱中央的小窗戶喷進0.7毫升本發明組成 物（1)。在喷灑後給定時間期間，調查擊落的昆蟲數目並計 算擊落率（knock down rate，KD率）。依照相同方法，使 用本發明組成物（2)及（3)及比較組成物（1)至（4)，計算在 給定時間期間後之KD率（2次）。 27 322448 201124080 結果係顯示於表1。 表1 本發明酯化合物A 用量(w/n) 本發明酯化合物B 用量(W/V%) 7分鐘後之KD率 (%) 本發明組成物（1) 0.00156 0.00156 90 比較組成物（1) - 0.00156 10 比較組成物（2) 0.00156 - 20 本發明組成物（2) 0.00156 0.00313 95 本發明組成物（3) 0.00313 0.00156 95 比較組成物（3) - 0.00313 20 比較組成物（4) 0.00313 - 25 如上述，本發明可提供對病蟲害具有優異效果之病蟲 害防治組成物及病蟲害防治方法。 【圖式簡單說明】 無 【主要元件符號說明】 無 28 322448Ground coating: dissolved in 96.7 parts of acetone to prepare a solution, and 1 ml of C was obtained by molding 4 g of 2,4,6-triisopropyl di-,trioxane under pressure (4 t/cm 2 ). A disc-shaped solid material (3 metric = (coffee) thick), followed by drying to obtain _. Straight 仏 and 3 调 调 例 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 22 A tablet (3 cm diameter and 3 mm thick) of the f-alkane was blended in Example 23 and d water was used to obtain a tablet. bJ 〇. 2 g of the vinegar compound a, 〇. 〇 2 g of the vinegar compound of the present invention, the mixture of 4' 6~triisopropyl~1,3, 5'' is prepared by heating and melting. Cool to room temperature to obtain a tablet. The invention has the advantages of (1R)-trans-3~(2,2-dichlorovinyl). In the following test examples, as for the ester compound A of the present invention, (1R)-trans-3~(2,2-dichlorovinyl) is used. -2,2-Dimercaptocyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(methoxyindenyl)phenyl]methyl ester. Further, as for the ester compound B of the present invention, (1R)-cis/trans-2,2-dimercapto-3-(2-methyl-1-propynyl)cyclopropanecarboxylic acid [2, 5-tertiary oxy-3·~(2-propynyl)-1-isosole methyl ester. Test Example 1 An oily solution was prepared by diluting the ester compound of the present invention with a given amount of an isothermal hydrocarbon solvent (IS0PAR®, a registered trademark of Exxon Chemical Co., Ltd.) at a concentration shown in Table 1 below (hereinafter referred to as a comparative composition). Items (1) and (3)). Similarly, an oily solution (hereinafter referred to as a comparative composition) was prepared by diluting the ester compound A of the present invention with a given amount of an isoparaffin solvent (IS0PAR Μ 'registered trademark of Exxon Chemical Co., Ltd.) at the concentration shown in Table 1 below. (2) and (4)). Further, the ester compound A of the present invention and the ester compound B of the present invention were diluted with a given amount of the iso-smouldering solvent (ISOPAR M, registered trademark of Exxon Chemical Co., Ltd.) at a concentration of the active ingredient shown in Table 1 below to prepare an oily property. The solution (hereinafter referred to as the compositions (1), (2) and (3) of the present invention). Release 10 home ropes i/o/z/esi/ca) (5 males and 5 females) to a 70 cm square box on each side and use a spray gun (spray pressure: 0.9 kg/cm2) 0.7 ml of the composition of the invention (1) was sprayed from a small window in the center of the box. During the given time after spraying, the number of insects shot down was investigated and the knockdown rate (KD rate) was calculated. According to the same method, the compositions (2) and (3) of the present invention and the comparative compositions (1) to (4) were used, and the KD rate (2 times) after a given period of time was calculated. 27 322448 201124080 The results are shown in Table 1. Table 1 The amount of the ester compound A of the present invention (w/n) The amount of the ester compound B of the present invention (W/V%) The KD rate after 7 minutes (%) The composition of the present invention (1) 0.00156 0.00156 90 Comparative composition (1) - 0.00156 10 Comparative composition (2) 0.00156 - 20 Composition of the invention (2) 0.00156 0.00313 95 Composition of the invention (3) 0.00313 0.00156 95 Comparative composition (3) - 0.00313 20 Comparative composition (4) 0.00313 - 25 As described above, the present invention can provide a pest control composition and a pest control method which have excellent effects on pests and diseases. [Simple diagram description] None [Main component symbol description] None 28 322448
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| CN (1) | CN102047899A (en) |
| AR (1) | AR079020A1 (en) |
| AU (1) | AU2010236007A1 (en) |
| BR (1) | BRPI1010466A2 (en) |
| MX (1) | MX2010011914A (en) |
| RU (1) | RU2010144525A (en) |
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| JPS609715B2 (en) * | 1977-06-20 | 1985-03-12 | 住友化学工業株式会社 | Carboxylic acid esters, their production methods, and insecticides and acaricides containing them as active ingredients |
| EP0054360B1 (en) * | 1980-12-17 | 1985-06-05 | Imperial Chemical Industries Plc | Fluorobenzyl cyclopropane carboxylates, their preparation, compositions comprising them and their use as insecticides |
| JP4994702B2 (en) * | 2005-04-21 | 2012-08-08 | 住友化学株式会社 | Pest control agent |
| JP3909717B1 (en) * | 2006-07-04 | 2007-04-25 | 大日本除蟲菊株式会社 | Flies and mosquito coils |
| CN100534303C (en) * | 2007-05-16 | 2009-09-02 | 江苏同大有限公司 | Insect aerosol of aircraft, and preparation method |
| JP2009019015A (en) * | 2007-07-12 | 2009-01-29 | Sumitomo Chemical Co Ltd | Molded article for insect pest control |
| JP5407224B2 (en) * | 2007-09-05 | 2014-02-05 | 住友化学株式会社 | Pest control composition and pest control method |
| JP2009235040A (en) * | 2008-03-28 | 2009-10-15 | Sumitomo Chemical Co Ltd | Method for controlling fly |
| CN100545144C (en) * | 2008-04-29 | 2009-09-30 | 江苏扬农化工股份有限公司 | A kind of optically active pyrethroid coumpound and its production and application |
| CN101524084B (en) * | 2009-04-30 | 2012-11-07 | 江苏扬农化工股份有限公司 | Muscicide incense and preparation method and application thereof |
| JP2011116737A (en) * | 2009-10-30 | 2011-06-16 | Sumitomo Chemical Co Ltd | Harmful organism-controlling composition and method for controlling harmful organism |
| JP5589712B2 (en) * | 2009-10-30 | 2014-09-17 | 住友化学株式会社 | Pest control composition and pest control method |
| JP5598204B2 (en) * | 2009-10-30 | 2014-10-01 | 住友化学株式会社 | Pest control composition and pest control method |
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| TR201008917A2 (en) | 2011-05-23 |
| RU2010144525A (en) | 2012-05-10 |
| CN102047899A (en) | 2011-05-11 |
| JP2011116741A (en) | 2011-06-16 |
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| ZA201007757B (en) | 2011-08-31 |
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