TW201025425A - Methods to promote adhesion between barrier layer and porous low-k film deposited from multiple liquid precursors - Google Patents
Methods to promote adhesion between barrier layer and porous low-k film deposited from multiple liquid precursors Download PDFInfo
- Publication number
- TW201025425A TW201025425A TW098123972A TW98123972A TW201025425A TW 201025425 A TW201025425 A TW 201025425A TW 098123972 A TW098123972 A TW 098123972A TW 98123972 A TW98123972 A TW 98123972A TW 201025425 A TW201025425 A TW 201025425A
- Authority
- TW
- Taiwan
- Prior art keywords
- gas mixture
- flow rate
- film
- carbon
- chamber
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/56—After-treatment
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
- H10P14/63—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the formation processes
- H10P14/6326—Deposition processes
- H10P14/6328—Deposition from the gas or vapour phase
- H10P14/6334—Deposition from the gas or vapour phase using decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
- H10P14/6336—Deposition from the gas or vapour phase using decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition in the presence of a plasma [PECVD]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
- H10P14/66—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials
- H10P14/665—Porous materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
- H10P14/66—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials
- H10P14/668—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
- H10P14/66—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials
- H10P14/668—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials
- H10P14/6681—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials the precursor containing a compound comprising Si
- H10P14/6682—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials the precursor containing a compound comprising Si the compound being a silane, e.g. disilane, methylsilane or chlorosilane
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
- H10P14/66—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials
- H10P14/668—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials
- H10P14/6681—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials the precursor containing a compound comprising Si
- H10P14/6684—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials the precursor containing a compound comprising Si the compound comprising silicon and oxygen
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
- H10P14/66—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials
- H10P14/668—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials
- H10P14/6681—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials the precursor containing a compound comprising Si
- H10P14/6684—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials the precursor containing a compound comprising Si the compound comprising silicon and oxygen
- H10P14/6686—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials the precursor containing a compound comprising Si the compound comprising silicon and oxygen the compound being a molecule comprising at least one silicon-oxygen bond and the compound having hydrogen or an organic group attached to the silicon or oxygen, e.g. a siloxane
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
- H10P14/69—Inorganic materials
- H10P14/692—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses
- H10P14/6921—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses containing silicon
- H10P14/6922—Inorganic materials composed of oxides, glassy oxides or oxide-based glasses containing silicon the material containing Si, O and at least one of H, N, C, F or other non-metal elements, e.g. SiOC, SiOC:H or SiONC
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Vapour Deposition (AREA)
- Formation Of Insulating Films (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/173,659 US20100015816A1 (en) | 2008-07-15 | 2008-07-15 | Methods to promote adhesion between barrier layer and porous low-k film deposited from multiple liquid precursors |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201025425A true TW201025425A (en) | 2010-07-01 |
Family
ID=41530671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW098123972A TW201025425A (en) | 2008-07-15 | 2009-07-15 | Methods to promote adhesion between barrier layer and porous low-k film deposited from multiple liquid precursors |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20100015816A1 (https=) |
| JP (1) | JP2011528508A (https=) |
| KR (1) | KR20110039556A (https=) |
| CN (1) | CN102099897A (https=) |
| TW (1) | TW201025425A (https=) |
| WO (1) | WO2010008930A2 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110241200A1 (en) * | 2010-04-05 | 2011-10-06 | International Business Machines Corporation | Ultra low dielectric constant material with enhanced mechanical properties |
| WO2014143337A1 (en) * | 2013-03-14 | 2014-09-18 | Applied Materials, Inc. | Adhesion layer to minimize dilelectric constant increase with good adhesion strength in a pecvd process |
| CN104103572B (zh) * | 2013-04-02 | 2017-02-08 | 中芯国际集成电路制造(上海)有限公司 | 多孔低k介质层的形成方法及多孔低k介质层 |
| US10510852B2 (en) * | 2017-11-28 | 2019-12-17 | Taiwan Semiconductor Manufacturing Company, Ltd. | Low-k feature formation processes and structures formed thereby |
| CN113166937A (zh) * | 2018-11-27 | 2021-07-23 | 弗萨姆材料美国有限责任公司 | 1-甲基-1-异丙氧基-硅杂环烷烃和由其制备的致密有机硅膜 |
| US11430654B2 (en) * | 2019-11-27 | 2022-08-30 | Applied Materials, Inc. | Initiation modulation for plasma deposition |
| KR102913505B1 (ko) * | 2023-06-08 | 2026-01-16 | 에스케이트리켐 주식회사 | 저 유전율 실리콘 함유 박막 형성용 전구체 및 이를 이용한 저 유전율 실리콘 함유 박막 형성 방법. |
| KR20250016873A (ko) * | 2023-07-26 | 2025-02-04 | 에스케이트리켐 주식회사 | 저 유전율 박막 형성용 전구체 및 상기 전구체를 이용한 저 유전율 실리콘 함유 박막 형성 방법 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH043926A (ja) * | 1990-04-20 | 1992-01-08 | Sony Corp | 半導体装置の製造方法 |
| US6340435B1 (en) * | 1998-02-11 | 2002-01-22 | Applied Materials, Inc. | Integrated low K dielectrics and etch stops |
| JP2001035845A (ja) * | 1999-07-21 | 2001-02-09 | Nec Corp | 半導体装置の製造方法及びそれに使用されるプラズマ絶縁膜の成膜装置 |
| US6258735B1 (en) * | 2000-10-05 | 2001-07-10 | Applied Materials, Inc. | Method for using bypass lines to stabilize gas flow and maintain plasma inside a deposition chamber |
| SG98468A1 (en) * | 2001-01-17 | 2003-09-19 | Air Prod & Chem | Organosilicon precursors for interlayer dielectric films with low dielectric constants |
| US6518646B1 (en) * | 2001-03-29 | 2003-02-11 | Advanced Micro Devices, Inc. | Semiconductor device with variable composition low-k inter-layer dielectric and method of making |
| US6570256B2 (en) * | 2001-07-20 | 2003-05-27 | International Business Machines Corporation | Carbon-graded layer for improved adhesion of low-k dielectrics to silicon substrates |
| US6933586B2 (en) * | 2001-12-13 | 2005-08-23 | International Business Machines Corporation | Porous low-k dielectric interconnects with improved adhesion produced by partial burnout of surface porogens |
| US7056560B2 (en) * | 2002-05-08 | 2006-06-06 | Applies Materials Inc. | Ultra low dielectric materials based on hybrid system of linear silicon precursor and organic porogen by plasma-enhanced chemical vapor deposition (PECVD) |
| US7098149B2 (en) * | 2003-03-04 | 2006-08-29 | Air Products And Chemicals, Inc. | Mechanical enhancement of dense and porous organosilicate materials by UV exposure |
| US6913992B2 (en) * | 2003-03-07 | 2005-07-05 | Applied Materials, Inc. | Method of modifying interlayer adhesion |
| US8137764B2 (en) * | 2003-05-29 | 2012-03-20 | Air Products And Chemicals, Inc. | Mechanical enhancer additives for low dielectric films |
| WO2005053009A1 (ja) * | 2003-11-28 | 2005-06-09 | Nec Corporation | 多孔質絶縁膜及びその製造方法並びに多孔質絶縁膜を用いた半導体装置 |
| US7030041B2 (en) * | 2004-03-15 | 2006-04-18 | Applied Materials Inc. | Adhesion improvement for low k dielectrics |
| US7547643B2 (en) * | 2004-03-31 | 2009-06-16 | Applied Materials, Inc. | Techniques promoting adhesion of porous low K film to underlying barrier layer |
| US7102232B2 (en) * | 2004-04-19 | 2006-09-05 | International Business Machines Corporation | Structure to improve adhesion between top CVD low-k dielectric and dielectric capping layer |
| US7166544B2 (en) * | 2004-09-01 | 2007-01-23 | Applied Materials, Inc. | Method to deposit functionally graded dielectric films via chemical vapor deposition using viscous precursors |
| KR20070083745A (ko) * | 2004-09-22 | 2007-08-24 | 벤자민 데이비드 해튼 | 유기실리카 물질 내의 가교 유기 기의 변환방법 |
| US7501354B2 (en) * | 2005-01-18 | 2009-03-10 | Applied Materials, Inc. | Formation of low K material utilizing process having readily cleaned by-products |
| US20060156980A1 (en) * | 2005-01-19 | 2006-07-20 | Samsung Electronics Co., Ltd. | Apparatus including 4-way valve for fabricating semiconductor device, method of controlling valve, and method of fabricating semiconductor device using the apparatus |
| US7259111B2 (en) * | 2005-01-19 | 2007-08-21 | Applied Materials, Inc. | Interface engineering to improve adhesion between low k stacks |
| JP5324734B2 (ja) * | 2005-01-21 | 2013-10-23 | インターナショナル・ビジネス・マシーンズ・コーポレーション | 誘電体材料とその製造方法 |
| US7265437B2 (en) * | 2005-03-08 | 2007-09-04 | International Business Machines Corporation | Low k dielectric CVD film formation process with in-situ imbedded nanolayers to improve mechanical properties |
| US7189658B2 (en) * | 2005-05-04 | 2007-03-13 | Applied Materials, Inc. | Strengthening the interface between dielectric layers and barrier layers with an oxide layer of varying composition profile |
| JP2006339506A (ja) * | 2005-06-03 | 2006-12-14 | Semiconductor Process Laboratory Co Ltd | 成膜方法及び半導体装置の製造方法 |
| US7390757B2 (en) * | 2005-11-15 | 2008-06-24 | Applied Materials, Inc. | Methods for improving low k FSG film gap-fill characteristics |
| US7381659B2 (en) * | 2005-11-22 | 2008-06-03 | International Business Machines Corporation | Method for reducing film stress for SiCOH low-k dielectric materials |
| JP5093479B2 (ja) * | 2005-11-24 | 2012-12-12 | 日本電気株式会社 | 多孔質絶縁膜の形成方法 |
| JP2007258403A (ja) * | 2006-03-23 | 2007-10-04 | United Microelectronics Corp | 多孔性低誘電率薄膜及びその製作方法 |
| US7297376B1 (en) * | 2006-07-07 | 2007-11-20 | Applied Materials, Inc. | Method to reduce gas-phase reactions in a PECVD process with silicon and organic precursors to deposit defect-free initial layers |
| US7598183B2 (en) * | 2006-09-20 | 2009-10-06 | Applied Materials, Inc. | Bi-layer capping of low-K dielectric films |
| US7799377B2 (en) * | 2006-12-07 | 2010-09-21 | Electronics And Telecommunications Research Institute | Organic/inorganic thin film deposition method |
| US7615482B2 (en) * | 2007-03-23 | 2009-11-10 | International Business Machines Corporation | Structure and method for porous SiCOH dielectric layers and adhesion promoting or etch stop layers having increased interfacial and mechanical strength |
-
2008
- 2008-07-15 US US12/173,659 patent/US20100015816A1/en not_active Abandoned
-
2009
- 2009-06-30 WO PCT/US2009/049216 patent/WO2010008930A2/en not_active Ceased
- 2009-06-30 CN CN2009801283109A patent/CN102099897A/zh active Pending
- 2009-06-30 JP JP2011518779A patent/JP2011528508A/ja active Pending
- 2009-06-30 KR KR1020117003518A patent/KR20110039556A/ko not_active Ceased
- 2009-07-15 TW TW098123972A patent/TW201025425A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011528508A (ja) | 2011-11-17 |
| US20100015816A1 (en) | 2010-01-21 |
| WO2010008930A2 (en) | 2010-01-21 |
| CN102099897A (zh) | 2011-06-15 |
| WO2010008930A3 (en) | 2010-04-08 |
| KR20110039556A (ko) | 2011-04-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5312588B2 (ja) | プラズマ促進化学蒸着で高い機械的諸特性を有する超低k膜を作製するための新規なケイ素前駆体 | |
| CN101109074B (zh) | 在硅和有机前驱物的pecvd工艺中减少气相反应以沉积无缺陷起始层方法 | |
| KR101141459B1 (ko) | 하부 배리어 층에 저 유전체 상수 (k) 다공성 막의 부착을촉진하는 기술 | |
| CN101743247B (zh) | 利用等离子体增强化学气相沉积来制造高机械性能的极低k膜的硅前驱物 | |
| KR20130124511A (ko) | 얇은 초 저-k 유전체 막에 대한 접착 층 두께를 저감시키고 손상 내성을 개선하기 위한 프로세스 | |
| TW201025425A (en) | Methods to promote adhesion between barrier layer and porous low-k film deposited from multiple liquid precursors | |
| TW201142945A (en) | Ultra low dielectric materials using hybrid precursors containing silicon with organic functional groups by plasma-enhanced chemical vapor deposition | |
| CN103238206A (zh) | 原位低介电常数加盖以改良整合损坏抗性 | |
| TW201131652A (en) | Flowable dielectric using oxide liner | |
| KR101376969B1 (ko) | 저―κ의 유전 필름의 이중층 캡핑 | |
| TW200845202A (en) | Method of improving initiation layer for low-k dielectric film by digital liquid flow meter |