TW200526B - - Google Patents

Abstract

Disclosed is an improved detergent composition comprising one or more anionic surfactants, nonionic surfactants, or mixtures thereof, and detersive enzymes, the improvement which comprises incorporating into said composition an enzyme performance-enhancing amount of a polyhydroxy fatty acid amide material of formula (I), wherein R<1> is H1, C1-C4 hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl, or a mixture thereof, R2 is C5-C31 hydrocarbyl, and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least three hydroxyls directly connected to said chain, or an alkoxylated derivative thereof.

Description

A 6 B 6 V. Description of the invention (!) The present invention is pseudo-declared. The present invention is printed on the cleansing dysentery composition. It is printed by the employee consumer cooperative of the Ministry of Economics, the Central Standards Bureau. In particular, the old product composition of other primes is a blue heart compound, and the addition of Qing is often used to demonstrate the performance of suspicion, and it is necessary to consider the commercial properties of Yi Di, but the chemical formula and formula. The enzyme is used in the long-term cleansing group, it will be obvious, especially, and the formate cleansing group is used in the enzyme matching, which can be more synergistic. It will strengthen the long-term fermentation user's invention section. The cleansing agent group contains enzymes and polyhydroxy lipid 0. It works in both liquids and tablets to enhance the cleansing performance. Protein water Other enzymes, such as starch, and their combinations have also been suggested for use in the laundry of the suspect. More importantly, the acid beats in the form of a surfactant. It is added to the solution _ added solution _ for the conventional use for this purpose, iron thread _, fat plum. This use is used f. The first use of yeast in the composition of the literature Read the precautions of the flank surface, then 塡 • Woben w The biological substance is completely mixed and connected to the “post-composition, the notice is essentially that the liquid has been designed, and the acetamide complex contains enzymes that are relatively high and the final Not expensive, theoretically its performance. The activity of the element is better, so it is clean. Because it is often higher than the cleaning agent, a variety of thin, and / or liquids provided are more expensive, and the user additives are not only available. However, the good performance of the market will be affected by the combination. Or all kinds of enzymes can be added and improved, so that the enzyme no matter what the situation is, the cleansing-3-denaturation effect, and it is matched with the seed brewing or stored in the store, containing the stability of the yeast. Thin I. For example, the qualitative characterization of short-yung-yong fatty acids. In such a composition. The combination of thin, clean and costly. Because it is beneficial for stabilization, the net purpose is to stabilize or strengthen the composition. The presence of inactivation contains quite a variety of boron it: on the fermentation rack compared to the cleaning agent HI. It is often stabilized. In the case, if the fermentation is resistant to degradation, it must be the same. The bound book Paper scales are used in China National Sample Standard (CNS) Grade 4 (210 &gt; &lt; 297 gong) ____136_ Λ 6 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (2) Stabilize or enhance the performance of enzymes in the fully-dispensed Zhijie thin composition, all of which are suspected that all enzymes are very expensive, and almost all enzymes will lose at least part of their activity when stored in germanium. Copies. Although not wishing to be bound by theory, it seems that the type of polyhydroxy fatty acid ketamine interfacial activity disclosed later will provide enzymes with a stabilizing and / or performance-enhancing function. It is very likely that when the enzyme attacks the dirt and stains, the polyhydroxy fatty acid acylate has the function of removing the "H-cut" of the generated molecule, thus allowing the thin element to function more effectively. Regardless of the mechanism of its function, the present invention is transformed into a transporter to enhance the ultimate goal of removing enzyme instability, dirt and stains, thus improving the overall performance of the enzyme-contained enzyme-containing composition. In addition to improving enzyme performance, the polyhydroxy fatty acid amide is itself a superior cleansing interface active agent. Furthermore, this type of surfactant can be obtained mostly or completely from natural, renewable raw materials. Partially replaces oil strip surfactants without losing cleaning power. Dorsal twig S A variety of polyhydroxy fatty acid sleep amines. Has been described in this technology. For example, NS group, Η-methyl sulfopyramide, replaced by JW Goodby, Μ.Α. Marcus, E. Chin, and PL Finn, 掲 shown in &quot; the hot direction of some direct bond sulfonic acid compounds double affinity_ Liquid crystal properties &quot; Liquid Crystal. 1988, Volume 3, Issue 11, pages 1569-1581, and by A. Muller-Fahrnow, V. Zabel, M. Steifa, and R. Hilgenfeld, shown in &quot; Non-ionic cleaning thread: Nonyl-N-methyl glucosamine molecule and crystal structure-4-(Please read 1Ϊ first. Note on the back and then this page) This paper is used in scale B Η 楳 楳 准 (CNS) A 4 specifications (210X297) << ΰ cii ύ ο ο 66 ΛΒ Printed by the Beigongxiaot Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (3) ", J. Che ·. Soc Chen. Conaun. · 1986, p. 1573- 1574. N-alkyl polyhydroxyamide interface activity ^ Recently, FFI has been interested in biochemistry, such as the dissociation of biofilms. See , For example, the journal article "ND-« Grapeyl-H-Methyl-Pyridinamide Compound, a New Type of Non-androgenic Cleaning for Thin Film Biochemistry_ ", Bi〇-chen. J. ( 1982), vol. 207, pages 363-366, published by J. EK Hi ldreth. The use of N-alkyl "glucamine" in the detergent group has also been discussed. December 20, 1960 U.S. Patent 2,965,576 issued to ER Wilson, and the announcement dated February 18, 1959. It is suspected to belong to Thomas Hedley ’s British Patent 809,060. You can clean the interface activity of anionic surfactants and certain enzymes. _Composition, which may contain H-methylglucose, added as a low suds foam enhancer. These compounds include an N-acyl group of 10 to 14 sulfonic atoms in a high-density straight fat. These compositions may also contain auxiliary rib substances, such as age metal phosphate, age gold silicate, sulfate and sulfonate. It is also generally pointed out that other ingredients can also be added to this composition Ingredients that impart desired properties to the composition, such as fluorescent dyes, bleaches, perfumes, etc. US Patent 2,703,789 issued to AM Schwartz on March 8, 1955. Pseudo-containing contains N-alkyl glucosamine and a fatty acid Knitting reaction product It is said that the product of this reaction can be used in water-based cleaning composition without further purification. It is also known to prepare an acid ester of acetylated amine, as shown in US Patent 2,717,894 issued to A. M. Schwartz on September 13, 1955. (Please read the precautions on the back before filling in this page) This paper is used in the "National Sample (CNS) A4 Specification (210X297" ":) Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Λ 6 _ B6_ V. Description of the invention (4) PCT International Application W0 83/04412, published by J. Hildreth on December 22, 1983, Gulan is a double-affinity compound containing a polyhydroxylized aliphatic base, according to It can be used for a variety of purposes, including use as an interfacial active agent in cosmetics, lotions, lotions, lotions and eye ointments, as emulsifying and dispersing agents on beta lotions, and to dissolve films biochemically , Integer cells, or other groups of suspected samples, and used to prepare lipid. Included in this description are compounds of the formula R'CON (R) CHeR "and R" CON (R) R ', where R is hydrogen or an organic group, and R' is a lipid with at least three tilted atoms Group hydrocarbon group, and r is a residue of aldose. Announced on October 12, 1988, European Patent 0 285 768, issued to H. Kelkenberg, et al., Using N-polyhydroxyalkyl fatty acid aldehyde amines as an increase in water-based detergents . Included are amides of the formula RiUcnm X) R2, where RiSCt-C ^ i is preferably C7-C17) alkyl, Ra is argon, Ci-Cie (preferably ^-) alkyl, or a gas Alkylene, and X is a polyhydroxyalkyl group with 4 to t atoms, such as N-methyl, tallow-based fatty acid grape vinegar amine, the thickening properties of this amine, can be used for other Shi Li "Liquid Interfacial Activity of Sulfonates" system, but this aqueous interfacial active W series can contain other anionic interfacial adaptability agents, such as alkaryl sulfonic acid, olefin phosphate, sulfosuccinic acid Hemiesters and lipase ether sulfonates, and non-sickle interfacial active AI, such as lipase polydizyme ethers, alkyl polydizyme ethers, fatty acid polydizyme esters, polyoxypropylene-polyepoxy Polymerization of ethane mixed «etc. An example is the formulation of panate / N-methyl coconut fatty acid glucosamine / non-ionic surface-active thin shampoo. In addition to the thickening properties, it is said that this N-polyhydroxyalkane-6 (please read the precautions on the first side and then release this page) This paper is not used in the standard 掑 家家 准 (CNS) f 4 specifications (210X297 g *) hi 〇〇ύ as Λ 6 13 6 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of invention (5) The base fatty acid compound amine, which has the permissible specialty of surpassing the skin. May 2, 1961, issued to Boettner et al. Meituan Patent 2,982.737, Pseudo-two-to-clean block, which contains urea, sodium maleate sodium lauryl sulfate interface activity and a non-ionic interface activity of H-alkyl glucose amine In the plan, its 傜 S is derived from H-methyl, M-rowanyl lauryl 8 amine and H-methyl, H-rowanyl myristamide. Other glucosamine surfactants are shown in, for example, the DT Patent 2,226,872 issued to HW Eckert et al. On December 20, 1973, and its conglomerate is in a detergent composition, which contains one or more surfactants and ribs. The lotion salts are selected from the group consisting of polymeric phosphates, polyvalent mixtures, and salt detergents, which are improved by adding an N-acyl polyhydroxyalkylamine having the formula fUncnfUReKHdCHOHUCHaOH, where RigCi-Ca alkyl.1? 2 is (: 10-(: 188 alkyl, and η is 3 or 4. Add this N-acyl polyhydroxyalkylamine as a kind of soil suspension agent. It was awarded to HW Eckert on April 4, 1972 Renmei Meituan Patent 3,654, 166, is a detergent composition, which contains at least one surfactant, which is derived from anionic, zwitterionic, and nonionic interfacial activity_, and as a textile and male softener_formula 111 ^ (2 &gt; (:( 0) 112 of acryl, &gt; (-alkyl polyhydroxyalkyl compounds, of which 1 to 1 are (: 10- (: 22 alkyl, Ra is C7-C21 alkyl, 1U IU are all 23 to 39 塪 塪 atoms, and Z is a polyhydroxyalkyl, which can be -CH2 (CH0H) »-CHa0H. Where" is 3 or 4. 1977 3 Awarded to H. Μόΐ ler et al., U.S. Patent 4,021,539 on March 3, like a cosmetic composition for treatment of two skins, which contains N-polyhydroxyalkylamine, which contains a compound of the formula RiNmCfHCHOfn-Re, where ^ is !!, Low -7-(Please read the precautions on the back, and then write this page) This paper is used in the country B "China (CNS) A 4 specifications (210x297 g **) Λ 6 13 6 Economy Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Education 5. Description of invention (6) Sulfonyl, sulfonyl-lower sulfonyl or aminoalkyl, and heteroaminylaminoalkyl, 1 {Same as 111, but two None of them are H, and Ra insults CHeOH or COOHo. On April 26, 1963, he was found to be the patent of 1,360,018 in a commercial analytic company. It resembles the formaldehyde solution in the anti-polymerization process, And add the formula RC (0) N (RJG enzyme amine, where R is a carboxylic acid functional group having at least t sulfonic atoms, ^ is hydrogen or low alkyl group, and G is a dehydrated water having at least 5 塤 atoms Glyceryl group. German patent 1,261,861 issued to A. Heins on February 29, 1986, pseudo-glucose derivatives, which can be used as wetting and dispersing agents, which have the formula NUMI UXIU). Where R is a glycosaminoglycan residue, 1 is (: 10-Cao halide, and R2 is Ci-Cs alkynyl. Announced on February 15, 1956, suspected to belong to the British group of Atlas Powder Company Patent 745,036, about heterocyclic sleep amines and their carboxylic acid esters, is said to be used as chemical intermediates, emulsifiers, moisturizers and dispersants, detergents, textile softeners, etc. These compounds are pseudo-represented by the formula NUXRjJCiinRi !, where R is the residue of an anhydrous hexanepentanol or its carboxylate, Ri is a monovalent radical, and -C (0) Re is a atom with 2 to 25 atoms The acyl group of the carboxylic acid. U.S. Patent No. 3,312,627, issued to DT Hooker on April 4, 1967, shows solid soap, which is substantially free of anionic detergents and sickle ribal wash substances, but it contains lithium soap of certain fatty acids, a non- Ionic surfactants, helmets from certain oxypropylene-ethylenediamine-Chenqi ethane condensates, chenqi propane-propanediene-ring gas ethane condensates, and polymerized ethane fermentation. And also Contains a non-ionic foaming ingredient, which may include polyhydroxylamide of formula RCiinNR1 ^ 2), where RC (0) contains about 10 to about 14® atoms, and R1 (please read the precautions on the back before filling This page) Binding. Ordered-This paper ruler / t is printed in China National Standard (CNS) Grade 4 (210X297 male dragon) 1005S6 Λ 6 136 Printed by the Ministry of Economic Affairs Central Bureau of Industry and Commerce Beigong Consumer Cooperatives (7) and 1 {2 are each H or Ci-Ce alkyl groups, the alkyl group having a gold moiety having a sulfo atom number of 2 to about 7, and a gold moiety substituted hydroxy group having a number of 2 to about 6. A kind of similar display content was found in US Patent 3,312,626 and was also granted to D. T. Hooker on April 4, 1967. Invention Shushu The present invention provides an improved cleaning cocoon composition, which contains one or more anionic interface activity, non-ionic interface activity, or a mixture thereof, and cleaning enzymes, where improvements are included in the combination It is blended with an enzyme performance enhancement amount of the following polyhydroxy fatty acid enzyme amines 0 Ri if IR *-C-N-Z where R1 is IU, Ci-C * hydrocarbyl, 2-hydroxyethyl, 2-hydroxy Propyl, or a mixture thereof, Ra is Ce-C31 «group, and Z is a polyhydroxy hydrocarbon group having a linear hydrocarbon chain (where at least 3 hydroxyl groups are pseudo-connected directly to the chain), or an alkylated derivative thereof . The present invention further provides a method for improving the cleaning performance of a detergent composition, the detergent composition contains a clean interface activity such as anionic, nonionic or cationic interface active surface, especially an anionic surfactant, In the presence of an aqueous medium, an enzyme-enhanced amount of the above-mentioned polyhydroxy fatty acid amide is added to the Lujielan composition. The present invention further provides a method for treating a substrate (such as following dimensions, suspects, hard surfaces, leather, etc.) by contacting the substrate with a cleansing composition, the cleansing composition includes One or more anionic, nonionic, or cationic surfactants and a cleansing enzyme, among which -9-(please read the precautions on page f before writing this page) This paper »China National Standards (CNS) A4 specifications (210X297 g *) ^ 005 Λ 6 13 6 Printed by the Employees ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of the invention (8) The composition contains an enzyme-enhancing amount of polyhydroxy fatty acid amide Surfactant. ， 发 昍 洚 沭 Name @ 葚 脂 昉 蘼 逋 銀 界 性 性 The detergent composition here contains "enzymatic performance enhancing amount" of polyhydroxy fatty acid succinylamine. Those who admire the "enzyme enhancing effect" composition of the pseudo-intentional composition can choose a certain amount of polyhydroxylipid aldehyde to be incorporated into this composition, which will improve the enzyme cleaning of the cleaning and bleaching composition performance. For Yijiao, for the cleansing containing conventional fermented yeast, adding about 1% by weight of polyhydroxy fatty acid ammonium will enhance the performance of the enzyme. The cleansing composition here will typically contain at least about 1% (by weight basis) polyhydroxy fatty acid-based surfactant, preferably at least about 3%, and more preferably S contains about 3% to about 50%, most preferably about 3% to about 30% According to the invention, the multi-based fat-based lipids are engraved according to the interface active composition, including the chemical formula of the structural formula as follows: 0 Ri (I) Rz-C-N-Z Where: R1 is H, Ci -CU hydrocarbyl, 2-hydroxyethyl, 2-hydroxypropyl, or a mixture thereof. Preferably C; l-C4 alkyl, more preferably (^ or (: 2 alkyl, most preferably {^ 菸 基(Meaning methyl); and R2 is a C5-C3i hydrocarbon group, preferably a straight-chain C7-C19 alkyl or alkenyl group, more preferably a straight-bonded C9-C17 alkyl group or an aryl group, most preferably a straight-bonded Cu- Cts alkyl group or alkenyl group, or a mixture thereof; and Z is a linear hydrocarbon group bond (at least 3 hydroxy groups are directly connected to the polyhydroxy hydrocarbon hydrazine, -10-(please read the precautions on the back before filling this page )

This paper ruler A Xiao is printed in China National Standards (CNS) A4 specifications (210x297 mm). Λ 6 Β6 Printed by the Ministry of Economic Affairs, Central Bureau of Economics and Technology Co-operative Society of Fifth, Invention Instructions (9) or its alkoxylation Derivatives (preferably ethylated or propoxylated). Z is preferably derived from a raw sugar in a pyrogenic amination reaction; z is more preferably a glycidyl group. The original selenium selenium includes sucrose, fructose, maltose, milk squid, galacto, mannose, and xylose. Can be used from dextrose corn prawns, corn fruit sugar paddles, and high malt corn syrup Pulp, as well as the sugars listed above, are used as raw materials. These corn syrups can produce a mixture of sugar ingredients for z. It is clear that it is by no means intended to remove other suitable raw materials. Z is preferably selected Self-included -CH8- (CH0HU-CH20H, -CH (CH20H)-(CHOH) ni-CHgOH, -CHa-(CHOH) 2 (CHOR *) (CHOH) -CHe0H, where n is 3 to 5 (inclusive) Integer, and R 'is H or a cyclic or aliphatic mono-emulsion, and its alkylated derivatives. The best is a water-binding glycosyl group, where η is 4, the other is -CHe- (CHOH) 4-CH2〇He Yu type In I), R 'may be, for example, N-methyl, H-ethyl, N-propyl, N-isopropyl, N-butyl, N-2-hydroxyethyl, or N-2-hydroxypropyl R2-C0-N <may be, for example, cocoamide, stearylamine, oleamide, laurylamine, myristylamide, decamide, palmetamide, tallowamide, etc. Z may Prepare water for 1-deoxygenated «Grape base, 2-deoxygenated fruit base, Bu degassed maltose base, Bu degassed lactose base, 1-Degassed galactose base, 1-Degassed shrink Mannose group, 1-degassed water maltotriosyl group, etc. The preparation method of polyhydroxy fatty acid amide is known in this technology. Generally speaking, the preparation method can be carried out in a kind of amidation reaction In the reaction of an alkylamine and a lotus root to form a corresponding N-alkyl polyhydroxyamine, and then the N-alkyl polyhydroxyamine and a fatty aliphatic ester or triglyceride. In the condensation / aldehyde N-alkyl and polyhydroxy-11 are formed by the reaction in the amination reaction step-(please read the legal matters on the back before filling out this page) (210x297mm *) 200 fine Λ 6 Β6 warp Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of V. Invention description (10) Fatty acid sleeping limb products. For the composition containing polyhydroxy fatty acid fatty limb, the cracking method is shown in the announcement on February 18, 1959, ρ to Tho »As Hedley ’s British Patent Application Case 809,060, US Patent 2,965,576 issued to ER Wilson on December 20, 1960, and US Painting Patent 2,703,798 issued to Anthony M. Schwartz on March 8, 1955, and December 1934 The Meituan patent of 1,985,424 was issued to Piggott on May 25, and all patents are incorporated herein for reference. In a method for manufacturing N-alkyl or N-hydroxyalkyl, N-degassed glycosaminoglycan fatty acid amides, wherein the hydrolyzyl-based constituents are derived from vinegar, N-alkyl or N-hydroxy The alkyl functional group is assumed to be N-methyl, N-ethyl, N-propyl, N-butyl, N-hydroxyethyl, or hydroxypropyl. This product is manufactured by using H-alkyl- or N- Hydroxyalkyl-glucosamine reacts with a grain of fatty esters. The fatty acids are prepared from fatty methyl esters, fatty ethyl esters, and fatty triglycerides in the presence of a kind of mortar medium. Trilithium carbamate, trisodium phosphate, tripotassium androsate, tetrasodium pyrophosphate, pentapotassium tripolyphosphate, hydrogenation_, sodium hydride, hydrogen hydroxide, hydrogen peroxide, lithium nitrate, sulfonic acid m, sulfonic acid Potassium acid, dipotassium tartrate, sodium potassium tartrate, trisodium citrate, tripotassium citrate, sodium sickle silicate, aging potassium silicate, salty aluminum aluminosilicate, and alligator potassium aluminosilicate, And its mixture. Based on N-alkyl or N-hydroxyalkyl-glucosamine 10,000 ears *, the amount of the vehicle is preferably about 0.5% to about 50%, more preferably about 2.0% to about 10% About 10 mol%. This reaction is preferably carried out at about 138C to about 170t: typically about 20 to about 90 minutes. When triglycerides are used as fatty esters in the reaction mixture, this reaction is preferably also carried out using about 1 to about 10% by weight of a phase transfer agent. This amount should be in the range of -12-(please read Please fill in this page for the legal aspects of the f-face. The Chinese national standard (CNS) A4 specifications (210x297 mm) for each paper standard port ^ 00536 Λ 6 Β6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy (11) Calculate based on the reset percentage of the mixture of anti-cancer compounds. It is believed that it is associated with lipolytic polyethoxylates, alkyl polyglycosides, linear inulin, and their mixtures. This method is preferably carried out as follows: (a) Preheat the fatty ester to about 1381C to about 17〇υ; (b) Add N-alkyl or N-hydroxyalkyl vinegar to the heated fatty acid ester Acanthamine, and mix to the extent necessary to form a two-phase tungsten / liquid mixture; (c) Mix the catalyst in the reaction mixture; and (d &gt; Stir, after the set inversion time. Also preferred The situation is that if the fatty ester is triglyceride, it will be about 2% to about 20 based on the reactant reset % The preformed suspected H-alkyl / N-hydroxyl group, N-linear glucosinolate fatty acid amine products are added to the anti-molecular compound as a phase transfer agent. This reaction will be inoculated and will increase Reaction rate. In the following experiments, detailed experimental procedures are provided. The polyhydroxy "fatty acid" amines used in this article also provide the following benefits to the detergent builders, and can also be used for gold or mainly from It is made of natural, renewable, non-petroleum raw materials, and it is degradable. It also shows low toxicity to aquatic organisms. It should be understood that the polyhydroxy fatty acid formula (I) is pressed with the legs to produce them The method will typically produce a certain amount of non-volatile by-products, such as ester amines and polyhydroxy fatty acid amides. The degree of these by-products will vary depending on the to-be-determined anti-kappa and physical conditions. Preferably The situation is that the polyhydroxy fatty acid amide in the two cleaning compositions will provide a form-13-(please read the precautions before filling in this page. This page) This paper is not in use. CHS) T 4 specifications (210X297 public goods) A 6 Β6 Ministry of Economic Affairs Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards (5) The invention description (12), so that the composition containing polyhydroxy fatty acid amides added to this detergent contains less than about 10%, preferably less than Jun 4% oval-shaped polyhydroxy fatty acid amide. The above-mentioned preferred method has the advantage that it can produce a relatively low degree of by-products. The detergent enzyme can be included in this detergent formulation for various purposes, including for example Remove stains based on protein-based, water-based compounds, or triglyceride-based, and prevent the transfer of dye loss. Enzymes to be added, including protease, starch mash, fat, ferritinase and Per-gasification enzymes and their mixtures. Other types of enzymes can also be included. It can be obtained from any suitable source, such as plant, animal, bacterial, li® and yeast sources. However, its choice is pseudo-dominated by several factors, such as the most suitable conditions for pH-activity and / or stability, thermal stability, and stability for active cleaning, rib washing, etc. in this regard. The better ones are bacterial amylase and protein and fungal fiber # enzyme. Enzymes are usually added to an extent sufficient to provide up to about 5 mg per gram of composition (weight ratio>, more typically from about 0.05¾ grams to about 3¾ grams of active enzyme. An example of a suitable flute for protein_ is Bacillus subtilis protein plum, which It is obtained from B. subtilis (B. subtilis) and B. licheniforB (Bacillus licheniformis>). Another suitable protease is obtained from a rod mackerel strain, which is in an inclination pH range of 8-12. It has the maximum activity and is developed and marketed by Nove Industries A / S as a registrar Esperase *. The cleavage of this enzyme and similar enzymes is pseudo-described in Novo British Patent Specification 1,243,784. It is suitable for removing proteins as Proteolytic enzymes of basic strains, of which -14-(please read 1 ^ = face-to-face: ΜIssues and then fill out this page) -install- order- line-this paper " CNS) f 4 specifications (210X297 public *> 〇〇5ί〇'ό A 6 136 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy V. Description of invention (13) The available ones, including trademarks ALCALASE and SAVINASE, Sold by Novo Industries A / S (Denmark), and by Tuan, Jisheng Synthetic Materials Corporation (MAX) sold by MAXATASE. Those who are interested in proteolytic enzymes, especially users of the A composition for cleaning liquids, are referred to herein as protein》 A and protein _ Enzyme of B. Protein_VI and its preparation method are described in the application of Shizhou Jiali 130, 756, published on January 9, 1985, and referenced herein. Protein_8 is a proteolytic enzyme, which The difference of protein_A is that it has a leucine acid instead of tyrosine at the 217th position of its amino acid sequence. Protein "B" is pseudo-described in European Patent Application No. 87303761.8 filed on April 28, 1987. , And for reference herein. The preparation method of protein_B is also shown in the announcement on January 9, 1985, issued to Bott et al., And the patent of Shizhou, 130,756, and for reference herein. Self-sustaining special bacteria B. licheniforra of oc- ;? 5 powder_, the pseudo is more detailed in the British Patent Specification 1,296,839 (Novo), and has been referenced in the foregoing. The powder decomposes protein, including for example RAPIDASE (International Bio Synthetic Materials Corporation) and TMRMAMYL (Novo Industries Corporation). It can be used in the invention of guoweisu_, including fine-grained or bacteriocidyl_. It is preferably changed to have a pH optimum value between 5 and 9.5. 逋 当 继 维 素梅 假 掲 is shown on March 6, 1984 U.S. Patent 4.435,307 issued to Barbesgoard et al. On the Japanese date is hereby incorporated by reference. Among them, the bacterial cellulose ϋ made from Hueico la insol en (humic plug) is shown. Appropriate following vitamins are also shown in British patent GB-A-2.075.028; GB-A-2.095.275 and German patent DE-0S-2.247 · 832. -15-(Please read the details on the back and then fill out this page) The paper size is printed in Chinese National Standard (CNS) 4 (210X297 g *) Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs 4 〇 0〇 ^ v Λ6 ___BG_ V. Description of the invention (14) This example of Zhai Jiweisu enzyme, Yi is the conversion of Huiiicola insolen (Eupatorium graminearum var. The "a〇idea &gt; Piwei strain produced by Binjiang strain, wait until it is The erbium plug strain DSM 1800, and the cellulose produced by the bacterium N Zhenbin or a kind of Aeromonas spp. That produces cellulose_212 Zhenbin and from a marine 1 abe 1 1 a Aur i cu 1 a So 1 ander) androgen extract from hepatopancreas _. Appropriate fat for cleansing, including those produced by microorganisms such as Pseudomonas stutzeri (Pseudomonas stutzeri) ATCC 19.154, as shown in British Patent 1,372,034, and incorporated herein by reference. Appropriate lipases include those that show a positive immunological cross-reactivity with adipose-anti-chicken, by P seud 〇ο nasf 1 u 〇resce η (L. fluorescens) IAM 1057 spawned by creatures. Fat_ and its purification method have been described in Japanese Patent Application No. 53-20487 published on February 24, 1978. This lipase is available from Amano Pharmaceuticals (Nagoya, Japan) under the trade name Fat_P ”ABan 〇 ", hereinafter referred to as" Aiano-P ". The lipase of the present invention should cross-react with the positive immunological reaction of Amano-P antibody, and use the standard color epidemic mine according to the standard of Ouch ter lony. Procedure (Acta. Med. Scan., 133, pages 76-79 (1950)) S. These fats, and the method of immunological cross-reaction with Aiano-P, are also described on November 7, 1987 U.S. Patent 4,707,291 issued to Thon et al. And incorporated herein by reference. A typical example of this is Anano-P fat _. Fat from Pseudoio-nas fragi (Pseudomonas berry) FERM P 1339 _ (trademark available Name Aiaano-B), obtained from the Pseudomonas nitroreducen variant lipolyticum FERM P1338 fat _ (Aaano -16 can be traded as a sample name-(please read the precautions on the Ϊ surface first and then fill out this page) Pack. Order &lt; thread · this paper Standard Yangtze Standard (CHS) Grade 4 (210X297 public goods) Λ 6 Β6 Central Standard of the Ministry of Economic Affairs Printed by the Employee Consumer Cooperative. V. Description of invention (15)-Obtained by CES), obtained from Chr〇B〇bacter viscosu ·, M $ DChro ^ o — bacter viscosu · variant lipolyticui.NRRLB 3673 Fat_. Available commercially From Toyo Jozo (Tegata, Japan); and other Chroiobacter viscosua cell B from Meituan Biochemical (USA) and Disoynth (Netherlands), and from Pseudomonas gladioli (Dangjiang Capsule) fat_. Over-gasification_Combined with the sources of gas, such as per-salt, perborate, persulfate, hydrogen peroxide, etc. It is pseudo-used in "solution bleaching", which means to prevent the dye or yankeae removed from the substrate from being transferred to other substrates in the wash solution during the washing operation. Enzymes are known in this technique, and include, for example, horseradish gasification _, lignin _, and halogen-based gasification enzymes (such as bromo-overgasification containing «(chemical»淸 洁 _Composition, for announcement on October 19, 1989, was awarded to the PCT Inter-Park Application W0 89/099813 of 0. Kirk, which was attributed to Novo Industries A / S, and is hereby incorporated by reference The extremely wide range of enzymatic enzymes and their incorporation into synthetic detergent particles are also shown in the US Patent 3,5 53,139 issued to McCarty et al. On January 5, 1971 (and provided for Reference). Enzymes are further shown in U.S. Patent 4,101,457 issued to Place et al. On July 18, 1978, and U.S. Patent 4,507,219 issued to Hughes on March 26, 1985, both of which are incorporated herein by reference. The enzymes that can be used in the formulations of the liquid decontamination formula and the method of incorporating such formulations are shown in the US Patent 4,261,868 issued to Hora et al. On April 14, 1981, and are incorporated herein by reference. For granulated Zhijie W, the enzyme is preferably used pseudo--17 which is inert to the enzyme-(please read the precautions of the noodles before filling in, Page) This paper scale is printed with C00S36 A6 _____B6_ printed by the China National Standards (CNS) Grade 4 (210X297 commonweed) Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. V. Description of the invention (16) Adding coating to make The formation of gray ash is minimized and the stability of the skeleton is improved. The technology that has become this project is known to this technology. In the liquid «formulation, it is better to use an enzyme to stabilize the system. 鼸The alcohol stabilization technique in aqueous detergent compositions is well-known to the art. For example, a technique for stabilizing enzymes in aqueous solutions for the use of free calcium ions from sources such as Calcium acetate, calcium formate and calcium propionate. Calcium ions can be used in combination with short carboxylates (preferably formic acid). # Yue, for example, U.S. Patent 4,318,818 issued to Let ton et al. On March 9, 1982. It is also referred to in this article. It has also been proposed to use multi-enzymes similar to glycerin and rowan fermentation. Alkane fermentation, dialkyl glyoxyl fermentation, poly-fermentation and multi-functional aliphatic amines (such as alkanase Acetamide, triacetamide, di-isopropanamide, etc.) Mixture, and acid or alkali metal millate. Enzyme stabilization technology is shown separately and exemplified in U.S. Patent 4,26, 863, March 17, 1971, issued to Horn et al. On April 14, 1981 In U.S. Patent 3,600,319 issued to Gedge et al., Both patents are hereby incorporated by reference, and published on October 29, 1986, European Patent Application Dish Bulletin 0 199 405 issued to Venegas, and application for decree 86200586.5. "Acid Crushing" is better. The enzyme stabilization system is also described in, for example, U.S. Patent Nos. 4,261,868, 3,600, 319 and 3,519,570. In addition to the polyhydroxy fatty acid amine, the composition of this * may contain other cleaning interface active pads to help clean the ribs. The holding interface activity used is two, which can be widely changed, and any cleaning interface activity scheme can be used, which can be used for the imaginary unfinished final throwaway. Enzyme-containing cleansing _ most commonly used to clean clothing, suspects, spinning suspects, Xiongwei, hard surfaces, etc.逋 当 Interface-18-(please read the precautions first and then fill in this page) Installation · Line-This paper ruler A Xiao uses the Chinese National Standard (CNS) A 4 specifications (210X297 public; ":"): 〇〇 Vertical Λ 6 13 6 Printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economy V. Description of the invention (17) The active substances include anionic, nonionic, cationic and other surfactants, and examples are as follows. Preferably, the composition includes one or more anionic surfactants, one or more other nonionic surfactants, or a combination thereof. The benefits of the present invention are particularly prevalent in the following composition, which pseudo-contains surfactants or other ingredients that are detrimental to enzymes. Generally speaking, its pseudo includes (but not limited to) anionic surfactants, such as alkyl ester oxylates, linear alkylbenzene sulfonates, alkyl sulfates, etc. Typically, the amount of extra cleansing surfactant present is about 3% to about 40%, preferably about 5% to about 30%, by weight of the i-cleanser composition. As follows, Yin_ 芊 袢 cuts and circumcises a usable form of a sickle-like surfactant, including alkyl ester sulfonate. It is what I expected, because it can be made from renewable non-petroleum sources: the cracking chrysanthemum of the next interface active ingredient of the alkyl ester sulfonic acid. It can be difficult to achieve by the known methods shown in the technical literature. For example, linear esters of ce-c2〇 carboxylic acid can be stimulated with gaseous Sf) 3 sulfonate and squeezed, "Journal of the American Society of Oil Chemists", 52 (1975) pages 323-329. The starting materials include, for example, natural fatty substances derived from tallow, palm oil, coconut oil, etc. Preferred alkyl ester sulfonate surfactants, especially for users of laundry applications, include alkanes with the following groove formation Ester sulfonate surfactant: 0 R *-CH-C-0R4 S0, N where R3 is a Ce-C2O hydrocarbon group, preferably an alkyl group, and its combination, R4 is G--19-(please first Read the precautions on the f side and fill out this page) Pack-This paper is used again in the "National Standard (CNS) Yu 4 specifications (210x297 public goods) OOo ^ 1 A 6 B 6 Zhengong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Printing 5. Description of invention (18) C6 hydrocarbon group, preferably alkyl group, or a combination thereof, and μ is a cation that can form a soluble salt. Appropriate salts include, for example, sodium salt, potassium and lithium salts , And substituted or unsubstituted ammonium ions, such as methyl-, dimethyl-, trimethyl-ammonium, and quaternary ammonium cations, such as tetramethylammonium and Pyridinium dimethyl hexahydropyridine, and cations derived from alkanosamines (such as monoacetamide, diacetamide, and triacetamide). Preferably, R3 is Ci〇-Cie alkyl, and R 4 It is methyl, ethyl or isopropyl. Especially preferred is methyl ester salt, in which 3? Is C14_C16 alkyl. Alkyl sulfate interface active cocoon, for the use of this article, another kind of importance Anionic surfactant type. «When used in combination with polyhydroxy fatty acid amide, in addition to providing excellent cleaning performance, including good oil / oil cleaning performance at Guangfanyuan temperature, washing temperature and washing time »It can be used to obtain the dissolution of alkylsulfate and the improved matching ability in the formula of Liquid Cleaning, which is assumed to be a water-soluble salt or acid having the formula R0S03M, where R is preferably C10-C24 The hydrocarbon group is preferably an alkyl group or a hydroxyalkyl group having a C1〇-C20 alkyl component, more preferably a c12-cie alkyl group or a hydroxyalkyl group, and M is Η or a cation, such as an alkali metal cation (such as a pin, a charge) , Beating substituted or unsubstituted ammonium ions, such as methyl-, dimethyl- and trimethyl Ammonium, as well as quaternary cations such as tetramethylammonium and dimethylpyridine, and cations derived from alkanoses (eg, acetamide, diethylacetamide, triethylacetamide, and mixtures thereof) . And the like. Typically, C12-Cle alkyl bonds are preferred for lower washing temperatures (e.g. below about 50t), while C16-Cie alkyl bonds are preferred for lower wash temperatures (e.g. above Approximately 50C) is better. -20-(Please read the precautions before filling out this page) Private paper standard for easy use "National Standard (CNS) A 4 specifications (210x297 mm) ^ 0052Β Λ 6 13 6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (19) Alkyl alkyl chlorosulfate interface activity_, another useful anionic interface activity «catenium-like. These interfacial beading agents are hydrolyzable salts or acids, which are typically of the formula R0 (A) m-S03M, where R is an unsubstituted C10-Cm alkyl group, or has (: 10-(: 24 alkane The hydroxyalkyl group is preferably a C12-Ceo alkyl group or a hydroxyalkyl group, more preferably a C12-Cie alkyl group or a hydroxyalkyl group, and A is an ethoxy or propyl group. The above is between about 0.5 and about 6, more preferably between about 0.5 and about 3, and M is Η or a cation, this cation can be, for example, a metal Kuma ion (eg, sodium, lithium, lithium, calcium , Magnesium, etc.), ammonium or substituted ammonium cations. Alkyl acetylated sulfates and alkyl propylated sulfates are intended to be covered here. Special examples of substituted ammonium ions include methyl groups -, Dimethyl-, trimethyl-ammonium, and quaternary ammonium cations, such as tetramethylammonium, dimethylhexapyridine, and derivatives derived from alkane amides (such as monoethylamine, diethylamine) , And triethylenzyme) cations, and mixtures thereof. The interface activity _ iso is (: 12- (: 18 alkyl polyethoxylated Π .0 &gt; lanate, (: 12- {: 18 Alkyl polyethoxylation (2.25) Acid salt, (: 12-(: 18 alkyl polyethylated gasification (3.0) sulfate, and (: 12-(: 18 alkyl polyethylated gasification (4.0) sulfuric acid, where M is conveniently selected from Pin and Potassium. The other anionic surfactants that can be used for cleaning purposes can also be included in this composition. They can include soap salts (eg, including reeds, Potassium, ammonium, and substituted ammonium salts, such as mono-, di-, and triethylacetamide salts (Ce-c2O linear alkylbenzene sulfonate), ce-c22-grade or secondary alkane sulfonate, Ce- Olefin sulfonate. A sulfonated polycarboxylic acid made by sulfonation reaction of the product of the hydrolysis of _ (tujin hurricane), for example in the British Patent Specification -21-(please read the legal meaning on the back Matters need to be re-filled on this page) This paper adopts China _ Jiayubi (CNS) T 4 specification (210X297 g *) Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 200526 Λ6 _B6_ V. Description of Invention (20) Article 1,082,179 »As described in. Alkyl glycerol sulfonate, fatty acid glycerol sulfonate, fatty oil glycerol sulfonium sulfonate phenol ethylene oxide sulfate, sulfonate hydrocarbon salt, Glyoxalates. Isethionates, such as acetoyl isethionate, N-acyl taurate, methyl taurine fatty acid amide, alkyl succinic acid amine and sulfonate Succinate, monoester of acid succinic acid (especially shaved and unsaturated C12-Cie monoester), androstenyl succinic acid diester (especially shaved and unsaturated Ce-C14 diester), N-benzylmethylaminoacetate, an alkyl polyhedral sulfate, such as an alkyl polyglucoside sulfate (its non-ionic, unsulfated compound, pseudo-described below), branched Primary alkyl sulfate, alkyl polyethoxy carboxylic acid. For example, the formula R0 (CH2CH20UCHjiC00-M +, where R is Ce-Ca2 alkyl, k is an integer from 0 to 10, and M is a cation that can form a soluble salt , And the use of isethionic acid esterification and the use of europium hydroxide to neutralize fatty acids. Resin acids and hydrogenated resins are also suitable, such as Lifan, hydrogenated rosin, and resin acids and hydrogenated resin acids present in or derived from tall oil. Other examples are pseudo-described in "Surface Active Agents and Cleaners (Volumes 1 and II, Schwartz, Pe" ry and Be "ch &gt; Multiple such interfacial activities", also shown generally on December 30, 1975 U.S. Patent 3,929,678 issued to 1 ^ 1 ^} «1 丨 〇 et al., Line 23 || line 58 to line 29 of orange 29 (and is provided for reference). Appropriate job payment is non-androgynous, "interface active, for general purpose, shown in U.S. Patent 3,929,678, issued December 30, 1975 to Laughlin et al., 12th, lines 14 to 16 for line 6. , And for reference in this article. Non-limiting types of useful non-ionic interfacial activity W, examples of which are listed below. -22-(please read first-note on the surface before writing this page) This paper size is not used + National Sample Standard (CNS) A4 specification (210X297 ft), 00536 V. Description of invention (21) Λ6 B6 Printed by Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economics 1. Polyphenolic alkyl phenol, polycyclic «Propane, and polyoxybutane condensate. Generally speaking, the combination of polyethylene gas and ethane is preferred [these compounds include alkylphenols and "A condensation product of alkylene, the alkylphenol has an alkyl group with a straight bond or a branched bond, and contains about 6 to about 12 sulfon atoms. In a preferred embodiment, the ring gas ethane It is supplied with an alkyl phenol equivalent to about 5 to about 25 moles of ethylene oxide. This type of non-ionic interfacial active pad available on the market, including Isepe 丨 C0-630, is sold by GAF. ; And Triton X-45, X-1 14, X-100, and) (-102, all sold by Rohii & Haas. These compounds can be called alkylphenol alkyl sulfonyl compounds (such as alkylphenol ethyl Oxygen compounds). 2. Aliphatic yeast and condensation products of about 1 to about 25 moles of earrings. The alkyl bond of this aliphatic yeast can be a straight bond or a branch, primary or secondary. And usually Contains about 8 to about 22 sulfon atoms. Particularly preferred are alcohols having an alkyl group containing about 10 to about 20 sulfo atoms, and about 2 to about 18 moles of gaseous ethane per ear alcohol. Knitted products. Commercially available nonionic surfactants of this type, examples of which include the entangled product of Tergitol lSHiCu-Cis linear secondary enzyme and 9 Methyloxylethane), Tergitol 24-L -6NMW (Cie-C14 first-class yeast and 6 mol ethylene oxide compound product, which has a narrow molecular weight distribution>, the analysts are sold by Union Carbide; NE0D0L 45-9 ((^ 4- (: 18 Condensation products of nickel-type yeast and 9-mole earrings gas ethane>, NE0D0L 23-6.5 ((: 12- (: 13 entanglement products of linear yeast and 6.5 ginger gas ethane), NE0D0L 45-7 (C14 -Cls »the entanglement product of sex yeast and 7 oxyl oxirane), NE0D0L 45-4 ((^ 4-(^ 8 the condensation product of nickel sex yeast and 4 quinol ethylene oxide), by Shell Chemical Company绡 售 ， 和 KYR〇Ε0Β (C13-C18 -23-(please read ¾ of the noodles first .. Please fill in this page before you fill in the details). 装. __ 线. Private paper size 揑 用 中 家 «CN (CNS ) T4 specifications (210 to 297 mm) Λ 6 Β6 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (22) Mengyu 9 Yingluo «Condensation Products of Ethane), by Procter &amp; Gaible Company sales. These non-ionic interfacially active compounds are called "alkyl ethyl compounds". 3. A combination of ring gas ethane and a hydrophobicity, the hydrophobicity of the gas_propane and propane The formation of the ferment of the leaven. The hydrophobic portion of these chemical compounds preferably has a molecular weight of about 1500 to about 1800 and is water-insoluble. In this hydrophobic part, the addition of polyethylidene moiety will easily increase the water solubility of the molecular scorpion, and maintain the liquid properties of this product, up to the content of polyethylene ether as the total weight of the knitted product It is about 50% of the point. The codling is used to condense the oxygen to the alkane to about 40. Examples of this type of compound, including certain commercially available Pluronic interface actives, are suspected of being sold by BASF. 4. The ring «ethane is derived from the condensate product of the ring gas propane and ethylene diamine. The hydrophobic parts of these products are pseudo-composed of the reaction product of ethylenediamine and propane, and usually have a molecular weight of about 2500 to about 3000. The water-based portion is used for condensation of ethane gas to a certain degree, so that the embroidered product contains about 40% to about 80% (by weight) polyethylenimine and has a molecular weight of about 5,000 to about 11,000 . Examples of this type of nonionic interfacial activity Λ include certain commercially available Tetronic compounds sold by BASF Yong. 5. Semi-aperture non-curvilinear interfacial activity, a kind of non-ionic interfacial activity M, which includes water-soluble amine compounds, which contains an alkyl group with a value of about 10 to about 18 sulfonate atoms Parts, and 2 parts, including alkyl and hydroxyalkyl, which contains about 1 to about 3 pour sulfon atoms; water-soluble "Radon-24-(please read first-the precautions for the surface before scorpion-¾ (This page)

T Xiangben paper ”size A is made of Chinese National Standard (CNS) Grade 4 (210X297 g *) ____136_ ____136_ Centralized Bureau of Ministry of Economic Affairs Employee's consumption cooperation du printing ^ οο〇2δ Λ 6 V. Invention description (23) Chemicals , Which contains an alkyl moiety with a tilt of about 10 to about 18 tilt carbon atoms, and 2 moieties, selected from the group consisting of alkyl moieties containing 1 to 3 sulfa seeds and hydroxyalkyl groups; , Which contains an alkyl group portion of about 10 to about 18 atoms, and one alkyl group selected from the group consisting of about 1 to about 3 sulfonium and hydroxyalkyl groups. Semi-polar nonionic detergent surfactants, including amine chloride surfactants having the formula: 0 R3 (0R *) xN (R *) 2 where R3 is an alkyl group containing about 8 to about 22 distillate atoms , Hydroxyalkyl or alkylphenyl, or a mixture thereof; R4 is a subalkyl or hydroxyalkylene group containing from about 2 to about 3 sulfonic atoms, or a mixture thereof; x is from 0 to about 3; and each Rs is containing about An alkyl or hydroxyalkyl group of 1 to about 3 to 5 member atoms, or a polymethylene group containing about 1 to about 3 partial vaporized vinyl groups> r 5 groups can be connected to each other, as in the past: Solid or nitrogen atoms, and form the Hunjie ditch. These amine vaporizer surfactants include oxidation of c10-ciaalkyl dimethylamine and oxidation of ce-c12 alkoxyethyldihydroxyethylamine. 6. Alkyl polybranches, shown in U.S. Patent No. 4,565,647 issued to Llenado on January 21, 1986, which have about 6 to about 30 knot atoms, preferably about 10 to about 16 nitrate atoms Hydrophobic groups, and more than one, for example, a polyglycoside, containing from about 1.3 to about 10, preferably from about 1.3 to about 3, most preferably from about 1.3 to about 2.7 sugar units, hydrophilic groups containing 5 Any lotus sugar, such as glucose, galactose, and galactose base parts can be used to replace dextrose base parts (this hydrophobic base_ 可 -25-this paper size Happy Use China National Standards (CNS) Grade A 4 (210x297 public address) (Please read the precautions of the threatened surface before writing this page)

(〇Od3S A 6 Π 6 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of invention (24) Depending on the situation, it can be connected to its 2-, 3-, 4-, etc. positions, thus obtaining the glucoside Or galactosides contrary to glucose or galactosidum). This interactive key can be located, for example, between one instrument position of the other unit and the 2-, 3-, 4-, and / or 6-position on the aforementioned unit. Optionally, and less desirably, it may be a poly-gasified subalkyl bond connecting the hydrophobic part and the multi-part. The preferred gasified alkene is ethyl ethane. Typical hydrophobic groups include alkyl. Planed and unplaned and branched or unbranched, containing from about 8 to about 18, preferably from about 10 to about 16 knot atoms. This alkyl group is preferably a straight-bonded citranyl group. This alkyl group may contain up to about 3 dysprosium hydroxyl groups, and / or its poly-vaporized subalkyl group mirrors may contain up to about 10, preferably less than 5 parts of the oxidized subalkyl group. Suitable alkyl polybranches are octyl, nonyldecyl, H-yldodecyl, tridecyl, tetradecyl, fifteen, hexadecyl, heptadecyl and octadecyl, di-, tri -, Four-, five- and six «glucosides, galactosides, lactosides, glucose, fructoside, fructose and / or galactose. Appropriate mixtures include live alkyl, di-, tri-, tetra-, and pentaglycosides, and tallow alkyl tetra-, penta-, and hexaglucosides. Preferred alkyl polysaccharide ridges have the following formula R20 (CnHj! «0) t (cabinyl) χ where R2 is pseudo-selected and includes alkyl, alkylphenyl, hydroxyalkyl, hydroxyalkylphenyl and mixtures thereof, wherein alkyl Contains about 10 to about 18, preferably about 12 to about 14 mercapto atoms; η is 2 or 3, preferably 2; t is 0 to about 10, preferably 0; and X is about 1.3 to about 10, preferably about 1.3 to about 3, and most preferably about 1.3 to about 2.7. This sugar group is preferably derived from selenium glucose. In order to prepare these compounds, first form its yeast or alkyl polyethylenyl yeast, and then with glucose or a kind of "-26 _ This paper scale is used in China National Standard (CNS) A 4 specifications (210x297 male dragon) ( Please read the precautions on the t-face first. Please fill in this page). Installed. • 1Τ, printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of Invention (25) The source of the grapevine is reversed, and glucoside is formed (connected At its Bu position>. Then other glycosyl units can be connected to its Bu position-the aforementioned glycosyl units 2-, 3-, 4- and / or 6-position (preferably mainly its 2-position) 7. Fatty acid amide surfactant with the following formula: 0 R *-C-N (R ^) 2 where R6 contains about 7 to about 21 (preferably about 9 to about 17) sulfur Atom's courtyard, and each R7 pseudo-selection includes M, C1-C4 courtyard, Ci_-CU Xiangyuan and-(C 2 Η 4 0 U Η, where X varies from about 1 to about 3. Preferred aldehyde The amines are Ce-C20 amidoamine, monoethanolamine, diethanolamine and isopropanolamide. It is also a cationic cleansing surfactant which can also be included in the present invention. Cleaner combination In the case of Yang Jingzi, it is rare to swell, and the active ammonium interfacially active, such as alkyl dimethyl iridium halide, and these interfacially active thin I have the following formula: [R2 (〇R3) yi! [R4 (OR3) y] zRsN + X- where R2 is an alkyl or alkyl group having about 8 to about 18 bow atoms in the alkyl chain, and each R3 pseudo-silkworm includes -CH2CH2-, -CH2CH (CH3) -, -CH2-CH (CH2〇H)-, -CH2CH2CH2-, and mixtures thereof; each R4 is pseudo-selected from S living Ci-c4 alkyl, Ci-C4 hydroxyalkyl, by connecting the two R4 groups The formed nodal ring structure, -ch2choh-chohcor6chohch2oh, where R6 is any hexose or hexose polymer with a molecular weight of less than about 10,000, and when y is not 0, it is false; Rs 傜 and R4-he, Or an alkyl bond, where the carbon number of R 2 plus R 3 is infinite, not more than about 18: each y is from 0 to about 10, and -27-Λ 6 Β6 (please read the note f on the first side before filling in Λthis page) -installation and ordering * The size of this paper is easy to use China National Standards (CNS) f4 specification (210x297 mm) Λ 6 Β6 Printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economy V. Description of invention (26) y The sum of the values is from 0 to about 15; and X is any compatible shade Ion. Other cationic interfacial transitions that can be used here are also described on October 14, 1980 in «Cibre ’s Beauty Plaque 4,228,044, and are provided for reference. 黧 他 It ffi method 4» _ can be used Interface Activity_ Incorporated in this two combinations of Lu Jie. These interfacial activities can be broadly described as aliphatic derivatives of secondary or tertiary amines, or aliphatic derivatives of hetero- and tertiary amines, where the aliphatic can be linear or branched. One of the aliphatic components pseudo contains at least about 8 tilt sulfon atoms, typically about 8 to about 18 tilt sulfon atoms, and at least one of them contains an anionic water-soluble radical, such as carboxyl, acid, sulfuric acid root. See U.S. Grant No. 3,929,677 issued on December 30, 1975 to "1", et al., 19th tear, lines 18-35 (and referenced herein). Examples. Zwitterionic interfacial activity can also be incorporated into this composition. These interfacial activities can be described as derivatives of secondary and tertiary amines, derivatives of heterocyclic secondary and tertiary amines, or derivatives of tertiary ammonium, tertiary or tertiary sulfonamide compounds. . See U.S. Government 3,929,678, Line 19_, Lines 38 to 22, and Line 48 (also referenced herein) issued to Laugh 1 in et al. On December 30, 1975. Instance. Amphoteric and zwitterionic interface activity_, usually one or more anionic and / or nonionic interface activities are used in combination. In addition to enzymes, polyhydroxy fatty acid amide, and any clean interface for irrigation 28-(please read the precautions of 1 ^ before filling in this page)-install · f Standard (CNS) A4 specifications (210X297 g *) Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ 6 Β 6 __ Fifth, the invention description (2γ) The cleaning agent here may include one or A variety of other cleaning agent additional substances may be used to help or enhance the cleaning performance, to treat the substrate to be treated, or to change the appearance of the composition of the Jiejieer compound (such as perfume, coloring, dyes, etc.). Zhi Jie Cocoon Rib Lotion can be optionally included in the composition here to help control the firmness of the substance. Both inorganic and organic builders can be used. The content of rib wash can vary widely, depending on the end use of the composition and its desired physical form. When present, the composition typically contains at least about 1% rib lotion. Liquid formulations typically include at least about 5% to about 50¾. More typically about 596 to about 30% (weight ratio> cleaning_rib lotion. Granular formulations typically include about 10% to about 80%, more typically about 15% to about 50% (by weight) of clean ribbed wash. However, it is not intended to exclude lower or higher S content of builders. Inorganic detergent builders include (but not Limited to) Polyandrostate (the examples of which are tripolyphosphoric acid, pyrophosphoric acid, and glassy polymer metaphosphoric acid>, oxalic acid, phytic acid, silicic acid, phosphoric acid (including dibasic acid and triacid), Thioammonium and silicic acid _ Jin Yi, ammonium and alkanoammonium salts. Can also be used as a salt builder, as well as a builder containing a borate-forming substance, which is stored or washed in the detergent It can produce boric acid (hereinafter, collectively referred to as "acid rib lotion"). Preferably, the composition of the present invention which is to be used for washing conditions is less than about 50C, especially less than about 40 = 0 In the case of using non-borate rib wash ganga silicate builder, the example is aging gold silicate, the other is Si oa -29-(please read the back (Notes to be filled out &gt; page) This paper is used in the national standard (CNS) A 4 specification (210X297); tt) A 6 B6 printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Invention description (2g ): HaiS〇 ratio in the range of 1.6: 1 to 3.2: 1, and the scalloped silicate ray, such as layered silicate reed, for the description of May 12, 1987 was awarded to Η.P. Ri- U.S. Patent No. 4,664,839 of eck and incorporated herein by reference. However, other silicates can also be used, such as magnesium silicate, which can be used as a crisp formulation in granular formulations (crispe η ί n gt agent &gt;, As the stability of oxygen supply Weibai and as a component of the foam control system. Examples of the sulfonate ribalcyl are the sickle metal and the sickle metal sulfonate. Including sodium sulfonate and sodium trihydrogenate, and A mixture with ultrafine calcium silicate, such as the German Patent Application No. 2,321.001 published on November 15, 1973, the contents of which are shown and incorporated herein by reference. Aluminosilicates are particularly useful in the present invention. Aluminum Silicate Risal is of great importance in the recently sold powerful granular granular cleansing composition, It can also be an important builder component in the formulation of the liquid Jiejieli. Aluminosilicate builders include those with the following experimental formula: M &gt; (zA102 · ySiOe) where Μ is europium, deuterium, calcium or substituted ammonium, z is about 0.5 to about 2; and y is 1; this substance has a magnesium ion exchange capacity of at least about 50 milligrams of anhydrous aluminosilicic acid at a local CaC03 hardness. Preferably, silicic acid is a zeolite rib having the following formula 111

Naz [(A10s). (SiO) ^] · ΧΗβ0 where ζ y is an integer of at least 6, the molar ratio of ζ to y is within the range of 1.0 to about 0.5, and X is from about 15 to about 264 Integer. Useful exchange materials for male aluminosilicates are available in the market. These aluminosilicates * can be crystalline or amorphous in structure, and can be naturally-produced aluminum-30-This paper scale uses the Chinese National Standard (CNS) A4 specification (210x297) * (please Read the precautions on the back first and then fill out this page) Binding-Ordering * Printed by Beigong Consumer Cooperation of the Bureau of Standards, Ministry of Economic Affairs, Du Λ 6 _ D6_ V. Description of invention (29) Silicate, or derived synthetically Get. "Aluminosilicate", a preparation method of the Ion Exchange Materials Division, is shown in the US patent 3,985.669 issued to Kruuel et al. On October 1, 1976, and is incorporated herein by reference. The preferred synthetic crystalline molybdenum silicate ion exchange material family that can be used here is available for purchase as Phosphate A, Zeolite P (B), and Zeolite X. In a pending example, this crystalline aluminosilicate "male exchange material has the following formula: Nais [(Al〇e) i2 (Si〇e) 12] * XHe〇 where x is about 20 to about 30, especially about 27. This material is called Zeolite A. This aluminosilicate has a particle diameter size of about 0.110 mm. Examples of special treatments for polydisperse salts are cockroach gold tripolyphosphate, potassium, ammonium pyro and maleate, europium and potassium orthocarnate, and polyphosphoricose, of which the degree of polymerization is about 6 to about 21, and the salts of phytic acid hexaphosphate. Examples of acid-removing rib lotion salts are the water-soluble salts of ethane 1-hydroxy-1,1-dibasic acid, the other being its sodium and potassium salts, and the water-soluble salts of methylene bisacid acid, such as its three sodium And tribenzyl salts, and water-soluble salts of substituted methylene bis-acids, such as the three-pin * and tribenzyl acid of isopropylidene, isopropylidene, benzylmethylene and halomethylene acid salt. The above-mentioned types of pickled and acid ribs washed cocoon salt were shown on December 1, 1964 and October 19, 1965, and were granted to Diehl ’s Meiji patents 3, 159,581 and 3,213,030; on January 14, 1969, Roy ’s Meitang patent 3,422,021; and 3,400,148 and 3,422,137, which were awarded to Quhby on September 3, 1968 and January 14, 1969. The contents of this disclosure are incorporated herein by reference. Eaves cleaning rib wash suitable for the purposes of the present invention includes, but is not limited to, a variety of polycarboxylate compounds. "Polycarboxyl-31" used in this article-This paper is used in the Ba family standard (CNS) A4 specification (210x297 g *). Printed by the Beigong Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs Λ6 _Η6_ V. Description of the invention (3〇) acid pass "refers to a compound having a polycarboxylic acid group, preferably at least 3 carboxylic acid groups. , Polycarboxylate builder ϋ, can usually be added to the composition in acid form. But it can also be added in the form of a neutral salt. When used in the form of pain, it is preferably salted gold, such as pin, lithium and lithium, especially europium salt, or ammonium and substituted ammonium (e.g. alkanoyl ammonium) Η. Included in the polycarboxylic acid rib wash, which is a variety of useful substances and the like. An important category of polycarboxylate rib wash HI includes ether polycarboxylates. Many ether polycarboxylates have been shown to be used as detergents for cleaning steel ribs. Examples of useful polycarboxylic acids include oxydihydroperoxides, such as U.S. Patent 3,128,287 issued to Berg on April 7, 1964, and U.S. Patent 3 issued to Lambert i et al. On January 18, 1972 , 635, 830, both cases are incorporated herein for reference. An unspecified type of ether polycarboxylate * which can be used as a builder in the present invention also includes those having the following general formula: CH (A) (COOX) -CH (COOX) -0-CH (COOX) -CH (COOX) (B) where Ran is 11 or 011; 8 is 11 or -0-(: 11 ({: 0 (^ &gt;-(: 112 ((: 0 (^); and Q is 11 or one Form a "separator". For example, if in the above formula, A and B are both Η, the compound is succinic acid and its water-soluble salt. If A is OH and B is Η, then the compound is Tartrate succinic acid (TMS) and its water-soluble salts. If A is Η and B is -0-CH (C00X) -CHa (C00X), then this compound is tartrate disuccinic acid (TDS) and its water-soluble salts .The mixture of these rib lotions. It is the best for the purpose of this article. The best one is the mixture of TMS and TDS. The weight ratio of TMS to TDS is about 97: 3 to about 20:80. These rib lotions -32-This paper _ Zhang Xiaoxiao used in the B National Standard (CNS) A 4 specifications (210X297 mm) Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. The description of the invention (31) You are shown in 1987 US Patent 4,663,071 issued to Bush et al. On May 5. · Didan ether polycarboxylic acid also includes It is a cyclic compound, such as those described in US 3,923,679; 3,835,163; 4,158,635; 4, 120,874 and 4,102,903, all of which are incorporated herein by reference. Other useful cleaning aids, including The ether hydroxy polycarboxylate represented by the following structure: H0- [C (R) (COOM) -C (R) (COOH) -Oln-H where Μ is 簋 or a Kuma ion, and the salt formed is water soluble It is preferably mineral ore, more or substituted ammonium cation. Η is about 2 to about 15 (η is preferably about 2 to about 10, η is more preferably for an average of about 2 to about 4), and each R is the same or different, and is derived from hydrogen, Ci-4 alkyl, or substituted alkyl (R is preferably hydrogen). Yet other ether polycarboxylates, pseudo-living maleic anhydride and ethylene or vinyl methyl Copolymer of ether, 1,3,5-trihydroxybenzene-2,4,6-trisulfonic acid, and carboxymethyl gas succinic acid. Organic polycarboxylate rib wash IH, also including various sickles of polyacrylic acid Gold, ammonium, and substituted salts. Examples of polyacetic acid builder salts are ethylenediamine tetraacetic acid and europium tribasic acid, lithium, ammonium, and substituted soft salts. Polycarboxylic acids are also included The salt is, for example, methylene hexamethylene Acids, succinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic acid, benzene pentacarboxylic acid, and carboxymethyl * succinic acid, and soluble salts thereof. Tonic acid rib lotion, such as boric acid And its soluble genus (especially sodium salt), a polycarboxylic acid that is particularly important for the formulation of powerful liquid stern cleaners -33-Λ 6 Β6 (please read the note Ϋ on the back and fill in this page) line · This paper scale is in accordance with Chinese National Standard (CNS) Grade 4 specifications (210x297 g). 5. Description of invention (32) Λ 6 Β6 The printed washing aid is printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economic Affairs, but it can also be used in In granular composition. Other carboxylate rib washs, including carboxylated sulfonated water compounds, are shown in US Patent No. 3,723,322 issued to Diehl on March 28, 1973, and are incorporated herein by reference. Also suitable for use in the cleansing composition of the present invention is 3,3-dicarboxy-4-oxo-1,6-adipate and its phase sugar compound, whose supply is shown on January 28, 1936. Bush's beautiful group of 4,566,984, and for reference in this article. Useful succinic rib lotions include C8-C20 alkyl succinic acid and its salts. One preferred compound of this type is dodecenyl succinic acid. Alkyl succinic acid typically has the general formula R-CH (COOH> CH2 (COOH), which is a derivative of EP succinic acid, where R is an alkyl group, such as C10-Ce〇alkyl or alkenyl, preferably C12 Cie, or where R can be substituted with a thin group, a sulfonic acid group, a sulfonyl group, or a substituent, all of which are described above. The succinate rib wash is preferably used in the form of its water-soluble salt , Including its sales, potassium, ammonium and alkanoammonium salts. Specific examples of succinic acid lotion lotion, including: lauryl succinate, carbohydrate; 3-yl succinate, palm oleyl succinate, 2- Dodecenyl succinate (preferred), 2-pentadecenyl succinate, etc. Lauryl succinate is the preferred rib lotion for this group, and it is described in the announcement on November 5, 1986 »Continent Patent Application Case 86200690.5 / 0,200,263. Examples of useful rib wash_. Also includes carboxymethyl gas malonic acid, carboxymethyl oxysuccinic acid, cis-xanthene hexacarboxylic acid, 颙 -¾pentane- The sodium urethane salt of tetracarboxylic acid, water-soluble polyacrylic acid salt (these polyacrylic acid "with a molecular weight of about 2,000, can also be effectively used as a partial rinse , And maleic anhydride Yu B-34-Please read the notes before reading the book. • Write this page. The paper size is not in the standard of China ’s Standard B (CNS) A 4 (210x297 male dragon). 〇〇5 ^ δ Λ 6 Β6 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of Invention (33) Copolymers of ene methyl ether or ethylene. Other suitable polycarboxylates are polyacetal carboxylic acid 9 |, which is shown in 1979 Patent No. 4.144,226 issued to Crutch field et al. On March 13, 2014 and is hereby incorporated by reference. These polyacetal carboxylic acids can be polymerized under the polymerization conditions by allowing the esters of glyoxylic acid to undergo polymerization It is made by combining together. It is then combined with the formed polyaldehyde carboxylate to the terminal plaque of chemical stabilization, so as to stabilize the polyalkali carboxylic acid to resist the rapidity in crocodile solution Depolymerization and conversion to its corresponding salt, and then added to a surfactant. Polycarboxylate rib lotion, also shown on March 7, 1967, Diehl, U.S. Patent 3,308,067, and is hereby incorporated by reference Such materials include water-soluble salts of homopolymers and copolymers of aliphatic carboxylic acids. Acids such as maleic acid, decomposed aconitic acid, methyl fumaric acid, semaric acid, cycloaconitic acid, methyl maleic acid and methylene malonic acid. Others known in this technology are: _Rib wash can also be used. For example, monocarboxylic acids with long bond hydrocarbon groups and soluble salts can be used. Japanese can include substances commonly known as &quot; soaps. &Quot; Typical use is (: 10--: 20 The length of the bond. This hydrocarbon group can be saturated or unsaturated. Pu Baihua meeting material-Dao Bai cut Zhou Luo Bai Fa servant. This * Zhi Jie "composition, may contain Luo Bai _ or whitening composition, this whitening composition It contains bleaching and one or more bleach activations. When a bleaching compound is present, it is typically present in an amount ranging from about 20% to about 20% of the cleaning period, and more typically from about 1% to about 10%. In general, bleaching compounds are S-components in non-liquid formulations (such as granular detergents). If present, the amount of bleach activator is typically about 0.1% to -35 in the whitening composition-(please read the precautions on the back before filling this page) (CNS) A4 specifications (210x297 mm) Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs £ 005 ^ 6 Λ6 ___B6_ V. Description of Invention (34) About 60%, more typically about 0.5% to about 40% . The bleaching used herein may be any bleaching agent which can be used in the cleaning-composition composition for textile cleaning, sulfonating surface cleaning, or other cleaning purposes currently known or becoming known. It includes Oxyxiaobai and other whitening agents. For washing conditions below about 501C, especially below about 40¾, the composition here preferably does not contain millate, or a substance that can form boric acid under clean «Yong storage or washing conditions« ( Yi Di can form the substance of acetic acid a). Therefore, under these conditions, it is best to use a non-boric acid a, which will not form a zygomatic whitening agent of borate. Detergents to be used at these temperatures are like substances that are substantially free of borate and can form borate. As used herein "substantially free of" acid salts and boric acid-forming substances ", this composition contains no more than about 2% by weight of any type of acid containing _ and can form" acid salts Substances, preferably not exceeding 1%, more preferably 0%. A class of bleaching agents that can be used, including percarboxylic acid bleaching agents and their salts. Examples of such trials include the case of single gas phthalic acid and hexahydrate, meta-peroxybenzoic acid, 4-nonylamino-4-oxoperoxybutyric acid and diperoxydodecanedioic acid. _salt. This type of bleaching is shown in U.S. Patent 4,483,781 issued to Hart nan on November 20, 1984. Burns et al. Filed a lawsuit on the United States on June 3, 1985. 740,446, February 20, 1985 On the day of announcement, Banks et al.'S Pizhou Patent Application No. 0,133,354, and Meituanli 4,412,934 issued to Chung et al. On November 1, 1983, are incorporated herein by reference. Highly preferred irrigating ϋ, also including 6-sylamino-6-gas peroxyhexanoic acid, as described in US Patent 4,6 34,551 issued to Burns et al. On January 6, 1987, and This article is for reference. -36-This paper scale is in accordance with the Chinese W Home Standard (CNS) A4 specification (210x297 g *) &quot; 'One (please read the precautions on the back before writing this page). Installed. Bei Gong, Bureau of Standards, Ministry of Economic Affairs Printed by the Consumer Cooperative on 200 Talks 5. Description of Invention (35) Another type of bleaching agent that can be used. Examples of active halogen bleaching agents, hypohalate bleaching agents, for example, e including trichlorotripoly. , And two-gas trimeric heteroaqueous acid honing and pressing, and N-nitrogen and N-bromoalkanesulfonamide. These substances are usually added at 0.5-10% by weight of the final product, preferably 5% by weight. 〇You can also use an over-air bleaching in addition to over-compounds. Appropriate peroxygen bleaching compounds, including sodium peroxysulfate sulfonate, pyrophosphate peroxygen hydrate, urea peroxyhydrate hydrate bite sodium chloride, peroxygen bleaching agent is preferably combined with bleaching It is used to generate peroxyacid corresponding to the bleach activator on the spot in the water solution (meaning during the washing procedure). A preferred bleach activator that is incorporated into the composition of the present invention has the following general formula 0 II R-C-L where !? contains about 1 to about 13: the phenyl group of aniseite. It extends and contains a carbonyl group The longest linear alkyl bond of sulfonate contains pseudo atoms from about 6 to about 10, and L is a leaving group, and its conjugate acid has a pKa value ranging from about 4 to about 13, such bleach activation_ 傜 described in 1 U.S. Patent 4,915,854, issued to Mao et al. On April 10, 990, and incorporated herein by reference, and U.S. Patent 4,412,934, which was previously incorporated herein by reference. Bleaching agent other than air bleaching agent. It is also known in this art, and can be used for this snorkel, a non-air bleaching jaw type that is particularly interesting and interesting, and contains light-activated bleaching agent, for example Sulfonated zinc and / or aluminum thin, these are -37-Μ (please read the precautions on the back before filling out this page). The size of the paper used in this book is based on the Chinese National Standard (CNS) 4 (210X297 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ^ ΟΟο.οΟ Λ 6 _B_6_ V. Description of the invention (3g) The quality can settle on the substrate during the washing process. When irradiated with light, in the presence of air, such as hanging clothes outdoors and drying in the sun, the sulfonated zinc phthalocyanine is activated, thus bleaching the substrate. The preferred zinc cyanine and a photoactivated bleaching procedure are pseudo-described in U.S. Patent 4,033,718 issued to Hoi conbe et al. On July 5, 1977, and are incorporated herein by reference. Typically, Zhijie composition contains about 0.025% to about 1.25% (by weight) of sulfonated zinc phthalocyanine. Party 9 »Go to the Noodles Any polymer decontamination that is familiar to this person can be used in the practice of the present invention. The motivation of polymeric pulp detergents is that they have hydrophilic segments to make the surface of hydrophobic secondary dimensions (such as polyester and nylon) hydrophilic, and have hydrophobic segments to sink on the hydrophobic secondary dimensions, and It remains adhered to it until the washing and rinsing cycles are completed, and thus acts as a hydrophilic anchor. This makes the stains that occur after using the decontamination and cutting treatment easier to treat later in the sickle washing process. Although it may be advantageous to use polymerized detergents in any of the cleaning_compositions here, especially in compositions used in laundry or other applications that require the removal of esters and oils from hydrophobic surfaces Staining agent, but the presence of polyhydroxy fatty acid sleep amines in the cleaning composition that also contains anionic interfacial activity can enhance the performance of many of the more commonly used polymer-based detergents. Yin-and-male surfactant can interfere with the deposition of certain detergents and the ability of catfish to attach to hydrophobic surfaces. These polymeric "detergents, have nonionic hydrophilic fragments or hydrophobic H-interactions that can interact with the male and female interface activity". -38-(Please read the precautions on the back before filling out this page) Binding · Order _ This paper size is used in China Standards (CNS) A 4 specifications (210x297 public Jie) Λ 6 13 6 Central Bureau of Standards of the Ministry of Economic Affairs Printed by the Negative Workers Cooperative Society 5. Description of the invention (37) W. By using. Polyhydroxycholic acid amide, and a composition that can improve the performance of the polymer decontamination agent, which contains one kind of anionic Surfactant system, an anionic surfactant-interactive decontamination _ and a decontamination zygosity enhanced 1 polyhydroxy fatty acid Kamine (PFA), of which: (I) 澸 洁 »combined Yang Zhi decontamination劂 予 阴 _Sub-interface speech_Interaction between anions_Interaction, can be confirmed by comparing the degree of decontamination_ (SRA) Shen Zhen in aqueous solution with hydrophobic male dimension (such as polyester) That means comparing between the following two, (/ U-item “control” operation, in which the deposition of SRA in an aqueous solution is measured in the presence of no other liquid cleansing ingredients (in the presence of ingredients, and (B) -item "SRA / Anionic Surfactant" "with trial operation, in which the pseudo The same type I and amount of anionic surfactant system used in the Zhijie composition is the same weight as the SRA in the aqueous solution, and the SRA is the same weight as the anionic interface active blue system of the Zhijie composition The ratio is combined, so (B) reduces the amount of sedimentation compared to (A), as shown by the interaction of anionic surfactants; and (II) does the detergent composition contain a decontamination_enhanced polyhydroxy fatty acid aldol It can be obtained by comparing (B) SRA / Anionic surfactant test operation of SRA Shen Zhen Jt, Yu (C) "SRA / Anionic interface active cutting / PFA test operation", and the detergent deposit is obtained, In the (C) test operation, change the same type of the composition and the polyhydroxy fatty acid sleep amine contained in the composition, and the decontamination and yin and male sex of the phase plaque in the SRA / anionic interface activity epilepsy test operation The surface activity is combined, and the improved deposition of detergent oranges in experimental operation (C) in experimental operation (B) indicates that there is a detergent-enhanced amount of polyhydroxy fatty acid aldehyde amine. For the purpose, Wait for test-39-(please read the precautions on the back before filling in this page) Binding-Order _ Line-This paper ruler * speed is in the B country #quasi (CNS) A 4 specifications (210x297 public address) Λ 6 13 6 ------- Fifth, the description of the invention (38) (please read the precautions on the back before writing this page). The test of the codling at the ionic interface activity is carried out under the following aqueous solution. * Di Liyu The anionic interface transition of the test operation (Α) is carried out at a B-cell concentration (CMC) in an aqueous solution, and is preferably supplied above about 100ρρ. The concentration of this polymerization «de-B» should be at least 15ρρ · . "Using a small piece of polyferrous iron cloth, as a hydrophobic metal. The same cloth was diffused in the 351C aqueous solution of the test operation and stirred for 12 minutes, then removed and analyzed. Polymerization decontamination _ sedimentation content can be shown by spraying and rubbing before decontamination "!, and then by radiochemical analysis, according to the technology known in this technology. An alternative method of the above radiochemical analysis method is to measure the ultraviolet nickel (UV) absorption of the solution to be measured according to the technique known in this technology, and to perform the above-mentioned test operations (meaning test operations A, B, In C), landing de-emetic agent Shen Zhen. After removing the water-based secondary-dimensional material, the reduced UV absorption in the waiting solution corresponds to increasing the amount of SRA. As the person familiar with this case knows, UV analysis should not be used on the types and contents of substances containing substances that can cause UV absorption interference, such as the interface activity Μ ( For example, alkylbenzene sulfonate, etc.). Printed by the β-Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Therefore, the “decontamination_enhancement amount” of polyhydroxy fatty acid amide, which you mean by this interface activity, will enhance decontamination _ in the above hydrophobicity Following the role of Shen Zhen in maintenance, or in the next cleaning operation. For fabrics washed in this cleaning »composition, the amount of enhanced oil / oil cleaning performance may be used. The amount of polyhydroxy fatty acid amide required for enhanced deposition is selected according to the selected anionic surfactant. The amount of anionic surfactant is -40. A4 specifications (210x297 g; ¢) Λ 6 B6 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention description (3g) S to be decontaminated, and selected polyhydroxy fatty acid amine And change. In general, about 0.01% to about 10% of lycopodium in the composition (the amount of sealant> polymer decontamination is typically about 0.1% to about 5%, and about 1% to about 50%, more typical The above is about 4% to about 30% anionic interface activity. Such a composition usually contains at least about 1%, preferably at least about 3% (by weight) of polyhydroxy fatty acid sugar amines, but does not want to give It must be limited to this. In the presence of anionic surfactants, polymerized detergents that enhance their performance with polyhydroxy fatty acid enzymes, Pseudo-Bao Tian has the following decontamination properties: (a) —or a variety of non-ionic The hydrophilic component is basically composed of the following fragments. (I) a polyoxyethylene group with a degree of polymerization of at least 2 or (Π) a gaseous ethyl group or a polymer with a degree of polymerization of 2 to 10 Gas propyl group H, where the hydrophilic group H does not include any gas propyl units, unless it is connected to the adjacent part by an ether link at each end, or Uii) contains gas ethyl groups and 1 A mixture of gas alkyl groups up to about 30M oxypropylene units, wherein the mixture contains sufficient gas ethyl units to render the hydrophilic The hydrophilicity is large enough to increase the hydrophobicity of conventional polyester synthetic surfaces to facilitate decontamination_deposition on such surfaces. The hydrophilic pH preferably includes at least about 25% * ethylidene Units, and more preferably (especially for this component), have about 20 to 30 gas propyl units, at least about 50% * ethyl units; or (b) —or multiple hydrophobic components, this hydrophobic component Including (i &gt; C3 oxyalkylene terephthalate Η cut, wherein the rose water component also includes squalene ethyl terephthalate, oxyethylene ethyl terephthalate: C3 gas The ratio of hypoalkylene terephthalate units is about 2: 1 or lower, -41-(please read the precautions on the back and then fill out this page) Dingben paper standard for the use of "national standards ( CNS) A 4 specifications (210x297 mm) Λ 6 Β6 Printed by Beigong Consumer Cooperation of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (40) (ii) C4-Ce subalkyl or gas C ^ Ce subalkyl Break, or a mixture thereof, (iii) poly (vinyl ester) Η eye, preferably poly. (Vinyl acetate), which has a degree of polymerization of at least 2, or an ether or C4 hydroxyalkyl W Substituent, or a mixture thereof, wherein the substituent is pseudo in the form of Ci-k alkyl_ or C4 hydroxyalkyl ether androstin derivative. Or a mixture thereof, and such secondary vitamin derivative is amphiphilic, Thus, it has a sufficient degree of Ci-Cj alkyl ether and / or C4 hydroxyalkyl_ units to deposit on the surface of the conventional polyester male dimension, and maintain a sufficient degree of hydroxyl groups, once adhered to such a conventional synthetic surface , You can increase the hydrophilicity of the fiber surface, or the combination of (a) and (b) Ο Typically, the poly-gaseous ethyl fragments of (a) (i) will have a degree of polymerization of 2 to about 200, but can be used The degree of separation is preferably 3 to about 150, more preferably 6 to about 100. The entangled gas C4-C6 alkyl alkyl hydride, including (but not limited to) the end of the polymer decontamination, such as M03S (CH2) "0CH2CHa0-, where Μ is nano, and η is an integer 4-6, For example, U.S. Patent No. 4,721,580 issued to Gosselink on January 26, 1988, and is incorporated herein by reference. Polymeric decontamination that can be used in the present invention includes cellulose derivatives, such as hydroxyether cellulose polymerized, terephthalic acid Copolymer block of ethylene glycol or propylene terephthalate with polyethylene oxide or polypropane terephthalate, and the like. Mineral derivatization derivative with decontamination function , Which is available from Fuma, and includes the hydroxyl group of fervain such as MethocelR (Do «>. Androsin detergent for use in this article, also includes those derived from alkyl and C4 hydroxyalkyl androstane, such as formic acid Quixon, ethyl androsion, hydroxypropyl-42-(please read the precautions on the back before filling in this page) Packed (This paper standard is the National Standard (CNS) A 4 specification (210X297 g * ) A 6 B6

^ OOdSS A, description of invention Co) (please read the precautions on the back before writing this page) methyl methylcellulose and hydroxybutyl methyl methoxine. It is available as a ferric derivative that can be used as a decontamination polymeric crocodile. You are shown in the Meituan patent 4,000,093 issued to Nicol et al. On December 28, 197, and is incorporated herein by reference. Take the hydrophobic segment of poly (vinyl ester) as a special detergent, including poly (vinyl ester) joint copolymer, such as Ci-Ce vinyl ester, preferably poly (vinyl acetate), via Branched on the polycyclic gasification olefin frame, such as the polycyclic gas ethane skeleton. Such objects are known in this technology and are described in the European Patent Application 0 219 048 filed by Kud et al. Published on April 22, 1987. Suitable commercially available detergents of this type include SokaUn-type substances, such as Sokalan HP-22, available from BASF (West Germany). Printed by the Employee Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs. A preferred decontamination type is a copolymer with random blocks of ethylene terephthalate and polyethylene oxide (PE0) terephthalate. More specifically, these polymerized materials are composed of ethylene terephthalate and PEO terephthalate units, and the ethylene terephthalate unit is PEE terephthalate. The unit has a ratio of about 25:75. To about 35:65. The PEO terephthalate military position contains polyoxyethylene with molecular weights of about 300 to about 2000. The molecular weight of the polymer decontamination is thin, ranging from about 25,000 to about 55,000. See Lang Lang, May 25, 1976, awarded to Hays Meipu Patent 3,959,230, and for reference in this article. Please also refer to the US Patent 3,893,929 issued on July 8, 1975 for 8333 &lt; ^ »* (and is hereby incorporated by reference), in which Li Xi shows a similar article. Another good polymer decontamination "I is a polyester with repeated terephthalate positions of ethylene terephthalate, which contains 10-15 weight percent ethylene terephthalate units, and 90-80 weight"% poly Oxyethylidene terephthalate, derived from Ping-43-This paper scale is used in China National Standards (CNS) A 4 specifications (210x297 mm) ^ 〇〇o〇6 Λ 6 13 6 Economy Printed by the Employees ’Cooperative of the Central Bureau of Standards of the Ministry 5. Description of inventions (42) The average molecular weight is 300-5,000 polyoxyethylene glyoxylate, and in this polymerization compound, the ethylene terephthalate unit is polyoxymethylene ethyl The ratio of ten thousand terephthalate units is like 2: 1 and 6: 1. Examples of this polymeric crocodile include commercially available materials ZELCOH 5126 (available from DuPont) and MILEASE T (available from 1C I). These polymerization methods and their splitting methods are more fully described in the US Patent No. 4,702,857 issued on October 27, 1987 to 0336361, and are incorporated herein by reference. Another preferred polymer "detergent is a sulfonated product of a substantially linear ester oligomer, whose pseudo-weight unit is the oligomeric ester backbone of the unit after heavy weight of terephthaloyl and gaseous alkoxy groups. Composed of the last part of the skeleton, the decontamination is derived from allylic acid acetylate, dimethyl aphthalate and 1,2-propanediol, wherein after sulfonation, each oligomer The terminal part of the object has an average gold part of about 1 to about 4 sulfonic acid groups. These decontamination procedures are fully described in U.S. Patent 4,968,451 issued to JJ Scheibe and EP Gosse-link on November 6, 1990, and U.S. Patent Application Serial No. 07 / 474,709 filed on January 29, 1990 , And for reference in this article. C Other suitable polymeric decontaminants, including ethyl- or methyl-terminated 1,2-propylene terephthalate-polygaseous ethyl terephthalate polyester , US Patent 4,711,730 issued by Gosselink et al. On December 8, 1987; U.S. Patent 4,721,580 issued to Gosselink on January 26, 1988, in which the capillary end of Sickle contains Sulfonate-polyethoxy group of PEG; block polyester oligomeric compound of US Patent 4,702,857 issued to Gosselink on October 27, 1987, which has the formula X- (0CH2CH2) n-polyethylene Oxygen-terminated, where η is from 12 to about 43, den • 44-(please read the precautions on page f before filling in this page) This paper is used in the Chinese National Standard (CNS) A4 specification (210x297 Kg) 〉 100538 Λ 6 Β6 The Ministry of Economic Affairs, Central Standards Bureau, Beigong Consumer Co., Ltd. Du Printed V. Description of Invention) The father is (: 1- (: 4 alkyl, Methyl is preferred, and these patents are all incorporated herein by reference. ♦ Other polymer decontamination agents, including the decontamination fll of 4,877,896, which was granted to Mel Donado et al. On October 31, 1989. , Especially sulfonated aryl aryl group, sealed terephthalate, which is also incorporated herein by reference. This terephthalic acid phthalate contains an asymmetrically substituted gas-1,2-hypoalkyl group Units. The decontamination polymer contained in Misakiri 4,877,896 is assumed to have a polyethylenic ethyl hydrophilic component or the above-mentioned (b) U &gt; hydrophobic component of C3 chlorinated alkyl parabens (for Propylenediphthalate_> Substance of the unit after weight. One or both of these standards are the emblems of this polymerized decontamination _, which can be separated in the presence of anionic interface activity due to the addition of polyhydroxyl Fatty acid lipidamine is beneficial. If decontamination is used, it usually accounts for about 0.01% to about 10.0% of the weight of the cleaning composition here, typically about 0.1% to about 5%, preferably about 0.2 % To about 3.0%. The combined cleansing agent composition of this article can also optionally contain one or more male or manganese chelate The joint surface is used as an auxiliary substance for washing. This kind of chelate can include amino carboxylates, amino phosphonates, polyfunctionally substituted aromatic chelating agents and mixtures thereof, as described later Definition. Without wishing to be bound by theory, I believe that the benefits of these substances are partly due to the formation of soluble chelates I, and the ability to remove iron and plug ions from the washing solution. The amine carboxylate which can be used as a chelating agent for S in the composition of the present invention may have one or more, preferably at least two of the following structural units: -45-(Please read the precautions first塡 write this page) -installed-ordered 'This paper size 4 is used in "National Sample Standard (CNS) A 4 specifications (210x297 g; t) ^ 00528 V. Invention description (44) Λ 6 13 6 Central Bureau of Standards of the Ministry of Economic Affairs Beigong Consumer Cooperative printed CH2 \ N-(CH,) X-COQM, where M is hydrogen, gold test plaque, amine or substituted (for example, ethanolamine). And x is 1 to about 3, preferably 1. These amine carboxylates preferably do not contain alkyl or alkenyl groups with more than about 6 large atoms. Amine carboxylates, including ethylenediamine tetraacetate, hydroxyethylethylenediamine trisalt, nitrogen triacetate, ethylenediamine tetrapropionate, triethylenetetramine hexaacetate, diethyl Triamine pentaacetate, and ethanol diglycolic acid. Its glory metal. Ammonium and substituted technical salt, and mixtures thereof. When at least a low level of total phosphorus is allowed in the detergent composition, ketoacid is also suitable for use as a gadolinium in the composition of the present invention. Compounds having one or more, preferably at least two of the following structural units CH *, N (CH2) x P0jM2, where M is hydrogen, metal, ammonium or substituted ammonium, and x is from 1 to about 3 , Preferably 1, and includes ethanedisulfonate> Yitian # (methylene phosphonate) and diethylenetriamine (methylene phosphonate). These amino succinates preferably do not contain alkyl or alkenyl groups having about β sulfonic atoms. ： Aromatic compounds that can be substituted by several functional groups with multiple functional groups, and can also be used in the compound of this article. These compounds may include the compound with the general formula 0H 0H RR- 46-

The standard of this paper is "Chinese Family Standard (CNS) A4 Specification (210X297) *) • 1 (Please read the precautions on the back before filling in. This page)

^ 00536 V. Description of invention k) Λ 6 Β6 Printed by the Employee Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs. Among them, at least one prepared R is -S03H or -C00H or soluble salts of haemaphora, and mixtures thereof. U.S. Patent 3,812,044 (contained herein by reference) issued to Connor et al. On May 21, 1974. Li shows polyfunctionally substituted aromatic chelating and sequestering agents. The preferred compound of this type in acid form is dihydroxydi «acylbenzene, such as 1,2-dihydroxy-3,5-disulfonylbenzene. Age-related detergent compositions may contain these substances in the form of their metal, ammonium or substituted (eg, tri- or triethanol) salts. If such a chelating agent is used, it usually accounts for about 0.1% to about 10% of the reset of the cleaning composition here. The chelating agent is more preferably about 0.1% to about 3.0% by weight of the composition. Sticky dirt removal / scratch-up and sinking of kiwi The composition of the present invention can also optionally contain water-soluble ethylamine-based amines with clay dirt removal and anti-redeposition properties: containing these! The granular detergent composition of heptahydrate typically contains about 0.01% to about 10.0% &lt; weight ratio) water-capacitive ethoxylated amine; the liquid detergent progenitor typically contains about 0.01% to about 5%. Preferred combinations of these compounds are selected from: (1) Ethoxylated monoamines having the following formula: (XL-)-N- (Ra) a (2 &gt; Ethylation double presses having the following formula: R2-N-R1-NR * (R *) aN-Ri-N- (R *) j LL i.IIIXXX or (XL-) 2-N-Rl-N- (R2) 2 -47-(please first Read the precautions on the back and then fill out this page) This paper scale is in accordance with the Chinese National Standard (CNS) A 4 specifications (210x297 g *) 1 ^ 00536 Λ 6 Β6 Printed by Beigongxiaot Cooperative, Central Bureau of Standards, Ministry of Economic Affairs (Milk) (3) Xingyi polyamines with the following formula: r R3-[(Al) q '(R4) tNLX] p (4) Ethyl chloride amine polymerization protector with the following general formula: R * [(RiJj-NJwER'-NJxE ^ -NJyER ^ NL-XJz LIX and (5) mixtures thereof; wherein A 1 is 〇〇〇〇〇〇η ο »ιι &gt; &lt; -NC-, -NC0-,- NCN-, -CN-, -0CN-, RRRRR k 〇ο Ο 0 0 It I η η,》 -C0-, -OCO-, -0C-, -CNC *, R or R is [1 or (: 1 -〇4 alkyl or hydroxyalkyl; R1 is Ca-C12 ^ alkyl, hydroxy sulfide S, sub-feed $ · sulfydyl or sub-alkyl aryl group. Or 罠 has 2 to about 20 qi gas alkyl group units The C2-C3 oxyalkylene moiety, provided that no O-M bond is formed; each 2 Is (^-(: 4 or hydroxyalkyl, -LX part, or two-pitch R2 together form-(CH2) r. -A2- (CH2) s- part, where A2 is -〇- or -CH2 -, r ^ l or 2, s is 1 or 2, and r + s is 3 or 4; X is a non-ionic radical, anionic group or a mixture thereof; R3 is a substituted C3_Cl2 courtyard group, Xiangyuan group, Alkenyl, aryl, or alkaryl having a substituted position; R4 is Cl-C 12 alkylene, hydroxyalkylene, alkylene, alkylene, or secondary aryl, or has 2 to about 2 0 An oxygen secondary embankment, "C 2-C a oxygen secondary base part of the position" and its condition -48 &quot; (please read the precautions on the back before filling in. This page). Install. • Order. Line · This paper Du Xiao Yong Zhong® National Standard (CNS) Grade 4 (210 &gt; &lt; 297mm) Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Λ 6 ___ Β6_ V. Description of invention (47) is not formed 0-0 Or 0-Ν bonding; L is a hydrophilic chain. It contains a polyoxyalkylene moiety-[(Rs〇) »(CH2CH2〇> n]-, RBac3-C4 alkyl or hydroxyalkylene Radicals, and η is such that _ (CH2CH20) n- accounts for at least about 50% of the weight of the polychlorinated alkyl moiety; for the monoamine , "Is 0 to about 4, and η is at least about 12; for the diamine • from 0 to about 3, and η is at least about 6, then R1 is C2-C3 alkyl, hydroxy alkyl , Or alkenyl; and at least about 3, then R1 is not C2-C3 alkyl, hydroxyalkyl or hypoalkenyl; for the polyamine and amine polymer, m is 0 to about 10 , And η is at least about 3; ρ is 3 to 3; s is 1 or 0; t is 1 or 0; the condition is that when 8 is 1, then t is 1; w is 1 or 0; x + y + z Is at least 2; and y + z is at least 2. The best decontamination and anti-redeposition agent is tetraethylpentamine which is ethylated. Examples of ethoxylated amines are further described in U.S. Patent 4,597,898 issued to VanderMeer on July 1, 1986, and are incorporated herein by reference. S-group preferred clay; the loss-in-material transfer / resistance to re-settling is split into a cationic compound, and its removal is shown in the announcement on June 27, 1984, European Patent Application 111, 965 of Oh and Gosselink This article is for reference. Other clay soil removal / anti-resettling agents that can be used, including ethoxylated amine polymers, the pseudo-announcement of which is shown in the announcement on June 27, 1984, Gossel ink's Pizhou patent application 111,984; zwitterion Polymer Nail, whose 傜 was revealed in the announcement on July 4, 1984, Gos · sel〗 〖European patent application 112,592; and the amine "chemical, its pseudo-announcement was shown on October 22, 1985, US Patent 4,548 issued to Connor, 7 44, are incorporated in this article for reference. Other clay soil removal and / or anti-redeposition sediments known in this technology can also be used in this composition. Another type of better anti-redeposition agent, -49-(please read the precautions on the back before filling in this page). This paper is in accordance with China National Standard (CNS) Grade 4 (210x297 mm). Employee consumption cooperation du printing

ijooo ^ aΛ 6 ____B6_. Fifth, the description of the invention (gu) encapsulates the carboxymethyl ferricin (CMC) substance. These substances are familiar to those skilled in the art. . Polymerized ytterbium sub-projections Polymerized dispersants can be advantageously used in this composition. These substances can help control the hardness of rib calcium and magnesium. Appropriate polymerization of crocodile agent, including polycarboxylate diffused polyethylene glycol, but other substances known in this technology can also be used. Although not wishing to be bound by theory, it is generally believed that when the polymer dispersion is combined with other rib washers (including lower molecular weight polycarboxylates), the pseudo-grain is produced by crystal growth Decontamination and dissolution can resist redeposition, and strengthen the cleaning performance of rib cleaning agent. The polycarboxylate substance that can be used as a polymer sub-agent in this case is a polymeric compound or copolymer containing at least about 60% by weight of the following general formula fragment — XZ (please read the back: Ma Yi Matters and then fill in This page) Binding-Binding-Y C00M tmm η where X, Υ, and Z each include hydrogen, methyl, carboxy, carboxymethyl, carboxy, and carboxymethyl; a salt-forming cation, and η is about 30 to about 400. Preferably, X is S or hydroxyl, Y is hydrogen or carboxyl, Z is S. And M is radium, "gold bromide, ammonium or substituted ammonium :. This type of polymerizable polycarboxylate material can be It is made by the polymerization or copolymerization of Shifuweirun and monohydrate (preferably m in its acid form): unsaturated monohydrate that can be polymerized to form a suitable polymerizable polycarboxylate salt, including propylene and horse Acetic acid (or maleic anhydride), fumaric acid, decomposed aconitic acid, aconitic acid. A-50-This paper scale is used in China's sleepy standard (CNS) A4 specifications (210X297 g *) Central Bureau of Standards Printed by employee consumer cooperatives 20052S Λβ _Ββ_ V. Description of the invention (θ-based fumaric acid, methyl maleic acid and methylene malonic acid. Monoamines without carboxylic acid groups, such as vinyl A-ether, styrene, ethylene, etc., suitable for the polymerizable polycarboxylic acid present here, the coating is that such Η break will not constitute an excess of about 40% by weight. To be suitable polymerizable polycarboxylate Acid salt, which can be derived from acrylic acid. It can be used for the polymerization of acrylic strips here, and it is a water-soluble salt of polymerized acrylic acid. Acidic polymerized mule. Its average molecular weight is preferably from about 2,000 to 10,000, more preferably from about 4,000 to 7,000, and most preferably from about 4,000 to 5,000. The water-soluble salts of such acrylic acid polymerized mules may include, for example, sickle gold "Yi, ammonium and substituted ammonium". This type of soluble polymer is a known substance. The use of this type of polyacrylate in detergent compositions has been shown, for example, on March 7, 1967, by the Diehl patent 3,308,067. This patent is incorporated herein by reference. It can also be used as a preferred component of dispersant / anti-redeposition agent for acrylic / maleic strip copolymers. Such substances include water soluble acrylic acid and maleic copolymers. The acidic copolymer has an average molecular weight of about 2,000 to 100,000, more preferably about 5,000 to 75,000, and most preferably about 7,000 to 65,000. In this copolymer, acrylate The ratio of maleic acid H is generally about 30: 1 to about 1: 1, more preferably about 10: 1 to 2: 1. Such water-soluble salts of acrylic acid / maleic acid copolymers may include, for example Its _ Jin Yi, ammonium and substituted ammonium ". This type of soluble Acrylate / maleate copolymers are known, and their description is described in the Xizhou Patent Application 66915 published on December 15, 1982, which is incorporated herein by reference. -51 _ (please first Read the precautions on the back and then fill out this page) The size of this paper is printed in China (CNS) Standard 4 (210x297 g *). Printed by the Employees Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. ) Included is B-a kind of polymeric mule substance, which is polyethylene glycol (PEG). PEG can show the performance of dispersant, and can be used as clay soil removal / anti-redeposition agent. A typical molecular weight range for these purposes is from about 500 to about 100,000, preferably from about 1,000 to about 50,000, and more preferably from about 1,500 to about 10.000. Any optical brightener or other known on the white surface technology Zeng® or whitening agent can be incorporated into the detergent composition here. The whitening agent for use in the cleaning agent composition depends on many factors, such as the type of cleaning agent, the properties of other ingredients present in the cleaning agent composition, and the cleanliness of the washing water , "The degree of mixing, and the ratio of the washed material to the size of the eaves barrel. The selection of whitening _ also depends on the type of materials to be washed, such as plumbing products, synthetic materials, etc. Since most laundry cleaning products are used to clean a variety of irons, the cleaning period composition should contain a mixture of brighteners, which will be effective against a variety of suspects. The distillate components of such a brightener mixture must of course be compatible. The commercially available optical brighteners that can be used in the present invention can be classified into several subfamilies, including (but not necessarily limited to) &gt; derivatives of the following substances, stilbene, pyrazoline, lavenderin , Carboxylic acid, methine, diphenylpyrrolidine-5,5-dioxide, azoles, 5- and 6-membered compounds, and other miscellaneous tests such as whitening examples, pseudo-indicated In "Manufacture and Use of Fluorescent Brighteners", M. Zahradnik, sold by John Wiley & Sons, contract (1982), the content of which is shown and is for reference in this article. -52 _ Λ 6 Β6 (please (Read the precautions on the back before writing this page) This paper uses the Chinese BB Standard (CNS) A 4 specifications (210x297 mm) -005¾ ^ Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy Λ 6 _____ Β6__ V. Invention Description (51) The stilbene derivatives that can be used in the present invention, including (but not necessarily limited to) bis (tri «tyl) amino-stilbene, derivatives: bis-stilbene amine Derivatives; tricyanazole derivatives of stilbene; oxadiazole derivatives of diphenylethyl; oxazole derivatives of stilbene And styrene derivatives of diphenyl ethyl. Some bis (tricyanato) amino stilbene derivatives that can be used in the present invention can be prepared from 4,4 · -diamine stilbene- 2,2'-dioic acid. Chlorophyllin derivatives that can be used in the present invention include (but are not necessarily limited to) at its 3-position, at its 7-position, and at its 3- and 7 -Derivatives substituted in position. Carboxylic acid derivatives that can be used in the present invention include (but are not necessarily limited to) fumaric acid derivatives; benzoic acid derivatives; p-phenylene-bis-acrylic acid derivatives; Naphthalene bis · acid derivatives: succinic acid derivatives; and cinnamic acid derivatives Derivatives, styryl «azole, styryl benzofuran, styryl" di «azole, styryl tricyanazole, and styryl polyphenyl substances, for example on page 77 of the Zahradnik reference As shown. Styryl "azole can be further subdivided into styryl phenoxazole, styryl imidazole and styrene Kepazole. As shown on page 78 of the Zahradnik reference material. It should be understood that these three confirmed subclasses may not necessarily reflect the unimpeded * learning of subclasses where styrene can be reclassified. Single. It can be used for another type of optical whitening and thinning of the present invention (for Kirk-nth-flrhua-53-(please read the back of the back of the first page and then the page 1). Standard (CNS) T4 specification (210X297 g *) Λ 6 13 6 Printed by the Employee Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs V. Invention Instructions (52) Zhaoji tf? S Μ Bamboo Shoots Volume 3, 737-750 Page (John tfi ley &amp; Son, 1962) on page 74 bu 749, the dibenzoxanthene-5, «5-dioxide derivatives, the contents of which are shown and are incorporated herein by reference, It also includes 3,7-diaminodiphenothiazine-2,8-disulfonic acid 5,5-digas. Class 3 optical brighteners that can be used in the present invention include azoles, which are derivatives of 5-membered heterocycles. It can be further categorized as monozole and dicyandiazole. The examples of monocyanidazole and dicyandiazole are shown in the Kirk-Oth.er reference material. The S-type optical brighteners that can be used in the present invention are 6-Beizhuo_zhuo derivatives shown in Kirk-Qthaer reference materials. Examples of such compounds include whitening JW derived from pigen, and 4-aminocyanamide. In addition to the whitening agents already described, miscellaneous agents can also be used as whitening agents. Examples of such miscellaneous tests are shown on pages 93-95 of Zahrdn 丨 k reference materials, and include hydroxy-3,6,3-suntrisulfonic acid; 2,4-dimethylamino-1 , 3,5-Tri «Geng-6-yl-Sun; 4,5-diphenyl quinazolone-disulfonic acid; and pyrazoline-« Porphyrin, which can be used in other optical whitening systems of the present invention_ For example, Su is identified in US Patent 4,790,856 issued to Wixon on December 13, 1988, the contents of which are shown and incorporated herein by reference. Such whitening _ includes PH0RWHITE Shito whitening from Verona _. Other whitenings shown in this reference include: Tinopal UHPA, Tinopal CBS and Tinopal 5BM, available from C ί ba-G eigy; Arctic W hite CC and Artic W h ί te CWD, available from Hilton- Davis, located in Italy; 2- (4-styryl-phenyl) -2H-naphthalene [l, 2-d] triazole; 4,4 · -wen- (l, 2,3-three Azole- -54-This paper scale is printed in China B Family Standard (CNS) A4 specifications (210x297 gong) Printed by the Ministry of Economy Central Standards Bureau Beigong Consumer Cooperative Society £ 005SS Aft Λ 6 _ _ B6_ V. Description of invention ( 53) 2-yl &gt;-stilbene; 4,4 · -bis (styrene) bisphenyl; and y-amino lavenderin. Examples of special treatments for these whitening agents Yl-7-diethylamino lavender; 1,2-bis (phenylpyrazol-2-yl) ethylene; 1,3-dibenzyl oxazoline (? 111 * 32〇146); 2 , 5-bis (phenylpyridazol-2-yl> thiophene; 2-styryl-ammonium [l, 2-d] Pfazole; and 2- (stilbene-4-yl) -2H- Naphthalene [1,2-d] tricyanazole. It can be used in other optical whitening schemes of the present invention, including U.S. Patent No. 3,646,015, issued to HaniUon on February 29, 1972, the contents of which are shown in this document. For reference. Dip-in-oil dip can be used to reduce or suppress the formation of known or turned into known compounds into the composition of the present invention. Incorporate this substance (hereinafter referred to as "foam inhibitor" "> Nuo is expected, because the polyhydroxy fatty acid licking surfactant can increase the foam stability of the thin cleaning composition. When the cleaning cocoon composition contains a relatively foaming interface When the activity is combined with polyhydroxy fatty acid amide surfactants, foam suppression may be of special importance. Foam suppression »is particularly intended to be used in compositions intended for use in front-loading automatic laundry eaves. The typical feature is that it has a drum to contain the washing clothes and washing water, which has a rotating effect of rotating the car and the ring. This 81-mixing form can form the foam and reduce it. The cleaning performance. Under hot water washing conditions and high interfacial activity under two degrees of temperature, the use of foam suppression padding may also be of special importance. You can use a wide variety of substances in this composition霣, as a foam suppressor -55 _ (please read the precautions on the back before filling in this page) Loading · The size of this paper is universal Chinese National Standards (CNS) A 4 specifications (210x297 mm) Λ 6 Β6 Employees of Central Bureau of Standards, Ministry of Economic Affairs Printed by the consumer cooperative V. Description of invention (54) Two. Foam inhibitors are known to artists familiar with this art. It is generally described in, for example, Kirk Othier's Encyclopedia of Chemical Technology, Third Vendor, Volume 7 «, pages 430-447 (John Wiley & Sons, 1979). A particularly interesting and interesting foam-suppressing buccal genus includes monocarboxylic fatty acids and soluble salts. These materials are for reference in the U.S. Patent 2,954.347 issued to Vayne St. John on September 27, 1960, which is false and incorporated herein by reference. The monocarboxy fatty acids and their salts used for both foam suppression are typically replaced with hydrocarbon chains having 10 to about 24 sulfon atoms, preferably 12 to 18 sap atoms. Salts include their metal salts, such as sodium, potassium, and lithium salts, and ammonium and alkanoammonium salts. These qualities are a preferred category of foam inhibitors for use in the composition. The cleaning composition may also contain non-interface active foam inhibitors. It includes, for example, the following: high molecular weights, such as lizard smoke and halogenated lizards, fatty acid esters (such as fatty triglycerides), fatty alcohol esters of military alcohols, aliphatic cie-c40 ketones (such as stearin Ketone) etc. Other suds suppressors, including N-alkylated cyanamide, such as tri- to hexa-alkyl melamine or di- to tetra-alkyl diamine cyanogen A product of the first or second amine containing 1 to 24 fistula atoms, oxypropylene, and monostearyl phosphate, such as monostearyl phosphate (such as mono Stearyl di-sickle metal (eg K, Na, Li) discoate and monostearyl di-M gold intestine (eg K, Na, Li) eel phosphate. This type of cigarettes, such as stone pan «and halogen-based paraffins, can be used in liquid form. This liquid rancid, like liquid mule at room temperature and atmospheric pressure, has a pour point in the range of about -40t and about, and the minimum boiling point is -56-(please read the precautions on the back first (This page is written on this page.) This paper uses the Chinese SB Standard (CNS) A4 specification (210X297 g *). Σ〇03 Zhan Λ 6 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of Invention (55) Below about 1101C (atmospheric pressure). It is also known that the worm-like shape can be used, preferably having a melting point of less than about 100C. This type of Dai constitutes a preferred type of foam suppressing thinner for cleaning thin compositions. ) S foam suppression, for example, described in US Patent 4,265,779 issued to Gando If 〇 et al. On May 5, 1981, and is incorporated herein by reference. Therefore, this category includes aliphatic, aliphatic, aromatic, heterocyclic, and unsaturated hydrocarbons with a value of about 12 to about 70 atoms. As used in the discussion of suds suppressors, the term "stone smoke" is intended to include the combination of true paraffinic hydrocarbons and xenomorphic hydrocarbons. Another preferred non-interface active rhesus foam inhibitor »is like a sock, which includes a silicone foam inhibitor. This type of compound includes the use of polyorganosiloxane oils, such as polydimethylsilane, polysilicone oils or resin dispersions or emulsions, and the combined use of polyorganosiloxanes and silica Particles, in which polyorganosiloxanes are chemically adsorbed or fused on silica. Silicone Foam Suppression_ As is known in this technology, the pseudo-announcement is shown in, for example, U.S. Patent 4,265,779 issued to Gando If 〇 et al. On May 5, 1981, and the announcement on February 7, 1990 , European Patent Application No. 89307851.9 issued to Starch, MS, both benefits are incorporated herein for reference. Other silicone foam inhibitors are shown in U.S. Patent 3,455,839, which is a composition and method for adding a small amount of polydimethylsiloxane stream to defoam an aqueous solution. A mixture of silicone and silanized silica is described in, for example, the German Patent Application DOS 2,124,526. The silicone defoaming and foam control cocoons in the granular granular detergent composition are shown in Bartolotta et al. Meituan Patent 3,933,672, and issued on March 24, 1987 to 831 * 1; 〇1〇1 ^ 3The beauty of others-57-(Please read the notes on the back of the performance first and then fill out this page)-Binding · Order ·-Line · This paper standard is universal Chinese a standard (CNS) A 4 specifications (210x297 mm), 〇0〇δ * δ Λ 6 B6 V. Description of the invention (56) Among the 3,933,672 patents printed by the National Consumer Standardization Bureau of the Ministry of Economic Affairs of the Ministry of Economy, and 4,652,392 issued by Bag inski and others on March 24, 1987. «An example of a silicone foam inhibitor for use herein is a foam control agent with a foam suppression amount, which basically includes: (i) polydimethylsilicone having a viscosity of about 20 cs to about 1500 cs at 25 = Gas ane flow; (ii) For every 100 parts by weight of (i), about 5 to about 50 parts of silane resin, this resin is composed of (CH3> 3Si01 / iS unit and Si〇2 unit, where ( The ratio of CHaUSiCKi units to Si02 units, from about 0.6: 1 to about 1.2: 1; and (Hi) per 100 parts by weight of (i), about 1 to about 20 parts of solid silicon syrup; for use in automatic washing machines For any cleaning agent composition, the foam should not form to the extent that it overflows out of the washing machine. The foam inhibitor, when used, is preferably pretended to be "foam suppression set". "Foam suppression amount" is confounded. The formulator of this composition can choose a certain amount of such foam control agent, which is enough to control the foam, so as to cause low foaming laundry detergent. For use in automatic washing machines. This foam control amount, For the change of the active interface between the two interfaces of the Jie Jie, as for example, the use of high foaming It has a thinner interfacial activity, which is relatively thinner than the one that uses less foaming and uses relatively more foam control to achieve the desired foam control effect. In general, you should add foot boy to the low foaming composition The foam suppresses the stroke, so that the foam formed during the washing process of the automatic washing machine (under the condition of the cleanness of the minnow and the degree of sag of the intended purpose, it is cleaned _ in the aqueous solution * accompanied by), does not exceed the inclusion of the washing machine About 75% of the drums are empty except for the vines, and the bubble is preferably not more than that. -58-η Read the notes on the back first and then fill in * write this page to install π line paper paper standard B a family standard (CNS ) A4 specifications (210X297 mm) V. Description of invention (59) Λ 6 Β6 The Ministry of Economic Affairs, Central Standards Bureau employee elimination cooperative printed this tribute image to illustrate an example for the use of this article, bu methyl, 1-degassed hydride Preparation method of tallowyl laurylamine surfactant. Although a skilled chemist can change the structure of the device, a suitable device for use in this article includes a three-liter four-necked flask with a horse-driving prize * Mixer and length A thermometer sufficient to contact the anti-codbite medium. The other two necks of this burner are equipped with a value of "airborne removal tube, and a wide hole side" (Note: In the case of extremely rapid release of formazan, ¾ hole The side arm is very important). This side arm is connected to a condensate tube and a vacuum outlet tube that are effectively collected. The latter is connected to a cyanide gas outlet tube and a vacuum gauge, and then connected to an aspirator and a gas collector. Place a 500-watt to-be-heated army (which has a variable transformer temperature controller (&quot; Variac ”) to heat the reaction on a americium experimental crane so that it can rise up or Decrease to further control the reverse® temperature, combine N-methyl »glycosamine (195 g, 1.0 mol, Aldrich, M4700-0) and methyl laurate (Procter & Gamble CE 1270, 220.9 g, 1.0 Ears), placed in a beaker. Under «air sweeping, the solid / liquid mixture is heated and stirred to form a melt (about 25 minutes furnace). When the temperature of this melt reached 14510, a catalyst (anhydrous powdered sodium silicate, 10.5 g, 0.1 mol, J. T. Baker) was added. Sweep off the cyan gas, adjust the aspirator and nitrogen outflow tube, and get 5 inches (5/31 atmospheric pressure) Hg vacuum. From this point on, the temperature of the anti-hybrid is kept below 150 ° by adjusting Variac and / or by raising or lowering the heating mantle. Within 7 minutes of sickle, first see A-61 at the liquid level of the anti-mixture-(please read the unfilled items on the back and then fill out this page) -_ Standard (CNS) A 4 specifications (210X297) «6 Β6 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (57) About 50% of Chen Qianzhen, of which the empty suspects are supplied by the inclusive drum The total difference between the round of 縹 縹 and the water plus the clothing of Luo Zhen, the difference between the two. This composition usually contains from 0% to about 5% of suds suppressor. When monocarboxylic fatty acids and their salts are used as suds suppressors, they are typically present, as high as about 5% by weight of the composition. Preferably, about 0.5% to about 3% fatty monocarboxylate foam inhibitors are pseudo-used. Silicone sleep inhibitors are typically used until they are about 2.0% by weight of the detergent composition, but higher amounts can be used. This upper limit is practical, mainly because it is related to keeping costs to a minimum and the effectiveness of effectively controlling the lower amount of foaming. Preferably, about 0.01 to about 1% silicone foam inhibitor is used, and more preferably about 0.25% to about 0.5%. When used in this article, these weight percent values, nickel include any silica that can be used in combination with polyorganosiloxane, and additives that can be used. Monostearyl phosphate, usually used Fan Fanyuan is about 0.1% to about 2% by weight of the composition. Hydrocarbon foam inhibitors, the typical dosage range is about 0.01% to about 5.0%, but can be used in a better degree. A large variety of other ingredients that can be used in the detergent composition can be included in the composition here, including other active ingredients, carrier, water-soluble solubilizer, processing ribs, dyes or pigments, liquid supply "Solutions for recipes, etc." The liquid detergent composition may contain water and other solvents as a carrier. Take low-molecular-weight primary or secondary enzymes, such as formazan, ethylenzyme, propanol and isopropanol, for example. Monohydroxylase is preferred for dissolving surfactants, but polyhydric enzymes can also be used, for example, containing 2 to about 6 atoms and 2 to about 6 hydroxyl groups-5 9 _ (please read the notes on the back first (Fill in this page again) --- Binding-Ordering-This paper standard is used in the aa family standard (CNS) A4 specifications (210x297 mm) too miscellaneous V. Invention description (58) (such as malonan, ethane Leaven, glycerin and 1,2-propanediol). The cleansing composition is preferably prepared for use so that during use in water-based cleaning, the washed wood has a pH between about 6.5 and about 11, preferably between about 7.5 and about 10.5 . The liquid product formulation preferably has a pH between about 7.5 and about 9.5. Even better is between about 7.5 and 9.0. The techniques used to control the pH at the level of use of Jianbin include the use of retarders, _sexual substances, acids, etc., and they are well-known to those who are familiar with this plan. The present invention further provides a method for improving the performance of a cleaning agent containing anionic, nonionic, and / or cationic interface activity_ and a cleansing enzyme by using an amount of the above-mentioned polyhydroxy fatty acid in which the enzyme performance is enhanced The amine interface activity Μ is typically at least about 1%. The present invention further provides the basis for printing (such as Jiwei, iron, hard surface, printed by the Central Standard Bureau of the Ministry of Economic Affairs, Bei Gong Xiao # Cooperative Society)

η Read first, read the precautions before writing-I, Pilu, etc.), the method is to make the matrix with a cleaning enzyme and one or more anionic, nonionic or cationic surfactants The cleaning composition is suspected, in which the cleaning agent composition contains an enzymatically enhanced amount of polyhydroxy fatty acid amide, typically at least about 1% of the composition reset, in the presence of dissolved I, such as water or water It is miscible and miscible (for example, primary and secondary yeast). It is best to provide mixing to enhance the cleaning effect. Provide «mixing methods, including hand rubbing, or preferably using brushes, sea brushes, cloths, mops or other cleaning devices, automatic washing machines, automatic dishwashers, etc. 60-This paper scale is printed in China National Standards (CNS) Grade 4 (210x297 gongs) by the Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs A 6 B6 V. Description of invention (60). The fierce reaction took place in the Lifan residence. "Steaming" leaves formazan until its rate subsides. It was completely emptied to a vacuum of about 10 inches Hg (, 10/31 atm). Roughly increase the vacuum (in inches Hg / minute) as follows: 10/3, 20/7, 25/10. 11 minutes after the release of formazan, the heating and stirring were stopped, and some foam was generated at this time. Cold and solidify this product. The following examples are intended to illustrate the composition of the present invention, but are not intended to limit or otherwise define the scope of the invention, which is based on the application patent garden described below.

Fen Li T-TTT These examples pseudo-describe the potent type Gu Liangjie thin composition containing polyhydroxy fatty acid aldamine and protein W:% Taimian Granules T II III Cl4-lS cinnamyl alkyl ethanoate Gasification (2.25) N-methyl N-1-deoxyglycosyl sulfate 16.9 16.9 16.9 cocoaamide 5.6 5.6 5.6 zeolite A 30.1 18.8 18.8 citrate reed 11.3 11.3 sodium silicate 16.9 16.9 16.9 silicic acid pin 5.6 5.6 5.6 Sulphuric acid sales 15.1 15.1 15.1 Polyacrylic acid sodium (4500MW) 1. 1 1.1 1.1 Polyglyphine (8000MW) 1.1 62-1.1 1.1 This paper scale is used in a family standard (CNS) A4 specification (210X297 Cli) (Please read the unintentional matters on the back before filling in this page) Pack. Order-Λ 6 Β6 V. Description of the invention (61) Tallow fatty acid whitening cream will be applied to its h protease fragrance Cm 3 alkyl Ethyl compounds (6.5 fruit ears) Water and miscellaneous substances 0. 0.2 0.9 0.9 3. (Please read the precautions on the back before writing this page) The example printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is based on basic _ copies And the following rust spraying is made of the following _ prednisone N-methyl cocoa C 1 2-1 C 1 4- 1 100.0 100.0 Bu III is a formula that preferably uses about 1400PP. It is washed for use at temperatures below about 50TC. In the above example, the granular components are combined into a slurry, which is sprayed thinly to about 4-8%. The remaining dry ingredients are mixed in the form of granules or powder. The granules are mixed in a rotating mixing drum, and then the liquid surfactant and perfume are swept on it. The example of TV-TX shows the composition containing polyhydroxy fatty acid amide and protease. rv V N-1-deoxyglycosol 'glycosyl group 10,0 5.5 amine amine • alkyl ethyl chloride compound (6.5 mol) 15. ί alkyl ethoxy group (2,25> eluyl sulfate-63 ~ 17.0 100.0 Water reset by using this residual water, with meridian ingredients and starch

JLL 2.5 17.0 Pack _ This paper is printed in accordance with China National Standard (CNS) Grade 4 (210x297 gongs). Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^ OOoS ^ Λ6 _B6 V. Description of the invention (62) C12-14 Fatty acid 3.0 3.0 3.0 Dodecyl trimethyl cyanide is less than 0.2 «0.2 0.2 Strenghenic acid 1.0 1.0 1.0 Monoethanolamine 2.5 2.5 2.5 Ethoxylated tetraethylenepentamine 1.5 1.5 1.5 Protein (3.1% active) 0.4 0.5 0.4 Amylase (11.5% active substance> 0.2 Miscellaneous substances and solvent balance balance balance 100.0 100.0 100. VTT VTTT TX N-methyl N-1-deoxydehydroglycosyl 4.2 3.1 3.1 cocoamide (: 14-18 alkyl ethyl gas (2.25) sulfate 12.6 9.3 (: 12-18 alkyl ethyl gas (2.5) sulfate 6. C12-14 alkyl sulfate 3. C12-14 alkyl ethoxy compound 3.4 Dodecyltrimethylammonium chloride 0.5 Dodecenyl succinate 5. Benzoate 3.4 15. TMS / TDS (80/20) &quot; 3.4 C12-14 fatty acids 3.0 Gas succinic acid 20.0 -64- (Please read the precautions on the back before writing this page) -Installation · Line. This paper size is generally used in country B Standard (CNS) A 4 size (210X297 male Long)

200〇SS Λ 6 Β6 V. Description of the invention (63) Ethylene-based tetraethylenepentamine polyacrylate (4500MW) Protein _ (3.1% active) Starch _ (11.5% active) Miscellaneous substances and soluble sulfonate 0. 2 Balance Balance Balance Printed by the Central Bureau of Standards of the Ministry of Economic Affairs β Industrial and Consumer Cooperatives 100.0 100.0 100.0 • TMS / TDS is an example of tartrate monosuccinate / tartrate disuccinate IV-IX is preferably used at about 2000ρρβ, with the weight of washing water As a benchmark, for washing temperatures below about 50C. Preparation Example IV-IX by combining non-aqueous solvent, aqueous interface, water or water, melted fatty acid, polysulfonate solution and aqueous solution of other salts, water-based Amine, buffer, caustic cockroach, and residual water. Adjust the pH to about pH 8.5 using an aqueous solution of tartaric acid or hydrogenated sodium. After the pH value is adjusted, add the final ingredients, such as detergent, alcohol, colorant, and fragrance, and stir the mixture until a single phase is obtained. Fen Yong X Another method for preparing the polyhydroxy fatty acid amide used in this article is as follows. A reaction mixture was used which included 84,87 grams of fatty acid methyl ester (clamp source: Procter &amp; Gamble Methyl Ester CE1270), 75 grams of N-methyl-D-S6 glucose (Lai: Aldrich Chemical Company M4700- 0. 1.04 -65-(Please read the precautions on the back before writing this page) Binding ·-Book size standard for easy use Β Β home standard (CNS) A 4 specifications (210X297 mm) Λ 6 Β6 V. Description of the invention (valve sodium formazan (source: Aldrich Chemical Company 16,499-2), and 68.51 grams of formazan. The reverse «container contains a standard reflux, device, which is equipped with a drying tube, a cold pipette and a stir bar. In this procedure, combine N-methylglucosamine with formazan and mix under argon, and heat and mix thoroughly (stirring bar; reflux). After 15-20 minutes, when the solution has reached At the desired temperature, add this ester and methanol refining medium. Sampling periodically to monitor the reaction process, but it should be noted that this solution is completely transparent at 63.5 minutes. Nearly completed. The reaction mixture was kept under reflux for 4 hours. After the methanol was removed, it was recovered The weight of the product is 156.16 grams. After drying and purification in the air, the pure product with a yield of 106.92 grams is recovered. However, the yield percentage is not calculated on this basis. This is because you take regular rules throughout the reaction process, making The percentage yield value of the whole chrysanthemum is meaningless. This anti-plaque can be carried out at 80% and 90% reactant concentration for up to 6 hours, and produces very little by-products. The modern, suspected laundry detergent particles are as follows (Please read the precautions on the back before filling in this page) Binding · Order _ Printed by the Ministry of Economic Affairs, Bureau of Standards, and Employee Consumer Cooperatives. XT Ingredients Heavyweight% Cl4-lS Hospital-Based Enzyme Androgen 13 (： 14-18 Alkyl Polyethoxy (2.25) Sulfonic Acid 5.60 C12-13 Alkyl Polyethylene Gas Compound (6.5) 1.45 Ci2-14 Fatty Acid N-Methyl Glycosyl Phenylamine 2.50 Sodium Aluminosilicate (for Hydrated Zeolite A) 25.2 Crystalline layered silicate ribbed sea bream 1 25.3 Acidic acid 10.0 -66-The size of this paper is universal Chinese National Standard (CNS) Grade 4 (210x297 mm)

20032S Λ 6 Β6 V. Description of the invention (65) Na-acrylic acid sodium polyacrylic acid (Uw 2000-4500) II 2: Triamine pentaacetic acid Savinase2 6-nonanoic acid amino-6-oxo hexanoic acid peroxy acid sodium Hydrate nonyl benzene sulfonic acid whitening agent makes the washing liquid pH = 9.90 3.2 0.45 0.70 7.40 2.10 5.00 0.10 1 layered silicate rib wash »as known in this technology». It is preferably layered sodium silicate. See, for example, US Pat. No. 4,664,859 of H. P. Rieck, issued May 12, 1987, for layered sodium silicate assisted scrubbing, and is incorporated herein by reference. A suitable layered silicate ribs can be obtained from Hoechst Corporation as SKS-6. 2 Available from Hove Hordisk A / S, Copenhagan. (Please read the back-notes before filling in this page) Packing--Order _ The Central Standards Bureau of the Ministry of Economic Affairs Beigong Consumer Cooperative prints the above-mentioned types of particles with better degree of dispersion, for the inclusion of about 0.0001% to about 2% ( Weight Λ ratio) active enzyme, and at least about 1% by weight of the more fatty acid amide, and the best is where the male and female interface activity is not an alkylbenzene sulfonate surfactant. The following is a pseudo-preparation for the preparation of a preferred liquid detergent strong laundry detergent according to the present invention. It should be understood that the stability of enzymes in such compositions. You are worse than in granular detergents. However, a can be protected from the use of typical enzyme stabilizers such as formate and acid, lang fat _ and Ji Wei Su _ -67-(This paper is not used by China Β 家 橾 毕 (CNS) 肀 4 Specifications (210x297g *)

COOd ^ S Λ 6 B6 Printed by the Employee Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs V. Description of the invention (66) Degraded by protein. However, in the presence of the alkylbenzene sulfonate (&quot; LAS ”) interface, the fat stability is still phased, and the difference is obvious. Obviously, LAS will partially denature the lipase. Furthermore, it seems that the denatured fat _More susceptible to protein attack. Ting is based on the aforementioned considerations, as noted. It may be specially treated in the liquid wake-up composition, the way is to provide a liquid cleanser that contains fat, protease and following vitamins together A challenge for the composition of epilepsy I. It is a challenge to provide such an effective blend of three enzymes in a stable liquid detergent, accompanied by a clean interfacial activity. In addition, it is difficult to In this composition, it is stable to incorporate gasification_ and / or starch_. Various mixtures of fat_, protein_, cellulose breast, starch_, and gasification enzymes have been determined in certain non-alkyl Benzoate interface activity is moderately stable in the presence of the two systems, so that effective, strong type of solid certificate and even liquid detergent can be formulated. In fact, the stability, liquid, and cleaning agent composition The deployment of Tong constitutes the technology provided by the present invention A highly advantageous and preferred embodiment. In particular, the prior art »liquid hunger cleansing _ composition, typically contains pseudo-LAS, or R0 (A)» S03A type (&quot; AES ”as mentioned above ) A mixture of surfactants, meaning OILAS / ASE mixture. In comparison, the liquid detergent here preferably contains a two-phase mixture of AES and the polyhydroxy fatty acid amide of the type shown here. Although there can be a minimum amount of LAS, it should be understood that the stability of the enzyme will be reduced accordingly. Therefore, the better image in this liquid composition is substantially free (that is, contains less than about 10%, preferably less than about 5%, more preferably less than about 1%, and most preferably 0%) LAS. * 68-(Please read the precautions on the back before writing this page) This paper uses the Chinese National Standard (CNS) A 4 specifications (210X297) * Λ 6 Η 6 〇0〇 ^^ (67) (Please read the note on the back-item Ϋ before filling out this page) The present invention pseudo provides a liquid steamed detergent composition, which contains: (a) about 1% to about 50%, preferably about 4% To about 40% anionic interface active thin I; (b) about 0.0001% to about 2% active cleansing enzyme; (c) an amount of yeast reinforcement (preferably about 0.5% to about 12%) Polyhydroxy fatty acid amide material 0 R1

R *-ί-Λ-Z where R1 is! U, Ct-u hydrocarbyl. 2-hydroxyethyl, 2-hydroxypropyl, or a mixture thereof, Ra is a C5-C31 hydrocarbyl group, and Z is a linear hydrocarbyl group (where at least three hydroxyl groups are directly connected to the bond ) Of the polyhydroxy hydrocarbon group, or its alkylated derivatives; and the composition does not substantially contain alkyl benzene sulfonate. , Than; the water-soluble Sil ionic interfacial activity, preferably pseudo-S activity "AES"):

R0 (A) ™ S03M Printed by Beigong Consumer Cooperatives, Bureau of Standards, Ministry of Economic Affairs, where R is unsubstituted C10-C24 alkyl or hydroxyalkyl (C1〇-C24) and A is ethyl or propylene Unit, m is an integer greater than 0, and M hydrogen or cation. Preferably, R is an unsubstituted C12-Cia alkyl group, A is an ethyl chloride unit, m is from about 0.5 to about 6, and M is a cation. This cation is preferably a gold plaque cation (eg, sodium (Preferred), lithium, calcium, magnesium, etc.) or ammonium or substituted ammonium cations. The ratio of the above-mentioned surfactant (&quot; AES ”to the polyhydroxyacrylic acid amide of this article. It is preferably about 1: 2 to about 8: 丨, preferably about 1: 1 to about 5: 1, most Jiawei-69-This paper is used in beta β «Home Sample Standard (CNS) A4 specifications (2 丨 0x297mm) Λ 6 Β6 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention (68) About 1: 1 to about 4: 1 β Alternatively, the liquid mule composition here may contain polyhydroxy fatty acid amine,% ASE, and about 0.5% to about 5% by Ce-Ca2 (preferably (: 10 -(: 80) linear fermentation and the condensation product formed by ethylene oxide (Emolyl) between about 1 and about 25 moles, preferably between about 2 and about 18 moles. As mentioned above, The liquid composition of this * has a pH value of about 6.5 to about 11.0, preferably about 7.0 to about 8.5 in a 10% aqueous solution at 20C, and the composition of the present invention preferably further contains about 0.1% to about 50 % Cleansing rib lotion. These compositions preferably contain from about 0.1% to about 20% citric acid, or its water-soluble starch, and from about 0.1% to about 20% water-soluble succinate tartrate, especially its Satin salt, and mixtures thereof, or about 0.1% to about 20 % (Weight ratio) oxydisuccinate, or its mixture with the aforementioned rib cleansing face. 0.1% -50% alkenyl succinate can also be used. The preferred liquid composition here, pseudo including about 〇. 〇〇〇1? Meaning to about 2%, preferably from about 0.0 001% to about 1%, most preferably from about 0.001% to about 0.5% (based on the active substance) of clean fermentation benzene: These enzymes are more Jialuanwan includes protein_ (preferred), fat_ (preferred), powder splash_, cellulase, gasification_, and mixtures thereof. Preferably, it is a composition with two or more enzyme types, The best one is one of the proteases. Although various descriptions of cleansing protein sea, Jiweisu, etc. can be obtained in the literature, cleansing fats may be slightly unfamiliar. Therefore, it is a recipe for helpers , The fat plum that is interesting and interesting, including Anano AKG and BacHlis Sp fat _ (such as Solvay enzyme). Please also refer to the patent EP A 0 399 681 (announced on November 8, 1990), EP A 0 218 -70-(please read the precautions on the back first and then ** this page) The paper size is free to use China National Standard (CNS) A4 specifications (210X297 *) Λ 6 Β6 V. Description of the invention (69) 272 (announced on April 15, 1987) and PCT / DK 88/00177 (announced on May 18, 1989), both of which are incorporated herein for reference. «Appropriate Bacteria Fats, including those made from Hun i co 1 a 1 anug i nosa (humus) and Thernonyces lanuginosus. The best is the gene obtained from Humicola lanuginosa via asexual propagation ΚΙ, and the fat expressing this gene in Aspergillus oryzae (Aspergillus oryzae) as described in European Patent Application 0 258 068 and is incorporated herein by reference , Commercially available under the trade name LIP0LASE. From about 2 to about 20,000, preferably from about 10 to about 6,000 lipase units per fat (LU / s) fat plum product can be used in these compositions. One-pound fat_Military position is the amount of lipase that can titrate butyric acid to produce 1 skimmer at a fixed pH value, where the pH value is 7.0, the ancestry degree is 30 X :, and the substrate is emulsified tributyl Glycerol acid ester and arabic mash, Ca + + and H a C 1 are present in phosphate Newton liquid. The following example pseudo-describes a better powerful liquid detergent composition, which contains: Central Bureau of Standards, Ministry of Economic Affairs Printed by employee consumer cooperatives (please read the precautions on the back before writing this page) (a)-Enzymes derived from protein plum, following vitamin plum and lipase, or preferably their complexes, which are typical The upper part accounts for about 0.01% to about 2% of the weight of the gold department composition, but the amount can be adjusted according to the desires of the formulator. In order to provide the "effective amount" (the amount of Italian decontamination) of the enzyme or enzyme mixture; ( b) The polyhydroxy fatty acid amide surfactants of the type shown here typically represent at least about 2% by weight of the composition, more typically from about 3% to about 15%, preferably from about 7% to about 14 %; (c> As shown in this book, the R0.UUS03M type surfactant is preferably R0 (CH2 -71. The paper standard is free of Chinese national standard ( CNS) A4 specification (210X297mm) 200〇 &quot; Λ 6 Β6 V. Description of invention (70) CH2〇) eS〇3M, where R is Ci4-Cis (average> and * is 2-3 (average) , Where Μ is Η or a yang male that can form a water-soluble gelatin, such as Na +%, the interfacial activity _ typically accounts for about 5% to about 25% of the weight of the composition; (d) selective use as herein The R0S03M type surface active agent of the formula, wherein R is preferably C12-C14 (average), the surface active agent preferably accounts for about 1% to about 10% by weight of the composition; (e)-a liquid carrier Agents, especially water or water-alcohol mixtures; (f) selective use, but it is best to use an effective amount of enzyme stabilizer, typically about 1% to about 10% by weight of the composition; (g) selective Use, but it is preferable to use water-soluble rib lotion, especially polycarboxylate rib lotion, typically about 4% to about 25% of the weight of the composition; (h) Choose to use, as indicated above Various additives, whitening agents, etc., are typically (if used) about expensive to about 10% of this composition; and (i) this composition is essentially free of LAS. (Please read the back Please pay attention to enjoy the item, and then fill out this page.) Packing and Ordering_ Printed by the Central Standards Bureau of the Ministry of Economic Affairs Beigong Consumer Cooperatives. Fenli XT T Ingredient U Ci4-ls alkyl polyethoxylated (2.25) sulfonic acid 21.0 C12-14 fatty acid N-Methylglucosamine 1 7.0 Mono- and di-tartrate sodium succinate (80:20 mixture) 4.00 Cimic acid 3.80 Cl2-14 fatty acid 3.00 -72-This paper scale is used in accordance with the Chinese Standard (CNS) A 4 Specifications (210X297 Gonglong) Printed by the Consumers ’Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 0063 ^ 5 Λ 6 Β6 V. Description of the invention (71) Tetraethylenepentamine ethyl * compound (15-18) 1.50 Polyethylene-poly Propylene terephthalate polysulfonic acid * 0.20 of ethoxylated copolymer proteinase B (34 g / L) 2 0.68 fat plum (100 KLU / g) 3 0.47 fervain_ (5000 cevu / g) 4 0.14 Whitening La 365 0.15 Ethanol 5.20 Monoethanolamine 2.00 Sodium formate 0.32 1,2-propanediase 8.00 Hydrogen sodium 3.10 Silicone foam inhibitor 0.037 2.00 Water / Miscellaneous substances make up the balance to 100 (Please read the precautions on the back first (Write this page) 1 Made as disclosed above. 2 protein_B is a modified bacterial serine protein_, which is described in European Patent Application No. 87 303 761 filed on April 28, 1987, on pages 17, 24 and 98. 3 The fat IS used in this article is assumed to be a gene obtained by asexual reproduction from Hum i col a lanuginosa, and this gene is expressed in Aspergillus oryzae, and the resulting fat is as described in European Patent Application No. 0 258 068 It can be obtained commercially under the trade name LIP0LASE (available from Nove Nordisk A / S, Copenhagen Denmark). 〇-73-^ Paper size Xiaozhong Zhongming National Standard (CNS) A 4 specifications (210 father 297 public potion) Printed by the Central Standards Bureau employee consumer cooperative. Λ 6 Β6 V. Description of invention (72) 4 The cellulose used in this article is sold as a commercial sample CAREZYME (Novo Hordisk, A / S, Copenhagen Denmark). 8 Brightener 36 Pseudo is commercially available from TIKOPAL TAS 36. This brightener is a premix of 4.5% whitening agent, monoethanolamine (60%) and water (35.5%), which is prepared separately, and added to the composition. The following is not intended to limit the present invention, but only to further illustrate other aspects of this technology, which can be considered by those who are prepared when using polyhydroxy fatty acid amide to make a wide variety of detergent compositions. It is immediately apparent that the polyhydroxy fatty acid amide, because of its thiamine bond, is subject to some instability under highly alkaline or highly acidic conditions. Although some decomposition can be tolerated, it is best not to subject these substances to pH values of about 11, preferably 10, nor less than about 3, after an inappropriate period of time. The pH of the final product (liquid brewing) is typically 7.0-9. 0. During the manufacture of polyhydroxy fatty acid aldamines, the alkaline catalyst used to form its amide bond must typically be at least partially neutralized, although any acid Both can be used for this project, but the plaque of the cleanser satisfies a simple and convenient way to pseudo-use an acid that can provide anions, which are useful and desired in the final cleaning composition. For example, citric acid can be used for neutralization purposes, and the formed citrate ions (about 1%) are allowed to remain with about 40% of the polyhydroxy fatty acid aldol amine slurry, and pumped into the whole cleaning _ 制 迪Later in the manufacturing phase of the procedure. The acid formula of the following substances can be used in the same manner, for example, oxosuccinic acid, bait triformic acid S, ethylenediamine tetraacetate, tartrate / succinate, and the like. -7 4 _ I Paper size for the use of China National Standards (CNS) A 4 specifications (210 father 297 epimedium) C ......... installed ..... ^ 1. · Line (please first Read the note on the back to enjoy Xiang Zeng Zai β page) 5. Description of the invention (73) Λ 6 Β6 Polyhydroxy fatty acid S derived from coconut alkyl fatty acids (mainly C12-C14) printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Amine, which is easier to dissolve than its ruthenium alkyl group (mainly, (: 18-(: 18) pairing. Therefore, the C ^ -Cm substance is slightly easier to formulate in the liquid composition and is more soluble in cold water In the laundry bath. However, Cie-Cie substances are also very useful, especially in the case of using warm to hot washing water. In fact, this (: 18-(: 18 substance may be better than its C12-C14 pairing It is a good cleansing surfactant. Therefore, when the formulator chooses an undetermined polyhydroxy fatty acid acid amine for a specific formulation, it may wish to strike a balance between ease of manufacturing and performance. It should also be clear , The solubility of polyhydroxy fatty acid zymamine can be increased by having unsaturated viscosity and / or branching in fatty acid. , For example, polyhydroxy fatty acid naphthylamine derived from oleic acid and isostearic acid is more soluble than its n-alkyl pair. Tongkangdi, a polyhydroxy fatty acid amide derived from disaccharides, trisaccharides, etc. Its solubility is usually greater than that of its monosaccharide-derived pairing substance. These higher solubility may be particularly helpful when it is used with liquid snakehead ancestors. Furthermore, this polyhydroxy fatty acid promethamine, in which polyhydroxy is derived From malt, when it is used in combination with conventional alkylbenzene sulfonate (&quot; LAS ”), it seems to be particularly good as a cleaning agent. Although it is not intended to be limited by theory, it seems that LAS Combined use with the polyhydroxy fatty acid amide derived from more distant mussels (such as malt) will cause a large and unexpected reduction of interfacial tension in aqueous media, thus enhancing the cleaning performance. (Derived from malt The preparation method of the polyhydroxy fatty acid amide is described below>. Polyhydroxy fatty acid amide can not only be made from pure sugar, but also hydrolyzed -75-η Please read the notes on the back before writingThis page of the paper size is free to use the Chinese National Standard (CNS) A 4 specifications (210X297) «A 6 B6 Printed by the Consumer Cooperative of the Bureau of Standards of the Ministry of Economic Affairs V. Invention description (1 starch, such as corn splash powder, potato Starch, or any other suitable plant-derived starch, which contains the mono-, di-, and other sugars that the blender wants. From the economic point of view, this is particularly important. Therefore, "high glucose" corn syrup , "High maltose" corn syrup, etc., can be used conveniently and economically. Delignification, hydrolyzed androgen pulp, can also provide a source of raw materials for polyhydroxy fatty acid sleep amine. As mentioned above, derived from higher _ Class (such as maltose, milk, etc.) polyhydroxy fatty acid aldamine, pseudo than its sugar pair, more soluble, moreover, it shows that the more soluble polyhydroxy fatty acid aldamine can help it less The pairing of solubility dissolves to varying degrees. Therefore, the formulator can choose to use raw materials that contain, for example, corn starch syrup, but choose syrup containing malt modified substances (eg, 1% or more). The resulting polyhydroxy fatty acid mixture, usually more complex than the "pure" glucose-derived polyhydroxy fatty acid amide, exhibits greater solubility properties over a wider temperature and concentration range. Therefore, for mixtures of sugars other than pure sugar reactants, In particular, in addition to any economic benefits, the polyhydroxy fatty acid blend made from mixed sugars can provide great benefits in terms of performance and / or ease of formulation. However, in some cases, the content of fatty acid maltolamine is high At about 25%, some loss of grease removal performance (without washing effect) can be noticed, and above about 33%, there is some loss in foaming effect (the percentage is derived from malt syrup) The percentage of polyhydroxy fatty acid amide to glucose-derived polyhydroxy fatty acid amide in the mixture). This can be changed slightly, depending on the bond length of the fatty acid portion. So, typically, the use of this mixture is chosen For those who match, you can find that it is beneficial to choose the following polyhydroxy fatty acid S amine mixture, of which -76-(please read the precautions on the back before filling this page) This paper The standard uses the Chinese B home sample standard (CNS) A4 specifications (210X297 g *). 0 A 6 B 6 V. Description of the invention (75) Contains single brew (such as glucose) versus two-and higher brews (such as maltose) The ratio is about 4: 1 to about 99: 1. 、 The method of making better uncyclized polyhydroxy fatty acid amide from fatty ester and N-alkyl polyacryloylase can be used in fermentation solvent at about 30 υ-90 υ It is preferably carried out at a temperature of about 50 80. At present, it has been determined that, for example, for liquid detergents, this procedure can be conveniently carried out in 1,2-malonolysis JW, because in Before being used in the final Zhijie_ formulation, the two fermentation enzymes do not need to be completely removed from the reaction product. Similarly, for example, Gulu, which is typically a granular detergent composition, can It was found that it can be conveniently carried out in a thinner solution at 30 90 t: the solution contains ethoxylated enzymes, such as ethylated (E0 3-8) (: 12-(: 14 yeast For example, it can be purchased from NE0D0L 23 E06.5 (Shell). When using this ethane-based compound, it is best not to contain a large amount of unethylated yeast, and the best is It does not contain Dazhijunyi gasified alcohol (named "T"). Although the method of manufacturing polyhydroxy fatty acid chloramine itself is not part of the present invention, the formulator can also note that Other synthetic methods of polyhydroxy fatty acid amides described in this article. Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Typically, it is used to prepare better non-rose-like polyhydroxy fatty acid amines in the industrial reaction sequence, such as including ： Step-Preparation of N-alkyl polyhydroxyamine derivatives from the desired sugar or idol mixture by forming an adduct of N-alkylamine and sugar, and then reacting with hydrogen in the presence of a catalyst ; Next for Yan JB, the aforementioned polyhydroxyamine is preferably reacted with a fatty ester to form an amide bond. Although the various N-alkyl polyhydroxyamines that can be thrown away in step 2 of this reaction sequence can be made by the methods shown in various techniques, the following method is -77-This paper standard is generally accepted by the Chinese National Standard ( CNS) A4 specifications (210X297mm) Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention (76) It is appropriate and economical syrup can be used as the original subject. It should be noted that when the chieftain uses this kind of raw material, it should be infused with a very light color, or preferably almost colorless ("water white") syrup, for the best fruit / manufacture. The plant-derived cabinet gills are poorly loaded with M-alkanes. I. Adduct formation-the following is a purifying method. Among them, about 420 g will have about 55% of Gardner color less than 1 (Corn syrup-about 231 grams of grapefruit-about 1.28 moles). With about 119 grams of about 50% methylamine (59.5 grams of methylamine-1.92 moles) aqueous solution. Using N2, the methylamine (MMA) solution is scrubbed and coated, and cooled to about 10T or lower. At a temperature of about 10-20P, Na is used to scrub and coat the corn jelly. At the specified reaction temperature, slowly add corn syrup to the MMA solution. Under the specified approximate time (minutes &gt;, set the Gardner color. I ”Time (minute_): UL UJL 1M. 240 Pi 1 _ 温 庠 f T) __ Gardner Ya Xiang f roughly Bu) _______ Λ 6 Β 6 ( Please read the precautions on the back before filling this page) 0 1 1 1 1 1 1 20 1 1 1 1 1 1 30 1 1 2 2 4 5 50 4 6 10 _ • As you can see from the data in the table above In addition, when the temperature rises above about 301 and at about 50C, the Gardner color of this adduct is poor, and the adduct with Gardner color below 7 is only about 30 minutes. For -78-This paper standard is commonly used in Β Η home sample standard (CNS) A 4 specifications (210x297 male dragons). 77) For longer anti-plaque and / or fixed time, its pass should be less than about 201C. For good color glucosamine, the Gardner color should be less than about 7, and preferably * won is less than about 4. When we use a lower temperature to form this adduct, the time to reach the equilibrium concentration of the adduct is shortened as by using the amine-to-gel ratio. Using the 1.5: 1 molar ratio of amine to silica as shown, equilibrium is reached in about two hours at a reaction temperature of about 30 t !. Under the same conditions, at a ratio of 1.2: 1 pike, this time is at least about three hours. For a good color, the combination of amine: sugar ratio, reaction temperature, and reaction time is selected to achieve a substantially balanced conversion, for example, more than about 90t: preferably about 95%, and more preferably About 99% (sugar-based), and for adducts, its color is less than about 7, more preferably less than about 4, more preferably less than about 1. Using the above method, at a reaction temperature of less than about 20T :, and using corn syrup with different Gardner colors as shown, the color of the MMa adduct (within at least about two hours, after reaching the real equilibrium)傜 as shown in the table Ο Table 2 _ Gardner · color (female teacher h) _ corn syrup 1 1 1 1+ 0 0 〇 + adduct 3 4/5 7/8 7/8 1 2 1 as available from As seen in the table above, the starting sugar substance must be nearly colorless to consistently have acceptable adducts. When the sugar has about 1 -79-(please read the precautions on the back before filling in this Page) Packing · This paper standard uses the China Sleepless Standard (CNS) A4 specifications (210x297 public goods)

Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs V. Description of Invention (78) When Gardner colors, their adducts are sometimes acceptable, sometimes unacceptable. When the Gardner color is away from 1, the adduct formed is unacceptable. The better the initial color of sugar, the better the color of the adduct. II. Nitride-The above-mentioned adducts with Gardner color 1 or lower will be hydrogenated according to the following procedure. Add about 539 grams of adduct in water, and about 23.1 charge together with "Medium G49B Ni catalyst, add one liter of Heat® tweezers, and scrub twice with 200psig H2 at about 20t: Raise to about 1400 psi, and the temperature to about 50C. Then increase the S-force to about 1600psU, and fix the temperature at about 50-55C, press for about three hours. The product is now pseudo-hydrogenated by about 95%. Raise the temperature to about 851C, press for about 30 minutes, then decanted the reaction mixture, and filter out the catalyst. After removing the water and MMA by evaporation, the product is about 95? &Lt; H-methylglucosamine It is a white powder. Use about 23.1 grams of Raney Νί catalyst and the following changes, repeat the above procedure. Wash the catalyst three times, and use 200psig Η2 to clean the reactor (the suspected medium in the reactor) Gas twice, under 1600 pSU, using 112 to pressurize the reactor for two hours, under one hour, release the pressure and repressurize the reactor to 1600 psig. Then add the adduct to 200 psig and 20TC In the reactor, as described above, the reactor was scrubbed with 200 psig Hβ, etc. In each case, the resulting The material pseudo is greater than about 95% N-methylglucosamine; with less than about 10 OppulU (based on cucurbitamine>; and with a solution color less than about Gardner 2. -80-(Please read the back side first. Note Matters write this page again)

The size of this paper is easy to use. The standard of CNS A4 (210X297 g *) 005 ^^ A 6 B6 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The invention description (79) Based on «glucosamine, the pseudo color settles to about 140T (after a short exposure time). Has a low sugar content (less than about 5%, preferably less than about 1%> and good color (less than about 7, preferably pseudo less than about 4 Gardner, more preferably less than about 1), for good The adduct is very important. In another reaction, chromium uses about 159 grams of 50% methylamine (in water) to start the preparation of the adduct, which is about 10-20t :, using N2 for scrubbing and Coated. At about 50C, use K2 to degas about 330g of about 70% corn syrup (near water white), and slowly add it to the methylamine solution at a temperature below about 20C. Mix this solution About 30 minutes, and get about 95% of the adduct, which is a very pale yellow solution. Add about 190 grams of adduct (in water), and about 9 grams of G49B Hi catalyst, add 200 ml of hot press In the pot, at about 201C, use H2 scrubbing three times 3 to increase the H2 pressure to about 200ps, and the temperature to about 50. Raise the pressure to 250psi, and the temperature is fixed at about 50-551C, after about Three hours. Then about 95% of the hydrogenated product at this time was raised to about 85 1C temperature for about 30 minutes, and after removing water and evaporation, this product was about 95% N- It is a white powder. When the pressure of 1 ^ is less than about 1000ps 〖g, in order to minimize the content of Ni in glucosamine, the connection between the adduct and the bighead medium is reduced. The lowest is also very important. In this reaction, the Nc-methylglucosamine contains about 10 ppb of Dong, which is less than 10 ppm in the aforementioned anti- *. Use H2 to carry out the following anti-mole A direct comparison of the temperature effect of the flood reaction Ο -81-(please read the precautions on the back before filling in this page) This paper is at scale and uses the Chinese trapped home standard (CNS) A 4 specifications (210X297 g *) a Λ 6 B6 V. Description of the invention (80) Using a 200 ml thermal reactor reactor, follow the typical procedure similar to the one proposed above to produce adducts, and perform hydrogen inversion at different temperatures.% Used to manufacture Glycosamine The adduct is obtained by combining approximately 420 grams of approximately 55% «glucose (corn syrup) solution (231 grams of dextrose; 1.28 mils) (this solution is made using 99DE corn syrup from CarGill, this The solution has a lower color than Gardnerl), and about 119 grams of 50% methylamine (59.5 grams> (»^; 1.92 mole) (available from Air The company's reaction process is as follows: 1. Add about 119 grams of 50% methylamine solution to the H2 scrubbed reactor, coat with Na and cool to less than about 10P. 2. At 10-201C Next, use N2 to degas and / or scrub the 5 5% corn syrup solution to remove oxygen in the solution. 3. Add the corn syrup solution slowly to the methylamine solution and keep the temperature below About 20 C. 4. Once all the corn syrup solution has been added, mix the eaves for about 1-2 hours. η Read the precautions on the back before * 1 This page is bound by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperative. After printing this additive image, it will be used in the hydrogen reaction or stored at low temperature to prevent further degradation. . «The hydrogen reaction of the glucosamine adduct is as follows: 1. Add about 134 grams of adduct (the color is lower than about Gardner 1) and about 5.8 grams of G49B Νί to a 200 ml hot-pressed stage. 2. At about 20-30T :, use about 200psi H2 to scrub the anti-mixture twice. 3. Add 15 to about 400 psi with H2 and raise the temperature to about 50. -82-This paper standard is common in the B country sample standard (CNS) A 4 specification (210X297 g *) 00526 5. Description of the invention (δl) Λ 6 Β6 Printed by the Beigongxiaot cooperative of the Central Bureau of Standards of the Ministry of Economy 4. Lifting pressure To about 500psi, the reaction takes about 3 hours. Keep the temperature at about 50-55 * C. Take a try 1. | 5. Raise the temperature to about 35t :, after about 30 minutes sickle. 6. Decant and filter out the Νί catalyst. Take a try 2. Conditions for reaction at constant flux: 1. In a 200 ml autoclave, add about 134 g of adduct and about 5.8 g of G49B Ni. 2. At low temperature, scrub twice with about 200 psi H2. 3. Use H2 to pressurize to about 400psi, and raise the temperature to about 50t :. 4. Raise the pressure to about 500 psi, react for about 3.5 hours, and keep the temperature at the indicated temperature. 5. Decant and filter out the Ni catalyst. Sample 3 was obtained at about 50-55T: test 4 was obtained at about 75 &quot;C; and sample 5 was obtained at about 85t (response time to about 85 1C, about 45 minutes) ). All operations obtained N-methyl glucosamine of similar purity (approximately 94%>: The Gardner * colors of these operations were similar after the reaction, but only two stages of heat treatment achieved good color stability And 85t: operation, the marginal color is obtained at the time after the anti-smoke. Fen XIII is used for the tallow of N-methyl maltamine (hardening &gt; fatty acid amide) used in the cleaning agent composition according to the present invention The preparation method is as follows: Coupling-reactant: malt monohydrate (Aldrich, batch number 01318 〇); methylamine (40% by weight, in water) (Aldrich, batch number 83, please read the notes on the back if and then • This page is a binding page. The paper is used in the beta standard (CNS) A 4 specifications (210 x 297 g *) ^ ΟΟο ^ δ Λ 6 Β 6 V. Invention description (82) Bei Gong, Central Standards Bureau, Ministry of Economic Affairs Printed by Consumer Cooperatives (03325TM)); Ruan Nikon, 50% slurry (UAD 52-73D, Aldrich, batch number 12921LW). | Add the reactant to a glass refill bottle (250g maltose, 428g methylamine solution, 100g contact Medium slurry-50 grams of Raney Ni), and placed in a 3 liter shaking broadcast hot press stage, with "gas (3x500psig) hydrogen gas (2x500psig) scrubbing, and sway at room temperature H2 over the weekend, in the Tongdu Fanyuan from 28T to 50 death. The crude reaction mixture was vacuum filtered twice, after passing through the silica entropy filter Glass fiber filter. The filtrate is concentrated into a thick cobalt. The final amount of water is removed by azeotrope by dissolving this substance in methanol, and then removing the enzyme / water on the rotary evaporator. . Final drying under high vacuum. Dissolve the crude product in refluxing formazan, meet the filter. Cool to recrystallize, filter, and dry the filter at 35 = vacuum. This is the second part. , It should be until the precipitation starts to form, and store it in the freezer overnight. Filter the solid and dry under vacuum. This is the fraction K2. The filtrate is once again shrinked to half of its accumulation, and then Crystallization. Less precipitate is formed. Add a small amount of ethyl yeast, and leave this solution in the refrigerator to pass through the Min Min and Guo Honggu materials, and dry in vacuum. The combined solid waist includes N-methyl maltamine, Its pseudo-use is used in the step cost of the synthesis synthesis 2. Step Li 2-Reaction Substances: N-methyl maltamine (available from Step®1); hardened tallow methyl ester; sodium methoxide (25% in formazan); anhydrous methanol (solvent); Pod ratio 1: 1 amine: ester ; The initial catalyst content is 10 pod% (w / r maltamine), which is increased to 20 mol%; the solvent content is 50% (weight). In a sealed bottle, heat 20.36 grams of beast fat methyl ester to its Melting point (water bath) and put into a 250ml 3-neck hairpin bottle with mechanical agitation. -8 4-This paper is used in the national standard (CNS) A 4 specifications (210x2 mm) η Read the notes first, and then write this page * Printed by the Ministry of Economy + Central Standards Bureau Beigong Consumer Cooperatives Λ 6 Β6 V. Description of the invention (83) Heat the flask to about 70 to prevent the ester from solidifying. In addition, 25.0 g of N-methyl maltamine was combined with 45.36 g of formazan, and the resulting slurry was added to tallow ester and mixed thoroughly. Add 1.51 g of 25% formazan bream (in formazan). After four hours, the anti-alcohol mixture has not yet been cleared, so add 10% of the outside of the «medium (20% of the total of the ears), and let the reaction hold ore overnight (about 68t!), After this time, The mixture is transparent. Then change the reaction flask for steaming. The temperature was increased to 110 and the shovel was continuously distilled under atmospheric pressure for 60 minutes. Then start steaming under high vacuum for 14 minutes, when the product is extremely thick. The product was developed in ether at που (external temperature) to spend the weekend. Remove on a rotary evaporator and store the product in an oven overnight, then grind it to a powder. Use silico to remove any remaining N-methyl maltamine from the product. Tuck the siliceous pulp in 100% formazan into a funnel and wash it with 100% formazan several times. A concentrated product sample (20 g in 100 ml of 100% methanol) was loaded onto silicone rubber), washed with vacuum and methanol several times, and dissolved several times. Dry the collected ionized liquid stool (rotary evaporator). ϋ Developed in ethyl sugar acid in night, followed by filtration to remove any residual tallow ester. Dry the spleen in vacuum overnight. This product is tallow alkyl N-methyl maltolamine. In an alternative chess game, the aforementioned reaction sequence step »1 can be carried out using commercial corn syrup, which contains a mixture of" glucose "or" granula "and typically maltose of 5% or more. The polyhydroxy fatty acid amines and mixtures formed can be used in any of the «cleaning agent compositions». In yet another mode, step 2 of the aforementioned reaction sequence can be carried out in 1,2-propanediol or NEODOL. According to the wishes of the deployer, it is used in the -85-This paper standard is universal Chinese H standard (CNS) A 4 specifications (210X297 public *) (please read the precautions on the back and fill in 1 page) Order _ Printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ι〇ο〇3 ^ * Λ6 ____B6_ V. Description of the invention (84) Before the preparation of the detergent composition, it is not necessary to remove the malonan or NE0D0L from the anti-nickel products. Once again, according to the wishes of the matchmaker, the methate can be neutralized by tartaric acid, and the sodium gallate can be obtained, which can be left in the polyhydroxy fatty acid amide. Ο According to the wishes of the matchmaker Certainly, the composition of this * may contain more or less different foam controls «). Typically, for dishwashing, the pseudo-hope high foaming effect is used, so foam is not used to control the twig. It may be desirable to add some foam control agent for the laundry in the top-mounted laundry laundry, and for the front-mounted bleach washing machine, it may be better to add some foam control agent . A wide variety of foam control agents are known to those skilled in the art and can be routinely selected for use here. In fact, the choice of foam control agent, or foam control agent mixture, for any detergent composition to be determined depends not only on the presence and amount of the polyhydroxy fatty acid diamide used in it, but also on the formulation The other interfacial activity depends on 1, but it shows that for users with polyhydroxy fatty acid enzymes, various types of silicone foam control agents are more effective than various other types of foam control agents (meaning , You can use lower settings). Silicone foam control agents purchased from X2-3419 and (32_ 3302 (Dow Corn ins) are particularly useful here. The formulator can advantageously select a wide variety of known substances as the go-to laundry composition. Staining agents (see, for example, U.S. Patent Nos. 3,962,152; 4, 1 16,885; 4,238,531; 4,702,857; 4,721,580 and 4,877,896). Other decontamination substances that can be used here; including a nonionic oligomeric esterification product of a mixture , The reaction mixture includes C; i-C4 alkoxy-86-(please read the precautions on the back before filling in this page). Packing. -.Ίτ- Thread (210x297mm) V. Description of the invention (85) A6 B6 group-terminalized polyethylene gas from the position of the base (for example, CHdOChCHdn OH), the origin of terephthalic acid unit (Xuan ,, for Dimethyl phthalate); source of poly (gaseous ethyl) oxygen units (for example, polyethylene glycol 丨 500); source of gas iso-propylene gas units (for example, 1,2-propanediol); And the source of oxygen ethyl gas units (such as ethylene glycol), especially the oxygen ethyl gas units: oxygen iso- The ratio of propylene oxygen units to at least about 0.55: U This non-stepon detergent has the following general formula: R10- (CH2CH20) x 0 — 0 D-^^-C0-CH-CH20 R2 _

C0 (CH2CH20) y (Please read the precautions on the back before filling in this page) Employee Consumer Cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs Du Printing ϋ-^^-C-0 (CHjCHiOJx-R1 where R1 is low sulfide (eg L- C4) alkyl, especially methyl; X and y are each an integer from about 6 to about 100; η is an integer from about 0.75 to about 30; η is an integer from about 0.25 to about 20; and R2 is Η Mixed kiss with CH3 to provide a molar ratio of ethyl gas: oxyisopropyl gas of at least about 0.5: 1. Another better decontamination method that can be used for this qian_type: Patent 4.877 of Xinguo The general anionic type described in 896, but the brilliance is such that the test should be substantially free of H0R0H type single hydride, where R is propylidene or homoalkyl group. Therefore, the decontamination of US Patent 4,877,896 For example, it may include the anti-products of dimethyl terephthalate, ethylene glycol, 1,2-propanediol, and 3-nasulfonic acid, however, other detergents may include, for example, The reaction product of methyl ester, ethylene glycol, 5-n-sulfonic acid isophthalate and 3-n-sulfonic acid benzoic acid. Such reagents are preferably used in granular laundry cleaning tablets The paper size is used in the Chinese National Standard (CNS) A 4 specifications (210x297 mm). • Town, line. Q〇0_ Λ 6 B 6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention Instructions (86) It can also be determined that it can be beneficial to add a non-oversalt bleaching dysentery, especially in the strong granular washing and cleaning. Many kinds of perchlorinated bleach are available, It can be used for this «, but the persulfonate salt is suitable and economical. Therefore, the composition here can contain a solid fishy persulfate salt white rain, usually in the form of Liqina salt, the most combination 3% to 20% of the weight of the child (weight ratio is better 5% to 18%, and most preferably 8% to 15%. Sodium persulfate is an addition compound, which has a corresponding to 2Na3C03 * 3H20 Chemical formula, and it is commercially available as a crystalline solid. Most commercially available substances include low-level heavy metal multivalent candidates, such as EDTA, 1-hydroxyethylene 1,1-diphosphonic acid (HEDP ) Or amine- knee acid salt, which is added during the manufacturing process. For the purpose here, pernitrate can be incorporated into the clear In the composition, no other protection is required, but the preferred embodiment of the present invention is to use a pseudo-stabilized form (FMC) of this substance. Although a variety of coatings can be used, the most economical is the ratio of Si02: Na20 to 1.6: 1 to 2.3: 1, preferably 2.0: 1 silicate reed, coated with an aqueous solution and dried to obtain 2% to 10% (usually 3% to 5%) silicate solid (as persalt Recalculation). Magnesium silicate can also be used, and a chelating agent, such as one of the above, can also be added to this calendar. The particle size of crystalline persulfonate ranges from 350 microns to 450 microns, with an average of about 400 microns. When coated, the crystal S has a size in the range of 400 to 600 microns. Although the heavy metals present in sodium silicate used to make sodium percarbonate can be controlled by adding a polyvalent chelating agent to the reaction mixture, but this has passed -88-(please read the precautions on the back before filling this book Page) This paper is not suitable for the use of the middle class standard (CNS) A4 specifications (210X297). ^ 00026 V. Description of the invention (87) Λ 6 Β6 Master salt still needs to be protected, as tortoise heavy metals are present in this product. As impurities in other ingredients. It has been found that the total content of male, copper and manganese ions in the product should not exceed 25ρρπ «. It should preferably be less than 20ρρβ to avoid unacceptable adverse effects on the stability of the persulfonate salt. XTV The following describes a detergent composition of perborate bleach plus bleach activator of the present invention, which is prepared by mixing the listed ingredients in a mixing drum. In this example, zeolite A pseudo-refers to hydrated crystalline zeolite A, which contains about 20% water and has an average particle size of 1 to 10, preferably 2 to 5 milligrams; LAS refers to C12.3 linear alkylbenzene Sodium sulfonate; AS refers to C14-1S sodium alkyl sulfate; non-ionic substance refers to coconut yeast which is condensed with about 6.5M oxirane per mole of olean and extracts unethoxylated and monoethyl Oxygenated leaven is also condensed into C n A EG. 5; and 3 TP A (¾ 揩 二乙 三 胺 五 醏 激 纳 (please read the precautions on the back and fill in, write this page). Order-The final composition printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs &gt; had been approved »Box granules% a certain too textile 1 51.97 100.0 AS 9.44 18.16 LAS 2.92 5.62 moisture 4.47 8.60 sodium silicate (1.6 ratio ) 1.35 2.60 Sodium sulfate 6.47 12.45 Polyacrylic acid sodium (4500MW) 2.61 5.02 PEG8000 1.18 2.27 -89-This paper scale is universal Chinese National Standard (CNS) A 4 specifications (210X297 public) 00 yarn Λ6 B6 V. Description of invention (88) Non-ionic substances printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 0.46 0.89 Sodium Phosphate 13.29 25.57 Whitening agent 0.20 0. 38 Aluminosilicate reed 9.11 17.53 'DTPA 0.27 0.52 Perfume 0.20 0. 38 NAPA Α Lai granule 2 6.09 100.00 N APAA 2.86 46. 96 LAS 0. 30 4.93 Sulfate and miscellaneous substances 2.93 48.11 NOBS granules 3. 3.88 100.00 NOBS 3.15 81.89 LAS 0.12 3.09 PEG 3000 0.19 4.90 Miscellaneous substance 0.42 10.80 Zeolite particles 4 12.00 100.00 Sodium aluminosilicate 7.39 61.58 PEG 8000 1.50 12.47 Non-ionic substance 1.16 9.70 Moisture 1.66 13.83 Miscellaneous substance 0.29 2.42 £ _η SKS -6 Layered Sodium Silicate 15.84 Protease-90-(please read the precautions on the back before writing this page) The paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210X297) *. 5. Description of invention ( 89) Λ 6 Β6 (0.078¾ g / g active> 0.52 sodium perborate hydrate 1.33, citric acid 6.79 C12-C14N-methyl glucosamine 1.58 all final composition 100.00 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 1 Basic particles are made by spray-drying a mixture of water-based substrates of the listed ingredients. 2—A freshly-made NAPAA wet-splitting sample, its typical 1: contains about 60% water, about 2% pergas acid available gas (Avo) (equivalent to about 36% NAP, 4A> and the rest (about 4%) Unreacted starting material. This wet hydrazine is a crude reaction product of N AAA (monononylacetamide of adipic acid), sulfuric acid, and gasified hydrogen, which is then added to water to stop the reaction , Then filtered, washed with distilled water, washed with phosphate buffer, and finally suction filtered to recover wet corpus. A part of the wet cake is dried at room temperature. 1 and a bath is tried. Its typical Including about 5% Avo (corresponding to about 90% NAPAA) ft about 10% of the starting material at the end of the reaction: in a dry 'bath. The pH value of this test is about 4, 5: Preparation of NAPAA particles, the method is in CUIS1NART mixer is mixed with about 51.7 parts of dried or mixed (containing about 10% of the final reaction material), about 11.1 parts of Ci2.3 linear alkylbenzene sulfonate (LAS) paste (45% active), About 43.3 parts of sodium sulfate and about 30 parts of water. After drying, pass the No. 14 Tyler sieve to sieve the particles (which contain about 47% NAPPA> sieve, and keep all particles not passing 65 ℃ Ty ler sieve. When the tide is analyzed with Mavern particle size, the average amide peroxyacid particle (agglomerate) size is about 5-40 microns, and the intermediate particle size is about H) -20 microns> ~ 91-(Please read the precautions on the back before filling out this page)-Binding · Order _-Line &lt; This paper standard is used in the "National Sample Standard (CNS) A 4 specifications (210χ29γ public excitation) 〇〇6r ^ Λ 6 _____B6_ V. Description of the invention (90) 3 NOBS (nonylaminobenzenesulfonic acid a) _ granules, made according to US Patent 4,997, 596 issued to Bow H ng et al. On March 5, 1991, It is here for reference. 4 Zeolite particles with the following composition are made by mixing zeolite A, PEG 8000 and CnAE6.5T in Eirich R08 intensive mixing system. Lei Fanzao (please read the notes on the back first Then write this page) Installed-The PEG 8000 is printed by the Beigongxiaot Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs for 50% water, and it is at a temperature of about 5TU2.8 t :). The CnAE6.5T image was in a liquid flooded state, and was pseudo-maintained at about 90 T; 32.2t). The M pump oil passes through a bow 12-element static mixer to combine the two liquids. The formed cementitious material has an exit temperature of approximately 75 ° F (U3.9T1) and a drillability of approximately 5000 cps. The ratio of PEG8000 and CnAE6.5T passing through this static mixer is 72:28. Eirich R08 powerful mixer, pseudo-operation in a batch type chess. First, weigh 34.1 kg of powdered zeolite A and place it in the tray of the mixer. Start running the mixer. First rotate the tray counterclockwise at about 75 rpm per minute, then rotate the rotor blade H clockwise at 1800 rpm. The binding substance is then pumped directly from the static mixer into the EiiMch R08 intensive mixer containing zeolite A. The feed rate of this sticky substance is about 2 minutes. Allow the mixer to continue mixing for another 1 minute of Yung-92-Zeon A before drying and after drying (including bound water> 70.00 76.99 PEG 8000 10.80 12.49 CnAE6.5T 8.40 9.72 free water 10.80 0.80 (CNS) A4 specifications (210X297 g *) 〇〇 You Λ6 _B6_ V. Description of the invention (91), and the total batch time is about 3 minutes> Then the batch is discharged and collected in the iron-dimensional drum _ Repeat this batch of steps until about 225 kg of wet product has been collected. Then the discharged product is dried on the fluid bed at 240-270T (116-132 t). This drying step will remove most of the Free water, and change the composition as described above. In batch mode, the total energy input of the mixer to the product is about 1.31 × l0ia ears / at a rate of about 2.18 × 10 ears / kg-second. Kg. Free-flowing agglomerates formed with an average particle size of about 450-500 microns.

Fenfu XV is a liquid laundry detergent composition suitable for use in relatively high concentrations of automatic washing machines commonly used in front loading, especially in Pizhou and in a wide temperature range, as follows: Department% (please read the precautions on the back and then name this page) Binding · Ordering-Coconut Nylon (C12) N-Methylgluconate Compound 14 C14-1SE0 Printed by Cooperative Staff of the Central Standards Bureau of the Ministry of Economic Affairs 2.25) Sulfate, Ha salt 10.0 Ci4-isE0 (7) 4.0 C12-14 alkenyl succinic anhydride 1 4.0 C12-14 fatty acid-3.0 citraconic acid (anhydrous) 4.6 protease (enzyme> 2 0.37 Ternaayl (enzyme) 3 0.12 L ί po 1 ase (Enzyme) 4 0.36 -93-This paper scale is in accordance with the Chinese National Standard (CNS) A 4 specifications (210x297 g) (J V. Description of the invention (92) A6B6 Beigong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs Print

Car * ezy®e (Enzyme) 0 Dequest 2060S8, NaOH (pH value to 7.6) 1,2-propanediol ethanol sodium metaborate CaCla ethoxylated tetraethylenepentamine 7 whitening agent 8 silane 9 decontamination polymer 1G silicon Ketone (foam control) 11 Silicone dispersant 12 Water and less 1 substance 1 from SYNPRAX 3 from ICI or from DTSA from Monsanto 2 as protein_β, as described in EP0 0342177 (November 15, 1989) , The ratio is 40 g / l. 3 Starch K, obtained from NOV0; the ratio is 300 KNU / g. 4 Lipase, obtained from NOV0; the ratio is 100 KLU / g. s fiber jacket, from N0V0; the ratio is 5000 CEVU / liter. 8 Available from Monsanto. 7 Available from BASF as LUTENS0L P6105. 8BLANK0PH0R CPG766, Bayer〇9 silane corrosion inhibitor, available as A1130 from Union Ca "b -94-0. 12 1. 0 5. 5 4. 7 4. 0 4. 0 0. 014 0. 4 0. 13 0 · 04 0. 2 0. 4 0. 2 balance i de, (please read the precautions on the back and then 1 page)

The standard of this paper is the National B Standard (CNS) Grade 4 (210x297mm) Q. A 6 _Β6__ V. Description of the invention (93) or available from Hiils as DYHASYLAN TRIA.MINO. 1 (5 polyester, according to US Patent 4,711,730. 11 Silicone foam control agent, available from Dow Corning as Q2-3302. 12 Dispersant for silicone foam control agent, available from Dow Cor ni ng as DC-3225C. • The preferred fatty acid is the upper end core, which contains 12% oleic acid and _2% each of stearic acid and linseed oleic acid. Fen XVT A hammer granular laundry detergent composition, which is suitable for commonly used Installed in the front of the «automatic washing machine with relatively high concentration, especially in Europe, and (please read the precautions on the back before filling out this page) installed &lt; printed by the Ministry of Economic Affairs Central Standards Bureau Bei Gong Consumer Cooperative * Use within the temperature range as follows: Composition mm% SOKALAN CP5 (100% live ft, NaS) 1 3.52 DEQUEST 2066 (100% acid) 2 0.45 TINOPAL DMS3 0.28 MgS〇4 0.49 Zeolite A (anhydrous) 17.92 CMC (100% active) 4 0.47 Na2C03 9.44 citric acid 3.5 layered silicate SKS-6 12.9 tallow alkyl alkanoate (100% active; Na salt) 2.82 C14-C1S alkyl sulfate (100% Active substance; Na salt) -95-BB Family Sample Standard (CNS) Grade 4 Regulations for this paper (210X297 公 *) Order. Ru. 〇j V Λ 6 Β6 V. Description of the invention (94) c12-c18 alkyl E0 (3) Sulphuric acid a 1.76 Please Cie-CieN-Methyl glucosamine 1 4.1 Read first D0BAH0L C1 a ~ C1 5 E0 (3) 3.54 Read back L IPOLASE (100, 000 LU / g> s 0.42 SAV INASE (4.0 KNPU) 6 1.65 0.55 items and X2-34197 0.22 1.08 Stearyl Alcohol 0.35 Sodium Persuccinate (Coated) 22.3 Tetraethylene Acetyl Diamine (TAED) 5.9 k Zinc Phthalocyanine 0.02 Water (from Zeolite) Balance 1 SOKALAH is polyacrylic acid available from Hoechst Malay reed 2 Monsanto brand pentabenic acid methyldiethylenetriamine. 3 Optical brightener, available from Ciba Gegyi. Printed by Beigong Consumer Cooperative, Bureau of Standards, Ministry of Economic Affairs 4 Trade name FIHHFIX, Available from Metasaliton. 5 SAVINASE protein _, obtained from NOVO. 7 X2-3419 is an abrasive ring foam inhibitor available from Dow Corning. The procedures for preparing the granules include various tower drying, coagulation, dry addition, etc., as described below. The percentage is based on the final composition. A. Crushing and blowing through the tower Using treatment technology, the following ingredients are crushed and the tower is dried. -96-This paper scale uses Chinese National Standard (CNS) A4 specifications (210X297 male dragon :) V. Description of invention (95) Λ 6 Β6 SOKALAN CP5 3.52% DEQUEST 2066 ^ 0.45¾ TINOPAL DMS 0.28% magnesium sulfate 0.49% Zeolite A (Dried) 7.1% CMC 0.47% B. Boundary and thin I agglomerates B1. Straight-chain alkaloids and squalene sodium salt RfM.I) Sulfadiphenone sodium agglomerates-will be tallow alkyl The 50% active paste of thiosulfate salt and 70% of C12-C15E0 (3) sulfuric acid, zeolite A and sodium silicate are condensed according to the following formula (after this condensate is dried, it contributes to the formulation of the detergent ). Tallow alkyl sulfate 2.82% Cia-18E0 (3 &gt; sulfate 1.18% zeolite A 5.35¾ europium sulfonate 4.5% (please read the precautions on the back before filling this page) Dingbei Consumer Cooperatives Printed B2. Γυ-Ci B alkyl sulfone. C ·· X alkane and Z argon even arson. NnRANni. Η, 〇-Πι κ F: n (; n and Πι 〇-Ci glucosamine -Synthesis of C16-ie glucosamine non-ionic substance, in which during the reaction of methyl ester with N-methyl glucosamine, D0BAH0L C12-1SE0 (3) exists. Ci2-18E0 (3) is used as melting point, Thinning I, which allows the reaction to proceed without the formation of undesirable glucose-like glucosamine. Badger gets 20% D0BAH0L Cia-i5 E0 (3) and 80% C18-CieN-methylglucose amide surfactant Mixture and co-agglomerate with 10% sodium citrate -97-This paper size is common in a 1 楳 溳 quasi (CNS) A 4 specifications (210X297 g *) 5. Description of the invention (96) Λ 6 Β6 Secondly, the above The particles are co-condensed with C14-C1S alkyl sulfuric acid and C12-C18E0 (3) sodium sulfate high active lake (70%), and zeolite A is mixed with sodium silicate. This particle proves C18-CieN-methyl Grape amide It has good dispersing ability in water. The overall formula of this particle (after the agglomerate is dried, the contributor printed by the Consumer Cooperative of the Ministry of Economic Affairs and the Bureau of Standards for the cleaning agent formula) is: Cie-CieN-Methylglucosamine 4.1% D0BAN0L Ci2-Cis E0 (3) 0.94% sodium silicate 4.94¾ zeolite A 5.3% (: 14-13 Alkanoic acid Ha 3.596 C12-ie E0 (3) Na sulfate 0.59% c. ILSJSJKLa Add the following ingredients. Peroxysalt 22.3¾ TAED (Tetraethylethylenediamine) 5.9% Layered silicate silicate SKS6 12.90¾ from Hoechst 12.90¾ Citrate 3.5% Lipase 0.42% 100, OOOLu / g SAVINASE 4.0 ΚΝΡϋ 1.65% Zinc呔 青 (photobleach) 0.02% nm m -98-(Please read the back side first. Precautions and then this page)

The size of this paper is used in a B family sample (CNS) A 4 specification (210x297 g *) 5. Description of invention (Λ 6 Β6 DOBAHOL Ci2-CieE0 (3) 2.60% fragrance, 0.53% R. Inquiry method oil system " I will be obtained from Dow Corning's Silicone Foam Suppression Analysis X2-3419 (95% -97% high molecular weight linear silica; 396-5% hydrophobic silica), and Zeolite A (2-5 micron size), starch and Stearic-based fermented catfish co-aggregating agent. This particle has the following formula: Zeolite A 0.22¾ starch 1.08% (please read the notes on the back first, and then fill in this page) Printed by Beigong Consumer Cooperative, Bureau of Standards, Ministry of Economic Affairs X2-3419 Stearic enzymes when used in European washing machine 30Ό, 40t :, 60 * 0 and 9010 detergent preparations Hao Shiqing Yue solubility In any of the foregoing examples, the equivalent amount of maltamide interface active awakening amine / In the maltoglycosamine industry composition, the use of acetaminophen is used. In addition, the use of «sour base sweetness can provide superior foaming effect. It is about 5% of the group that wants to use high foaming, more preferably less than about 2% fatty acids are present because they will all be 0.22% 0.35¾, for example, in AEG brand washing machines, when using 85 grams of Jiejiem in Xunchen , This clear, superior performance and foam control. Fenzheng XV IT fatty acid glucose is replaced by a surfactant, or a mixture of surfactants derived from plant sources. These seem to be helpful in the final formulation In the case of cold-temperature stable vegetable sickle (aka &quot; sultaine ") interfacially active compound, it is best to have only less than, and most preferably, there is substantially no c14 or higher sulfonate to suppress foaming. Group 99-Packing--Order _ Line-This paper standard is used in the national B standard (CNS) A 4 specifications (210x297 mm). Printed by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperatives 〇〇0〇 ^^ Λ 6 ' _Ιί_6 Fifth, the description of the invention ((J8) compounders, will hope to avoid color, the amount of such foaming fatty acid into the high foaming composition with polyhydroxy fatty acid sleep amine, and / or avoid color When the final composition is stored, C14 and higher sulfonic acid are formed. A simple way is to use the C12 ester reactant to prepare the polyhydroxy fatty acid amides here. Fortunately, use amine oxide or sulfonated beet sickle interface activity Thin, can be overcome due to fatty acids Some of the negative foaming effects caused. Want to add anionic optical brighteners containing relatively high concentrations (such as 10% and greater> anionic or polyanionic substitutes (such as polycarboxylate builder) The formulator of the liquid cleaner can find this whitening cut pre-mixed with water and polyhydroxy fatty acid amide, and then add this premix to the final composition, it is useful. Polyglutamic acid or multi-day door Aspartate dispersant can be used together with zeolite-builder detergent. AE 黑 髑 or thin Η and DC-544 (Dow Corning) are other habits that can be used for foam control here. Those skilled in this chemistry should be aware of the use of two- and higher brews (such as maltose) The preparation of the polyhydroxylipid cage amines here will result in the formation of polyhydroxy fatty acid amides, in which the linear substituent Z is "capped" by the polyhydroxyhydrazine structure. This kind of substance exchange is completely intended to be used in this article, and it does not deviate from the scope and scope of the patents and patents shown and claimed in this article. (Please read the notes on the back of item r before writing this page) -100-This paper scale is easy to use Chinese Sleepy Standard (CNS) A 4 specifications (210X297 public *) Eighth Ο — 08—Patent No. 9 Apply for supplementary instructions in Chinese (July 81) (omitted) Under my fingertips and control • Conducted various tests to evaluate the cleansing compound containing enzymes and various deionized surfactants, as well as the case The stability and performance of similar compounds of polyhydroxy fatty acid glycoamine surfactants are shown. The following is the generational test. In the following tests, each writing has the following significance: -N LAS is the conventional alkyl benzene sulfonate surfactant AES is the conventional alkyl ethoxy laurate surfactant AS is the conventional alkyl sulfonate interface activity PHFA is an interface active cocoon based on polyhydroxy fatty acid acetamide used in this case. Based on these tests, I can conclude: (1) The lipase enzyme cleans the sister compound in the potent liquid suspect containing PHFA and anionic surfactant The storage stability is better than that of the sister compound containing only anionic interface active surface; (2) Fat _ yeast is in the sister compound containing PHFA and in the sister compound containing sodium ion surfactant The cleansing activity of the oily dirt is equal; (3) The method disclosed in Μ 本 菜 · By using PHFA in the sister compound, K can be prepared with a large amount of enzyme stability and at least equal to the anti-oil pollution suspect Wash sister composition. The following tests, including various stains and stains, can support my conclusions made above. a_ 1. Cells of 81 acres, a liquid detergent composition with mixed tartrate / succinate (4%) and citrate (8%) rib lotion

ENN0092.G 1 -1

Fat K activity keeps S at 90 T; storage time? Yupeng 2 Spoon LAS / AES / PHFA 100 100 LAS / AES 18 14 AS / AES / PHFA 100 83 * AS / AES 57 44 * 26 days / 90F 2 titration面 ti [播! A single surfactant solution in ImM Cf2 fat_activity

Wt% Relative hh Example Water — 100 LAS 6.0 39 C23AS 6.0 43 AES 6.0 0 PHFA 6.0 53 W W Cleaner as described in (1) above. US / AES vs. LAS / AES / PHFA △ PSIT was washed with phase control without 1 lipase (second cycle) I.AS/AFS I.AS/AF.S/PHFA B. Grease / c1 1.18 0.26 Macaroni S / PC2 2.12 2.38 Macaroni β / c 1.97 2.f &gt;? average 1.76 1.72

EN \ 0092.G 2 ^ 005: 0ΰ * PSD is a scoring unit, and the professional evaluation team judges the removal of dyeing with the naked eye. 1MPC "World cotton suspect 2 &quot; PC" world polyester / cotton mixed suspect The above-mentioned (1) cleansing agent 〇AS / AES seal AS / AES / PHFA △ PSU to the corresponding control sister without lipase »L * polyester f 毎 [2 漷 pre-) .Fat / c 0.37 0.61 macaroni β / P c 1.36 0.44 macaroni e / c 0.98 2.09 macaroni sauce / P Ο.δΟ 0.10 average 0.48 0.81 box of physiological AS / AFS AS / AFS / PHFA B. fat / c 2.73 1.42 macaroni S / pc 1.69 1.56 macaroni sauce / c 3.73 1.42 average _ 2.37 1.76 "as described in (1) above. AS / AES pair / PHFA / AES Δ PSU pair corresponding control sisters without lipase »浼 POL （Fei 2 inserted 瑱）

\. ^ S, / ^ KS, PHFA / AES B. Grease / c 1.56 0.58 Macaroni S / pc 0.88 0.90 -3-en \ 0092. G

OOo: ^ macaroni noodles / c average 2.9 4 1.80 2.2R 1.28

l. AS / ARS PHFA / AF.S B. Grease / c 1.02 3.74 Macaroni Seedlings / pc 0.89 1.50 Macaroni Road / C 0,87 1,06 average 0.93 1.77 (omitted) -4- en \ 0092. g

Claims (1)

”中 t G HR 8 ό o d 请 o’ No. of the original / &amp; a / 范 一 οto 7 7 7 7 A B C Π Printed and amended by the Central Kneading Bureau of the Ministry of Economic Affairs 81. 12,22 Supplement 1. An improved detergent compound containing one or more anionic surfactants, nonionic surfactants or mixtures thereof, And at least 0.0001% cleansing enzymes, the improvement of which is included in the composition, adding 1% to 50% of the following polyhydroxy fatty acid acetamide substance Q Ri Rz-c-N-2 where R1 is Η, Ci-U Alkyl, 2-hydroxyethyl, 2-hydroxypropyl, 1 ^ 2 is Cn-Cn alkyl or alkenyl, and Z is a linear alkyl chain with at least 5 carbon atoms containing at least 3 hydroxyl groups directly connected To the polyhydroxy hydrocarbon group to the bond, Z is derived from a cannose sugar, wherein the enzyme includes alkaline protease, amylase, lipase, trichosinase, or peroxidized IS, or a mixture thereof. 2. The compositional protease according to item 1 of the patent application. 3. The composition according to item 1 of the patent application hydroxy fatty acid amide. 4. The sister compound Z according to item 1 of the patent application scope is -CH2 (C_) 4CH20H. 5. According to the sister compound of the first patent application, fatty acid amide, Z is derived from glucose or maltose or a mixture thereof. 6. According to the sister compound of the first item in the scope of application, Z is derived from a mixture of monosaccharides, double hungers and selected polysaccharides, which contains at least 1% by weight of Shuangku, which can be obtained from Plant source. 7. The sister compound according to item 1 of the patent application scope, which contains 0.0001%, where the enzyme includes alkali, which includes at least more than 3%, where R1 is methyl, and, regarding the polyhydroxyl group (please read the back (Notes and fill in this page again) • Installed • • Ordered. • Line • f 4 (210X297 public) 200 miscellaneous A7 B7 C7 D7 6. Apply for patent scope to 2% of active enzymes * and at least 1% by weight Compared with the polyhydroxy fatty acid acetamide. 8. The sister compound according to item 1 of the patent application scope * wherein the anionic surfactant is not an alkyl benzoate surfactant. 9. A liquid cleanser composition, which contains: (a) 1% to 50% anionic surfactant; (b) 0.0001% to 2% active cleaning enzyme, wherein the enzyme contains alkaline protease, starch Enzymes, lipases, reductases, or peroxidases, or mixtures thereof; (c) 1% to 50% polyhydroxy fatty acid acylamines of the formula 0 Rz-C-fl-z where R1 is H, Ca -C * alkyl, 2-hydroxyethyl, 2-hydroxypropyl, alkyl or alkenyl, and Z is a linear alkyl group with at least 5 carbon atoms containing at least 3 hydroxyl groups directly attached to the chain Polyhydroxy hydrocarbon group, Z is derived from a kind of raw sugar, and the sister compound is substantially free of alkylbenzene sulfonate. (Please read the notes on the back before filling in the book) it Central Ministry of Economic Affairs Printed by the quasi-bureau 10. The sister compound according to item 9 of the patent application scope, wherein the anionic surfactant includes: R0 (A) "S03M where R is unsubstituted C10-C24 alkyl or hydroxyalkyl (C1〇-C24) A is an ethoxy or propoxy unit, m is greater than 0 and M is hydrogen or cation. A 4 (210X297 g; ¥) ^ 00όZO6 Α7 Β7 C 7 D7 VI. Patent Application Range ..................................................... ........ 51 · (please read the precautions on the back before you go to this page) The composition according to item 9 of the patent application, where R is unsubstituted C12-C18 alkyl, A It is an ethoxy unit, m is 0.5 to 6, and M is a cation. 12. According to the eleventh compound of the patent application scope, it contains 4% to 40% of the anionic surfactant. 13. According to the patent application The composition of item 12 of the scope, wherein the anionic; the ratio of the surfactant to the polyhydroxy fatty acid acetamide is 1: 2 to 8: 1 0 14. According to the sister compound of item 11 of the patent application scope, The cleansing enzymes include protease and one other cleansing enzyme. 15. According to the sister compound of item 14 of the patent application range _ * based on active substances, each of which contains 0.0001% to 1% protease and lipase. • Order · 16. According to the sister compound of item 15 of the scope of patent application, which further contains 0.5% to 5% by (: 8- (: 22 linear alcohol and 1 to 25 mole ethylene oxide (per mole enzyme) The condensation product formed. According to the sister compound of item 15 of the patent application scope, wherein the lipase is derived from Humicola lanuginosa (Humicola). Green 18. According to the sister compound of item 12 of the application scope, which contains 0.5% to 12 % The polyhydroxy fatty acid acetamide. 19. According to the compound of claim 18 of the patent application, the polyhydroxy fatty acid amide> Z is derived from glucose or maltosan or a mixture thereof. Printed and printed by the Central Bureau of Standards of the Ministry of Economic Affairs 20. The sister compound according to item 18 of the patent application range • Z is derived from Shanku, Shuangji and selected mixtures of polyglycosides> which contains at least 1% by weight Sugars, the mixture can be obtained from plant sources. f 4 (210X297 公 潆) & &gt;. Jil 02 [7 7 7 7 AB c D t 'patent application scope 21 · The composition according to item 18 of the patent application garden% to 10% water-soluble alkyl tellurium Acid salt. 22. The combination according to item 9 of the scope of patent application * which contains 0.00 1% to 1%% 23. The substance according to item 9 of the scope of patent application, which is at 10% pH value under 2〇υ. 24. According to the sister compound of item 23 of the patent application scope, which further contains 1 K of active substance as a benchmark The sister of 6.5 to 11.0 is in the anionic field (please read the precautions on the back before filling in this page). The ratio of surfactant to polyhydroxy fatty acid acetamide is 3: 1 to 4: 1 25. According to The composition of claim 23, wherein the composition further contains 0.1% to 50% cleaning builder. 26. The sister compound according to item 25 of the patent application scope, wherein the sister compound contains 0.1% to 20% citric acid, 0.1% to 20% sodium tartrate succinate, and 0.1% to 20% oxydisuccinic acid Salt, 0.1% to 50% alkenyl succinate, or a mixture thereof. 27. According to the sister compound of item 26 of the scope of the patent application * regarding the polyhydroxy fatty acid amide, Z is derived from glucose or maltose or a mixture thereof. 28. The sister compound according to item 26 of the patent application scope, wherein Z is derived from a mixture of monosaccharides, diacids and selected polysaccharides, which contains at least 1% by weight of disaccharides, the mixture is available from Plant source. Printed by the Central Kneading Bureau of the Ministry of Economic Affairs 29.-A method to enhance the cleaning enzyme performance of the cleaning agent compound, which contains at least 0.0001% cleaning enzyme in the presence of an aqueous medium. This method is included in the sister Add 1% to 50% of the compound to the following formula: Dopamine 4 (210X297). 6. Patent application model A7 B7 C7 D7-based fatty acid amide compound 0 R1 »I R2-C-N-Z: where R1 Is Η, (Μ4 alkyl, 2-hydroxyethyl, 2-hydroxypropyl, R2g C ^ -Cn alkyl or alkenyl, and Z is a linear alkyl group having at least 5 carbon atoms contains at least 3 The hydroxyl group is directly connected to the polyhydric, hydrocarbyl group of the chain, and Z is derived from a dow sugar, wherein the enzyme includes alkaline protease, amylase, lipase, cellulase, or peroxidase, or a mixture thereof. . According to the method of claim 29, wherein Z is derived from glucose, maltose or a mixture thereof, which can be obtained from plant sources. 31. According to the method of claim 29, wherein the aqueous medium is substantially free of alkanes Benzene sulfonate surfactant. (Please read the back Jing intended to do to fill out this page) • installed. Play · Ministry of Economic Affairs Bureau of the Central Sao quasi-printed T 4 (210X 297 public shaggy dog) 5