SU786863A3 - Компонент катализатора дл полимеризации пропилена - Google Patents
Компонент катализатора дл полимеризации пропилена Download PDFInfo
- Publication number
- SU786863A3 SU786863A3 SU772455223A SU2455223A SU786863A3 SU 786863 A3 SU786863 A3 SU 786863A3 SU 772455223 A SU772455223 A SU 772455223A SU 2455223 A SU2455223 A SU 2455223A SU 786863 A3 SU786863 A3 SU 786863A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- catalyst
- camphor
- polymerization
- ketone
- component
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 34
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims abstract description 9
- 238000006116 polymerization reaction Methods 0.000 title claims description 29
- 229920000642 polymer Polymers 0.000 claims abstract description 17
- 150000002576 ketones Chemical class 0.000 claims abstract description 16
- 229960000846 camphor Drugs 0.000 claims description 23
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 20
- 241000723346 Cinnamomum camphora Species 0.000 claims description 20
- 229930008380 camphor Natural products 0.000 claims description 20
- -1 bicyclic monoterpene ketones Chemical class 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 4
- USMNOWBWPHYOEA-UHFFFAOYSA-N 3‐isothujone Chemical compound CC1C(=O)CC2(C(C)C)C1C2 USMNOWBWPHYOEA-UHFFFAOYSA-N 0.000 claims description 2
- 229930003642 bicyclic monoterpene Natural products 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 229930003647 monocyclic monoterpene Natural products 0.000 claims description 2
- 150000002767 monocyclic monoterpene derivatives Chemical class 0.000 claims description 2
- 229930007110 thujone Natural products 0.000 claims description 2
- VARQGBHBYZTYLJ-UHFFFAOYSA-N tricosan-12-one Chemical compound CCCCCCCCCCCC(=O)CCCCCCCCCCC VARQGBHBYZTYLJ-UHFFFAOYSA-N 0.000 claims 2
- USVZHTBPMMSRHY-UHFFFAOYSA-N 8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-9-[2-(2-chlorophenyl)ethyl]purin-6-amine Chemical compound C=1C=2OCOC=2C=C(Br)C=1SC1=NC=2C(N)=NC=NC=2N1CCC1=CC=CC=C1Cl USVZHTBPMMSRHY-UHFFFAOYSA-N 0.000 claims 1
- 125000001309 chloro group Chemical class Cl* 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 125000002619 bicyclic group Chemical group 0.000 abstract description 2
- 125000002950 monocyclic group Chemical group 0.000 abstract description 2
- 239000004711 α-olefin Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 21
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 20
- 238000000227 grinding Methods 0.000 description 17
- 238000000034 method Methods 0.000 description 16
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229920000576 tactic polymer Polymers 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010011878 Deafness Diseases 0.000 description 1
- 101000800055 Homo sapiens Testican-1 Proteins 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 102100033390 Testican-1 Human genes 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000002288 cocrystallisation Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229930003658 monoterpene Natural products 0.000 description 1
- 235000002577 monoterpenes Nutrition 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- OJUGVDODNPJEEC-UHFFFAOYSA-N phenylglyoxal Chemical compound O=CC(=O)C1=CC=CC=C1 OJUGVDODNPJEEC-UHFFFAOYSA-N 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/731,267 US4124530A (en) | 1976-10-12 | 1976-10-12 | Olefin polymerization catalyst comprising a monoterpenic ketone and process employing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU786863A3 true SU786863A3 (ru) | 1980-12-07 |
Family
ID=24938791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU772455223A SU786863A3 (ru) | 1976-10-12 | 1977-02-25 | Компонент катализатора дл полимеризации пропилена |
Country Status (26)
| Country | Link |
|---|---|
| US (1) | US4124530A (https=) |
| JP (1) | JPS5347393A (https=) |
| AR (1) | AR213512A1 (https=) |
| AT (1) | AT354725B (https=) |
| AU (1) | AU507801B2 (https=) |
| BE (1) | BE851154A (https=) |
| BR (1) | BR7700658A (https=) |
| CA (1) | CA1090766A (https=) |
| CH (1) | CH635112A5 (https=) |
| CS (1) | CS196208B2 (https=) |
| DE (1) | DE2705825A1 (https=) |
| ES (1) | ES456358A1 (https=) |
| FR (1) | FR2367778A1 (https=) |
| GB (1) | GB1575238A (https=) |
| HU (1) | HU176011B (https=) |
| IN (1) | IN145983B (https=) |
| IT (1) | IT1081473B (https=) |
| MX (1) | MX144111A (https=) |
| NL (1) | NL7701148A (https=) |
| NO (1) | NO151589C (https=) |
| PL (2) | PL114939B1 (https=) |
| PT (1) | PT67123B (https=) |
| RO (1) | RO72501A (https=) |
| SU (1) | SU786863A3 (https=) |
| TR (1) | TR19253A (https=) |
| ZA (1) | ZA77534B (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4415714A (en) * | 1979-01-02 | 1983-11-15 | Conoco Inc. | Catalyst and method for preparation of drag reducing substances |
| US4433123A (en) * | 1979-01-29 | 1984-02-21 | Conoco Inc. | Polymerization process for drag reducing substances |
| US4493903A (en) * | 1981-05-12 | 1985-01-15 | Conoco Inc. | Polymerization process for drag reducing substances |
| US4493904A (en) * | 1981-06-29 | 1985-01-15 | Conoco Inc. | Catalyst and method for preparation of drag reducing substances |
| US4701505A (en) * | 1984-09-26 | 1987-10-20 | Mitsubishi Petrochemical Company Limited | Process for production of olefin polymers |
| US5259986A (en) * | 1991-12-31 | 1993-11-09 | Phillips Petroleum Company | Copper (I) carboxylate-containing olefin complexing reagents |
| US5841627A (en) * | 1997-06-03 | 1998-11-24 | Univ Chicago | Pseudo-capacitor device for aqueous electrolytes |
| US6306983B1 (en) | 1999-05-14 | 2001-10-23 | 3M Innovative Properties Company | Ziegler-Natta polymerization of alpha-olefins in the presence of non-polymerizing olefins |
| JP2005518655A (ja) * | 2001-07-15 | 2005-06-23 | アプライド マテリアルズ インコーポレイテッド | 処理システム |
| CN113929803B (zh) * | 2021-11-11 | 2022-11-01 | 中国科学院长春应用化学研究所 | 一种高强度航空轮胎胎面仿生橡胶及其制备方法、应用 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3129256A (en) * | 1959-12-01 | 1964-04-14 | Gulf Research Development Co | Alkylation of benzene with propylene in the presence of a catalyst containing titanium tetrachloride, alkyl aluminum sesquichloride, and oxygen |
| US3210332A (en) * | 1963-05-03 | 1965-10-05 | Phillips Petroleum Co | Production of solid olefin polymers |
| US3549717A (en) * | 1968-02-28 | 1970-12-22 | Gosei Chem Ind Co Ltd | Process for the production of 1,5,9-cyclododecatriene |
| US3843619A (en) * | 1968-10-12 | 1974-10-22 | Sir Soc Italiana Resine Spa | Process for polymerizing olefins |
| US3530107A (en) * | 1968-11-06 | 1970-09-22 | Mitsui Toatsu Chemicals | Modified catalyst system and process for production of polymers of 1-olefins |
| US3701763A (en) * | 1969-10-20 | 1972-10-31 | Mitsui Petrochemical Ind | Process for polymerization of olefins and catalysts therefor |
| US3850899A (en) * | 1970-06-15 | 1974-11-26 | Mitsui Petrochemical Ind | Process for polymerizing olefins and catalyst therefor |
-
1976
- 1976-10-12 US US05/731,267 patent/US4124530A/en not_active Expired - Lifetime
-
1977
- 1977-01-03 ZA ZA770534A patent/ZA77534B/xx unknown
- 1977-01-25 AU AU21623/77A patent/AU507801B2/en not_active Expired
- 1977-01-25 GB GB2936/77A patent/GB1575238A/en not_active Expired
- 1977-01-27 AR AR266338A patent/AR213512A1/es active
- 1977-01-27 CA CA270,535A patent/CA1090766A/en not_active Expired
- 1977-02-01 MX MX167900A patent/MX144111A/es unknown
- 1977-02-02 NO NO770349A patent/NO151589C/no unknown
- 1977-02-02 BR BR7700658A patent/BR7700658A/pt unknown
- 1977-02-03 NL NL7701148A patent/NL7701148A/xx not_active Application Discontinuation
- 1977-02-07 BE BE2055648A patent/BE851154A/xx not_active IP Right Cessation
- 1977-02-07 IT IT47943/77A patent/IT1081473B/it active
- 1977-02-08 RO RO7789318A patent/RO72501A/ro unknown
- 1977-02-09 CS CS77853A patent/CS196208B2/cs unknown
- 1977-02-11 CH CH171077A patent/CH635112A5/de not_active IP Right Cessation
- 1977-02-11 DE DE19772705825 patent/DE2705825A1/de not_active Ceased
- 1977-02-14 AT AT97977A patent/AT354725B/de not_active IP Right Cessation
- 1977-02-15 HU HU77SA3012A patent/HU176011B/hu unknown
- 1977-02-17 TR TR19253A patent/TR19253A/xx unknown
- 1977-02-25 PL PL1977196265A patent/PL114939B1/pl not_active IP Right Cessation
- 1977-02-25 SU SU772455223A patent/SU786863A3/ru active
- 1977-02-25 IN IN280/CAL/77A patent/IN145983B/en unknown
- 1977-02-25 PL PL1977213117A patent/PL110430B1/pl unknown
- 1977-02-28 ES ES456358A patent/ES456358A1/es not_active Expired
- 1977-03-03 FR FR7706184A patent/FR2367778A1/fr active Granted
- 1977-03-04 JP JP2373277A patent/JPS5347393A/ja active Granted
- 1977-10-06 PT PT67123A patent/PT67123B/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO72501A (ro) | 1982-02-26 |
| ATA97977A (de) | 1979-06-15 |
| CH635112A5 (de) | 1983-03-15 |
| BE851154A (nl) | 1977-08-08 |
| JPS6128681B2 (https=) | 1986-07-02 |
| PL110430B1 (en) | 1980-07-31 |
| MX144111A (es) | 1981-08-27 |
| IT1081473B (it) | 1985-05-21 |
| CS196208B2 (en) | 1980-03-31 |
| PL114939B1 (en) | 1981-03-31 |
| AR213512A1 (es) | 1979-02-15 |
| AT354725B (de) | 1979-01-25 |
| NO151589B (no) | 1985-01-21 |
| NO151589C (no) | 1985-05-08 |
| DE2705825A1 (de) | 1978-04-13 |
| FR2367778B1 (https=) | 1981-05-22 |
| ZA77534B (en) | 1977-12-28 |
| US4124530A (en) | 1978-11-07 |
| CA1090766A (en) | 1980-12-02 |
| PT67123B (en) | 1979-03-16 |
| AU507801B2 (en) | 1980-02-28 |
| GB1575238A (en) | 1980-09-17 |
| AU2162377A (en) | 1978-08-03 |
| NL7701148A (nl) | 1978-04-14 |
| BR7700658A (pt) | 1978-05-02 |
| JPS5347393A (en) | 1978-04-27 |
| ES456358A1 (es) | 1978-01-16 |
| FR2367778A1 (fr) | 1978-05-12 |
| IN145983B (https=) | 1979-02-03 |
| PL196265A1 (pl) | 1978-05-08 |
| TR19253A (tr) | 1978-08-15 |
| HU176011B (en) | 1980-11-28 |
| NO770349L (no) | 1978-04-13 |
| PT67123A (en) | 1977-11-01 |
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