SU735171A3 - Способ получени транс-1,4-полибутадиена - Google Patents
Способ получени транс-1,4-полибутадиена Download PDFInfo
- Publication number
- SU735171A3 SU735171A3 SU752159096A SU2159096A SU735171A3 SU 735171 A3 SU735171 A3 SU 735171A3 SU 752159096 A SU752159096 A SU 752159096A SU 2159096 A SU2159096 A SU 2159096A SU 735171 A3 SU735171 A3 SU 735171A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- trichloroacetic acid
- vanadium
- polybutadiene
- triacetylacetonate
- trans
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 8
- 229920003194 trans-1,4-polybutadiene polymer Polymers 0.000 title claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 12
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims abstract description 7
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 7
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims abstract description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 4
- 239000003054 catalyst Substances 0.000 claims abstract description 4
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 3
- 239000002904 solvent Substances 0.000 claims abstract description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- VHFUHRXYRYWELT-UHFFFAOYSA-N methyl 2,2,2-trichloroacetate Chemical compound COC(=O)C(Cl)(Cl)Cl VHFUHRXYRYWELT-UHFFFAOYSA-N 0.000 claims description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 2
- 239000001257 hydrogen Substances 0.000 abstract description 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 150000005826 halohydrocarbons Chemical class 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 150000003682 vanadium compounds Chemical class 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 6
- 239000000047 product Substances 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- 229920008712 Copo Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT25936/74A IT1017870B (it) | 1974-08-02 | 1974-08-02 | Procedimento per la preparazione in alta resa di polimeri a strut tura trans delle diolefine coniu gate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU735171A3 true SU735171A3 (ru) | 1980-05-15 |
Family
ID=11218189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU752159096A SU735171A3 (ru) | 1974-08-02 | 1975-08-01 | Способ получени транс-1,4-полибутадиена |
Country Status (20)
| Country | Link |
|---|---|
| JP (1) | JPS5137977A (en, 2012) |
| AU (1) | AU8323775A (en, 2012) |
| BE (1) | BE832059A (en, 2012) |
| CA (1) | CA1042141A (en, 2012) |
| CH (1) | CH606146A5 (en, 2012) |
| CS (1) | CS192550B2 (en, 2012) |
| DD (1) | DD119251A5 (en, 2012) |
| DE (1) | DE2534495A1 (en, 2012) |
| DK (1) | DK351775A (en, 2012) |
| FR (1) | FR2280647A1 (en, 2012) |
| GB (1) | GB1519471A (en, 2012) |
| HU (1) | HU171173B (en, 2012) |
| IL (1) | IL47731A0 (en, 2012) |
| IT (1) | IT1017870B (en, 2012) |
| LU (1) | LU73115A1 (en, 2012) |
| NL (1) | NL7509278A (en, 2012) |
| NO (1) | NO752706L (en, 2012) |
| SE (1) | SE7508743L (en, 2012) |
| SU (1) | SU735171A3 (en, 2012) |
| ZA (1) | ZA754585B (en, 2012) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5845240A (ja) * | 1981-09-14 | 1983-03-16 | Bridgestone Corp | ゴム組成物およびそれを用いたラジアルタイヤ |
-
1974
- 1974-08-02 IT IT25936/74A patent/IT1017870B/it active
-
1975
- 1975-07-16 ZA ZA00754585A patent/ZA754585B/xx unknown
- 1975-07-17 CA CA231,723A patent/CA1042141A/en not_active Expired
- 1975-07-17 GB GB30115/75A patent/GB1519471A/en not_active Expired
- 1975-07-18 IL IL47731A patent/IL47731A0/xx unknown
- 1975-07-21 AU AU83237/75A patent/AU8323775A/en not_active Expired
- 1975-07-29 FR FR7523699A patent/FR2280647A1/fr active Granted
- 1975-07-31 LU LU73115A patent/LU73115A1/xx unknown
- 1975-07-31 DD DD187607A patent/DD119251A5/xx unknown
- 1975-07-31 CH CH1007975A patent/CH606146A5/xx not_active IP Right Cessation
- 1975-07-31 CS CS755359A patent/CS192550B2/cs unknown
- 1975-08-01 HU HU75SA00002823A patent/HU171173B/hu unknown
- 1975-08-01 NO NO752706A patent/NO752706L/no unknown
- 1975-08-01 BE BE158886A patent/BE832059A/xx not_active IP Right Cessation
- 1975-08-01 SE SE7508743A patent/SE7508743L/xx unknown
- 1975-08-01 JP JP50093241A patent/JPS5137977A/ja active Pending
- 1975-08-01 DK DK351775A patent/DK351775A/da unknown
- 1975-08-01 DE DE19752534495 patent/DE2534495A1/de active Pending
- 1975-08-01 SU SU752159096A patent/SU735171A3/ru active
- 1975-08-04 NL NL7509278A patent/NL7509278A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CS192550B2 (en) | 1979-08-31 |
| GB1519471A (en) | 1978-07-26 |
| LU73115A1 (en, 2012) | 1976-03-02 |
| FR2280647A1 (fr) | 1976-02-27 |
| IT1017870B (it) | 1977-08-10 |
| DK351775A (da) | 1976-02-03 |
| BE832059A (fr) | 1976-02-02 |
| FR2280647B1 (en, 2012) | 1980-07-25 |
| ZA754585B (en) | 1976-07-28 |
| JPS5137977A (en, 2012) | 1976-03-30 |
| IL47731A0 (en) | 1975-11-25 |
| HU171173B (hu) | 1977-11-28 |
| CA1042141A (en) | 1978-11-07 |
| SE7508743L (sv) | 1976-02-03 |
| NL7509278A (nl) | 1976-02-04 |
| AU8323775A (en) | 1977-01-27 |
| NO752706L (en, 2012) | 1976-02-03 |
| CH606146A5 (en, 2012) | 1978-10-31 |
| DD119251A5 (en, 2012) | 1976-04-12 |
| DE2534495A1 (de) | 1976-02-12 |
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