SU685160A3 - Вулканизуема резинова смесь на основе карбоцепного каучука - Google Patents

Вулканизуема резинова смесь на основе карбоцепного каучука

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Publication number
SU685160A3
SU685160A3 SU772456906A SU2456906A SU685160A3 SU 685160 A3 SU685160 A3 SU 685160A3 SU 772456906 A SU772456906 A SU 772456906A SU 2456906 A SU2456906 A SU 2456906A SU 685160 A3 SU685160 A3 SU 685160A3
Authority
SU
USSR - Soviet Union
Prior art keywords
rubber
cabrochain
naphthol
vulcanizable
mixture
Prior art date
Application number
SU772456906A
Other languages
English (en)
Inventor
Джордж Пинто Фрэнк
Каплан Эрл
Original Assignee
Американ Цианамид Компани (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Американ Цианамид Компани (Фирма) filed Critical Американ Цианамид Компани (Фирма)
Application granted granted Critical
Publication of SU685160A3 publication Critical patent/SU685160A3/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34922—Melamine; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/721—Fibre-reinforced materials
    • B29C66/7214—Fibre-reinforced materials characterised by the length of the fibres
    • B29C66/72141—Fibres of continuous length
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)
  • Moulding By Coating Moulds (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Description

(54) ВУЛКАНИЗУЕМАЯ РЕЗИНОВАЯ СМЕСЬ НА ОСНОВЕ КАРБОЦЕПНОГО КАУЧУКА
Изобретение относитс  к резиновой промышленности. Известна резинова  смесь на основе карбоцепного каучука, включаю ща  N-меламин формулы ,ox ., г гдеХ-Н, низший Cj-Cg-алкил; В , В, Bj, Bj и Bjj - Н, низши Ci-Cj-алкил, и адгезионную добавку, например резотропин 1. Однако резины.из такой смеси хот  и имеют необходимые адгезион свойства (к корду), например до 30 кгс/см, но обладают значительно токсичностью из-за использовани  резотропина. Цель изобретени  состоит в снижении токсичности резины из такой смеси при сохранении повышенной адгезии резины к корду. Поставленна  це.пъ достигаетс  т что вулканизуема  резинова  смесь . на основе карбоцепного каучука, вк чающа  N-меламин указанной выше формулы, в качестве адгезионной добавки содержит соединение, выбранное из группы 1, l-метиленбис- (2-нафтол) ,2,2-метиленбис (1-нафтол); смесь 1 1-метиленбис (2-нафтола) и 2,2-метиленбис (1-нафтола) ; 1, l-тиобис (2-нафтол ), 2,2-тиобис(1-нафтол); смесь 1, l-туобис(2-нафтола) и 2,2-тиобис ( 1-нафтола) ; 4, 4-метиленбиа (1-нафтол) 4 , 4-тиобис (1-нафтола) , при соотношении компонентов,вес.ч.: Карбоцепной каучук100 N-Меламин указанной формулы1-10 Адгезионна  добавка . 0,5-8. Изготовление смеси и вулканизата из нее состоит в следующем: каучук, газовую сажу, окись цинка, целевые добавки и соединение биснафтола смешивают в смесителе Бэнбера при температуре . Образовавшуюс  маточную смесь смешивают на стандартных резиновых вальцах с серой, ускорител ми, окисью кремни  и Nметиламином , содержащим у к-атома замещенную оксиметильную группу. Способную к вулканизации см муют , привод т в контакт с ющим материалом, т.е. с тек волокном или стальной прово и вулканизуют. Возможен вариант обработ латексом бутадиен-стирольно ( SBR) или бутадиен-винилпир. каучука- или их смесью, сод соединение биснафтола и N-м имеющий у N-атома замещенну тильную группу (пропитанный привод т в контакт с резино и вулканизуют). Пример. Получают сл маточные смеси, содержащие каучука. В табл.1 приведена рецеп точных смесей. Табл Натуральный каучук (SMR-5L) 52 52 52 18 18 Полибутадиен SBR 1500 (бутадиенстирольный каучук) 30 Газова  сажа Окись цинка Стеаринова  кислота 2 Цианфлекс Е Sff 2 Резорц(н2 1, l-метиленбис (2-нафтол) 1,1- иобис (2-н4фтол) 151 151 15
продукт взаимодействи  дифениламина и ацетона.
Эти маточные смеси на стандартных резиновых вальцах при в течение 5 мин, соедин ют с компонентами, указанными в табл.2.
в
«1
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i,

Claims (1)

1. Патент США 3361617, .кл. 161-247, 1963 (прототип),
SU772456906A 1976-03-08 1977-03-05 Вулканизуема резинова смесь на основе карбоцепного каучука SU685160A3 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/664,468 US4092455A (en) 1976-03-08 1976-03-08 Use of methylenebis- and thiobisnaphthols as promoters in tire cord adhesion to rubber

Publications (1)

Publication Number Publication Date
SU685160A3 true SU685160A3 (ru) 1979-09-05

Family

ID=24666090

Family Applications (1)

Application Number Title Priority Date Filing Date
SU772456906A SU685160A3 (ru) 1976-03-08 1977-03-05 Вулканизуема резинова смесь на основе карбоцепного каучука

Country Status (13)

Country Link
US (1) US4092455A (ru)
JP (1) JPS52108448A (ru)
AR (1) AR212981A1 (ru)
AU (1) AU2172177A (ru)
BE (1) BE852178A (ru)
BR (1) BR7701343A (ru)
DE (1) DE2709879A1 (ru)
FR (1) FR2343774A1 (ru)
IT (1) IT1081491B (ru)
NL (1) NL7702181A (ru)
SE (1) SE7702551L (ru)
SU (1) SU685160A3 (ru)
ZA (1) ZA77412B (ru)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4169112A (en) * 1978-10-30 1979-09-25 The General Tire & Rubber Company Heat and humidity resistant steel reinforced tire
US4338263A (en) * 1979-05-04 1982-07-06 The General Tire & Rubber Company Tire cord adhesives
US5298539A (en) * 1990-09-05 1994-03-29 Cytec Industries, Inc. Additives for improving tire cord adhesion and toughness of vulcanized rubber compositions
US5244725A (en) * 1992-02-24 1993-09-14 Indspec Chemical Corporation Hydroxyalkyl aryl ethers of di- and polyhydric phenols
US5936056A (en) * 1997-03-07 1999-08-10 Indspec Chemical Corporation Non-volatile resorcinolic resins and methods of making and using the same
US7259199B2 (en) * 2004-12-09 2007-08-21 The Goodyear Tire & Rubber Company Tire with rubber containing in-situ resin
US20060169382A1 (en) * 2005-01-28 2006-08-03 Sandstrom Paul H Tire with internal cord reinforced rubber component
BRPI0805232A2 (pt) * 2007-11-27 2009-09-15 Goodyear Tire & Rubber pneu com banda de rodagem de sìlica tendo resina de auto-condensação
US7605202B2 (en) 2007-11-27 2009-10-20 The Goodyear Tire & Rubber Company Tire with silica tread having self condensing resin
US20090151838A1 (en) 2007-12-17 2009-06-18 Erik Paul Sandstrom Tire containing an internal cord reinforced rubber component
US20100051157A1 (en) 2008-08-29 2010-03-04 Bina Patel Botts Insert and belt overlay containing chopped carbon fibers
US8053510B2 (en) 2009-09-03 2011-11-08 The Goodyear Tire & Rubber Company Pneumatic tire
US20110174422A1 (en) 2010-01-20 2011-07-21 Kelly Sue King Pneumatic tire with compound apex
US8299165B2 (en) 2011-02-24 2012-10-30 The Goodyear Tire & Rubber Company Pneumatic tire
US20120241066A1 (en) 2011-03-24 2012-09-27 Paul Harry Sandstrom Tire containing an internal composite comprised of metal cord reinforced rubber layer with auxiliary buffer rubber layer
US20130133803A1 (en) 2011-11-25 2013-05-30 Paul Harry Sandstrom Tire containing internal cord reinforced rubber layer
US9441325B2 (en) 2012-10-04 2016-09-13 The Goodyear Tire & Rubber Company Atmospheric plasma treatment of reinforcement cords and use in rubber articles
US8962719B2 (en) 2012-11-01 2015-02-24 The Goodyear Tire & Rubber Company Rubber composition with encapsulated resin and pneumatic tire
US20140135433A1 (en) 2012-11-13 2014-05-15 The Goodyear Tire & Rubber Company Tire with rubber containing flavone
EP2878458B1 (en) 2013-11-27 2018-12-26 The Goodyear Tire & Rubber Company Pneumatic tire
US9387737B2 (en) 2014-08-07 2016-07-12 The Goodyear Tire & Rubber Company Passage tube for air maintenance tire
US20160052344A1 (en) 2014-08-20 2016-02-25 The Goodyear Tire & Rubber Company Rubber composition containing tin carboxylate salt
US20160167449A1 (en) 2014-12-16 2016-06-16 The Goodyear Tire & Rubber Company Pneumatic tire
WO2016176080A1 (en) 2015-04-30 2016-11-03 Bridgestone Americas Tire Operations, Llc Rubber-covered textile cords, tires containing same, and related methods
US10077343B2 (en) 2016-01-21 2018-09-18 Eastman Chemical Company Process to produce elastomeric compositions comprising cellulose ester additives
US10427463B2 (en) 2016-11-16 2019-10-01 The Goodyear Tire & Rubber Company Pneumatic tire having a dual layer tread
EP3336140B1 (en) 2016-12-19 2019-07-24 The Goodyear Tire & Rubber Company Atmospheric plasma treatment of reinforcement cords and use in rubber articles
EP3336141B1 (en) 2016-12-19 2019-08-14 The Goodyear Tire & Rubber Company Atmospheric plasma treatment of reinforcement cords and use in rubber articles
US20200070579A1 (en) 2018-09-04 2020-03-05 The Goodyear Tire & Rubber Company Pneumatic tire
EP4015201B1 (en) 2020-12-18 2023-09-13 The Goodyear Tire & Rubber Company Process for the production of a non-pneumatic tire

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3212955A (en) * 1962-05-10 1965-10-19 American Cyanamid Co Tire cord bonding with polymethylolmelamine resins
US3361617A (en) * 1962-06-06 1968-01-02 American Cyanamid Co Tire cord bonding with aminoplast resins and butadiene/vinylpyridine latex

Also Published As

Publication number Publication date
NL7702181A (nl) 1977-09-12
FR2343774A1 (fr) 1977-10-07
SE7702551L (sv) 1977-09-09
AU2172177A (en) 1978-08-03
BE852178A (fr) 1977-09-07
US4092455A (en) 1978-05-30
AR212981A1 (es) 1978-11-30
BR7701343A (pt) 1977-10-18
ZA77412B (en) 1977-12-28
DE2709879A1 (de) 1977-09-15
IT1081491B (it) 1985-05-21
JPS52108448A (en) 1977-09-10

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