SU520031A3 - Способ получени сложных жидкокристаллических эфиров - Google Patents
Способ получени сложных жидкокристаллических эфировInfo
- Publication number
- SU520031A3 SU520031A3 SU1971742A SU1971742A SU520031A3 SU 520031 A3 SU520031 A3 SU 520031A3 SU 1971742 A SU1971742 A SU 1971742A SU 1971742 A SU1971742 A SU 1971742A SU 520031 A3 SU520031 A3 SU 520031A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- acid
- mmol
- product
- absolute
- thionyl chloride
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 7
- 150000002148 esters Chemical class 0.000 title claims description 4
- 239000004973 liquid crystal related substance Substances 0.000 title claims 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims description 22
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 21
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000001953 recrystallisation Methods 0.000 claims description 5
- 239000000741 silica gel Substances 0.000 claims description 5
- 229910002027 silica gel Inorganic materials 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 3
- CVNOWLNNPYYEOH-UHFFFAOYSA-N 4-cyanophenol Chemical compound OC1=CC=C(C#N)C=C1 CVNOWLNNPYYEOH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 238000004821 distillation Methods 0.000 claims description 2
- XYKIUTSFQGXHOW-UHFFFAOYSA-N propan-2-one;toluene Chemical compound CC(C)=O.CC1=CC=CC=C1 XYKIUTSFQGXHOW-UHFFFAOYSA-N 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 9
- 239000000047 product Substances 0.000 claims 7
- -1 p-n-heptylbenzoic acid chloride anhydride Chemical class 0.000 claims 3
- 235000011121 sodium hydroxide Nutrition 0.000 claims 3
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims 2
- HBQUXMZZODHFMJ-UHFFFAOYSA-N 4-hexoxybenzoic acid Chemical compound CCCCCCOC1=CC=C(C(O)=O)C=C1 HBQUXMZZODHFMJ-UHFFFAOYSA-N 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 125000004423 acyloxy group Chemical group 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 2
- 239000012043 crude product Substances 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- KZEVSDGEBAJOTK-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[5-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]ethanone Chemical compound N1N=NC=2CN(CCC=21)C(CC=1OC(=NN=1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O KZEVSDGEBAJOTK-UHFFFAOYSA-N 0.000 claims 1
- VSUKEWPHURLYTK-UHFFFAOYSA-N 4-heptylbenzoic acid Chemical compound CCCCCCCC1=CC=C(C(O)=O)C=C1 VSUKEWPHURLYTK-UHFFFAOYSA-N 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 125000005278 alkyl sulfonyloxy group Chemical group 0.000 claims 1
- 125000005279 aryl sulfonyloxy group Chemical group 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000012153 distilled water Substances 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 239000005457 ice water Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000005711 Benzoic acid Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000751065 Monotropa hypopitys Species 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000011097 chromatography purification Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
- C07C51/60—Preparation of carboxylic acid halides by conversion of carboxylic acids or their anhydrides or esters, lactones, salts into halides with the same carboxylic acid part
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/04—Monocyclic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
- C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Liquid Crystal Substances (AREA)
- Underground Structures, Protecting, Testing And Restoring Foundations (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH258672A CH565234A5 (enrdf_load_html_response) | 1972-02-23 | 1972-02-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU520031A3 true SU520031A3 (ru) | 1976-06-30 |
Family
ID=4237116
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1971743A SU511849A3 (ru) | 1972-02-23 | 1973-11-29 | Способ получени сложных жидкокристаллических эфиров |
| SU1971742A SU520031A3 (ru) | 1972-02-23 | 1973-11-29 | Способ получени сложных жидкокристаллических эфиров |
| SU1971741A SU515440A3 (ru) | 1972-02-23 | 1973-11-29 | Способ получени сложных жидкокристаллических эфиров |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1971743A SU511849A3 (ru) | 1972-02-23 | 1973-11-29 | Способ получени сложных жидкокристаллических эфиров |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1971741A SU515440A3 (ru) | 1972-02-23 | 1973-11-29 | Способ получени сложных жидкокристаллических эфиров |
Country Status (20)
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4978683A (enrdf_load_html_response) * | 1972-12-06 | 1974-07-29 | ||
| JPS50111042A (enrdf_load_html_response) * | 1974-02-13 | 1975-09-01 | ||
| JPS50111043A (enrdf_load_html_response) * | 1974-02-15 | 1975-09-01 | ||
| JPS5177591A (en) * | 1974-12-28 | 1976-07-05 | Dainippon Toryo Kk | Nemachitsukuekishososeibutsu |
| JPS54126775U (enrdf_load_html_response) * | 1978-02-22 | 1979-09-04 | ||
| DE2937911A1 (de) * | 1978-09-19 | 1980-03-27 | Daikin Ind Ltd | Fluor enthaltende phenylbenzoatverbindungen, verfahren zu ihrer herstellung und ihre verwendung |
| FR2439765A1 (fr) * | 1978-10-27 | 1980-05-23 | Thomson Csf | Compose organique mesomorphe dont la formule chimique derive d'un acide alcoxy-4 tetrafluorobenzoique, et dispositif a cristal liquide utilisant un tel compose |
| JPH0438873Y2 (enrdf_load_html_response) * | 1985-08-30 | 1992-09-10 | ||
| US4833794A (en) * | 1988-08-10 | 1989-05-30 | Advance Systems, Inc. | Dryer apparatus for floating a running web and having baffle means for spent return air |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2024269A1 (en) * | 1970-05-19 | 1971-12-02 | Merck Patent Gmbh | Nematic mixtures - of low melting point, used in electronics |
-
0
- BE BE795776D patent/BE795776A/xx unknown
-
1972
- 1972-02-23 CH CH258672A patent/CH565234A5/xx not_active IP Right Cessation
-
1973
- 1973-01-16 ZA ZA730331A patent/ZA73331B/xx unknown
- 1973-01-18 AU AU51229/73A patent/AU444106B2/en not_active Expired
- 1973-01-22 IL IL41362A patent/IL41362A/en unknown
- 1973-01-31 IT IT19833/73A patent/IT978487B/it active
- 1973-02-07 AR AR246463A patent/AR195823A1/es active
- 1973-02-09 CS CS827A patent/CS177892B2/cs unknown
- 1973-02-09 CS CS829A patent/CS177894B2/cs unknown
- 1973-02-09 CS CS970A patent/CS177856B2/cs unknown
- 1973-02-09 CS CS828A patent/CS177893B2/cs unknown
- 1973-02-19 NL NL737302276A patent/NL152917B/xx not_active IP Right Cessation
- 1973-02-20 CA CA164,069A patent/CA1013364A/en not_active Expired
- 1973-02-21 DD DD177564*A patent/DD110737A5/xx unknown
- 1973-02-21 JP JP48020324A patent/JPS5211677B2/ja not_active Expired
- 1973-02-21 SE SE7302455A patent/SE402278B/xx unknown
- 1973-02-21 DD DD168980A patent/DD108525A5/xx unknown
- 1973-02-22 FR FR7306255A patent/FR2173165B1/fr not_active Expired
- 1973-02-22 AT AT155373A patent/AT335530B/de not_active IP Right Cessation
- 1973-02-22 ES ES411901A patent/ES411901A1/es not_active Expired
- 1973-02-22 NO NO730/73A patent/NO132477C/no unknown
- 1973-02-22 TR TR18233A patent/TR18233A/xx unknown
- 1973-02-23 GB GB905273A patent/GB1373610A/en not_active Expired
- 1973-06-06 NO NO2390/73A patent/NO139052C/no unknown
- 1973-11-29 SU SU1971743A patent/SU511849A3/ru active
- 1973-11-29 SU SU1971742A patent/SU520031A3/ru active
- 1973-11-29 SU SU1971741A patent/SU515440A3/ru active
-
1975
- 1975-01-29 SE SE7500978A patent/SE7500978L/xx unknown
- 1975-04-16 JP JP50045391A patent/JPS522902B2/ja not_active Expired
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