SU1205757A3 - Способ получени терефталевой кислоты - Google Patents
Способ получени терефталевой кислоты Download PDFInfo
- Publication number
- SU1205757A3 SU1205757A3 SU813357502A SU3357502A SU1205757A3 SU 1205757 A3 SU1205757 A3 SU 1205757A3 SU 813357502 A SU813357502 A SU 813357502A SU 3357502 A SU3357502 A SU 3357502A SU 1205757 A3 SU1205757 A3 SU 1205757A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- temperature
- pressure
- water
- crude
- mixt
- Prior art date
Links
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 48
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims abstract description 23
- 230000007062 hydrolysis Effects 0.000 claims abstract description 22
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 230000032050 esterification Effects 0.000 claims abstract description 8
- 238000005886 esterification reaction Methods 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 239000003054 catalyst Substances 0.000 claims abstract description 5
- 238000010992 reflux Methods 0.000 claims description 10
- 238000004821 distillation Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 150000004702 methyl esters Chemical class 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 238000002955 isolation Methods 0.000 claims 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical class [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000012452 mother liquor Substances 0.000 abstract description 5
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 abstract description 4
- 238000004064 recycling Methods 0.000 abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- 239000012071 phase Substances 0.000 abstract 3
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 239000007790 solid phase Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 20
- 230000003647 oxidation Effects 0.000 description 9
- 238000007254 oxidation reaction Methods 0.000 description 9
- 239000000725 suspension Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
- GOUHYARYYWKXHS-UHFFFAOYSA-N 4-formylbenzoic acid Chemical compound OC(=O)C1=CC=C(C=O)C=C1 GOUHYARYYWKXHS-UHFFFAOYSA-N 0.000 description 1
- PWWVAXIEGOYWEE-UHFFFAOYSA-N Isophenergan Chemical compound C1=CC=C2N(CC(C)N(C)C)C3=CC=CC=C3SC2=C1 PWWVAXIEGOYWEE-UHFFFAOYSA-N 0.000 description 1
- 239000000061 acid fraction Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical compound [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N methyl monoether Natural products COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3044617A DE3044617C2 (de) | 1980-11-27 | 1980-11-27 | Verfahren zur Herstellung von Terephthalsäure aus Dimethylterephthalat als Zwischenprodukt |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1205757A3 true SU1205757A3 (ru) | 1986-01-15 |
Family
ID=6117670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU813357502A SU1205757A3 (ru) | 1980-11-27 | 1981-11-26 | Способ получени терефталевой кислоты |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5795925A (enExample) |
| BR (1) | BR8107687A (enExample) |
| DE (1) | DE3044617C2 (enExample) |
| FR (1) | FR2494684A1 (enExample) |
| IN (1) | IN155627B (enExample) |
| IT (1) | IT1172099B (enExample) |
| SU (1) | SU1205757A3 (enExample) |
| UA (1) | UA8349A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3639958A1 (de) | 1986-01-10 | 1987-07-16 | Amberger Kaolinwerke Gmbh | Mehrstufige anordnung zur gegenstromwaschung, sowie zugehoerige verfahrensmassnahmen |
| FR2611708B1 (fr) * | 1987-02-25 | 1989-06-09 | Elf Aquitaine | Procede de production d'acides alcane-sulfoniques |
| DE3904586A1 (de) * | 1989-02-16 | 1990-08-23 | Huels Chemische Werke Ag | Verfahren zur herstellung von dmt-zwischenprodukt bestimmter reinheit sowie dessen weiterverarbeitung zu reinst-dmt und/oder mittel- oder hochreiner terephthalsaeure |
| EP0725054A1 (de) * | 1995-01-24 | 1996-08-07 | Hüls Aktiengesellschaft | Verfahren zur Herstellung von Terephthalsäure und ihrer Isomeren |
| DE19536814B4 (de) * | 1995-01-24 | 2008-03-27 | Hermann-Josef Dr. Korte | Ein neues Verfahren zur Herstellung von Terephthalsäure und ihrer Isomeren |
| JP2002167469A (ja) * | 2000-12-01 | 2002-06-11 | Teijin Ltd | ポリエステル廃棄物のリサイクルシステムとその方法 |
| EP1344765B1 (en) * | 2000-11-27 | 2014-07-30 | Teijin Limited | Process for producing a dimethyl terephthalate composition |
| US7462649B2 (en) | 2001-10-16 | 2008-12-09 | Teijin Limited | Method for recycling pet bottle |
| JP2025117714A (ja) * | 2024-01-31 | 2025-08-13 | 三菱重工業株式会社 | 加水分解反応システム及び制御方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3833647A (en) * | 1971-09-07 | 1974-09-03 | Lummus Co | Production of aromatic polycarboxylic acids |
| DE2916197C2 (de) * | 1979-04-21 | 1982-01-28 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von Terephthalsäure aus Dimethyltherephthalat als Zwischenprodukt |
-
1980
- 1980-11-27 DE DE3044617A patent/DE3044617C2/de not_active Expired
-
1981
- 1981-02-27 JP JP56027110A patent/JPS5795925A/ja active Granted
- 1981-11-03 FR FR8120589A patent/FR2494684A1/fr active Granted
- 1981-11-25 IT IT49767/81A patent/IT1172099B/it active
- 1981-11-26 UA UA3357502A patent/UA8349A1/uk unknown
- 1981-11-26 SU SU813357502A patent/SU1205757A3/ru active
- 1981-11-26 IN IN1331/CAL/81A patent/IN155627B/en unknown
- 1981-11-26 BR BR8107687A patent/BR8107687A/pt unknown
Non-Patent Citations (1)
| Title |
|---|
| Патент СССР № 1041029, кл. С 07 С 69/82, 1979. * |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2494684A1 (fr) | 1982-05-28 |
| UA8349A1 (uk) | 1996-03-29 |
| FR2494684B1 (enExample) | 1985-03-29 |
| IT8149767A0 (it) | 1981-11-25 |
| IN155627B (enExample) | 1985-02-16 |
| JPH0525867B2 (enExample) | 1993-04-14 |
| JPS5795925A (en) | 1982-06-15 |
| BR8107687A (pt) | 1982-08-24 |
| DE3044617A1 (de) | 1982-06-03 |
| IT1172099B (it) | 1987-06-18 |
| DE3044617C2 (de) | 1985-09-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5286896A (en) | Process for the production of DMT-intermediate product of specific purity | |
| SU1217250A3 (ru) | Способ обработки маточного раствора | |
| JPS6399039A (ja) | マイレン酸ジアルキルの製造方法 | |
| JP4184948B2 (ja) | 精製テレフタル酸の製造方法 | |
| JP5209573B2 (ja) | 芳香族ジカルボン酸の製造のための２段階酸化方法 | |
| SU1041029A3 (ru) | Способ получени терефталевой кислоты | |
| JP2004513160A (ja) | 多塩基性酸のエステルの製造法 | |
| US6433222B1 (en) | Method for producing acrylic acid | |
| JPS6019286B2 (ja) | フアイバ−グレ−ドのテレフタル酸の製法 | |
| SU1205757A3 (ru) | Способ получени терефталевой кислоты | |
| CN105017022A (zh) | 一种甲酯化回收利用pta氧化残渣的方法 | |
| CN111943849A (zh) | 高效节能型乳酸乙酯反应精馏生产方法及装置 | |
| CN103025700B (zh) | 芳香族羧酸的制备 | |
| KR102592022B1 (ko) | 산화에 의해 방향족 디카복실산을 제조하기 위한 에너지 및 환경적으로 통합된 방법 | |
| SK9196A3 (en) | Manufacturing process of terephthalic acid and its isomers | |
| SU1581218A3 (ru) | Способ получени терефталевой кислоты | |
| Nakaoka et al. | Preparation of Terephthalic Acid Using Paraldehyde Promotor | |
| CN107963970A (zh) | 废渣废水中苯甲酸的回收利用方法 | |
| US4797497A (en) | Trimellitic anhydride purification process | |
| KR830001517B1 (ko) | 디메틸 테레프탈레이트의 가수분해에 의한 테레프탈산의 제조방법 | |
| CA3054775C (en) | Energy and environmentally integrated method for production of aromatic dicarboxylic acids by oxidation | |
| EP1019357A1 (en) | Process for the purification of naphthalenedicarboxylic acid | |
| JPH06122652A (ja) | カルボン酸エステルの製造方法 | |
| SU889655A1 (ru) | Способ очистки сложных эфиров | |
| CN113527084A (zh) | 芳族二羧酸的制备 |