SK7812001A3 - A method of dewatering organic liquids - Google Patents
A method of dewatering organic liquids Download PDFInfo
- Publication number
- SK7812001A3 SK7812001A3 SK781-2001A SK7812001A SK7812001A3 SK 7812001 A3 SK7812001 A3 SK 7812001A3 SK 7812001 A SK7812001 A SK 7812001A SK 7812001 A3 SK7812001 A3 SK 7812001A3
- Authority
- SK
- Slovakia
- Prior art keywords
- molecular sieve
- mixture
- ammonia
- contacting
- water
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 46
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 239000002808 molecular sieve Substances 0.000 claims abstract description 69
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 69
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 63
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 31
- 239000002253 acid Substances 0.000 claims abstract description 7
- 235000019441 ethanol Nutrition 0.000 claims description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 27
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 17
- 238000003795 desorption Methods 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 9
- 239000010457 zeolite Substances 0.000 claims description 9
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 8
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical class [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims description 7
- 229910021536 Zeolite Inorganic materials 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Chemical class 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- WDAXFOBOLVPGLV-UHFFFAOYSA-N ethyl isobutyrate Chemical compound CCOC(=O)C(C)C WDAXFOBOLVPGLV-UHFFFAOYSA-N 0.000 claims description 4
- 235000010333 potassium nitrate Nutrition 0.000 claims description 4
- 239000004323 potassium nitrate Substances 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 239000011148 porous material Substances 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 2
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 claims description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229940017219 methyl propionate Drugs 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 235000019355 sepiolite Nutrition 0.000 claims description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 1
- KFNNIILCVOLYIR-UHFFFAOYSA-N Propyl formate Chemical group CCCOC=O KFNNIILCVOLYIR-UHFFFAOYSA-N 0.000 claims 1
- 239000004113 Sepiolite Substances 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 235000011114 ammonium hydroxide Nutrition 0.000 claims 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims 1
- 230000001172 regenerating effect Effects 0.000 claims 1
- 230000008929 regeneration Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 claims 1
- 239000012266 salt solution Substances 0.000 claims 1
- 229910052624 sepiolite Inorganic materials 0.000 claims 1
- 235000010344 sodium nitrate Nutrition 0.000 claims 1
- 239000004317 sodium nitrate Substances 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 150000001298 alcohols Chemical class 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- -1 alkali metal salt Chemical class 0.000 description 9
- 238000005342 ion exchange Methods 0.000 description 9
- 210000004534 cecum Anatomy 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 229910001414 potassium ion Inorganic materials 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 5
- 238000006703 hydration reaction Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000036571 hydration Effects 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 235000021536 Sugar beet Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011491 glass wool Substances 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000010893 paper waste Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010931 ester hydrolysis Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 150000002905 orthoesters Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3408—Regenerating or reactivating of aluminosilicate molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3491—Regenerating or reactivating by pressure treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/56—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
- B01J2220/56—Use in the form of a bed
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Removal Of Specific Substances (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Water Treatment By Sorption (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Physical Water Treatments (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9827099.4A GB9827099D0 (en) | 1998-12-10 | 1998-12-10 | A method of dewatering organic liquids |
| GBGB9904910.8A GB9904910D0 (en) | 1999-03-03 | 1999-03-03 | A method of dewatering organic liquids |
| GBGB9906298.6A GB9906298D0 (en) | 1999-03-18 | 1999-03-18 | A method of dewatering organic liquids |
| PCT/GB1999/003881 WO2000034217A1 (en) | 1998-12-10 | 1999-11-19 | A method of dewatering organic liquids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK7812001A3 true SK7812001A3 (en) | 2002-01-07 |
Family
ID=27269580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK781-2001A SK7812001A3 (en) | 1998-12-10 | 1999-11-19 | A method of dewatering organic liquids |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US6582607B2 (cs) |
| EP (1) | EP1137619B1 (cs) |
| JP (1) | JP2002531538A (cs) |
| KR (1) | KR100650964B1 (cs) |
| AT (1) | ATE250567T1 (cs) |
| AU (1) | AU756131B2 (cs) |
| BR (1) | BR9916057B1 (cs) |
| CA (1) | CA2353919A1 (cs) |
| CZ (1) | CZ300404B6 (cs) |
| DE (1) | DE69911644T2 (cs) |
| HU (1) | HUP0104714A3 (cs) |
| MY (1) | MY119876A (cs) |
| NO (1) | NO326933B1 (cs) |
| NZ (1) | NZ512268A (cs) |
| SA (1) | SA00200909B1 (cs) |
| SK (1) | SK7812001A3 (cs) |
| TW (1) | TW495383B (cs) |
| WO (1) | WO2000034217A1 (cs) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6743745B2 (en) * | 2002-01-22 | 2004-06-01 | Zeochem | Process for production of molecular sieve adsorbent blends |
| FR2850963B1 (fr) * | 2003-02-11 | 2005-03-25 | Ceca Sa | Adsorbants agglomeres, leur procede de preparation et leur utilisation pour le sechage de composes organiques |
| FR2868338B1 (fr) * | 2004-03-31 | 2007-02-02 | Ceca Sa Sa | Composition zeolitique adsorbante, son procede de preparation et son utilisation pour l'elimination de h20 et ou h2s contenus dans des melanges gazeux ou liquides |
| CN100516111C (zh) * | 2007-02-06 | 2009-07-22 | 四川大学 | 一种聚对二氧环己酮的合成方法及其反应装置 |
| FR2940801B1 (fr) * | 2009-01-06 | 2012-08-17 | Arkema France | Procede de fabrication d'un methacrylate de methyle derive de la biomasse |
| US8680344B2 (en) | 2011-01-25 | 2014-03-25 | Zeochem Llc | Molecular sieve adsorbent blends and uses thereof |
| US9487469B2 (en) * | 2013-08-09 | 2016-11-08 | Gas Technology Institute | Process for purification of methyl methacrylate using molecular sieve membranes |
| WO2015093527A1 (ja) | 2013-12-20 | 2015-06-25 | 日本ゼオン株式会社 | フッ素化炭化水素化合物の精製方法 |
| CN105732378B (zh) * | 2014-12-08 | 2018-09-07 | 厦门伟捷化工工程有限公司 | 一种有机含水混合物进行脱水提纯的方法 |
| CN108486172B (zh) * | 2018-04-04 | 2020-12-29 | 江南大学 | 一种两相法厌氧发酵产己酸的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4130484A (en) * | 1976-06-28 | 1978-12-19 | Phillips Petroleum Company | Purification process |
| AU2815977A (en) * | 1976-08-26 | 1979-03-01 | Unique E L | Three dimensional noughts and crosses |
| DE3146553A1 (de) * | 1980-11-28 | 1982-09-09 | Coal Industry (Patents) Ltd., London | "verfahren zur behandlung wasserhaltiger organischer loesungsmittel" |
| GB2088739B (en) * | 1980-11-28 | 1983-11-30 | Coal Industry Patents Ltd | Drying organic solvents |
| US4319057A (en) * | 1980-12-08 | 1982-03-09 | Grain Processing Corporation | Regeneration of molecular sieves |
| US4726818A (en) * | 1984-12-20 | 1988-02-23 | Union Carbide Corporation | Bulk removal of water from organic liquids |
| US4894142A (en) * | 1987-03-24 | 1990-01-16 | Uop | Hydrocracking process employing low acidity Y zeolite |
| US5316656A (en) * | 1990-05-07 | 1994-05-31 | Uop | Hydrocarbon conversion processes with molecular sieve agglomerates having improved transport properties |
| US5143878A (en) * | 1990-06-04 | 1992-09-01 | Texaco Inc. | Zeolite treating process |
| US5504259A (en) * | 1992-10-29 | 1996-04-02 | Midwest Research Institute | Process to convert biomass and refuse derived fuel to ethers and/or alcohols |
-
1999
- 1999-11-19 CZ CZ20012008A patent/CZ300404B6/cs not_active IP Right Cessation
- 1999-11-19 AU AU12824/00A patent/AU756131B2/en not_active Ceased
- 1999-11-19 SK SK781-2001A patent/SK7812001A3/sk unknown
- 1999-11-19 HU HU0104714A patent/HUP0104714A3/hu unknown
- 1999-11-19 JP JP2000586667A patent/JP2002531538A/ja active Pending
- 1999-11-19 CA CA002353919A patent/CA2353919A1/en not_active Abandoned
- 1999-11-19 BR BRPI9916057-9A patent/BR9916057B1/pt not_active IP Right Cessation
- 1999-11-19 DE DE69911644T patent/DE69911644T2/de not_active Expired - Lifetime
- 1999-11-19 AT AT99956173T patent/ATE250567T1/de not_active IP Right Cessation
- 1999-11-19 EP EP99956173A patent/EP1137619B1/en not_active Expired - Lifetime
- 1999-11-19 WO PCT/GB1999/003881 patent/WO2000034217A1/en active IP Right Grant
- 1999-11-19 NZ NZ512268A patent/NZ512268A/en not_active IP Right Cessation
- 1999-11-19 KR KR1020017007212A patent/KR100650964B1/ko not_active IP Right Cessation
- 1999-11-26 TW TW088120720A patent/TW495383B/zh not_active IP Right Cessation
- 1999-12-09 MY MYPI99005350A patent/MY119876A/en unknown
-
2000
- 2000-01-31 SA SA00200909A patent/SA00200909B1/ar unknown
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2001
- 2001-06-05 US US09/873,317 patent/US6582607B2/en not_active Expired - Lifetime
- 2001-06-08 NO NO20012854A patent/NO326933B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CZ300404B6 (cs) | 2009-05-13 |
| KR100650964B1 (ko) | 2006-11-29 |
| TW495383B (en) | 2002-07-21 |
| SA00200909B1 (ar) | 2006-09-25 |
| CZ20012008A3 (cs) | 2001-11-14 |
| NO20012854D0 (no) | 2001-06-08 |
| NZ512268A (en) | 2003-08-29 |
| DE69911644T2 (de) | 2004-08-05 |
| AU1282400A (en) | 2000-06-26 |
| CA2353919A1 (en) | 2000-06-15 |
| HUP0104714A2 (hu) | 2002-03-28 |
| ATE250567T1 (de) | 2003-10-15 |
| MY119876A (en) | 2005-07-29 |
| HUP0104714A3 (en) | 2003-08-28 |
| AU756131B2 (en) | 2003-01-02 |
| JP2002531538A (ja) | 2002-09-24 |
| DE69911644D1 (de) | 2003-10-30 |
| BR9916057B1 (pt) | 2011-11-01 |
| BR9916057A (pt) | 2001-12-26 |
| EP1137619B1 (en) | 2003-09-24 |
| EP1137619A1 (en) | 2001-10-04 |
| NO20012854L (no) | 2001-08-07 |
| KR20010101159A (ko) | 2001-11-14 |
| US6582607B2 (en) | 2003-06-24 |
| US20020014457A1 (en) | 2002-02-07 |
| NO326933B1 (no) | 2009-03-16 |
| WO2000034217A1 (en) | 2000-06-15 |
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