SK131297A3 - Thermoplastic olefin articles having high surfafce gloss and mar resistance - Google Patents
Thermoplastic olefin articles having high surfafce gloss and mar resistance Download PDFInfo
- Publication number
- SK131297A3 SK131297A3 SK1312-97A SK131297A SK131297A3 SK 131297 A3 SK131297 A3 SK 131297A3 SK 131297 A SK131297 A SK 131297A SK 131297 A3 SK131297 A3 SK 131297A3
- Authority
- SK
- Slovakia
- Prior art keywords
- composition
- olefin
- ethylene
- copolymer
- parts
- Prior art date
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- 229920002397 thermoplastic olefin Polymers 0.000 title abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 65
- 239000004711 α-olefin Substances 0.000 claims abstract description 41
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000005977 Ethylene Substances 0.000 claims abstract description 35
- 239000000314 lubricant Substances 0.000 claims abstract description 28
- 229920001577 copolymer Polymers 0.000 claims abstract description 20
- 229920001384 propylene homopolymer Polymers 0.000 claims abstract description 18
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 14
- 229920001897 terpolymer Polymers 0.000 claims abstract description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 33
- 239000008096 xylene Substances 0.000 claims description 33
- -1 propylene-ethylene Chemical group 0.000 claims description 25
- 150000001336 alkenes Chemical class 0.000 claims description 24
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 20
- 238000006116 polymerization reaction Methods 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 15
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 15
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 5
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 5
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 5
- 239000002861 polymer material Substances 0.000 claims description 5
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 claims description 4
- 229920005604 random copolymer Polymers 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 abstract description 12
- 229920001198 elastomeric copolymer Polymers 0.000 abstract description 3
- 229920000098 polyolefin Polymers 0.000 abstract description 2
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 28
- 150000001875 compounds Chemical class 0.000 description 9
- 239000003381 stabilizer Substances 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000002667 nucleating agent Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 4
- 239000004299 sodium benzoate Substances 0.000 description 4
- 235000010234 sodium benzoate Nutrition 0.000 description 4
- 239000011949 solid catalyst Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical class Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000002083 X-ray spectrum Methods 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 150000003140 primary amides Chemical class 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical group Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- HEJCZAMFVMNFLC-UHFFFAOYSA-N 10-oxo-10-(2,2,6,6-tetramethylpiperidin-4-yl)oxydecanoic acid Chemical compound CC1(C)CC(OC(=O)CCCCCCCCC(O)=O)CC(C)(C)N1 HEJCZAMFVMNFLC-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- ZLNMVQYTHBJFHL-UHFFFAOYSA-N 4-tert-butylphenol;propanoic acid Chemical compound CCC(O)=O.CC(C)(C)C1=CC=C(O)C=C1 ZLNMVQYTHBJFHL-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- MURWRBWZIMXKGC-UHFFFAOYSA-N Phthalsaeure-butylester-octylester Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC MURWRBWZIMXKGC-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- ZVMRWPHIZSSUKP-UHFFFAOYSA-N dicyclohexyl(dimethoxy)silane Chemical compound C1CCCCC1[Si](OC)(OC)C1CCCCC1 ZVMRWPHIZSSUKP-UHFFFAOYSA-N 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
- 229940099607 manganese chloride Drugs 0.000 description 1
- 235000002867 manganese chloride Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 1
- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- IGEIPFLJVCPEKU-UHFFFAOYSA-N pentan-2-amine Chemical compound CCCC(C)N IGEIPFLJVCPEKU-UHFFFAOYSA-N 0.000 description 1
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- LYDRKKWPKKEMNZ-UHFFFAOYSA-N tert-butyl benzoate Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1 LYDRKKWPKKEMNZ-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71985396A | 1996-09-30 | 1996-09-30 | |
| US08/912,169 US6048942A (en) | 1996-09-30 | 1997-08-15 | Thermoplastic olefin articles having high surface gloss and mar resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK131297A3 true SK131297A3 (en) | 1999-03-12 |
Family
ID=27110151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK1312-97A SK131297A3 (en) | 1996-09-30 | 1997-09-26 | Thermoplastic olefin articles having high surfafce gloss and mar resistance |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6048942A (zh) |
| EP (1) | EP0832925B1 (zh) |
| JP (2) | JPH111585A (zh) |
| KR (1) | KR100565015B1 (zh) |
| CN (1) | CN1128177C (zh) |
| AR (1) | AR009104A1 (zh) |
| AT (1) | ATE202588T1 (zh) |
| AU (1) | AU721480B2 (zh) |
| CA (1) | CA2217165C (zh) |
| DE (1) | DE69705373T2 (zh) |
| ES (1) | ES2158417T3 (zh) |
| PL (1) | PL191311B1 (zh) |
| RU (1) | RU2194726C2 (zh) |
| SK (1) | SK131297A3 (zh) |
| TR (1) | TR199701086A2 (zh) |
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| US6048942A (en) * | 1996-09-30 | 2000-04-11 | Montell North America Inc. | Thermoplastic olefin articles having high surface gloss and mar resistance |
| JP3434698B2 (ja) * | 1998-01-21 | 2003-08-11 | 日本プラスト株式会社 | エアバッグ収納用ケース |
| IT1302029B1 (it) * | 1998-08-19 | 2000-07-20 | Montech Usa Inc | Processo per produrre composizioni polimeriche eterofasiche ecomposizioni cosi' ottenute |
| US6177515B1 (en) | 1998-12-17 | 2001-01-23 | Montell Technology Company Bv | Polypropylene graft copolymers with improved scratch and mar resistance |
| JP3966668B2 (ja) * | 2000-03-16 | 2007-08-29 | 旭化成ケミカルズ株式会社 | オレフィン系エラストマー組成物 |
| KR100361550B1 (ko) * | 2000-05-29 | 2002-11-22 | 삼성종합화학주식회사 | 투명성과 내충격성이 우수한 압출중공성형용 수지 조성물 |
| AU2003208706B2 (en) * | 2002-03-12 | 2008-08-14 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch for preparing impact-resistant polyolefin articles |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| CA2499951C (en) | 2002-10-15 | 2013-05-28 | Peijun Jiang | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| US6806313B2 (en) * | 2003-03-05 | 2004-10-19 | W. R. Grace & Co.-Conn. | Erucamide-free closure and liner compositions |
| US7288598B2 (en) * | 2003-03-06 | 2007-10-30 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch for preparing impact-resistant polyolefin articles |
| US7390574B2 (en) * | 2004-07-07 | 2008-06-24 | Ciba Specialty Chemicals Corporation | Scratch resistant polyolefins |
| WO2006131455A1 (en) * | 2005-06-07 | 2006-12-14 | Ciba Specialty Chemicals Holding Inc. | Scratch resistant polyolefins |
| US20070066729A1 (en) * | 2005-09-22 | 2007-03-22 | Ashutosh Sharma | Scratch resistant coatings compositions |
| US7462670B2 (en) * | 2005-09-22 | 2008-12-09 | Ciba Specialty Chemicals Corporation | Scratch resistant polymer compositions |
| KR100706422B1 (ko) * | 2005-10-20 | 2007-04-10 | 현대자동차주식회사 | 칫수안정성이 우수한 폴리프로필렌 나노복합 수지 |
| US20090096130A1 (en) * | 2007-09-28 | 2009-04-16 | Advanced Composites, Inc. | Thermoplastic polyolefin material with high surface gloss |
| BRPI0923420A2 (pt) | 2008-12-22 | 2018-10-16 | Basf Se | uso, ou método de uso, ou processo de uso de um agente de redução de fricção em combinação com um polímero enxertado , em adição a uma amida de acido graxo. |
| US20100267882A1 (en) * | 2009-04-15 | 2010-10-21 | Advanced Composites, Inc. | Polyolefin Compositions |
| WO2011081317A2 (ko) * | 2009-12-31 | 2011-07-07 | 제일모직 주식회사 | 열가소성 수지 조성물 및 이를 이용한 성형품 |
| FR2961517B1 (fr) * | 2010-06-18 | 2014-04-11 | Thermoplastiques Cousin Tessier | Composition elastomerique reticulee, et produit comprenant une telle composition |
| CN103068901B (zh) * | 2010-06-30 | 2015-07-08 | 巴塞尔聚烯烃意大利有限责任公司 | 交联的聚烯烃组合物 |
| EP2650329B1 (en) | 2012-04-12 | 2017-04-05 | Borealis AG | Automotive material with high quality perception |
| WO2014172901A1 (en) * | 2013-04-26 | 2014-10-30 | The Procter & Gamble Company | A glossy container |
| EP3020760B1 (en) * | 2013-07-08 | 2019-05-08 | Prime Polymer Co., Ltd. | Propylene-based resin composition |
| RU2680845C2 (ru) * | 2014-03-04 | 2019-02-28 | Дау Корнинг Корпорейшн | Маточный концентрат для термопластичного полимера |
| GB201405722D0 (en) * | 2014-03-31 | 2014-05-14 | Dow Corning | Thermoplastic polymer compositions having low friction resistance |
| CN103910937A (zh) * | 2014-04-04 | 2014-07-09 | 金发科技股份有限公司 | 一种具有耐划伤及高光泽免喷涂美学效果的聚丙烯组合物及其制备方法与应用 |
| US10385199B2 (en) * | 2015-06-24 | 2019-08-20 | Basell Poliolefine Italia S.R.L. | LLDPE-containing impact modifier polyolefin composition |
| CN105061901A (zh) * | 2015-08-28 | 2015-11-18 | 合肥会通新材料有限公司 | 一种无缝仪表板用聚丙烯复合材料及其制备方法 |
| BR112018006226B1 (pt) | 2015-10-06 | 2022-03-15 | Borealis Ag | Composição de polipropileno, e, artigo automotivo. |
| US11161966B2 (en) | 2016-01-18 | 2021-11-02 | The Procter And Gamble Company | Article with visual effects |
| EP3478761A4 (en) * | 2016-07-01 | 2019-12-25 | The Procter and Gamble Company | POLYPROPYLENE FILM |
| EP3275918A1 (en) | 2016-07-27 | 2018-01-31 | Clariant Plastics & Coatings Ltd | Compositions comprising polyacrylate-polysilane block copolymers |
| EP3526261A1 (en) * | 2016-10-12 | 2019-08-21 | Borealis AG | Beta-nucleated propylene terpolymer composition with good toughness |
| EP4194501B1 (en) * | 2021-12-08 | 2024-02-07 | SABIC Global Technologies, B.V. | A polypropylene composition having improved scratch resistance properties |
| EP4306444A1 (en) * | 2022-07-14 | 2024-01-17 | Borealis AG | Composition |
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| JPS54149752A (en) * | 1978-05-17 | 1979-11-24 | Mitsui Toatsu Chem Inc | Polyolefin resin composition for injection molding |
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| US4461872A (en) * | 1983-02-22 | 1984-07-24 | E. I. Du Pont De Nemours And Company | Blends of a propylene/α-olefin copolymer with isotactic prolypropylene |
| US4604324A (en) * | 1984-09-28 | 1986-08-05 | Mobil Oil Corporation | Multi-layer polypropylene film structure and method of forming the same |
| JPH0643532B2 (ja) * | 1985-03-13 | 1994-06-08 | 住友化学工業株式会社 | 耐傷付き性改良ポリオレフインエラストマ−組成物 |
| EP0277707B1 (en) * | 1987-01-12 | 1994-04-06 | Unitika Ltd. | Polyolefinic biconstituent fiber and nonwoven fabric produced therefrom |
| JP2816972B2 (ja) * | 1987-07-02 | 1998-10-27 | 富士写真フイルム株式会社 | 写真フィルムパトローネ用容器本体 |
| JPH02127520A (ja) * | 1988-10-31 | 1990-05-16 | Unitika Ltd | 熱接着性繊維及びその不織布 |
| US5268220A (en) * | 1989-05-11 | 1993-12-07 | Nippon Petrochemicals Company, Limited | Polypropylene film |
| JPH0381765A (ja) * | 1989-08-25 | 1991-04-08 | Fuji Photo Film Co Ltd | 写真フィルムパトローネ用容器本体 |
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| US5476898A (en) * | 1990-01-20 | 1995-12-19 | Synthopol Chemie Dr. Rer. Pol. Koch Gmbh & Co., Kg | Copolymer solutions based on addition products of α, β-unsaturated carboxylic acid with glycidyl esters and copolymerisable α, β-unsaturated monomers |
| US5331019A (en) * | 1990-09-04 | 1994-07-19 | Becton, Dickinson And Company | Lubricious radiation stable polymeric composition and articles therefrom |
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| US6048942A (en) * | 1996-09-30 | 2000-04-11 | Montell North America Inc. | Thermoplastic olefin articles having high surface gloss and mar resistance |
-
1997
- 1997-08-15 US US08/912,169 patent/US6048942A/en not_active Expired - Lifetime
- 1997-09-25 AT AT97116680T patent/ATE202588T1/de not_active IP Right Cessation
- 1997-09-25 EP EP97116680A patent/EP0832925B1/en not_active Expired - Lifetime
- 1997-09-25 DE DE69705373T patent/DE69705373T2/de not_active Expired - Lifetime
- 1997-09-25 ES ES97116680T patent/ES2158417T3/es not_active Expired - Lifetime
- 1997-09-26 SK SK1312-97A patent/SK131297A3/sk unknown
- 1997-09-29 AU AU39310/97A patent/AU721480B2/en not_active Ceased
- 1997-09-29 RU RU97116196/04A patent/RU2194726C2/ru not_active IP Right Cessation
- 1997-09-29 CA CA002217165A patent/CA2217165C/en not_active Expired - Fee Related
- 1997-09-30 CN CN97119369A patent/CN1128177C/zh not_active Expired - Fee Related
- 1997-09-30 PL PL322371A patent/PL191311B1/pl not_active IP Right Cessation
- 1997-09-30 JP JP9266258A patent/JPH111585A/ja active Pending
- 1997-09-30 KR KR1019970049845A patent/KR100565015B1/ko not_active IP Right Cessation
- 1997-09-30 AR ARP970104492A patent/AR009104A1/es active IP Right Grant
- 1997-09-30 TR TR97/01086A patent/TR199701086A2/xx unknown
-
2008
- 2008-09-26 JP JP2008248535A patent/JP2008308699A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ES2158417T3 (es) | 2001-09-01 |
| DE69705373T2 (de) | 2001-11-15 |
| US6048942A (en) | 2000-04-11 |
| ATE202588T1 (de) | 2001-07-15 |
| JPH111585A (ja) | 1999-01-06 |
| TR199701086A3 (tr) | 1998-04-21 |
| AU3931097A (en) | 1998-04-02 |
| PL322371A1 (en) | 1998-04-14 |
| EP0832925B1 (en) | 2001-06-27 |
| AR009104A1 (es) | 2000-03-08 |
| KR100565015B1 (ko) | 2006-07-10 |
| AU721480B2 (en) | 2000-07-06 |
| TR199701086A2 (xx) | 1998-04-21 |
| CN1185458A (zh) | 1998-06-24 |
| MX9707473A (es) | 1998-06-30 |
| CA2217165A1 (en) | 1998-03-30 |
| DE69705373D1 (de) | 2001-08-02 |
| EP0832925A1 (en) | 1998-04-01 |
| PL191311B1 (pl) | 2006-04-28 |
| KR19980025134A (ko) | 1998-07-06 |
| JP2008308699A (ja) | 2008-12-25 |
| RU2194726C2 (ru) | 2002-12-20 |
| CN1128177C (zh) | 2003-11-19 |
| CA2217165C (en) | 2002-09-24 |
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