SG11201901909QA - Acid aromatization catalyst with improved activity and stability - Google Patents

Acid aromatization catalyst with improved activity and stability

Info

Publication number
SG11201901909QA
SG11201901909QA SG11201901909QA SG11201901909QA SG11201901909QA SG 11201901909Q A SG11201901909Q A SG 11201901909QA SG 11201901909Q A SG11201901909Q A SG 11201901909QA SG 11201901909Q A SG11201901909Q A SG 11201901909QA SG 11201901909Q A SG11201901909Q A SG 11201901909QA
Authority
SG
Singapore
Prior art keywords
international
pct
stability
english
september
Prior art date
Application number
SG11201901909QA
Other languages
English (en)
Inventor
Gabriela Alvez-Manoli
Original Assignee
Chevron Phillips Chemical Co Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co Lp filed Critical Chevron Phillips Chemical Co Lp
Publication of SG11201901909QA publication Critical patent/SG11201901909QA/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • B01J27/10Chlorides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • B01J27/12Fluorides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/61Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
    • B01J29/62Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0246Coatings comprising a zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22Halogenating
    • B01J37/24Chlorinating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22Halogenating
    • B01J37/26Fluorinating
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41Catalytic processes
    • C07C5/415Catalytic processes with metals
    • C07C5/417Catalytic processes with metals of the platinum group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/20After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/128Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13Platinum group metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • C07C2529/068Noble metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/60Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L
    • C07C2529/61Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L containing iron group metals, noble metals or copper
    • C07C2529/62Noble metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70Catalyst aspects

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11201901909QA 2016-09-08 2017-09-07 Acid aromatization catalyst with improved activity and stability SG11201901909QA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662384746P 2016-09-08 2016-09-08
PCT/US2017/050485 WO2018049033A1 (en) 2016-09-08 2017-09-07 Acid aromatization catalyst with improved activity and stability

Publications (1)

Publication Number Publication Date
SG11201901909QA true SG11201901909QA (en) 2019-04-29

Family

ID=59901606

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201901909QA SG11201901909QA (en) 2016-09-08 2017-09-07 Acid aromatization catalyst with improved activity and stability

Country Status (10)

Country Link
US (3) US10556228B2 (enExample)
EP (1) EP3509747A1 (enExample)
JP (1) JP7034141B2 (enExample)
KR (1) KR102421931B1 (enExample)
CN (1) CN109689206A (enExample)
MY (2) MY202101A (enExample)
RU (1) RU2716704C1 (enExample)
SA (1) SA519401247B1 (enExample)
SG (1) SG11201901909QA (enExample)
WO (1) WO2018049033A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3509747A1 (en) * 2016-09-08 2019-07-17 Chevron Phillips Chemical Company LP Acid aromatization catalyst with improved activity and stability
US10226761B2 (en) 2016-12-20 2019-03-12 Chevron Phillips Chemical Company, Lp Aromatization catalyst preparation with alkali metal present during a washing step
US10118167B2 (en) * 2016-12-20 2018-11-06 Chevron Phillips Chemical Company Lp Methods for regenerating sulfur-contaminated aromatization catalysts
US11260376B2 (en) 2016-12-21 2022-03-01 Chevron Phillips Chemical Company Lp Methods of preparing an aromatization catalyst
US10487025B2 (en) * 2016-12-21 2019-11-26 Chevron Phillips Chemical Company Lp Methods of preparing an aromatization catalyst
US10300476B2 (en) * 2017-05-17 2019-05-28 Chevron Phillips Chemical Company Lp Methods of regenerating aromatization catalysts with a decoking step between chlorine and fluorine addition
US11103856B2 (en) * 2018-05-07 2021-08-31 Chevron Phillips Chemical Company, Lp Aromatization catalyst and methods of making and using same
CN111377792B (zh) * 2018-12-29 2023-04-18 国家能源投资集团有限责任公司 低碳烷烃芳构化的方法
JP7241893B2 (ja) * 2019-01-25 2023-03-17 エクソンモービル ケミカル パテンツ インコーポレイテッド 低金属含量触媒の活性化
US10478794B1 (en) 2019-02-26 2019-11-19 Chevron Phillips Chemical Company Lp Bi-modal radial flow reactor
EP4182077A1 (en) * 2020-07-17 2023-05-24 Chevron Phillips Chemical Company Lp Aromatization catalyst activity and selectivity improvement with alcohol addition during catalyst preparation
US11529617B2 (en) 2020-08-12 2022-12-20 Chevron Phillips Chemical Company, Lp Catalyst supports and catalyst systems and methods
EP4511451A1 (en) 2022-06-17 2025-02-26 Chevron Phillips Chemical Company LP Use of high fluoride-containing catalyst in front reactors to extend the life and selectivity of reforming catalyst
US12473498B2 (en) 2023-04-10 2025-11-18 Chevron Phillips Chemical Company Lp In-reactor activation of a high chloride aromatization catalyst
US20250084327A1 (en) 2023-09-07 2025-03-13 Chevron Phillips Chemical Company Lp Sustainable jet fuel and process

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3849290A (en) 1972-08-02 1974-11-19 Mobil Oil Corp Upgrading of reformates by catalyst compositions selective for cracking low and high boiling paraffin components
FR2323664A1 (fr) 1975-09-10 1977-04-08 Erap Procede de deshydrocyclisation d'hydrocarbures aliphatiques
US4456527A (en) 1982-10-20 1984-06-26 Chevron Research Company Hydrocarbon conversion process
BR8304402A (pt) 1983-10-19 1985-03-26 Mobil Oil Corporation Processo para melhorar a seletividade da forma de um zeolito cristalino poroso e processo para craqueamento de uma carga de alimentacao de hidrocarboneto
US4681865A (en) 1985-05-07 1987-07-21 Research Association For Utilization Of Light Oil Catalyst for the production of aromatic hydrocarbons
US5196631A (en) 1986-10-04 1993-03-23 Research Association For Utilization Of Light Oil Catalyst for production of aromatic hydrocarbons and process for production of aromatic hydrocarbons using same
JPH0829255B2 (ja) * 1986-10-04 1996-03-27 出光興産株式会社 芳香族炭化水素製造用触媒およびこれを用いた芳香族炭化水素の製造方法
US4808295A (en) 1987-08-25 1989-02-28 Mobil Oil Corporation Two stage process for the production of a high benzene aromatic product
US4861932A (en) 1987-12-31 1989-08-29 Mobil Oil Corp. Aromatization process
US4954245A (en) 1988-12-20 1990-09-04 Amoco Corporation Catalyst and process for high selectivity reforming with Pt/Re on Ba-K-L zeolite
US5507939A (en) 1990-07-20 1996-04-16 Uop Catalytic reforming process with sulfur preclusion
US5207042A (en) * 1991-06-07 1993-05-04 Molinar Raoul G Studless building structure
US5247178A (en) 1991-12-12 1993-09-21 Fusion Systems Corporation Method and apparatus for treating fluids by focusing reflected light on a thin fluid layer
US5401386A (en) 1992-07-24 1995-03-28 Chevron Research And Technology Company Reforming process for producing high-purity benzene
WO1994009878A1 (en) 1992-10-28 1994-05-11 Chevron Chemical Company High purity benzene production using extractive distillation
US5314854A (en) 1992-11-12 1994-05-24 Uop Stable, high-yield reforming catalyst
US5389235A (en) 1992-12-02 1995-02-14 Uop Catalytic reaction zone for sulfur contaminant sensitive catalyst
US5520798A (en) 1994-06-23 1996-05-28 Chevron Chemical Company Process for reforming hydrocarbon feedstocks over a sulfur sensitive catalyst
MX9703769A (es) 1994-11-23 1998-05-31 Exxon Chemical Patents Inc Proceso de conversion de hidrocarburos usando un catalizador de ceolita ligado a ceolita.
US5914028A (en) 1997-01-10 1999-06-22 Chevron Chemical Company Reforming process with catalyst pretreatment
RU2223818C2 (ru) * 1997-06-12 2004-02-20 Идемицу Козан Ко., Лтд. Галогенсодержащий катализатор и способ его получения
WO1998056502A1 (fr) 1997-06-12 1998-12-17 Idemitsu Kosan Co., Ltd. Catalyseur contenant un halogene et procede de fabrication
US5885439A (en) * 1997-11-04 1999-03-23 Uop Llc Catalytic reforming process with multiple zones
US5980731A (en) 1997-11-07 1999-11-09 Exxon Chemical Patents Inc. Naphtha reforming catalyst and process
US6812180B2 (en) 1997-12-10 2004-11-02 Idemitsu Kosan Co., Ltd. Method for preparing catalyst
JPH11169729A (ja) 1997-12-10 1999-06-29 Idemitsu Kosan Co Ltd 触媒の調製方法
US5879538A (en) 1997-12-22 1999-03-09 Chevron Chemical Company Zeolite L catalyst in conventional furnace
US6190539B1 (en) 1998-01-08 2001-02-20 Chevron Chemical Company Llc Reforming using a bound halided zeolite catalyst
US6207042B1 (en) 1998-01-08 2001-03-27 Chevron Chemical Company Llc Reforming using a bound halided zeolite catalyst
EP1109880B1 (en) 1998-08-17 2003-11-26 Chevron Phillips Chemical Company LP Process for production of aromatics in parallel reformers
US6406614B1 (en) 1999-12-22 2002-06-18 Phillips Petroleum Company Method for zeolite platinization
US7153801B2 (en) * 2003-06-18 2006-12-26 Chevron Phillips Chemical Company Lp Aromatization catalyst and methods of making and using same
US7932425B2 (en) 2006-07-28 2011-04-26 Chevron Phillips Chemical Company Lp Method of enhancing an aromatization catalyst
US7902105B2 (en) * 2007-10-11 2011-03-08 Chevron Phillips Chemical Company Lp Aromatization catalyst comprising prolongated silica and methods of making and using same
US8664145B2 (en) * 2008-12-23 2014-03-04 Chevron Phillips Chemical Company Lp Methods of preparing an aromatization catalyst
CN102895992B (zh) * 2011-07-25 2014-11-19 中国石油天然气股份有限公司 一种烷烃芳构化催化剂的制备及应用
US8835341B2 (en) 2011-09-07 2014-09-16 Chevron Phillips Chemical Company Lp Processed support and methods of making and using same
US8716161B2 (en) 2012-03-05 2014-05-06 Chevron Phillips Chemical Company Methods of regenerating aromatization catalysts
US8912108B2 (en) * 2012-03-05 2014-12-16 Chevron Phillips Chemical Company Lp Methods of regenerating aromatization catalysts
US9387467B2 (en) 2012-09-26 2016-07-12 Chevron Phillips Chemical Company Lp Aromatization catalysts with high surface area and pore volume
CN104174427B (zh) * 2013-05-24 2018-04-13 中国石油化工股份有限公司 一种双组分重整催化剂及其制备方法与应用
EP3509747A1 (en) * 2016-09-08 2019-07-17 Chevron Phillips Chemical Company LP Acid aromatization catalyst with improved activity and stability

Also Published As

Publication number Publication date
MY193455A (en) 2022-10-14
US11291978B2 (en) 2022-04-05
JP2019529084A (ja) 2019-10-17
JP7034141B2 (ja) 2022-03-11
SA519401247B1 (ar) 2022-12-15
CN109689206A (zh) 2019-04-26
EP3509747A1 (en) 2019-07-17
MY202101A (en) 2024-04-03
RU2716704C1 (ru) 2020-03-16
WO2018049033A1 (en) 2018-03-15
KR20190042021A (ko) 2019-04-23
US20200139354A1 (en) 2020-05-07
US20180065115A1 (en) 2018-03-08
KR102421931B1 (ko) 2022-07-15
US11850576B2 (en) 2023-12-26
US10556228B2 (en) 2020-02-11
US20220176356A1 (en) 2022-06-09

Similar Documents

Publication Publication Date Title
SG11201901909QA (en) Acid aromatization catalyst with improved activity and stability
SG11201908470UA (en) Enzymatic production of hexoses
SG11201811431VA (en) Multispecific antibodies against cd40 and cd137
SG11201909618TA (en) Compositions and methods for library construction and sequence analysis
SG11201906147VA (en) Optimized strategy for exon skipping modifications using crispr/cas9 with triple guide sequences
SG11201408678WA (en) Catalysts and methods for polyester production
SG11201803900UA (en) Process for preparing polyurea microcapsules with improved deposition
SG11201900746RA (en) Engineered antibodies and other fc-domain containing molecules with enhanced agonism and effector functions
SG11201809912UA (en) Hybrid carriers for nucleic acid cargo
SG11201908675PA (en) Computer-implemented system and method for performing transaction mixing on a blockchain
SG11201908546XA (en) Noble metal and base metal dewaxing catalyst
SG11201907129VA (en) Motion generating platform assembly
SG11201903060XA (en) Metallocene catalysts, catalyst systems, and methods for using the same
SG11201809531SA (en) BINDING MOLECULES SPECIFIC FOR FCγGAMMA RIIA AND USES THEREOF
SG11201803336TA (en) Base metal dewaxing catalyst
SG11201408224SA (en) Novel ruthenium complexes, their use in the metathesis reactions, and a process for carrying out the metathesis reaction
SG11201407774XA (en) Conversion of biomass
SG11201408746XA (en) Novel prime-boosting regimens involving immunogenic polypeptides encoded by polynucleotides
SG11201804843TA (en) Hydrogen sulfide production process and related reactor vessels
SG11201807544WA (en) Improved muconic acid production from genetically engineered microorganisms
SG11201804704PA (en) Compositions and methods for decreasing tau expression
SG11201908393YA (en) Modulators of pcsk9 expression
SG11201804543RA (en) Dewaxing catalyst with improved aromatic saturation activity
SG11201806430TA (en) A process for the preparation of propylene oxide
SG11201903076QA (en) Carbamoyl phenylalaninol compounds and uses therof