SG11201804543RA - Dewaxing catalyst with improved aromatic saturation activity - Google Patents

Dewaxing catalyst with improved aromatic saturation activity

Info

Publication number
SG11201804543RA
SG11201804543RA SG11201804543RA SG11201804543RA SG11201804543RA SG 11201804543R A SG11201804543R A SG 11201804543RA SG 11201804543R A SG11201804543R A SG 11201804543RA SG 11201804543R A SG11201804543R A SG 11201804543RA SG 11201804543R A SG11201804543R A SG 11201804543RA
Authority
SG
Singapore
Prior art keywords
versal
zsm
international
iii
dewaxing
Prior art date
Application number
SG11201804543RA
Inventor
Matthew Ide
Stephen Mccarthy
Gary Schleicher
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of SG11201804543RA publication Critical patent/SG11201804543RA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7461—MRE-type, e.g. ZSM-48
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau 1111111111111II III III OE III II 1113111111HW 11111 RIII 1111111H (10) International Publication Number WO 2017/116754 Al WIPO I PCT (43) International Publication Date 6 July 2017 (06.07.2017) (51) International Patent Classification: (74) Agents: YARNELL, Scott, F. et al.; Exxonmobil Re- CLOG 45/64 (2006.01) CLOG 47/18 (2006.01) search and Engineering Company, 1545 Route 22 East, BOM 29/74 (2006.01) P.O. Box 900, Annandale, NJ 08801-0900 (US). (21) International Application Number: (81) Designated States (unless otherwise indicated, for every PCT/US2016/067166 kind of national protection available): AE, AG, AL, AM, (22) International Filing Date: 16 December 2016 (16.12.2016) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KB, KN, English (25) Filing Language: KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, English (26) Publication Language: MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, (30) Priority Data: RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, 62/271,468 28 December 2015 (28.12.2015) US TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, (71) Applicant: EXXONMOBIL RESEARCH AND ENGIN- ZA, ZM, ZW. EERING COMPANY [US/US]; 1545 Route 22 East, (84) Designated States (unless otherwise indicated, for every P.O. Box 900, Annandale, NJ 08801-0900 (US). kind of regional protection available): ARIPO (BW, GH, (72) Inventors: IDE, Matthew, S.; 3708 Royce Court, Hills- GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, borough, NJ 08844 (US). MCCARTHY, Stephen, J.; TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, 4440 Devonshire Drive, Center Valley, PA 18034 (US). TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, SCHLEICHER, Gary, P.; 7 Meadow Run Road, Milford, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, NJ 08848 (US). LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). [Continued on next page] (54) Title: DEWAXING CATALYST WITH IMPROVED AROMATIC SATURATION ACTIVITY (57) : Methods are provided for dewaxing distillate feeds using a dewaxing catalyst with improved aro- matic saturation activity. The dewaxing can be performed using a catalyst in- cluding a zeolitic molecular sieve with a beneficial ratio of zeolitic molecular sieve to binder and/or using a catalyst including a zeolitic molecular sieve with a reduced ratio of silica to alu- mina. TA Co nve rsion ( %) 25 090:10 ZSM-48:Versal-300 80:20 ZSM-48:Versal-300 80:20 ZSM-48:Versal-300 24 - n 70:30 ZSM-48:Versal-300 90:10 ZSM-48:Versal-300 65:35 ZSM-48:Versal-300 60:40 ZSM-48:Versal-300 23 - 50:50 ZSM-48:Versal-300 40:60 ZSM-48:Versal-300 22 - • All Data 70:30 ZSM-48:Versal-300 60:40 ZSM-48:Versal-300 21 - 65:35 ZSM-48:Versal-300 20 - 41:k 50:50 ZSM-48:Versal-300 19 - 40:60 ZSM-48:Versal-300 18 W O 20 1711675 / 4 Al 07 0.8 0.5 0.6 0.1 0.2 00 0.3 0 4 WHSV -1 FIG. 1 WO 2017/116754 All#111DIMOREEIRDEFEEHOMMEHIMEIEDIMI Declarations under Rule 4.17: Published: as to applicant's entitlement to apply for and be granted with international search report (Art 21(3)) a patent (Rule 4.17(ii)) as to the applicant's entitlement to claim the priority of the earlier application (Rule 4.17(iii))
SG11201804543RA 2015-12-28 2016-12-16 Dewaxing catalyst with improved aromatic saturation activity SG11201804543RA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562271468P 2015-12-28 2015-12-28
PCT/US2016/067166 WO2017116754A1 (en) 2015-12-28 2016-12-16 Dewaxing catalyst with improved aromatic saturation activity

Publications (1)

Publication Number Publication Date
SG11201804543RA true SG11201804543RA (en) 2018-07-30

Family

ID=57963415

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201804543RA SG11201804543RA (en) 2015-12-28 2016-12-16 Dewaxing catalyst with improved aromatic saturation activity

Country Status (5)

Country Link
US (1) US9944865B2 (en)
EP (1) EP3397724B1 (en)
CA (1) CA3009872A1 (en)
SG (1) SG11201804543RA (en)
WO (1) WO2017116754A1 (en)

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US10738247B2 (en) * 2017-11-15 2020-08-11 Gas Technology Institute Processes and systems for reforming of methane and light hydrocarbons to liquid hydrocarbon fuels
WO2019194975A1 (en) * 2018-04-06 2019-10-10 Exxonmobil Research And Engineering Company Catalysts and methods for distillate end point reduction
WO2019213050A1 (en) 2018-05-01 2019-11-07 Novvi Llc Hydrocarbon mixture exhibiting unique branching structure
WO2020060590A1 (en) 2018-09-20 2020-03-26 Novvi Llc Process for preparing hydrocarbon mixture exhibiting unique branching structure
US11753355B2 (en) 2019-05-01 2023-09-12 Chevron U.S.A. Inc. Base oil synthesis via ionic catalyst oligomerization and waterless separation of the oligomerization catalyst
EP3963031A1 (en) 2019-05-01 2022-03-09 Chevron U.S.A. Inc. Base oil from nao via ionic catalyst oligomerization and hydroisomerization
EP4013839A1 (en) 2019-08-14 2022-06-22 Chevron U.S.A. Inc. Method for improving engine performance with renewable lubricant compositions
US20230092322A1 (en) 2021-09-09 2023-03-23 Chevron U.S.A. Inc. Renewable Based E-Drive Fluids

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US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US4744884A (en) * 1985-09-25 1988-05-17 Union Oil Company Of California Process for producing lubrication oil of high viscosity index
US5314854A (en) 1992-11-12 1994-05-24 Uop Stable, high-yield reforming catalyst
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Also Published As

Publication number Publication date
EP3397724A1 (en) 2018-11-07
US20170183583A1 (en) 2017-06-29
CA3009872A1 (en) 2017-07-06
WO2017116754A1 (en) 2017-07-06
US9944865B2 (en) 2018-04-17
EP3397724B1 (en) 2024-04-17

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