SG11201408224SA - Novel ruthenium complexes, their use in the metathesis reactions, and a process for carrying out the metathesis reaction - Google Patents
Novel ruthenium complexes, their use in the metathesis reactions, and a process for carrying out the metathesis reactionInfo
- Publication number
- SG11201408224SA SG11201408224SA SG11201408224SA SG11201408224SA SG11201408224SA SG 11201408224S A SG11201408224S A SG 11201408224SA SG 11201408224S A SG11201408224S A SG 11201408224SA SG 11201408224S A SG11201408224S A SG 11201408224SA SG 11201408224S A SG11201408224S A SG 11201408224SA
- Authority
- SG
- Singapore
- Prior art keywords
- international
- rule
- carrying
- applicant
- metathesis
- Prior art date
Links
- 238000005649 metathesis reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 150000003303 ruthenium Chemical class 0.000 title 1
- 238000005865 alkene metathesis reaction Methods 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical class [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000008520 organization Effects 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D307/28—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F132/00—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
- C08F132/02—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings
- C08F132/06—Homopolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings having two or more carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
- C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
- C08G2261/3325—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/41—Organometallic coupling reactions
- C08G2261/418—Ring opening metathesis polymerisation [ROMP]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL400162A PL400162A1 (pl) | 2012-07-27 | 2012-07-27 | Nowe kompleksy rutenu, ich zastosowanie w reakcjach metatezy oraz sposób prowadzenia reakcji metatezy |
| PCT/EP2013/065839 WO2014016422A1 (en) | 2012-07-27 | 2013-07-26 | Novel ruthenium complexes, their use in the metathesis reactions, and a process for carrying out the metathesis reaction |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SG11201408224SA true SG11201408224SA (en) | 2015-01-29 |
Family
ID=48917515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SG11201408224SA SG11201408224SA (en) | 2012-07-27 | 2013-07-26 | Novel ruthenium complexes, their use in the metathesis reactions, and a process for carrying out the metathesis reaction |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9328132B2 (ru) |
| EP (1) | EP2877478B1 (ru) |
| JP (1) | JP6121533B2 (ru) |
| KR (1) | KR101749238B1 (ru) |
| CN (1) | CN104428306B (ru) |
| AU (1) | AU2013294909B2 (ru) |
| CA (1) | CA2875956C (ru) |
| IL (1) | IL236128A (ru) |
| PL (2) | PL400162A1 (ru) |
| RU (1) | RU2586213C1 (ru) |
| SG (1) | SG11201408224SA (ru) |
| WO (1) | WO2014016422A1 (ru) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL400162A1 (pl) | 2012-07-27 | 2014-02-03 | Apeiron Synthesis Spólka Z Ograniczona Odpowiedzialnoscia | Nowe kompleksy rutenu, ich zastosowanie w reakcjach metatezy oraz sposób prowadzenia reakcji metatezy |
| PL238806B1 (pl) | 2015-09-30 | 2021-10-04 | Apeiron Synthesis Spolka Akcyjna | Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin |
| US10857530B2 (en) * | 2015-12-10 | 2020-12-08 | Umicore Ag & Co. Kg | Olefin metathesis catalysts |
| WO2018236191A1 (ko) * | 2017-06-23 | 2018-12-27 | 광주과학기술원 | 루테늄 착물 형성을 위한 리간드, 루테늄 착물 촉매 및 이의 제조방법과 용도 |
| TWI758525B (zh) | 2017-08-10 | 2022-03-21 | 日商住友電木股份有限公司 | 作為光學材料之聚環烯烴聚合物組成物 |
| TWI777027B (zh) * | 2018-01-26 | 2022-09-11 | 日商住友電木股份有限公司 | 聚環烯烴單體及由能夠產生光酸作為光學材料的化合物活化之催化劑 |
| TWI794520B (zh) | 2018-06-29 | 2023-03-01 | 日商住友電木股份有限公司 | 作為 3d 列印材料之聚環烯烴單體及由能夠產生光酸之化合物活化之催化劑 |
| JP7466908B2 (ja) * | 2018-06-29 | 2024-04-15 | アペイロン シンセシス エス アー | オレフィンメタセシス用の触媒前駆体としての有機ルテニウム錯体 |
| US11142662B2 (en) | 2018-12-21 | 2021-10-12 | Promerus, Llc | High impact strength 3D printing materials derived from polycycloolefin monomers and crosslinkers |
| KR102670566B1 (ko) * | 2019-01-18 | 2024-05-31 | 광주과학기술원 | 루테늄 착화합물, 이의 제조를 위한 리간드 및 이의 용도 |
| KR20220042380A (ko) | 2019-07-25 | 2022-04-05 | 프로메러스, 엘엘씨 | 광학재료로서의 안정적인 폴리시클로올레핀 중합체 및 무기 나노입자 조성물 |
| KR20220069920A (ko) * | 2019-09-27 | 2022-05-27 | 니폰 제온 가부시키가이샤 | 중합체 함유물 및 그 제조 방법, 그리고, 필름 |
| KR20230144001A (ko) | 2021-02-02 | 2023-10-13 | 아페이론 신세시스 에스.아. | 올레핀 복분해를 위한 (전)촉매로서의 긴 저장 수명 안정성을 갖는 유기 루테늄 복합체 |
| WO2024083874A1 (en) | 2022-10-21 | 2024-04-25 | Merck Patent Gmbh | Composition |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100869981B1 (ko) * | 2001-03-26 | 2008-11-24 | 다우 글로벌 테크놀로지스 인크. | 불포화 지방산 에스테르 또는 불포화 지방산과 저급 올레핀과의 상호교환반응 |
| US7683180B2 (en) * | 2001-04-16 | 2010-03-23 | California Institute Of Technology | Group 8 transition metal carbene complexes as enantionselective olefin metathesis catalysts |
| PL199412B1 (pl) * | 2002-10-15 | 2008-09-30 | Boehringer Ingelheim Int | Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania |
| PL199428B1 (pl) | 2003-12-29 | 2008-09-30 | Polska Akademia Nauk Instytut | Nowe kompleksy rutenu, pochodne 2-alkoksy-4-nitrostyrenu jako (pre)katalizatory (54) reakcji metatezy, pochodne 2-alkoksy-4-nitrostyrenu jako związki pośrednie oraz sposób ich wytwarzania |
| KR101269568B1 (ko) * | 2005-07-04 | 2013-06-04 | 자난 사이텍 컴퍼니 리미티드 | 루테늄 착물 리간드, 루테늄 착물, 고정 루테늄 착물 촉매및 그의 제조방법과 용도 |
| RU2311231C1 (ru) * | 2006-08-15 | 2007-11-27 | ООО "Объединенный центр исследований и разработок" | Катализатор для получения эфиров акриловой кислоты по реакции метатезиса диалкилмалеатов (варианты) и каталитическая композиция на его основе |
| DE102006040569A1 (de) * | 2006-08-30 | 2008-03-06 | Lanxess Deutschland Gmbh | Verfahren zum Metathese-Abbau von Nitrilkautschuken |
| DE102006043704A1 (de) | 2006-09-18 | 2008-03-27 | Umicore Ag & Co. Kg | Neue Metathesekatalysatoren |
| EP2255877B1 (en) | 2009-05-07 | 2014-09-24 | Umicore AG & Co. KG | Method for preparation of ruthenium-based metathesis catalysts with chelating alkylidene ligands |
| RU2402572C1 (ru) * | 2009-07-09 | 2010-10-27 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Способ получения полидициклопентадиена и материалов на его основе |
| CN102476060B (zh) * | 2010-11-24 | 2013-07-10 | 中国石油化工股份有限公司 | 一种烯烃复分解催化剂及其制备方法 |
| PL400162A1 (pl) | 2012-07-27 | 2014-02-03 | Apeiron Synthesis Spólka Z Ograniczona Odpowiedzialnoscia | Nowe kompleksy rutenu, ich zastosowanie w reakcjach metatezy oraz sposób prowadzenia reakcji metatezy |
-
2012
- 2012-07-27 PL PL400162A patent/PL400162A1/pl unknown
-
2013
- 2013-07-26 WO PCT/EP2013/065839 patent/WO2014016422A1/en active Application Filing
- 2013-07-26 RU RU2014152207/04A patent/RU2586213C1/ru active
- 2013-07-26 CA CA2875956A patent/CA2875956C/en active Active
- 2013-07-26 CN CN201380036034.XA patent/CN104428306B/zh active Active
- 2013-07-26 SG SG11201408224SA patent/SG11201408224SA/en unknown
- 2013-07-26 KR KR1020157000377A patent/KR101749238B1/ko active IP Right Grant
- 2013-07-26 JP JP2015523570A patent/JP6121533B2/ja active Active
- 2013-07-26 AU AU2013294909A patent/AU2013294909B2/en active Active
- 2013-07-26 US US14/406,741 patent/US9328132B2/en active Active
- 2013-07-26 EP EP13745377.5A patent/EP2877478B1/en active Active
- 2013-07-26 PL PL13745377T patent/PL2877478T3/pl unknown
-
2014
- 2014-12-08 IL IL236128A patent/IL236128A/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| IL236128A (en) | 2017-07-31 |
| JP6121533B2 (ja) | 2017-04-26 |
| EP2877478A1 (en) | 2015-06-03 |
| CN104428306B (zh) | 2017-05-24 |
| EP2877478B1 (en) | 2016-11-16 |
| AU2013294909B2 (en) | 2015-11-19 |
| WO2014016422A1 (en) | 2014-01-30 |
| PL400162A1 (pl) | 2014-02-03 |
| JP2015525776A (ja) | 2015-09-07 |
| RU2586213C1 (ru) | 2016-06-10 |
| CN104428306A (zh) | 2015-03-18 |
| IL236128A0 (en) | 2015-02-01 |
| CA2875956C (en) | 2016-01-19 |
| PL2877478T3 (pl) | 2017-05-31 |
| US20150158896A1 (en) | 2015-06-11 |
| US9328132B2 (en) | 2016-05-03 |
| KR101749238B1 (ko) | 2017-06-20 |
| AU2013294909A1 (en) | 2015-01-22 |
| KR20150023672A (ko) | 2015-03-05 |
| CA2875956A1 (en) | 2014-01-30 |
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