SE450833B - Forfarande for framstellning av tricyklohexyltennhydroxid - Google Patents
Forfarande for framstellning av tricyklohexyltennhydroxidInfo
- Publication number
- SE450833B SE450833B SE8004716A SE8004716A SE450833B SE 450833 B SE450833 B SE 450833B SE 8004716 A SE8004716 A SE 8004716A SE 8004716 A SE8004716 A SE 8004716A SE 450833 B SE450833 B SE 450833B
- Authority
- SE
- Sweden
- Prior art keywords
- reaction
- reaction vessel
- halide
- cyclohexylmagnesium
- tin
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 22
- 238000002360 preparation method Methods 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims description 48
- -1 cyclohexylmagnesium halide Chemical class 0.000 claims description 26
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 15
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- WCMMILVIRZAPLE-UHFFFAOYSA-M cyhexatin Chemical compound C1CCCCC1[Sn](C1CCCCC1)(O)C1CCCCC1 WCMMILVIRZAPLE-UHFFFAOYSA-M 0.000 claims description 9
- 238000004821 distillation Methods 0.000 claims description 9
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 7
- 239000003518 caustics Substances 0.000 claims description 7
- 230000007062 hydrolysis Effects 0.000 claims description 7
- 238000006460 hydrolysis reaction Methods 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000012074 organic phase Substances 0.000 description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- 239000003153 chemical reaction reagent Substances 0.000 description 10
- 238000009833 condensation Methods 0.000 description 10
- 230000005494 condensation Effects 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 239000008346 aqueous phase Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000010924 continuous production Methods 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- JUISPCSEIXBMNI-UHFFFAOYSA-N tetracyclohexylstannane Chemical compound C1CCCCC1[Sn](C1CCCCC1)(C1CCCCC1)C1CCCCC1 JUISPCSEIXBMNI-UHFFFAOYSA-N 0.000 description 5
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- WMJMABVHDMRMJA-UHFFFAOYSA-M [Cl-].[Mg+]C1CCCCC1 Chemical compound [Cl-].[Mg+]C1CCCCC1 WMJMABVHDMRMJA-UHFFFAOYSA-M 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- BRCGUTSVMPKEKH-UHFFFAOYSA-N dicyclohexyltin Chemical compound C1CCCCC1[Sn]C1CCCCC1 BRCGUTSVMPKEKH-UHFFFAOYSA-N 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- YICRPERKKBDRSP-UHFFFAOYSA-N methyl 3-amino-4-methylthiophene-2-carboxylate Chemical compound COC(=O)C=1SC=C(C)C=1N YICRPERKKBDRSP-UHFFFAOYSA-N 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000003747 Grignard reaction Methods 0.000 description 1
- 239000004063 acid-resistant material Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- QULMZVWEGVTWJY-UHFFFAOYSA-N dicyclohexyl(oxo)tin Chemical compound C1CCCCC1[Sn](=O)C1CCCCC1 QULMZVWEGVTWJY-UHFFFAOYSA-N 0.000 description 1
- NXLNBJXGFFFGIT-UHFFFAOYSA-L dicyclohexyltin(2+);dichloride Chemical compound C1CCCCC1[Sn](Cl)(Cl)C1CCCCC1 NXLNBJXGFFFGIT-UHFFFAOYSA-L 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000004094 preconcentration Methods 0.000 description 1
- RNVJQUPAEIQUTC-UHFFFAOYSA-N tricyclohexyltin Chemical compound C1CCCCC1[Sn](C1CCCCC1)C1CCCCC1 RNVJQUPAEIQUTC-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2224—Compounds having one or more tin-oxygen linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT23893/79A IT1121958B (it) | 1979-06-27 | 1979-06-27 | Procedimento per ottenere tricicloesilstagno idrossido di elevata purezza con alte rese |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE8004716L SE8004716L (sv) | 1980-12-28 |
| SE450833B true SE450833B (sv) | 1987-08-03 |
Family
ID=11210697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8004716A SE450833B (sv) | 1979-06-27 | 1980-06-26 | Forfarande for framstellning av tricyklohexyltennhydroxid |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US4330477A (forum.php) |
| JP (1) | JPS5639095A (forum.php) |
| AR (1) | AR220847A1 (forum.php) |
| AT (1) | AT379813B (forum.php) |
| AU (1) | AU538683B2 (forum.php) |
| BE (1) | BE883956A (forum.php) |
| BR (1) | BR8003920A (forum.php) |
| CA (1) | CA1136150A (forum.php) |
| CH (1) | CH646708A5 (forum.php) |
| DE (1) | DE3023149A1 (forum.php) |
| DK (1) | DK280880A (forum.php) |
| ES (1) | ES492809A0 (forum.php) |
| FR (1) | FR2459804B1 (forum.php) |
| GB (1) | GB2053224B (forum.php) |
| IL (1) | IL60297A (forum.php) |
| IT (1) | IT1121958B (forum.php) |
| MX (1) | MX155945A (forum.php) |
| NL (1) | NL8003407A (forum.php) |
| SE (1) | SE450833B (forum.php) |
| SU (1) | SU1213987A3 (forum.php) |
| YU (1) | YU40881B (forum.php) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3435717A1 (de) * | 1984-09-28 | 1986-04-10 | Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München | Verfahren zur herstellung von tricyclohexylzinnhydroxid |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3010979A (en) * | 1955-07-05 | 1961-11-28 | Metal & Thermit Corp | Chemical process and product |
| US3067226A (en) * | 1960-04-20 | 1962-12-04 | Exxon Research Engineering Co | Preparation of organotin compounds |
| FR1434534A (fr) * | 1964-04-08 | 1966-04-08 | M & T Chemicals | Procédé de préparation de composés organiques d'étain |
| GB1084076A (forum.php) * | 1964-04-08 | 1900-01-01 | ||
| US3355470A (en) * | 1964-05-06 | 1967-11-28 | M & T Chemicals Inc | Process for preparing tri-cyclohexyltin halides |
| US3402189A (en) * | 1966-03-29 | 1968-09-17 | M & T Chemicals Inc | Process for preparing tricyclohexyl tin hydroxide |
| US3607891A (en) * | 1969-04-16 | 1971-09-21 | M & T Chemicals Inc | Process for preparing tricyclohexyltin halides |
| IL42501A (en) * | 1972-06-24 | 1976-12-31 | Oxon Italia Spa | Process for preparing tricyclohexyltin derivatives |
| IT1002391B (it) * | 1973-12-28 | 1976-05-20 | Oxon Italia Spa | Procedimento per la preparazione di tricicloesilstagno derivati |
| IT1038754B (it) * | 1975-06-06 | 1979-11-30 | Oxon Italia Spa | Procedimento continuo per la produzione di cicloesilmagnesioaloge nuri |
| US4174346A (en) * | 1976-01-30 | 1979-11-13 | Albright & Wilson Limited | Process for preparing organotin compounds |
| DD134529A1 (de) * | 1978-01-09 | 1979-03-07 | Alfred Tzschach | Verfahren zur herstellung von tricyclohexylzinnverbindungen |
-
1979
- 1979-06-27 IT IT23893/79A patent/IT1121958B/it active
-
1980
- 1980-05-20 US US06/151,594 patent/US4330477A/en not_active Expired - Lifetime
- 1980-06-11 IL IL60297A patent/IL60297A/xx unknown
- 1980-06-12 NL NL8003407A patent/NL8003407A/nl not_active Application Discontinuation
- 1980-06-17 CH CH469980A patent/CH646708A5/it not_active IP Right Cessation
- 1980-06-20 DE DE19803023149 patent/DE3023149A1/de active Granted
- 1980-06-23 FR FR8013842A patent/FR2459804B1/fr not_active Expired
- 1980-06-23 BE BE0/201136A patent/BE883956A/fr not_active IP Right Cessation
- 1980-06-24 BR BR8003920A patent/BR8003920A/pt not_active IP Right Cessation
- 1980-06-25 GB GB8020843A patent/GB2053224B/en not_active Expired
- 1980-06-26 SE SE8004716A patent/SE450833B/sv not_active IP Right Cessation
- 1980-06-26 AT AT0335280A patent/AT379813B/de not_active IP Right Cessation
- 1980-06-26 SU SU802938601A patent/SU1213987A3/ru active
- 1980-06-26 MX MX182919A patent/MX155945A/es unknown
- 1980-06-26 AR AR281551A patent/AR220847A1/es active
- 1980-06-26 ES ES492809A patent/ES492809A0/es active Granted
- 1980-06-26 CA CA000354891A patent/CA1136150A/en not_active Expired
- 1980-06-27 JP JP8768780A patent/JPS5639095A/ja active Granted
- 1980-06-27 AU AU59730/80A patent/AU538683B2/en not_active Ceased
- 1980-06-27 YU YU1692/80A patent/YU40881B/xx unknown
- 1980-06-27 DK DK280880A patent/DK280880A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE3023149A1 (de) | 1981-01-08 |
| AU5973080A (en) | 1981-01-08 |
| GB2053224A (en) | 1981-02-04 |
| ES8105739A1 (es) | 1981-06-01 |
| SU1213987A3 (ru) | 1986-02-23 |
| US4330477A (en) | 1982-05-18 |
| NL8003407A (nl) | 1980-12-30 |
| CA1136150A (en) | 1982-11-23 |
| BR8003920A (pt) | 1981-01-27 |
| ES492809A0 (es) | 1981-06-01 |
| YU40881B (en) | 1986-08-31 |
| ATA335280A (de) | 1985-07-15 |
| FR2459804B1 (fr) | 1986-06-13 |
| DE3023149C2 (forum.php) | 1989-07-13 |
| MX155945A (es) | 1988-05-27 |
| IL60297A (en) | 1984-11-30 |
| DK280880A (da) | 1980-12-28 |
| GB2053224B (en) | 1983-07-13 |
| JPS5639095A (en) | 1981-04-14 |
| BE883956A (fr) | 1980-10-16 |
| SE8004716L (sv) | 1980-12-28 |
| AT379813B (de) | 1986-03-10 |
| AR220847A1 (es) | 1980-11-28 |
| JPS6352630B2 (forum.php) | 1988-10-19 |
| CH646708A5 (it) | 1984-12-14 |
| IT1121958B (it) | 1986-04-23 |
| FR2459804A1 (fr) | 1981-01-16 |
| AU538683B2 (en) | 1984-08-23 |
| YU169280A (en) | 1983-10-31 |
| IT7923893A0 (it) | 1979-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS639498B2 (forum.php) | ||
| CA1192908A (en) | Producing oximinosilanes, oximinogermanes and oximinostannanes | |
| US4196289A (en) | Process for producing triallyl isocyanurate | |
| JPH10158280A (ja) | カルボノイルオキシシラン中の酸性の塩素の残量の除去法および該方法で得られたカルボノイルオキシシラン | |
| US4968823A (en) | Process for the fractional production of alkytin oxide | |
| SE450833B (sv) | Forfarande for framstellning av tricyklohexyltennhydroxid | |
| GB2063264A (en) | Treatment of waste stream from adipic acid manufacture | |
| EP3774726A1 (en) | Process for producing 4,4`-dichlorodiphenyl sulfoxide | |
| CN110003266B (zh) | 一种高品质的3-辛酰基硫代-1-丙基三乙氧基硅烷的环保生产方法 | |
| EP3921303A1 (en) | A process for obtaining 4,4'-dichlorodiphenyl sulfoxide | |
| JPH08795B2 (ja) | 炭酸ジアリ−ルの製造方法 | |
| US10919924B2 (en) | Treatment of antimony bearing residues for production of potassium antimony tartrate | |
| JP3750000B2 (ja) | フェノキシエタノールの回収方法及びフルオレン誘導品の製造方法 | |
| US3751437A (en) | Batch and continuous process for preparing menadione | |
| EP3921301A1 (en) | Process for producing 4,4'-dichlorodiphenyl sulfoxide | |
| CN113666821A (zh) | 高收率三氯乙酰氯制备系统及方法 | |
| EP0136995A2 (en) | Preparation of 2-(methylthiomethyl)-6-(trifluoromethyl) aniline from ortho-aminobenzotrifluoride | |
| JPH08291189A (ja) | ６−オキソ−（６Ｈ）−ジベンズ−［ｃ，ｅ］［１，２］−オキサフオスフオリンの製造法 | |
| CN1027062C (zh) | 2-氯对苯二酰氯的制备 | |
| JPH08325183A (ja) | ビスフェノールａの製造方法 | |
| US3555074A (en) | Process for producing an insecticide | |
| JP3818744B2 (ja) | ジアリールカーボネートの精製方法 | |
| US20220162068A1 (en) | Processes useful in the manufacture of cyclododecasulfur | |
| JP4096375B2 (ja) | ジアリールカーボネートの製造方法 | |
| US20220169506A1 (en) | Processes useful in the manufacture of cyclododecasulfur |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
Ref document number: 8004716-0 Effective date: 19930109 Format of ref document f/p: F |