SE439301B - Forfarande for kontinuerlig bildning av en syraflourid av kolmonoxid, vattenfri vetefluorid och ett olefin - Google Patents
Forfarande for kontinuerlig bildning av en syraflourid av kolmonoxid, vattenfri vetefluorid och ett olefinInfo
- Publication number
- SE439301B SE439301B SE8200471A SE8200471A SE439301B SE 439301 B SE439301 B SE 439301B SE 8200471 A SE8200471 A SE 8200471A SE 8200471 A SE8200471 A SE 8200471A SE 439301 B SE439301 B SE 439301B
- Authority
- SE
- Sweden
- Prior art keywords
- high turbulence
- olefin
- reaction
- reactor
- reactant mixture
- Prior art date
Links
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims description 19
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 title claims description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 12
- 238000000034 method Methods 0.000 title claims description 10
- 241000209140 Triticum Species 0.000 title 1
- 235000021307 Triticum Nutrition 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 claims description 39
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 37
- 238000006243 chemical reaction Methods 0.000 claims description 34
- 239000000376 reactant Substances 0.000 claims description 19
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 15
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 12
- 239000007791 liquid phase Substances 0.000 description 9
- 239000012071 phase Substances 0.000 description 7
- 238000001816 cooling Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- -1 ethylene, propylene, butene Chemical class 0.000 description 3
- 230000000135 prohibitive effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- 238000006471 dimerization reaction Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- KZDCMKVLEYCGQX-UDPGNSCCSA-N 2-(diethylamino)ethyl 4-aminobenzoate;(2s,5r,6r)-3,3-dimethyl-7-oxo-6-[(2-phenylacetyl)amino]-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid;hydrate Chemical compound O.CCN(CC)CCOC(=O)C1=CC=C(N)C=C1.N([C@H]1[C@H]2SC([C@@H](N2C1=O)C(O)=O)(C)C)C(=O)CC1=CC=CC=C1 KZDCMKVLEYCGQX-UDPGNSCCSA-N 0.000 description 1
- FSQOYWQCIXSBNP-UHFFFAOYSA-N 2-methylpropanoyl fluoride Chemical compound CC(C)C(F)=O FSQOYWQCIXSBNP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 230000000447 dimerizing effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/38—Acyl halides
- C07C53/42—Acyl halides of acids containing three or more carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/228,305 US4495110A (en) | 1981-01-26 | 1981-01-26 | Method of continuously forming an acid fluoride from carbon monoxide, anhydrous hydrogen fluoride and an olefin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE8200471L SE8200471L (sv) | 1983-07-29 |
| SE439301B true SE439301B (sv) | 1985-06-10 |
Family
ID=22856621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8200471A SE439301B (sv) | 1981-01-26 | 1982-01-28 | Forfarande for kontinuerlig bildning av en syraflourid av kolmonoxid, vattenfri vetefluorid och ett olefin |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US4495110A (pl) |
| JP (1) | JPS6024087B2 (pl) |
| KR (1) | KR850001371B1 (pl) |
| AT (1) | AT386598B (pl) |
| AU (1) | AU527823B2 (pl) |
| BR (1) | BR8200427A (pl) |
| CA (1) | CA1172657A (pl) |
| CH (1) | CH649278A5 (pl) |
| DD (1) | DD208346A5 (pl) |
| DE (1) | DE3202292C2 (pl) |
| ES (1) | ES8302601A1 (pl) |
| FR (1) | FR2498593B1 (pl) |
| GB (1) | GB2092142B (pl) |
| IT (1) | IT1150154B (pl) |
| MX (1) | MX157368A (pl) |
| NL (1) | NL187806C (pl) |
| PL (1) | PL139817B1 (pl) |
| SE (1) | SE439301B (pl) |
| ZA (1) | ZA82501B (pl) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3213395A1 (de) * | 1982-04-10 | 1983-10-13 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung von isobuttersaeurefluorid bzw. isobuttersaeure |
| US4499029A (en) * | 1983-06-15 | 1985-02-12 | Ashland Oil, Inc. | Isobutyryl fluoride manufacture |
| CA1253880A (en) * | 1984-06-18 | 1989-05-09 | Carlo Scaccia | Gas-liquid process for preparing isobutyryl fluoride and reactor therefor |
| DE3771684D1 (de) * | 1986-11-20 | 1991-08-29 | Atochem | Katalytisches alkankarbonylierungsverfahren. |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3059005A (en) * | 1962-10-16 | Process for the production of | ||
| US2831877A (en) * | 1952-03-24 | 1958-04-22 | Studiengesellschaft Kohel Mit | Production of carboxylic acids from olefins |
| US2876241A (en) * | 1954-05-15 | 1959-03-03 | Studiengesellschaft Kohle Mit | Process for the production of carboxylic acids |
| US3005846A (en) * | 1959-04-06 | 1961-10-24 | Sinclair Refining Co | Production of acids and esters |
| US3065242A (en) * | 1960-02-23 | 1962-11-20 | Du Pont | Production of acyl halides, carboxylic acids and lactones |
| DE1226557B (de) * | 1962-03-03 | 1966-10-13 | Schering Ag | Verfahren zur Herstellung von Methyl-, AEthyl- oder Propylestern gesaettigter alpha-alkylverzweigter Fettsaeuren mit mindestens 4 Kohlenstoffatomen |
| FR1377834A (fr) * | 1963-12-19 | 1964-11-06 | Exxon Research Engineering Co | Procédé perfectionné de synthèse d'acides carboxyliques |
| NL6910591A (pl) * | 1969-07-10 | 1971-01-12 | ||
| US3661951A (en) * | 1969-12-01 | 1972-05-09 | Armour Ind Chem Co | Carboxylation of olefins |
-
1981
- 1981-01-26 US US06/228,305 patent/US4495110A/en not_active Expired - Lifetime
-
1982
- 1982-01-22 CA CA000395816A patent/CA1172657A/en not_active Expired
- 1982-01-26 JP JP57011458A patent/JPS6024087B2/ja not_active Expired
- 1982-01-26 IT IT19317/82A patent/IT1150154B/it active
- 1982-01-26 DD DD82236979A patent/DD208346A5/de not_active IP Right Cessation
- 1982-01-26 BR BR8200427A patent/BR8200427A/pt unknown
- 1982-01-26 DE DE3202292A patent/DE3202292C2/de not_active Expired
- 1982-01-26 GB GB8202156A patent/GB2092142B/en not_active Expired
- 1982-01-26 ES ES509885A patent/ES8302601A1/es not_active Expired
- 1982-01-26 KR KR8200312A patent/KR850001371B1/ko not_active Expired
- 1982-01-26 ZA ZA82501A patent/ZA82501B/xx unknown
- 1982-01-26 CH CH730/82A patent/CH649278A5/de not_active IP Right Cessation
- 1982-01-26 MX MX191145A patent/MX157368A/es unknown
- 1982-01-26 AT AT0027582A patent/AT386598B/de not_active IP Right Cessation
- 1982-01-26 NL NLAANVRAGE8200276,A patent/NL187806C/xx not_active IP Right Cessation
- 1982-01-26 FR FR8201196A patent/FR2498593B1/fr not_active Expired
- 1982-01-27 AU AU79893/82A patent/AU527823B2/en not_active Ceased
- 1982-01-28 SE SE8200471A patent/SE439301B/sv not_active IP Right Cessation
- 1982-02-23 PL PL1982235185A patent/PL139817B1/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA1172657A (en) | 1984-08-14 |
| AT386598B (de) | 1988-09-12 |
| DD208346A5 (de) | 1984-05-02 |
| FR2498593B1 (fr) | 1985-06-28 |
| IT1150154B (it) | 1986-12-10 |
| ES509885A0 (es) | 1983-01-16 |
| IT8219317A0 (it) | 1982-01-26 |
| KR850001371B1 (ko) | 1985-09-24 |
| DE3202292A1 (de) | 1982-08-12 |
| AU527823B2 (en) | 1983-03-24 |
| ES8302601A1 (es) | 1983-01-16 |
| NL187806B (nl) | 1991-08-16 |
| PL139817B1 (en) | 1987-02-28 |
| SE8200471L (sv) | 1983-07-29 |
| US4495110A (en) | 1985-01-22 |
| ATA27582A (de) | 1988-02-15 |
| JPS57142939A (en) | 1982-09-03 |
| MX157368A (es) | 1988-11-18 |
| GB2092142A (en) | 1982-08-11 |
| CH649278A5 (de) | 1985-05-15 |
| BR8200427A (pt) | 1982-11-30 |
| PL235185A1 (en) | 1983-03-28 |
| FR2498593A1 (fr) | 1982-07-30 |
| GB2092142B (en) | 1984-12-05 |
| ZA82501B (en) | 1982-12-29 |
| KR830008970A (ko) | 1983-12-16 |
| DE3202292C2 (de) | 1985-06-20 |
| NL187806C (nl) | 1992-01-16 |
| AU7989382A (en) | 1982-08-05 |
| JPS6024087B2 (ja) | 1985-06-11 |
| NL8200276A (nl) | 1982-08-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
Ref document number: 8200471-4 Effective date: 19940810 Format of ref document f/p: F |