SE427752B - Forfarande for framstellning n-fosfonometylglycin - Google Patents

Forfarande for framstellning n-fosfonometylglycin

Info

Publication number
SE427752B
SE427752B SE7505040A SE7505040A SE427752B SE 427752 B SE427752 B SE 427752B SE 7505040 A SE7505040 A SE 7505040A SE 7505040 A SE7505040 A SE 7505040A SE 427752 B SE427752 B SE 427752B
Authority
SE
Sweden
Prior art keywords
phosphonomethylgyline
procedure
preparation
Prior art date
Application number
SE7505040A
Other languages
English (en)
Swedish (sv)
Other versions
SE7505040L (sv
Inventor
A Hershman
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of SE7505040L publication Critical patent/SE7505040L/xx
Publication of SE427752B publication Critical patent/SE427752B/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SE7505040A 1974-05-01 1975-04-30 Forfarande for framstellning n-fosfonometylglycin SE427752B (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/465,976 US3969398A (en) 1974-05-01 1974-05-01 Process for producing N-phosphonomethyl glycine
KR7500924A KR790000297B1 (en) 1974-05-01 1975-04-30 Process for producing n-phosphono methyl gylcine

Publications (2)

Publication Number Publication Date
SE7505040L SE7505040L (sv) 1975-11-03
SE427752B true SE427752B (sv) 1983-05-02

Family

ID=26625851

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7505040A SE427752B (sv) 1974-05-01 1975-04-30 Forfarande for framstellning n-fosfonometylglycin

Country Status (27)

Country Link
US (1) US3969398A (OSRAM)
JP (1) JPS5330690B2 (OSRAM)
KR (1) KR790000297B1 (OSRAM)
AR (1) AR215840A1 (OSRAM)
AT (1) AT336637B (OSRAM)
BE (1) BE828599A (OSRAM)
BG (1) BG26398A3 (OSRAM)
BR (1) BR7502651A (OSRAM)
CA (1) CA1030157A (OSRAM)
CH (1) CH613210A5 (OSRAM)
CS (1) CS179938B2 (OSRAM)
DD (1) DD119241A5 (OSRAM)
DE (1) DE2519388C3 (OSRAM)
DK (1) DK138655B (OSRAM)
EG (1) EG11700A (OSRAM)
ES (1) ES437154A1 (OSRAM)
FR (1) FR2269533B1 (OSRAM)
GB (1) GB1467778A (OSRAM)
IE (1) IE41118B1 (OSRAM)
IT (1) IT1037766B (OSRAM)
MY (1) MY7800280A (OSRAM)
NL (1) NL161763C (OSRAM)
PH (1) PH12324A (OSRAM)
RO (1) RO70907A (OSRAM)
SE (1) SE427752B (OSRAM)
YU (1) YU40117B (OSRAM)
ZA (1) ZA752792B (OSRAM)

Families Citing this family (93)

* Cited by examiner, † Cited by third party
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US4100275A (en) * 1975-01-27 1978-07-11 Hoffmann-La Roche Inc. Compositions having antibiotic properties
IL48835A (en) * 1975-01-27 1979-05-31 Sparamedica Ag Amino acyl and peptidyl derivatives of phophonic acids, their preparation and pharmaceutical compositions containingthem
US4127649A (en) * 1975-01-27 1978-11-28 Hoffmann-La Roche Inc. Compositions having antibiotic properties
US4134972A (en) * 1976-07-21 1979-01-16 Hoffmann-La Roche Inc. Compositions having antibiotic properties
MX4703E (es) * 1976-12-20 1982-08-04 Monsanto Co Procedimiento mejorado para la preparacion de mono y disales de n-fosfonometilglicina
HU184168B (en) * 1979-05-11 1984-07-30 Mta Koezponti Kemiai Kutato In Process for producing n-bracket-phosphono-methyl-bracket closed-glycine
US4454043A (en) * 1980-11-17 1984-06-12 Monsanto Company Column switching procedure
IL65187A (en) * 1982-03-08 1985-03-31 Geshuri Lab Ltd N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them
IL66824A0 (en) * 1982-06-25 1982-12-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
US4442041A (en) * 1982-06-30 1984-04-10 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
US4654429A (en) * 1983-12-02 1987-03-31 Monsanto Company Process for the preparation of a glyphosate product
US4617415A (en) * 1983-12-02 1986-10-14 Monsanto Company α-Substituted N-phosphonomethyliminodiacetic acid
US4624937A (en) * 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US5874612A (en) * 1984-12-28 1999-02-23 Baysdon; Sherrol L. Process for the preparation of glyphosate and glyphosate derivatives
US5068404A (en) * 1984-12-28 1991-11-26 Monsanto Company Thermal dealkylation of N-alkyl N-phosphonomethylglycine
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
DE3532344A1 (de) * 1985-09-11 1987-03-19 Hoechst Ag Verfahren zur herstellung von n-phosphonomethylglycin
US4684483A (en) * 1985-09-23 1987-08-04 Monsanto Company Preparation of N-substituted amino acids
US4694082A (en) * 1985-09-23 1987-09-15 Monsanto Company Compound 1,4-diisopropyl-2,5-diketopiperazine
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
US4740608A (en) * 1985-10-09 1988-04-26 Monsanto Company (Phosphonomethyl)trifluoromethyl sulfonates
US4853159A (en) * 1987-10-26 1989-08-01 Monsanto Company Process for producing N-phosphonomethylglycine
US4898972A (en) * 1988-09-26 1990-02-06 Monsanto Company Process for producing N-phosphonomethylglycine
US4965403A (en) * 1988-11-07 1990-10-23 Monsanto Company Oxidation/dealkylation process
US4937376A (en) * 1989-05-25 1990-06-26 Monsanto Company Process for producing N-phosphonomethylglycine
US4952723A (en) * 1989-07-31 1990-08-28 Monsanto Company Process for producing N-phosphonomethylglycine
US5095140A (en) * 1990-06-25 1992-03-10 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5312973A (en) * 1993-03-25 1994-05-17 Finchimica S.P.A. Process for producing n-phosphono-methyl-imino-diacetic acid
GB9410524D0 (en) * 1993-06-21 1994-07-13 Zeneca Ltd Manufacture of n- phosphonomethylglycine and its salts
SI9400449A (en) * 1994-12-20 1996-06-30 Pinus D D Process for preparing N-phosphonomethyl glycin
DE19500121A1 (de) * 1995-01-04 1996-07-11 Bayer Ag Verfahren zur Herstellung von N-Phosphonomethylglycin
TW322481B (OSRAM) * 1995-03-07 1997-12-11 Sankyo Co
AU699417B2 (en) * 1995-03-14 1998-12-03 Monsanto Company Treatment of a formaldehyde-containing waste stream
US6365772B1 (en) * 1995-05-30 2002-04-02 Hampshire Chemical Corp. Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
US6054608A (en) * 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
JP2002510305A (ja) * 1998-02-12 2002-04-02 モンサント カンパニー Ｎ―置換グリホサートの酸化によるグリホサートの製造方法
US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
ZA991905B (en) 1998-03-09 1999-11-29 Monsanto Co Tank mixtures and premixtures for weed control programs that include postemergence application of glyphosate plus graminicides in glyphosate tolerant soybeans.
US5942643A (en) * 1998-05-14 1999-08-24 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a low temperature catalytic carbon
US5962729A (en) * 1998-05-14 1999-10-05 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
JP2002522549A (ja) * 1998-08-12 2002-07-23 モンサント カンパニー Ｎ−（ホスホノメチル）イミノ二酢酸の連続製造法
BR9907000A (pt) * 1998-09-08 2000-09-26 Hampshire Chemical Corp Sìntese de ácido fosfonometiliminodiacético com efluente reduzido
US6194604B1 (en) 1998-12-10 2001-02-27 Monsanto Company Process for producing phosphorous acid
HUP0201940A2 (en) 1999-07-23 2002-09-28 Basf Ag Method of producing glyphosate or a salt thereof
PL355888A1 (en) 1999-12-21 2004-05-31 Monsanto Technology Llc. Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal-containing catalyst in liquid phase oxidation reactions
DE10007702A1 (de) * 2000-02-19 2001-08-23 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-(Phosphonomethyl)glycin
US6274760B1 (en) 2000-03-14 2001-08-14 Monsanto Co. Preparation of formylphosphonic acid from tertiary aminomethylphosphonic acid N-oxides
US6376708B1 (en) 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
CN100354256C (zh) 2000-05-15 2007-12-12 孟山都技术有限责任公司 以单乙醇胺为原料制备亚氨基二乙酸化合物
AR038654A1 (es) * 2000-05-22 2005-01-26 Monsanto Technology Llc Sistemas de reaccion para producir compuestos de n-(fosfonometil) glicina
US6927304B2 (en) 2000-05-22 2005-08-09 Monsanto Technology Llc De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions
CN101311183B (zh) * 2000-05-22 2011-08-31 孟山都技术有限责任公司 制备n-(膦酰基甲基)甘氨酸化合物的反应系统
US6441223B1 (en) 2000-11-30 2002-08-27 Monsanto Technology Llc Method of making phosphorus-containing compounds and products thereof
US6818450B2 (en) 2001-05-22 2004-11-16 Monsanto Technology Llc Use of infrared spectroscopy for on-line process control and endpoint detection
DE10130136A1 (de) * 2001-06-22 2003-01-02 Basf Ag Verfahren zur Gewinnung von N-Phosphonomethylglycin
CN1729052A (zh) 2001-10-18 2006-02-01 孟山都技术公司 用于伯醇脱氢以制备羧酸盐的方法和催化剂
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
CN1315570C (zh) * 2002-02-14 2007-05-16 孟山都技术公司 氧化催化剂及其制备方法和使用该催化剂的氧化方法
US6921834B2 (en) 2002-05-22 2005-07-26 Dow Agrosciences Llc Continuous process for preparing N-phosphonomethyl glycine
JP4202047B2 (ja) * 2002-05-24 2008-12-24 富士通株式会社 ヘッド位置制御方法及びデイスク記憶装置
AR040319A1 (es) * 2002-06-28 2005-03-23 Monsanto Technology Llc Uso de telurio en catalizadores con contenido de metales nobles y con soporte de carbon para reacciones de oxidacion en fase liquida
CN1867404B (zh) 2003-08-14 2011-06-22 孟山都技术公司 含有过渡金属-碳化物和氮化物的催化剂、它们的制备方法和作为氧化和脱氢催化剂的用途
US7179936B2 (en) * 2003-09-17 2007-02-20 Monsanto Technology Llc Process for recovering a crystalline product from solution
FR2865468B1 (fr) * 2004-01-22 2006-04-28 Ceca Sa Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.
AU2005235111B2 (en) 2004-03-30 2010-10-28 Monsanto Technology Llc Methods for controlling plant pathogens using N-phosphonomethylglycine
CN100372857C (zh) * 2004-05-12 2008-03-05 江苏好收成韦恩农药化工有限公司 N-膦酰基甲基甘氨酸的生产方法
US7893004B2 (en) * 2004-09-06 2011-02-22 Japan Envirochemicals, Ltd. Oxidation reaction catalyst and process for producing a compound using the same
AR051926A1 (es) * 2004-09-15 2007-02-21 Monsanto Technology Llc Catalizadores de oxidacion, procedimientos de preparacion de dichos catalizadores y proceso para la elaboracion de n-( fosfonometil)glicina o una sal de la misma
TW200624151A (en) * 2004-11-12 2006-07-16 Monsanto Technology Llc Recovery of noble metals from aqueous process streams
US8198479B2 (en) 2005-02-17 2012-06-12 Monsanto Technology Llc Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
CN101170907B (zh) 2005-03-04 2012-10-03 孟山都技术公司 减轻用除草剂草甘膦制剂处理的草甘膦耐受性转基因棉花植物内的坏死
BRPI0708081A2 (pt) * 2006-02-17 2011-05-17 Monsanto Technology Llc catalisadores contendo metal de transição e processos para a sua preparação e uso como catalisadores de pilha termoelétrica
CN100460408C (zh) * 2007-01-26 2009-02-11 捷马化工股份有限公司 资源再利用的催化氧化制备草甘膦方法
US7771494B2 (en) * 2007-01-31 2010-08-10 Monsanto Technology Llc Process for selective removal of water and impurities from N-(phosphonomethyl)glycine
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
CN101337978B (zh) * 2008-05-13 2011-06-29 浙江新安化工集团股份有限公司 一种利用富氧气体催化氧化双甘膦制取草甘膦的方法
CN101481387B (zh) * 2008-11-27 2012-02-01 浙江新安化工集团股份有限公司 一种催化氧化合成草甘膦的制备方法
CN101508701B (zh) * 2008-12-10 2012-09-05 上海泰禾(集团)有限公司 一种活性碳作催化剂氧气氧化双甘膦制备草甘膦的方法
WO2010135141A1 (en) 2009-05-18 2010-11-25 Monsanto Technology Llc Recovery of phosphorus values and salt impurities from aqueous waste streams
CN101781332B (zh) * 2010-03-02 2012-10-24 广西壮族自治区化工研究院 活性炭催化空气氧化双甘膦制备草甘膦的方法
CN102241703B (zh) * 2011-05-07 2014-05-07 安徽国星生物化学有限公司 一种改进的双甘膦制备草甘膦的方法
CN104854117B (zh) 2012-07-17 2018-12-25 孟山都技术有限责任公司 用于合成n-膦酰基甲基亚氨基二乙酸的方法
ES2632779T3 (es) 2012-07-17 2017-09-15 Straitmark Holding Ag Método para la síntesis de N-(fosfonometil) glicina
PL2875037T3 (pl) 2012-07-17 2017-06-30 Straitmark Holding Ag Sposób syntezy N-(fosfonometylo)glicyny
EP2875036A1 (en) 2012-07-17 2015-05-27 Straitmark Holding AG Method for the synthesis of aminoalkylenephosphonic acid
US20150232493A1 (en) 2012-07-17 2015-08-20 Straitmark Holding Ag Method for the synthesis of alpha-aminoalkylenephosphonic acid
WO2019005718A1 (en) 2017-06-26 2019-01-03 Monsanto Technology Llc PHOSPHORUS CONTROL FOR WASTE FLOWS FROM GLYPHOSATE MANUFACTURING PROCESSES
CN115215900A (zh) * 2022-07-01 2022-10-21 安徽东至广信农化有限公司 一种草甘膦的节能生产方法

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Also Published As

Publication number Publication date
NL161763C (nl) 1980-03-17
CA1030157A (en) 1978-04-25
CH613210A5 (OSRAM) 1979-09-14
DK188175A (OSRAM) 1975-11-02
IT1037766B (it) 1979-11-20
JPS5330690B2 (OSRAM) 1978-08-29
PH12324A (en) 1979-01-16
DE2519388C3 (de) 1978-03-09
GB1467778A (en) 1977-03-23
DK138655C (OSRAM) 1979-02-26
AR215840A1 (es) 1979-11-15
DE2519388A1 (de) 1975-11-13
BE828599A (fr) 1975-10-30
DD119241A5 (OSRAM) 1976-04-12
ZA752792B (en) 1976-04-28
IE41118B1 (en) 1979-10-24
FR2269533B1 (OSRAM) 1978-02-24
AU8070175A (en) 1976-11-04
SE7505040L (sv) 1975-11-03
RO70907A (ro) 1980-04-15
ATA333975A (de) 1976-09-15
ES437154A1 (es) 1977-01-16
CS179938B2 (en) 1977-12-30
DE2519388B2 (de) 1977-07-14
DK138655B (da) 1978-10-09
BR7502651A (pt) 1976-03-16
JPS50160222A (OSRAM) 1975-12-25
YU111575A (en) 1982-06-30
MY7800280A (en) 1978-12-31
BG26398A3 (bg) 1979-03-15
YU40117B (en) 1985-08-31
US3969398A (en) 1976-07-13
KR790000297B1 (en) 1979-04-23
EG11700A (en) 1977-10-31
FR2269533A1 (OSRAM) 1975-11-28
IE41118L (en) 1975-11-01
NL161763B (nl) 1979-10-15
AT336637B (de) 1977-05-10
NL7505071A (nl) 1975-11-04

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