SE414266B - USE OF ETHYLENOXIDE, METHYL FORMAT, OR MIXTURES THEREOF FOR THE INHIBITION OF MICOTOXINES FROM MOLD Fungi - Google Patents

USE OF ETHYLENOXIDE, METHYL FORMAT, OR MIXTURES THEREOF FOR THE INHIBITION OF MICOTOXINES FROM MOLD Fungi

Info

Publication number
SE414266B
SE414266B SE7404642A SE7404642A SE414266B SE 414266 B SE414266 B SE 414266B SE 7404642 A SE7404642 A SE 7404642A SE 7404642 A SE7404642 A SE 7404642A SE 414266 B SE414266 B SE 414266B
Authority
SE
Sweden
Prior art keywords
mixtures
methyl formate
micotoxines
ethylenoxide
inhibition
Prior art date
Application number
SE7404642A
Other languages
Swedish (sv)
Other versions
SE7404642L (en
Inventor
G Mayr
Original Assignee
Deutsche Ges Schaedlingsbek
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deutsche Ges Schaedlingsbek filed Critical Deutsche Ges Schaedlingsbek
Publication of SE7404642L publication Critical patent/SE7404642L/xx
Publication of SE414266B publication Critical patent/SE414266B/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3409Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Food Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Fodder In General (AREA)
  • Beans For Foods Or Fodder (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Soy Sauces And Products Related Thereto (AREA)
  • Catching Or Destruction (AREA)

Description

'7404642-6 svampar, med etylenoxid, metylformiat eller en blandning av dessa gaser, varvid efter behandlingen inga ytterligare omsättningsprodukter bildas, så mögelsvamparna själva avdödas. I Med mycket gott resultat användes en gasblandning av 40-60 volymprocent metylformiat och 40-60 volymprocent etylenoxid. Fungi, with ethylene oxide, methyl formate or a mixture of these gases, whereby after the treatment no further reaction products are formed, so that the molds themselves are killed. With very good results, a gas mixture of 40-60% by volume of methyl formate and 40-60% by volume of ethylene oxide was used.

För att minska faran för antändning är det i många fall lämpligt att för behandlingen använda en gasblandning, som förutom etylenoxid och/eller metylformiat innehåller en inert gas, såsom kväve eller koldioxid.In order to reduce the risk of ignition, it is in many cases suitable to use for the treatment a gas mixture which, in addition to ethylene oxide and / or methyl formate, contains an inert gas, such as nitrogen or carbon dioxide.

Av säkerhetsskäl är det lämpligt att genomföra behandlingen under reducerat tryck. Vid användning av dessa åtgärder förhindras att behandlingsgasen strömmar ut om behandlingsbehållaren eller behandlingsrummet blir otäta.For safety reasons, it is advisable to carry out the treatment under reduced pressure. When using these measures, the treatment gas is prevented from flowing out if the treatment container or treatment room becomes leaky.

Exempel l.Example 1

Jordnötsexpellermassa, som genom angrepp av en stam av Asper- gillus flavus per gram innehöll 12 pg aflatoxin Bl, infördes i en begasningskammare med en volym av ll liter. Kammaren evakuerades till ett resttryck av 40 torr. Det flytande behandlingsmedlet förgasades i en värmeväxlare och infördes i begasningskammaren. Efter begas- ningstiden avsögs behandlingsmedlet med hjälp av en vakuumpump och steril friskluft infördes genom ett bomullsfilter i begasningskamma- ren till tryckutjämning.Peanut expeller pulp, which by attack of one strain of Aspergillus flavus per gram contained 12 pg of aflatoxin B1, was introduced into a gasification chamber with a volume of 11 liters. The chamber was evacuated to a residual pressure of 40 torr. The liquid treatment agent was gasified in a heat exchanger and introduced into the gasification chamber. After the gassing time, the treatment agent was aspirated by means of a vacuum pump and sterile fresh air was introduced through a cotton filter into the gassing chamber for pressure equalization.

För behandlingen användes följande gaser: A etylenoxid B metylformiat C en blandning av 50 volymprocent etylenoxid och 50 volumprocent metylformiat.The following gases were used for the treatment: A ethylene oxide B methyl formate C a mixture of 50% by volume of ethylene oxide and 50% by volume of methyl formate.

Försöksresultaten framgår av nedanstående tabell: Begasnings- Mängd begasnings- Begasningstid Aflatoxin medel medel g/m3 timmar pg/g - - - 12 A 750_ 6 ll,5 B 750 6 10 C 750 6 8 A 750 16 9,5 B 750 16 6 C 750 16 5,5 forts. tabell '7h04642~6 Begasnings- Mängd begasnings- Begasningstid Aflatoxin medel medel g/m3 timmar ng/g A 1250 6 8 B 1250 4,5 C 1250 6 4 A 1250 16 6,5 B 1250 16 4 C 1250 16 2,5 Påvisningen och den kvantitativa bestämningen av aflatoxin genomfördes enligt förfarandet av Hanssen och Hagedorn (ZUL l4l (1969) 3, l29-145).The test results are shown in the table below: Gassing Amount of gassing Gassing time Aflatoxin average mean g / m3 hours pg / g - - - 12 A 750_ 6 ll, 5 B 750 6 10 C 750 6 8 A 750 16 9.5 B 750 16 6 C 750 16 5.5 cont. table '7h04642 ~ 6 Gassing Amount of gassing Gassing time Aflatoxin average average g / m3 hours ng / g A 1250 6 8 B 1250 4.5 C 1250 6 4 A 1250 16 6.5 B 1250 16 4 C 1250 16 2.5 The detection and quantitative determination of aflatoxin was performed according to the procedure of Hanssen and Hagedorn (ZUL 141 (1969) 3, 132-145).

Exemgel 2.Example 2.

Jordnötter som starkt angripits av en stam av Aspergillus flavus behandlades enligt förfarandet i exempel l. Resultaten framgår av nedanstående tabell: Begasnings- Mängd begasnings- Begasningstid Aflatoxin medel medel g/m3 timmar pg/g - - - 168,0 A 1250 16 115,0 B 1250 16 76,0 C 1250 16 32,5Peanuts heavily infested with a strain of Aspergillus flavus were treated according to the procedure in Example 1. The results are shown in the following table: Gassing Amount of gassing- Gassing time Aflatoxin average mean g / m3 hours pg / g - - - 168.0 A 1250 16 115, 0 B 1250 16 76.0 C 1250 16 32.5

Claims (4)

'74046lf2-6 IL PATENTKRAV'74046lf2-6 IL PATENTKRAV 1. l. Användning av etylenoxid O H // \\ 2C CH2 eller metylformiat O H3C - O - å - CH3 eller blandningar av dessa båda ämnen för att oskadliggöra mykotoxiner härrörande från mögelsvampar.Use of ethylene oxide O H // \\ 2C CH2 or methyl formate O H3C - O - å - CH3 or mixtures of these two substances to neutralize mycotoxins derived from molds. 2. Användning enligt patentkravet l av en blandning av 40-60 volymprocent metylformiat och 40-60 volymprocent etylenoxid.Use according to claim 1 of a mixture of 40-60% by volume of methyl formate and 40-60% by volume of ethylene oxide. 3. ' 3. Användning enligt patentkravet l eller 2 av en gasblandning, som förutomvetylenoxid och/eller metylformiat även innehåller en inert gas. I gUse according to claim 1 or 2 of a gas mixture which, in addition to methylene oxide and / or methyl formate, also contains an inert gas. I g 4. Användning enligt något av patentkraven l-3 av etylenoxid, metylformiat eller blandningar av dessa båda ämnen under reducerat tryck. ANF ÖRDA PUBLIKÅTI ON ER :Use according to any one of claims 1-3 of ethylene oxide, methyl formate or mixtures of these two substances under reduced pressure. ANNOUNCED PUBLICATIONS:
SE7404642A 1974-03-23 1974-04-05 USE OF ETHYLENOXIDE, METHYL FORMAT, OR MIXTURES THEREOF FOR THE INHIBITION OF MICOTOXINES FROM MOLD Fungi SE414266B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2414146A DE2414146A1 (en) 1974-03-23 1974-03-23 PROCEDURE FOR DETERMINING THE TOXIC METABOLIZER PRODUCTS FROM MOLD

Publications (2)

Publication Number Publication Date
SE7404642L SE7404642L (en) 1975-09-24
SE414266B true SE414266B (en) 1980-07-21

Family

ID=5910997

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7404642A SE414266B (en) 1974-03-23 1974-04-05 USE OF ETHYLENOXIDE, METHYL FORMAT, OR MIXTURES THEREOF FOR THE INHIBITION OF MICOTOXINES FROM MOLD Fungi

Country Status (23)

Country Link
JP (1) JPS5337419B2 (en)
AT (1) AT349875B (en)
AU (1) AU7026974A (en)
BE (1) BE816904A (en)
CA (1) CA1030396A (en)
CH (1) CH568023A5 (en)
CS (1) CS172882B2 (en)
CY (1) CY993A (en)
DE (1) DE2414146A1 (en)
DK (1) DK195074A (en)
ES (1) ES425401A1 (en)
FI (1) FI129574A (en)
FR (1) FR2264483B1 (en)
GB (1) GB1442466A (en)
HU (1) HU167434B (en)
IT (1) IT1011770B (en)
NL (1) NL7406365A (en)
NO (1) NO741303L (en)
PL (1) PL88731B1 (en)
SE (1) SE414266B (en)
TR (1) TR19642A (en)
YU (1) YU103074A (en)
ZA (1) ZA743678B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2557599C3 (en) * 1975-12-20 1979-09-27 Degesch Gmbh, 6000 Frankfurt Process for rendering the toxic metabolic products of molds harmless
JPS53106623U (en) * 1977-01-31 1978-08-26

Also Published As

Publication number Publication date
TR19642A (en) 1979-09-19
GB1442466A (en) 1976-07-14
JPS50125051A (en) 1975-10-01
YU103074A (en) 1982-06-30
SE7404642L (en) 1975-09-24
CY993A (en) 1979-08-02
DK195074A (en) 1975-09-24
BE816904A (en) 1974-10-16
ATA291174A (en) 1978-09-15
DE2414146A1 (en) 1975-09-25
PL88731B1 (en) 1976-09-30
AT349875B (en) 1979-04-25
ES425401A1 (en) 1976-06-01
ZA743678B (en) 1975-06-25
NO741303L (en) 1975-09-24
JPS5337419B2 (en) 1978-10-09
FR2264483A1 (en) 1975-10-17
CS172882B2 (en) 1977-01-28
FR2264483B1 (en) 1977-03-11
AU7026974A (en) 1976-01-08
IT1011770B (en) 1977-02-10
CA1030396A (en) 1978-05-02
CH568023A5 (en) 1975-10-31
NL7406365A (en) 1975-09-25
FI129574A (en) 1975-09-24
HU167434B (en) 1975-10-28

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SE414266B (en) USE OF ETHYLENOXIDE, METHYL FORMAT, OR MIXTURES THEREOF FOR THE INHIBITION OF MICOTOXINES FROM MOLD Fungi
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