NO741303L - - Google Patents
Info
- Publication number
- NO741303L NO741303L NO741303A NO741303A NO741303L NO 741303 L NO741303 L NO 741303L NO 741303 A NO741303 A NO 741303A NO 741303 A NO741303 A NO 741303A NO 741303 L NO741303 L NO 741303L
- Authority
- NO
- Norway
- Prior art keywords
- ethylene oxide
- methyl formate
- mixture
- volumes
- treatment
- Prior art date
Links
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 230000002503 metabolic effect Effects 0.000 claims description 7
- 231100000331 toxic Toxicity 0.000 claims description 7
- 230000002588 toxic effect Effects 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 2
- 238000009877 rendering Methods 0.000 claims description 2
- 229930195730 Aflatoxin Natural products 0.000 description 3
- 231100000678 Mycotoxin Toxicity 0.000 description 3
- 239000005409 aflatoxin Substances 0.000 description 3
- 239000002636 mycotoxin Substances 0.000 description 3
- XWIYFDMXXLINPU-UHFFFAOYSA-N Aflatoxin G Chemical compound O=C1OCCC2=C1C(=O)OC1=C2C(OC)=CC2=C1C1C=COC1O2 XWIYFDMXXLINPU-UHFFFAOYSA-N 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 241000228197 Aspergillus flavus Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 235000020232 peanut Nutrition 0.000 description 2
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241000271566 Aves Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000265913 Crataegus laevigata Species 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3409—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
- A23L5/27—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Food Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Fodder In General (AREA)
- Beans For Foods Or Fodder (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- General Preparation And Processing Of Foods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Soy Sauces And Products Related Thereto (AREA)
- Catching Or Destruction (AREA)
Description
Fremgangsmåte til uskadeliggjøring Procedure for neutralization
av giftige stoffvekselprodukter fra of toxic metabolic products from
muggsopp. mold.
Tallrike muggsopper som eksempelvis muggsopp av slekten Aspergillus og Penicillium utvikler meget giftige stoffvekselprodukter, som betegnes .som mykotoksiner. Disse mykotdksiner, hvorav de forskjellige aflatoksiner er de mest kjente,.virker meget giftig overfor varmblodsdyr som fugler og pattedyr. Numerous molds, such as molds of the genera Aspergillus and Penicillium, develop highly toxic metabolic products, which are referred to as mycotoxins. These mycotoxins, of which the various aflatoxins are the best known, are highly toxic to warm-blooded animals such as birds and mammals.
Det er kjent å anvende etylenoksyd, metylformiat eller en blanding av begge gasser til utrydning av muggsopp. Det var imidlertid ikke kjent om hvorledes disse gasser eller gassblandinger innvirker på mykotoksinen. It is known to use ethylene oxide, methyl formate or a mixture of both gases to eradicate mould. However, it was not known how these gases or gas mixtures affect the mycotoxin.
Oppfinnelsens oppgave er en fremgangsmåte til uskadelig-gjøring av disse giftige stoffskifteprodukter. En ytterligere oppgave med oppfinnelsen er å' tilveiebringe en slik fremgangsmåte, hvor- ved også selve muggsoppen utryddes, således at etter behandlingen ifølge oppfinnelsen kan det ikke mere oppstå ytterligere giftige stoffskifteprodukter. The task of the invention is a method for rendering these toxic metabolic products harmless. A further task of the invention is to provide such a method, whereby the mold itself is also eradicated, so that after the treatment according to the invention no further toxic metabolic products can arise.
Denne oppgave løses, ifølge oppfinnelsen ved at man behandler gjenstander, stoffer eller stoffblandingers om inneholder de giftige stoffskifteprodukter av muggsopp med etylenoksyd, med metylformiat eller med blandinger av begge gasser. This task is solved, according to the invention, by treating objects, substances or substance mixtures containing the toxic metabolic products of molds with ethylene oxide, with methyl formate or with mixtures of both gases.
Med meget godt resultat anvendes en gassblanding av A gas mixture of is used with very good results
40 til 60 volum- metylformiat og 40 til 60 volum- etylenoksyd. 40 to 60 volumes of methyl formate and 40 to 60 volumes of ethylene oxide.
Por å nedsette brannfaren er det i mange tilfeller an-bragt til behandlingen å anvende en gassblanding som foruten etylenoksyd og/eller metylformiat inneholder en inert gass, som nitrogen eller karbondioksyd. In order to reduce the risk of fire, in many cases it is appropriate for the treatment to use a gas mixture which, in addition to ethylene oxide and/or methyl formate, contains an inert gas, such as nitrogen or carbon dioxide.
Av sikkerhetsgrunner er det hensiktsmessig å utføre behandlingen under nedsatt trykk.. Ved anvendelse av denne forholds-regel hindres at ved utettheter av behandlingsbeholdere eller behand-lingsrom trer behandlingsgassene utad. For safety reasons, it is appropriate to carry out the treatment under reduced pressure. By applying this precaution, it is prevented that the treatment gases escape in the event of leaks in treatment containers or treatment rooms.
Eksempel' 1. Example' 1.
Jordnøtt-"expeller" som ved angrep med en stamme av Aspergillus flavus pr. g inneholdt 12^ug Aflatoxin B-^ble bragt i Peanut "expeller" which in case of attack with a strain of Aspergillus flavus per g contained 12 µg Aflatoxin B-^ was brought in
et begasningskammer med et innhold av 11 liter. Kamrene ble evakuert til et resttrykk på 40 torr. Det flytende behandlingsmidlet ble forgasset i en varmeutveksler og ført inn i begasningskammeret. a gasification chamber with a content of 11 litres. The chambers were evacuated to a residual pressure of 40 torr. The liquid treatment agent was gasified in a heat exchanger and introduced into the gasification chamber.
Etter avløp av begasningstiden hver gang ble behandlingsmidlet frasugd ved hjelp av en vakuumpumpe og steril friskluft ble innført gjennom et vattfilter i begasningskammeret til trykkutligning. After the gassing time had expired each time, the treatment agent was sucked off using a vacuum pump and sterile fresh air was introduced through a cotton filter into the gassing chamber for pressure equalization.
Til behandling ble det anvendt følgende gasser: The following gases were used for treatment:
A Etylenoksyd A Ethylene oxide
B Metylformiat B Methyl formate
C en blanding av 50 volum- etylenoksyd og C a mixture of 50 volumes of ethylene oxide and
50 volum- metylformiat. 50 volumes of methyl formate.
Forsøksresultatene er oppstillet i følgende tabell: The test results are listed in the following table:
Påvisningen av den kvantitative bestemmelse av Aflatoxin ble gjennomført etter fremgangsmåten av Hanssen og Hagedorn (ZUL l4l (1969) 3, 129-145). The detection of the quantitative determination of Aflatoxin was carried out according to the method of Hanssen and Hagedorn (ZUL 141 (1969) 3, 129-145).
Eksempel 2. Example 2.
Jordnøtter med et sterkt angrep av en stamme av Aspergillus flavus ble behandlet med fremgangsmåten ifølge eksempel 1. Resultatene er oppstillet i følgende tabell: Peanuts with a strong attack of a strain of Aspergillus flavus were treated with the method according to example 1. The results are listed in the following table:
Claims (4)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2414146A DE2414146A1 (en) | 1974-03-23 | 1974-03-23 | PROCEDURE FOR DETERMINING THE TOXIC METABOLIZER PRODUCTS FROM MOLD |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO741303L true NO741303L (en) | 1975-09-24 |
Family
ID=5910997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO741303A NO741303L (en) | 1974-03-23 | 1974-04-08 |
Country Status (23)
| Country | Link |
|---|---|
| JP (1) | JPS5337419B2 (en) |
| AT (1) | AT349875B (en) |
| AU (1) | AU7026974A (en) |
| BE (1) | BE816904A (en) |
| CA (1) | CA1030396A (en) |
| CH (1) | CH568023A5 (en) |
| CS (1) | CS172882B2 (en) |
| CY (1) | CY993A (en) |
| DE (1) | DE2414146A1 (en) |
| DK (1) | DK195074A (en) |
| ES (1) | ES425401A1 (en) |
| FI (1) | FI129574A (en) |
| FR (1) | FR2264483B1 (en) |
| GB (1) | GB1442466A (en) |
| HU (1) | HU167434B (en) |
| IT (1) | IT1011770B (en) |
| NL (1) | NL7406365A (en) |
| NO (1) | NO741303L (en) |
| PL (1) | PL88731B1 (en) |
| SE (1) | SE414266B (en) |
| TR (1) | TR19642A (en) |
| YU (1) | YU103074A (en) |
| ZA (1) | ZA743678B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2557599C3 (en) * | 1975-12-20 | 1979-09-27 | Degesch Gmbh, 6000 Frankfurt | Process for rendering the toxic metabolic products of molds harmless |
| JPS53106623U (en) * | 1977-01-31 | 1978-08-26 |
-
1974
- 1974-03-23 DE DE2414146A patent/DE2414146A1/en active Pending
- 1974-04-05 SE SE7404642A patent/SE414266B/en not_active IP Right Cessation
- 1974-04-08 HU HUDE846A patent/HU167434B/hu unknown
- 1974-04-08 DK DK195074A patent/DK195074A/da unknown
- 1974-04-08 AT AT291174A patent/AT349875B/en not_active IP Right Cessation
- 1974-04-08 NO NO741303A patent/NO741303L/no unknown
- 1974-04-08 CS CS2508A patent/CS172882B2/cs unknown
- 1974-04-11 YU YU01030/74A patent/YU103074A/en unknown
- 1974-04-16 CH CH523974A patent/CH568023A5/xx not_active IP Right Cessation
- 1974-04-17 ES ES425401A patent/ES425401A1/en not_active Expired
- 1974-04-19 PL PL1974170485A patent/PL88731B1/pl unknown
- 1974-04-23 IT IT68290/74A patent/IT1011770B/en active
- 1974-04-24 JP JP4641674A patent/JPS5337419B2/ja not_active Expired
- 1974-04-26 FI FI1295/74A patent/FI129574A/fi unknown
- 1974-05-10 NL NL7406365A patent/NL7406365A/en not_active Application Discontinuation
- 1974-06-10 CY CY993A patent/CY993A/en unknown
- 1974-06-10 GB GB2560974A patent/GB1442466A/en not_active Expired
- 1974-06-10 ZA ZA00743678A patent/ZA743678B/en unknown
- 1974-06-12 CA CA202,293A patent/CA1030396A/en not_active Expired
- 1974-06-20 AU AU70269/74A patent/AU7026974A/en not_active Expired
- 1974-06-21 FR FR7421664A patent/FR2264483B1/fr not_active Expired
- 1974-06-26 BE BE145924A patent/BE816904A/en not_active IP Right Cessation
-
1978
- 1978-06-27 TR TR19642A patent/TR19642A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| TR19642A (en) | 1979-09-19 |
| GB1442466A (en) | 1976-07-14 |
| JPS50125051A (en) | 1975-10-01 |
| YU103074A (en) | 1982-06-30 |
| SE7404642L (en) | 1975-09-24 |
| SE414266B (en) | 1980-07-21 |
| CY993A (en) | 1979-08-02 |
| DK195074A (en) | 1975-09-24 |
| BE816904A (en) | 1974-10-16 |
| ATA291174A (en) | 1978-09-15 |
| DE2414146A1 (en) | 1975-09-25 |
| PL88731B1 (en) | 1976-09-30 |
| AT349875B (en) | 1979-04-25 |
| ES425401A1 (en) | 1976-06-01 |
| ZA743678B (en) | 1975-06-25 |
| JPS5337419B2 (en) | 1978-10-09 |
| FR2264483A1 (en) | 1975-10-17 |
| CS172882B2 (en) | 1977-01-28 |
| FR2264483B1 (en) | 1977-03-11 |
| AU7026974A (en) | 1976-01-08 |
| IT1011770B (en) | 1977-02-10 |
| CA1030396A (en) | 1978-05-02 |
| CH568023A5 (en) | 1975-10-31 |
| NL7406365A (en) | 1975-09-25 |
| FI129574A (en) | 1975-09-24 |
| HU167434B (en) | 1975-10-28 |
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