SE190240C1

SE190240C1 -

Info

Publication number: SE190240C1
Authority: SE; Sweden
Prior art keywords: weight; polymer; acid; water; sucrose
Prior art date: 1964-01-01

Application number

Other languages

English (en)

Swedish (sv)

Publication date

1964-01-01

1964-01-01 Publication of SE190240C1 publication Critical patent/SE190240C1/sv

Links

229920000642 polymer Polymers 0.000 claims description 159
239000000203 mixture Substances 0.000 claims description 156
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 62
239000000178 monomer Substances 0.000 claims description 51
229920000570 polyether Polymers 0.000 claims description 50
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 43
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 43
239000005720 sucrose Substances 0.000 claims description 42
239000002253 acid Substances 0.000 claims description 41
239000004721 Polyphenylene oxide Substances 0.000 claims description 40
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 39
229930006000 Sucrose Natural products 0.000 claims description 36
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 34
239000000853 adhesive Substances 0.000 claims description 31
230000001070 adhesive effect Effects 0.000 claims description 31
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 28
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 27
239000002904 solvent Substances 0.000 claims description 26
238000000034 method Methods 0.000 claims description 24
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 20
230000008569 process Effects 0.000 claims description 20
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 18
229920001897 terpolymer Polymers 0.000 claims description 18
239000004971 Cross linker Substances 0.000 claims description 17
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 16
238000006116 polymerization reaction Methods 0.000 claims description 16
239000000463 material Substances 0.000 claims description 15
150000008064 anhydrides Chemical class 0.000 claims description 14
150000005846 sugar alcohols Polymers 0.000 claims description 14
ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical group C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 12
150000002170 ethers Chemical group 0.000 claims description 12
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 12
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims description 12
229930195733 hydrocarbon Natural products 0.000 claims description 10
150000002430 hydrocarbons Chemical class 0.000 claims description 10
238000002156 mixing Methods 0.000 claims description 10
229920001577 copolymer Polymers 0.000 claims description 9
150000004820 halides Chemical class 0.000 claims description 9
239000007787 solid Substances 0.000 claims description 9
125000001033 ether group Chemical group 0.000 claims description 8
230000000379 polymerizing effect Effects 0.000 claims description 8
239000004215 Carbon black (E152) Substances 0.000 claims description 7
238000003776 cleavage reaction Methods 0.000 claims description 7
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 7
230000007017 scission Effects 0.000 claims description 7
230000002522 swelling effect Effects 0.000 claims description 7
230000002378 acidificating effect Effects 0.000 claims description 6
125000003342 alkenyl group Chemical group 0.000 claims description 6
239000002585 base Substances 0.000 claims description 6
239000003431 cross linking reagent Substances 0.000 claims description 6
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 5
230000000694 effects Effects 0.000 claims description 5
239000007788 liquid Substances 0.000 claims description 5
229920003169 water-soluble polymer Polymers 0.000 claims description 5
125000002877 alkyl aryl group Chemical group 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 4
125000003710 aryl alkyl group Chemical group 0.000 claims description 4
229910052736 halogen Inorganic materials 0.000 claims description 4
150000002367 halogens Chemical group 0.000 claims description 4
239000001257 hydrogen Substances 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
125000002560 nitrile group Chemical group 0.000 claims description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 3
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
150000002431 hydrogen Chemical group 0.000 claims description 3
229920001542 oligosaccharide Polymers 0.000 claims description 3
150000002482 oligosaccharides Chemical class 0.000 claims description 3
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical class ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 3
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 claims description 2
229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
150000001721 carbon Chemical class 0.000 claims 1
238000004132 cross linking Methods 0.000 claims 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 36
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 31
-1 hugs Substances 0.000 description 22
150000003839 salts Chemical class 0.000 description 22
238000002360 preparation method Methods 0.000 description 20
229940086737 allyl sucrose Drugs 0.000 description 19
238000006386 neutralization reaction Methods 0.000 description 19
230000008961 swelling Effects 0.000 description 19
229940052303 ethers for general anesthesia Drugs 0.000 description 18
239000003795 chemical substances by application Substances 0.000 description 17
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 16
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 16
239000006072 paste Substances 0.000 description 16
239000000499 gel Substances 0.000 description 14
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 14
159000000000 sodium salts Chemical class 0.000 description 14
238000006243 chemical reaction Methods 0.000 description 13
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
150000001875 compounds Chemical class 0.000 description 10
239000000126 substance Substances 0.000 description 10
238000000227 grinding Methods 0.000 description 9
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238000010992 reflux Methods 0.000 description 8
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 7
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 7
239000012736 aqueous medium Substances 0.000 description 7
239000003054 catalyst Substances 0.000 description 7
239000000843 powder Substances 0.000 description 7
239000000243 solution Substances 0.000 description 7
239000000600 sorbitol Substances 0.000 description 7
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
241000416162 Astragalus gummifer Species 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
MUPFEKGTMRGPLJ-RMMQSMQOSA-N Raffinose Natural products O(C[C@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O[C@@]2(CO)[C@H](O)[C@@H](O)[C@@H](CO)O2)O1)[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 MUPFEKGTMRGPLJ-RMMQSMQOSA-N 0.000 description 6
229920001615 Tragacanth Polymers 0.000 description 6
MUPFEKGTMRGPLJ-UHFFFAOYSA-N UNPD196149 Natural products OC1C(O)C(CO)OC1(CO)OC1C(O)C(O)C(O)C(COC2C(C(O)C(O)C(CO)O2)O)O1 MUPFEKGTMRGPLJ-UHFFFAOYSA-N 0.000 description 6
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 6
239000000227 bioadhesive Substances 0.000 description 6
150000001735 carboxylic acids Chemical class 0.000 description 6
FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 6
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MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 6
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229960000834 vinyl ether Drugs 0.000 description 6
239000003513 alkali Substances 0.000 description 5
UZKWTJUDCOPSNM-UHFFFAOYSA-N butyl vinyl ether Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 5
238000001035 drying Methods 0.000 description 5
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 5
239000004570 mortar (masonry) Substances 0.000 description 5
235000000346 sugar Nutrition 0.000 description 5
229940034610 toothpaste Drugs 0.000 description 5
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
239000004386 Erythritol Substances 0.000 description 4
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VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
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235000019414 erythritol Nutrition 0.000 description 4
229940009714 erythritol Drugs 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 description 4
239000003292 glue Substances 0.000 description 4
238000011065 in-situ storage Methods 0.000 description 4
229960000367 inositol Drugs 0.000 description 4
239000011976 maleic acid Substances 0.000 description 4
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HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 4
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SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 description 4
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239000002674 ointment Substances 0.000 description 4
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150000008163 sugars Chemical class 0.000 description 4
239000004753 textile Substances 0.000 description 4
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RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 3
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 3
HEBKCHPVOIAQTA-QWWZWVQMSA-N D-arabinitol Chemical compound OC[C@@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-QWWZWVQMSA-N 0.000 description 3
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CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
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WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
150000001720 carbohydrates Chemical group 0.000 description 3
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CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 3
239000004816 latex Substances 0.000 description 3
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239000003960 organic solvent Substances 0.000 description 3
229940059574 pentaerithrityl Drugs 0.000 description 3
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CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
229910001415 sodium ion Inorganic materials 0.000 description 3
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FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
FBPFZTCFMRRESA-ZXXMMSQZSA-N D-iditol Chemical compound OC[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-ZXXMMSQZSA-N 0.000 description 2
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NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
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