SE1550639A1 - Process for Inhibiting Biological Growth On a Gravity Fed Disc Filter - Google Patents

Process for Inhibiting Biological Growth On a Gravity Fed Disc Filter Download PDF

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Publication number
SE1550639A1
SE1550639A1 SE1550639A SE1550639A SE1550639A1 SE 1550639 A1 SE1550639 A1 SE 1550639A1 SE 1550639 A SE1550639 A SE 1550639A SE 1550639 A SE1550639 A SE 1550639A SE 1550639 A1 SE1550639 A1 SE 1550639A1
Authority
SE
Sweden
Prior art keywords
backwash
biocide
filter
filter media
pressurized
Prior art date
Application number
SE1550639A
Other languages
English (en)
Inventor
Herve Buisson
Pille Kängsepp
Rune Strube
Janne Olavi Väänänen
Original Assignee
Veolia Water Solutions & Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Veolia Water Solutions & Tech filed Critical Veolia Water Solutions & Tech
Publication of SE1550639A1 publication Critical patent/SE1550639A1/sv

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D33/00Filters with filtering elements which move during the filtering operation
    • B01D33/44Regenerating the filter material in the filter
    • B01D33/48Regenerating the filter material in the filter by flushing, e.g. counter-current air-bumps
    • B01D33/50Regenerating the filter material in the filter by flushing, e.g. counter-current air-bumps with backwash arms, shoes or nozzles
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D33/00Filters with filtering elements which move during the filtering operation
    • B01D33/15Filters with filtering elements which move during the filtering operation with rotary plane filtering surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D33/00Filters with filtering elements which move during the filtering operation
    • B01D33/15Filters with filtering elements which move during the filtering operation with rotary plane filtering surfaces
    • B01D33/21Filters with filtering elements which move during the filtering operation with rotary plane filtering surfaces with hollow filtering discs transversely mounted on a hollow rotary shaft
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D33/00Filters with filtering elements which move during the filtering operation
    • B01D33/80Accessories
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D33/00Filters with filtering elements which move during the filtering operation
    • B01D33/80Accessories
    • B01D33/804Accessories integrally combined with devices for controlling the filtration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2201/00Details relating to filtering apparatus
    • B01D2201/08Regeneration of the filter
    • B01D2201/081Regeneration of the filter using nozzles or suction devices
    • B01D2201/084Nozzles placed on the filtrate side of the filtering element
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2201/00Details relating to filtering apparatus
    • B01D2201/08Regeneration of the filter
    • B01D2201/085Regeneration of the filter using another chemical than the liquid to be filtered
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2201/00Details relating to filtering apparatus
    • B01D2201/08Regeneration of the filter
    • B01D2201/088Arrangements for killing microorganisms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/005Processes using a programmable logic controller [PLC]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/20Prevention of biofouling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Filtration Of Liquid (AREA)

Description

15 20 25 30 35 Figure 2 is an illustration of one embodiment of the backwash manifold and biocide supply.
Figure 3 is an illustration of another embodiment of the backwash manifold and biocide supply.
Figure 4 is a schematic illustration showing an alternative embodiment where the biocide is sprayed directly onto the filter media of respective disc shaped filter members.
DETAlLED DESCRIPTION The current invention is directed towards methods for inhibiting biological growth on rotary disc filters. Rotary disc filters are well known and widely used to provide water filtration.
As used herein, the term 'water' encompasses all forms of feedwater, to include wastewater.
Rotary disc filters are shown and described in patents and other published materials. For example, reference is made to U.S. Patent No. 7,597,805 and U.S. Patent Publication No. 2008/0035584. The disclosures of these two publications are expressly incorporated herein by reference. A complete and unified understanding of disc filters, their structure, and operation can be gained by reviewing these materials.
A brief overview of the structure and operation of a typical disc filter may be beneficial.
Figure 1 shows a disc filter indicated generally by the numeral 10. Disc filter 10 includes an outer housing 12 or an open frame structure for installation in channels. Rotatively mounted in the housing 12 is a drum. Generally, the drum is enclosed, except that it includes an inlet opening and a series of openings formed in the surface thereof for enabling influent to flow from the drum into a series of rotary filter disc, indicated generally by the numeral 14, mounted on the drum. That is, as will be appreciated from subsequent discussions herein, influent is directed into the drum, and from the drum through openings in the surface thereof into the respective rotary filter discs 14.
The number of rotary filter discs 14 secured on the drum and rotatable therewith can vary. Basically, each rotary filter disc 14 includes a filter frame 16 and filter media 18 secured on opposite sides of each rotary filter disc 14. A holding area is defined inside each rotary filter disc 14 for receiving influent to be filtered by the rotary filter disc 14.
The disc filter 10 is provided with a drive system for rotatively driving the drum and the rotary filter discs 14 mounted thereon. There is provided a drum motor 64 that is operative to drive a sprocket or sheave (not shown) connected to the drum. See Figure 1A. Various means can be operatively interconnected between the drum motor 64 and the sprocket for driving the sprocket, and hence the drum. For example, a belt drive can be utilized. Various other types of drive systems can be utilized to rotate the drum and the rotary filter discs 14 mounted thereon.
Continuing to refer to Figure 1, the disc filter 10 includes an influent inlet 22. lnfluent inlet 22 leads to an influent holding tank 24. lnfluent holding tank 24 is disposed adjacent an inlet opening formed in the drum such that influent held within the influent holding tank 24 can 2 10 15 20 25 30 35 flow from the holding tank into the drum. As seen in the drawings, the influent holding tank is disposed on the upstream side of the disc filter 10. Disposed around and generally below the influent holding tank 24 is a bypass tank 30. An outlet 32 enables influent to flow from the bypass tank 30. Note that the influent holding tank 24 includes overflow openings. These overflow openings permit influent overflow to flow from the influent holding tank 24 downwardly into the bypass tank 30. This effectively limits the water level height in the influent holding tank 24.
Disc filter 10 also includes an effluent holding tank 26. Effluent holding tank 26 is disposed about a downstream end portion of the disc filter 10, and as shown in the drawings, extends around at least a lower portion of the rotary filter discs 14. As the influent moves outwardly through the filter media 18, this results in the water being filtered, and it follows that the filtered water constitutes an effluent. lt is this effluent that is held within the effluent holding tank 26. There is also provided an effluent outlet associated with the effluent holding tank 26 for directing effluent or filtered water from the disc filter 10.
Therefore, it follows that influent water to be treated or filtered is directed into the influent inlet 22 and into the influent holding tank 24 where the water accumulates to a selected height therein so as to provide a head pressure for effectively causing the water to move from the inner portions of the rotary filter discs 14 outwardly through the filter media 18. influent held within the holding tank 24 eventually is directed into the drum, and from the drum through openings therein into the interior areas of the rotary filter discs 14. Now, the water within the rotary filter disc moves outwardly through the filter media 18 into the effluent holding tank 26, and eventually out the effluent outlet.
The present application focuses on methods for preventing biological growth on disc filters. One way to prevent, eliminate, or inhibit biological growth is to utilize a biocide.
Biocides are substances (or in some cases organisms) that kill currently growing biological contaminants and deter growth of new biological contaminants. For example, the biocide chlorine has long been added to swimming pools and spas to both kill bacteria present in the pool water and prevent new bacterial growth therein.
The methods disclosed herein may be used with any biocide that can remove biofilm from filter media. ln preferred embodiments, the biocide is one that does not cause environmental harm. One preferred type of biocide is peroxy acids. One example of a peroxy acid is peracetic acid. Peracetic acid inhibits growth of a broad range of biological contaminants. After treatment, peracetic acid breaks down into hydrogen peroxide and acetic acid, which are non-toxic and environmentally friendly. ln one exemplary embodiment, the concentration of the peracetic acid used is approximately 2-15% by weight. Another example of a peroxy acid (biocide) is performic acid. Performic acid effectively inhibits growth of, inter alia, bacteria, fungi, viruses, and other microorganisms. Because performic acid degrades to carbon dioxide, oxygen, and water, it is an environmentally friendly biocide. 3 10 15 20 25 30 35 The present invention envisions incorporating a biocide application into the backwashing system of a rotary disc filter. One such backwashing system is shown in Figures 1 and 1A. Generally the backwashing system includes a manifold 40 that extends along a side of the disc filter 10 and is operatively connected to a backwash pump 42 that is operative to direct high pressure wash water (usually filtrate produced by the disc filter) through the manifold 40. Extending off the manifold 40 are a series of feed pipes 44 with each feed pipe being connected at its outer end to a nozzle array 46. As seen in the drawings there is a sludge or backwash water outlet 50. Outlet 50 is operatively connected to a trough or a catch structure that extends through the drum and is disposed generally underneath the various nozzle arrays 46. When the backwashing system is in operation, the debris, sludge and wash water fall into the trough or catch structure and through gravity pass from the disc filter 10 through the sludge or backwash water outlet 50. As shown in Figures 2-3, manifold 40 is operatively connected to a backwash pump 62, which in turn is operatively connected to a backwash supply 64. As alluded to above, in many instances the backwash system will utilize the filtered water produced by the disc filter as the backwash. As seen in Figure 2, for example, the dosing pump 68 is operatively connected to the biocide supply 66 which typically includes one or more tanks for supplying the selected biocide such as peracetic acid (performic acid which can be produced on site). Some biocides, for example performic acid (the biocide), can be produced on site and supplied to the dosing pump 68. The dosing pump 68 includes an outlet that is operatively connected to the manifold 40 of the backwash system. As seen in Figure 2, the biocide pumped from the dosing pump 68 can be directed into the manifold 40 either upstream or downstream of the backwash pump 62. lt is believed generally that it is preferable for the biocide to be injected into the manifold 40 downstream of the backwash pump 62. However, in tank versions of the disc filter, it may be possible to inject the biocide on the suction side (i.e., upstream side) of the backwash pump 62. This may have the extra benefit of cleaning the backwash pump 62. ln some embodiments, a controller 70 is used to regulate biocide dosing.
One of skill in the art appreciates that many types of controllers may be utilized, to include timers, PLCs, and computer-based systems (which may include remote and wireless control features). ln one embodiment, shown in Figure 2, controller 70 is a PLC. ln this embodiment, controller 70 may consider one or a combination of factors to control the frequency and amount of doses. Examples of such factors include, but are not limited to, filtrate flow, influent flow, backwash frequency, head level, and head loss (the difference between the height of the influent head and the height of the filtrate level). One of skill in the art is aware of numerous other factors that could also be used. ln one embodiment, shown in Figure 3, controller 70 is a timer. ln this case, the timer is set or programmed to permit dosing of the biocide into the backwash at selected times and for selected time periods. ln this embodiment, backwash pump 62 is configured to communicate with the timer, such that the timer only permits dosing from dosing pump 68 when backwash pump 62 is at the on position. 4 10 15 20 25 30 35 ln one embodiment, the biocide is dosed to the backwash at a concentration of The concentration of the biocide dosed and the frequency of dosing will vary depending upon approximately 10-300 ppm, with dosing occurring approximately 5-100% of the time. conditions and particular application. ln one embodiment, for example, it is believed that in many applications a concentration of approximately 20-80 ppm of biocide with a dosing frequency of 10-20°/0 will be sufficient to control biofouling on the filter media. The term “frequency of dosing” is a term that compares the frequency of applying the biocide relative to the frequency of backwashing. For example, a dosing frequency of 50% means that the biocide is being mixed with the backwash one-half or 50% of the time. ln order to backwash the filter media 18, the drum can be continuously or intermittently rotated such that the filter media or filter panels 18 enter the accumulated effluent in the effluent holding tank 26. lt is appreciated that only a bottom portion of the filter media 18 is effective at any one time to filter the influent. From time-to-time the drum and rotary filter discs 14 will be rotated, and when this occurs, some portions of the filter media 18 will be rotated to an upper portion and in this position the filter media 18 will not be in a position to filter the effluent.
During a backwash cycle, high pressure backwash-biocide solution is sprayed from the nozzle arrays 46 onto the outer surfaces of the filter media 18 to clean them. This can occur when the drum and rotary filter discs 14 are stationary or being rotated. The backwash-biocide solution sprayed on from the nozzle arrays 46 impacts the outer surface of the filter media 18, vibrating the filter media and even penetrating the filter media. This causes debris caught on the inner side of the filter media 18 to be dislodged or removed from the inner surface of the filter media 18. This debris and the backwash water fall into the underlying trough extending through the drum. Thereafter the debris and backwash water are channeled out the outlet 50. lt is appreciated that, while upper portions of the filter media 18 are backwashed, disinfected, and cleaned, the lower submerged portions of the filter media can continue to filter the influent. ln another embodiment, the biocide could be applied to the filter media independently of the backwash system. ln this case, a separate set of nozzles could be utilized to spray the biocide onto the filter media. The biocide could be chemically diluted and applied at a relatively low pressure, for example, 1-2 bar, while the filter discs are rotated relatively slowly. An example of this embodiment is shown in Figure 4. ln the Figure 4 embodiment, the biocide pump 84 is operatively connected to a manifold 80 that includes a plurality of nozzles 82. The nozzles 82 are spaced such that one or more nozzles are directed to each side of each disc- shaped filter member 14. Biocide pump 84 is operatively connected to a biocide supply 66 which could be a biocide tank or a system for producing biocide on site. Biocide pump 84 is controlled by a controller 70 or, as discussed above, a timer or other type of control system. ln this case, from time-to-time, the biocide will be sprayed onto the filter media of the disc filters 14 to control or inhibit biofouling. ln this embodiment, biocide is pumped from the biocide supply to 10 the biocide pump 84 and then directed into the manifold 80. Thereafter, the biocide is sprayed under pressure onto the filter media of the individual disc-shaped filter members.
Although the present methods have been shown and described in considerable detail with respect to only a few/particular exemplary embodiments thereof, it should be understood by those skilled in the art that it is not intended to limit the methods to the embodiments since various modifications, omissions, and additions may be made to the disclosed embodiments without materially departing from the novel teachings and advantages of the methods, particularly in light of the foregoing teachings.
The present invention may, of course, be carried out in other specific ways than those herein set forth without departing from the scope and the essential characteristics of the invention. The present embodiments are therefore to be construed in all aspects as illustrative and not restrictive and all changes coming within the meaning and equivalency range of the appended claims are intended to be embraced therein.

Claims (10)

CLAIMS What is claimed is:
1. A method for treating water with a rotary disc filter having filter media and backwashing the filter media and inhibiting biofouling of the filter media by employing an integrated system for applying a backwash and a biocide to the filter media, comprising: directing the water into a rotatable drum forming a part of the rotary disc filter wherein the rotary disc filter comprising a plurality of disc-shaped filter members mounted on the rotatable drum and where the disc-shaped filter members include the filter media for filtering the water; providing the water with a head pressure and causing the water to flow from the drum into the disc-shaped filter members and out the filter media to produce a filtrate; pumping the backwash from a backwash supply and pressurizing the backwash to form a pressurized backwash and wherein a backwash pump is employed to pump the backwash; directing a biocide from a biocide holding tank associated with the rotary disc filter; dosing the pressurized backwash with the biocide by mixing the biocide with the pressurized backwash to form a pressurized backwash-biocide solution; pumping the pressurized backwash-biocide solution to a series of nozzles disposed adjacent the filter media on the filter discs and spraying the pressurized backwash-biocide solution towards the filter media and impacting the outer surface of the filter media with the pressurized backwash-biocide solution and vibrating the filter media and penetrating the filter media with the pressurized backwash-biocide solution; in response to impacting the outer surface of the filter media with the pressurized backwash-biocide solution, dislodging and removing debris caught on an inner surface of the filter media by causing the dislodged debris to fall into an underlying trough extending inside the drum; and wherein the pressurized backwash-biocide solution backwashes debris from the filter media and inhibits biological growth on the filter media.
2. The method of Claim 1 wherein the rotary disc filter includes a controller associated therewith and wherein the controller receives a series of signals that are representative of one or more of the following process variables: filtrate flow, head level, backwash frequency and on- 7 off state of the backwash pump; and wherein the method includes employing the controller to control the dosing of the biocide into the pressurized backwash based on one or more of said process variables.
3. The method of claim 1 wherein the method includes first and second modes of operation; in the first mode of operation, the method comprising backwashing the filter media by spraying the pressurized backwash onto the filter media; and in the second mode of operation, dosing the pressurized backwash with the biocide to form the pressurized backwash-biocide solution and spraying the pressurized backwash-biocide solution onto the filter media.
4. The method of claim 3 including dosing the pressurized backwash with the paracetic acid or performic acid.
5. The method of claim 1, further including employing a biocide pump to pump the biocide into the pressurized backwash; and controlling the biocide pump with a controller and controlling the amount of the biocide dose into the pressurized backwash and the frequency in which the biocide is dosed into the pressurized backwash.
6. The method of Claim 3 wherein the rotary disc filter includes two sets of nozzles and the method includes, in the first mode of operation, spraying the pressurized backwash onto the filter media through the first set of nozzles; in the second mode of operation, spraying the pressurized backwash-biocide solution onto the filter media through the second set of nozzles.
7. A rotary disc filter for filtering water comprising: a rotary drum for receiving water to be filtered; a drive for rotatively driving the rotary drum; a plurality of disc-shaped filter members secured about the drum and being rotatable with the drum; each disc-shaped filter member including filter media secured on each side thereof; wherein the water directed into the rotary disc filter provides a head pressure that causes the water to flow from the drum into the disc-shaped filter members and out through the filter media to produce a filtrate; an integrated backwash and biocide application system for applying a backwash and a biocide to the filter media of the disc-shaped filter members, the integrated backwash and biocide application system comprising: vii. a backwash pump for pumping the backwash from a backwash source and pressurizing the backwash to form a pressurized backwash; a biocide holding tank associated with the rotary disc filter for holding the biocide; a biocide dosing pump for pumping the biocide from the biocide holding tank into the pressurized backwash and causing the biocide to be mixed with the pressurized backwash to form a pressurized backwash-biocide solution; a series of nozzles disposed adjacent the disc-shaped filter members and the filter media thereon; wherein the backwash pump is configured to pump the pressurized backwash-biocide solution through the nozzles and spray the pressurized backwash-biocide solution onto the filter media causing the pressurized backwash-biocide solution to penetrate and vibrate the filter media; in response to penetrating the outer surface of the filter media with a pressurized backwash-biocide application, debris caught on an inner surface of the filter media is dislodged and caused to fall into an underlying trough within the drum; and a controller operatively connected to the biocide dosing pump for controlling the amount of biocide dosed into the pressurized backwash and the frequency of dosing.
8. The rotary disc filter of claim 7 wherein the controller is configured to receive input signals representative of process variables and wherein the controller controls the biocide dosing pump based on the signals received which are representative of process variables.
9. The rotary disc filter of claim 8 wherein the controller is a programmed logic controller that receives a series of signals that are representative of a combination of the following process variables: filtrate rate, head level, backwash frequency and on/off state of the backwash pump.
10. The rotary disc filter of claim 7 wherein the rotary disc filter is configured to operate in first and second modes of operation, and wherein in the first mode of operation, the rotary disc filter is operative to spray the pressurized backwash onto the filter media disposed on the disc- shaped filter members; and in the second mode of operation, the rotary disc filter is configured to spray the pressurized backwash-biocide solution onto the filter media on the disc-shaped filter members. 10
SE1550639A 2012-11-07 2013-11-06 Process for Inhibiting Biological Growth On a Gravity Fed Disc Filter SE1550639A1 (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/671,068 US20140124461A1 (en) 2012-11-07 2012-11-07 Process for Inhibiting Biological Growth On a Gravity Fed Disc Filter
PCT/US2013/068642 WO2014074547A2 (en) 2012-11-07 2013-11-06 Process for inhibiting biological growth on a gravity fed disc filter

Publications (1)

Publication Number Publication Date
SE1550639A1 true SE1550639A1 (sv) 2015-05-20

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SE1550639A SE1550639A1 (sv) 2012-11-07 2013-11-06 Process for Inhibiting Biological Growth On a Gravity Fed Disc Filter

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Country Link
US (1) US20140124461A1 (sv)
EP (1) EP2917154A2 (sv)
JP (1) JP2016501715A (sv)
KR (1) KR20150068485A (sv)
CN (1) CN104884391A (sv)
AR (1) AR093351A1 (sv)
CA (1) CA2889610A1 (sv)
GB (1) GB2522154A (sv)
RU (1) RU2015121619A (sv)
SE (1) SE1550639A1 (sv)
WO (1) WO2014074547A2 (sv)

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EP2917154A2 (en) 2015-09-16
AR093351A1 (es) 2015-06-03
US20140124461A1 (en) 2014-05-08
GB201508396D0 (en) 2015-07-01
KR20150068485A (ko) 2015-06-19
CN104884391A (zh) 2015-09-02
WO2014074547A3 (en) 2014-07-24
GB2522154A (en) 2015-07-15
CA2889610A1 (en) 2014-05-15
RU2015121619A (ru) 2016-12-27
JP2016501715A (ja) 2016-01-21

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