SA98190939B1 - المادة المحفزة للتكسير المائي hyderocracking catalyst لانتاج المواد المقطرة distillates الوسيطة وكذلك عملية تحضيرها - Google Patents
المادة المحفزة للتكسير المائي hyderocracking catalyst لانتاج المواد المقطرة distillates الوسيطة وكذلك عملية تحضيرها Download PDFInfo
- Publication number
- SA98190939B1 SA98190939B1 SA98190939A SA98190939A SA98190939B1 SA 98190939 B1 SA98190939 B1 SA 98190939B1 SA 98190939 A SA98190939 A SA 98190939A SA 98190939 A SA98190939 A SA 98190939A SA 98190939 B1 SA98190939 B1 SA 98190939B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- ranging
- catalyst
- alumina
- carrier
- surface area
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 76
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 230000008569 process Effects 0.000 title claims description 7
- 238000002360 preparation method Methods 0.000 title description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 13
- 238000001035 drying Methods 0.000 claims abstract description 10
- 238000004898 kneading Methods 0.000 claims abstract description 6
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims description 25
- 239000002184 metal Substances 0.000 claims description 24
- 239000011148 porous material Substances 0.000 claims description 17
- 239000011959 amorphous silica alumina Substances 0.000 claims description 13
- 150000002739 metals Chemical class 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 10
- 239000012876 carrier material Substances 0.000 claims description 10
- 238000007334 copolymerization reaction Methods 0.000 claims description 8
- 230000000737 periodic effect Effects 0.000 claims description 8
- 238000000975 co-precipitation Methods 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000002054 inoculum Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 5
- 229910052759 nickel Inorganic materials 0.000 abstract description 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 description 18
- 239000000463 material Substances 0.000 description 14
- 239000002253 acid Substances 0.000 description 9
- 238000010335 hydrothermal treatment Methods 0.000 description 9
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 238000002791 soaking Methods 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- KBIWNQVZKHSHTI-UHFFFAOYSA-N 4-n,4-n-dimethylbenzene-1,4-diamine;oxalic acid Chemical compound OC(=O)C(O)=O.CN(C)C1=CC=C(N)C=C1 KBIWNQVZKHSHTI-UHFFFAOYSA-N 0.000 description 1
- 241001136792 Alle Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 241001580017 Jana Species 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-L Oxalate Chemical compound [O-]C(=O)C([O-])=O MUBZPKHOEPUJKR-UHFFFAOYSA-L 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 102000051759 human factor J Human genes 0.000 description 1
- 108700008420 human factor J Proteins 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- -1 large molecule hydrocarbons Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- AFTOAIRATFQPGK-UHFFFAOYSA-N pentaazanium 2-hydroxypropane-1,2,3-tricarboxylate oxalate Chemical compound C(C(=O)[O-])(=O)[O-].C(CC(O)(C(=O)[O-])CC(=O)[O-])(=O)[O-].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+] AFTOAIRATFQPGK-UHFFFAOYSA-N 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97122139 CN1055960C (zh) | 1997-11-24 | 1997-11-24 | 一种中油型加氢裂化催化剂及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SA98190939B1 true SA98190939B1 (ar) | 2006-11-04 |
Family
ID=5176700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SA98190939A SA98190939B1 (ar) | 1997-11-24 | 1998-12-27 | المادة المحفزة للتكسير المائي hyderocracking catalyst لانتاج المواد المقطرة distillates الوسيطة وكذلك عملية تحضيرها |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN1055960C (zh) |
| SA (1) | SA98190939B1 (zh) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1098917C (zh) * | 2000-01-04 | 2003-01-15 | 中国石油化工集团公司 | 一种中油型加氢裂化催化剂及其制备方法 |
| CN1098916C (zh) * | 2000-01-04 | 2003-01-15 | 中国石油化工集团公司 | 一种中油型加氢裂化催化剂及其制备方法 |
| CN100377780C (zh) * | 2004-11-30 | 2008-04-02 | 中国石油化工股份有限公司 | 一种烃类重整催化剂及制备方法 |
| CN104588072B (zh) * | 2013-11-03 | 2017-02-15 | 中国石油化工股份有限公司 | 一种制备加氢裂化催化剂的方法 |
| CN105013498B (zh) * | 2014-02-20 | 2017-08-22 | 中国石油化工股份有限公司 | 一种加氢处理催化剂及其应用 |
| CN109622028A (zh) * | 2018-12-31 | 2019-04-16 | 中海油天津化工研究设计院有限公司 | 一种高稳定性催化裂化柴油加氢裂化催化剂及其制备方法 |
-
1997
- 1997-11-24 CN CN 97122139 patent/CN1055960C/zh not_active Expired - Lifetime
-
1998
- 1998-12-27 SA SA98190939A patent/SA98190939B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1218090A (zh) | 1999-06-02 |
| CN1055960C (zh) | 2000-08-30 |
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