SA518391947B1 - أنظمة محفز تكوين أوليجومرات مضادة للاتساخ - Google Patents
أنظمة محفز تكوين أوليجومرات مضادة للاتساخ Download PDFInfo
- Publication number
- SA518391947B1 SA518391947B1 SA518391947A SA518391947A SA518391947B1 SA 518391947 B1 SA518391947 B1 SA 518391947B1 SA 518391947 A SA518391947 A SA 518391947A SA 518391947 A SA518391947 A SA 518391947A SA 518391947 B1 SA518391947 B1 SA 518391947B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- titanate
- catalyst system
- antifouling
- compound
- aluminum
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 75
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 70
- 238000006384 oligomerization reaction Methods 0.000 title description 13
- 239000002519 antifouling agent Substances 0.000 claims abstract description 68
- -1 titanate compound Chemical class 0.000 claims abstract description 40
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 32
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 29
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 24
- 125000003636 chemical group Chemical group 0.000 claims abstract description 17
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 33
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 27
- 239000005977 Ethylene Substances 0.000 claims description 27
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 25
- 229920000642 polymer Polymers 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 9
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical group CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000539 dimer Substances 0.000 claims description 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000413 hydrolysate Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 4
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 claims description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 2
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 claims description 2
- 239000013638 trimer Substances 0.000 claims 3
- VCUXVXLUOHDHKK-UHFFFAOYSA-N 2-(2-aminopyrimidin-4-yl)-4-(2-chloro-4-methoxyphenyl)-1,3-thiazole-5-carboxamide Chemical compound ClC1=CC(OC)=CC=C1C1=C(C(N)=O)SC(C=2N=C(N)N=CC=2)=N1 VCUXVXLUOHDHKK-UHFFFAOYSA-N 0.000 claims 1
- 241000511343 Chondrostoma nasus Species 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- 229940125898 compound 5 Drugs 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 239000011800 void material Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 description 35
- 238000006243 chemical reaction Methods 0.000 description 15
- 125000004429 atom Chemical group 0.000 description 10
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 7
- 238000006471 dimerization reaction Methods 0.000 description 6
- 125000004430 oxygen atom Chemical group O* 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 108010067035 Pancrelipase Proteins 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- IFKWVQNWZSUEIA-UHFFFAOYSA-N but-1-ene;hex-1-ene Chemical compound CCC=C.CCCCC=C IFKWVQNWZSUEIA-UHFFFAOYSA-N 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229940092125 creon Drugs 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- DEVSOMFAQLZNKR-RJRFIUFISA-N (z)-3-[3-[3,5-bis(trifluoromethyl)phenyl]-1,2,4-triazol-1-yl]-n'-pyrazin-2-ylprop-2-enehydrazide Chemical compound FC(F)(F)C1=CC(C(F)(F)F)=CC(C2=NN(\C=C/C(=O)NNC=3N=CC=NC=3)C=N2)=C1 DEVSOMFAQLZNKR-RJRFIUFISA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- BHXSRLKYVPSYMQ-UHFFFAOYSA-N C=CC=C.C=CC=C Chemical compound C=CC=C.C=CC=C BHXSRLKYVPSYMQ-UHFFFAOYSA-N 0.000 description 1
- 241001433320 Dimeria Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000000427 antigen Substances 0.000 description 1
- 108091007433 antigens Proteins 0.000 description 1
- 102000036639 antigens Human genes 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229960002685 biotin Drugs 0.000 description 1
- 239000011616 biotin Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- YICCTZQUAAGDTO-UHFFFAOYSA-N but-1-ene Chemical compound CCC=C.CCC=C YICCTZQUAAGDTO-UHFFFAOYSA-N 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000020335 dealkylation Effects 0.000 description 1
- 238000006900 dealkylation reaction Methods 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 230000000447 dimerizing effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- WHRNULOCNSKMGB-UHFFFAOYSA-N tetrahydrofuran thf Chemical compound C1CCOC1.C1CCOC1 WHRNULOCNSKMGB-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/128—Mixtures of organometallic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0204—Ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/123—Organometallic polymers, e.g. comprising C-Si bonds in the main chain or in subunits grafted to the main chain
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00654—Controlling the process by measures relating to the particulate material
- B01J2208/00707—Fouling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/068—Polyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662275932P | 2016-01-07 | 2016-01-07 | |
| PCT/US2017/012299 WO2017120310A1 (en) | 2016-01-07 | 2017-01-05 | Antifouling oligomerization catalyst systems |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SA518391947B1 true SA518391947B1 (ar) | 2022-11-13 |
Family
ID=57985015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SA518391947A SA518391947B1 (ar) | 2016-01-07 | 2018-07-02 | أنظمة محفز تكوين أوليجومرات مضادة للاتساخ |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US11104621B2 (OSRAM) |
| EP (1) | EP3400102A1 (OSRAM) |
| JP (1) | JP6921088B2 (OSRAM) |
| KR (1) | KR102698053B1 (OSRAM) |
| CN (1) | CN108602058A (OSRAM) |
| RU (1) | RU2731387C2 (OSRAM) |
| SA (1) | SA518391947B1 (OSRAM) |
| SG (1) | SG11201805653UA (OSRAM) |
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Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102545317B1 (ko) | 2015-06-19 | 2023-06-21 | 사우디 아라비안 오일 컴퍼니 | 방오성 올리고머화 촉매 시스템 |
| US11104621B2 (en) | 2016-01-07 | 2021-08-31 | Saudi Arabian Oil Company | Antifouling oligomerization catalyst systems |
| US10280125B2 (en) | 2016-12-07 | 2019-05-07 | Sumitomo Chemical Company, Limited | Process for selective ethylene oligomerization with antifouling components |
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| US10889533B2 (en) | 2017-09-22 | 2021-01-12 | Saudi Arabian Oil Company | Inline process to make antifouling agent co-catalyst for ethylene oligomerization |
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| US11098140B2 (en) | 2020-01-03 | 2021-08-24 | Saudi Arabian Oil Company | Production of 1-butene and ultra-high-molecular-weight polyethylene |
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| US11440980B2 (en) | 2020-07-22 | 2022-09-13 | Saudi Arabian Oil Company | Methods for forming ultra high molecular weight polyethylenes and methods for reducing contaminant content in such |
| WO2022115748A1 (en) | 2020-11-30 | 2022-06-02 | Saudi Arabian Oil Company | Catalyst systems |
| WO2022115751A1 (en) * | 2020-11-30 | 2022-06-02 | Saudi Arabian Oil Company | Catalyst systems |
| WO2022115749A1 (en) * | 2020-11-30 | 2022-06-02 | Saudi Arabian Oil Company | Catalyst systems |
| WO2022115750A1 (en) | 2020-11-30 | 2022-06-02 | Saudi Arabian Oil Company | Catalyst systems |
| US11458463B2 (en) * | 2020-11-30 | 2022-10-04 | Saudi Arabian Oil Company | Catalyst systems |
| CN116917040A (zh) | 2021-03-12 | 2023-10-20 | 沙特阿拉伯石油公司 | 催化剂体系 |
| WO2023027749A1 (en) | 2021-08-26 | 2023-03-02 | Saudi Arabian Oil Company | Catalyst systems |
| US11639321B1 (en) | 2022-08-31 | 2023-05-02 | Saudi Arabian Oil Company | Catalyst systems that include meta-alkoxy substituted n-aryl bis-diphosphinoamine ligands |
| US11623901B1 (en) | 2022-08-31 | 2023-04-11 | Saudi Arabian Oil Company | Catalyst systems that include silyl ether moieties |
| US12240791B1 (en) * | 2023-08-21 | 2025-03-04 | Saudi Arabian Oil Company | Process for selective ethylene oligomerization with antifouling components |
| EP4616945A1 (en) | 2024-03-15 | 2025-09-17 | Hindustan Petroleum Corporation Limited | A catalyst composition for reduction of polymer formation in etthylene dimerization |
Family Cites Families (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2738151A (en) | 1951-10-04 | 1956-03-13 | Carpenter And Paterson Inc | Pipe-supporting expansion rocker |
| BE562871A (OSRAM) * | 1956-12-04 | |||
| GB1312974A (en) | 1969-05-29 | 1973-04-11 | Toyo Soda Mfg Co Ltd | Process and catalyst for dimerization of alpha-olefins |
| US4242531A (en) | 1978-08-14 | 1980-12-30 | Phillips Petroleum Company | Olefin dimerization |
| JPS59219258A (ja) | 1983-05-28 | 1984-12-10 | Ajinomoto Co Inc | α−Ｌ−アスパルチル−Ｌ−フエニルアラニンメチルエステル又はその塩酸塩の製法 |
| US4484016A (en) | 1983-07-05 | 1984-11-20 | The Dow Chemical Company | Process for making a mixture of ethylene and butene-1 |
| US4487847A (en) | 1983-07-25 | 1984-12-11 | Phillips Petroleum Company | Ethylene dimerization |
| EP0135441B1 (fr) | 1983-09-20 | 1986-11-05 | Institut Français du Pétrole | Procédé amélioré de synthèse du butène-1 par dimérisation de l'éthylène |
| US4538018A (en) | 1983-12-13 | 1985-08-27 | Phillips Petroleum Company | Surface conditioning in olefin dimerization reactors |
| FR2573432B1 (fr) * | 1984-11-20 | 1987-02-13 | Inst Francais Du Petrole | Procede ameliore de fabrication d'un copolymere ethylene/butene-1 par polymerisation de l'ethylene |
| EP0221206B1 (en) | 1985-09-27 | 1990-11-28 | Indian Petrochemicals Corporation Ltd. | Process for making butene-1 from ethylene |
| SU1662996A1 (ru) * | 1987-07-13 | 1991-07-15 | Отделение Института химической физики АН СССР | Способ получени бутена-1 |
| IT1226550B (it) | 1988-07-29 | 1991-01-24 | Enichem Anic Spa | Processo di oligomerizzazione selettiva di olefine e nuovo catalizzatore per tale processo. |
| DE4126093A1 (de) | 1991-08-07 | 1993-02-11 | Hoechst Ag | Verfahren zur herstellung von ethylen(co)polymeren |
| US5811618A (en) | 1991-10-16 | 1998-09-22 | Amoco Corporation | Ethylene trimerization |
| US5376706A (en) | 1992-11-17 | 1994-12-27 | E. I. Du Pont De Nemours And Company | Anhydride epoxy coating composition modified with a silane polymer |
| JP2889075B2 (ja) | 1993-03-23 | 1999-05-10 | 帝人化成株式会社 | 合成樹脂粒体に同伴する微粉体の除去装置及び貯留基地 |
| FI101479B (fi) * | 1994-12-22 | 1998-06-30 | Borealis Polymers Oy | Menetelmä likaantumisen estämiseksi polymerointireaktoreissa |
| FR2733497B1 (fr) | 1995-04-28 | 1997-06-06 | Inst Francais Du Petrole | Procede de production de butene-1 par dimerisation de l'ethylene comportant une zone de recuperation amelioree de catalyseur use |
| US5856612A (en) | 1996-02-02 | 1999-01-05 | Mitsubishi Chemical Corporation | Process for producing α-olefin oligomer |
| FR2748019B1 (fr) | 1996-04-26 | 1998-06-26 | Inst Francais Du Petrole | Procede ameliore de conversion de l'ethylene en butene-1 avec utlisation d'additifs a base de sels d'ammonium quaternaire |
| FR2748020B1 (fr) * | 1996-04-26 | 1998-06-26 | Inst Francais Du Petrole | Procede ameliore de conversion de l'ethylene en butene-1 avec utilisation d'additifs a base de polyethyleneglycols et de leurs derives |
| US6184428B1 (en) | 1998-04-22 | 2001-02-06 | Saudi Basic Industries Corporation | Catalyst and process for ethylene oligomerization |
| JP3670163B2 (ja) * | 1999-05-24 | 2005-07-13 | 三井化学株式会社 | オレフィンのスラリー重合方法 |
| FR2804622B1 (fr) | 2000-02-04 | 2002-04-05 | Inst Francais Du Petrole | Composition catalytique pour la dimerisation, la codimerisation et l'oligomerisation des olefines |
| US6757975B1 (en) | 2001-01-25 | 2004-07-06 | Brigham Young University | Multi-layered compliant mechanisms and method of manufacture |
| DE10122111B4 (de) | 2001-05-08 | 2007-03-01 | Ticona Gmbh | Verfahren zur Herstellung von Olefinpolymeren, sowie ausgewählte Katalysatoren |
| JP4266827B2 (ja) | 2001-12-20 | 2009-05-20 | サソル テクノロジー （ピーティーワイ）リミテッド | クロムを主成分とした触媒を使用したオレフィン類の三量化およびオリゴマー化 |
| US6767975B1 (en) | 2003-07-14 | 2004-07-27 | Equistar Chemicals, Lp | Olefin polymerization with pyridine moiety-containing singe-site catalysts |
| EP1564229A1 (en) * | 2004-02-13 | 2005-08-17 | Total Petrochemicals Research Feluy | Olefin polymerization process in the presence of an anti-fouling agent |
| EP1574525B1 (en) * | 2004-03-12 | 2007-05-02 | Saudi Basic Industries Corporation | Catalyst composition for polymerization of olefins and polymerization process using the same |
| US20050261440A1 (en) | 2004-05-20 | 2005-11-24 | Dickakian Ghazi B | Dispersant material for mitigating crude oil fouling of process equipment and method for using same |
| US7964763B2 (en) | 2004-06-18 | 2011-06-21 | Sasol Technology (Pty) Limited | Oligomerisation of olefinic compounds in an aliphatic medium |
| EP1731535A1 (en) | 2005-06-07 | 2006-12-13 | Saudi Basic Industries Corporation Inc. | Process for polymerization of olefins |
| EP1888653B1 (en) | 2005-06-07 | 2016-01-13 | Saudi Basic Industries Corporation | Process for the polymerization of olefins |
| US20070027276A1 (en) | 2005-07-27 | 2007-02-01 | Cann Kevin J | Blow molding polyethylene resins |
| US20070049711A1 (en) * | 2005-09-01 | 2007-03-01 | Chi-I Kuo | Catalyst compositions comprising support materials having an improved particle-size distribution |
| US7122497B1 (en) * | 2005-09-07 | 2006-10-17 | Equistar Chemicals, Lp | Olefin polymerization catalyst system |
| US7638597B2 (en) | 2007-12-17 | 2009-12-29 | Equistar Chemicals, Lp | Removal of metal contaminants from polyethylene |
| ATE510619T1 (de) | 2008-04-04 | 2011-06-15 | Saudi Basic Ind Corp | Katalysator für die oligomerisierung von ethylen, methode zu seiner darstellung und oligomerisationsprozess in seiner gegenwart |
| JP5463886B2 (ja) * | 2008-12-24 | 2014-04-09 | 住友化学株式会社 | オレフィン重合用固体触媒成分前駆体の製造方法 |
| US8227653B2 (en) | 2009-03-27 | 2012-07-24 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization reaction processes exhibiting reduced fouling |
| ES2603052T3 (es) | 2010-07-30 | 2017-02-23 | Total Research & Technology Feluy | Procedimiento de preparación de poliolefinas y uso de agentes antiensuciamiento en el mismo |
| CN102807632B (zh) | 2011-06-03 | 2014-04-02 | 中国石油化工股份有限公司 | 一种用于乙烯聚合反应的催化剂组分及其催化剂 |
| WO2013154446A1 (ru) | 2012-04-09 | 2013-10-17 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук | Каталитическая система и способ получения реакторного порошка сверхвысокомолекулярного полиэтилена |
| WO2013166369A1 (en) | 2012-05-03 | 2013-11-07 | David Bradin | Production of polypropylene from renewable resource |
| JP5996099B2 (ja) | 2012-05-11 | 2016-09-21 | サウジ アラビアン オイル カンパニー | エチレンのオリゴマー化プロセス |
| CN103665201B (zh) | 2012-09-07 | 2016-12-21 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其制备方法和催化体系 |
| FR2995893B1 (fr) | 2012-09-21 | 2014-09-05 | Axens | Procede de production de butadiene-1,3 mettant en oeuvre la dimerisation de l'ethylene et la deshydrogenation des butenes obtenus |
| EP2738151B8 (en) | 2012-11-28 | 2014-12-17 | Saudi Basic Industries Corporation | Process for oligomerization of ethylene |
| CN103124149B (zh) | 2013-01-30 | 2014-12-17 | 东南大学 | 空间调相环形行波超声波电机结构误差补偿控制方法 |
| US20140250835A1 (en) | 2013-03-05 | 2014-09-11 | Howmedica Osteonics Corp. | Process for removing contaminants from polymeric powders |
| US9919298B2 (en) | 2013-12-13 | 2018-03-20 | Saudi Basic Industries Corporation | Catalyst compositions for selective dimerization of ethylene |
| EP3102326B1 (en) | 2014-02-06 | 2019-12-18 | Sabic Global Technologies B.V. | Modifying organoaluminum co-catalysts for improved performance |
| RU2561921C1 (ru) | 2014-07-23 | 2015-09-10 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Способ получения реакторных порошков сверхвысокомолекулярного полиэтилена полимеризацией этилена |
| ES2838599T3 (es) | 2014-09-02 | 2021-07-02 | Univation Tech Llc | Producción de poliolefina con catalizadores basados en cromo |
| KR102545317B1 (ko) | 2015-06-19 | 2023-06-21 | 사우디 아라비안 오일 컴퍼니 | 방오성 올리고머화 촉매 시스템 |
| US11104621B2 (en) | 2016-01-07 | 2021-08-31 | Saudi Arabian Oil Company | Antifouling oligomerization catalyst systems |
| CN107778388B (zh) | 2016-08-29 | 2019-12-27 | 中国石油化工股份有限公司 | 超高分子量聚乙烯连续水洗装置和方法 |
| US10280125B2 (en) | 2016-12-07 | 2019-05-07 | Sumitomo Chemical Company, Limited | Process for selective ethylene oligomerization with antifouling components |
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2016
- 2016-12-29 US US15/393,865 patent/US11104621B2/en active Active
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- 2017-01-05 EP EP17703820.5A patent/EP3400102A1/en active Pending
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| CN108602058A (zh) | 2018-09-28 |
| JP6921088B2 (ja) | 2021-08-18 |
| US20210347712A1 (en) | 2021-11-11 |
| EP3400102A1 (en) | 2018-11-14 |
| US11104621B2 (en) | 2021-08-31 |
| SG11201805653UA (en) | 2018-07-30 |
| US20210355049A1 (en) | 2021-11-18 |
| RU2018128919A3 (OSRAM) | 2020-02-27 |
| US11840493B2 (en) | 2023-12-12 |
| JP2019508227A (ja) | 2019-03-28 |
| KR102698053B1 (ko) | 2024-08-26 |
| KR20180100193A (ko) | 2018-09-07 |
| RU2018128919A (ru) | 2020-02-10 |
| US20170197892A1 (en) | 2017-07-13 |
| US12331004B2 (en) | 2025-06-17 |
| WO2017120310A1 (en) | 2017-07-13 |
| RU2731387C2 (ru) | 2020-09-02 |
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