SA516370514B1 - طريقة لإنتاج بوليولات بولي إثير كربونات - Google Patents
طريقة لإنتاج بوليولات بولي إثير كربوناتInfo
- Publication number
- SA516370514B1 SA516370514B1 SA516370514A SA516370514A SA516370514B1 SA 516370514 B1 SA516370514 B1 SA 516370514B1 SA 516370514 A SA516370514 A SA 516370514A SA 516370514 A SA516370514 A SA 516370514A SA 516370514 B1 SA516370514 B1 SA 516370514B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- polyether carbonate
- carbonate polyols
- phosphorus
- producing polyether
- compound
- Prior art date
Links
- 239000004721 Polyphenylene oxide Substances 0.000 title abstract 4
- -1 carbonate polyols Chemical class 0.000 title abstract 4
- 229920000570 polyether Polymers 0.000 title abstract 4
- 229920005862 polyol Polymers 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/02—Aliphatic polycarbonates
- C08G64/0208—Aliphatic polycarbonates saturated
- C08G64/0225—Aliphatic polycarbonates saturated containing atoms other than carbon, hydrogen or oxygen
- C08G64/0258—Aliphatic polycarbonates saturated containing atoms other than carbon, hydrogen or oxygen containing phosphorus
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/42—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
- C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/30—General preparatory processes using carbonates
- C08G64/305—General preparatory processes using carbonates and alcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/329—Phosphorus containing acids
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyethers (AREA)
Abstract
يتعلق الاختراع بطريقة لإنتاج بوليولات بولي إثير كربونات polyether carbonate polyols، (1) يضاف واحد أو أكثر من أكسيد (أكاسيد) ألكيلين alkylene oxide(s) وثاني أكسيد الكربون إلى واحدة أو أكثر من مادة (مواد) بادئة وظيفية-H في وجود حفاز سيانيد فلز مزدوج double metal cyanide catalyst أو في وجود حفاز معقد فلز يعتمد على الفلزات زنك و/أو كوبالت، خليط تفاعل يحتوي على بوليول بولي إثير كربونات polyether carbonate polyol الناتج، يتميز بأن (2) يضاف مكون K واحد على الأقل إلى خليط التفاعل الناتج الذي يحتوي على بوليول بولي إثير كربونات polyether carbonate polyol، حيث ينتقى مكون K من مركب واحد على الأقل يحتوي على رابطة فوسفور- أكسجين phosphorus-oxygen أو مركب من الفوسفور phosphorus قادر على تشكيل واحد أو أكثر من روابط P-O بواسطة التفاعل مع مركبات وظيفية-OH.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13179165 | 2013-08-02 | ||
EP14175611 | 2014-07-03 |
Publications (1)
Publication Number | Publication Date |
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SA516370514B1 true SA516370514B1 (ar) | 2017-12-12 |
Family
ID=51224950
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SA516370514A SA516370514B1 (ar) | 2013-08-02 | 2016-02-01 | طريقة لإنتاج بوليولات بولي إثير كربونات |
Country Status (10)
Country | Link |
---|---|
US (2) | US9815965B2 (ar) |
EP (1) | EP3027673B1 (ar) |
JP (1) | JP2016525619A (ar) |
KR (1) | KR102230969B1 (ar) |
CN (1) | CN105637013B (ar) |
ES (1) | ES2758076T3 (ar) |
RU (1) | RU2668974C2 (ar) |
SA (1) | SA516370514B1 (ar) |
SG (1) | SG11201600626YA (ar) |
WO (1) | WO2015014732A1 (ar) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
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EP2865700A1 (de) * | 2013-10-23 | 2015-04-29 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
EP3050907A1 (de) * | 2015-01-28 | 2016-08-03 | Covestro Deutschland AG | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
US20180127536A1 (en) * | 2015-04-29 | 2018-05-10 | Covestro Deutschland Ag | Mixtures of polyether carbonate polyols and polyether polyols for producing polyurethane soft foams |
GB201515350D0 (en) * | 2015-08-28 | 2015-10-14 | Econic Technologies Ltd | Method for preparing polyols |
CN108602933B (zh) * | 2015-12-09 | 2021-10-22 | 科思创德国股份有限公司 | 基于聚醚碳酸酯多元醇的聚氨酯泡沫材料 |
EP3260483A1 (de) * | 2016-06-22 | 2017-12-27 | Covestro Deutschland AG | Verfahren zur herstellung von polyethercarbonatpolyolen |
EP3385295A1 (de) * | 2017-04-05 | 2018-10-10 | Covestro Deutschland AG | Flammgeschützte phosphorfunktionelle polyethercarbonatpolyole und verfahren zu deren herstellung |
EP3424967A1 (de) * | 2017-07-07 | 2019-01-09 | Covestro Deutschland AG | Verfahren zur herstellung von funktionalisierten polyoxyalkylenpolyolen |
WO2019076862A1 (de) * | 2017-10-18 | 2019-04-25 | Covestro Deutschland Ag | Diblockcopolymere und deren verwendung als tenside |
US20190119444A1 (en) * | 2017-10-25 | 2019-04-25 | Covestro Llc | Process to remove dmc catalysts from polyether carbonate polyols |
EP3567067A1 (de) * | 2018-05-08 | 2019-11-13 | Covestro Deutschland AG | Abtrennung von doppelmetallcyanid-katalysator |
EP3895791B1 (en) * | 2018-12-19 | 2024-05-15 | Lg Chem, Ltd. | Method for separating organic zinc catalyst using filtration membrane |
EP3683251A1 (de) * | 2019-01-15 | 2020-07-22 | Covestro Deutschland AG | Verfahren zur herstellung von diol |
EP3917988B1 (en) | 2019-01-31 | 2024-07-31 | Dow Global Technologies LLC | Purification process for polyether-carbonate polyols |
WO2020249433A1 (de) | 2019-06-11 | 2020-12-17 | Covestro Deutschland Ag | Verfahren zur herstellung von polyethercarbonatpolyolen |
EP3750940A1 (de) | 2019-06-11 | 2020-12-16 | Covestro Deutschland AG | Verfahren zur herstellung von polyethercarbonatpolyolen |
EP3763426A1 (de) * | 2019-07-12 | 2021-01-13 | Covestro Deutschland AG | Destillation von polyisocyanaten |
WO2021018753A1 (de) * | 2019-07-31 | 2021-02-04 | Covestro Deutschland Ag | Verfahren zur herstellung von polyethercarbonatpolyolen |
EP3771724A1 (de) * | 2019-07-31 | 2021-02-03 | Covestro Deutschland AG | Verfahren zur herstellung von polyethercarbonatpolyolen |
WO2021032554A1 (de) | 2019-08-19 | 2021-02-25 | Covestro Deutschland Ag | Verfahren zur herstellung von polyethercarbonatalkoholen |
EP3783045A1 (de) | 2019-08-19 | 2021-02-24 | Covestro Deutschland AG | Verfahren zur herstellung von polyethercarbonatpolyolen |
KR102624002B1 (ko) * | 2019-09-30 | 2024-01-12 | 주식회사 엘지화학 | 폴리알킬렌 카보네이트 중합 용액으로부터 유기 아연 촉매를 분리하는 방법 |
CN111138623B (zh) * | 2020-01-10 | 2021-02-19 | 浙江大学 | 一种有机硅改性聚醚-聚碳酸酯水性聚氨酯及其制备方法 |
EP3916055A1 (de) | 2020-05-26 | 2021-12-01 | Covestro Deutschland AG | Polycarbonat-zusammensetzungen enthaltend polyethercarbonatpolyole |
CN115403759B (zh) * | 2022-11-02 | 2023-02-28 | 山东一诺威聚氨酯股份有限公司 | 无卤阻燃聚醚酯多元醇及其制备方法和应用 |
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2014
- 2014-07-25 ES ES14742532T patent/ES2758076T3/es active Active
- 2014-07-25 WO PCT/EP2014/065992 patent/WO2015014732A1/de active Application Filing
- 2014-07-25 JP JP2016530451A patent/JP2016525619A/ja active Pending
- 2014-07-25 KR KR1020167005001A patent/KR102230969B1/ko active IP Right Grant
- 2014-07-25 SG SG11201600626YA patent/SG11201600626YA/en unknown
- 2014-07-25 US US14/908,600 patent/US9815965B2/en active Active
- 2014-07-25 EP EP14742532.6A patent/EP3027673B1/de active Active
- 2014-07-25 CN CN201480054582.XA patent/CN105637013B/zh active Active
- 2014-07-25 RU RU2016107402A patent/RU2668974C2/ru not_active IP Right Cessation
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2016
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2017
- 2017-10-02 US US15/722,047 patent/US10662314B2/en active Active
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US20160208080A1 (en) | 2016-07-21 |
CN105637013A (zh) | 2016-06-01 |
US9815965B2 (en) | 2017-11-14 |
WO2015014732A1 (de) | 2015-02-05 |
SG11201600626YA (en) | 2016-03-30 |
EP3027673B1 (de) | 2019-10-02 |
RU2016107402A3 (ar) | 2018-05-08 |
KR102230969B1 (ko) | 2021-03-23 |
KR20160040240A (ko) | 2016-04-12 |
US10662314B2 (en) | 2020-05-26 |
CN105637013B (zh) | 2019-07-30 |
US20180079890A1 (en) | 2018-03-22 |
RU2668974C2 (ru) | 2018-10-05 |
ES2758076T3 (es) | 2020-05-04 |
RU2016107402A (ru) | 2017-09-07 |
EP3027673A1 (de) | 2016-06-08 |
JP2016525619A (ja) | 2016-08-25 |
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