RU2712660C2 - Антибактериальные композиции водных чернил, содержащие композитные иономерные смолы, содержащие ион металла - Google Patents
Антибактериальные композиции водных чернил, содержащие композитные иономерные смолы, содержащие ион металла Download PDFInfo
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- RU2712660C2 RU2712660C2 RU2016125892A RU2016125892A RU2712660C2 RU 2712660 C2 RU2712660 C2 RU 2712660C2 RU 2016125892 A RU2016125892 A RU 2016125892A RU 2016125892 A RU2016125892 A RU 2016125892A RU 2712660 C2 RU2712660 C2 RU 2712660C2
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- Prior art keywords
- poly
- styrene
- acrylate
- silver
- methacrylate
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- 239000002131 composite material Substances 0.000 title claims abstract description 128
- 239000011347 resin Substances 0.000 title claims abstract description 65
- 229920005989 resin Polymers 0.000 title claims abstract description 65
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 48
- 229910021645 metal ion Inorganic materials 0.000 title claims abstract description 37
- 239000000203 mixture Substances 0.000 title claims description 137
- 229920000554 ionomer Polymers 0.000 title claims description 36
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 133
- 229910052751 metal Inorganic materials 0.000 claims abstract description 93
- 239000002184 metal Substances 0.000 claims abstract description 93
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000002105 nanoparticle Substances 0.000 claims abstract description 59
- 238000000034 method Methods 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000758 substrate Substances 0.000 claims abstract description 34
- 238000007639 printing Methods 0.000 claims abstract description 31
- 239000006184 cosolvent Substances 0.000 claims abstract description 23
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010949 copper Substances 0.000 claims abstract description 17
- 229910052802 copper Inorganic materials 0.000 claims abstract description 17
- 239000000126 substance Substances 0.000 claims abstract description 17
- 239000002952 polymeric resin Substances 0.000 claims abstract description 16
- 230000000843 anti-fungal effect Effects 0.000 claims abstract description 12
- 230000003115 biocidal effect Effects 0.000 claims abstract description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 11
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 11
- 239000002174 Styrene-butadiene Substances 0.000 claims abstract description 10
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011115 styrene butadiene Substances 0.000 claims abstract description 10
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 10
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 10
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 230000000840 anti-viral effect Effects 0.000 claims abstract description 8
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 7
- 239000010941 cobalt Substances 0.000 claims abstract description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940121375 antifungal agent Drugs 0.000 claims abstract description 5
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- 239000000178 monomer Substances 0.000 claims description 110
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- -1 poly (alkyl methacrylate-acrylic acid Chemical compound 0.000 claims description 91
- 239000004332 silver Substances 0.000 claims description 91
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- SJNNZXIPFSRUJB-UHFFFAOYSA-N 4-[2-[2-[2-(4-formylphenoxy)ethoxy]ethoxy]ethoxy]benzaldehyde Chemical compound C1=CC(C=O)=CC=C1OCCOCCOCCOC1=CC=C(C=O)C=C1 SJNNZXIPFSRUJB-UHFFFAOYSA-N 0.000 claims description 56
- 229920000642 polymer Polymers 0.000 claims description 52
- 239000004094 surface-active agent Substances 0.000 claims description 29
- 238000004040 coloring Methods 0.000 claims description 25
- PQCHENNROHVIHO-UHFFFAOYSA-M silver;2-methylprop-2-enoate Chemical compound [Ag+].CC(=C)C([O-])=O PQCHENNROHVIHO-UHFFFAOYSA-M 0.000 claims description 23
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- 125000000217 alkyl group Chemical group 0.000 claims description 8
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
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- 150000002843 nonmetals Chemical class 0.000 claims description 6
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- HOIWWOKSBHULCU-UHFFFAOYSA-N butyl prop-2-enoate;2-methylbuta-1,3-diene Chemical compound CC(=C)C=C.CCCCOC(=O)C=C HOIWWOKSBHULCU-UHFFFAOYSA-N 0.000 claims description 5
- IYCOKCJDXXJIIM-UHFFFAOYSA-N butyl prop-2-enoate;prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1.CCCCOC(=O)C=C IYCOKCJDXXJIIM-UHFFFAOYSA-N 0.000 claims description 5
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- NRDDLSFHZLETFD-UHFFFAOYSA-N 2-methylbuta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound CC(=C)C=C.COC(=O)C(C)=C NRDDLSFHZLETFD-UHFFFAOYSA-N 0.000 claims description 4
- HNJKLOSHGNUTBM-UHFFFAOYSA-N 2-methylbuta-1,3-diene;methyl prop-2-enoate Chemical compound CC(=C)C=C.COC(=O)C=C HNJKLOSHGNUTBM-UHFFFAOYSA-N 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- VMMVQEIZBCZSNG-UHFFFAOYSA-N buta-1,3-diene prop-1-enylbenzene Chemical compound C=CC=C.CC=CC1=CC=CC=C1 VMMVQEIZBCZSNG-UHFFFAOYSA-N 0.000 claims description 4
- WOYXYXOSUAZDIA-UHFFFAOYSA-N buta-1,3-diene;butyl 2-methylprop-2-enoate Chemical compound C=CC=C.CCCCOC(=O)C(C)=C WOYXYXOSUAZDIA-UHFFFAOYSA-N 0.000 claims description 4
- YIEXROAWVNRRMJ-UHFFFAOYSA-N buta-1,3-diene;butyl prop-2-enoate Chemical compound C=CC=C.CCCCOC(=O)C=C YIEXROAWVNRRMJ-UHFFFAOYSA-N 0.000 claims description 4
- UWWYTVDAXIVRAJ-UHFFFAOYSA-N buta-1,3-diene;ethyl 2-methylprop-2-enoate Chemical compound C=CC=C.CCOC(=O)C(C)=C UWWYTVDAXIVRAJ-UHFFFAOYSA-N 0.000 claims description 4
- UCPLVEOTDDIMJD-UHFFFAOYSA-N buta-1,3-diene;ethyl prop-2-enoate Chemical compound C=CC=C.CCOC(=O)C=C UCPLVEOTDDIMJD-UHFFFAOYSA-N 0.000 claims description 4
- KLIYQWXIWMRMGR-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound C=CC=C.COC(=O)C(C)=C KLIYQWXIWMRMGR-UHFFFAOYSA-N 0.000 claims description 4
- LRTQWXGNPCHTFW-UHFFFAOYSA-N buta-1,3-diene;methyl prop-2-enoate Chemical compound C=CC=C.COC(=O)C=C LRTQWXGNPCHTFW-UHFFFAOYSA-N 0.000 claims description 4
- XPRLOFXIQNKWMK-UHFFFAOYSA-N buta-1,3-diene;propyl prop-2-enoate Chemical compound C=CC=C.CCCOC(=O)C=C XPRLOFXIQNKWMK-UHFFFAOYSA-N 0.000 claims description 4
- QQIMXPLXJVRMNX-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;2-methylbuta-1,3-diene Chemical compound CC(=C)C=C.CCCCOC(=O)C(C)=C QQIMXPLXJVRMNX-UHFFFAOYSA-N 0.000 claims description 4
- WWPXOMXUMORZKI-UHFFFAOYSA-N butyl prop-2-enoate;prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1.CCCCOC(=O)C=C WWPXOMXUMORZKI-UHFFFAOYSA-N 0.000 claims description 4
- 125000004386 diacrylate group Chemical group 0.000 claims description 4
- RXQXUXZUWNFWJV-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate;2-methylbuta-1,3-diene Chemical compound CC(=C)C=C.CCOC(=O)C(C)=C RXQXUXZUWNFWJV-UHFFFAOYSA-N 0.000 claims description 4
- OIMDJNFWDDTLOZ-UHFFFAOYSA-N propyl prop-2-enoate;styrene Chemical compound CCCOC(=O)C=C.C=CC1=CC=CC=C1 OIMDJNFWDDTLOZ-UHFFFAOYSA-N 0.000 claims description 4
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- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 claims description 3
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| DE102017006544A1 (de) | 2017-07-11 | 2019-01-17 | Daimler Ag | Verfahren zum Herstellen einer antimikrobiellen Oberfläche sowie Bauteil mit einer solche Oberfläche |
| WO2019027417A1 (en) | 2017-07-31 | 2019-02-07 | Hewlett-Packard Development Company, L.P. | OBJECTS HAVING HEARTS COMPRISING BINDERS OF METAL NANOPARTICLES |
| US10696471B2 (en) | 2017-10-31 | 2020-06-30 | Medline Industries, Inc. | Enclosure for gloves with antimicrobial ink coating and methods for making the same |
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Also Published As
| Publication number | Publication date |
|---|---|
| MX388189B (es) | 2025-03-19 |
| CA2936411A1 (en) | 2017-01-23 |
| US10570290B2 (en) | 2020-02-25 |
| US20170022370A1 (en) | 2017-01-26 |
| US20180037750A1 (en) | 2018-02-08 |
| CA2936411C (en) | 2019-07-09 |
| JP2017025303A (ja) | 2017-02-02 |
| JP6698448B2 (ja) | 2020-05-27 |
| US9840626B2 (en) | 2017-12-12 |
| KR102404063B1 (ko) | 2022-05-31 |
| DE102016213201B4 (de) | 2023-08-31 |
| KR20170012023A (ko) | 2017-02-02 |
| MX2016008892A (es) | 2017-01-23 |
| DE102016213201A1 (de) | 2017-01-26 |
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