RU2691149C2 - Способ покрытия металлических поверхностей, основания, покрытые таким способом, и их применение - Google Patents
Способ покрытия металлических поверхностей, основания, покрытые таким способом, и их применение Download PDFInfo
- Publication number
- RU2691149C2 RU2691149C2 RU2016134227A RU2016134227A RU2691149C2 RU 2691149 C2 RU2691149 C2 RU 2691149C2 RU 2016134227 A RU2016134227 A RU 2016134227A RU 2016134227 A RU2016134227 A RU 2016134227A RU 2691149 C2 RU2691149 C2 RU 2691149C2
- Authority
- RU
- Russia
- Prior art keywords
- ions
- calculated
- coating
- content
- aqueous composition
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 72
- 238000000034 method Methods 0.000 title claims abstract description 57
- 239000011248 coating agent Substances 0.000 title claims abstract description 50
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 41
- 239000002184 metal Substances 0.000 title claims abstract description 41
- 239000000203 mixture Substances 0.000 claims abstract description 82
- 150000002500 ions Chemical class 0.000 claims abstract description 50
- 230000002378 acidificating effect Effects 0.000 claims abstract description 38
- 238000006243 chemical reaction Methods 0.000 claims abstract description 37
- 238000007739 conversion coating Methods 0.000 claims abstract description 30
- 239000000126 substance Substances 0.000 claims abstract description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 10
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011574 phosphorus Substances 0.000 claims abstract description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 10
- 229910019142 PO4 Inorganic materials 0.000 claims description 29
- 235000021317 phosphate Nutrition 0.000 claims description 29
- -1 sulfonate anions Chemical class 0.000 claims description 29
- 238000005406 washing Methods 0.000 claims description 29
- 229920001577 copolymer Polymers 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 229920000620 organic polymer Polymers 0.000 claims description 23
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 22
- 239000002966 varnish Substances 0.000 claims description 21
- 239000010452 phosphate Substances 0.000 claims description 20
- 239000004094 surface-active agent Substances 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 19
- 150000001450 anions Chemical class 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 17
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 15
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 15
- 230000015572 biosynthetic process Effects 0.000 claims description 15
- 229910000077 silane Inorganic materials 0.000 claims description 15
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 14
- 150000001768 cations Chemical class 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 9
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 9
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 6
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
- 229910001385 heavy metal Inorganic materials 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 238000004458 analytical method Methods 0.000 claims description 5
- 150000007942 carboxylates Chemical class 0.000 claims description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 5
- 238000009434 installation Methods 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- 239000002987 primer (paints) Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 238000004876 x-ray fluorescence Methods 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229910001416 lithium ion Inorganic materials 0.000 claims description 3
- 229910001415 sodium ion Inorganic materials 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 2
- 238000010790 dilution Methods 0.000 claims description 2
- 239000012895 dilution Substances 0.000 claims description 2
- 238000011089 mechanical engineering Methods 0.000 claims description 2
- 229910001414 potassium ion Inorganic materials 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 7
- 229910015667 MoO4 Inorganic materials 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 46
- 239000010410 layer Substances 0.000 description 42
- 239000011701 zinc Substances 0.000 description 29
- 239000011572 manganese Substances 0.000 description 22
- 229910052725 zinc Inorganic materials 0.000 description 21
- 239000002585 base Substances 0.000 description 20
- 238000005260 corrosion Methods 0.000 description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 18
- 238000007792 addition Methods 0.000 description 18
- 230000007797 corrosion Effects 0.000 description 18
- 239000000243 solution Substances 0.000 description 15
- 229910000831 Steel Inorganic materials 0.000 description 14
- 239000010959 steel Substances 0.000 description 14
- 229910052742 iron Inorganic materials 0.000 description 12
- 229910052748 manganese Inorganic materials 0.000 description 11
- 239000004922 lacquer Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 7
- 239000010960 cold rolled steel Substances 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 238000005530 etching Methods 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 238000005275 alloying Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 229910001335 Galvanized steel Inorganic materials 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 239000008397 galvanized steel Substances 0.000 description 2
- 229910000398 iron phosphate Inorganic materials 0.000 description 2
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 238000001420 photoelectron spectroscopy Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- DXIGZHYPWYIZLM-UHFFFAOYSA-J tetrafluorozirconium;dihydrofluoride Chemical compound F.F.F[Zr](F)(F)F DXIGZHYPWYIZLM-UHFFFAOYSA-J 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 150000003682 vanadium compounds Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/361—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing titanium, zirconium or hafnium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/364—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/44—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102014201209 | 2014-01-23 | ||
| DE102014201209.0 | 2014-01-23 | ||
| PCT/EP2015/051272 WO2015110541A1 (de) | 2014-01-23 | 2015-01-22 | Verfahren zur beschichtung von metallischen oberflächen, derart beschichtete substrate und ihre verwendung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2016134227A RU2016134227A (ru) | 2018-03-01 |
| RU2016134227A3 RU2016134227A3 (es) | 2018-11-08 |
| RU2691149C2 true RU2691149C2 (ru) | 2019-06-11 |
Family
ID=52462284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2016134227A RU2691149C2 (ru) | 2014-01-23 | 2015-01-22 | Способ покрытия металлических поверхностей, основания, покрытые таким способом, и их применение |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20170009351A1 (es) |
| EP (1) | EP3097221B1 (es) |
| JP (1) | JP6622206B2 (es) |
| KR (1) | KR102416141B1 (es) |
| CN (1) | CN106574372B (es) |
| AU (1) | AU2015208176B2 (es) |
| BR (1) | BR112016017018B1 (es) |
| CA (1) | CA2938414A1 (es) |
| DE (1) | DE102015201090A1 (es) |
| ES (1) | ES2921449T3 (es) |
| HU (1) | HUE059458T2 (es) |
| PL (1) | PL3097221T3 (es) |
| RU (1) | RU2691149C2 (es) |
| WO (1) | WO2015110541A1 (es) |
| ZA (1) | ZA201605375B (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11078573B2 (en) * | 2016-01-19 | 2021-08-03 | Thyssenkrupp Ag | Method for producing a steel product with a Zn coating and a tribologically active layer deposited on the coating, and a steel product produced according to said method |
| EP3659716A1 (en) * | 2018-11-27 | 2020-06-03 | Rhodia Operations | Polymers for metal surface treatment |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2125118C1 (ru) * | 1992-04-01 | 1999-01-20 | Хенкель Корпорейшн | Способ получения композиции и способ обработки ею металла, его вариант |
| US6361622B1 (en) * | 1997-08-21 | 2002-03-26 | Henkel Corporation | Process for coating and/or touching up coatings on metal surfaces |
| US20030215653A1 (en) * | 2002-05-17 | 2003-11-20 | Jianping Liu | Non-chromate conversion coating compositions, process for conversion coating metals, and articles so coated |
| DE102005059314A1 (de) * | 2005-12-09 | 2007-06-14 | Henkel Kgaa | Verfahren und Produkt zur Korrosionsschutzbehandlung von Metalloberflächen, insbesondere von Stahloberflächen |
| EP2151481A1 (de) * | 2008-08-01 | 2010-02-10 | Chemische Werke Kluthe GmbH | Wässrige Lösung und Verfahren zur Beschichtung von metallischen Oberflächen sowie Verwendung von modifizierter Kieselsäure bzw. Konzentratzusammensetzung zur Bereitstellung einer wässrigen Beschichtungslösung |
| EP2537674A1 (en) * | 2010-02-15 | 2012-12-26 | Nihon Parkerizing Co., Ltd. | Aluminum or aluminum alloy material having surface treatment coating film, and surface treatment method therefor |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1333043C (en) * | 1988-02-15 | 1994-11-15 | Nippon Paint Co., Ltd. | Surface treatment chemical and bath for aluminium and its alloy |
| CN1214097C (zh) * | 2000-05-31 | 2005-08-10 | 坎梅陶尔股份有限公司 | 处理或预处理容器的方法 |
| US6488990B1 (en) * | 2000-10-06 | 2002-12-03 | Chemetall Gmbh | Process for providing coatings on a metallic surface |
| MY117334A (en) * | 2000-11-10 | 2004-06-30 | Nisshin Steel Co Ltd | Chemically processed steel sheet improved in corrosion resistance |
| US9175170B2 (en) * | 2003-02-25 | 2015-11-03 | Chemetall Gmbh | Method for coating metallic surfaces with a composition that is rich in polymers |
| DE10308237B4 (de) * | 2003-02-25 | 2014-01-16 | Chemetall Gmbh | Verfahren zur Beschichtung von metallischen Oberflächen, zugehörige Zusammensetzung und ihre Verwendung |
| DE10349728A1 (de) * | 2003-10-23 | 2005-05-25 | Basf Ag | Im wesentlichen Chrom-freies Verfahren zum Passivieren von metallischen Oberflächen aus Zn, Zn-Legierungen, AI oder AI-Legierungen |
| JP4402991B2 (ja) * | 2004-03-18 | 2010-01-20 | 日本パーカライジング株式会社 | 金属表面処理用組成物、金属表面処理用処理液、金属表面処理方法および金属材料 |
| US8101014B2 (en) * | 2004-11-10 | 2012-01-24 | Chemetall Gmbh | Process for coating metallic surfaces with a multicomponent aqueous composition |
| US20060099332A1 (en) * | 2004-11-10 | 2006-05-11 | Mats Eriksson | Process for producing a repair coating on a coated metallic surface |
| TR201906343T4 (tr) * | 2004-11-10 | 2019-05-21 | Chemetall Gmbh | Metalik yüzeylerin sulu bir silan/silanol/siloksan/polisiloksan bazlı bileşim ile kaplanmasına yönelik yöntem. |
| US20080138615A1 (en) * | 2005-04-04 | 2008-06-12 | Thomas Kolberg | Method for Coating Metallic Surfaces with an Aqueous Composition and Said Composition |
| JP2007162098A (ja) * | 2005-12-15 | 2007-06-28 | Nippon Parkerizing Co Ltd | 水系金属表面処理剤、表面処理方法及び表面処理金属材料 |
| US20070264511A1 (en) * | 2006-05-09 | 2007-11-15 | Roberto Ponzellini | Method and composition for forming a coloured coating on a metallic surface |
| ES2391870T3 (es) * | 2007-02-12 | 2012-11-30 | Henkel Ag & Co. Kgaa | Procedimiento para tratar superficies metálicas |
| CN101701336B (zh) * | 2009-11-26 | 2011-04-13 | 芜湖市瑞杰环保材料科技有限公司 | 一种环保的金属表面处理剂及其使用方法 |
| CN101717931A (zh) * | 2009-12-22 | 2010-06-02 | 上海大学 | 一种用于铜表面钝化的稀土离子复配钝化剂及其制备方法 |
| ES2428290T3 (es) * | 2011-03-22 | 2013-11-06 | Henkel Ag & Co. Kgaa | Tratamiento anticorrosivo de varios pasos para componentes metálicos, que por lo menos parcialmente presentan superficies de cinc o de aleaciones de cinc |
| ES2556967T3 (es) * | 2011-10-24 | 2016-01-21 | Chemetall Gmbh | Procedimiento para el recubrimiento de superficies metálicas con una composición acuosa de múltiples componentes |
| EP2964806B1 (en) * | 2013-03-06 | 2020-08-05 | PPG Industries Ohio, Inc. | Methods for treating a ferrous metal substrate |
-
2015
- 2015-01-22 WO PCT/EP2015/051272 patent/WO2015110541A1/de active Application Filing
- 2015-01-22 PL PL15703001.6T patent/PL3097221T3/pl unknown
- 2015-01-22 KR KR1020167022936A patent/KR102416141B1/ko active IP Right Grant
- 2015-01-22 EP EP15703001.6A patent/EP3097221B1/de active Active
- 2015-01-22 HU HUE15703001A patent/HUE059458T2/hu unknown
- 2015-01-22 CN CN201580015618.8A patent/CN106574372B/zh active Active
- 2015-01-22 CA CA2938414A patent/CA2938414A1/en not_active Abandoned
- 2015-01-22 US US15/113,489 patent/US20170009351A1/en not_active Abandoned
- 2015-01-22 DE DE102015201090.2A patent/DE102015201090A1/de not_active Withdrawn
- 2015-01-22 RU RU2016134227A patent/RU2691149C2/ru active
- 2015-01-22 BR BR112016017018-0A patent/BR112016017018B1/pt active IP Right Grant
- 2015-01-22 JP JP2016548170A patent/JP6622206B2/ja active Active
- 2015-01-22 AU AU2015208176A patent/AU2015208176B2/en active Active
- 2015-01-22 ES ES15703001T patent/ES2921449T3/es active Active
-
2016
- 2016-08-04 ZA ZA2016/05375A patent/ZA201605375B/en unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2125118C1 (ru) * | 1992-04-01 | 1999-01-20 | Хенкель Корпорейшн | Способ получения композиции и способ обработки ею металла, его вариант |
| US6361622B1 (en) * | 1997-08-21 | 2002-03-26 | Henkel Corporation | Process for coating and/or touching up coatings on metal surfaces |
| US20030215653A1 (en) * | 2002-05-17 | 2003-11-20 | Jianping Liu | Non-chromate conversion coating compositions, process for conversion coating metals, and articles so coated |
| DE102005059314A1 (de) * | 2005-12-09 | 2007-06-14 | Henkel Kgaa | Verfahren und Produkt zur Korrosionsschutzbehandlung von Metalloberflächen, insbesondere von Stahloberflächen |
| EP2151481A1 (de) * | 2008-08-01 | 2010-02-10 | Chemische Werke Kluthe GmbH | Wässrige Lösung und Verfahren zur Beschichtung von metallischen Oberflächen sowie Verwendung von modifizierter Kieselsäure bzw. Konzentratzusammensetzung zur Bereitstellung einer wässrigen Beschichtungslösung |
| EP2537674A1 (en) * | 2010-02-15 | 2012-12-26 | Nihon Parkerizing Co., Ltd. | Aluminum or aluminum alloy material having surface treatment coating film, and surface treatment method therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| US20170009351A1 (en) | 2017-01-12 |
| KR102416141B1 (ko) | 2022-07-04 |
| EP3097221A1 (de) | 2016-11-30 |
| KR20160111989A (ko) | 2016-09-27 |
| WO2015110541A1 (de) | 2015-07-30 |
| ZA201605375B (en) | 2017-11-29 |
| AU2015208176B2 (en) | 2018-11-08 |
| ES2921449T3 (es) | 2022-08-25 |
| BR112016017018B1 (pt) | 2022-09-06 |
| PL3097221T3 (pl) | 2022-08-29 |
| DE102015201090A1 (de) | 2015-07-23 |
| JP6622206B2 (ja) | 2019-12-18 |
| CN106574372B (zh) | 2020-11-24 |
| JP2017506291A (ja) | 2017-03-02 |
| AU2015208176A1 (en) | 2016-08-25 |
| RU2016134227A (ru) | 2018-03-01 |
| CN106574372A (zh) | 2017-04-19 |
| CA2938414A1 (en) | 2015-07-30 |
| RU2016134227A3 (es) | 2018-11-08 |
| HUE059458T2 (hu) | 2022-11-28 |
| BR112016017018A2 (es) | 2017-08-08 |
| EP3097221B1 (de) | 2022-05-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101098983B (zh) | 以水性组合物涂布金属表面的方法 | |
| CA2864467C (en) | Pretreating zinc surfaces prior to a passivating process | |
| KR20100028542A (ko) | 아연 표면의 사전 금속화 처리 | |
| WO1995005496A1 (en) | Composition and method for treatment of phosphated metal surfaces | |
| KR20180053306A (ko) | 지르코늄- 및 몰리브데넘-함유 조성물로의 알루미늄 표면의 전처리 | |
| KR20190021341A (ko) | 강철, 아연도금된 강철, 알루미늄, 마그네슘 및/또는 아연-마그네슘 합금을 함유하는 금속 표면의 부식방지 예비처리를 위한 개선된 방법 | |
| US8597482B2 (en) | Process for depositing rinsable silsesquioxane films on metals | |
| US20220364240A1 (en) | Bismuth compositions for metal pretreatment applications | |
| CA2663659A1 (en) | Non-chrome thin organic-inorganic hybrid coating on zinciferous metals | |
| KR102490922B1 (ko) | 강철, 아연도금된 강철, 알루미늄, 알루미늄 합금, 마그네슘 및/또는 아연-마그네슘 합금을 함유하는 금속 표면의 부식-방지 예비처리를 위한 개선된 방법 | |
| RU2691149C2 (ru) | Способ покрытия металлических поверхностей, основания, покрытые таким способом, и их применение | |
| WO2018031981A1 (en) | Two-step pretreatment system and method | |
| KR102301323B1 (ko) | 아연-함유 금속 표면 상에서 핀홀을 방지하기 위해 금속성 표면을 코팅하는 방법 | |
| Lampman | Chemical Conversion Coatings | |
| KR20200081415A (ko) | 3가 크롬 화합물을 이용한 금속 표면을 처리하기 위한 공정 및 조성물 |