RU2640759C2 - Мелкокристаллический zsm-5, его синтез и применение - Google Patents
Мелкокристаллический zsm-5, его синтез и применение Download PDFInfo
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- RU2640759C2 RU2640759C2 RU2015129627A RU2015129627A RU2640759C2 RU 2640759 C2 RU2640759 C2 RU 2640759C2 RU 2015129627 A RU2015129627 A RU 2015129627A RU 2015129627 A RU2015129627 A RU 2015129627A RU 2640759 C2 RU2640759 C2 RU 2640759C2
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- molecular sieve
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- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
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- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
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- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
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- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
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- C07C5/52—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor with a hydrocarbon as an acceptor, e.g. hydrocarbon disproportionation, i.e. 2CnHp -> CnHp+q + CnHp-q
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- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
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- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
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- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
- C07C2529/44—Noble metals
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- C07C2529/46—Iron group metals or copper
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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- C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- Geology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Analytical Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
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Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261740908P | 2012-12-21 | 2012-12-21 | |
| US61/740,908 | 2012-12-21 | ||
| EP13155722 | 2013-02-19 | ||
| EP13155722.5 | 2013-02-19 | ||
| PCT/US2013/071456 WO2014099262A1 (en) | 2012-12-21 | 2013-11-22 | Small crystal zsm-5, its synthesis and use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015129627A RU2015129627A (ru) | 2017-02-02 |
| RU2640759C2 true RU2640759C2 (ru) | 2018-01-11 |
Family
ID=47739133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015129627A RU2640759C2 (ru) | 2012-12-21 | 2013-11-22 | Мелкокристаллический zsm-5, его синтез и применение |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US10081552B2 (enExample) |
| EP (3) | EP3266747A1 (enExample) |
| JP (1) | JP6238377B2 (enExample) |
| KR (1) | KR102166191B1 (enExample) |
| CN (2) | CN107697928B (enExample) |
| CA (1) | CA2895232C (enExample) |
| RU (1) | RU2640759C2 (enExample) |
| SG (2) | SG10201705927UA (enExample) |
| WO (1) | WO2014099262A1 (enExample) |
| ZA (1) | ZA201503617B (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3266747A1 (en) * | 2012-12-21 | 2018-01-10 | ExxonMobil Chemical Patents Inc. | Small crystal zsm-5 and use |
| US10118165B2 (en) | 2015-02-04 | 2018-11-06 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and use in heavy aromatics conversion processes |
| US10053403B2 (en) | 2015-02-04 | 2018-08-21 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes |
| WO2016129659A1 (ja) * | 2015-02-13 | 2016-08-18 | 東ソー株式会社 | ペンタシル型ゼオライト及びその製造方法 |
| US9851313B2 (en) * | 2015-03-03 | 2017-12-26 | Panalytical B.V. | Quantitative X-ray analysis—ratio correction |
| EP3416915B1 (en) * | 2016-02-19 | 2025-01-01 | ExxonMobil Technology and Engineering Company | Synthesis of small crystal, high surface area emm-30 zeolites |
| WO2018132228A1 (en) * | 2017-01-11 | 2018-07-19 | Chevron U.S.A. Inc. | Synthesis of mfi framework type molecular sieves |
| US11033886B2 (en) | 2019-02-27 | 2021-06-15 | Chevron U.S.A. Inc. | Molecular sieve SSZ-115, its synthesis and use |
| CA3146853A1 (en) | 2019-08-20 | 2021-02-25 | Exxonmobil Research And Engineering Company | Metal-organic framework catalysts and their use in catalytic cracking |
| US10737946B1 (en) * | 2019-08-29 | 2020-08-11 | Chevron U.S.A. Inc. | Synthesis of aluminum-containing molecular sieves of SEW framework type |
| JP2022163831A (ja) * | 2021-04-15 | 2022-10-27 | 東ソー株式会社 | Mfi型ゼオライト |
| EP4406646B1 (en) | 2023-01-27 | 2025-10-01 | Hindustan Petroleum Corporation Limited | Nano size crystal zsm-5 and its preparation and applications thereof |
| WO2025058925A1 (en) | 2023-09-12 | 2025-03-20 | ExxonMobil Technology and Engineering Company | Zeolitic materials in polyolefin decomposition via pyrolysis |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5240892A (en) * | 1987-09-02 | 1993-08-31 | Mobil Oil Corporation | Small crystal ZSM-5, as a catalyst |
| RU2143397C1 (ru) * | 1995-06-06 | 1999-12-27 | Мобил Ойл Корпорейшн | Способ синтезирования пористого кристаллического материала, имеющего структуру zsm-5 |
| US7244409B2 (en) * | 1999-10-27 | 2007-07-17 | Sud-Chemie Ag | Process for producing synthetic zeolites with MFI structure |
| RU2312063C1 (ru) * | 2006-04-12 | 2007-12-10 | Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") | Синтетический пористый кристаллический материал и способ его получения |
| RU2313486C1 (ru) * | 2006-04-12 | 2007-12-27 | Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") | Синтетический цеолит и способ его получения |
| RU2313488C1 (ru) * | 2006-04-24 | 2007-12-27 | Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") | Синтетический цеолит и способ его получения |
| US7361328B2 (en) * | 2002-12-30 | 2008-04-22 | Sk Corporation | Method of preparing ZSM-5 using variable temperature without organic template |
| WO2010087633A2 (ko) * | 2009-02-02 | 2010-08-05 | 한국과학기술원 | 싸이클릭다이암모늄을 이용한 메조기공 및 마크로기공을 추가적으로 포함하는 bea, mtw, mfi 구조의 제올라이트의 제조과정 |
| US20120027673A1 (en) * | 2010-07-30 | 2012-02-02 | University Of Iowa Research Foundation | Synthesis of hierarchical nanocrystalline zeolites with controlled particle size and mesoporosity |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| US3941871A (en) | 1973-11-02 | 1976-03-02 | Mobil Oil Corporation | Crystalline silicates and method of preparing the same |
| JPS59184723A (ja) * | 1983-04-06 | 1984-10-20 | Res Assoc Petroleum Alternat Dev<Rapad> | 結晶性メタロシリケ−トの製造法 |
| EP0514715B1 (en) * | 1991-05-17 | 1997-12-29 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for producing a particulate zeolite |
| GB9122498D0 (en) * | 1991-10-23 | 1991-12-04 | Exxon Chemical Patents Inc | Process for preparing uniform mfitype zeolite crystals |
| ZA933879B (en) * | 1992-06-05 | 1993-12-27 | Exxon Chemical Patents Inc | ZSM-5-zeolite |
| DE60127095T2 (de) * | 2000-01-05 | 2007-11-15 | Exxonmobil Chemical Patents Inc., Baytown | Poröse anorganische makrostrukturen und verfahren zur herstellung derselben |
| CN1100005C (zh) * | 2000-06-28 | 2003-01-29 | 中国科学院山西煤炭化学研究所 | 导向剂法快速合成zsm-5分子筛的方法 |
| CN1281494C (zh) * | 2004-06-29 | 2006-10-25 | 中国石油化工股份有限公司 | 一种小晶粒zsm-5沸石的制备方法 |
| ITMI20042136A1 (it) * | 2004-11-08 | 2005-02-08 | Sasol Italy S P A | Procedimento perfezionato per la preparazione di zeoliti zsm-5 |
| CN100455511C (zh) * | 2006-11-10 | 2009-01-28 | 南京工业大学 | 一种合成小晶粒zsm-5沸石分子筛的方法 |
| CN101733143B (zh) * | 2008-11-21 | 2012-08-01 | 中国石油化工股份有限公司 | 小晶粒zsm-5分子筛及其用途 |
| CN102372284B (zh) * | 2010-08-23 | 2013-01-09 | 中国石油化工股份有限公司 | 小晶粒zsm-5沸石的制备方法 |
| CN103842294B (zh) | 2011-08-04 | 2016-08-17 | 埃克森美孚化学专利公司 | Emm-23分子筛材料、其合成和用途 |
| CN102502696B (zh) | 2011-11-16 | 2014-04-23 | 大连理工大学 | 一种zsm-5沸石的合成方法 |
| WO2014099261A1 (en) * | 2012-12-21 | 2014-06-26 | Exxonbobil Chemical Patents Inc. | Synthesis of zsm-5 |
| EP3266747A1 (en) * | 2012-12-21 | 2018-01-10 | ExxonMobil Chemical Patents Inc. | Small crystal zsm-5 and use |
-
2013
- 2013-11-22 EP EP17186970.4A patent/EP3266747A1/en not_active Withdrawn
- 2013-11-22 CA CA2895232A patent/CA2895232C/en active Active
- 2013-11-22 WO PCT/US2013/071456 patent/WO2014099262A1/en not_active Ceased
- 2013-11-22 KR KR1020157016273A patent/KR102166191B1/ko active Active
- 2013-11-22 SG SG10201705927UA patent/SG10201705927UA/en unknown
- 2013-11-22 EP EP13808320.9A patent/EP2935102B1/en active Active
- 2013-11-22 CN CN201710862536.8A patent/CN107697928B/zh active Active
- 2013-11-22 US US14/648,800 patent/US10081552B2/en active Active
- 2013-11-22 CN CN201380066799.8A patent/CN104870367B/zh active Active
- 2013-11-22 SG SG11201503973UA patent/SG11201503973UA/en unknown
- 2013-11-22 JP JP2015549410A patent/JP6238377B2/ja active Active
- 2013-11-22 RU RU2015129627A patent/RU2640759C2/ru active
- 2013-11-22 EP EP16163846.5A patent/EP3056470B1/en active Active
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2015
- 2015-05-21 ZA ZA2015/03617A patent/ZA201503617B/en unknown
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2018
- 2018-08-22 US US16/108,216 patent/US10662068B2/en active Active
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| US5240892A (en) * | 1987-09-02 | 1993-08-31 | Mobil Oil Corporation | Small crystal ZSM-5, as a catalyst |
| RU2143397C1 (ru) * | 1995-06-06 | 1999-12-27 | Мобил Ойл Корпорейшн | Способ синтезирования пористого кристаллического материала, имеющего структуру zsm-5 |
| US7244409B2 (en) * | 1999-10-27 | 2007-07-17 | Sud-Chemie Ag | Process for producing synthetic zeolites with MFI structure |
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| RU2313486C1 (ru) * | 2006-04-12 | 2007-12-27 | Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") | Синтетический цеолит и способ его получения |
| RU2313488C1 (ru) * | 2006-04-24 | 2007-12-27 | Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") | Синтетический цеолит и способ его получения |
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| US20120027673A1 (en) * | 2010-07-30 | 2012-02-02 | University Of Iowa Research Foundation | Synthesis of hierarchical nanocrystalline zeolites with controlled particle size and mesoporosity |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2015129627A (ru) | 2017-02-02 |
| EP3056470B1 (en) | 2017-10-18 |
| CA2895232C (en) | 2020-07-28 |
| US20190062171A1 (en) | 2019-02-28 |
| JP2016505498A (ja) | 2016-02-25 |
| CA2895232A1 (en) | 2014-06-26 |
| WO2014099262A1 (en) | 2014-06-26 |
| EP3266747A1 (en) | 2018-01-10 |
| ZA201503617B (en) | 2016-02-24 |
| SG10201705927UA (en) | 2017-08-30 |
| EP2935102A1 (en) | 2015-10-28 |
| SG11201503973UA (en) | 2015-06-29 |
| EP2935102B1 (en) | 2017-01-25 |
| CN104870367B (zh) | 2017-09-22 |
| KR102166191B1 (ko) | 2020-10-15 |
| EP3056470A1 (en) | 2016-08-17 |
| KR20150100677A (ko) | 2015-09-02 |
| US20150298981A1 (en) | 2015-10-22 |
| CN107697928B (zh) | 2020-09-01 |
| CN107697928A (zh) | 2018-02-16 |
| US10662068B2 (en) | 2020-05-26 |
| JP6238377B2 (ja) | 2017-11-29 |
| US10081552B2 (en) | 2018-09-25 |
| CN104870367A (zh) | 2015-08-26 |
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