ZA201503617B - Small crystal zsm-5, its synthesis and use - Google Patents

Small crystal zsm-5, its synthesis and use

Info

Publication number
ZA201503617B
ZA201503617B ZA2015/03617A ZA201503617A ZA201503617B ZA 201503617 B ZA201503617 B ZA 201503617B ZA 2015/03617 A ZA2015/03617 A ZA 2015/03617A ZA 201503617 A ZA201503617 A ZA 201503617A ZA 201503617 B ZA201503617 B ZA 201503617B
Authority
ZA
South Africa
Prior art keywords
synthesis
small crystal
crystal zsm
zsm
small
Prior art date
Application number
ZA2015/03617A
Other languages
English (en)
Inventor
Mobae Afeworki
Christine E Kliewer
Allen W Burton
Original Assignee
Exxonmobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patents Inc filed Critical Exxonmobil Chemical Patents Inc
Publication of ZA201503617B publication Critical patent/ZA201503617B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/007—Borosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/50—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor
    • C07C5/52—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor with a hydrocarbon as an acceptor, e.g. hydrocarbon disproportionation, i.e. 2CnHp -> CnHp+q + CnHp-q
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/46—Iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
ZA2015/03617A 2012-12-21 2015-05-21 Small crystal zsm-5, its synthesis and use ZA201503617B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261740908P 2012-12-21 2012-12-21
EP13155722 2013-02-19
PCT/US2013/071456 WO2014099262A1 (en) 2012-12-21 2013-11-22 Small crystal zsm-5, its synthesis and use

Publications (1)

Publication Number Publication Date
ZA201503617B true ZA201503617B (en) 2016-02-24

Family

ID=47739133

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA2015/03617A ZA201503617B (en) 2012-12-21 2015-05-21 Small crystal zsm-5, its synthesis and use

Country Status (10)

Country Link
US (2) US10081552B2 (enExample)
EP (3) EP3056470B1 (enExample)
JP (1) JP6238377B2 (enExample)
KR (1) KR102166191B1 (enExample)
CN (2) CN107697928B (enExample)
CA (1) CA2895232C (enExample)
RU (1) RU2640759C2 (enExample)
SG (2) SG10201705927UA (enExample)
WO (1) WO2014099262A1 (enExample)
ZA (1) ZA201503617B (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107697928B (zh) * 2012-12-21 2020-09-01 埃克森美孚化学专利公司 小晶体zsm-5,其合成和用途
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
US10053403B2 (en) 2015-02-04 2018-08-21 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes
WO2016129659A1 (ja) * 2015-02-13 2016-08-18 東ソー株式会社 ペンタシル型ゼオライト及びその製造方法
US9851313B2 (en) * 2015-03-03 2017-12-26 Panalytical B.V. Quantitative X-ray analysis—ratio correction
CN108602683A (zh) 2016-02-19 2018-09-28 埃克森美孚研究工程公司 小晶体、高比表面积的emm-30沸石、其合成及用途
WO2018132228A1 (en) * 2017-01-11 2018-07-19 Chevron U.S.A. Inc. Synthesis of mfi framework type molecular sieves
JP7341247B2 (ja) * 2019-02-27 2023-09-08 シェブロン ユー．エス．エー． インコーポレイテッド モレキュラーシーブｓｓｚ－１１５、その合成及び使用
WO2021034426A1 (en) 2019-08-20 2021-02-25 Exxonmobil Research And Engineering Company Metal-organic framework catalysts and their use in catalytic cracking
US10737946B1 (en) * 2019-08-29 2020-08-11 Chevron U.S.A. Inc. Synthesis of aluminum-containing molecular sieves of SEW framework type
JP2022163831A (ja) * 2021-04-15 2022-10-27 東ソー株式会社 Ｍｆｉ型ゼオライト
EP4406646B1 (en) 2023-01-27 2025-10-01 Hindustan Petroleum Corporation Limited Nano size crystal zsm-5 and its preparation and applications thereof
EP4777562A1 (en) 2023-09-12 2026-07-22 ExxonMobil Technology and Engineering Company Zeolitic materials in polyolefin decomposition via pyrolysis

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
JPS59184723A (ja) 1983-04-06 1984-10-20 Res Assoc Petroleum Alternat Dev<Rapad> 結晶性メタロシリケ−トの製造法
US5240892A (en) 1987-09-02 1993-08-31 Mobil Oil Corporation Small crystal ZSM-5, as a catalyst
JPH05310415A (ja) 1991-05-17 1993-11-22 Asahi Chem Ind Co Ltd ゼオライト微粒子体の製造方法
GB9122498D0 (en) * 1991-10-23 1991-12-04 Exxon Chemical Patents Inc Process for preparing uniform mfitype zeolite crystals
ZA933879B (en) * 1992-06-05 1993-12-27 Exxon Chemical Patents Inc ZSM-5-zeolite
JP4065560B2 (ja) 1995-06-06 2008-03-26 モービル オイル コーポレーション 大きな結晶のｚｓｍ−５の製造方法
DE19951781A1 (de) 1999-10-27 2001-05-03 Sued Chemie Ag Verfahren zur Herstellung von synthetischen Zeolithen mit MFI-Struktur
AU2763701A (en) * 2000-01-05 2001-07-16 Exxon Chemical Patents Inc. Porous inorganic macrostructure materials and process for their preparation
CN1100005C (zh) * 2000-06-28 2003-01-29 中国科学院山西煤炭化学研究所 导向剂法快速合成zsm－5分子筛的方法
EP1587756A4 (en) 2002-12-30 2011-07-06 Sk Energy Co Ltd PROCESS FOR THE PREPARATION OF ZSM-5 BY VARIABLE TEMPERATURE WITHOUT ORGANIC STENCIL MATERIAL
CN1281494C (zh) * 2004-06-29 2006-10-25 中国石油化工股份有限公司 一种小晶粒zsm－5沸石的制备方法
ITMI20042136A1 (it) * 2004-11-08 2005-02-08 Sasol Italy S P A Procedimento perfezionato per la preparazione di zeoliti zsm-5
RU2312063C1 (ru) 2006-04-12 2007-12-10 Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") Синтетический пористый кристаллический материал и способ его получения
RU2313486C1 (ru) 2006-04-12 2007-12-27 Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") Синтетический цеолит и способ его получения
RU2313488C1 (ru) 2006-04-24 2007-12-27 Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") Синтетический цеолит и способ его получения
CN100455511C (zh) * 2006-11-10 2009-01-28 南京工业大学 一种合成小晶粒zsm-5沸石分子筛的方法
CN101733143B (zh) * 2008-11-21 2012-08-01 中国石油化工股份有限公司 小晶粒zsm-5分子筛及其用途
KR101147007B1 (ko) 2009-02-02 2012-05-22 한국과학기술원 싸이클릭다이암모늄을 이용한 메조기공 및 마크로기공을 추가적으로 포함하는 ｂｅａ, ｍｔｗ, ｍｆｉ 구조의 제올라이트의 제조과정
US8951498B2 (en) * 2010-07-30 2015-02-10 University Of Iowa Research Foundation Synthesis of hierarchical nanocrystalline zeolites with controlled particle size and mesoporosity
CN102372284B (zh) * 2010-08-23 2013-01-09 中国石油化工股份有限公司 小晶粒zsm-5沸石的制备方法
CA2844120C (en) * 2011-08-04 2019-07-02 Exxonmobil Chemical Patents Inc. Emm-23 molecular sieve material, its synthesis and use
CN102502696B (zh) * 2011-11-16 2014-04-23 大连理工大学 一种zsm-5沸石的合成方法
CN107697928B (zh) * 2012-12-21 2020-09-01 埃克森美孚化学专利公司 小晶体zsm-5,其合成和用途
EP2935101B1 (en) * 2012-12-21 2016-12-21 ExxonMobil Chemical Patents Inc. Synthesis of zsm-5

Also Published As

Publication number Publication date
CN104870367B (zh) 2017-09-22
JP2016505498A (ja) 2016-02-25
CN107697928B (zh) 2020-09-01
US10662068B2 (en) 2020-05-26
KR20150100677A (ko) 2015-09-02
KR102166191B1 (ko) 2020-10-15
SG11201503973UA (en) 2015-06-29
CN107697928A (zh) 2018-02-16
EP2935102A1 (en) 2015-10-28
US10081552B2 (en) 2018-09-25
US20150298981A1 (en) 2015-10-22
CA2895232A1 (en) 2014-06-26
CN104870367A (zh) 2015-08-26
US20190062171A1 (en) 2019-02-28
RU2015129627A (ru) 2017-02-02
EP3266747A1 (en) 2018-01-10
EP3056470A1 (en) 2016-08-17
SG10201705927UA (en) 2017-08-30
WO2014099262A1 (en) 2014-06-26
RU2640759C2 (ru) 2018-01-11
JP6238377B2 (ja) 2017-11-29
CA2895232C (en) 2020-07-28
EP2935102B1 (en) 2017-01-25
EP3056470B1 (en) 2017-10-18

Similar Documents

Publication Publication Date Title
SG11201503973UA (en) Small crystal zsm-5, its synthesis and use
GB2508204B (en) Orthosis
AU347535S (en) Bracelet
EP2919722A4 (en) DEVICE FOR SUPPORTING THE HALF-SPIRIT COLUMN
PL3701800T3 (pl) Zastosowanie
GB201216800D0 (en) Novel use
LT2858606T (lt) Įtvaras
GB201203881D0 (en) Mesoporous single crystal semiconductore
PL2650310T3 (pl) Przeciwciało przeciw-ADAMTS-5, jego pochodne i zastosowania
PL2670382T3 (pl) Zastosowanie kosmetyczne
ZA201405392B (en) Substituted phenylimidazopyrazoles and use thereof
GB201111630D0 (en) Novel compounds and their use
GB201218352D0 (en) Compounds and their synthesis
IL232809A0 (en) Carboxamides converted at position 2 in isothiazolopyridine and their use as medicinal preparations
ZA201407348B (en) Zeolite zsm-18,its synthesis and its use
GB201217093D0 (en) Crystal structure I
GB201212463D0 (en) Novel use
GB201220297D0 (en) Back up bar
TWM432402U (en) Spine activator structure
GB201202256D0 (en) Novel use
GB201206393D0 (en) Use
GB201217779D0 (en) New Capo
GB201213726D0 (en) Novel compounds and their use
EM19749080001S (bg) Ремъци за носене
EM19749080002S (fi) Hihnat