CN107697928B - 小晶体zsm-5,其合成和用途 - Google Patents

小晶体zsm-5,其合成和用途 Download PDF

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CN107697928B
CN107697928B CN201710862536.8A CN201710862536A CN107697928B CN 107697928 B CN107697928 B CN 107697928B CN 201710862536 A CN201710862536 A CN 201710862536A CN 107697928 B CN107697928 B CN 107697928B
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surface area
zsm
molecular sieve
product
synthesis
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CN107697928A (zh
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A·W·伯顿
C·E·克里威尔
M·阿菲沃奇
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ExxonMobil Chemical Patents Inc
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    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
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    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
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    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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    • C07C5/52—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor with a hydrocarbon as an acceptor, e.g. hydrocarbon disproportionation, i.e. 2CnHp -> CnHp+q + CnHp-q
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
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CN201710862536.8A 2012-12-21 2013-11-22 小晶体zsm-5,其合成和用途 Active CN107697928B (zh)

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US201261740908P 2012-12-21 2012-12-21
US61/740,908 2012-12-21
EP13155722 2013-02-19
EP13155722.5 2013-02-19
CN201380066799.8A CN104870367B (zh) 2012-12-21 2013-11-22 小晶体zsm‑5,其合成和用途

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EP (3) EP3266747A1 (enExample)
JP (1) JP6238377B2 (enExample)
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CN (2) CN107697928B (enExample)
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Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3266747A1 (en) * 2012-12-21 2018-01-10 ExxonMobil Chemical Patents Inc. Small crystal zsm-5 and use
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
US10053403B2 (en) 2015-02-04 2018-08-21 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes
WO2016129659A1 (ja) * 2015-02-13 2016-08-18 東ソー株式会社 ペンタシル型ゼオライト及びその製造方法
US9851313B2 (en) * 2015-03-03 2017-12-26 Panalytical B.V. Quantitative X-ray analysis—ratio correction
EP3416915B1 (en) * 2016-02-19 2025-01-01 ExxonMobil Technology and Engineering Company Synthesis of small crystal, high surface area emm-30 zeolites
WO2018132228A1 (en) * 2017-01-11 2018-07-19 Chevron U.S.A. Inc. Synthesis of mfi framework type molecular sieves
US11033886B2 (en) 2019-02-27 2021-06-15 Chevron U.S.A. Inc. Molecular sieve SSZ-115, its synthesis and use
CA3146853A1 (en) 2019-08-20 2021-02-25 Exxonmobil Research And Engineering Company Metal-organic framework catalysts and their use in catalytic cracking
US10737946B1 (en) * 2019-08-29 2020-08-11 Chevron U.S.A. Inc. Synthesis of aluminum-containing molecular sieves of SEW framework type
JP2022163831A (ja) * 2021-04-15 2022-10-27 東ソー株式会社 Ｍｆｉ型ゼオライト
EP4406646B1 (en) 2023-01-27 2025-10-01 Hindustan Petroleum Corporation Limited Nano size crystal zsm-5 and its preparation and applications thereof
WO2025058925A1 (en) 2023-09-12 2025-03-20 ExxonMobil Technology and Engineering Company Zeolitic materials in polyolefin decomposition via pyrolysis

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1303816A (zh) * 2000-06-28 2001-07-18 中国科学院山西煤炭化学研究所 导向剂法快速合成小晶粒zsm－5分子筛的方法
CN1715186A (zh) * 2004-06-29 2006-01-04 中国石油化工股份有限公司 一种小晶粒zsm－5沸石的制备方法
CN1958453A (zh) * 2006-11-10 2007-05-09 南京工业大学 一种合成小晶粒zsm－5沸石分子筛的方法
CN101733143A (zh) * 2008-11-21 2010-06-16 中国石油化工股份有限公司 小晶粒zsm-5分子筛及其用途
CN102372284A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 小晶粒zsm-5沸石的制备方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
JPS59184723A (ja) * 1983-04-06 1984-10-20 Res Assoc Petroleum Alternat Dev<Rapad> 結晶性メタロシリケ−トの製造法
US5240892A (en) 1987-09-02 1993-08-31 Mobil Oil Corporation Small crystal ZSM-5, as a catalyst
EP0514715B1 (en) * 1991-05-17 1997-12-29 Asahi Kasei Kogyo Kabushiki Kaisha Method for producing a particulate zeolite
GB9122498D0 (en) * 1991-10-23 1991-12-04 Exxon Chemical Patents Inc Process for preparing uniform mfitype zeolite crystals
ZA933879B (en) * 1992-06-05 1993-12-27 Exxon Chemical Patents Inc ZSM-5-zeolite
CA2222585C (en) * 1995-06-06 2007-10-02 Mobil Oil Corporation Large crystal zsm-5, its synthesis and use
DE19951781A1 (de) 1999-10-27 2001-05-03 Sued Chemie Ag Verfahren zur Herstellung von synthetischen Zeolithen mit MFI-Struktur
DE60127095T2 (de) * 2000-01-05 2007-11-15 Exxonmobil Chemical Patents Inc., Baytown Poröse anorganische makrostrukturen und verfahren zur herstellung derselben
EP1587756A4 (en) 2002-12-30 2011-07-06 Sk Energy Co Ltd PROCESS FOR THE PREPARATION OF ZSM-5 BY VARIABLE TEMPERATURE WITHOUT ORGANIC STENCIL MATERIAL
ITMI20042136A1 (it) * 2004-11-08 2005-02-08 Sasol Italy S P A Procedimento perfezionato per la preparazione di zeoliti zsm-5
RU2312063C1 (ru) 2006-04-12 2007-12-10 Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") Синтетический пористый кристаллический материал и способ его получения
RU2313486C1 (ru) 2006-04-12 2007-12-27 Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") Синтетический цеолит и способ его получения
RU2313488C1 (ru) 2006-04-24 2007-12-27 Общество с ограниченной ответственностью "Томскнефтехим" (ООО "Томскнефтехим") Синтетический цеолит и способ его получения
KR101147007B1 (ko) * 2009-02-02 2012-05-22 한국과학기술원 싸이클릭다이암모늄을 이용한 메조기공 및 마크로기공을 추가적으로 포함하는 ｂｅａ, ｍｔｗ, ｍｆｉ 구조의 제올라이트의 제조과정
US8951498B2 (en) * 2010-07-30 2015-02-10 University Of Iowa Research Foundation Synthesis of hierarchical nanocrystalline zeolites with controlled particle size and mesoporosity
CN103842294B (zh) 2011-08-04 2016-08-17 埃克森美孚化学专利公司 Emm-23分子筛材料、其合成和用途
CN102502696B (zh) 2011-11-16 2014-04-23 大连理工大学 一种zsm-5沸石的合成方法
WO2014099261A1 (en) * 2012-12-21 2014-06-26 Exxonbobil Chemical Patents Inc. Synthesis of zsm-5
EP3266747A1 (en) * 2012-12-21 2018-01-10 ExxonMobil Chemical Patents Inc. Small crystal zsm-5 and use

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1303816A (zh) * 2000-06-28 2001-07-18 中国科学院山西煤炭化学研究所 导向剂法快速合成小晶粒zsm－5分子筛的方法
CN1715186A (zh) * 2004-06-29 2006-01-04 中国石油化工股份有限公司 一种小晶粒zsm－5沸石的制备方法
CN1958453A (zh) * 2006-11-10 2007-05-09 南京工业大学 一种合成小晶粒zsm－5沸石分子筛的方法
CN101733143A (zh) * 2008-11-21 2010-06-16 中国石油化工股份有限公司 小晶粒zsm-5分子筛及其用途
CN102372284A (zh) * 2010-08-23 2012-03-14 中国石油化工股份有限公司 小晶粒zsm-5沸石的制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Molecular and Meso- and Macroscopic properties of Hierarchical Nanocrystalline ZSM-5 Zeolite Prepared by Seed Silanization;D.P.Serrano et al.;《Chemistry of Materials》;20090128;第21卷(第4期);第643页第3段，第644页图1，第648页图3b，表1，表2 *

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