RU2604726C2 - Производство органических материалов с использованием способа окислительного гидротермического растворения - Google Patents
Производство органических материалов с использованием способа окислительного гидротермического растворения Download PDFInfo
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- RU2604726C2 RU2604726C2 RU2013157530/04A RU2013157530A RU2604726C2 RU 2604726 C2 RU2604726 C2 RU 2604726C2 RU 2013157530/04 A RU2013157530/04 A RU 2013157530/04A RU 2013157530 A RU2013157530 A RU 2013157530A RU 2604726 C2 RU2604726 C2 RU 2604726C2
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- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
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- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
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- C—CHEMISTRY; METALLURGY
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- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D333/40—Thiophene-2-carboxylic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
- C07H1/06—Separation; Purification
- C07H1/08—Separation; Purification from natural products
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/006—Combinations of processes provided in groups C10G1/02 - C10G1/08
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
- C10G1/047—Hot water or cold water extraction processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatment Of Sludge (AREA)
- Processing Of Solid Wastes (AREA)
- Compounds Of Unknown Constitution (AREA)
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US201161492910P | 2011-06-03 | 2011-06-03 | |
US61/492,910 | 2011-06-03 | ||
PCT/US2012/040746 WO2012167252A1 (en) | 2011-06-03 | 2012-06-04 | Production of organic materials using an oxidative hydrothermal dissolution method |
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RU2013157530A RU2013157530A (ru) | 2015-07-20 |
RU2604726C2 true RU2604726C2 (ru) | 2016-12-10 |
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RU2013157530/04A RU2604726C2 (ru) | 2011-06-03 | 2012-06-04 | Производство органических материалов с использованием способа окислительного гидротермического растворения |
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EP (1) | EP2714855A4 (ko) |
JP (1) | JP2014520104A (ko) |
KR (1) | KR20140090564A (ko) |
CN (1) | CN103764804A (ko) |
AU (1) | AU2012261870A1 (ko) |
BR (1) | BR112013031137A2 (ko) |
CA (1) | CA2836738A1 (ko) |
RU (1) | RU2604726C2 (ko) |
WO (1) | WO2012167252A1 (ko) |
ZA (1) | ZA201308767B (ko) |
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FI20135224A (fi) * | 2013-03-08 | 2014-09-09 | Upm Kymmene Corp | Prosessi bioöljyn konvertoimiseksi |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2665249A (en) * | 1950-03-27 | 1954-01-05 | Sterling Drug Inc | Waste disposal |
WO1981000854A1 (en) * | 1979-09-27 | 1981-04-02 | Modar Inc | Treatment of organic material in supercritical water |
US5560823A (en) * | 1994-12-21 | 1996-10-01 | Abitibi-Price, Inc. | Reversible flow supercritical reactor and method for operating same |
RU2008147899A (ru) * | 2006-05-05 | 2010-06-10 | БИОеКОН Интернэшнл Холдинг Н.В. (NL) | Способ конверсии биомассы в жидкое топливо и специальные химикаты |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4384897A (en) * | 1981-11-23 | 1983-05-24 | The Regents Of The University Of California | Method of treating biomass material |
US6576145B2 (en) * | 1997-02-27 | 2003-06-10 | Continuum Environmental, Llc | Method of separating hydrocarbons from mineral substrates |
JP3284234B2 (ja) * | 1998-09-10 | 2002-05-20 | 独立行政法人産業技術総合研究所 | 木質系廃棄物の処理方法 |
JP2001062424A (ja) * | 1999-08-27 | 2001-03-13 | Shinko Pantec Co Ltd | ケミカルリサイクル処理方法及び装置 |
JP4714837B2 (ja) * | 2001-02-09 | 2011-06-29 | エス.エス.アロイ株式会社 | 木質バイオマスを原料にした分解物質の製造方法および装置 |
JP2003236491A (ja) * | 2002-02-12 | 2003-08-26 | Kurita Water Ind Ltd | 廃木材の処理装置 |
JP3724438B2 (ja) * | 2002-03-08 | 2005-12-07 | 株式会社日立製作所 | 超臨界水による重質油の処理方法と処理装置及び重質油処理装置を備えた発電システム |
US7179379B2 (en) * | 2003-03-28 | 2007-02-20 | Ab-Cwt, Llc | Apparatus for separating particulates from a suspension, and uses thereof |
US7692050B2 (en) * | 2003-03-28 | 2010-04-06 | Ab-Cwt, Llc | Apparatus and process for separation of organic materials from attached insoluble solids, and conversion into useful products |
DK176540B1 (da) * | 2004-09-24 | 2008-07-21 | Cambi Bioethanol Aps | Fremgangsmåde til behandling af biomasse og organisk affald med henblik på at udvinde önskede biologisk baserede produkter |
JP5314917B2 (ja) * | 2008-04-23 | 2013-10-16 | 川崎重工業株式会社 | セルロース系バイオマスの糖化分解方法及び糖化分解装置 |
JP5103260B2 (ja) * | 2008-04-23 | 2012-12-19 | 川崎重工業株式会社 | セルロース系バイオマスの糖化分解方法及び糖化分解装置 |
US7931784B2 (en) * | 2008-04-30 | 2011-04-26 | Xyleco, Inc. | Processing biomass and petroleum containing materials |
CN102307970B (zh) * | 2009-02-11 | 2015-04-29 | 南伊利诺斯州立大学 | 在超热水中使煤、生物质和其它有机固体增溶的方法 |
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2012
- 2012-06-04 RU RU2013157530/04A patent/RU2604726C2/ru not_active IP Right Cessation
- 2012-06-04 AU AU2012261870A patent/AU2012261870A1/en not_active Abandoned
- 2012-06-04 KR KR1020137031981A patent/KR20140090564A/ko not_active Application Discontinuation
- 2012-06-04 JP JP2014513791A patent/JP2014520104A/ja active Pending
- 2012-06-04 CA CA2836738A patent/CA2836738A1/en not_active Abandoned
- 2012-06-04 EP EP12793493.3A patent/EP2714855A4/en not_active Withdrawn
- 2012-06-04 BR BR112013031137A patent/BR112013031137A2/pt not_active Application Discontinuation
- 2012-06-04 WO PCT/US2012/040746 patent/WO2012167252A1/en active Application Filing
- 2012-06-04 CN CN201280026415.5A patent/CN103764804A/zh active Pending
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2013
- 2013-11-21 ZA ZA2013/08767A patent/ZA201308767B/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2665249A (en) * | 1950-03-27 | 1954-01-05 | Sterling Drug Inc | Waste disposal |
WO1981000854A1 (en) * | 1979-09-27 | 1981-04-02 | Modar Inc | Treatment of organic material in supercritical water |
US5560823A (en) * | 1994-12-21 | 1996-10-01 | Abitibi-Price, Inc. | Reversible flow supercritical reactor and method for operating same |
RU2008147899A (ru) * | 2006-05-05 | 2010-06-10 | БИОеКОН Интернэшнл Холдинг Н.В. (NL) | Способ конверсии биомассы в жидкое топливо и специальные химикаты |
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AU2012261870A1 (en) | 2014-01-09 |
ZA201308767B (en) | 2015-02-25 |
EP2714855A1 (en) | 2014-04-09 |
RU2013157530A (ru) | 2015-07-20 |
EP2714855A4 (en) | 2014-11-12 |
NZ618723A (en) | 2015-12-24 |
KR20140090564A (ko) | 2014-07-17 |
CN103764804A (zh) | 2014-04-30 |
JP2014520104A (ja) | 2014-08-21 |
WO2012167252A9 (en) | 2013-12-05 |
CA2836738A1 (en) | 2012-12-06 |
WO2012167252A1 (en) | 2012-12-06 |
BR112013031137A2 (pt) | 2017-06-27 |
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