RU2572810C1 - Катализатор очистки выхлопного газа - Google Patents
Катализатор очистки выхлопного газа Download PDFInfo
- Publication number
- RU2572810C1 RU2572810C1 RU2014126415/04A RU2014126415A RU2572810C1 RU 2572810 C1 RU2572810 C1 RU 2572810C1 RU 2014126415/04 A RU2014126415/04 A RU 2014126415/04A RU 2014126415 A RU2014126415 A RU 2014126415A RU 2572810 C1 RU2572810 C1 RU 2572810C1
- Authority
- RU
- Russia
- Prior art keywords
- palladium
- layer
- upper layer
- exhaust gas
- rhodium
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 102
- 238000000746 purification Methods 0.000 title claims abstract description 64
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 289
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 145
- 239000007789 gas Substances 0.000 claims abstract description 96
- 239000010948 rhodium Substances 0.000 claims abstract description 77
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 74
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 74
- 239000001301 oxygen Substances 0.000 claims abstract description 74
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 74
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 73
- 230000003197 catalytic effect Effects 0.000 claims abstract description 69
- 239000000463 material Substances 0.000 claims abstract description 30
- 239000010970 precious metal Substances 0.000 claims abstract description 23
- 239000010410 layer Substances 0.000 claims description 261
- 239000011247 coating layer Substances 0.000 claims description 44
- 239000012876 carrier material Substances 0.000 claims description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract description 69
- 239000000758 substrate Substances 0.000 abstract description 16
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 29
- 238000003860 storage Methods 0.000 description 20
- 230000015572 biosynthetic process Effects 0.000 description 18
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 15
- 239000000446 fuel Substances 0.000 description 13
- 238000011144 upstream manufacturing Methods 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 11
- 229910052788 barium Inorganic materials 0.000 description 9
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- 230000007423 decrease Effects 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 238000005245 sintering Methods 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 6
- 239000011232 storage material Substances 0.000 description 6
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 5
- 238000001354 calcination Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 230000004927 fusion Effects 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 5
- 229910052746 lanthanum Inorganic materials 0.000 description 5
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229910052761 rare earth metal Inorganic materials 0.000 description 5
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 208000005374 Poisoning Diseases 0.000 description 4
- 231100000572 poisoning Toxicity 0.000 description 4
- 230000000607 poisoning effect Effects 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000001603 reducing effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- ITHZDDVSAWDQPZ-UHFFFAOYSA-L barium acetate Chemical compound [Ba+2].CC([O-])=O.CC([O-])=O ITHZDDVSAWDQPZ-UHFFFAOYSA-L 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- RCFVMJKOEJFGTM-UHFFFAOYSA-N cerium zirconium Chemical class [Zr].[Ce] RCFVMJKOEJFGTM-UHFFFAOYSA-N 0.000 description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 2
- 229910052878 cordierite Inorganic materials 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
- 150000002940 palladium Chemical class 0.000 description 2
- -1 palladium hydrocarbon Chemical class 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 206010017740 Gas poisoning Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QWDUNBOWGVRUCG-UHFFFAOYSA-N n-(4-chloro-2-nitrophenyl)acetamide Chemical compound CC(=O)NC1=CC=C(Cl)C=C1[N+]([O-])=O QWDUNBOWGVRUCG-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- VXNYVYJABGOSBX-UHFFFAOYSA-N rhodium(3+);trinitrate Chemical compound [Rh+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VXNYVYJABGOSBX-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1023—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1025—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
- B01D2255/2061—Yttrium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
- B01D2255/2065—Cerium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/902—Multilayered catalyst
- B01D2255/9022—Two layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/908—O2-storage component incorporated in the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011288798A JP5807782B2 (ja) | 2011-12-28 | 2011-12-28 | 排ガス浄化用触媒 |
| JP2011-288798 | 2011-12-28 | ||
| PCT/JP2012/008343 WO2013099251A1 (en) | 2011-12-28 | 2012-12-26 | Exhaust gas purification catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2572810C1 true RU2572810C1 (ru) | 2016-01-20 |
Family
ID=47915305
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2014126415/04A RU2572810C1 (ru) | 2011-12-28 | 2012-12-26 | Катализатор очистки выхлопного газа |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9440223B2 (enExample) |
| EP (1) | EP2797678B1 (enExample) |
| JP (1) | JP5807782B2 (enExample) |
| CN (1) | CN104039426B (enExample) |
| BR (1) | BR112014016151B1 (enExample) |
| RU (1) | RU2572810C1 (enExample) |
| WO (1) | WO2013099251A1 (enExample) |
| ZA (1) | ZA201405124B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2678766C1 (ru) * | 2018-09-28 | 2019-02-01 | Андрей Александрович Нестеренко | Способ изготовления катализаторов для очистки выхлопных газов |
| RU2712124C1 (ru) * | 2019-07-22 | 2020-01-24 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт химии силикатов им. И.В. Гребенщикова Российской академии наук (ИХС РАН) | СПОСОБ ПОЛУЧЕНИЯ КОМПОЗИЦИОННЫХ НАНОКРИСТАЛЛИЧЕСКИХ МЕЗОПОРИСТЫХ ПОРОШКОВ В СИСТЕМЕ CeO2(ZrO2)-Al2O3 ДЛЯ ТРЕХМАРШРУТНЫХ КАТАЛИЗАТОРОВ |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9744529B2 (en) * | 2014-03-21 | 2017-08-29 | Basf Corporation | Integrated LNT-TWC catalyst |
| US10512898B2 (en) * | 2015-06-24 | 2019-12-24 | Basf Corporation | Layered automotive catalyst composites |
| JP6699113B2 (ja) * | 2015-08-28 | 2020-05-27 | 三菱自動車工業株式会社 | 内燃機関の排ガス浄化システム及び排ガス浄化触媒 |
| KR101814455B1 (ko) | 2015-12-02 | 2018-01-04 | 희성촉매 주식회사 | Pd-Rh 합금을 포함하는 삼원촉매 |
| JP6378222B2 (ja) * | 2016-02-12 | 2018-08-22 | トヨタ自動車株式会社 | 排ガス浄化触媒装置、排ガス浄化システム、及び排ガス浄化触媒装置の劣化検出方法 |
| JP6724531B2 (ja) * | 2016-05-02 | 2020-07-15 | 三菱自動車工業株式会社 | 内燃機関の排ガス浄化触媒 |
| US10960389B2 (en) | 2016-05-24 | 2021-03-30 | Cataler Corporation | Exhaust gas purification catalyst |
| CN109310992A (zh) * | 2016-06-07 | 2019-02-05 | 株式会社科特拉 | 废气净化用催化剂 |
| WO2017218092A2 (en) * | 2016-06-13 | 2017-12-21 | Basf Corporation | Catalytic article comprising combined pgm and osc |
| MX2018015865A (es) * | 2016-06-17 | 2019-04-22 | Basf Corp | Catalizador de oxidacion diesel de paladio. |
| JP6604323B2 (ja) | 2016-12-28 | 2019-11-13 | トヨタ自動車株式会社 | 内燃機関の排ガス浄化システム及び排ガス浄化用触媒の使用方法 |
| JP6753811B2 (ja) | 2017-04-19 | 2020-09-09 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| EP3616790A4 (en) | 2017-04-28 | 2021-01-13 | Umicore Shokubai Japan Co., Ltd. | EXHAUST GAS PURIFICATION CATALYZER AND EXHAUST GAS PURIFICATION METHOD USING IT |
| CN110785230B (zh) * | 2017-04-28 | 2022-09-23 | 优美科触媒日本有限公司 | 废气净化用催化剂及使用其的废气净化方法 |
| JP2019058876A (ja) * | 2017-09-27 | 2019-04-18 | イビデン株式会社 | ハニカム触媒 |
| JP6954796B2 (ja) | 2017-10-06 | 2021-10-27 | トヨタ自動車株式会社 | 自動車用排ガス浄化用触媒 |
| KR102474347B1 (ko) * | 2017-10-26 | 2022-12-05 | 현대자동차 주식회사 | 배기가스 정화장치 |
| BR112020009925A2 (pt) | 2017-12-08 | 2020-11-24 | Johnson Matthey (Shanghai) Chemicals Limited | artigo catalisador para o tratamento de gás de escape, sistema de tratamento de emissão para tratar um fluxo de um gás de escape de combustão, e, método de tratamento de um gás de escape de um motor de combustão interna |
| EP3733289B1 (en) * | 2017-12-28 | 2024-02-28 | Umicore Shokubai Japan Co., Ltd. | Phosphorus-compound-containing-exhaust-gas purifying catalyst |
| JP7026530B2 (ja) * | 2018-02-22 | 2022-02-28 | エヌ・イーケムキャット株式会社 | 排ガス浄化用三元触媒 |
| US11097260B2 (en) * | 2018-03-30 | 2021-08-24 | Mitsui Mining & Smelting Co., Ltd. | Exhaust gas purification device |
| CN108927149A (zh) * | 2018-07-24 | 2018-12-04 | 中自环保科技股份有限公司 | 一种与scr匹配使用的lnt催化剂以及制备方法 |
| US20200030776A1 (en) * | 2018-07-27 | 2020-01-30 | Johnson Matthey Public Limited Company | Twc catalysts containing high dopant support |
| JP6778845B1 (ja) * | 2019-01-22 | 2020-11-04 | 三井金属鉱業株式会社 | 排ガス浄化用触媒 |
| JP7195995B2 (ja) | 2019-03-27 | 2022-12-26 | 株式会社キャタラー | 排ガス浄化用触媒 |
| JP7288331B2 (ja) * | 2019-03-29 | 2023-06-07 | 株式会社キャタラー | 排ガス浄化触媒装置 |
| JP7386651B2 (ja) * | 2019-09-02 | 2023-11-27 | 株式会社キャタラー | 排ガス浄化用触媒 |
| EP3889404A1 (en) * | 2020-03-30 | 2021-10-06 | Johnson Matthey Public Limited Company | Multi-region twc catalysts for gasoline engine exhaust gas treatments with improved h2s attenuation |
| EP4237141A1 (en) | 2020-10-30 | 2023-09-06 | Johnson Matthey Public Limited Company | Novel tri-metal pgm catalysts for gasoline engine exhaust gas treatments |
| US11788450B2 (en) * | 2020-10-30 | 2023-10-17 | Johnson Matthey Public Limited Company | TWC catalysts for gasoline engine exhaust gas treatments |
| JP7355775B2 (ja) | 2021-03-05 | 2023-10-03 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| JP7600910B2 (ja) * | 2021-07-06 | 2024-12-17 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995000235A1 (en) * | 1993-06-25 | 1995-01-05 | Engelhard Corporation | Layered catalyst composite |
| EP1704910A2 (en) * | 2005-03-24 | 2006-09-27 | Tokyo Roki Co. Ltd. | Exhaust gas purification catalyst |
| EP2036603A1 (en) * | 2006-07-04 | 2009-03-18 | Cataler Corporation | Exhaust gas purifying catalyst |
| RU2372141C2 (ru) * | 2005-06-20 | 2009-11-10 | Тойота Дзидося Кабусики Кайся | Катализатор для очистки выхлопного газа |
| RU2395341C1 (ru) * | 2006-03-28 | 2010-07-27 | Тойота Дзидося Кабусики Кайся | Катализатор для очистки выхлопных газов, способ регенерации такого катализатора, а также устройство и способ очистки выхлопных газов при использовании данного катализатора |
| US20110099987A1 (en) * | 2008-06-30 | 2011-05-05 | Akemi Satou | Exhaust gas purification catalyst |
Family Cites Families (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4128506A (en) * | 1978-01-23 | 1978-12-05 | General Motors Corporation | Platinum-rhodium catalyst for automotive emission control |
| JP2788293B2 (ja) * | 1989-07-21 | 1998-08-20 | 東京濾器株式会社 | 排気ガス浄化用触媒 |
| JP3061399B2 (ja) * | 1990-06-20 | 2000-07-10 | 株式会社日本触媒 | ディーゼルエンジン排ガス浄化用触媒および浄化方法 |
| JP3375358B2 (ja) * | 1993-01-29 | 2003-02-10 | マツダ株式会社 | 排気ガス浄化用触媒 |
| US5948723A (en) * | 1996-09-04 | 1999-09-07 | Engelhard Corporation | Layered catalyst composite |
| ES2131980T3 (es) * | 1996-11-11 | 1999-08-01 | Degussa | Catalizador purificador de gas de escape con una mejor capacidad de conversion para hidrocarburos |
| US6348430B1 (en) * | 1997-06-20 | 2002-02-19 | Degussa Ag | Exhaust gas treatment catalyst for internal combustion engines with two catalytically active layers on a carrier structure |
| US6107239A (en) * | 1998-01-19 | 2000-08-22 | Luchuang Environment Protection Science Co. Ltd. | Heat resistant metallic oxide catalyst for reducing pollution emission |
| US6294140B1 (en) * | 1999-04-23 | 2001-09-25 | Degussa Ag | Layered noble metal-containing exhaust gas catalyst and its preparation |
| EP1066874B1 (en) * | 1999-07-09 | 2009-09-23 | Nissan Motor Company, Limited | Exhaust gas purifying catalyst and method of producing same |
| US6881384B1 (en) * | 1999-08-30 | 2005-04-19 | Daihatsu Motor Co., Ltd. | Catalytic converter for cleaning exhaust gas |
| US6864214B2 (en) * | 2000-09-26 | 2005-03-08 | Daihatsu Motor Co., Ltd. | Exhaust gas purifying catalyst |
| JP3845274B2 (ja) * | 2001-06-26 | 2006-11-15 | ダイハツ工業株式会社 | 排ガス浄化用触媒 |
| JP3855266B2 (ja) * | 2001-11-01 | 2006-12-06 | 日産自動車株式会社 | 排気ガス浄化用触媒 |
| FR2862005B1 (fr) * | 2003-11-06 | 2006-01-06 | Air Liquide | Ajout d'agent(s) bloquant(s) dans une membrane ceramique pour bloquer la croissance cristalline des grains lors du frittage sous atmosphere |
| US8975204B2 (en) * | 2004-10-28 | 2015-03-10 | Cataler Corporation | Exhaust-gas-purifying catalyst |
| JP4696546B2 (ja) * | 2004-12-10 | 2011-06-08 | マツダ株式会社 | 排気ガス浄化用触媒 |
| US8168560B2 (en) * | 2005-10-05 | 2012-05-01 | Cataler Corporation | Exhaust gas purifying catalyst |
| KR101155847B1 (ko) * | 2006-06-14 | 2012-06-20 | 도요타 지도샤(주) | 배기 가스 정화용 촉매 |
| JP4726713B2 (ja) * | 2006-06-16 | 2011-07-20 | 株式会社豊田中央研究所 | 無機酸化物、及びそれを用いた排ガス浄化用触媒 |
| PL2038046T3 (pl) * | 2006-06-29 | 2018-09-28 | Umicore Ag & Co. Kg | Dwuwarstwowy katalizator trójdrożny i jego zastosowanie |
| JP2008023501A (ja) * | 2006-07-25 | 2008-02-07 | Toyota Motor Corp | 排ガス浄化用触媒 |
| US7758834B2 (en) * | 2006-08-21 | 2010-07-20 | Basf Corporation | Layered catalyst composite |
| US7550124B2 (en) * | 2006-08-21 | 2009-06-23 | Basf Catalysts Llc | Layered catalyst composite |
| US7517510B2 (en) * | 2006-08-21 | 2009-04-14 | Basf Catalysts Llc | Layered catalyst composite |
| CN101568381B (zh) * | 2007-02-01 | 2012-05-09 | 第一稀元素化学工业株式会社 | 用于机动车废气净化装置中的催化剂体系、使用该催化剂体系的废气净化装置及废气净化方法 |
| ATE482766T1 (de) * | 2007-03-19 | 2010-10-15 | Umicore Ag & Co Kg | Doppelschichtiger dreiweg-katalysator |
| JP5232401B2 (ja) * | 2007-04-05 | 2013-07-10 | 株式会社キャタラー | 排ガス浄化用触媒 |
| JP4858463B2 (ja) * | 2007-04-27 | 2012-01-18 | マツダ株式会社 | 排気ガス浄化用触媒およびその製造方法 |
| JP5173282B2 (ja) | 2007-07-04 | 2013-04-03 | 株式会社キャタラー | 排ガス浄化用触媒 |
| DE102007046158B4 (de) * | 2007-09-27 | 2014-02-13 | Umicore Ag & Co. Kg | Verwendung eines katalytisch aktiven Partikelfilters zur Entfernung von Partikeln aus dem Abgas von mit überwiegend stöchiometrischem Luft/Kraftstoff-Gemisch betriebenen Verbrennungsmotoren |
| DE502007002874D1 (de) * | 2007-09-28 | 2010-04-01 | Umicore Ag & Co Kg | Entfernung von Partikeln aus dem Abgas von mit überwiegend stöchiometrischem Luft/Kraftstoff-Gemisch betriebenen Verbrennungsmotoren |
| JP5065180B2 (ja) | 2008-06-30 | 2012-10-31 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| US8337791B2 (en) * | 2008-12-03 | 2012-12-25 | Daiichi Kigenso Kagaku Kogyo Co., Ltd. | Exhaust gas purification catalyst, exhaust gas purification apparatus using the same and exhaust gas purification method |
| CA2754405C (en) * | 2009-03-06 | 2017-05-16 | Ict Co., Ltd. | Catalyst for purifying exhaust gas |
| JP5544921B2 (ja) * | 2009-11-18 | 2014-07-09 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| JP5903205B2 (ja) * | 2010-01-04 | 2016-04-13 | 株式会社キャタラー | 排ガス浄化用触媒 |
| JP5458973B2 (ja) | 2010-03-09 | 2014-04-02 | マツダ株式会社 | 排気ガス浄化用触媒 |
| JP5573710B2 (ja) | 2010-07-23 | 2014-08-20 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| US8950174B2 (en) * | 2010-09-02 | 2015-02-10 | Basf Se | Catalysts for gasoline lean burn engines with improved NH3-formation activity |
| US9242242B2 (en) * | 2010-09-02 | 2016-01-26 | Basf Se | Catalyst for gasoline lean burn engines with improved NO oxidation activity |
| US8323599B2 (en) * | 2010-11-22 | 2012-12-04 | Umicore Ag & Co. Kg | Three-way catalyst having an upstream multi-layer catalyst |
| US8557204B2 (en) * | 2010-11-22 | 2013-10-15 | Umicore Ag & Co. Kg | Three-way catalyst having an upstream single-layer catalyst |
| JP5287884B2 (ja) | 2011-01-27 | 2013-09-11 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
-
2011
- 2011-12-28 JP JP2011288798A patent/JP5807782B2/ja not_active Expired - Fee Related
-
2012
- 2012-12-26 CN CN201280065163.7A patent/CN104039426B/zh not_active Expired - Fee Related
- 2012-12-26 EP EP12834572.5A patent/EP2797678B1/en not_active Not-in-force
- 2012-12-26 RU RU2014126415/04A patent/RU2572810C1/ru active
- 2012-12-26 US US14/369,217 patent/US9440223B2/en not_active Expired - Fee Related
- 2012-12-26 BR BR112014016151-8A patent/BR112014016151B1/pt not_active IP Right Cessation
- 2012-12-26 WO PCT/JP2012/008343 patent/WO2013099251A1/en not_active Ceased
-
2014
- 2014-07-14 ZA ZA2014/05124A patent/ZA201405124B/en unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995000235A1 (en) * | 1993-06-25 | 1995-01-05 | Engelhard Corporation | Layered catalyst composite |
| EP1704910A2 (en) * | 2005-03-24 | 2006-09-27 | Tokyo Roki Co. Ltd. | Exhaust gas purification catalyst |
| RU2372141C2 (ru) * | 2005-06-20 | 2009-11-10 | Тойота Дзидося Кабусики Кайся | Катализатор для очистки выхлопного газа |
| RU2395341C1 (ru) * | 2006-03-28 | 2010-07-27 | Тойота Дзидося Кабусики Кайся | Катализатор для очистки выхлопных газов, способ регенерации такого катализатора, а также устройство и способ очистки выхлопных газов при использовании данного катализатора |
| EP2036603A1 (en) * | 2006-07-04 | 2009-03-18 | Cataler Corporation | Exhaust gas purifying catalyst |
| US20110099987A1 (en) * | 2008-06-30 | 2011-05-05 | Akemi Satou | Exhaust gas purification catalyst |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2678766C1 (ru) * | 2018-09-28 | 2019-02-01 | Андрей Александрович Нестеренко | Способ изготовления катализаторов для очистки выхлопных газов |
| RU2712124C1 (ru) * | 2019-07-22 | 2020-01-24 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт химии силикатов им. И.В. Гребенщикова Российской академии наук (ИХС РАН) | СПОСОБ ПОЛУЧЕНИЯ КОМПОЗИЦИОННЫХ НАНОКРИСТАЛЛИЧЕСКИХ МЕЗОПОРИСТЫХ ПОРОШКОВ В СИСТЕМЕ CeO2(ZrO2)-Al2O3 ДЛЯ ТРЕХМАРШРУТНЫХ КАТАЛИЗАТОРОВ |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2797678A1 (en) | 2014-11-05 |
| EP2797678B1 (en) | 2017-11-15 |
| CN104039426B (zh) | 2016-08-24 |
| CN104039426A (zh) | 2014-09-10 |
| BR112014016151B1 (pt) | 2020-12-22 |
| JP2013136032A (ja) | 2013-07-11 |
| BR112014016151A8 (pt) | 2017-07-04 |
| JP5807782B2 (ja) | 2015-11-10 |
| US9440223B2 (en) | 2016-09-13 |
| US20140357480A1 (en) | 2014-12-04 |
| WO2013099251A1 (en) | 2013-07-04 |
| BR112014016151A2 (pt) | 2017-06-13 |
| ZA201405124B (en) | 2015-12-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2572810C1 (ru) | Катализатор очистки выхлопного газа | |
| US8802016B2 (en) | Zoned catalyzed soot filter | |
| EP2301661B1 (en) | Honeycomb catalyst for purifying exhaust gas discharged from automobile, method for producing the same, and exhaust gas purifying method using the catalyst | |
| CN107206372B (zh) | 废气净化用催化剂 | |
| KR101868176B1 (ko) | 개선된 no 산화 활성을 갖는 가솔린 린번 엔진용 촉매 | |
| US8858904B2 (en) | Catalyzed soot filter | |
| CN102083531B (zh) | 净化废气的催化剂装置和净化废气的方法 | |
| US9833771B2 (en) | Exhaust gas purifying catalyst | |
| US10737219B2 (en) | Exhaust gas purifying catalyst | |
| RU2631814C2 (ru) | Нанесенный катализатор на основе благородного металла для обработки выхлопного газа | |
| JP2010510884A (ja) | 熱時効耐性NOx貯蔵材料及びトラップ | |
| JPWO2017204008A1 (ja) | 排ガス浄化用触媒 | |
| JP2009273986A (ja) | 排ガス浄化用触媒 | |
| US20230277986A1 (en) | Exhaust Gas Purification Catalyst | |
| JP4980987B2 (ja) | 排ガス浄化用触媒 |