RU2561100C2 - Способ получения катализатора на основе титанового цеолита - Google Patents
Способ получения катализатора на основе титанового цеолита Download PDFInfo
- Publication number
- RU2561100C2 RU2561100C2 RU2012126602/04A RU2012126602A RU2561100C2 RU 2561100 C2 RU2561100 C2 RU 2561100C2 RU 2012126602/04 A RU2012126602/04 A RU 2012126602/04A RU 2012126602 A RU2012126602 A RU 2012126602A RU 2561100 C2 RU2561100 C2 RU 2561100C2
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- titanium zeolite
- stage
- hydrocarbon
- propylene
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 346
- 239000010936 titanium Substances 0.000 title claims abstract description 147
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 146
- 239000010457 zeolite Substances 0.000 title claims abstract description 146
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 145
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 133
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 128
- 238000000034 method Methods 0.000 title claims abstract description 127
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- 238000006243 chemical reaction Methods 0.000 claims abstract description 59
- 238000006735 epoxidation reaction Methods 0.000 claims abstract description 34
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- 239000012530 fluid Substances 0.000 claims abstract description 28
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- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002390 heteroarenes Chemical class 0.000 description 1
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
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- 239000000017 hydrogel Substances 0.000 description 1
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- 238000005216 hydrothermal crystallization Methods 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000033444 hydroxylation Effects 0.000 description 1
- 238000005805 hydroxylation reaction Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
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- 229910052758 niobium Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 1
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- 150000002894 organic compounds Chemical class 0.000 description 1
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- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- MTKUTYOMTJQXAY-UHFFFAOYSA-N pent-1-ene-1,1-diamine Chemical compound CCCC=C(N)N MTKUTYOMTJQXAY-UHFFFAOYSA-N 0.000 description 1
- KJOMYNHMBRNCNY-UHFFFAOYSA-N pentane-1,1-diamine Chemical compound CCCCC(N)N KJOMYNHMBRNCNY-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002647 polyamide Chemical class 0.000 description 1
- 229920000728 polyester Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- DAFQZPUISLXFBF-UHFFFAOYSA-N tetraoxathiolane 5,5-dioxide Chemical compound O=S1(=O)OOOO1 DAFQZPUISLXFBF-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/90—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/084—Decomposition of carbon-containing compounds into carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26473709P | 2009-11-27 | 2009-11-27 | |
| US61/264,737 | 2009-11-27 | ||
| PCT/EP2010/067987 WO2011064191A1 (en) | 2009-11-27 | 2010-11-23 | Process for the preparation of a titanium zeolite catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012126602A RU2012126602A (ru) | 2014-01-10 |
| RU2561100C2 true RU2561100C2 (ru) | 2015-08-20 |
Family
ID=43416565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012126602/04A RU2561100C2 (ru) | 2009-11-27 | 2010-11-23 | Способ получения катализатора на основе титанового цеолита |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9302257B2 (enExample) |
| EP (1) | EP2504098B1 (enExample) |
| JP (1) | JP5933445B2 (enExample) |
| KR (1) | KR101844084B1 (enExample) |
| CN (1) | CN102740968B (enExample) |
| BR (1) | BR112012012634A2 (enExample) |
| ES (1) | ES2596223T3 (enExample) |
| MX (1) | MX339546B (enExample) |
| MY (1) | MY160594A (enExample) |
| RU (1) | RU2561100C2 (enExample) |
| SG (1) | SG10201407829TA (enExample) |
| WO (1) | WO2011064191A1 (enExample) |
| ZA (1) | ZA201204699B (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2672357C1 (ru) * | 2017-08-08 | 2018-11-14 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Катализатор для получения синтетических углеводородов с высоким содержанием изоалканов и способ его получения |
| US11291980B2 (en) | 2016-12-20 | 2022-04-05 | Basf Se | Process for preparing an extrudable composition comprising a titanium-containing zeolitic material, having framework type MWW |
| RU2776838C2 (ru) * | 2016-12-20 | 2022-07-27 | Басф Се | Способ приготовления экструдируемой композиции, содержащей титансодержащий цеолитный материал, имеющий структурный тип mww |
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| US9527751B2 (en) | 2011-11-11 | 2016-12-27 | Basf Se | Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure |
| EP3216520B1 (en) * | 2012-02-07 | 2024-07-17 | Basf Se | Molding containing a zeolitic mww type material containing ti and zn and use thereof as a catalyst |
| CN110002463B (zh) * | 2013-02-05 | 2022-10-11 | 巴斯夫欧洲公司 | 制备具有mww骨架结构的含钛沸石材料的方法 |
| US9329159B2 (en) * | 2013-03-08 | 2016-05-03 | Ecolab Usa Inc. | Methods and systems for analyzing a liquid medium |
| CN103143390A (zh) * | 2013-03-15 | 2013-06-12 | 华东师范大学 | 一种微球钛硅分子筛催化剂的改性方法 |
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| WO2015029055A1 (en) * | 2013-08-30 | 2015-03-05 | Süd-Chemie India Pvt Ltd. | An abbreviated process to custom-make titanium silicate based catalysts with variegated physico-chemical properties |
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| SG11201605483XA (en) * | 2014-01-22 | 2016-08-30 | Lyondell Chemical Tech Lp | Method of preparing epoxidation catalysts |
| US9764313B2 (en) | 2014-06-18 | 2017-09-19 | Basf Corporation | Molecular sieve catalyst compositions, catalyst composites, systems, and methods |
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| ES2767100T3 (es) | 2014-07-29 | 2020-06-16 | Evonik Operations Gmbh | Procedimiento para la epoxidación de una olefina |
| WO2016173887A1 (en) | 2015-04-28 | 2016-11-03 | Evonik Degussa Gmbh | Process for the epoxidation of propene |
| BR102016026121B1 (pt) * | 2015-11-09 | 2021-09-14 | China Petroleum & Chemical Corporation | Peneira molecular scm-10, processo para sua produção, composição e uso |
| BR102016026135B1 (pt) * | 2015-11-09 | 2021-09-21 | Shanghai Research Institute Of Petrochemical Technology, Sinopec | Peneira molecular que apresenta a estrutura sfe, processo para sua produção, composição e uso |
| BR102016026128B1 (pt) | 2015-11-09 | 2022-10-04 | Shanghai Research Institute Of Petrochemical Technology, Sinopec | Peneiras moleculares scm-11, processo para a produção das mesmas, seus usos e composição de peneira molecular |
| EP3438101A1 (en) * | 2017-08-01 | 2019-02-06 | Evonik Degussa GmbH | Process for the epoxidation of propene |
| JP6947011B2 (ja) * | 2017-12-25 | 2021-10-13 | 東ソー株式会社 | ゼオライト−シリカ成形体 |
| KR102672200B1 (ko) * | 2018-03-15 | 2024-06-05 | 스미또모 가가꾸 가부시키가이샤 | 티탄 함유 규소 산화물 성형체의 제조 방법, 및 티탄 함유 규소 산화물 성형체 |
| EP3864010A1 (en) * | 2018-10-09 | 2021-08-18 | Basf Se | A molding comprising a zeolitic material having framework type mfi |
| US20220219154A1 (en) * | 2019-04-29 | 2022-07-14 | Basf Se | Molding comprising a type mfi zeolitic titanosilicate and a silica binder, its preparation process and use as catalyst |
| KR102811135B1 (ko) * | 2019-05-29 | 2025-05-21 | 스미또모 가가꾸 가부시끼가이샤 | 티탄 함유 규소 산화물의 제조 방법, 에폭시드의 제조 방법, 및 티탄 함유 규소 산화물 |
| WO2021099456A1 (en) | 2019-11-20 | 2021-05-27 | Basf Se | Zeolite catalyzed process for the amination of propylene oxide |
| JP2021087901A (ja) * | 2019-12-02 | 2021-06-10 | 栗田工業株式会社 | 水処理用浄化剤の製造方法 |
| JP7400421B2 (ja) * | 2019-12-06 | 2023-12-19 | 栗田工業株式会社 | 吸着剤、その製造方法及び水処理方法 |
| BR112022018861A2 (pt) * | 2020-03-23 | 2022-11-22 | Basf Se | Material zeolítico, composto contendo ti, uso de um composto contendo ti, processos para preparar um material zeolítico e para oxidar um composto orgânico, moldagem, uso de uma moldagem, e, óxido de propileno |
| KR20230048099A (ko) | 2020-08-03 | 2023-04-10 | 바스프 에스이 | 휘발성 유기 화합물의 가스 배출이 낮은 폴리에스테르 성형물 |
| EP4192818B1 (en) | 2020-08-04 | 2024-10-09 | Basf Se | Heterogeneous catalyzed process for the production of 2,2,4,6,6-pentamethyl-1,2,5,6-tetrahydro-pyrimidine |
| CN115231590B (zh) * | 2021-04-22 | 2023-10-31 | 中国石油化工股份有限公司 | B-euo/mtw共结晶分子筛及其制备方法和应用 |
| JP2024543122A (ja) | 2021-11-22 | 2024-11-19 | ビーエーエスエフ ソシエタス・ヨーロピア | エポキシ化触媒及びその調製方法 |
| KR20240115875A (ko) | 2021-11-29 | 2024-07-26 | 바스프 에스이 | 과산화수소 활성화를 위한 촉매 |
| KR20260018107A (ko) | 2023-05-31 | 2026-02-06 | 바스프 에스이 | 과산화수소 활성화를 위한 촉매 성형체 |
| EP4719665A1 (en) | 2023-05-31 | 2026-04-08 | Basf Se | Catalyst for epoxidation of propylene |
| WO2026104452A1 (en) | 2024-11-13 | 2026-05-21 | Basf Se | Catalyst for epoxidation of propylene |
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- 2010-11-23 WO PCT/EP2010/067987 patent/WO2011064191A1/en not_active Ceased
- 2010-11-23 KR KR1020127016503A patent/KR101844084B1/ko active Active
- 2010-11-23 SG SG10201407829TA patent/SG10201407829TA/en unknown
- 2010-11-23 MX MX2012005845A patent/MX339546B/es active IP Right Grant
- 2010-11-23 RU RU2012126602/04A patent/RU2561100C2/ru active
- 2010-11-23 MY MYPI2012002324A patent/MY160594A/en unknown
- 2010-11-23 JP JP2012540397A patent/JP5933445B2/ja not_active Expired - Fee Related
- 2010-11-23 BR BR112012012634-2A patent/BR112012012634A2/pt not_active Application Discontinuation
- 2010-11-23 CN CN201080062435.9A patent/CN102740968B/zh active Active
- 2010-11-23 EP EP10779561.9A patent/EP2504098B1/en active Active
- 2010-11-26 US US12/954,802 patent/US9302257B2/en not_active Expired - Fee Related
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| US4638106A (en) * | 1984-07-13 | 1987-01-20 | Exxon Research & Engineering Co. | Two stage process for improving the catalyst life of zeolites in the synthesis of lower olefins from alcohols and their ether derivatives |
| US4798816A (en) * | 1986-12-19 | 1989-01-17 | Union Oil Company Of California | Process for increasing the selectivity of an alkylation catalyst for monoalkylation |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11291980B2 (en) | 2016-12-20 | 2022-04-05 | Basf Se | Process for preparing an extrudable composition comprising a titanium-containing zeolitic material, having framework type MWW |
| RU2776838C2 (ru) * | 2016-12-20 | 2022-07-27 | Басф Се | Способ приготовления экструдируемой композиции, содержащей титансодержащий цеолитный материал, имеющий структурный тип mww |
| RU2672357C1 (ru) * | 2017-08-08 | 2018-11-14 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Катализатор для получения синтетических углеводородов с высоким содержанием изоалканов и способ его получения |
| RU2808562C2 (ru) * | 2018-10-09 | 2023-11-29 | Басф Се | Формованное изделие, содержащее цеолитный материал, имеющий тип каркасной структуры mfi |
Also Published As
| Publication number | Publication date |
|---|---|
| SG10201407829TA (en) | 2015-01-29 |
| WO2011064191A1 (en) | 2011-06-03 |
| CN102740968B (zh) | 2015-07-01 |
| US20110130579A1 (en) | 2011-06-02 |
| US9302257B2 (en) | 2016-04-05 |
| BR112012012634A2 (pt) | 2020-09-15 |
| JP5933445B2 (ja) | 2016-06-08 |
| ES2596223T3 (es) | 2017-01-05 |
| RU2012126602A (ru) | 2014-01-10 |
| CN102740968A (zh) | 2012-10-17 |
| EP2504098B1 (en) | 2016-07-06 |
| JP2013512082A (ja) | 2013-04-11 |
| ZA201204699B (en) | 2013-09-25 |
| KR20120087180A (ko) | 2012-08-06 |
| KR101844084B1 (ko) | 2018-03-30 |
| MX339546B (es) | 2016-05-30 |
| EP2504098A1 (en) | 2012-10-03 |
| MX2012005845A (es) | 2012-08-01 |
| MY160594A (en) | 2017-03-15 |
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| HZ9A | Changing address for correspondence with an applicant |