RU2541476C2 - Стирол-бутадиеновый каучук, характеризующийся новым включением стирола - Google Patents
Стирол-бутадиеновый каучук, характеризующийся новым включением стирола Download PDFInfo
- Publication number
- RU2541476C2 RU2541476C2 RU2011142189/04A RU2011142189A RU2541476C2 RU 2541476 C2 RU2541476 C2 RU 2541476C2 RU 2011142189/04 A RU2011142189/04 A RU 2011142189/04A RU 2011142189 A RU2011142189 A RU 2011142189A RU 2541476 C2 RU2541476 C2 RU 2541476C2
- Authority
- RU
- Russia
- Prior art keywords
- styrene
- rubber
- butadiene rubber
- butadiene
- polymer
- Prior art date
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract description 231
- 239000005062 Polybutadiene Substances 0.000 title claims description 9
- 229920002857 polybutadiene Polymers 0.000 title claims description 9
- 229920000642 polymer Polymers 0.000 claims abstract description 176
- 229920001971 elastomer Polymers 0.000 claims abstract description 115
- 239000005060 rubber Substances 0.000 claims abstract description 115
- 239000000203 mixture Substances 0.000 claims abstract description 94
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 68
- 238000006243 chemical reaction Methods 0.000 claims abstract description 66
- 238000004073 vulcanization Methods 0.000 claims abstract description 14
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 39
- 229920002554 vinyl polymer Polymers 0.000 claims description 35
- 230000009477 glass transition Effects 0.000 claims description 25
- 238000007306 functionalization reaction Methods 0.000 claims description 14
- 244000043261 Hevea brasiliensis Species 0.000 claims description 7
- 229920003052 natural elastomer Polymers 0.000 claims description 7
- 229920001194 natural rubber Polymers 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 2
- 238000005096 rolling process Methods 0.000 abstract description 18
- 239000000126 substance Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000005755 formation reaction Methods 0.000 abstract 1
- 238000004017 vitrification Methods 0.000 abstract 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 139
- 238000004364 calculation method Methods 0.000 description 47
- 238000006116 polymerization reaction Methods 0.000 description 47
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 45
- 239000000178 monomer Substances 0.000 description 41
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 33
- 238000005859 coupling reaction Methods 0.000 description 27
- 238000011068 loading method Methods 0.000 description 25
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 24
- 230000035484 reaction time Effects 0.000 description 23
- 238000000034 method Methods 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 20
- 238000005259 measurement Methods 0.000 description 16
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 13
- 238000009472 formulation Methods 0.000 description 12
- 238000005481 NMR spectroscopy Methods 0.000 description 11
- 239000003999 initiator Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000005299 abrasion Methods 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 8
- 238000010998 test method Methods 0.000 description 7
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000004448 titration Methods 0.000 description 6
- 101100383698 Secale cereale rscc gene Proteins 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 238000003795 desorption Methods 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000012258 stirred mixture Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- -1 (tertiary butyl) ethyl dimethoxyethane Chemical compound 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 239000003607 modifier Substances 0.000 description 4
- 238000001542 size-exclusion chromatography Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000009827 uniform distribution Methods 0.000 description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 108010072348 sperm releasing substance Proteins 0.000 description 3
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 3
- 238000002198 surface plasmon resonance spectroscopy Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000004442 gravimetric analysis Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- 101150061737 rbck1 gene Proteins 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- JQYYUWHWGCJWTN-UHFFFAOYSA-N 2-ethoxyoxolane Chemical compound CCOC1CCCO1 JQYYUWHWGCJWTN-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- 101100149706 Arabidopsis thaliana SMR10 gene Proteins 0.000 description 1
- 239000005065 High vinyl polybutadiene Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007707 calorimetry Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- 238000007571 dilatometry Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- IUJLOAKJZQBENM-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SNC(C)(C)C)=NC2=C1 IUJLOAKJZQBENM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000001448 refractive index detection Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/20—Incorporating sulfur atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16168009P | 2009-03-19 | 2009-03-19 | |
| US61/161,680 | 2009-03-19 | ||
| PCT/US2010/025150 WO2010107555A1 (en) | 2009-03-19 | 2010-02-24 | Styrene butadiene rubber with novel styrene incorporation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2011142189A RU2011142189A (ru) | 2013-04-27 |
| RU2541476C2 true RU2541476C2 (ru) | 2015-02-20 |
Family
ID=42313758
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2011142189/04A RU2541476C2 (ru) | 2009-03-19 | 2010-02-24 | Стирол-бутадиеновый каучук, характеризующийся новым включением стирола |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8648141B2 (enExample) |
| EP (1) | EP2408626B1 (enExample) |
| JP (1) | JP5571765B2 (enExample) |
| KR (1) | KR101726457B1 (enExample) |
| CN (1) | CN102341251B (enExample) |
| BR (1) | BRPI1006235A2 (enExample) |
| ES (1) | ES2406812T3 (enExample) |
| MX (1) | MX341648B (enExample) |
| PL (1) | PL2408626T3 (enExample) |
| RU (1) | RU2541476C2 (enExample) |
| SG (1) | SG173195A1 (enExample) |
| TW (1) | TWI482819B (enExample) |
| WO (1) | WO2010107555A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2886566B1 (de) * | 2013-12-20 | 2016-09-14 | Continental Reifen Deutschland GmbH | Kautschukmischung und Fahrzeugreifen |
| WO2016093282A1 (ja) * | 2014-12-10 | 2016-06-16 | 株式会社ブリヂストン | ゴム組成物の製造方法 |
| JP2016169268A (ja) * | 2015-03-11 | 2016-09-23 | 株式会社ブリヂストン | タイヤ用ゴム組成物の製造方法 |
| EP3385320B1 (en) * | 2017-04-05 | 2019-11-20 | Sumitomo Rubber Industries, Ltd. | Rubber composition and pneumatic tire |
| US20190062533A1 (en) * | 2017-08-31 | 2019-02-28 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| KR102301667B1 (ko) * | 2018-02-07 | 2021-09-14 | 주식회사 엘지화학 | 고무 조성물 |
| US10767034B2 (en) * | 2018-09-04 | 2020-09-08 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| EP3674110A1 (en) * | 2018-12-24 | 2020-07-01 | Bridgestone Europe NV/SA | Pneumatic tyre with strips positioned beneath the tread for the reduction of the noise of pneumatic tyres |
| IT201800021037A1 (it) * | 2018-12-24 | 2020-06-24 | Bridgestone Europe Nv Sa | Pneumatico con strisce posizionate al di sotto del battistrada per la riduzione del rumore dei pneumatici |
| JP7546402B2 (ja) * | 2020-08-03 | 2024-09-06 | 旭化成株式会社 | ポリマーブレンド及びその製造方法、並びに、それを用いたゴム組成物及び空気入りタイヤ |
| JP6809632B1 (ja) * | 2020-08-12 | 2021-01-06 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| JP7590639B2 (ja) * | 2020-10-23 | 2024-11-27 | 横浜ゴム株式会社 | タイヤ |
| JP7534624B2 (ja) * | 2020-10-23 | 2024-08-15 | 横浜ゴム株式会社 | タイヤ |
| US12209183B2 (en) * | 2021-03-16 | 2025-01-28 | The Goodyear Rubber & Tire Company | Pneumatic tire having tread with three elastomers |
| IT202100023213A1 (it) | 2021-09-08 | 2023-03-08 | Pirelli | Pneumatico per ruote di veicoli |
| IT202200010532A1 (it) | 2022-05-20 | 2023-11-20 | Pirelli | Pneumatico per ruote di veicoli |
| CN118146741B (zh) * | 2024-04-08 | 2024-09-06 | 江苏国立化工科技有限公司 | 一种提高橡胶钢丝粘合胶性能的工艺 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4396743A (en) * | 1980-12-26 | 1983-08-02 | Bridgestone Tire Company Limited | Rubber composition for tires containing block copolymer having vinyl bonds |
| GB2158076A (en) * | 1984-03-15 | 1985-11-06 | Japan Synthetic Rubber Co Ltd | Rubber compositions |
| EP0263054A2 (en) * | 1986-09-29 | 1988-04-06 | The Goodyear Tire & Rubber Company | Rubber composition |
| EP0483046A1 (en) * | 1990-10-22 | 1992-04-29 | The Goodyear Tire & Rubber Company | Process for preparing a rubbery terpolymer of styrene, isoprene and butadiene |
| RU2181367C2 (ru) * | 1998-11-20 | 2002-04-20 | Открытое акционерное общество "Балаковорезинотехника" | Резиновая смесь |
| EP1559586A1 (en) * | 2004-01-29 | 2005-08-03 | The Goodyear Tire & Rubber Company | Tire with component of rubber composition comprised of functionalized styrene/butadiene elastomer, silica and styrene/alpha methylstyrene resin |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3094512A (en) | 1959-12-31 | 1963-06-18 | Phillips Petroleum Co | Process for the preparation of low vinyl low trans content random copolymer |
| NL136672C (enExample) | 1962-07-13 | |||
| SU366723A1 (ru) | 1971-09-27 | 1974-10-05 | Способ получени статистических дивинилстирольных каучуков | |
| JPS6018978B2 (ja) * | 1980-03-05 | 1985-05-14 | 富士写真フイルム株式会社 | 写真感光材料 |
| SE453298B (sv) | 1980-03-07 | 1988-01-25 | Shell Int Research | Elastisk sampolymer lemplig for anvendning i deck och sett for framstellning derav |
| US4948849A (en) | 1980-03-07 | 1990-08-14 | Shell Internationale Research Maatschappij B.V. | Process for making copolymers of aromatic vinyl compounds ADD conjugated diolefins having substantial increase in aromatic vinyl compound differential content |
| JPS5893709A (ja) | 1981-11-30 | 1983-06-03 | Japan Synthetic Rubber Co Ltd | ウェットスキッド特性及び摩耗特性が改良されたゴム組成物 |
| JPH0618978B2 (ja) | 1985-10-30 | 1994-03-16 | 日本合成ゴム株式会社 | ゴム組成物 |
| JPH0788439B2 (ja) | 1987-12-23 | 1995-09-27 | 日本ゼオン株式会社 | 防振ゴム組成物 |
| US5241008A (en) | 1991-09-03 | 1993-08-31 | Bridgestone/Firestone, Inc. | Process for producing continuously tapered polymers and copolymers and products produced thereby |
| US6372863B1 (en) | 1999-08-12 | 2002-04-16 | The Goodyear Tire & Rubber Company | Synthesis of styrene-butadiene rubber |
| FR2804688B1 (fr) | 2000-02-07 | 2006-08-11 | Michelin Soc Tech | Utilisation d'une composition de caoutchouc pour retarder lors du roulage l'apparition de l'usure irreguliere sur une bande de roulement de pneumatique destinee a porter de lourdes charges |
| CN1266165C (zh) * | 2001-02-15 | 2006-07-26 | 日本弹性体股份有限公司 | 改性橡胶,生产它的方法和含有它的组合物 |
| US7441572B2 (en) | 2004-09-17 | 2008-10-28 | The Goodyear Tire & Rubber Company | Pneumatic tire having a tread containing immiscible rubber blend and silica |
| CN101319064B (zh) * | 2008-07-18 | 2011-03-30 | 北京化工大学 | 端基官能化溶聚丁苯橡胶填充白炭黑复合材料的制备方法 |
| JP6018978B2 (ja) * | 2013-06-17 | 2016-11-02 | 矢崎総業株式会社 | コネクタ |
-
2010
- 2010-02-24 CN CN201080010578.5A patent/CN102341251B/zh not_active Expired - Fee Related
- 2010-02-24 BR BRPI1006235A patent/BRPI1006235A2/pt not_active Application Discontinuation
- 2010-02-24 ES ES10705757T patent/ES2406812T3/es active Active
- 2010-02-24 KR KR1020117024579A patent/KR101726457B1/ko not_active Expired - Fee Related
- 2010-02-24 JP JP2012500814A patent/JP5571765B2/ja not_active Expired - Fee Related
- 2010-02-24 MX MX2011009744A patent/MX341648B/es active IP Right Grant
- 2010-02-24 US US13/255,756 patent/US8648141B2/en not_active Expired - Fee Related
- 2010-02-24 RU RU2011142189/04A patent/RU2541476C2/ru not_active IP Right Cessation
- 2010-02-24 PL PL10705757T patent/PL2408626T3/pl unknown
- 2010-02-24 WO PCT/US2010/025150 patent/WO2010107555A1/en not_active Ceased
- 2010-02-24 EP EP10705757.2A patent/EP2408626B1/en not_active Not-in-force
- 2010-02-24 SG SG2011055159A patent/SG173195A1/en unknown
- 2010-03-03 TW TW099106125A patent/TWI482819B/zh not_active IP Right Cessation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4396743A (en) * | 1980-12-26 | 1983-08-02 | Bridgestone Tire Company Limited | Rubber composition for tires containing block copolymer having vinyl bonds |
| GB2158076A (en) * | 1984-03-15 | 1985-11-06 | Japan Synthetic Rubber Co Ltd | Rubber compositions |
| EP0263054A2 (en) * | 1986-09-29 | 1988-04-06 | The Goodyear Tire & Rubber Company | Rubber composition |
| EP0483046A1 (en) * | 1990-10-22 | 1992-04-29 | The Goodyear Tire & Rubber Company | Process for preparing a rubbery terpolymer of styrene, isoprene and butadiene |
| RU2181367C2 (ru) * | 1998-11-20 | 2002-04-20 | Открытое акционерное общество "Балаковорезинотехника" | Резиновая смесь |
| EP1559586A1 (en) * | 2004-01-29 | 2005-08-03 | The Goodyear Tire & Rubber Company | Tire with component of rubber composition comprised of functionalized styrene/butadiene elastomer, silica and styrene/alpha methylstyrene resin |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2011009744A (es) | 2011-10-19 |
| US8648141B2 (en) | 2014-02-11 |
| TW201038674A (en) | 2010-11-01 |
| KR101726457B1 (ko) | 2017-04-12 |
| PL2408626T3 (pl) | 2013-09-30 |
| EP2408626A1 (en) | 2012-01-25 |
| CN102341251A (zh) | 2012-02-01 |
| CN102341251B (zh) | 2014-09-24 |
| MX341648B (es) | 2016-08-29 |
| JP5571765B2 (ja) | 2014-08-13 |
| KR20120004455A (ko) | 2012-01-12 |
| JP2012520926A (ja) | 2012-09-10 |
| TWI482819B (zh) | 2015-05-01 |
| US20120010356A1 (en) | 2012-01-12 |
| WO2010107555A1 (en) | 2010-09-23 |
| SG173195A1 (en) | 2011-08-29 |
| EP2408626B1 (en) | 2013-05-08 |
| ES2406812T3 (es) | 2013-06-10 |
| BRPI1006235A2 (pt) | 2016-04-12 |
| RU2011142189A (ru) | 2013-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2541476C2 (ru) | Стирол-бутадиеновый каучук, характеризующийся новым включением стирола | |
| RU2501816C2 (ru) | Стирол-бутадиеновые полимеры со стирольным градиентом и способы изготовления таковых | |
| KR101508465B1 (ko) | 말단 기능성 공액 디엔계 중합체 및 이의 제조방법 | |
| US9725526B2 (en) | Modified conjugated diene polymer, modified rubber composition comprising same, and method for producing modified conjugated diene polymer | |
| CN101821297B (zh) | 液体聚合物和官能化聚合物的合成 | |
| EP3093301A1 (en) | Modified conjugated diene polymer, modified rubber composition comprising same, and method for producing modified conjugated diene polymer | |
| KR102744315B1 (ko) | 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물 | |
| KR102744314B1 (ko) | 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물 | |
| RU2823863C1 (ru) | Модифицированный полимер на основе сопряженного диена, способ его получения и включающая его резиновая композиция | |
| JP2021509133A (ja) | 変性共役ジエン系重合体及びこれを含むゴム組成物 | |
| KR102799011B1 (ko) | 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물 | |
| RU2779347C2 (ru) | In-situ полимерная смесь для шин |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PD4A | Correction of name of patent owner | ||
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20200225 |