RU2531277C2 - Способ получения акролеина из глицерола или глицерина - Google Patents

Способ получения акролеина из глицерола или глицерина Download PDF

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Publication number
RU2531277C2
RU2531277C2 RU2011123484/04A RU2011123484A RU2531277C2 RU 2531277 C2 RU2531277 C2 RU 2531277C2 RU 2011123484/04 A RU2011123484/04 A RU 2011123484/04A RU 2011123484 A RU2011123484 A RU 2011123484A RU 2531277 C2 RU2531277 C2 RU 2531277C2
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RU
Russia
Prior art keywords
glycerol
catalyst
acrolein
metal
zirconium oxide
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RU2011123484/04A
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English (en)
Russian (ru)
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RU2011123484A (ru
Inventor
Виржини БЕЛЛИЕР-БАКА
Стефан ЛОРИДАН
Жан-Марк МИЛЛЕ
Паскалин ЛОРИОЛЬ-ГАРБЕ
Original Assignee
Адиссео Франс С.А.С.
Сентр Насьональ Де Ла Решерш Сьентифик
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
RU2011123484/04A 2008-12-16 2009-12-16 Способ получения акролеина из глицерола или глицерина RU2531277C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0858624A FR2939791B1 (fr) 2008-12-16 2008-12-16 Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
FR08/58624 2008-12-16
PCT/FR2009/052577 WO2010076510A2 (fr) 2008-12-16 2009-12-16 Procede de preparation d'acroleine a partir de glycerol ou de glycerine

Publications (2)

Publication Number Publication Date
RU2011123484A RU2011123484A (ru) 2013-01-27
RU2531277C2 true RU2531277C2 (ru) 2014-10-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2011123484/04A RU2531277C2 (ru) 2008-12-16 2009-12-16 Способ получения акролеина из глицерола или глицерина

Country Status (10)

Country Link
US (2) US20110288323A1 (https=)
EP (1) EP2365954B1 (https=)
JP (1) JP6116799B2 (https=)
KR (1) KR101778103B1 (https=)
CN (2) CN105837420B (https=)
ES (1) ES2709479T3 (https=)
FR (1) FR2939791B1 (https=)
RU (1) RU2531277C2 (https=)
SG (1) SG171721A1 (https=)
WO (1) WO2010076510A2 (https=)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2939791B1 (fr) 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
FR2961507B1 (fr) * 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
FR2966456B1 (fr) * 2010-10-26 2013-03-15 Adisseo France Sas Procede d'obtention d'acroleine par deshydratation catalytique de glycerol ou de glycerine
FR2997398B1 (fr) * 2012-10-30 2014-11-21 Adisseo France Sas Procede de preparation de l’acroleine a partir de glycerol
FR3001728B1 (fr) * 2013-02-04 2015-11-13 Adisseo France Sas Procede de preparation d’une olefine par conversion catalytique d’au moins un alcool
KR101616528B1 (ko) 2013-07-16 2016-04-28 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
WO2015168683A1 (en) 2014-05-02 2015-11-05 University Of Tennessee Research Foundation Novel glycerol dehydration methods and products thereof
CN104892382B (zh) * 2015-05-28 2017-08-11 珠海凯美科技有限公司 甘油液相氧化制备丙烯醛的方法
KR102052708B1 (ko) * 2015-12-22 2019-12-09 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
KR102044428B1 (ko) 2015-12-23 2019-12-02 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
KR102210508B1 (ko) * 2015-12-23 2021-02-01 주식회사 엘지화학 글리세린 탈수 반응용 촉매의 제조 방법 및 아크롤레인의 제조 방법
CN109305899B (zh) * 2017-07-28 2021-09-03 中国石油化工股份有限公司 甘油脱水生产丙烯醛的方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU52208A1 (ru) * 1936-04-22 1936-11-30 Ю.Н. Вольнов Способ получени акролеина из глицерина
SU1428193A3 (ru) * 1983-11-14 1988-09-30 Монсанто Компани (Фирма) Способ получени 2-окси-4-(метилтио)-масл ной кислоты
WO2006087083A2 (en) * 2005-02-15 2006-08-24 Arkema France Process for dehydrating glycerol to acrolein
US20080214384A1 (en) * 2007-01-29 2008-09-04 Hubert Redlingshofer Process for regenerating a catalyst
JP2008266165A (ja) * 2007-04-17 2008-11-06 Nippon Shokubai Co Ltd アクロレインの製造方法

Family Cites Families (18)

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DE102005003990A1 (de) * 2005-01-28 2006-08-03 Degussa Ag Herstellung von 3-(Alkylthio)propanal
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
FR2884818B1 (fr) * 2005-04-25 2007-07-13 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
WO2007058221A1 (ja) * 2005-11-15 2007-05-24 Nippon Shokubai Co., Ltd. 多価アルコールの脱水方法
JP4041512B2 (ja) 2006-03-30 2008-01-30 株式会社日本触媒 グリセリン脱水用触媒、グリセリン脱水用触媒の製造方法、アクロレインの製造方法、およびアクロレイン誘導体の製造方法
EP2018360A4 (en) 2006-05-12 2011-06-15 Nippon Catalytic Chem Ind PROCESS FOR PRODUCING ACROLEIN
TW200811086A (en) 2006-07-11 2008-03-01 Adisseo Ireland Ltd Process for preparing 2-hydroxy-4-(methylthio)butyronitrile and methionine
FR2907444B1 (fr) 2006-10-20 2008-12-19 Rhodia Recherches & Tech Composition a acidite elevee a base d'oxydes de zirconium,de silicium et d'au moins un autre element choisi parmi le titane,l'aluminium,le tungstene,le molybdene,le cerium,le fer et le manganese
FR2907445B1 (fr) 2006-10-20 2010-09-03 Rhodia Recherches & Tech Composition a acidite elevee a base d'oxyde de zirconium, d'oxyde de titane et d'oxyde de tungstene,procede de preparation et utilisation dans le traitement des gaz d'echappement
US8076509B2 (en) 2006-12-01 2011-12-13 Nippon Shokubai Co., Ltd. Process for producing acrylic acid
DE102007004351A1 (de) 2007-01-29 2008-07-31 Evonik Degussa Gmbh Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin
FR2920767B1 (fr) 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
WO2009127889A1 (en) 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
WO2009136537A1 (ja) 2008-04-16 2009-11-12 日本化薬株式会社 グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造方法
FR2938535B1 (fr) 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
FR2939791B1 (fr) 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
FR2954312B1 (fr) 2009-12-21 2012-02-10 Adisseo France Sas Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine
FR2961507B1 (fr) 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU52208A1 (ru) * 1936-04-22 1936-11-30 Ю.Н. Вольнов Способ получени акролеина из глицерина
SU1428193A3 (ru) * 1983-11-14 1988-09-30 Монсанто Компани (Фирма) Способ получени 2-окси-4-(метилтио)-масл ной кислоты
WO2006087083A2 (en) * 2005-02-15 2006-08-24 Arkema France Process for dehydrating glycerol to acrolein
US20080214384A1 (en) * 2007-01-29 2008-09-04 Hubert Redlingshofer Process for regenerating a catalyst
JP2008266165A (ja) * 2007-04-17 2008-11-06 Nippon Shokubai Co Ltd アクロレインの製造方法

Also Published As

Publication number Publication date
ES2709479T3 (es) 2019-04-16
KR20110094198A (ko) 2011-08-22
WO2010076510A3 (fr) 2010-10-14
FR2939791B1 (fr) 2011-01-14
SG171721A1 (en) 2011-07-28
RU2011123484A (ru) 2013-01-27
US20110288323A1 (en) 2011-11-24
US20140171676A1 (en) 2014-06-19
CN105837420A (zh) 2016-08-10
KR101778103B1 (ko) 2017-09-13
EP2365954B1 (fr) 2018-11-07
JP2012512236A (ja) 2012-05-31
CN105837420B (zh) 2019-09-13
JP6116799B2 (ja) 2017-04-19
WO2010076510A2 (fr) 2010-07-08
US9447009B2 (en) 2016-09-20
FR2939791A1 (fr) 2010-06-18
CN102245552A (zh) 2011-11-16
EP2365954A2 (fr) 2011-09-21

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