RU2487879C2 - Реакционноспособные фосфонаты - Google Patents
Реакционноспособные фосфонаты Download PDFInfo
- Publication number
- RU2487879C2 RU2487879C2 RU2009125470/04A RU2009125470A RU2487879C2 RU 2487879 C2 RU2487879 C2 RU 2487879C2 RU 2009125470/04 A RU2009125470/04 A RU 2009125470/04A RU 2009125470 A RU2009125470 A RU 2009125470A RU 2487879 C2 RU2487879 C2 RU 2487879C2
- Authority
- RU
- Russia
- Prior art keywords
- acid
- zpo
- phosphonate
- formula
- phosphonate compound
- Prior art date
Links
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 7
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 7
- 239000012736 aqueous medium Substances 0.000 claims abstract description 6
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 6
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 5
- 150000002367 halogens Chemical class 0.000 claims abstract description 5
- 229940071870 hydroiodic acid Drugs 0.000 claims abstract description 5
- 239000003599 detergent Substances 0.000 claims abstract description 4
- 239000002270 dispersing agent Substances 0.000 claims abstract description 4
- 239000011785 micronutrient Substances 0.000 claims abstract description 4
- 235000013369 micronutrients Nutrition 0.000 claims abstract description 4
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000002455 scale inhibitor Substances 0.000 claims abstract description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 4
- -1 phosphonate compound Chemical class 0.000 claims description 27
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 6
- 239000000543 intermediate Substances 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- 238000005342 ion exchange Methods 0.000 claims description 4
- 229940079593 drug Drugs 0.000 claims description 3
- 239000003814 drug Substances 0.000 claims description 3
- 239000003337 fertilizer Substances 0.000 claims description 3
- 229910001505 inorganic iodide Inorganic materials 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002609 medium Substances 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 2
- 101000932768 Conus catus Alpha-conotoxin CIC Proteins 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910001503 inorganic bromide Inorganic materials 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 238000003786 synthesis reaction Methods 0.000 abstract description 4
- 238000011084 recovery Methods 0.000 abstract description 2
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 239000013067 intermediate product Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 125000004122 cyclic group Chemical group 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 238000005481 NMR spectroscopy Methods 0.000 description 8
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 6
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000011521 glass Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 235000013405 beer Nutrition 0.000 description 2
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 229960003750 ethyl chloride Drugs 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- IHPRVZKJZGXTBQ-UHFFFAOYSA-N 3-chloropropan-1-amine;hydron;chloride Chemical compound Cl.NCCCCl IHPRVZKJZGXTBQ-UHFFFAOYSA-N 0.000 description 1
- TVEXGJYMHHTVKP-UHFFFAOYSA-N 6-oxabicyclo[3.2.1]oct-3-en-7-one Chemical compound C1C2C(=O)OC1C=CC2 TVEXGJYMHHTVKP-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000006683 Mannich reaction Methods 0.000 description 1
- GWASTCVCPXFIQT-UHFFFAOYSA-N NC1OP(=O)O1 Chemical compound NC1OP(=O)O1 GWASTCVCPXFIQT-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000012445 acidic reagent Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001513 alkali metal bromide Inorganic materials 0.000 description 1
- 125000006294 amino alkylene group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 150000001539 azetidines Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- LHCGBIFHSCCRRG-UHFFFAOYSA-N dichloroborane Chemical class ClBCl LHCGBIFHSCCRRG-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000012048 reactive intermediate Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06025515A EP1932849A1 (en) | 2006-12-11 | 2006-12-11 | Reactive phosphonates |
| EP06025515.5 | 2006-12-11 | ||
| PCT/EP2007/063685 WO2008071691A2 (en) | 2006-12-11 | 2007-12-11 | Reactive phosphonates |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012114235/04A Division RU2012114235A (ru) | 2006-12-11 | 2012-04-12 | Реакционноспособные фосфонаты |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2009125470A RU2009125470A (ru) | 2011-01-20 |
| RU2487879C2 true RU2487879C2 (ru) | 2013-07-20 |
Family
ID=37959907
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2009125470/04A RU2487879C2 (ru) | 2006-12-11 | 2007-12-11 | Реакционноспособные фосфонаты |
| RU2012114235/04A RU2012114235A (ru) | 2006-12-11 | 2012-04-12 | Реакционноспособные фосфонаты |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012114235/04A RU2012114235A (ru) | 2006-12-11 | 2012-04-12 | Реакционноспособные фосфонаты |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20100063316A1 (enExample) |
| EP (3) | EP1932849A1 (enExample) |
| JP (2) | JP2010512371A (enExample) |
| CN (1) | CN101589054A (enExample) |
| BR (1) | BRPI0720094A2 (enExample) |
| CA (1) | CA2671316A1 (enExample) |
| MX (1) | MX314942B (enExample) |
| RU (2) | RU2487879C2 (enExample) |
| WO (1) | WO2008071691A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017039483A1 (ru) * | 2015-09-01 | 2017-03-09 | Общество с ограниченной ответственностью "Красная звезда" | Вещество для очистки сточных вод и способ его получения |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2112156A1 (en) * | 2008-04-25 | 2009-10-28 | Thermphos International B.V. | Method for the Manufacture of Aminoalkylene Phosphonic Acid |
| US8580097B2 (en) | 2009-04-27 | 2013-11-12 | Wako Pure Chemical Industries, Ltd. | Isotachophoresis of blood-derived samples |
| WO2011005510A2 (en) * | 2009-06-22 | 2011-01-13 | Cerapedics, Inc. | Peptide conjugates and uses thereof |
| FR2974090B1 (fr) | 2011-04-15 | 2013-05-31 | Chryso | Copolymeres a groupements gem-bisphosphones |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2335331A1 (de) * | 1972-07-11 | 1974-02-21 | Betz Laboratories | Verfahren zur korrosionshemmung in waessrigen systemen |
| DE2423881A1 (de) * | 1973-05-17 | 1974-12-05 | Monsanto Co | Phosphonomethylenaminocarbonsaeureverbindungen und verfahren zu ihrer herstellung |
| US4187245A (en) * | 1975-06-02 | 1980-02-05 | Petrolite Corporation | Hydroxypropylene-amino-phosphonic-sulfonic acids |
| US4707306A (en) * | 1986-12-11 | 1987-11-17 | National Starch And Chemical Corporation | Alpha-aminomethylene phosphonate betaines and polymers prepared therewith |
| EP0401833A2 (en) * | 1989-06-08 | 1990-12-12 | National Starch and Chemical Investment Holding Corporation | Aminophosphonate-Containing Polymers |
| EP0617008A1 (en) * | 1993-01-20 | 1994-09-28 | Aminkemi Ab | Iron chelate solutions |
| US5414112A (en) * | 1993-11-09 | 1995-05-09 | Nalco Chemical Company | N-bis(phosphonomethyl) amino acids and their use as scale inhibitors |
| EP0711733A1 (en) * | 1994-11-10 | 1996-05-15 | Calgon Corporation | Polyether polyamino methylene phosphonates for high pH scale control |
| US5945240A (en) * | 1995-12-27 | 1999-08-31 | Fuji Photo Film Co., Ltd. | Direct drawing type lithographic printing plate precursor |
| WO2002078448A1 (en) * | 2001-03-29 | 2002-10-10 | Nufarm Australia Limited | Insecticide and method of controlling insects |
| EP1887011A1 (en) * | 2006-08-09 | 2008-02-13 | Thermphos Trading GmbH | Alpha amino acid phosphonic acid compounds, method of preparation and use thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2841611A (en) * | 1954-09-01 | 1958-07-01 | Dow Chemical Co | Nu-alkyl substituted alkylene polyamine methylene phosphonic acids |
| JPS52100452A (en) * | 1976-02-19 | 1977-08-23 | Nissan Chem Ind Ltd | Preparation of n-phosphonomethyl-aniline derivatives |
| US4260738A (en) | 1980-01-10 | 1981-04-07 | National Starch And Chemical Corporation | Novel starch ether derivatives, a method for the preparation thereof |
| US4297299A (en) | 1980-01-10 | 1981-10-27 | National Starch And Chemical Corporation | Novel N-(alkyl)-N-(2-haloethyl)-aminomethylphosphonic acids, a method for the preparation thereof and their use in the preparation of starch ether derivatives |
| US4330487A (en) | 1980-10-29 | 1982-05-18 | Petrolite Corporation | N,N-Dimethylene phosponic acids of alkylene diamines |
| FR2696736B1 (fr) | 1992-10-12 | 1994-12-30 | Chryso | Fluidifiants pour suspensions aqueuses de particules minérales et pâtes de liant hydraulique. |
| ITMI20021706A1 (it) * | 2002-07-31 | 2004-02-01 | Bozzetto Giovanni Spa | Poliamminomeilenfosfono derivati. |
| US7297813B2 (en) * | 2004-08-05 | 2007-11-20 | Arkema Inc. | Removal of alkyl alkanesulfonate esters from alkanesulfonic acids and other organic media |
-
2006
- 2006-12-11 EP EP06025515A patent/EP1932849A1/en not_active Withdrawn
-
2007
- 2007-12-11 MX MX2009006164A patent/MX314942B/es active IP Right Grant
- 2007-12-11 BR BRPI0720094-3A2A patent/BRPI0720094A2/pt not_active IP Right Cessation
- 2007-12-11 EP EP12161861A patent/EP2484684A1/en not_active Withdrawn
- 2007-12-11 CN CNA2007800459025A patent/CN101589054A/zh active Pending
- 2007-12-11 JP JP2009540749A patent/JP2010512371A/ja active Pending
- 2007-12-11 EP EP07857377A patent/EP2125843B1/en not_active Not-in-force
- 2007-12-11 CA CA002671316A patent/CA2671316A1/en not_active Abandoned
- 2007-12-11 RU RU2009125470/04A patent/RU2487879C2/ru not_active IP Right Cessation
- 2007-12-11 WO PCT/EP2007/063685 patent/WO2008071691A2/en not_active Ceased
- 2007-12-11 US US12/518,694 patent/US20100063316A1/en not_active Abandoned
-
2012
- 2012-04-12 RU RU2012114235/04A patent/RU2012114235A/ru not_active Application Discontinuation
-
2014
- 2014-01-09 JP JP2014002216A patent/JP2014097998A/ja not_active Abandoned
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2335331A1 (de) * | 1972-07-11 | 1974-02-21 | Betz Laboratories | Verfahren zur korrosionshemmung in waessrigen systemen |
| DE2423881A1 (de) * | 1973-05-17 | 1974-12-05 | Monsanto Co | Phosphonomethylenaminocarbonsaeureverbindungen und verfahren zu ihrer herstellung |
| US4187245A (en) * | 1975-06-02 | 1980-02-05 | Petrolite Corporation | Hydroxypropylene-amino-phosphonic-sulfonic acids |
| US4707306A (en) * | 1986-12-11 | 1987-11-17 | National Starch And Chemical Corporation | Alpha-aminomethylene phosphonate betaines and polymers prepared therewith |
| EP0401833A2 (en) * | 1989-06-08 | 1990-12-12 | National Starch and Chemical Investment Holding Corporation | Aminophosphonate-Containing Polymers |
| EP0617008A1 (en) * | 1993-01-20 | 1994-09-28 | Aminkemi Ab | Iron chelate solutions |
| US5414112A (en) * | 1993-11-09 | 1995-05-09 | Nalco Chemical Company | N-bis(phosphonomethyl) amino acids and their use as scale inhibitors |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017039483A1 (ru) * | 2015-09-01 | 2017-03-09 | Общество с ограниченной ответственностью "Красная звезда" | Вещество для очистки сточных вод и способ его получения |
Also Published As
| Publication number | Publication date |
|---|---|
| MX314942B (es) | 2013-11-01 |
| RU2009125470A (ru) | 2011-01-20 |
| JP2010512371A (ja) | 2010-04-22 |
| BRPI0720094A2 (pt) | 2014-10-07 |
| WO2008071691A3 (en) | 2008-10-02 |
| EP2125843B1 (en) | 2012-11-14 |
| WO2008071691A2 (en) | 2008-06-19 |
| JP2014097998A (ja) | 2014-05-29 |
| EP2125843A2 (en) | 2009-12-02 |
| RU2012114235A (ru) | 2013-10-20 |
| CA2671316A1 (en) | 2008-06-19 |
| EP1932849A1 (en) | 2008-06-18 |
| EP2484684A1 (en) | 2012-08-08 |
| MX2009006164A (es) | 2009-06-19 |
| US20100063316A1 (en) | 2010-03-11 |
| CN101589054A (zh) | 2009-11-25 |
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